北半球中高纬度对流层顶转换层中O3/H2O 混合关系的结构形态

利用北半球40°N～50°N纬度带上HALOE实验测量的O₃和H₂O廓线资料,根据示踪成分O₃和H₂O空间分布的化学寿命以及输运特征时间常数等性质,在等熵坐标中构建了对流层顶附近及最低平流层300～390 K等熵面间,O₃/H₂O混合关系的结构形态和季节特征.结果表明: (1) 在对流层顶转换层的320～380 K等熵面间O₃混合比廓线的斜率具有空间转折"突变",而H₂O混合比廓线的斜率则出现空间渐变转折.在对流层顶附近O₃和H₂O的源分别是平流层与对流层,使O₃混合比和H₂O混合比在320～380 K等熵面的两侧显现出截然不同的垂直分布梯度.(2) 在对流层顶附近O₃/H₂O达到最小二乘意义上的最佳拟合时,两者参考关系的对流层支与平流层支呈现出非规则"L"结构形态的季节与季节内变化,其中对流层支的斜率为负,而平流层支的斜率可随季节出现正负变化.同时,由"L"形态的转角处可确定随季节变化的化学对流层顶(chemopause)特征.(3) 由O₃/H₂O混合关系反映出对流层不同区域空气携带的物质成分分别与平流层空气混合而形成混合层,而且可使混合层的混合线不恒定.混合层的表现在2003年、2005年1月和2003年4月的混合程度相当,混合的等熵厚度大约是30 K,即在320～350 K等熵面间.2005年11月的混合高度有所增高,进入平流层的H₂O混合比要比2003年和2005年1月的小,混合的等熵厚度大约为30 K,在330～360 K等熵面间.不同季节混合的等熵厚度变化较小,但高度可随季节而变化.O₃/H₂O混合关系的平流层支随季节的变化很明显,1月最低平流层空气脱水是引起平流层支季节变化的重要原因.     

Accretion, core formation, H and C evolution of the Earth and Mars

Recent understandings of planetary accretion have suggested that accumulation of a small number of large planetesimals dominates intermediate to final growth stages of the terrestrial planets, with impact velocity high enough to induce extensive melting of the planetesimal and target materials, resulting in formation of a large molten region in which gravitational segregation of silicate and metal, that is, core formation proceeds. In case of homogeneous accretion, volatiles contained in each planetesimal are likely subjected to partitioning among gas, silicate melt, and molten metallic iron at significantly high temperatures and pressures in such a massive molten region. Each phase would subsequently form the proto-atmosphere, -mantle, or-core, respectively. Such chemical reprocessing of H and C associated with core formation, which is followed by both degassing from mantle and atmospheric escape, may result in a diverse range of H₂O/CO₂ in planetary surface environments, which mainly depends on the H and C content relative to metallic iron in planetary building stones. This may explain inferred difference in volatile distribution between the Earth's (relatively H₂O-rich, CO₂-poor) and the martian (H₂O-poor, CO₂-rich) surface environments. Such volatile redistribution may be systematically described by using the retentivity of H₂O, ξ, defined as follows: ξ = 1 − ([CO]⁰ + 2[CH₄]⁰ + 2[C(gr)]⁰)/[H₂O]⁰, where [i]⁰ represents mol number of species i partitioned into non-metallic phases, that is, gas and silicate melt in impact-induced molten region. When ξ > 0.5, relatively H₂O-rich and CO₂-poor surface environment may eventually evolve, although a small portion of H₂O partitioned into the NON=metallic phases are possibly consumed by subsequent chemical reactions with reduced C-species with producing CO₂ and H₂. When ξ< 0.5, on the contrary, H₂O consumption by the above reactions and selective loss of H₂ to space may result in relative H₂O-depleted and CO₂-rich surface environment. Given the building stone composition by the two-component model by Ringwood (1977) and Wänke (1981), ξ is found to decrease with increasing the mixing fraction of the volatile-rich component: ξ > 0.5 for the mixing fraction smaller than about 15–20% and ξ < 0 for the mixing fraction larger than about 20–30%. This is not significantly dependent on temperature and pressure in molten region and H/C ratio in the building stone. The estimated mixing fraction of the volatile-rich component, about 10% for the Earth and 35% for Mars, is consistent with the observed difference in volatile distribution between the surfaces of both planets.     

A COMPARATIVE STUDY ON THE CHARACTERISTICS OF TWO STAGES OF FALLOUT PUMICES DEPOSITS FROM THE MILLENNIUM ERUPTION OF TIANCHI VOLCANO IN CHANGBAISHAN AREA

Tianchi volcano in Changbaishan area is located at the border between China and Democratic People's Republic of Korea, and is one of the most dangerous volcanoes in China. It has experienced several explosive eruptions in late Pleistocene and Holocene, i.e. 50000aBP eruption, 946 AD eruption, 1668 AD eruption, 1702 AD eruption, 1903 AD eruption. Especially, the 946 AD eruption(also known as "Millennium eruption")of this volcano is considered to be one of the largest volcanic eruptions in the world in the past 2000a. The eruption history and strata sequence of Tianchi volcano have long been the focus of attention. The stratigraphic unit division of fallout deposits in the past millennium is controversial, especially for the heterogeneous trachytic pumices(erupted from the Yuanchi stage)above the off-white pumices(erupted from the Chifeng stage). In this paper, through the detailed field exploration and strata comparation, it was found that there was no depositional interval between the two stage eruptions, or the interval was not long, and thus, it is believed that two stages of fallout pumice should be classified into the Millennium eruption. The off-white fallout pumices in Chifeng stage are relatively homogeneous, with angular shape, normal grading and good sorting. The median size(Md_Φ)and the sorting coefficient(σ_Φ)of Chifeng pumice are in the range of -4.25~-1.3 and 0.93~1.53, respectively. The eruption of Yuanchi stage is in pulsing pattern, and the strata show interbedding of rich khaki pumice layer and rich black pumice layer. The pumices with angular shape show inconspicuous grain grading and good sorting. The median size(Md_Φ)and the sorting coefficient(σ_Φ)of Yuanchi pumice are in the range of -2.55~-0.6 and 1~1.68, respectively. Both the granularities of the pumice particles from two stages are normally distributed and fall into the air-fall field in the median diameter versus sorting diagram. The pumices from 50000aBP and pyroclastic flow of Millennium eruption were also shown in the diagram. Phenocrysts in pumices are mainly feldspar and pyroxene, but the phenocrysts with obvious resorbed characteristic in Yuanchi black pumice are bigger, and the phenocryst contents are a little higher than those in others. Feldspar content in off-white pumice in Chifeng stage was 0.24%~1.77%, that in khaki pumice in Yuanchi stage was 0.2%~7.5%, and that in black pumice in Yuanchi stage was 3.02%~8.0%. The phenocrysts in Chifeng pumice are broken, which represents more violent explosion. The vesicles inside the pumice also reflect the intensity of the eruption. The Chifeng pumices have large, continuous vesicles and thin vesicle walls. The Yuanchi khaki pumices have continuous vesicles but thicker vesicle wall than the Chifeng pumices. The vesicularity is the lowest and the vesicle walls are the thickest in the black pumices in Yuanchi stage, indicating the eruption strength become weaker from Chifeng stage to Yuanchi stage. The Chifeng pumices with SiO₂ content of 69.12~72.71wt%, K₂O content of 4.33~4.52wt%, Na₂O content of 5.26~5.39wt%, Al₂O₃ content of 10.32~11.99wt%, CaO content of 0.29~0.95wt%, MgO content of 0.11~0.51wt%, TiO₂ content of 0.23~0.43wt% are comendite in composition. The pumices from 50000aBP eruption are comendite in composition, and their SiO₂ content(65.56~68.28wt%)is slightly lower than Chifeng pumices. The Yuanchi khaki pumices with SiO₂ content of 62.14~63.29wt%, K₂O content of 5.35~5.7wt%, Na₂O content of 5.35~5.62wt%, Al₂O₃ content of 15.00~15.59wt%, CaO content of 1.06~1.61wt%, MgO content of 0.25~0.57wt%, TiO₂ content of 0.4~0.64wt% belong to trachyte in composition, and are close to the composition of the black pumices on the Tianwen Peak. The Yuanchi black pumices are also trachyte in composition, but have obviously lower SiO₂(59.51~60.59wt%), K₂O(4.39~4.84wt%), and Na₂O(4.94~5.08wt%)content, and higher Al₂O₃(15.81~16.42wt%), CaO(2.78~3.66wt%), MgO(1.43~1.9wt%), TiO₂(1.04~1.4wt%)content than the khaki pumices. The above results show that the eruptive intensity of the Yuanchi stage is weaker than that of the Chifeng stage and the several magmatic compositions of pumices from the Millennium eruption reveal a complex magma system under the Tianchi volcano. The magma layers with different compositions may exist in the magma chamber contemporaneously. At Chifeng stage, only the upper comendite magma erupted, but the magma below erupted in the pulsing pattern at the Yuanchi stage.     

Non-volatile vs volatile behaviours of halogens during the AD 79 plinian eruption of Mt. Vesuvius, Italy

Pre-eruptive conditions and degassing processes of the AD 79 plinian eruption of Mt. Vesuvius are constrained by systematic F and Cl measurements in melt inclusions and matrix glass of pumice clasts from a complete sequence of the pumice-fallout deposits. The entire ‘white pumice’ (WP) magma and the upper part of the ‘grey pumice’ (GP) magma were saturated relative to sub-critical fluids (a Cl-rich H₂O vapour phase and a brine), with a Cl melt content buffered at ~ 5300 ppm, and a mean H₂O content of ~ 5%. The majority of the GP magma was not fluid-saturated. From these results it can be estimated that the WP magma chamber had a low vertical extent (< 500 m) and was located at a depth of ~ 7.5 km while the GP magma reservoir was located just beneath the WP one, but its vertical extent cannot be constrained. This is approximately two times deeper than previous estimates. H₂O degassing during the WP eruption followed a typical closed-system evolution, whereas GP clasts followed a more complex degassing path. Contrary to H₂O, Cl was not efficiently degassed during the plinian phase of the eruption.

This study shows that F and Cl behave as incompatible elements in fluid-undersaturated phonolitic melts. H₂O saturation is necessary for a significant partitioning of Cl into the fluid phase. However, Cl cannot be extracted in significant quantity from phonolitic melts during rapid H₂O degassing, e.g. during plinian eruptions, due to kinetics effects. Halogen contents are better preserved in volcanic glass (melt inclusions or matrix glass) than H₂O, therefore the combined analysis of both volatile species is required for reliable determination of pre-eruptive conditions and syn-eruptive degassing processes in magmas stored at shallow depths.     

Low-degree partial melting trends recorded in upper mantle minerals

The study of glass inclusions inside mantle minerals provides direct information about the chemistry of naturally occurring mantle-derived melts and the fine-scale complexity of the melting process responsible for their genesis. Minerals in a spinel lherzolite nodule from Grande Comore island contain glass inclusions which, after homogenization by heating, exhibit a continuous suite of chemical compositions clearly distinct from that of the host basanitic lava. The compositions range from silicic, with nepheline–olivine normative, 64 wt% SiO₂ and 11 wt% alkali oxides, to almost basaltic, with quartz normative, 50 wt% SiO₂ and 1–2 wt% alkali oxides. Within a single mineral phase, olivine, the inferred primary melt composition varies from 54 to 64 wt% SiO₂ for MgO content ranging from 8 to 0.8 wt%. An experimental study of the glass and fluid inclusions indicates that trapped melts represent liquids that are in equilibrium with their host phases at moderate temperature and pressure (T≈1230°C and P≈1.0 Gpa for melts trapped in olivine). Quantitative modelling of the compositional trends defined in the suite shows that all of the glasses are part of a cogenetic set of melts formed by fractional melting of spinel lherzolite, with F varying between 0.2 and 5%. The initial highly silicic, alkali-rich melts preserved in Mg-rich olivine become richer in FeO, MgO, CaO and Cr₂O₃ and poorer in SiO₂, K₂O, Na₂O, Al₂O₃ and Cl with increasing melt fractions, evolving toward the basaltic melts found in clinopyroxene. These results confirm the connection between glass inclusions inside mantle minerals and partial mantle melts, and indicate that primary melts with SiO₂ >60 wt%, alkali oxides >11%, FeO <1 wt% and MgO <1 wt% are generated during incipient melting of spinel peridotite. The composition of the primary melts is inferred to be dependent on pressure, and to reflect both the speciation of dissolved CO₂ and the effect of alkali oxides on the silica activity coefficient in the melt. At pressures around 1 GPa, low-degree melts are characterized by alkali and silica-rich compositions, with a limited effect of dissolved CO₂ and a decreased silica activity coefficient caused by the presence of alkali oxides, whereas at higher pressures alkali oxides form complexes with carbonates and, consequently, alkali-rich silica-poor melts will be generated.     

An evaluation of the global variations in the major element chemistry of arc basalts

Arc volcanoes occur at convergent margins with a wide range in subduction parameters, and variations in these parameters might be expected to lead to variations in the chemistry of magmas parental to arcs. Major element analyses from approximately 100 volcanic centers within 30 arcs, normalized to 6% MgO to minimize the effects of crystal fractionation, display wide variations. Na₂O and CaO at 6% MgO (Na_6.0 and Ca_6.0) correlate remarkably well with the thickness of the overlying crust. These systematics are consistent with two possible models. In the first model, the crust behaves as a chemical filter; where the crust is thick, magmas crystallize at higher pressure and interact more extensively with the arc crust. Modeling of high-pressure crystallization and assimilation, however, does not reproduce the associated variations in Na_6.0 and Ca_6.0 without calling upon complicated combinations of fractionating phases and assimilants. In the second model, crustal thickness determines the height of the mantle column available for melting beneath arc volcanoes. If melting begins beneath arcs at similar depths, then the column of mantle that undergoes decompression melting is much shorter beneath the thickest arc crust. The shorter mantle column for arcs built on thick crust will lead to smaller extents of melting in the mantle, and hence higher Na_6.0 and lower Ca_6.0 in the parental magmas. Modeling shows that variations in the extent of melting in the mantle can easily account for the associated variations in Ca_6.0 and Na_6.0. The abundances of the other major elements at 6% MgO do not correlate well with crustal thickness, or any other subduction parameter. Co-variation of some of these other major elements (e.g., Si_6.0 and Fe_6.0) within individual arcs suggests that they are strongly influenced by local crustal level processes that obscure partial melting systematics. Correction for the crustal processes improves the relationship between Na_6.0 and Ca_6.0 that is so readily explained by partial melting. The extents of melting in the mantle beneath arc volcanoes estimated from the ranges in Na_6.0 and Ca_6.0 are remarkably similar to those estimated beneath mid-ocean ridges. This observation provides further evidence that the mantle wedge, and not the slab, melts beneath arc volcanic fronts.     

利用超导重力数据检测日本Mw9.0地震的低频自由振荡及谱线分裂

准确估计低频自由振荡及谱线分裂是约束地球内部结构和改进地球模型的重要手段.本文利用四个不同台站的超导重力观测数据系统研究了日本M_w9.0大地震激发的低于1.5 mHz自由振荡及谱线分裂.研究结果表明:(1)选取适当的数据长度,超导重力观测数据可以检测出低于1.5 mHz除₁S₁以外的所有自由振荡;(2)除₀S₂、₀S₃、₀S₀、₂S₁、₃S₁、₁S₂和₀T₂外,重点探测出₃S₂、₀S₄和₁S₄谱线分裂的所有谱峰;(3)与PREM模型理论频率相比,₀S₀观测频率平均向右偏移0.354×10^-3mHz,说明PREM理论模型中地幔底部参数与真实地球可能存在微小偏差;(4)₃S₂的谱线分裂率r为1.485267,比PREM理论谱线分裂宽度约宽50%,表明PREM中地球内核中部介质参数可能存在一定误差,需要进一步改善.另外,quasi-₀T₂的r为1.254206,比PREM理论谱线分裂宽度约宽25%.     

Artificial watershed acidification on the Fernow Experimental Forest, USA

A whole-watershed manipulation project was begun on the Fernow Experimental Forest in West Virginia, USA, in 1987, with the objective of increasing understanding of the effects of acidic deposition on forest ecosystems. Two treatment watersheds (WS9 and WS3) and one control watershed (WS4) were included. Treatments were twice-ambient N and S deposition, applied via NH₄SO₄ fertilizer, with three applications per year. Three years of pretreatment data were collected and used for calibration. Stream water chemistry data collected during 3 years of treatment were evaluated. Stream water pH and electrical conductivity were not significantly affected by the elevated N and S inputs on either treatment watershed. On WS9, there were no statistically significant treatment effects on stream water export of Ca, SO₄, or NO₃. On WS3, however, stream export of both NO₃ and Ca have increased as a result of acidification treatments. The implications of these results are discussed. Research is continuing so that the processes involved may be elucidated. In addition, effects on vegetation, aquatic invertebrates and amphibians also are being evaluated.     

利用张家口地震台体应变观测资料检测地球自由振荡

在保证低频自由振荡信号分辨率,又不对高频自由振荡信号产生抑制效应的前提下,利用张家口地震台体应变观测资料,采用功率谱密度估计方法,获得2011年3月11日日本9.0级大地震激发的₀S₂-₀S₇₄基频球型振荡和17个谐频球型振荡（₃S₂、₅S₃、₂S₁₀、₂S₁₂、₃S₉、₁₁S₁、₇S₁₀、₅S₁₃、₄S₁₈、₅S₁₄、₁₄S₄、₄S₂₄、₁S₃₈、₇S₁₈、₁₄S₈、₉S₁₉、₅S₃₀）,并与地球初步参考模型（PREM）的理论自由振荡周期进行对比,发现与实测振荡周期基本一致。     

Primary differences in oxygen fugacity and depth of melting in the mantle source regions for oceanic basalts

Most abyssal basalt can be divided into two groups based on major and minor element compositions of the glassy rinds of pillow lavas. Crystal differentiation models cannot relate one group to the other. Instead, depth of partial melting may exert the primary control. The first group (MORB-1) is characterized by low TiO₂ and Na₂O and higher MgO, and is derived from a primary melt originating from the spinel peridotite facies. The higher TiO₂-NaO₂ group (MORB-2) appears to have been derived from the lower-pressure (shallower depth) plagioclase peridotite facies. Mössbauer spectra show that MORB-1 is from a mantle source region with lower oxidation states (between the QFM and NNO buffers) than for MORB-2 (around the NNO buffer).     

The impact of freshwater and wastewater irrigation on the chemistry of shallow groundwater: a case study from the Israeli Coastal Aquifer

Differences in the impact of irrigation with freshwater versus wastewater on the underlying shallow groundwater quality were investigated in the Coastal Aquifer of Israel. Seven research boreholes were drilled to the top-most 3–5 m of the saturated zone (the water table region-WTR) in the agricultural fields. The unsaturated zone and the WTR below the irrigated fields consist mainly of clayey sands, while the main aquifer comprises mainly of calcareous sandstones and sands. We show that the salinity and composition of the groundwater at the WTR are highly variable over a distance of less than 1 km and are controlled by the irrigating water and the processes in the overlying unsaturated zone. Tritium data in this groundwater (4.6 tritium units (TU)) support that these water are modern recharge. The water at the WTR is more saline and has a different chemical composition relative to the overlying irrigation water. High SAR values (sodium adsorption ratio) in wastewater irrigation lead to absorption of Na⁺ onto the clay and release of Ca²⁺ into the recharging water, resulting in low Na/Cl (0.4 compared to 1.2 in the wastewater) and high Ca/Cl ratios. In contrast, in the freshwater-irrigated field the irrigation water pumped from the aquifer (Na/Cl=0.9; SAR=0.6) is modified into Na-rich groundwater (Na/Cl=2.0) due to reverse base-exchange reactions. The high NO₃ concentration (>100 mg/l) in the WTR below both fields is derived from the agricultural activities. In the freshwater field, the source of NO₃ is fertilizer leachates, whereas in the wastewater field, where less fertilizers are applied, nitrate is probably derived from nitrification of the NH₄ in the wastewater. Some of the original inorganic nitrogen in the wastewater is consumed by the agricultural plants, resulting in a lower inorganic-N/Cl ratio in the WTR as compared to that in the wastewater. This study demonstrates the important role of the composition of irrigation water, combined with lithology and land use, in determining the quality of the water that recharge the aquifer below agricultural fields.     

鲁科一井上白垩统沉积岩岩石磁学和天然剩磁分析:兼论利用剩磁方向恢复钻孔岩芯原始方位的可行性

本文对"鲁科一井"(CCSD-LK-Ⅰ)768.9~1112.3m之间的上白垩统沉积岩样品进行了岩石磁学、磁化率各向异性(AMS)以及天然剩磁组分的研究.在此基础上,分析了利用特征剩磁(ChRM)和黏滞剩磁(VRM)方向恢复岩芯原始方位的可行性.三轴等温剩磁热退磁曲线、磁滞回线、反向场退磁曲线、一阶反转曲线等岩石磁学测量结果表明,沉积岩的主要载磁矿物为磁铁矿和赤铁矿.335块样品的AMS测量结果表明磁化率椭球主轴的最大轴K1和中间轴K2与水平面夹角较小,最小轴K3接近垂直于水平面分布,说明沉积岩保留了原始沉积磁组构特征.系统热退磁实验表明,多数样品在25~350℃和500~690℃温度段分别获得VRM和ChRM分量.利用ChRM偏角方向,并考虑构造旋转量校正,对VRM偏角方向进行恢复,Fisher统计得到DVRM=-1.3°,IVRM=59.6°,与当地现代地磁场方向(D=-6.7°,I=53.9°)基本一致.用ChRM偏角方向对磁化率主轴K1偏角方向进行校正,校正的结果为:D_(ch_K1)=349.2°,I_(ch_K1)=-0.7°.本文研究结果对于地质勘探中利用古地磁学方法恢复钻孔岩芯原始方位具有一定参考意义.     

地下水位的混沌和多重分形特征演化及其中短期预报意义

采用苏20井记录到的1995年7月1日至1997年6月30日地下水位观测数据作为研究的原始资料,计算并研究了1996年11月9日南黄海 M_S 6.1地震前后地下水位系统混沌吸引子的关联维数D₂、二阶熵K₂和最大Lyapunov指数λ₁,并用推广GP法研究了地震前后系统多重分形的广义维数谱D_q。研究结果表明:地下水位系统为混沌系统,系统的自由度在3~16之间;地震过程中系统有降维减熵现象,震前广义维数谱D_q左半边曲线变陡,因而可被看作为强震前的前兆信息。此结果对今后在预报工作中认识地震前兆观测的非线性动力学特征和利用这些特征进行地震预报具有重要的实用意义。     

Characterization of sewage sludge and toxicity evaluation with microalgae

Heavy metal contents (Cd, Cr, Cu, Pb, Ni and Zn) of digested sludge, collected from sewage treatment works (Shatin (ST), Shek Wu Hui (SWH), Tai Po (TP) and Yuen Long (YL)) in 1992, 1993 and 1994, were analysed by atomic absorption spectrophotometry after sequential extraction by 1 KNO₃, 0.5 KF, 0.1 Na₄P₂O₇, 0.1 EDTA and 6 HNO₃. It was found that the major forms of Cu, Pb, Ni and Zn were in the sulphide phase, organically-bound phase, adsorbed phase and carbonate phase, respectively. A dinoflagellate (Dunaliella tertiolecta) and a diatom (Thalassiosira sp.) were used as bioindicators to test the toxicity of digested sludge samples collected in 1994. Each of the algae were inoculated to elutriates of digested sludge at different concentrations. The toxicities of the four types of sludge, according to 96 h-IC₅₀s, were ranked as follows: TP > ST > SWH > YL for D. tertiolecta and ST > SWH > TP > YL for Thalassiosira sp. For D. tertiolecta, a significant correlation was found between algal inhibition and ammonium-N, both in sludge (p<0.05) and elutriates (p<0.01).     

N2O增加对大气环境影响的模拟及其与甲烷和平流层水汽影响的比较

本文利用美国国家大气环境中心(NCAR)的二维化学、辐射和动力相互作用的模式(SOCRATES),模拟了大气中N₂O增加对O₃和温度的影响,并从化学、辐射和动力过程讨论了影响原因,此外还与大气甲烷和平流层水汽增加对大气环境的影响进行了对比.分析表明:大气中N₂O浓度增加以后,将通过化学过程引起30 km以上O₃损耗,30~40 km损耗较多;30 km以上降温明显,下平流层中低纬度地区以及对流层O₃增加并有微弱升温;30~40 km附近,北半球中高纬地区O₃减少以及降温幅度都大于南半球.对流层升温主要是N₂O和O₃增加所致,而平流层温度变化主要受O₃控制.北半球中高纬地区动力过程对温度变化的反馈较其它地区明显,这种反馈对平流层中高层北半球中高纬地区温度和O₃的变化都有明显影响.大气中甲烷增加引起的O₃损耗在45 km以上,45 km以下O₃增加.平流层水汽增加会引起40 km以上O₃减少,20~40 km大部分地区O₃增加.N₂O增加造成的O₃损耗正好位于臭氧层附近,其排放对未来O₃层恢复至关重要.N₂O增加引起下平流层15~25 km中低纬度地区有弱的升温,这与其它温室气体增加对该地区温度的影响不同,CO₂,CH₄和H₂O等增加后下平流层通常是降温.     

Production of selected cosmogenic radionuclides by muons: 2. Capture of negative muons

We have determined the production yields for radionuclides in Al₂O₃, SiO₂, S, Ar, K₂SO₄, CaCO₃, Fe, Ni and Cu targets, which were irradiated with slow negative muons at the Paul Scherrer Institute in Villigen (Switzerland). The fluences of the stopped negative muons were determined by measuring the muonic X-rays. The concentrations of the long-lived and short-lived radionuclides were measured with accelerator mass spectrometry (AMS) and γ-spectroscopy, respectively. Special emphasis was put on the radionuclides ¹⁰Be, ¹⁴C and ²⁶Al produced in quartz targets, ²⁶Al in Al₂O₃ and S targets, ³⁶Cl in K₂SO₄ and CaCO₃ targets, and ⁵³Mn in Fe₂O₃ targets. These targets were selected because they are also the naturally occurring target minerals for cosmic ray interactions in typical rocks. We also present results of calculations for depth-dependent production rates of radionuclides produced after cosmic ray μ⁻ capture, as well as cosmic ray-induced production rates of geologically relevant radionuclides produced by the nucleonic component, by μ⁻ capture, by fast muons and by neutron capture.     

Andesitic magma degassing investigated through H2O vapour–melt partitioning of halogens at Soufrière Hills Volcano, Montserrat (Lesser Antilles)

Magma degassing at Soufrière Hills Volcano (SHV) is characterised by an almost permanent SO₂ flux and a HCl production rate which mainly depends on dome growth rate. Degassing processes have been studied through textural, H₂O and halogen analyses of clasts collected between 1995 and 2006 on the dome and in pyroclastic flows and vulcanian eruption deposits. Cl, Br and I are strongly depleted in melts during H₂O degassing with no significant Cl–Br–I fractionation, whereas F is almost unaffected. All magmas erupted at SHV have followed a multi-step degassing path from the magma chamber up to a shallow depth ( 1 km, P  20 MPa). From that depth, however, effusive and explosive paths are distinct; vulcanian eruptions are the result of closed system degassing (CSD), while effusive dome growth is the result of CSD up to a very shallow depth (≤ 200 m, P  5–2 MPa) followed by open system degassing (OSD). CSD is modelled using the H₂O solubility law, the perfect gas law and partition coefficients of halogens between a rhyolitic melt and H₂O vapour (d_v − lⁱ). Gas loss characteristic of OSD is modelled using a Rayleigh law. Degassing induced crystallisation is introduced through the ratio of crystallisation and degassing rates, which ranges from 150–500. d_v − l^Cl for OSD ranges between 50–300, increasing with melt Cl content. For CSD, the lower effective d_v − l^Cl ( 20) is attributed to kinetic effects.

Dome forming activity has a greater impact on atmospheric chemistry than vulcanian eruptions because OSD is much more efficient at extracting halogens. The model shows that HCl flux is a good proxy for the dome forming eruption rate. Comparison between model and measured gas compositions suggests a high HBr–BrO conversion rate (BrO/Total Br  1/3) in the SHV gas plume.

The degassing behaviour of Cl, Br and I implies similar Cl/Br ( 160) and Br/I ( 90) in initial melts, volcanic clasts and high temperature gases. The low Cl/Br at SHV compared to other island arcs ( 250–300) is attributed to a shallow, pre-eruptive Br enrichment. The almost permanent dome extrusion at SHV since 1995 has likely had a significant regional atmospheric impact because of the very efficient effusive degassing and the high conversion rate of halogens into reactive species within the gas plume.     

汤东活动断裂带气体地球化学特征

本文采用野外多期跨断层流动观测测定了汤东活动断裂带H₂,Rn和CO₂的分布特征,以此分析了该断裂带的气体地球化学特征及其活动背景,从而揭示了气体地球化学特征与构造之间的联系。分析结果显示:不同测量期次的H₂,Rn和CO₂浓度存在显著差异,其中张河村测线的各期次测量结果中6月份各组分气体浓度均显著高于其它期次,而邢李庄测线的测量结果中1月份各组分气体浓度均显著高于其它期次;各测量期次的各气体组分分布曲线特征相似,高值异常点的重现性较好。张河村测线多期测量的H₂和Rn浓度背景值分别为（8.93±3.92）×10?6和（17.38±4.28） kBq/m3,在测线西部距汤东主断裂135 m和230 m处H₂与Rn同步出现高值异常;邢李庄测线H₂和Rn的背景值分别为（41.20±16.64）×10?6和（29.00±8.28） kBq/m3,H₂与Rn在测线西部距汤东主断裂60 m处同步出现异常。两测线的气体浓度高值异常部位与地球物理、跨断层联合钻孔详勘结果之间存在较好的对应关系,由此可推断观测气体浓度能够敏感地指示断裂带位置,而且H₂和Rn浓度是汤东断裂带气体地球化学观测的关键指标。      

新保安—沙城断裂带土壤气地球化学特征分析

测量断裂带土壤气浓度变化, 是监测断裂活动性和地震危险性的重要途径之一。 2014年5月, 我们在怀来地区新保安-沙城断裂测量了断层土壤气H₂、 He、 CO₂、 Rn、 Hg浓度以及CO₂、 Rn、 Hg的通量。 测量结果显示: H₂、 He、 CO₂、 Rn、 Hg浓度变化范围分别为, H₂: (0.4～34.2)×10^-6、 He: (2.8～7)×10^-6、 CO₂: (0.051～1.19)%、 Rn: (0.31～18.22) kBq/m³、 Hg: (2～54) ng/m³。 土壤气H₂和Rn是揭示断层位置的有效参数之一, 在断层附近以及有陡坎的地区有明显高值异常。 通过对怀来地区新保安-沙城断裂土壤气浓度及通量地球化学研究初步确定断裂带有较高的脱气强度, 与此区域地震活动性有一定的关系。     

利用VP型垂直摆倾斜仪观测数据检测2011日本M_w9.0级地震激发的低频地球自由振荡

甚长周期VP型垂直摆倾斜仪对某些地球物理信号有特殊的敏感性,除了在观测小地震、慢地震等方面有优势之外,还可有效应用于低频地球自由振荡信号的探测.利用安置在武汉大学珞珈山的我国自行研制的VP型垂直摆倾斜仪在2011日本Mw9.0级大地震之后不同长度的观测数据,联合EEMD方法、自回归估计(AR)方法和bootstrap法,本文不仅检测到该地震激发的频率小于4.7 mHz的零阶球型振荡(0S2至0S38)和环型振荡(0T4至0T35)几乎所有振型以及15个谐频振型,还检测到5个其频率低于1mHz的低阶球型多线态(0S2、2S1、0S3、0S4和1S2)的部分或全部谱峰分裂现象,并给出了所有检测结果的精度评估.此外,本文分析了某些球型和环型振荡之间的耦合效应,结果表明耦合效应将显著影响地球自由振荡信号的相关参数.