攀西白马岩体的矿物结晶顺序与钒钛磁铁矿成因

距今约260 Ma的白马岩体位于上扬子板块西缘的攀西裂谷中,是一个大型的含钒钛磁铁矿镁铁质-超镁铁质杂岩体,是峨眉山大火成岩省的重要组成部分。含矿岩体主要由磁铁橄长岩和橄榄辉长岩组成,主要工业矿体赋存在下部的橄长岩岩相带中。显微镜下显示橄榄石和角闪石均存在2种不同的结构状态,岩浆具有多次脉动的侵位特点。矿物结构特点及磁铁矿、钛铁矿、橄榄石、角闪石及斜长石等矿物电子探针成分测定显示,矿物的结晶顺序大致为斜长石+橄榄石+辉石→角闪石+磁铁矿+钛铁矿→角闪石。根据角闪石和斜长石成分计算角闪石最低结晶温度为1090℃,斜长石的最高结晶温度是1120℃,推测磁铁矿的结晶温度介于1090~1120℃之间。橄榄石的Fo值由下部的磁铁橄长岩向上部的橄榄辉长岩呈逐渐降低的变化趋势,表明随着岩浆的结晶分异进程,系统的氧逸度是逐步变化的,暗示整个结晶分异过程系统处于封闭状态。磁铁矿中w(V2O3)变化于0.72%~1.37%之间,可近似看成是岩浆演化过程氧逸度较低的量化标志(FMQ+0.5),这种低氧逸度条件下硅酸盐矿物的结晶,会导致粒间熔体氧逸度逐步升高且成分向着富Fe的方向演化。岩浆的这种成分演化特点,是晚期形成不混溶熔浆及富Fe-Ti矿浆的主要原因。     

岩浆铜镍矿与钒钛磁铁矿的过渡类型--新疆哈密香山西矿床

铜镍硫化物矿床与钒钛磁铁矿矿床虽然同属与镁铁-超镁铁质岩有关的岩浆型矿床范畴,但在一般情况下,二者是不共生的.新疆东天山地区的香山西矿床则是一个铜镍矿与钛铁矿共生的实例.香山地区为一复式含矿杂岩体,最早期形成辉长岩(如角闪辉长岩、灰白色细粒辉长岩等)为主体的侵入;第二期侵入的是以辉橄岩、单辉橄榄岩、二辉橄榄岩等为主的超镁铁质岩,含铜镍硫化物矿化;第三期则为岩浆期后残余岩浆形成的含钛铁矿化的辉长岩(脉).香山西铜镍-钛铁矿床含矿岩石的碱度、镁铁指数、岩浆酸度、钙碱富集指数等地球化学参数,氧逸度和硫逸度等物理化学参数均介于独立的典型铜镍硫化物和典型钒钛磁铁矿矿床之间.矿床中磁铁矿较其他钒钛磁铁矿矿床(尾亚)具较高的V和Ti含量,同时黄铁矿和黄铜矿具较高的Co、Ni和Cu含量,反映出成矿过程中,Cu-Ni-Co系列与V-Ti-Fe系列的分离不够彻底.形成本区CuNi-VTi复合型矿床的原因,可能在于矿床所处独特的构造环境--产于造山带,而不是克拉通(边缘).     

红柳沟北镁铁-超镁铁质岩体矿物学特征及矿石成因分析

红柳沟北镁铁-超镁铁质岩体位于柴达木陆块北部的欧龙布鲁克微陆块东北缘,呈岩墙状,出露面积约0.1km~2,由方辉橄榄岩、橄榄二辉岩、含长单辉橄榄岩、橄榄辉长苏长岩、暗色橄榄辉长岩、苏长岩、辉长岩等组成,各岩相带在空间上呈渐变过渡关系。电子探针分析结果显示,岩体的主要造岩矿物为贵橄榄石、古铜辉石、普通辉石和斜长石,并且各矿物的结晶温度为1 307~1 122℃。岩体钛铁矿化明显,主要金属矿物为钛铁矿、钛磁铁矿和磁铁矿。利用橄榄石Fo最高值反演出原生岩浆MgO含量为8.49%,FeO含量为10.03%,TiO_2含量为1.63%,为普通玄武质岩浆。通过综合研究各矿物形成的温度和氧逸度条件,认为岩浆从橄榄石结晶到普通辉石结晶,其氧逸度是缓慢升高的,并且氧逸度是控制红柳沟北岩体Ti-Fe氧化物结晶的主要因素。     

华南花岗岩类中铁钛副矿物组合与氧逸度关系

华南花岗岩中存在两类矿物组合:(1)铁透闪石 钛铁矿 榍石 磁铁矿 石英;(2)钛铁矿 方解石 石英 磁铁矿 榍石。可通过以下关系分别计算上述两组矿物组合的岩浆氧逸度。组合(1)为: logfo_2=-24940.31/T 9.25 243.43(P-10~5Pa)/T 0.86logfH_2O-0.86logα铁透闪石组合(2)为: logfo_2=-3673.68/T-37.73 590.53(P-10~5Pa)/T 6logfco_2岩浆作用过程的氧逸度(fo_2)是控制磁铁矿、钛铁矿、榍石等铁、钛副矿物形成和稳定的重要因素。     

青海尕林格地区铁多金属矿床的地质特征与地球化学特征

尕林格地区铁多金属矿床的围岩为富钙铁矽卡岩类,矿石类型为磁铁矿和硫化物磁铁矿矿石.矿石与围岩具相似的稀土元素地球化学特征,显示其可能来自于同一源区.矿床形成于中高温条件,形成过程中遭受了多次地质作用的改造.矿石矿物的硫、氧同位素组成表明,成矿物质中硫主要为岩浆来源,成矿流体中水则主要源于喷流热液.本研究认为尕林格铁-钴-铋金多金属矿为热水喷流沉积-矽卡岩化改造型矿床.     

陕南凤凰岭南缘变质镁铁质—超镁铁质侵入岩矿物学特征——对Fe-Ti成矿作用的指示

陕南凤凰岭南缘变质镁铁质—超镁铁质侵入岩为富含Fe、Ti等有用元素的含矿岩体。利用岩石地球化学方法、偏光显微镜和电子探针技术对该区镁铁质—超镁铁质侵入岩的岩石学、地球化学和矿物学特征进行了研究,并对Fe-Ti氧化物的形成、富集进行了初步探讨,对成岩、成矿作用具有一定的参考意义。结果表明,成矿镁铁质—超镁铁质侵入岩与非成矿镁铁质—超镁铁质侵入岩为不同岩浆源区、同期岩浆作用的产物,镁铁质—超镁铁质侵入岩类的Fe-Ti矿化作用与初始岩浆的源岩之间具有密切关系。Fe-Ti氧化物主要以钛铁矿和榍石的形式存在,局部见少量金红石。化学成分上,钛铁矿具富锰贫镁特征,本区Fe-Ti氧化物的形成和富集过程经历了岩浆结晶分异阶段和热液蚀变阶段。     

陕南凤凰岭南缘变质镁铁质—超镁铁质侵入岩矿物学特征——对Fe-Ti 成矿作用的指示

陕南凤凰岭南缘变质镁铁质—超镁铁质侵入岩为富含Fe、Ti等有用元素的含矿岩体。利用岩石地球化学方法、偏光显微镜和电子探针技术对该区镁铁质—超镁铁质侵入岩的岩石学、地球化学和矿物学特征进行了研究,并对Fe-Ti氧化物的形成、富集进行了初步探讨,对成岩、成矿作用具有一定的参考意义。结果表明,成矿镁铁质—超镁铁质侵入岩与非成矿镁铁质—超镁铁质侵入岩为不同岩浆源区、同期岩浆作用的产物,镁铁质—超镁铁质侵入岩类的Fe-Ti矿化作用与初始岩浆的源岩之间具有密切关系。Fe-Ti氧化物主要以钛铁矿和榍石的形式存在,局部见少量金红石。化学成分上,钛铁矿具富锰贫镁特征,本区Fe-Ti氧化物的形成和富集过程经历了岩浆结晶分异阶段和热液蚀变阶段。     

中—酸性侵入岩中钛铁矿的锰含量及其岩石成因意义

美国西部和中国东部15个中性侵入岩和I型花岗岩中的钛铁矿绝大部分属氧化出溶型,主要形成温度为755°—450℃。氧化出溶型钛铁矿的锰含量与样品中石英加碱性长石含量呈正相关,与铁镁硅酸盐矿物含量和该含量与磁铁矿含量之比值呈负相关。原始岩浆成分、结晶方式及结晶过程的氧逸度/水逸度比值对锰的晶体/熔体分配系数产生直接影响,是制约钛铁矿中锰含量的主要因素。钛铁矿中锰含量有助于估测主要造岩矿物丰度,判别某些酸性火山岩和次火山岩,推测分离结晶方式及结晶过程的物理化学条件。     

塔里木大火成岩省皮羌层状岩体的矿物结晶顺序和钒钛磁铁矿矿石成因探讨

距今约276 Ma的皮羌层状岩体位于塔里木板块西缘,是二叠纪塔里木大火成岩省的组成部分。岩体主要由辉长岩组成并赋存大型钒钛磁铁矿矿床。矿物结构和磁铁矿、钛铁矿和单斜辉石成分变化特征表明,矿物结晶顺序为单斜辉石+斜长石→磁铁矿+钛铁矿。磁铁矿中V2O3含量变化于0.49%~0.97%,说明岩浆演化过程氧逸度较低(相似文献   

塔里木大火成岩省皮羌层状岩体的矿物结晶顺序和钒钛磁铁矿矿石成因探讨

距今约276 Ma的皮羌层状岩体位于塔里木板块西缘,是二叠纪塔里木大火成岩省的组成部分。岩体主要由辉长岩组成并赋存大型钒钛磁铁矿矿床。矿物结构和磁铁矿、钛铁矿和单斜辉石成分变化特征表明,矿物结晶顺序为单斜辉石+斜长石→磁铁矿+钛铁矿。磁铁矿中V2O3含量变化于0.49%~0.97%,说明岩浆演化过程氧逸度较低(相似文献   

The terrestrial fauna of the Late Triassic Pant-y-ffynnon Quarry fissures,South Wales,UK and a new species of Clevosaurus (Lepidosauria: Rhynchocephalia)

Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco.     

Définition d'une limite multicritère ; stratigraphie du passage Campanien–Maastrichtien du site géologique de Tercis (Landes,SW France)Definition of a multi-criteria boundary; stratigraphy of the Campanian–Maastrichtian interval of the geological site at Tercis (Landes,SW France)

Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414.     

The effect of water on accessory phase solubility in subaluminous and peralkaline granitic melts

The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H₂O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H₂O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species.     

Late Wuchiapingian (Late Dzhulfian,early Late Permian) limestone olistolites within the Tertiary flysch of Glypia Unit (Mount Parnon,central–eastern Peloponnesus,Greece)

Some olistolites reworked in a Tertiary flysch of Mount Parnon (Peloponnesus, Greece) exhibit a Late Permian assemblage, dominated by Paradunbarula (Shindella) shindensis, Hemigordiopsis cf. luquensis and Colaniella aff. minima. This association corresponds to the Late Wuchiapingian (=Late Dzhulfian), a substage whose algae and foraminifera are generally little known. Contemporaneous limestones crop out in the middle part of the Episkopi Formation in Hydra, but they are rather commonly reworked in Mesozoic and Cainozoic sequences. The palaeobiogeographical affinities shared by the foraminiferal markers of Greece, southeastern Pamir, and southern China, are very strong (up to the specific level), and are congruent with the Pangea B reconstructions. To cite this article: E. Skourtsos et al., C. R. Geoscience 334 (2002) 925–931.     

PALEONTOLOGY

正20141596 Liu Yunhuan(School of Earth Sciences and Resources,Chang’an University,Xi’an 710054,China);Shao Tiequan Early Cambrian Quadrapyrgites Fossils of Xixiang Boita in Southern Shaanxi Province(Journal of Earth Sciences and Environment,ISSN1672-6561,CN61-1423/P,35(3),2013,p.39-43,3 illus.,20 refs.)     

GEOCHEMICAL EXPLORATION

正20141719 Chen Zhijun(State Key Laboratory of Geological Processes and Mineral Resources,China University of Geosciences,Wuhan 430074,China);Chen Jianguo Automated Batch Mapping Solution for Serial Maps:A Case Study of Exploration Geochemistry Maps(Journal of Geology,ISSN1674-3636,CN32-1796/P,37(3),2013,p.456-464,2 illus.,2 tables,10 refs.)     

MICROPALAEONTOLOGY

正20140962 Chen Fenning(Xi’an Institute of Geology and Mineral Resources,Xi’an710054,China);Chen Ruiming Late Miocene-Early Pleistocene Ostracoda Fauna of Gyirong Basin,Southern Tibet(Acta Geologica Sinica,ISSN0001-5717,CN11-1951/P,87(6),2013,p.872-886,6illus.,56refs.)     

PETROLOGY

正1.IGNEOUS PETROLOGY20142008Cai Jinhui(Wuhan Center,China Geological Survey,Wuhan 430205,China);Liu Wei Zircon U-Pb Geochronology and Mineralization Significance of Granodiorites from Fuzichong Pb-Zn Deposit,Guangxi,South China(Geology and Mineral Resources of South China,ISSN1007-3701,CN42-1417/P,29(4),2013,p.271-281,7illus.,     

ENVIRONMENTAL GEOLOGY

正20141205Cheng Weiming(State Key Laboratory of Resources and Environmental Information System,Institute of Geographic Sciences and Natural Resources Research,CAS,Beijing 100101,China);Xia Yao Regional Hazard Assessment of Disaster Environment for Debris Flows:Taking Jundu Mountain,Beijing as an     

PROSPECTING EXPLORATION

正20141266Fan Chaoyan(Guangdong Provincial Key Laboratory of Mineral Resources and Geological Processes,Guangzhou 510275,China);Wang Zhenghai On Error Analysis and Correction Method of Measured Strata Section with Wire Projection Method(Journal of