冈底斯南缘变形花岗岩锆石U-Pb年龄和Hf同位素组成：新特提斯洋早侏罗世俯冲作用的证据

本文对产于冈底斯南缘一个变形花岗岩进行了主量元素、微量元素、原位锆石 LA-ICP-MS U-Pb 定年和锆石 Hf 同位素组成研究。结果表明,变形花岗岩为高硅(SiO_2=73.38%～76.06%)钙碱性岩系,K_2O/Na_2O=0.69～1.17,铝指数(A/CNK)=1.03～1.07,为弱过铝质岩石。变形花岗岩微量元素组成显示贫大离子亲石元素(e.g.Rb=47×10~(-6)～71×10~(-6))和高场强元素(e.g.Nb=1.3l×10~(-6)～3.09×10~(-6),Ta=0.23×10~(-6)～0.54×10~(-6)),具有岛弧型花岗岩的地球化学属性。变形花岗岩锆石 U-Pb 年龄为178±1Ma,该年龄代表岩浆结晶年龄。锆石 Hf 同位素组成显示ε_(Hf)(178Ma)值变化于 14.1～ 17.7,表明变形花岗岩岩浆来自初生地壳物质的部分熔融。变形花岗岩的岩石成因与新特提斯洋向欧亚板块南缘的俯冲消减作用存在联系,其岩浆结晶年龄反映了新特提斯洋发生俯冲消减的开始时代不晚于早侏罗纪,说明了新特提斯洋经历了较长时间的演化。     

东昆仑群力地区晚泥盆世A型花岗岩的年代学、地球化学和构造意义

报道了东昆仑群力地区正长花岗岩体的锆石U-Pb年龄和岩石地球化学特征,并对岩石成因及其构造意义进行了讨论。锆石LA-ICP-MS U-Pb定年结果表明群力正长花岗岩体的形成时代为376.2Ma(MSWD=0.25),属晚泥盆世。岩石地球化学成分显示其属于高钾钙碱性、准铝质-弱过铝质系列花岗岩。岩体富硅(SiO_2=74.61%～77.85%)、富碱(Na_2O+K_2O=7.03%～7.94%)、高铁镁比(FeO~T/MgO=11.39～36.93)、贫钙(CaO=0.50%～1.01%)、贫镁(MgO=0.06%～0.20%);稀土配分模式表现为"海鸥型"分布特点,具有强烈的负铕异常(δEu=0.08～0.09);高镓含量(Ga=22.86×10~(-6)～27.06×10~(-6)),富集高场强元素组合(Zr+Ce+Nb+Y=720×10~(-6)～891×10~(-6))、亏损Ba、Sr、P、Nb、Ta、Ti等;同时岩体具有高的锆石饱和温度(991℃～1 201℃)。综合岩石地球化学特征表明群力正长花岗岩体属于A型花岗岩中的A_2型花岗岩,结合区域研究成果,认为群力正长花岗岩形成于始特提斯洋闭合后的伸展构造背景。这一结果将始特提斯洋闭合后的伸展作用时限从中泥盆世延长到晚泥盆世。     

伊犁盆地南缘琼博拉二长花岗岩锆石年代学及形成动力学机制

西天山造山带内琼博拉地区的长条状岩体位于伊犁盆地南缘,由二长花岗岩组成。为厘定该二长花岗岩的形成机制,本文对该二长花岗岩进行了详细的锆石U-Pb年代学、主量元素、微量元素以及Sr-Nd-Pb同位素研究。LA-ICP-MS锆石年代学研究揭示出琼博拉地区二长花岗岩成岩年龄为(330.5±2.2)Ma、(339.7±2.2)Ma、(351.2±3.0)Ma,为早中石炭世花岗岩,比伊犁盆地511矿床含矿砂体的U-Pb同位素等时线年龄(308±26Ma)老,表明该二长花岗岩体可能是该含矿砂体的一部分物质来源。岩石主量元素、微量元素和Sr-Nd-Pb同位素测试结果揭示该二长花岗岩具有以下特征:(1)SiO_2(70.15%~73.38%)含量高,碱质(K_2O+Na_2O含量为6.32%~7.88%)含量较高,A/CNK(0.82~1.03)较高,表明二长花岗岩为准铝质岩石,属于高钾钙碱性系列;(2)LREE(50.19×10~(-6)~87.92×10~(-6))相对富集,HREE(9.44×10~(-6)~12.08×10~(-6))相对亏损,无明显Eu异常(δEu为0.71~0.97);(3)富集Rb、Th、K、Pb和Sr等大离子亲石元素,相对亏损Nb、Ta、Zr、P和Ti等高场强元素;(4)初始锶同位素比值为0.7050~0.7082,143Nd/144Nd值为0.512217~0.512254,ε_(Nd)(t)为0.3~1.0,Nd模式年龄为1010~1098 Ma。二长花岗岩的Sr、Nd、Pb同位素组成表明该岩石是由幔源玄武质岩浆与地壳重熔形成的硅铝质岩浆混染形成。结合区域构造演化,本文认为二长花岗岩形成于板块的同碰撞构造环境。     

内蒙古北山造山带百合山地区350 Ma石英闪长岩的成因及对红石山-百合山洋俯冲时限的制约

对内蒙古白山岩浆弧内百合山石英闪长岩进行了LA-ICP-MS锆石U-Pb测年、Hf同位素及岩石地球化学分析。结果显示,该岩体的形成年龄为350.8±1.5 Ma,岩浆锆石的ε_(Hf)(t)值在5.28～9.88之间,模式年龄为724～1018 Ma。地球化学数据显示,百合山石英闪长岩为一套I型钙碱性系列岩石,富碱(Na_2O+K_2O=6.03%～6.96%),富钠(Na_2O/K_2O2),较低的Mg~#(35.48～39.78)、Ni(2.06×10~(-6)～5.54×10~(-6))和Cr(2.11×10~(-6)～7.93×10~(-6))含量。相对富集轻稀土元素,重稀土分馏不明显,较低的(La/Yb)_N值(4.28～5.60),无明显Eu异常,相对富集Rb、K、U等大离子亲石元素,亏损Nb、Ta、P、Ti等高场强元素等,地球化学成分表明,石英闪长岩具有俯冲带成因的特征。石英闪长岩的锆石U-Pb年龄和岩石成因证明了350 Ma石英闪长岩是晚古生代白山岩浆弧内首次发现的可以明确与红石山-百合山洋俯冲消减作用有关的最早的弧岩浆记录。表明红石山-百合山洋于约350 Ma之前就已经开始发生俯冲消减,比前人一般认为的俯冲开始的时间提前了22 Ma。     

南秦岭随州地区正长花岗岩锆石SHRIMP U-Pb年代学与地球化学特征

随州北部正长花岗岩体呈岩脉出露,年代学研究表明,正长花岗岩中岩浆锆石SHRIMP U-Pb加权平均年龄为648.8±1.9Ma(MSWD=0.86),属新元古代。岩石地球化学成分显示其属于高钾钙碱性、准铝质系列花岗岩。岩体高硅(SiO_2=70.67%～75.75%)、富碱(K_2O+Na_2O=7.28%～8.53%)、铁镁比(FeO~T/MgO=26.37～35.50)较高、钙镁含量较低(CaO=0.60%～1.53%,MgO=0.07%～0.12%);稀土元素配分曲线呈右倾斜型,显示Eu负异常(δEu=0.33～0.56);1000Ga/Al值介于2.60～3.41,Zr+Nb+Ce+Y=552.48×10~(-6)～648.87×10~(-6);微量元素原始地幔标准化蛛网图显示,Rb、K和Th等大离子亲石元素明显富集,相对富集Zr、Hf、Nb、Ta等高场强元素,相对亏损Sr、P和Ti,以上特征表明随州北部正长花岗岩为A1型花岗岩。结合区域构造演化,认为随州北部正长花岗岩形成于板内伸展的构造环境,新元古代晚期,秦岭-桐柏-大别地区构造体制经历了重要的转变,在南秦岭东段由古秦岭洋的俯冲导致的挤压作用转换为弧后拉伸减薄作用。在伸展体制下,岩浆上涌形成本区A1型正长花岗岩。     

安徽金寨岩体地质和地球化学特征及LA-ICP-MS锆石U-Pb年龄

安徽金寨岩体为一钾长花岗岩体,位于大别造山带北淮阳构造带,LA-ICP-MS锆石U-Pb定年获得岩体侵位年龄为129.7±1.5Ma,属早白垩世岩浆活动产物。岩体周边发现有数个铅锌多金属矿点,与区域岩浆作用及其矿化一致。岩体富硅(SiO_2=72.47%~77.80%)、富碱(K_2O+Na_2O=7.48%~8.16%)、贫钙(CaO=0.15%~1.47%);稀土配分曲线呈现"海鸥式"分布特征,显示强烈的Eu负异常(δEu=0.18~0.40);微量元素特征显示具有较高的Ga(21.68×10~(-6)~24.12×10~(-6))、Zr(127.68×10~(-6)~196.75×10~(-6))、Nb(33.31×10~(-6)~60.53×10~(-6))和Y(14.57×10~(-6)~27.51×10~(-6))含量,较低的Sr(8.15×10~(-6)~138.52×10~(-6))、Ba(23.04×10~(-6)~332.63×10~(-6))含量,在微量元素原始地幔标准化蛛网图上显示明显的Ba、Sr、P、和Ti的负异常。以上特征表明金寨钾长花岗岩为A型花岗岩,可能是下地壳源岩部分熔融的产物。金寨钾长花岗岩是形成于造山后伸展环境下的板内A1型花岗岩,不是形成于非造山大地构造背景下的碱性花岗岩。     

松嫩地块西缘前寒武岩浆事件——来自龙江地区古元古代花岗岩锆石LA-ICP-MS U-Pb年代学证据

松嫩地块位于中亚造山带东段,该陆块是否具有前寒武纪结晶基底以及基底的规模和性质一直存在争议。我们在龙江地区识别出~1.8Ga的岩石,揭示了松嫩地块西缘古元古代结晶基底的存在。本文对其进行了岩石地球化学、锆石LA-ICP-MS U-Pb年代学和Hf同位素研究,为探讨松嫩地块西缘古元古代晚期构造演化提供了重要信息。研究结果表明,马山二长花岗岩中的锆石大多具有清晰的振荡生长环带,结合较高的Th/U比值(1.30~2.64),表明其为岩浆成因,岩浆锆石的~(207)Pb/~(206)Pb加权平均年龄为1808±14Ma,形成于古元古代晚期;马山二长花岗岩具有富硅(Si O_2=69.50%~75.11%)、碱(K_2O+Na_2O=5.30%~8.69%)和铁(Fe O~T=2.86%~4.53%),贫钙(Ca O=0.46%~1.87%)、镁(MgO=0.25%~0.93%)的特征。稀土总量较高(∑REE=357.2×10~(-6)~587.1×10~(-6)),具强轻稀土分异((La/Yb)_N为12.2~17.6)和负Eu异常(δEu为0.27~0.77)的"燕式"稀土分配模式。大离子亲石元素Rb、Ba等富集,亏损HFSEs(Nb、Ta、Ti)和P、Sr等元素。结合岩石的Zr+Nb+Ce+Y(772.1×10~(-6)~911.1×10~(-6))和10000×Ga/Al比值(2.41~3.17)较高,全岩锆石饱和温度为891~940℃,暗示其为A型花岗岩,具造山后A_2型花岗岩的特征。马山二长花岗岩锆石ε_(Hf)(t)值介于-9.2~-2.8之间,t_(DM2)=2992~3520Ma,与华北板块北缘~1.8Ga岩浆岩具有相似的锆石Hf模式年龄。上述结果表明,马山A型花岗岩起源于幔源岩浆底侵作用引起的中-新太古代地壳岩石的部分熔融,证明陆壳已转入伸展拉张构造环境,是Columbia超级大陆裂解事件在松嫩地块西缘的响应。综合资料发现,松嫩地块已经发现的新太古代-中元古代的岩浆事件在华北克拉通都有同期的构造地质事件响应,初步认为松嫩地块与华北克拉通具有一定的亲缘性。     

塔里木盆地西北缘早二叠世后碰撞花岗质岩浆活动及其构造意义

塔里木地块西北缘的阔什布拉克钾长花岗岩富碱(Na_2O+K_2O平均8.36%8%),富钾(K_2O/Na_2O=1.27～1.47),准铝质(A/CNK=0.82～0.88),属于高钾钙碱性系列岩浆岩。岩石的稀土含量较高(∑REE=263.90×10~(-6)～445.75×10~(-6)),富集Th、U、Ta、Nb、Hf和Y等高场强元素和大离子亲石元素Rb,具有强的负Eu异常(δEu=0.003～0.019),富集高不相容元素(Zr+Nb+Ce+Y=368×10~(-6)～531×10~(-6)350×10~(-6)),高Ga(Ga/Al×10 000=4.17～4.722.6),显示出A型花岗岩的地球化学特征。岩石Th/U比值(平均为3.86)、Nb/Ta比值(平均为12.75)和Rb-Th富集、Ti亏损指示其壳源成因。对花岗岩进行的LA-ICP-MS微区原位锆石U-Pb定年结果表明,花岗岩的结晶侵位年龄为275.4±2.8 Ma。综合西南天山与塔里木盆地早二叠世花岗质岩浆活动的特点,认为早二叠世西南天山的后碰撞岩浆活动不仅在西南天山内部引起了强烈的花岗质岩浆活动,而且对塔里木地块西北边缘的花岗质岩浆活动也有显著的影响。阔什布拉克A型花岗岩也说明西南天山地区的碰撞造山作用在275.4±2.8 Ma之前已经趋于结束,以南天山洋盆为代表的古亚洲洋已基本结束了其演化历史。     

新疆阿尔泰巴斯铁列克钨多金属矿区花岗质岩体年代学和地球化学特征及其对成矿的启示

巴斯铁列克钨多金属矿床位于新疆阿尔泰造山带南缘,是近年来在区内发现的首例中型钨多金属矿床。矿体主要产于二叠纪花岗岩与上志留统-下泥盆统康布铁堡组火山-沉积岩接触带的矽卡岩中。钨矿化与矿区花岗质岩石有明显的空间关系。然而,与钨矿化有关的花岗质岩石成因尚不清楚。本文对矿区出露的与矿化关系密切的黑云母花岗岩、二长花岗岩和二云母花岗岩进行了锆石U-Pb年代学和岩石地球化学研究。3个样品的LA-ICP-MS锆石U-Pb加权平均年龄分别为282.3±3.2Ma、284.3±2.2Ma和284.8±2.3Ma,属早二叠世岩浆活动的产物,与成矿年龄一致。所有岩石具有高硅(Si O_2=73.6%~78.3%)、富碱(K_2O+Na_2O=5.15%~9.62%)富钾(K_2O/Na_2O> 1.1)、贫钙(Ca O=0.19%~0.75%)和钛(Ti O_2=0.04%~0.24%)、弱过铝-强过铝质(A/CNK=1.01~1.39)特征。这些岩石稀土元素总量(∑REE)变化较大(变化于20.3×10^-6~328×10^-6),但二云母花岗岩显示轻重稀土元素分异不明显((La/Yb)N=0.96~2.06)、Eu强烈负异常(δEu=0.07~0.41)的深"V"型稀土元素分布特征,黑云母花岗岩和二长花岗岩显示轻稀土略富集((La/Yb)N分别为2.8~5.5和4.8~7.4)且Eu负异常(δEu=0.33~0.39和0.34~0.63)明显的右倾型稀土元素分布特征。所有样品均显示相对富集Rb、Th、U、Pb元素和相对亏损Nb、Ti、P、Sr、Ba元素,但二云母花岗岩中W含量(4.6×10^-6~9.4×10^-6)相对低于黑云母花岗岩和二长花岗岩中W含量(分别为15.1×10^-6~168×10^-6和8.4×10^-6~16.0×10^-6)。所有样品的锆石具有正的高εHf(t)值(+3.8~+11)和相对年轻的亏损地幔模式年龄(Hf的tDM2为0.60~1.0Ga)。以上特征说明,这些岩石属高钾钙碱性分异I-A过渡型花岗岩。结合区域地质背景,认为这些岩体是二叠纪时期后碰撞伸展环境下两个独立岩浆事件的产物,母岩浆均来源于新生地壳熔体与幔源岩浆,经过高度分异演化后结晶形成矿区岩石。花岗质岩浆活动为巴斯铁列克钨矿床提供了成矿物质,岩浆演化过程(结晶分异与熔体-流体作用)对成矿元素有富集作用。     

甘肃大佛寺、金佛寺花岗岩体的锆石U-Pb年龄、Hf-O同位素和全岩地球化学特征及地质意义

走廊过渡带大佛寺花岗岩为弱过铝质(A/CNK=1.03~1.06),SiO_2(76.7%~78.9%)、全碱(Na2O+K2O=7.7%~8.3%)、Rb(303×10~(-6)~383×10~(-6))、Nb(32×10~(-6)~42×10~(-6))、重稀土(Yb~8×10~(-6))含量以及和FeOT/MgO(6.3~7.6)、Ga/Al(3×10-4)、Rb/Ba(3.0~6.2)比值较高,MgO(~0.1%)、CaO(0.5%~0.6%)含量较低,Ba、Sr、Eu、Ti强烈亏损,属A型花岗岩,其源岩可能为泥质岩。大佛寺花岗岩中锆石δ18O和εHf(t)值分别为7.8‰~8.6‰(平均8.24±0.13‰)和-4.8~-2.0,Hf同位素两阶段亏损地幔模式年龄1540~1717Ma,岩浆温度达到~820℃以上。北祁连造山带北缘金佛寺花岗岩为过铝质(A/CNK=1.0~1.1),SiO_2(65.5%~75.0%)、MgO(0.6%~2.2%)、Fe2O3(1.9%~5.2%)、TiO_2(0.3%~0.8%)含量变化较大,其主量和微量元素特征与北祁连造山带的柴达诺花岗岩相似,源岩可能包括杂砂岩和角闪岩。金佛寺花岗岩的锆石δ18O为7.4%~9.7‰(平均8.03±0.36‰),εHf(t)在-0.5~+1.9之间,Hf同位素两阶段亏损地幔模式年龄为1289~1439Ma,岩浆温度达到800~900℃。走廊过渡带大佛寺花岗岩、北祁连造山带北缘金佛寺花岗岩的锆石U-Pb SIMS年龄分别为426.1±2.8Ma、424.0±1.6Ma,不同构造单元发育同时期岩浆活动以及A型花岗岩的出现,表明在~425Ma北祁连洋盆已经闭合,北祁连造山带及邻区进入到后碰撞拉伸阶段。     

Police, politics, and the right to the city

Space and spatiality have recently been at the core of debates concerning the political possibilities of the city. The arguments advanced in this paper might be seen as an attempt to contribute to these debates through a reflection on the spatiality of (in) justice, politics, and the right to the city. The case of French urban policy, with its focus on distressed urban areas, and the `suburban problem' in France are used as examples to make arguments more concrete.     

Rb-Sr, K-Ar, H-and O-Isotope systematics of the Middle Riphean shales from the Debengda Formation, the Olenek Uplift, North Sibera

Clay subfractions (SFs) of <0.1, 0.1–0.2, 0.2–0.3, 0.3–0.6, 0.6–2 and 2–5 μm separated from Middle Riphean shales of the Debengda Formation are studied using the TEM, XRD, K-Ar and Rb-Sr isotopic methods. The oxygen and hydrogen isotope compositions in the SFs are studied as well. The low-temperature illite-smectite is dominant mineral in all the SFs except for the coarsest ones. The XRD, chemical and isotopic data imply that two generations of authigenic illite-smectite different in age are mixed in the SFs. The illite crystallinity index decreases in parallel with size diminishing of clay particles. As compared to coarser SFs, illite of fine-grained subfractions is enriched in Al relative to Fe and Mg, contains more K, and reveals higher K/Rb and Rb/Sr ratios. The Rb-Sr age calculated by means of the leachochron (“inner isochron”) method declines gradually from 1254-1272 Ma in the coarsest SFs to 1038-1044 Ma in finest ones, while the K-Ar age decreases simultaneously from 1225–1240 to 1080 Ma. The established positive correlation of δ¹⁸O and δD values with dimensions of clay particles in the SFs seems to be also consistent with the mixing systematics. The isotopic systematics along with data on mineral composition and morphology lead to the conclusion that mixedlayer illite-smectite was formed in the Debengda shales during two periods 1211–1272 and 1038–1080 Ma ago. The first period is likely close to the deposition time of sediments and corresponds to events of burial catagenesis, whereas the second one is correlative with the regional uplift and changes in hydrological regime during the pre-Khaipakh break in sedimentation.     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Influences of the unsaturated,saturated, and riparian zones on the transport of nitrate near the Merced River,California, USA

Transport and transformation of nitrate was evaluated along a 1-km groundwater transect from an almond orchard to the Merced River, California, USA, within an irrigated agricultural setting. As indicated by measurements of pore-water nitrate and modeling using the root zone water quality model, about 63% of the applied nitrogen was transported through a 6.5-m unsaturated zone. Transport times from recharge locations to the edge of a riparian zone ranged from approximately 6 months to greater than 100 years. This allowed for partial denitrification in horizons having mildly reducing conditions, and essentially no denitrification in horizons with oxidizing conditions. Transport times across a 50–100-m-wide riparian zone of less than a year to over 6 years and more strongly reducing conditions resulted in greater rates of denitrification. Isotopic measurements and concentrations of excess N₂ in water were indicative of denitrification with the highest rates below the Merced River. Discharge of water and nitrate into the river was dependent on gradients driven by irrigation or river stage. The results suggest that the assimilative capacity for nitrate of the groundwater system, and particularly the riverbed, is limiting the nitrate load to the Merced River in the study area.     

扬子北缘马元铅锌矿床闪锌矿微量元素及S-Pb-He-Ar-C同位素地球化学研究

马元铅锌矿床是近年扬子陆块北缘铅锌找矿的新突破。矿体呈层状、似层状产于碑坝隆起翼部震旦系灯影组角砾状白云岩层间构造带中,围岩蚀变很弱。矿石中硫化物以闪锌矿、方铅矿为主,中粗粒晶质结构,充填于白云岩角砾间。闪锌矿富集Cd、Ge、Ag,贫In、Tl、Se,Ga/In为6~132,Ge/In多1000,成矿温度以中-低温为主。金属硫化物ε~(34)S值相对集中,为12.9‰~19.4‰,平均为17.4‰,来自于海相硫酸盐的还原。铅同位素组成稳定,~(206)Pb/~(204)Pb为17.858~17.918:~(207)Pb/~(204)Pb为15.603~15.694;~(208)Pb/~(204)Pb为37.756~38.046,具有造山带和上地壳铅的特征,震旦系可能提供了金属成矿物质。闪锌矿中流体包裹体的~3He/~4He为0.03Ra~1.05Ra,~(40)Ar/~(36)Ar为326.1~765.1,~(38)Ar/~(36)Ar为0.183~0.204,表明成矿流体主要为地壳流体和饱和大气水(大气降水或海水)的混合。闪锌矿内流体包裹体挥发分δ~(13)C_(CH_4)值为-36.01‰~-28.80‰,δ~(13)C_(C_2H_6)值为-27.72‰~-22.44‰,δ~(13)C_(CO_2)值为-23.24‰~-9.68‰,表明有机流体参与了成矿作用。石英、方解石的H-O同位素结果表明具有海水和有机水混合的特征。可见,成矿流体具有两种流体混合的特征,一为蒸发海水与围岩反应所形成的盆地卤水,二为有机流体。推测矿区可能存在一个古油气藏,由于TSR生成一高硫气藏,为区内还原性有机流体的主要来源。当富含Pb、Zn等成矿物质的成矿流体运移至富含CH_4和H_2S的还原性流体的矿区角砾岩带时,两种流体混合,Pb、Zn等遇到H_2S发生反应而沉淀成矿,并伴生热液白云石等,形成了马元铅锌矿床。综上所述,我们认为马元矿床属MVT型铅锌矿床。     

贵州岑巩羊桥罗家塘杷榔动物群的发现及其后生动物早期演化的意义

岑巩县羊桥乡罗家塘杷榔组仅出露中-上部地层,岩性单一,均为青灰、灰绿色粉砂质泥、页岩.在其上部层位发现了俞氏贵州始海百合(Guizhoueocrinus yui Zhao,Parsley et Peng,2007),计有棘皮动物始海百合、腕足动物、软体动物-软舌螺、节肢动物-三叶虫等8属9种,包括了2个未定名的新种和1...     

Breakthroughs in the biodiversity, biogeography, biostratigraphy, and basin analysis of the Beaufort group

Over the past decade researchers working on the rocks of the Beaufort Group in the main Karoo Basin of South Africa have vastly increased our understanding of this important Permo-Triassic sequence. Many new fossil forms have been discovered, allowing for breakthroughs into the biodiversity, biogeography and biostratigraphy of the group. Taxonomic and phylogenetic advances are many and varied, and cover most of the vertebrate taxa, but with emphasis placed on the temnospondyl amphibians, archosauriforms and non-mammalian synapsids, in particular the anomodontia. Biostratigraphic breakthroughs have centered on the Middle Permian Eodicynodon and Tapinocephalus assemblage zones, the Late Permian Dicynodon Assemblage Zone, and the Triassic Lystrosaurus and Cynognathus assemblage zones. Correlation of these biozones with better dated sequences in Europe, Russia and China has allowed for many chronostratigraphic refinements, which are in turn vital for sequence stratigraphical analysis of the basin fill. Based on fossil data, both the lower (Ecca–Beaufort) and upper (Beaufort–Molteno) contacts of the group have been proved to be highly diachronous. The refined chronostratigraphic framework has also allowed for a better analysis of the basin evolution through time, particularly in terms of the correlation of external stimuli that affect basin sedimentation patterns.     

Delivery of Trace Metals (Al,Fe, Mn,V, Co,Ni, Cu,Cd, Ag,Pb) from the Trinity River Watershed Towards the Ocean

The Trinity River (Texas, USA) contains in its watershed 23 different reservoir lakes, the largest one being Lake Livingston situated in the lower Trinity River watershed and two potentially polluting metroplexes, Dallas and Houston. In order to determine fluxes of nutrients and trace metals to Galveston Bay, a survey that included 24 discreet samples collected over a year and at various stages of discharge was carried out during 2000–2001. Geochemical (i.e., sorption by Fe oxyhydroxides), biological (i.e., seasonal uptake by sinking algae in Lake Livingston), and hydrological (i.e., dilution effects by increasing flow rates) controls were found to be mainly responsible for variations in dissolved trace metal concentrations rather than pollution sources. The Trinity River loads of suspended sediments and pollutant trace metals entering Galveston Bay at Anahuac were <20% of those reaching Lake Livingston, and only a few percent of the total upstream trace metal load is entering the Gulf of Mexico. Thus, during the transit through the 23 man-made lakes and an estuary, >96% of the pollutant trace metal load is lost to sediments.     

深港西部通道填海区地下水铜、钒、铊、镉、钨迁移的实验研究

填海工程使滨海地区的地下水物理化学条件改变,导致该区域地下水中重金属浓度升高。本文以深港西部通道填海区为例,采用实验室模拟填海条件的办法,初步探讨了影响填海区地下水重金属迁移的关键因素。模拟实验结果表明,填海区地下水中钨元素含量升高与地下水淡化、淤泥氧化过程以及填料风化有关;铜元素含量升高则与淤泥氧化过程以及填料风化有关;钒元素含量升高与地下水淡化和淤泥氧化过程有关,而其他元素含量升高则主要与填料风化释放有关。