A Preliminary Report on Yong＇anpu Tectonic Window in Suizhong County, Western Liaoning Province

For understanding the Mesozoic tectonics of Yanshan （燕山 ） belt, the authors took geological mapping in the belt. A large-scale thrust structure was identified in Yonganpu （永安堡） area. in the western part of Suizhong （绥中 ） County, Liaoning （辽宁 ） Province during our recent mapping in the Yanshan belt. The hanging wall of the thrust was composed of Archean gneiss and the overlying Early Cretaceous Zhangjiakou （张家口 ） Formation; meanwhile, the strongly ductile deformed volcanic rocks of Zhangjiakou Formation comprised the footwall in Yong＇anpu tectonic window. This discovery indicates the existence of strongly contractional deformation in the Yanshan belt after the eruption of Early Cretaceous Zhangjiakou volcanic rocks. On the basis of mapping and research, it is concluded that the published official geological maps have failed to identify the major structural features of the Yanshan belt.     

Genesis of Sr Isotopes in Groundwater of Hebei Plain

To analyze the genesis of Sr isotopes in groundwater of Hebei plain, time-accumulative effect of 87Sr/86Sr ratio was studied. It is shown that 87Sr/86Sr ratio increases with the increasing age and depth of groundwater and has a positive correlation to 4Heexc and a negative correlation to δ18O and δD. The groundwater is divided into three groups to discuss the relation between 87Sr/86Sr ratio and Sr2 content: ① moderate Sr2 content and higher 87Sr/86Sr ratio (water I); ② lower Sr2 content and higher 87Sr/86Sr ratio (water II); and ③ higher Sr2 content and lower 87Sr/86Sr ratio (water III), that is hot water. On the basis of integrated analysis, it was considered that ① the radiogenic Sr in the Quaternary groundwater (Q4-Q1) originates from weathering of silicate rich in Na and Rb, mainly from plagioclase; ② the radiogenic Sr of hot water in Huanghua port is attributed to carbonate disso- lution, with lower 87Sr/86Sr ratio and higher Sr/Na ratio; ③ the recharge area is laterally recharged by the groundwater flowing through igneous and metamorphic rocks, with moderate 87Sr/86Sr ratio. How- ever, the formation mechanism of Sr isotopes in Tertiary groundwater needs further studies.     

Acyclic Alkanes in the Cave in Qingjiang, Soil over Heshang Hubei Province

The reports that relate to the biomarker＇s fate and characteristics of the modern soil in the karst area are very lacking. By using gas chromatography-mass spectrometry （GC-MS）, a series of biomarkers were identified from the soils collected over Heshang cave （和尚洞） in Qingjiang （清江）, Hubei （湖北） Province. The distribution of n-alkanes is mainly from C2s to C33 in carbon number, with a maximum at C31. They have a strong odd-over-even carbon number predominance. These characteristics represent an input mainly from higher plants. The lipid parameters, including CPIh （carbon preference index）, Rb/t（ratio of lower- to higher-molecular-weight homologues） and ACL （average chain length）, show comparable trends with depth, probably reflecting vegetation change and microbial degradation. Series of monomethylalkanes and diploptene are present in the extractable organic matter; they might be derived from soil microbes, cyanobacteria in particular.     

Nd Isotopes and Geochemistry of Phanerozoic Clastic Sedimentary Rocks from the Yangtze Block and Their Tectonic Implications

This article presents Sm-Nd and geochemical data on fine-grained sediments of the northern margin from the Yangtze block, China, to understand the variations of Nd isotopic compositions and crustal evolution history in this area. The results are as follows: (1) Nd isotopic compositions for clastic sedimentary rocks of the Middle-Late Proterozoic have relatively positive Nd(t) values ( 2.72 to 0.69), with Nd model ages from 1.38 Ga to 1.55 Ga, corresponding to the contemporaneous volcanic rocks from the Xixiang (西乡) Group. This indicates that the arc-related materials from Middle-Late Proterozoic dominate the provenances of the Middle-Late Proterozoic periods. (2) The gradual decrease in εNd(t) during the Cambrian-Carboniferous periods is likely to reflect the progressively increasing proportion of erosion materials from the Foping (佛坪) and Qinling (秦岭) complexes, corresponding to a gradually decreasing trend in the La/Th ratios. (3) A prominent increase in the εNd(t) value of the Late Permian strata probably reflects the significant incorporation of the mantle-derived materials. The trace element data are compared with data of the Emeishan (峨嵋山) flood basalts. These data indicate that the volcanic dust has been added to the Late Permian strata during the Late Permian, represented by periods of extremely high Emeishan flood basalt activity in the south-eastern margin of the Yangtze block.     

REE geochemistry and isotopic data of Archean silicic volcanics and granitoids from the Pilbara Block,Western Australia: implications for the early crustal evolution

Eighteen silicic volcanic rocks of the Warrawoona Group and ten associated plutonic rocks from the Pilbara Block, Western Australia, have been chosen for geochemical and isotopic studies. Silicic volcanics of the UNSB (Upper member of North Star Basalt) are dated at 3.56—3.57

, by both the Rb-Sr and the Sm-Nd methods. The respective 1 (initial isotopic composition) values are 0.7005 ± 5 (Sr) and 0.50810 ± 39 (Nd). This age is consistent with the stratigraphic interpretation that the TalgaTalga Subgroup, in which the North Star Basalt occupies the lowermost position, is overlain by the Duffer Formation, whose age was earlier established at 3.45

by the zircon U-Pb method. The new Rb-Sr data on six silicic lava samples from the Duffer Formation yield an isochron of 3.23 ± 0.28 (2v). Though imprecise, this age agrees with the zircon age within error limits. Rb-Sr ages of 2.3–2.4.

obtained for the ‘Panorama’ rocks and the Wyman Formation do not correspond to their initial eruption ages. Chemical arguments suggest that these ages represent the time of metasomatism associated with the widespread thermal event in this region about 2.3–2.4

ago.Geochemically, most of these analyzed rocks (volcanic and plutonic) are of tonalite-trondhjemitegranodiorite (TTG) composition, a typical feature found in many other Archean terrains. They generally show fractionated REE patterns, except the Panorama Formation rocks. Furthermore, the Wyman Formation rhyolites and the post-tectonic adamellites show significant negative Eu anomalies, suggesting a similar mode of magma generation and a probable genetic link. Theoretical considerations suggest that most of these TTG rocks could have been generated by partial melting of amphibolitic or basaltic sources, followed by fractional crystallization.Although the Archean granitic gneisses often possess mantle-like I_sr values, the trace element data indicate that they could not have been derived by direct melting of upper mantle materials. The immediate tectonic implication is that in any Archean terrain, the formation of Na-rich continental crust of TTG suite must be preceded by the presence of basaltic crust. The occurrence of this basaltic crust is a matter of controversy. Such crust might have been totally destroyed by repeated melting processes, or its remnants are now represented by some of the mafic-ultramafic enclaves within the tonalite-trondhjemite batholiths.     

Origin and quantitative source assessment of deep oils in the Tazhong Uplift,Tarim Basin

A large amount of deep oil has been discovered in the Tazhong Uplift, Tarim Basin whereas the oil source is still controversial. An integrated geochemical approach was utilized to unravel the characteristics, origin and alteration of the deep oils. This study showed that the Lower Cambrian oil from well ZS1C (

_1x) was featured by small or trace amounts of biomarkers, unusually high concentration of dibenzothiophenes (DBTs), high δ³⁴S of DBTs and high δ¹³C value of n-alkanes. These suggest a close genetic relationship with the Cambrian source rocks and TSR alteration. On the contrary, the Middle Cambrian oils from well ZS1 (

_2a) were characterized by low δ¹³C of n-alkanes and relatively high δ³⁴S of individual sulfur compounds and a general “V” shape of steranes, indicating a good genetic affinity with the Middle–Upper Ordovician source rocks. The middle Cambrian salt rock separating the oils was suggested to be one of the factors responsible for the differentiation. It was suggested that most of the deep oils in the Tazhong Uplift were mixed source based on biomarkers and carbon isotope, which contain TSR altered oil in varied degree. The percentage of the oils contributed by the Cambrian–Lower Ordovician was in the range of 19–100% (average 57%) controlled by several geological and geochemical events. Significant variations in the δ³⁴S values for individual compounds in the oils were observed suggesting a combination of different extent of TSR and thermal maturation alterations. The unusually high DBTs concentrations in the Tazhong-4 oilfield suggested as a result of mixing with the ZS1C oil (

_1x) and Lower Ordovician oils based on δ³⁴S values of DBT. This study will enhance our understanding of both deep and shallow oil sources in the Tazhong Uplift and clarify the formation mechanisms of the unusually high DBTs oils in the region.     

http://www.sciencedirect.com/science/article/pii/S1674987112000874

<正>1.Introduction The continental crust,covering nearly a third of the Earth's surface,is dominantly made up of granites and granodiorites(Rudnick and Gao, 2003).Although the vast majority of these granitoids are amphiboleand /or biotite-bearing,orthopyroxene-bearing granitoids form a minor but important component of the lower continental crust in many high-grade terrains(e.g.,Bohlender et al.,1992;Kilpatrick and Ellis,1992;Sheraton et al.,1992;Berger et al.,1995;Zhou et al., 1995;Peucat et al.,1996;Duchesne and Wilmart,1997;Hughes et al.,1997;Prame.1997;Frost et al.,2000;Janasi,2002;Mendes     

Continental construction in Central Asia and actualistic comparisons with western Pacific: Preface

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Elevated passive continental margins: Numerical modeling vs observations. A comment on Braun (2018)

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Fission Track Geochronology of Xiaonanchuan Pluton and the Morphotectonic Evolution of Eastern Kunlun since Late Miocene

Apatite fission track （AFT） thermochronology of seven samples from the Xiaonanchuan （小南川） pluton in the Kunlun （昆仑） pass area was carried out, for the purpose of determining the timing of cooling and the relation between the exhumation and the morphotectonic processes. The AFT ages yield low denudation rates of 0. 020--0. 035 mm/a during the late Miocene, which correspond to a stable geomorphic and weak tectonic uplifting environment. The low denudation rates can be considered as the approximate tectonic uplifting rates. The AFT geochronology shows puroxysmully rapid cooling since the Pliocene and an apparent material unroofing of more than 3 km in the Xiaonanchuan area. This was not the result of simple denudation. The rapid cooling was coupled with the intensive orogeny since the Pliocene, which was driven by tectonic uplifting. The accelerated relief building was accompanied by a series of faulting, which caused the basin and the valley formation and sinking. The space pattern of the AFT ages also shows differential uplifting, which decreases northwardly. This trend is supported by the regional AFT data, which indicate that the exhumation decreases northwardly in eastern Kunlun. This trend also exists in cast-west orientation from the western Kunlun range to the eastern. The uplif- ting trend is also supported by gcomorphic characteristics including the elevation and the relief differences well as the distribution of the Late Cenozoic volcanism.     

Copper partitioning in a melt-vapor-brine-magnetite-pyrrhotite assemblage

The effect of sulfur on the partitioning of Cu in a melt-vapor-brine ± magnetite ± pyrrhotite assemblage has been quantified at 800 °C, 140 MPa, f_O2 = nickel-nickel oxide (NNO), logf_S2=-3.0 (i.e., on the magnetite-pyrrhotite curve at NNO), logf_H2S=-1.3 and logf_SO2=-1. All experiments were vapor + brine saturated. Vapor and brine fluid inclusions were trapped in silicate glass and self-healed quartz fractures. Vapor and brine are dominated by NaCl, KCl and HCl in the S-free runs and NaCl, KCl and FeCl₂ in S-bearing runs. Pyrrhotite served as the source of sulfur in S-bearing experiments. The composition of fluid inclusions, glass and crystals were quantified by laser-ablation inductively coupled plasma mass spectrometry. Major element, chlorine and sulfur concentrations in glass were quantified by using electron probe microanalysis. Calculated Nernst-type partition coefficients (±2σ) for Cu between melt-vapor, melt-brine and vapor-brine are , , and , respectively, in the S-free system. The partition coefficients (±2σ) for Cu between melt-vapor, melt-brine and vapor-brine are , , and , respectively, in the S-bearing system. Apparent equilibrium constants (±1σ) describing Cu and Na exchange between vapor and melt and brine and melt were also calculated. The values of are 34 ± 21 and 128 ± 29 in the S-free and S-bearing runs, respectively. The values of are 33 ± 22 and60 ± 5 in the S-free and S-bearing runs, respectively. The data presented here indicate that the presence of sulfur increases the mass transfer of Cu into vapor from silicate melt. Further, the nearly threefold increase in suggests that Cu may be transported as both a chloride and sulfide complex in magmatic vapor, in agreement with hypotheses based on data from natural systems. Most significantly, the data demonstrate that the presence of sulfur enhances the partitioning of Cu from melt into magmatic volatile phases.     

Sorption of yttrium and rare earth elements by amorphous ferric hydroxide: Influence of solution complexation with carbonate

The influence of solution complexation on the sorption of yttrium and the rare earth elements (YREEs) by amorphous ferric hydroxide was investigated at 25 °C over a range of pH (4.0-7.1) and carbonate concentrations . Distribution coefficients, defined as , where [MS_i]_T is the total concentration of sorbed YREE, M_T is the total YREE concentration in solution, and [S_i] is the concentration of amorphous ferric hydroxide, initially increased in magnitude with increasing carbonate concentration, and then decreased. The initial increase of is due to sorption of YREE carbonate complexes , in addition to sorption of free YREE ions (M³⁺). The subsequent decrease of , which is more extensive for the heavy REEs, is due to the increasing intensity of YREE solution complexation by carbonate ions. The competition for YREEs between solution complexation and surface complexation was modeled via the equation:

     

Dawsonite synthesis and reevaluation of its thermodynamic properties from solubility measurements: Implications for mineral trapping of CO2

Over the last decade, a significant research effort has focused on determining the feasibility of sequestering large amounts of CO₂ in deep, permeable geologic formations to reduce carbon dioxide emissions to the atmosphere. Most models indicate that injection of CO₂ into deep sedimentary formations will lead to the formation of various carbonate minerals, including the common phases calcite (CaCO₃), dolomite (CaMg(CO₃)₂), magnesite (MgCO₃), siderite (FeCO₃), as well as the far less common mineral, dawsonite (NaAlCO₃(OH)₂). Nevertheless, the equilibrium and kinetics that control the precipitation of stable carbonate minerals are poorly understood and few experiments have been performed to validate computer codes that model CO₂ sequestration.In order to reduce this uncertainty we measured the solubility of synthetic dawsonite according to the equilibrium: , from under- and oversaturated solutions at 50-200 °C in basic media at 1.0 mol · kg⁻¹ NaCl. The solubility products (Q_s) obtained were extrapolated to infinite dilution to obtain the solubility constants (. Combining the fit of these values and fixing  at 25 °C, which was derived from the calorimetric data of Ferrante et al. [Ferrante, M.J., Stuve, J.M., and Richardson, D.W., 1976. Thermodynamic data for synthetic dawsonite. U.S. Bureau of Mines Report Investigation, 8129, Washington, D.C., 13p.], the following thermodynamic parameters for the dissolution of dawsonite were calculated at 25 °C: , and . Subsequently, we were able to derive values for the Gibbs energy of formation (, enthalpy of formation ( and entropy ( of dawsonite. These results are within the combined experimental uncertainties of the values reported by Ferrante et al. (1976). Predominance diagrams are presented for the dawsonite/boehmite and dawsonite/bayerite equilibria at 100 °C in the presence of a saline solution with and without silica-containing minerals.     

The solubility of platinum and gold in NaCl brines at 1.5 kbar, 600 to 800°C: A laser ablation ICP-MS pilot study of synthetic fluid inclusions

The concentration and distribution of Pt and Au in a fluid-melt system has been investigated by reacting the metals with S-free, single-phase aqueous brines (20, 50, 70 wt% eq. NaCl) ± peraluminous melt at a confining pressure of 1.5 kbar and temperatures of 600 to 800 °C, trapping the fluid in synthetic fluid inclusions (quartz-hosted) and vesicles (silicate melt-hosted), and quantifying the metal content of the trapped fluid and glass by laser ablation ICP-MS. HCl concentration was buffered using the assemblage albite-andalusite-quartz and fO₂ was buffered using the assemblage Ni-NiO. Over the range of experimental conditions, measured concentrations of Pt and Au in the brines (, ) are on on the order of 1-10³ ppm. Concentrations of Pt and Au in the melt (, ) are ∼35-100 ppb and ∼400-1200 ppb, respectively. Nernst partition coefficients (, ) are on the order of 10²-10³ and vary as a function of (non-Henry’s Law behavior). Trapped fluids show a significant range of metal concentrations within populations of inclusions from single experiments (∼ 1 log unit variability for Au; ∼2-3 log unit variability for Pt). Variability in metal concentration within single inclusion groups is attributed to premature brine entrapment (prior to metal-fluid-melt equilibrium being reached); this allows us to make only minimum estimates of metal solubility using metal concentrations from primary inclusions. The data show two trends: (i) maximum and average values of and in inclusions decrease ∼2 orders of magnitude as fluid salinity () increases from ∼4 to 40 molal (20 to 70 wt % eq. NaCl) at a constant temperature; (ii) maximum and average values of increase approximately 1 order of magnitude for every 100°C increase temperature at a fixed . The observed behavior may be described by the general expression:

     

Complexation of Cu in Hydrothermal NaCl Brines: Ab initio molecular dynamics and energetics

Chloride complexation of Cu⁺ controls the solubility of copper(I) oxide and sulfide ore minerals in hydrothermal and diagenetic fluids. Solubility measurements and optical spectra of high temperature CuCl solutions have been interpreted as indicating the formation of CuCl, , and complexes. However, no other monovalent cation forms tri- and tetrachloro complexes. EXAFS spectra of high temperature Cu-Cl solutions, moreover, appear to show only CuCl and complexes at T > 100 °C. To reconcile these results, I investigated the nature and stability of Cu-Cl complexes using ab initio cluster calculations and ab initio (Car-Parrinello) molecular dynamics simulations for CuCl-NaCl-H₂O systems at 25 to 450 °C. Ab initio molecular dynamic simulations of 1 m CuCl in a 4 m Cl solution give a stable complex at 25 °C over 4 ps but show that the third Cl⁻ is weakly bound. When the temperature is increased along the liquid-vapour saturation curve to 125 °C, the complex dissociates into and Cl⁻; only forms at 325 °C and 1 kbar. Even in a 15.6 m Cl brine at 450 °C, only the complex forms over a 4 ps simulation run.Cluster calculations with a static dielectric continuum solvation field (COSMO) were used in an attempt directly estimate free energies of complex formation in aqueous solution. Consistent with the MD simulations, the complex is slightly stable at 25 °C but decreases in stability with decreasing dielectric constant (ε). The complex is predicted to be unstable at 25 °C and becomes increasingly unstable with decreasing dielectric constant. In hydrothermal fluids (ε < 30) both the and complexes are unstable to dissociation into and Cl⁻.The results obtained here are at odds with recent equations of state that predict and complexes are the predominant species in hydrothermal brines. In contrast, I predict that only complexes will be significant at T > 125 °C, even in NaCl-saturated brines. The high-temperature (T > 125 °C) optical spectra of CuCl solutions and solubility measurements of Cu minerals in Cl-brines need to be reinterpreted in terms of only the CuCl and complexes.