Crustal seismic velocity structure near Faial and Pico Islands (AZORES), from local earthquake tomography

The Azores archipelago (Portugal) is located on an oceanic plateau, in a geodynamic environment prone to intense seismic and volcanic activity. In order to investigate the crustal structure in this region, we have conducted a local earthquake tomography study in the area of the islands of Faial, Pico and S. Jorge using data recorded in July 1998. The July 9th 1998 earthquake, near Faial Island, triggered an aftershock sequence of thousands of events that lasted for several months and were recorded by a total of 14 stations located on the three islands surrounding the epicentral area. In the upper crustal layers, consistency is seen between the tomographic results and the islands' surface volcanic units. Beneath the Faial central volcano a low Vp (< 6.0 km/s) anomaly roughly located at 3–7 km depth, suggests a connection to the plumbing system, possibly the presence of a magma chamber. In NE Faial, a high Vp (> 6.3 km/s) body was found located at mid-lower crust, most likely an intrusion of gabbroic composition, that is bordered by the registered seismic activity; its shape suggesting a tectonic controlled mechanism. The relocated hypocenters, together with the overall analysis of the Tomographic model, suggest a tectonic segmentation of Faial Island. The crustal thickness under the islands volcanic buildings of the Faial–Pico area was estimated at around 14 km.     

Double-sided onshore–offshore seismic imaging of a plate boundary: “super-gathers” across South Island, New Zealand

Onshore–offshore seismic refraction profiling allows for the determination of crustal and mantle structures in the transition between continental and oceanic environments. Islands and narrow landmasses have the unique geometry of allowing for double-sided onshore–offshore experiments that favor the construction of composite “super-gathers” using the acquisition of onshore–offshore and ocean-bottom seismometer receiver gathers, land explosion shot gathers, and near-vertical incidence multichannel seismic (MCS) profiling. A number of sites at plate boundaries are amenable to the application of double-sided onshore–offshore imaging, including the Indo-Australian/Pacific transform boundary on South Island, New Zealand. By comparing the ratio of island width to mantle refraction (Pn) “maximum” crossover distance, using nondimensional distances, we provide an indicator of raypath “coverage” for crustal illumination. Islands or narrow land masses whose widths are less than twice their maximum crossover distance are candidates for double-sided onshore–offshore experiments. The SIGHT (South Island GeopHysical invesTigation) experiment in New Zealand is located where the width of South Island is sufficiently narrow with respect to its crustal thickness that a double-sided onshore–offshore experiment allows for complete crustal imaging of the associated plate boundary.     

The electrical conductivity of some hydrous and anhydrous molten silicates as a function of temperature and pressure

Electrical conductivity of the following molten silicate systems (in mol%): 60SiO₂-40Na₂O; 65SiO₂-35Na₂O; 75SiO₂-25Na₂O; 78SiO₂-22Na₂O; 72SiO₂-24Na₂O-4CaO; 66SiO₂-19Na₂O-15H₂O; and an anhydrous and hydrous (4 wt% H₂O) Mt. Erebus lava, have been measured as a function of temperature (to 1000°C) and pressure (to 1.3 kbar). The anhydrous soda-rich melts have a positive pressure coefficient of conductivity to ~200 bars and beyond this pressure the pressure coefficient is small and negative. Addition of water lowers the conductivity and gives rise to a negative pressure coefficient at the highest temperatures. The conductivity of hydrous Mt. Erebus lava passed through a maximum with increasing temperature at constant pressure. These phenomena are interpreted in terms of explanations of similar phenomena found in molten salt and aqueous electrolyte solutions.     

Shallow seismic stratigraphy and pockmarks of a hydrothermally influenced lake, Lake Rotoiti, New Zealand

Lake Rotoiti formed 11 850–20 000 years ago when lava flows dammed the drainage system through the Okataina caldera, one of the major rhyolitic centres of the intracontinental, back-arc, Taupo Volcanic Zone of North Island, New Zealand. The lake morphology reflects this complex origin, with remnants of the old caldera rim, the lava dam and relict river system being preserved. High resolution seismic reflection profiles (7 kHz) show the drowned river system channelled inflowing water into the lake basin, scouring and depositing sediments and maintaining an active sublacustrine channel in the former river valley. Airfall tephras are preserved in lake sediments. The tephrachronology, established from the surrounding catchments, can be correlated with the siesmic stratigraphy for eight major eruptions over the last 11 850 years. Hydrothermal fields underlying the lake generate gaseous sediments which mask seismic penetration. This is indistinguishable from seismic masking caused by biogenic gas accumulation within the sediments. Venting of hydrothermal gases at the surface creates pockmarks. From the seismic stratigraphy beneath pockmarks seven stages of pockmark genesis have been identified which show pockmarks grow, decay, migrate and persist over several thousand years.     

Petrologic Evolution of Anorthoclase Phonolite Lavas at Mount Erebus, Ross Island, Antarctica

Mount Erebus, Ross Island, Antarctica, is an active, intraplate,alkaline volcano. The strongly undersaturated sodic lavas rangefrom basanite to anorthoclase phonolite, and are termed theErebus lineage (EL). The lavas are porphyritic with olivine(Fo₈₈–51), clinopyroxene (Wo₄₅–53En₃₆–41Fs₈–30),opaque oxides (Usp₃₁–76), feldspar (An₇₂–11), andapatite. Rare earth element (REE) contents increase only slightlywith increasing differentiation compared with other incompatibleelements. The light REE are enriched (La_N/Yb_N= 14–20)and there are no significant Eu anomalies. ⁸⁷Sr/⁸⁶Sr is uniformand low ({small tilde} 0.7030) throughout the EL, suggestingderivation of the basanites from a depleted asthenospheric mantlesource, and lack of significant crustal contamination duringfractionation of the basanite. Regular geochemical trends indicatethat the EL evolved from the basanites by fractional crystallization.Major element mass balance calculations and trace element modelsshow that fractionation of 16% olivine, 52% clinopyroxene, 14%Fe-Ti oxides, 11% feldspar, 3% nepheline, and 3% apatite froma basanite parent leaves 23.5% anorthoclase phonolite. Minor volumes of less undersaturated, more iron-rich benmoreite,phonolite, and trachyte are termed the enriched iron series(EFS). The trachytes have ⁸⁷Sr/⁸⁶Sr of 0.704, higher than otherEFS and EL rocks, and they probably evolved by a combined assimilation-fractionalcrystallization process. The large volume of phonolite at Mt. Erebus requires significantbasanite production. This occurs by low degrees of partial meltingin a mantle plume (here termed the Erebus plume) rising at arate of about 6 cm/yr.     

Effusive Activity at Mount Etna Volcano (Italy) During the 20th Century: A Contribution to Volcanic Hazard Assessment

Mount Etna is an open conduit volcano, characterised by persistent activity, consisting of degassing and explosive phenomena at summit craters, frequent flank eruptions, and more rarely, eccentric eruptions. All eruption typologies can give rise to lava flows, which represent the greatest hazard by the volcano to the inhabited areas. Historical documents and scientific papers related to the 20th century effusive activity have been examined in detail, and volcanological parameters have been compiled in a database. The cumulative curve of emitted lava volume highlights the presence of two main eruptive periods: (a) the 1900–1971 interval, characterised by a moderate slope of the curve, amounting to 436 × 10⁶ m³ of lava with average effusion rate of 0.2 m³/s and (b) the 1971–1999 period, in which a significant increase in eruption frequency is associated with a large issued lava volume (767 × 10⁶ m³) and a higher effusion rate (0.8 m³/s). The collected data have been plotted to highlight different eruptive behaviour as a function of eruptive periods and summit vs. flank eruptions. The latter have been further subdivided into two categories: eruptions characterised by high effusion rates and short duration, and eruptions dominated by low effusion rate, long duration and larger volume of erupted lava. Circular zones around the summit area have been drawn for summit eruptions based on the maximum lava flow length; flank eruptions have been considered by taking into account the eruptive fracture elevation and combining them with lava flow lengths of 4 and 6 km. This work highlights that the greatest lava flow hazard at Etna is on the south and east sectors of the volcano. This should be properly considered in future land-use planning by local authorities.     

Tephra layers from Holocene lake sediments of the Sulmona Basin, central Italy: implications for volcanic activity in Peninsular Italy and tephrostratigraphy in the central Mediterranean area

We present a new tephrostratigraphic record from the Holocene lake sediments of the Sulmona basin, central Italy. The Holocene succession is represented by whitish calcareous mud that is divided into two units, SUL2 (ca 32 m thick) and SUL1 (ca 8 m thick), for a total thickness of ca 40 m. These units correspond to the youngest two out of six sedimentary cycles recognised in the Sulmona basin that are related to the lake sedimentation since the Middle Pleistocene. Height concordant U series age determinations and additional chronological data constrain the whole Holocene succession to between ca 8000 and 1000 yrs BP. This includes a sedimentary hiatus that separates the SUL2 and SUL1 units, which is roughly dated between <2800 and ca 2000 yrs BP. A total of 31 and 6 tephra layers were identified within the SUL2 and SUL1 units, respectively. However, only 28 tephra layers yielded fresh micro-pumices or glass shards suitable for chemical analyses using a microprobe wavelength dispersive spectrometer. Chronological and compositional constraints suggest that 27 ash layers probably derive from the Mt. Somma-Vesuvius Holocene volcanic activity, and one to the Ischia Island eruption of the Cannavale tephra (2920 ± 450 cal yrs BP). The 27 ash layers compatible with Mt. Somma-Vesuvius activity are clustered in three different time intervals: from ca 2000 to >1000; from 3600 to 3100; and from 7600 to 4700 yrs BP. The first, youngest cluster, comprises six layers and correlates with the intense explosive activity of Mt. Somma-Vesuvius that occurred after the prominent AD 79 Pompeii eruption, but only the near-Plinian event of AD 472 has been tentatively recognised. The intermediate cluster (3600–3100 yrs BP) starts with tephra that chemically and chronologically matches the products from the “Pomici di Avellino” eruption (ca 3800 ± 200 yrs BP). This is followed by eight further layers, where the glasses exhibit chemical features that are similar in composition to the products from the so-called “Protohistoric” or AP eruptions; however, only the distal equivalents of three AP events (AP3, AP4 and AP6) are tentatively designated. Finally, the early cluster (7600–4700 yrs BP) comprises 12 layers that contain evidence of a surprising, previously unrecognised, activity of the Mt. Somma-Vesuvius volcano during its supposed period of quiescence, between the major Plinian “Pomici di Mercato” (ca 9000 yrs BP) and “Pomici di Avellino” eruptions. Alternatively, since at present there is no evidence of a similar significant activity in the proximal area of this well-known volcano, a hitherto unknown origin of these tephras cannot be role out. The results of the present study provide new data that enrich our previous knowledge of the Holocene tephrostratigraphy and tephrochronology in central Italy, and a new model for the recent explosive activity of the Peninsular Italy volcanoes and the dispersal of the related pyroclastic deposits.     

Rare earth element geochemistry of Late Cenozoic alkaline lavas of the McMurdo Volcanic Group, Antarctica

Rare earth element (REE) concentrations were determined in 16 Ross Island and northern Victoria Land alkaline lava samples which were representative of four lava lineages of the McMurdo Volcanic Group, Antarctica. A kaersutite and two feldspar mineral separates were also analysed.

Two of the lava lineages, a basanite to nepheline benmoreite and a basanite to phonolite, have similar chondrite-normalized REE fractionation patterns, with a continuous enrichment of light and heavy REE and depletion of middle REE. The patterns result from the fractionation of olivine, clinopyroxene, spinels, feldspar, kaersutite and apatite. Kaersutite is an important fractionated phase responsible for the middle REE depletion.

Another of the lava lineages is mildly potassic with trachyandesite to peralkaline K-trachyte lavas which have partly overlapping REE fractionation patterns. There is a depletion in REE from tristanite to K-trachyte. Fractionation of olivine, clinopyroxene, feldspar and apatite probably control the REE chemistry of the lineage, greater degrees of apatite fractionation deplete the K-trachyte in REE relative to the tristanite. Feldspar fractionation in the genesis of the peralkaline K-trachyte is shown by a large negative Eu anomaly (Eu/Eu* = 0.10).

A nepheline hawaiite to anorthoclase phonolite lava lineage from the Erebus Centre shows enrichment of REE, although minor overlapping in the middle REE does occur. Anorthoclase phonolite has a positive Eu anomaly (Eu/Eu* = 1.31), indicating possible accumulation of anorthoclase. The lineage resulted from fractionation of olivine, clinopyroxene, magnetite and apatite.     

Large dyke intrusion and small eruption: The December 24, 2018 Mt. Etna eruption imaged by Sentinel‐1 data

On December 24th, Mt. Etna volcano underwent a seismic crisis beneath the summit and upper southern flank of the volcano, accompanied by significant ash emission. Eruptive fissures opened at the base of summit craters, propagating SE‐wards. This lateral eruption lasted until December 27th. Despite the small eruption, seismic swarm and ground deformation were very strong. Sentinel‐1 interferograms show a wide and intense ground deformation with some additional features related to volcano‐tectonic structures. We inverted DInSAR data to characterise the magma intrusion. The resulting model indicates that a large dyke intruded but aborted its upraise at about the sea level; however, this big intrusion stretched the edifice, promoting the opening of the eruptive fissures fed by a shallower small dyke, and activating also several faults. This model highlights that a big intrusion beneath a structurally complex volcano represents a main issue even if the eruption is aborted.     

Microearthquakes and faulting in the southern Okinawa Trough

Southern Okinawa Trough represents an early stage of back-arc rifting and is characterized by normal faulting and microearthquakes. Earthquake distribution and deep structure of fault was investigated to clarify active rifting in the southern Okinawa Trough, where two parallel grabens are located. A network of ocean bottom seismometers (OBSs) that displayed the hypocenters of 105 earthquakes were observed for a period of 4 days in southern-graben (SG). Most of the microearthquakes occurred in a cluster about 7 km wide, which on a cross-section striking N45°E dips 48° to the southwest. Relocated hypocenters, which are recorded by a local seismic network, show scattered distribution around the southern-graben. There are no remarkable surface faults in the southern-graben. On the other hand, the recalculation of hypocenter locations of 1996 earthquakes swarm recorded by a local seismic network suggests that the swarm is associated with normal faulting on the southern side of northern-graben (NG). Thus, the undeveloped southern-graben is located to the south of the developed northern-graben. Southward migration of rifting, which may be caused by migration of volcanism, could thus be occurring in the southern Okinawa Trough. The extension rate computed for the southern Okinawa Trough from the fault model of the northern-graben is 4.6 cm/year, which is 59–102% of the extension rate (GPS measurements). This result indicates that the majority of extensional deformation is concentrated within the center of the northern-graben in the Okinawa Trough.     

The role of olivine in the crystallization of the prehistoric Makaopuhi tholeiitic lava lake,Hawaii

On eruption, the tholeiitic basalt lava of the prehistoric Makaopuhi lake contained nearly seven percent euhedral olivine phenocrysts of approximately Fa₁₄ composition. In the center of the 225 foot vertical section of the lake, the lava became more than 90 percent solid at 1000° C after about 30 years. At the surface the lava was quenched to air temperature, whereas, at the bottom, quenching to 800° C was followed by a 40 year period before the temperature reached 700° C. The olivine phenocrysts settled at an average rate of about 4 × 10^–6 cm Sec^–1 to form a zone that contains 21 percent olivine 75 feet above the base. Sinking of olivines continued until some time after the beginning of the crystallization of augite and plagioclase. Thin rims of iron-rich olivine (up to Fa₅₅) surrounding the phenocrysts, and a second generation of fine-grained olivines (Fa₂₀ Fa₄₈) restricted to the uppermost 20 feet indicate local extensions of the period of crystallization of olivine. During crystallization of the groundmass and later subsolidus cooling in the range 1000° C to at least as low as 800° C, the olivine phenocrysts were converted to Fa_30–40 by interdiffusion of Fe, Mg, Ni, and Mn. Homogenization of Mg-rich cores and Fe-rich margins and equilibration of olivine composition with the groundmass phases was progressively less well achieved toward the top of the lake. Reaction rims around the olivines are composed primarily of Ca-rich pyroxene. Pigeonite crystallized alongside augite except in the uppermost 5 feet where there is abundant ground mass olivine. Poikilitic hypersthene grew at the expense of pre-existing ferromagnesian minerals in the cumulate zone.Publication authorized by the Director, U.S. Geological Survey.     

Geological development of Heard Island,Central Kerguelen Plateau

We report ⁴⁰Ar–³⁹Ar laser step-heating age determinations on 15 stratigraphically controlled lava flows and intrusive rocks from Heard Island, Central Kerguelen Plateau (Indian Ocean). The island history began with uplift of pelagic limestone intruded by 22 Ma gabbro sills. Subaerial and wave erosion levelled the early island, producing an unconformity onto which pillow lavas, tuffaceous sediments and shallow-water, fossiliferous marine siltstone (Drygalski Formation) were deposited, beginning in late Miocene time. Two volcanic systems then formed in the late Quaternary. Big Ben dominates the larger southeast part of the island, while Mount Dixon occupies the northwest Laurens Peninsula. Feeder dykes and the early lava flows in both systems are 400–200 ka. Lava flows with evolved compositions (trachytes, trachyandesites) erupted 100–20 ka. Well-preserved parasitic cones exposed at low elevations are 15–10 ka and younger. Mawson Peak, near the summit of Big Ben, has erupted lava flows as recently as 2007. Heard Island, and nearby active McDonald Island, are subaerial features of a larger Neogene volcanic region of Central Kerguelen Plateau that includes several large sea knolls and recently identified submarine fields of small cones. This broadly distributed volcanic activity is linked to incubation of plume material at the base of the nearly stationary overlying Central Kerguelen Plateau.     

Structure and peculiarities of the seismic regime in the source zone of the Takoe earthquake on September 1, 2001 (M W 5.2)

The Takoe earthquake (M _W 5.2) occurred between two en-echelon segments of the active Aprelovskii fault on September 1, 2001, and was accompanied by an earthquake swarm, which was successfully recorded by a local network of digital seismic stations located on the southern part of Sakhalin Island. Modern methods were applied to relocate the parameters of the sources for the earthquake swarm event and significantly specify their spatial distribution and relations to the structural-geological features of the complex system of interacting faults. New data on the correlation between the source mechanism and the modern geodynamic setting in the southern part of Sakhalin were obtained.     

25 years of mineral exploration and discovery in Indonesia

This paper traces the history of mineral exploration in Indonesia between 1967 and 1992, and discusses various technical aspects, such as area selection, exploration and discovery methods, and significant geologic features of the more important new discoveries.Exploration activity over the past 25 years can be divided into four main phases. Phase 1 (1967–1976) mostly involved investigations of mineral prospects and districts previously identified by the Dutch. These investigations resulted in many discoveries, including: a major copper-gold district (skarn-porphyry copper) in Irian Jaya, where exploration is still in progress (resources identified to date: 28 Mt Cu and 2,700 t Au); large nickel resources in Eastern Indonesia (13 Mt Ni); significant onshore and offshore tin resources in the Sumateran tin belt (0.13 Mt Sn); and large but low grade bauxite deposits in West Kalimantan (300 Mt Al₂O₃). Of the eight Contracts of Work signed between 1967 and 1972, six reached the mining stage. Phase 2 (1970–1975) consisted of an extensive porphyry copper search in the Sunda arc, the western arc of Sulawesi and the central belt of Irian Jaya. Best results were obtained from northern Sulawesi, where follow-up between 1976 and 1982 identified three potentially economic copper-gold deposits (1.7 Mt Cu and 140 t Au) and one subeconomic molybdenum porphyry system (0.8 Mt Mo). During Phase 3 (1981–1988) extensive coal exploration in South and East Kalimantan delineated over 5,000 Mt of coal of varying rank and quality, including 1,500 Mt as measured reserves in 17 deposits, eight of which have been developed to date. Phase 4 (1984–1990) involved a major gold rush, focused primarily on the Cenozoic magmatic belts of Kalimantan, Sulawesi, Moluccas and the Sunda arc. Over 80 primary and alluvial gold prospects were drill tested. Five of these were brought into production (two alluvial deposits, two new hard rock discoveries and one Dutch mine), containing approximately 135 tonnes of mineable gold, and several other projects are under development or undergoing feasibility studies. Total geological resources identified to date are estimated to contain about 700 tonnes of gold. Exploration during phase 4 also resulted in several gold-rich porphyry copper discoveries, including a major deposit in Sumbawa (2.7 Mt Cu and 250 t Au). Intermittent exploration for uranium, diamonds and lead/zinc since 1969 has been largely unsuccessful.Exploration is now passing to the next phase, which is likely to be multi-commodity in nature with a strong focus on gold, copper and coal. A number of deposits outlined during earlier phases will be developed.The unprecedented high level of mineral exploration activity over the past 25 years can be attributed to Indonesia's mineral prospectivity and favourable investment climate. Given a continued competitive commercial environment and sustained commodity prices, the next 25 years should see further strong development of the country's mineral resources.     

STUDY OF ERUPTIONS AND EARTHQUAKES ORIGINATING FROM VOLCANOES (PART 1 OF 3)

Reports of volcanic eruptions and earthquakes originating from volcanoes indicate that seismic activity preceding the eruption is related not only to eruption magnitude and structure of the volcano, but also to viscosity of the lava at the time of eruption. This follows, since lava of higher viscosity meets greater resistance as it ascends from the magma chamber to the earth's surface and, consequently, greater stress will be produced within and beneath the volcano. The writer gives a condensed statistical breakdown of earthquakes and explosive eruptions of Asama Volcano. The Asama earthquakes treated in the report are mainly those of rather low magnitude (T = 1. 0 sec, V = 350) at the Asama Volcano Observatory, situated 4. 2 km east of the center of the summit crater. This investigation showed that most of the explosive eruptions were preceded by an increase in micro-earthquakes. In addition, an experimental formula for predicting volcanic eruptions, based on the statistical relation between frequency of earthquakes originating from Asama and its explosive eruptions. The forthcoming report (Part II) will discuss the same problem based on seismic observations by more sensitive instruments set nearer the summit crater. — A. Eustus     

The quaternary geomorphology of Scotland: The research contribution of J.B. Sissons

Between 1958 and his retirement in 1982, J.B. Sissons published some 80 articles and two books. The majority of these were devoted to aspects of the Quaternary geomorphology of Scotland, but many of his findings have much wider application. This paper reviews the six main areas in which Sissons made an outstanding research contribution. In approximate chronological order, these were as follows: (i) reassessment of the significance of meltwater channels and related fluvioglacial landforms (1958–1963); (ii) the deciphering of an extremely complex sequence of raised and buried shorelines and associated sea-level changes in eastern Scotland (1962–1972), together with reinterpretation of the age and origin of marine rock-cut platforms in western Scotland (1974–1982); (iii) work on the data banking of borehole records and the relevance of certain aspects of drift stratigraphy to engineering operations (1969–1971); (iv) research on the extent and chronology of the last Scottish ice sheet and associated readvances (1961–1982); (v) the reconstruction of the extent and palaeoclimatic implications of Loch Lomond Stadial glaciers (1972–1982); and (vi) investigation into aspects of landscape evolution in the Glen Roy area, including the formation of former lake shorelines, the catastrophic drainage of former ice dammed lakes and its effects, the interpretation of complex terrace sequences and the discovery of links between deglaciation, unloading, faulting, earthquakes and landslides (1978–1982). This paper also includes a complete list of Sissons' publications.     

Fractionation of the platinum-group elments and Re during crystallization of basalt in Kilauea Iki Lava Lake, Hawaii

Kilauea Iki lava lake formed during the 1959 summit eruption of Kilauea Volcano, then crystallized and differentiated over a period of 35 years. It offers an opportunity to evaluate the fractionation behavior of trace elements in a uniquely well-documented basaltic system. A suite of 14 core samples recovered from 1967 to 1981 has been analyzed for 5 platinum-group elements (PGE: Ir, Os, Ru, Pt, Pd), plus Re. These samples have MgO ranging from 2.4 to 26.9 wt.%, with temperatures prior to quench ranging from 1140 °C to ambient (110 °C). Five eruption samples were also analyzed.Osmium and Ru concentrations vary by nearly four orders of magnitude (0.0006–1.40 ppb for Os and 0.0006–2.01 ppb for Ru) and are positively correlated with MgO content. These elements behaved compatibly during crystallization, mostly likely being concentrated in trace phases (alloy or sulfide) present in olivine phenocrysts or included chromite. Iridium also correlates positively with MgO, although less strongly than Os and Ru. The somewhat poorer correlation for Ir, compared with Os and Ru, may reflect variable loss of Ir as volatile IrF₆ in some of the most magnesian samples.Rhenium is negatively correlated with MgO, behaving as an incompatible trace element. Its behavior in the lava lake is complicated by apparent volatile loss of Re, as suggested by a decrease in Re concentration with time of quenching for lake samples vs. eruption samples. Platinum and Pd concentrations are negatively, albeit weakly, correlated with MgO, so these elements were modestly incompatible during crystallization of the major silicate phases. Palladium contents peaked before precipitation of immiscible sulfide liquid, however, and decline sharply in the most differentiated samples. In contrast, Pt appears to have been unaffected by sulfide precipitation. Microprobe data confirm that Pd entered the sulfide liquid before Re, and that Pt is not strongly chalcophile in this system. Occasional high Pt values in both eruption and lava lake samples suggest the presence of unevenly distributed, unidentified Pt-rich trace phases in some Kilauea Iki materials.Estimated mineral (olivine + chromite)/melt D values for Os, Ir, Ru and Pt for equilibrium crystallization for samples from ~ 7 to 27 wt.% MgO are 26, 8.2, 19 and 0.55, respectively. These Os, Ir and Ru estimates are somewhat higher than previous estimates for similar systems. If fractional crystallization is instead assumed, D values are much more similar.Results confirm many prior observations in other mafic systems that olivine (together with included phases) has a major effect on absolute and relative abundances of Re and the PGE. The relatively linear correlations between these elements and MgO potentially permit accurate estimation of the concentrations of these elements in the primary melts of comparable systems, especially in instances where the MgO content of the primary melt is well constrained.     

Ti-content of high-Ca pyroxenes as a petrogenetic indicator: an experimental study of Mafic Alkaline Rocks from the Mt. Erebus volcanic region,Antarctica

We report chemical and mineralogical data for one atmosphere melting experiments conducted on alkalic rocks from the Mt. Erebus volcanic region: DVDP2 basanite, two hawaiites (DVDP2 and a nepheline-bearing variety), and an anorthoclase phonolite. Temperatures between 1,224 and 1,049°C were investigated at f_O2~QFM. DVDP2 basanite appears to be an intermediate pressure liquid or a cumulate, because only olivine coexists with melt from above 1,224–1,160°C. High-Ca pyroxene joins olivine in the crystallization sequence at 1,138°C. These minerals are joined by plagioclase at a temperature between 1,120 and 1,104°C. In contrast, DVDP2 hawaiite appears to be relatively evolved, because it is multiply saturated with olivine, plagioclase, and high-Ca pyroxene near its liquidus (between 1,120 and 1,104°C). Plagioclase crystallizes in the Ne-hawaiite by 1,160°C followed by olivine below 1,120°C. The liquidus of anorthoclase phonolite is between the lowest temperatures investigated, 1,089 and 1,049°C, and plagioclase is the liquidus mineral. Our results indicate that DVDP2 hawaiite can be derived from a DVDP2 basanitic parental magma by crystal fractionation at low pressures, that the nepheline hawaiite is an olivine cumulate, and that the liquids parental to the anorthoclase phonolite represent the end products of crystal fractionation. They also allow us to illustrate how the Ti-content of pyroxene may be used as a petrogenetic indicator of processes and events in the evolution of the Erebus volcanic system.     

Active Tectonics in the Central Apennines (Italy) – Input Data for Seismic Hazard Assessment

Quaternary tectonics and paleoseismologicalinvestigations have defined a reliable framework ofactive faults in the southern Umbria and AbruzziApennines. Two sets of NW–SE to NNW–SSE trending, 16to 33 km-long, normal and normal-oblique faults orfault systems have caused the displacement of LatePleistocene–Holocene deposits and landforms within theinvestigated sector. Available data on verticaloffsets indicate that both Late Pleistocene–Holoceneand Quaternary (since the later part of the EarlyPleistocene; 0.9–1 Ma) slip rates range between 0.4and 1.2 mm/yr (range 0.6–0.8 mm/yr preferred).Paleoseismological investigations show that recurrenceintervals for surface faulting events are alwaysgreater than 1,000 years and are usually greater than2,000 years. Both paleoseismological data andlong-term seismicity show that activation of theinvestigated faults may result in earthquakes ofM = 6.5–7.0. The extension rate across the two sets ofprimary faults ranges between 0.7 and 1.6 mm/yr.Horizontal seismic strain has been calculated to be0.5–0.6 mm/yr, based on the summation of the seismicmoment of M > 5.3 earthquakes which have affected theinvestigated area since 1200 AD. This value may belower than that inferred through geological data,probably because the seismological record reliable forthe addition of the seismic moments covers a too shorttime window (about 800 years) to be consideredrepresentative of the tectonic activity in theinvestigated area. This conclusion iscorroborated by the large recurrence intervalper fault (>1,000–2,000 years) inferred frompaleoseismological analysis. A comparison of theactive-fault framework and historical-seismicitydistribution indicates that the entire eastern set ofactive faults has likely not been activated since 1000AD, thus indicating that the elapsed time since thelast activation for several faults of the investigatedarea may be greater than 1,000 years. In terms ofhazard, the highest probability of activation isrelated to the eastern set faults, due to theobservation that the elapsed time for some of thesefaults may be similar to the recurrence interval. Asan example, paleoseismological andarchaeoseismological data indicate that the elapsedtime for the Mt. Vettore and Mt. Morrone Faults may begreater than 1,650 and 1,850 years, respectively.These data may have significant implications for riskrelated to a number of towns in central Italy and tothe city of Rome. As for the latter, in fact,monumental heritage has suffered significant damagedue to earthquakes of M > 6.5 which originated in theinvestigated Apennine sector.     

Stress tensor analysis of the 1998–1999 tectonic swarm of northern Quito related to the volcanic swarm of Guagua Pichincha volcano, Ecuador

The phreatic activity and the subsequent dacitic dome growth in 1998–1999 at Guagua Pichincha volcano, Ecuador, were associated with two seismic swarms: one located in the northern part of Quito (population: 1,500,000) and another one, just below the active volcano, about 15–20 km SW from the first one. Quito swarm tectonic events have high frequencies (from 1 to 10–15 Hz). We registered more than 3200 events (among which 2354 events of 1.4≤M_L≤4.2) between June 1998 and December 1999 at the −2- and −17-km depth. The volcanic events below the Guagua Pichincha caldera have high (from 1 to 10–15 Hz) and low (less than 3 Hz) frequencies. Approximately, 130,000 events were registered between September 1998 and December 1999 at the +2.4- and −3.5-km depth. Here, we study the stress tensors of these two swarms deduced from the polarities of P first motions and compare them to the regional stress tensor deduced from CMT Harvard focal mechanisms. The Quito swarm stress tensor is relatively close to the regional stress tensor (the σ₁ axis was oriented N117°E close to the N102°E direction of the plate motion found by the GPS measurement, and σ₃ is nearly vertical). The difference may be due to the action of the closely active Guagua Pichincha volcano. The Guagua Pichincha stress tensor is very different from the regional tectonic one. The σ₁ axis of the volcano is oriented N214°E, almost perpendicular to the σ₁ of the swarm of Quito and σ₃ is almost horizontal. Even if these two tensors are different, they can be explained in a more general tectonic scheme. The almost horizontal direction of σ₃ just below the volcano is compatible with an extensional horizontal direction that may be expected in the shallow extrados part of a compressional region and consistent with an opening of the top of the Guagua Pichincha volcano. The movement of the fluids (magma, gas and/or groundwater) produced by the closely active Guagua Pichincha volcano seems to have an influence in the acceleration of the generation of seismic events.