40Ar/39Ar age pattern associated with differential uplift along the Eastern Highlands shear zone,Cape Breton Island,Canadian Appalachians

The Eastern Highlands shear zone in Cape Breton Island is a crustal scale thrust. It is characterized by an amphibolite-facies deformation zone ∼5 km wide formed deep in the crust that is overprinted by a greenschist-facies mylonite zone ∼1 km wide that formed at a more shallow level. Hornblende ⁴⁰Ar/³⁹Ar plateau ages on the hanging wall decrease towards the centre of the shear zone. In the older zone (over 7.8 km from the centre), the ages are between ∼565 and ∼545 Ma; in the younger zone (within 4.5 km of the centre), they are between ∼425 and ∼415 Ma; and in the transitional zone in between, they decrease abruptly from ∼545 to ∼425 Ma. Pressures of crystallization of plutons in the hanging wall, based on the Al-in-hornblende barometer and corresponding to depth of emplacement, increase towards the centre of the shear zone and indicate a differential uplift of up to ∼28 km associated with movement along the shear zone. The age pattern is interpreted to have resulted from the differential uplift. The pressure data show that rocks exposed in the younger zone were buried deep in the crust and did not cool through the hornblende Ar blocking temperature (∼500°C) until differential uplift occurred. The ⁴⁰Ar/³⁹Ar ages in the zone (∼425–415 Ma) thus date shear zone movement or the last stage of it. In contrast, rocks in the older zone were more shallowly buried before differential uplift and cooled through the blocking temperature soon after the emplacement of ∼565–555 Ma plutons in the area, long before shear zone movement. The transitional zone corresponds to the Ar partial retention zone before differential uplift. The ⁴⁰Ar/³⁹Ar age pattern thus reflects a Neoproterozoic to Silurian cooling profile that was exposed as a result of differential uplift related to movement along the shear zone. A similar K–Ar age pattern has been reported for the Alpine fault in New Zealand. It is suggested that such isotopic age patterns can be used to help constrain the ages, kinematics, displacements and depth of penetration of shear zones.     

The stratoid granites of central Madagascar: paleomagnetism and further age constraints on neoproterozoic deformation

A paleomagnetic and ⁴⁰Ar/³⁹Ar study of a 630-Ma alkaline granite suite in Madagascar, the so-called ‘stratoid’ granites, reveals a complex history of remagnetization during the formation of the Antananarivo Zone de Virgation at ∼560 Ma (D₂) and the Angavo shear zone at ∼550 Ma (D₃). ⁴⁰Ar/³⁹Ar dating of hornblende, biotite and potassium feldspar from rocks affected by D₂/D₃ show initial cooling rates of 8 °C/Ma during the 550–520 Ma interval followed by slower cooling of 2.5 °C/Ma. The thermal effects of the D₂ and D₃ events appear to be restricted to regions surrounding the shear zones as evidenced by a ⁴⁰Ar/³⁹Ar biotite age of 611.9±1.7 Ma north of the virgation zone. The paleomagnetic data from the stratoid granites are complex and some sites, particularly in areas to the north of the virgation zone, may have been rotated about non-vertical axes following their emplacement and cooling. Because of these possible rotations, our best estimate for the paleomagnetic pole for Madagascar is derived from sites within the virgation zone. This pole falls at 6.7°S, 352.6°E (a₉₅=14.2°). A post-metamorphic cooling history for the virgation zone indicates a magnetization age of 521.4±11.9 Ma. Our work in central Madagascar, coupled with previous studies, suggests that emplacement of the 630 Ma stratoid granites followed a collisional (?) tectonic event beginning around 650 Ma, recently recognized in southern Madagascar and in Tanzania. Subsequently, the stratoid granites in the Antananarivo virgation zone were reheated (∼750–800 °C) at pressures between 3.5 and 3.6 kbars resulting in a pervasive remagnetization. We suggest that the younger shear events are genetically related to collisional tectonics elsewhere during the final stages of Gondwana assembly and are a consequence of the Kuunga Orogeny further south.     

An 40Ar–39Ar investigation of the Mertz Glacier area (George V Land,Antarctica): Implications for the Ross Orogen–East Antarctic Craton relationship and Gondwana reconstructions

George V Land (Antarctica) includes the boundary between Late Archean–Paleoproterozoic metamorphic terrains of the East Antarctic craton and the intrusive and metasedimentary rocks of the Early Paleozoic Ross–Delamerian Orogen. This therefore represents a key region for understanding the tectono-metamorphic evolution of the East Antarctic Craton and the Ross Orogen and for defining their structural relationship in East Antarctica, with potential implications for Gondwana reconstructions. In the East Antarctic Craton the outcrops closest to the Ross orogenic belt form the Mertz Shear Zone, a prominent ductile shear zone up to 5 km wide. Its deformation fabric includes a series of progressive, overprinting shear structures developed under different metamorphic conditions: from an early medium-P granulite-facies metamorphism, through amphibolite-facies to late greenschist-facies conditions. ⁴⁰Ar–³⁹Ar laserprobe data on biotite in mylonitic rocks from the Mertz Shear Zone indicate that the minimum age for ductile deformation under greenschist-facies conditions is 1502 ± 9 Ma and reveal no evidence of reactivation processes linked to the Ross Orogeny. ⁴⁰Ar–³⁹Ar laserprobe data on amphibole, although plagued by excess argon, suggest the presence of a ∼1.7 Ga old phase of regional-scale retrogression under amphibolite-facies conditions. Results support the correlation between the East Antarctic Craton in the Mertz Glacier area and the Sleaford Complex of the Gawler Craton in southern Australia, and suggest that the Mertz Shear Zone may be considered a correlative of the Kalinjala Shear Zone. An erratic immature metasandstone collected east of Ninnis Glacier (∼180 km east of the Mertz Glacier) and petrographically similar to metasedimentary rocks enclosed as xenoliths in Cambro–Ordovician granites cropping out along the western side of Ninnis Glacier, yielded detrital white-mica ⁴⁰Ar–³⁹Ar ages from ∼530 to 640 Ma and a minimum age of 518 ± 5 Ma. This pattern compares remarkably well with those previously obtained for the Kanmantoo Group from the Adelaide Rift Complex of southern Australia, thereby suggesting that the segment of the Ross Orogen exposed east of the Mertz Glacier may represent a continuation of the eastern part of the Delamerian Orogen.     

Tectonic evolution of the India–Asia suture zone since Middle Eocene time,Lopukangri area,south-central Tibet

Suture zones often archive complex geologic histories underscored by episodes of varying style of deformation associated with intercontinental collision. In the Lopukangri area of south-central Tibet (29°54′N, 84°24′E) field relationships between tectonic units juxtaposed by the India–Asia suture are well exposed, including Indian passive margin rocks (Tethyan Sedimentary Sequence), forearc deposits (Xigaze Group), magmatic arc rocks (Gangdese batholith and Linzizong Formation) and syncollision deposits (Eocene–Miocene conglomerates). To better understand the structural history of this area, we integrated geologic mapping with biotite ⁴⁰Ar/³⁹Ar thermochronology and zircon U–Pb geochronology. The first-order structure is a system of north-directed thrusts which are part of the Great Counter thrust (GCT) that places Indian passive margin rocks and forearc deposits on top of magmatic arc rocks and syn-tectonic conglomerates. We infer the south-directed Late Oligocene Gangdese Thrust (GT) exists at unexposed structural levels based on field mapping, cross sections, and regional correlations as it has been documented immediately to the east. A granite in the footwall has a U–Pb zircon age of 38.4 ± 0.4 Ma, interpreted to be the age of emplacement of the granite, and a younger ⁴⁰Ar/³⁹Ar biotite age of 19.7 ± 0.1 Ma. As the granite sample is situated immediately below a nonconformity with low grade greenschist facies rocks, we interpret the younger age to reflect Miocene resetting of the biotite Ar system. Syn-tectonic deposits in the Lopukangri area consist of three conglomerate units with a total thickness of ∼1.5 km. The lower two units consist of cobble gravel pebble conglomerates rich in volcanic and plutonic clasts, transitioning to conglomerates with only sedimentary clasts in the upper unit. We correlate the syncollision deposits to the Eocene–Oligocene Qiuwu Formation based on field relationships, stratigraphy and petrology. Petrology and clast composition suggest the lower two units of the Qiuwu Formation had a northern provenance (Lhasa block and magmatic arc) and the upper unit had a southern provenance (Tethyan Sedimentary Sequence). Our observations are consistent with paleocurrent data from other studies which suggest a predominant south-directed paleoflow for this formation. We propose a model in which: (1) granites intrude at 38.4 ± 0.4 Ma; (2) are exhumed by erosion; (3) and buried due to regional subsidence and initial deposition of a conglomerate unit; (4) exposed by the GT at ∼27–24 Ma to provide detritus; (5) buried a second time by hanging wall-derived sedimentary deposits and the GCT, then (6) exposed from a depth of ∼12–10 km by a blind thrust at ∼19 Ma. An alternate model describes: (1) intrusion of the granites at 38.4 ± 0.4 Ma, followed by (2) exhumation of the granites via normal faulting to provide detritus; (3) then burial by the GCT at ∼24 Ma, followed by (4) exhumation via regional erosional denudation at ∼19 Ma. Exposure of the GT west of Xigaze has not been confirmed. We suggest that shallower structural levels of the India-Asia suture zone are exposed to the west of the study area, compared to the east, where the GT has been previously documented. The GCT in the area is short-lived, as it is cut and offset by a Middle Miocene ∼N-striking W-dipping oblique normal fault system.     

Anatomy of a world-class epizonal orogenic-gold system: A holistic thermochronological analysis of the Xincheng gold deposit,Jiaodong Peninsula,eastern China

Xincheng is a world-class orogenic-gold deposit hosted by the Early Cretaceous Guojialing granitoid in the Jiaodong Peninsula, eastern China. A zircon U–Pb age of 126 ± 1.4 Ma, together with previous data, constrain the emplacement of the Guojialing intrusion to 132–123 Ma. The granitoid underwent subsolidus ductile deformation at >500 °C following its intrusion. The small difference in age between the youngest zircon U–Pb age of unaltered granitoid (~123 Ma) and the ca. 120 Ma ⁴⁰Ar/³⁹Ar ages of sericite, associated with breccias and gold mineralization within it indicate initial rapid cooling from magmatic temperatures to those prevalent during brittle deformation and associated gold mineralization at ~220–300 °C. Evidence of a direct association between granitic magmatism and gold mineralization, such as at least localized near-magmatic depositional temperatures and metal zoning evident in undoubted intrusion-related gold deposits, is absent. The ⁴⁰Ar/³⁹Ar age of ~120 Ma coincides with the mineralization age of many other orogenic-gold deposits along the Jiaojia Fault. Sixteen zircon fission-track (ZFT) ages across the ore and alteration zones range from 112.9 ± 3.4 to 99.1 ± 2.7 Ma. The long period of cooling to the ~100 Ma ZFT closure temperatures recorded here suggests that ambient temperatures for hydrothermal alteration systems lasted to ~100 Ma, possibly because of their focus at Xincheng within the young Guojialing granitoid as it cooled more slowly below approximately 300 °C to 220 °C. However, the restricted number of auriferous ore stages, combined with the presence of cross-cutting gold-free quartz-carbonate veins, indicate that gold itself was only deposited over a restricted time interval at ~120 Ma, consistent with studies of orogenic gold deposits elsewhere. This highlights the complex interplay between magmatism, deformation and the longevity of hydrothermal systems that cause genetic controversies. Based on apatite fission-track (AFT) ages, the Xincheng gold deposit was then uplifted and exhumed to near the surface of the crust at 15 Ma, probably due to movement on the crustal-scale Tan-Lu Fault. Recognition of such exhumation histories along gold belts has conceptual exploration significance in terms of the probability of discovery of additional exposed or sub-surface gold ore bodies as discovery is as much a function of preservation as formation of the deposits.     

SHRIMP U–Pb and Ar–Ar geochronology of major porphyry and skarn Cu deposits in the Balkhash Metallogenic Belt,Central Asia,and geological implications

The Balkhash Metallogenic Belt (BMB) in Kazakhstan, Central Asia, with the occurrence of the super-large Kounrad and Aktogai, the large Borly porphyry Cu–Mo deposits, and the large Sayak skarn polymetallic ore-field, is one of the central regions of the Paleozoic Central Asian metallogenic domain and orogenic belt. In this study, newly obtained SHRIMP zircon U–Pb ages of nine samples and ⁴⁰Ar/³⁹Ar ages of six mineral samples (inclding hornblende, biotite and K-feldspar) give more detailed constraints on the timing of the granitic intrusions and their metallogeny. Porphyritic monzonite granite and tonalite porphyry from the Kounrad deposit yield U–Pb zircon SHRIMP ages of 327.3 ± 2.1 Ma and 308.7 ± 2.2 Ma, respectively. Quartz diorite and porphyritic granodiorite from the Aktogai deposit yield U–Pb SHRIMP ages of 335.7 ± 1.3 Ma and 327.5 ± 1.9 Ma, respectively. Porphyritic granodiorite and granodiorite from the Borly deposit yield U–Pb SHRIMP ages of 316.3 ± 0.8 Ma and 305 ± 3 Ma, respectively. Diorite, granodiorite, and monzonite from the Sayak ore-field yield U–Pb SHRIMP ages of 335 ± 2 Ma, 308 ± 10 Ma, and 297 ± 3 Ma, respectively. Hornblende, biotite, and K-feldspar from the Aktogai deposit yield ⁴⁰Ar/³⁹Ar cooling ages of 310.6 Ma, 271.5 Ma, and 274.9 Ma, respectively. Hornblende, biotite, and K-feldspar from the Sayak ore-field yield ⁴⁰Ar/³⁹Ar cooling ages of 287.3 ± 2.8 Ma, 307.9 ± 1.8 Ma, and 249.8 ± 1.6 Ma, respectively. The new ages constrain the timing of Late Paleozoic felsic magmatism to ∼336 to ∼297 Ma. Skarn mineralization in the Sayak ore-field formed at ∼335 and ∼308 Ma. Porphyry Cu–Mo mineralization in the Kounrad deposit and the Aktogai deposit formed at ∼327 Ma, and in the Borly deposit at ∼316 Ma. The Late Paleozoic regional cooling in the temperature range of ∼600 °C to ∼150 °C occurred from ∼307 to ∼257 Ma.     

Brachinite meteorites: Partial melt residues from an FeO-rich asteroid

Brachinites are ultramafic, dunitic to wherlitic, unbrecciated and essentially unshocked rocks that are low in SiO₂ (∼36–39 wt.%), high in MgO (∼27–30 wt.%) and notably high in FeO (∼26–37 wt.%), and low in Al₂O₃ (∼0.2–2.5 wt.%) and combined alkalis Na₂O and K₂O (∼0–0.7 wt.%). They consist mostly of olivine (∼71–96 vol.%; ∼Fo_64–73), major clinopyroxene (minor to ∼15 vol.%; ∼En_40–63Wo_36–48), with variable small amounts of plagioclase (0 to ∼10 vol.%; ∼An_15–33), and minor to trace amounts of orthopyroxene (none to ∼20 vol.%; En_69–73Wo_2–4), Fe-sulfides (trace to ∼7 vol.%), chromite (none to ∼5 vol.%), phosphates (none to ∼3 vol.%) and metallic Fe,Ni (trace to ∼2 vol.%). Minerals tend to be homogeneous, and textures are medium to coarse-grained (∼0.1–1.5 mm), with olivine commonly displaying triple junctions. Brachina has near-chondritic lithophile element abundances, whereas other brachinites show variable depletions in Al, Ca, Rb, K, Na, and LREE. Siderophile element abundance patterns vary and range from ∼0.01 to ∼0.9 CI. Oxygen isotope composition (Δ¹⁷O) ranges from ∼−0.09 to −0.39‰, with the mean = −0.23 ± 0.14‰. Brachinites are ancient rocks, as was recognized early by the detection, in some brachinites, of excess ¹²⁹Xe from the decay of short-lived ¹²⁹I (half-life 17 Ma) and of fission tracks from the decay of ²⁴⁴Pu (half-life 82 Ma) in phosphate, high-Ca clinopyroxene and olivine. The first precise crystallization age was determined for Brachina using ⁵³Mn–⁵³Cr systematics, relative to the Pb–Pb age of the angrite LEW 86010, and yielded an age of 4563.7 ± 0.9 Ma. Thus, Brachina is at most ∼4 Ma younger that the CAIs whose age is 4567.2 ± 0.6 Ma. There is no consensus on the origin of brachinites, but they most likely are primitive achondrites, i.e., ultra-mafic residues from various low degrees of partial melting. Partial melting experiments suggest that they possibly formed from a parent lithology chemically similar but not identical to the Rumuruti (R) chondrites, although the different oxygen isotopic compositions of the R chondrites and the brachinites put a serious constraint on this hypothesis. The apparent lack of abundant rocks representing the partial melts suggests that brachinites may have formed on a parent body <∼100 km in radius, where early partial melts were removed from the parent body by explosive pyroclastic volcanism. Graves Nunataks 06128 and 06129 are felsic, andesitic basalts which have properties that suggest a relationship to brachinites and thus, may be samples of the elusive partial melts.     

Geology,fluid inclusion geochemistry,and 40Ar/39Ar geochronology of the Wulasigou Cu deposit,and their implications for ore genesis,Altay, Xinjiang,China

The Wulasigou Cu deposit occurs as veins controlled by a NW-trending structure in a Devonian volcano-sedimentary basin of the Altay orogenic belt, Xinjiang, China. Igneous and sedimentary rocks exposed in the area have undergone greenschist-facies metamorphism. The ore-forming process can be divided into early, middle, and late stages, represented by, respectively, pyrite-quartz, polymetallic sulfide-quartz, and carbonate–quartz veins, veinlets, and/or replacement bodies. The early veins were deformed and brecciated during a compressional or transpressional event. The middle-stage veinlets filled fractures in the early-stage vein and alteration assemblages, and are undeformed, suggesting a tensional shear setting. The late-stage veinlets are mainly open-space fissure fillings that cut veins and replacement bodies formed in the earlier stages.Four types of fluid inclusions (FIs), including aqueous (W-type), mixed carbonic-aqueous (M-type), purely carbonic (C-type) and daughter mineral-bearing (S-type), have been identified in copper-related quartz and calcite from the Wulasigou deposit. The early-stage quartz contains M- and W-type primary FIs that completely homogenized at temperatures of 322–412 °C with low salinities of 0.9–6.5 wt.% NaCl equiv. In contrast, the late-stage quartz or calcite contains only the W-type FIs with homogenization temperatures of 101–234 °C, and salinities of 0.9–2.9 wt.% NaCl equiv. This indicates that the metallogenic system evolved from CO₂-rich, metamorphic to CO₂-poor, through input of meteoric fluids. All four types of FIs can only be observed in the middle-stage minerals, where they show evidence of vein formation during an episode of fluid immiscibility. These FIs homogenized at temperatures ranging mainly from 230 to 347 °C, with salinities clustering 2.7–10.2 wt.% NaCl equiv for the W-, M- and C-types, and 34.7–38.2 wt.% NaCl equiv for the S-type, respectively. The metal precipitation resulted from a decrease in copper solubility during the fluid immiscibility episode. The estimated trapping pressures for the middle-stage fluids are 1.55–3.55 kbar, suggesting an alternating lithostatic-hydrostatic fluid-system, controlled by fault-valve activity at a depth of 13–15.5 km.Muscovite separates from the middle-stage polymetallic-quartz veinlets yield a well-defined ⁴⁰Ar/³⁹Ar isotopic plateau age of 219.41 ± 2.10 Ma, and an ³⁹Ar/³⁶Ar - ⁴⁰Ar/³⁶Ar isochron age of 219.73 ± 2.17 Ma. This age postdates the final Paleo-Asia Ocean closure (at ca. 250 Ma) by about 30 Ma, and indicates that the Cu mineralization at Wulasigou has occurred in the Triassic continental collision setting. Hence, the Wulasigou Cu deposit may be the first example of orogenic lode Cu deposits formed in accretionary orogeny or continental collision.     

40Ar/39Ar and U–Pb dating of the Fish Canyon magmatic system,San Juan Volcanic field,Colorado: Evidence for an extended crystallization history

The ∼ 5000 km³ Fish Canyon Tuff (FCT) is an important unit for the geochronological community because its sanidine, zircon and apatite are widely used as standards for the ⁴⁰Ar/³⁹Ar and fission track dating techniques. The recognition, more than 10 years ago [Oberli, F., Fischer, H. and Meier, M., 1990. High-resolution ²³⁸U–²⁰⁶Pb zircon dating of Tertiary bentonites and Fish Canyon Tuff; a test for age “concordance” by single-crystal analysis. Seventh International Conference on Geochronology, Cosmochronology and Isotope Geology. Geological Society of Australia Special Publication Canberra, 27:74], of a ≥ 0.4 Ma age difference between the U–Pb zircon ages and ⁴⁰Ar/³⁹Ar sanidine ages has, therefore, motivated efforts to resolve the origin of this discrepancy. To address this controversial issue, we initially performed 37 U–Pb analyses on mainly air-abraded zircons at ETH Zurich and nearly 200 ⁴⁰Ar/³⁹Ar measurements on hornblende, biotite, plagioclase and sanidine obtained at the University of Geneva, using samples keyed to a refined eruptive stratigraphy of the FCT magmatic system.Disequilibrium-corrected ²⁰⁶Pb/²³⁸U ages obtained for 29 single-crystal and three multi-grain analyses span an interval of ∼ 28.67–28.03 Ma and yield a weighted mean age of 28.37 ± 0.05 Ma (95% confidence level), with MSWD = 8.4. The individual dates resolve a range of ages in excess of analytical precision, covering ∼ 600 ka. In order to independently confirm the observed spread in zircon ages, 12 additional analyses were carried out at the Berkeley Geochronology Center (BGC) on individual zircons from a single lithological unit, part of them pre-treated by the “chemical abrasion” (CA) technique [Mattinson, J.M., 2005. Zircon U–Pb chemical abrasion (“CA-TIMS”) method: Combined annealing and multi-step partial dissolution analysis for improved precision and accuracy of zircon ages. Chemical Geology, 220(1–2): 47–66]. Whereas the bulk of the BGC results displays a spread overlapping that obtained at ETH, the group of CA treated zircons yield a considerably narrower range with a mean age of 28.61 ± 0.08 Ma (MSWD = 1.0). Both mean zircon ages determined at ETH and BGC are older than the ∼ 28.0 Ma ⁴⁰Ar/³⁹Ar eruption age of FCT – even when considering the possibility that the latter may be low by as much as ∼ 1% due to a miscalibration of the ⁴⁰K decay constants – and is thus indicative of a substantial time gap between magma crystallization and extrusion. The CA technique further reveals that younger FCT zircon ages are likely to be associated with chemically unstable U-enriched domains, which may be linked to crystallization during extended magma residence or may have been affected by pre-eruptive and/or post-eruptive secondary loss of radiogenic lead. Due to their complex crystallization history and/or age bias due to Pb loss, the FCT zircon ages are deemed unsuitable for an accurate age calibration of FCT sandine as a fluence monitor for the ⁴⁰Ar/³⁹Ar method.Even though data statistics preclude unambiguous conclusions, ⁴⁰Ar/³⁹Ar dating of sanidine, plagioclase, biotite, and hornblende from the same sample of vitrophyric Fish Canyon Tuff supports the idea of a protracted crystallization history. Sanidine, thought to be the mineral with the lowest closure temperature, yielded the youngest age (28.04 ± 0.18 Ma at 95% c.l., using Taylor Creek Rhyolite [Renne, P.R. et al., 1998. Intercalibration of standards, absolute ages and uncertainties in ⁴⁰Ar/³⁹Ar dating. Chemical Geology, 145: 117–152.] as the fluence monitor), whereas more retentive biotite, hornblende and plagioclase gave slightly older nominal ages (by 0.2–0.3 Ma). In addition, a laser step-heating experiment on a 2-cm diameter feldspar megacryst produced a “staircase” argon release spectrum (older ages at higher laser power), suggestive of traces of inherited argon in the system. Thermal and water budgets for the Fish Canyon magma indicate that the body remained above its solidus (∼ 700 °C) for an extended period of time (> 10⁵ years). At these temperatures, argon volume diffusion is thought to be fast enough to prevent accumulation of radiogenic Ar. If this statement were true, an existing isotopic record should have been completely reset within a few hundred years, regardless of the phase and initial age of the phenocryst. As these minerals are unlikely to be xenocrysts that were incorporated within such a short time span prior to eruption, we suggest that a fraction of radiogenic Ar can be retained > 10⁵ years, even at T ∼ 700 °C.     

Structural analysis of the Baolun gold deposit,Hainan Island,South China: Implications for metallogeny

The Baolun gold deposit is a mesothermal orogenic gold deposit located in the southwestern part of Hainan Island, South China. The deposit comprises a series of NNW-trending quartz-sulfide lodes situated within a parallel array of fault zones traversing a sequence of variably foliated flysch siliciclastic rocks of the Lower Silurian. Detailed field mapping documented at least five phases of deformation in the deposit including NNW-trending folding of the Lower Silurian rocks (D1), development of NNW-trending, steeply dipping ductile shear zones with an oblique dextral sense corresponding to NNE-SSW shortening (D2), WNW-ESE shortening and extension associated with an early oblique sinistral ductile shearing along the NNW-trending fault zones (D3), ENE-WSW shortening (D4), and near N-S extension (D5). The gold-bearing quartz lodes cut the strata folded in the D1, show some laminar layering related to ductile shear in the D2 and are overprinted by brittle structures formed in the D3 to D5. ⁴⁰Ar–³⁹Ar dating on muscovite from an auriferous quartz lode yielded an age of 242 ± 2.5 Ma, which, together with the age of 232 ± 2.5 Ma for an aplite vein in the deposit, suggests that the mineralization may be related to a tectono-thermal event in the Triassic. In the context of the southern South China plate tectonics, the formation of the Baolun gold deposit is interpreted to be related to the oblique dextral ductile shearing (D2) along the NNW-trending fault zones during the Indosinian orogeny, in relation to the convergence between the Indochina and South China plates.     

The 40Ar/39Ar and Rb–Sr chronology of the Precambrian Aksu blueschists in western China

Three metapelite samples from the Aksu blueschist terrane, Xinjiang, China, were dated by the ⁴⁰Ar/³⁹Ar method on separated phengite grains, obtaining plateau ages in the range of 741−757 Ma. In contrast, the measured Rb and Sr isotope data for the three samples yielded isochron ages ranging from 630 Ma to 900 Ma, suggesting large heterogeneity in the blueschist protolith and suppression of diffusional exchange owing to the low-temperature metamorphic conditions. Because the protolith of Aksu blueschist is composed of oceanic materials that formed ⁴⁰Ar-free phengite during HP and UHP metamorphism and the apparent ⁴⁰Ar/³⁹Ar plateaus ages in this study are similar to previous K–Ar and Rb–Sr ages, the existence of excess argon in these rocks is considered to be insignificant. As a result, the ⁴⁰Ar/³⁹Ar plateau ages in this study (ca. 750 Ma) likely represent the approximate time for peak metamorphism, given the low peak metamorphic temperatures for the Aksu blueschist terrane (300−400 °C). This strongly implies that modern style, cold subduction tectonics operated along the margin of the Aksu terrane no later than 750 Ma, in Neoproterozoic time.     

Geochemical and geochronological constraints on the formation of shear-zone hosted Cu–Au–Bi–Te mineralization in the Stanos area,Chalkidiki, northern Greece

Copper–gold–bismuth–tellurium mineralization in the Stanos area, Chalkidiki Peninsula, Greece, occurs in the Proterozoic- to Silurian-aged Serbomacedonian Massif, which tectonically borders the Mesozoic Circum-Rhodope metamorphic belt to the west and crystalline rocks of the Rhodope Massif to the east. This area contains the Paliomylos, Chalkoma, and Karambogia prospects, which are spatially related to regional NW–SE trending shear zones and hosted by marble, amphibolite gneiss, metagabbro, and various muscovite–biotite–chlorite–actinolite–feldspar–quartz schists of the Silurian Vertiskos Unit. Metallic minerals occur as disseminated to massive aggregates along foliation planes and in boudinaged quartz veins. Iron-bearing sulfides (pyrite, arsenopyrite, and pyrrhotite) formed prior to a copper-bearing stage that contains chalcopyrite along with galena, sphalerite, molybdenite, and various minerals in the system Bi–Cu–Pb–Au–Ag–Te. Fluid inclusion homogenization temperatures of primary aqueous liquid–vapor inclusions in stage I quartz veins range from 170.1 °C to 349.6 °C (peak at ~ 230 °C), with salinities of 4.5 to 13.1 wt.% NaCl equiv. Calculated isochores intersect P–T conditions associated with the upper greenschist facies caused by local overpressures during late-stage tectonic movement along the shear zone in the Eocene, which produced stretching and unroofing of rocks in the region. Values of δ³⁴S for sulfides in the Stanos shear zone range from 2.42 to 10.19‰ and suggest a magmatic sulfur source with a partially reduced seawater contribution. For fluids in equilibrium with quartz, δ¹⁸O at 480 °C varies from 5.76 to 9.21‰ but does not allow for a distinction between a metamorphic and a magmatic fluid.A ¹⁸⁷Re–¹⁸⁷Os isochron of 19.2 ± 2.1 Ma for pyrite in the Paliomylos prospect overlaps ages obtained previously from intrusive rocks spatially-related to the Skouries porphyry Cu–Au, the Asimotrypes Au, and the intrusion-related Palea Kavala Bi–Te–Pb–Sb ± Au deposits in northern Greece, as well as alteration minerals in the carbonate-replacement Madem Lakkos Pb–Zn deposit. Ore-forming components of deposits in the Stanos area were likely derived from magmatic rocks at shallow depth that intruded an extensional shear environment at ~ 19 Ma.     

Chronologic implications of new Miocene mammals from the Cura-Mallín and Trapa Trapa formations,Laguna del Laja area,south central Chile

Recent work in the central Andean Main Range of Chile near Laguna del Laja (∼37.5°S, 71°W) has produced the first mammal fossils for the region. Fossils, locally abundant and well preserved, occur patchily across a wide area southeast of the lake. Mammalian remains are derived from generally strongly folded (kilometer-scale) exposures of the locally ∼1.8 km thick, early to middle Miocene Cura-Mallín Formation; two identifiable specimens have been recovered from the overlying Trapa Trapa Formation as well. Both formations consist primarily of well-stratified (1–5 m thick layers) volcaniclastic and volcanic strata, deposited predominantly in fluviatile systems. The Cura-Mallín Formation is possibly the southern continuation of (or lateral equivalent to) the richly fossiliferous Abanico Formation mapped between ∼32°S and 36°S. Intensive sampling in a series of localities east and south of Laguna del Laja has yielded diverse faunas, in addition to radioisotopically dateable horizons. The new fossil mammal faunas represent as many as six South American Land Mammal “Ages” (SALMAs). Fossils, together with preliminary ⁴⁰Ar/³⁹Ar radioisotopic dates, ranging from ∼9 to 20 Ma across the exposed thickness of the Cura-Mallín Formation and into the overlying Trapa Trapa Formation, provide a robust geochronological framework for middle Cenozoic strata in the Laguna del Laja region. The sequence of directly superposed mammalian assemblages at Laguna del Laja is one of the longest in all of South America, rivaled only by the classic Gran Barranca section of Patagonian Argentina. These data illuminate the geological history of the area and its record of mammalian evolution. The potential to isotopically date these diverse faunas with high precision (error ± 0.5 Ma) presents a rare opportunity to calibrate related portions of the SALMA sequence.     

Duration of high-pressure metamorphism and cooling during the intraplate Petermann Orogeny

The Ediacaran–Cambrian Petermann Orogeny, central Australia, is an exceptional example of intraplate orogenesis. It involved sub-eclogite facies metamorphism and extreme basin inversion during the exhumation of Musgrave Province basement from beneath the formerly contiguous Centralian Superbasin. Sensitive High Resolution Ion Microprobe (SHRIMP) U–Pb geochronology of zircon, titanite and rutile, along with Ti-in-zircon thermometry from meta-igneous samples, have been used to determine the timing and duration of high-pressure metamorphism and subsequent cooling associated with this orogenic event. Peak metamorphic temperatures of 720–760 °C were attained at 544 ± 7 Ma (U–Pb zircon). Subsequent cooling to 600–660 °C by ~ 521 Ma occurred at a rate of ~ 2.6–7.0 °C Myr^− 1, as recorded by the closure of Pb diffusion in titanite. Further cooling to 585–560 °C by 498–472 Ma occurred at a rate of 0.9–4.8 °C Myr^− 1, as recorded by Pb closure in rutile. The duration of tectonism was long-lived (> 40 Myr) across the central and western parts of the orogenic system, and deformation occurred in a comparatively warm and weak portion of crust, characterised by regional thermal gradients of 17–26 °C km^− 1. This proposed duration of tectonism is much longer than that permitted by a shear heating mechanism, which requires an exceptionally short duration of tectonism, and additionally, an overall cold lithosphere characterised by geothermal gradients of ~ 9 °C km^− 1.     

Palaeozoic polymetamorphism in the North Qinling orogenic belt,Central China: Insights from petrology and in situ titanite and zircon U–Pb geochronology

The Qinling orogenic belt experienced multiple phases of orogenesis during the Palaeozoic. Unraveling the timing and P–T conditions of these events is the key to understanding the convergence processes between the South China and the North China Blocks. The Songshugou Complex, located in the southern part of the North Qinling orogenic belt, has registered multistage metamorphism in Palaeozoic, and thus potentially provides insights into the tectonic evolution of the Qinling orogenic belt. In this study, three metabasic rocks (a garnet pyroxenite, a garnet amphibolite and a gneissic amphibolite) from the Songshugou Complex were selected for petrological study and zircon and titanite U–Pb dating. Our results show that the metabasic rocks experienced three metamorphic events during the Palaeozoic. The first metamorphic event (M1) is characterized by high pressure conditions. Two zircon grains in equilibrium with garnet and in absence of plagioclase were recognized from the garnet pyroxenite sample. They yielded Ti-in-zircon temperatures of 660–851 °C at ∼12.0 kbar and a weighted mean age of 498 ± 15 Ma, providing the constraints on the temperature and timing of prograde or peak metamorphism (M1-1). Zircons that are inequilibrium with garnet from the garnet pyroxenite and the garnet amphibolite gave U–Pb ages of 494 ± 9 Ma and 484 ± 4 Ma, and Ti-in-zircon temperatures of 793 ± 33 °C and 738 ± 18 °C, respectively. Thus, these zircons were formed on the retrograde amphibolite-facies conditions at ∼8.0 kbar (M1-2). Titanite inclusions were found in actinolite cores of zoned amphibole from the garnet amphibolite. They yielded a U–Pb age of ∼470 Ma and Zr-in-titanite temperature of 676 ± 23 °C at pressure of ∼7.0 kbar, suggesting that the amphibolite-facies retrogression perhaps persisted to ∼470 Ma.Weakly zoned zircons from the garnet amphibolite and inclusion-free titanites from the garnet pyroxenite gave consistent U–Pb ages of 418 ± 5 Ma and 423 ± 10 Ma, and Ti-in-zircon temperature of 742 ± 26 °C and Zr-in-titanite temperature of 764 ± 18 °C at ∼7.0 kbar, respectively. It is suggested that a heating event (M2) is registered by a subsequent phase of amphibolite-facies metamorphism. The ilmenite-bearing titanite crystals from the garnet pyroxenite yielded a U–Pb age of 352 ± 4 Ma, recording a late thermal event (M3).On the basis of combined petrological and geochronological results, we propose a revised tectonic model for the North Qinling orogeny in Palaeozoic. The high pressure granulites were formed by the northward subduction of the Shangdan oceanic slab and the arc-continent collision at ca. 500 Ma. Their exhumation happened at ca. 494–484 Ma as a result of slab breakoff. Subsequent amphibolite-facies metamorphism dated at ca. 440–420 Ma are coeval with the widespread magmatism in the North Qinling Terrane, which are likely caused by the reinitiation northward-subducted of Shangdan oceanic slab. At ca. 350 Ma, the North Qinling Terrane was likely affected by another thermal overprinting event.     

Rapid cooling of the Yanshan Belt,northern China: Constraints from 40Ar/39Ar thermochronology and implications for cratonic lithospheric thinning

The Yanshan Orogenic Belt is located in the northern part of the North China Craton (NCC), which lost ∼120 km of lithospheric mantle during Phanerozoic tectonic reactivation. Mesozoic magmatism in the Yanshan fold-and-thrust belt began at 195–185 Ma (Early Jurassic), with most of the granitic plutons being Cretaceous in age (138–113 Ma). Along with this magmatism, multi-phase deformational structures, including multiple generations of folds, thrust and reverse faults, extensional faults, and strike-slip faults are present in this belt. Previous investigations have mostly focused on geochemical and isotopic studies of these magmatic rocks, but not on the thermal history of the Mesozoic plutons. We have applied ⁴⁰Ar/³⁹Ar thermochronology to biotites and K-feldspars from several Lower Cretaceous granitic plutons to decipher the cooling and uplift history of the Yanshan region. The biotite ⁴⁰Ar/³⁹Ar ages of these plutons range from 107 to 123 Ma, indicating that they cooled through about 350 °C at that time. All the K-feldspar step-heating results modeled using multiple diffusion domain theory yield similarly rapid cooling trends, although beginning at different times. Two rapid cooling phases have been identified at ca. 120–105 and 100–90 Ma. The first phase of rapid cooling occurred synchronously with widespread extensional deformation characterized by the formation of metamorphic core complexes, A-type magmatism, large-scale normal faults, and the development of half-graben basins. This suggests rapid exhumation took place in an extensional regime and was a shallow-crustal-level response to lithospheric thinning of the NCC. The second phase of rapid cooling was probably related to the regional uplift and unroofing of the Yanshan Belt, which is consistent with the lack of Upper Cretaceous sediments in most of the Yanshan region.     

Magma mixing and gold mineralization in the Maevatanana gold deposit,Madagascar

The Maevatanana gold deposit in Madagascar is hosted by Archean metamorphic rocks in quartz–sulfide veins that are structurally controlled by NNW–SSE trending shear zones. Fluid inclusion data show that the trapping conditions in quartz range from 0.87 to 2.58 kbar at temperatures of 269–362 °C. Laser Raman spectroscopy confirms that these inclusions consist of CO₂, SO₂, and H₂O. The δ³⁴S values of the pyrites range from 1.7‰ to 3.6‰, with an average of 2.25‰, supporting a magmatic origin. Noble gases (He, Ne, Ar, Ke, Xe) are chemically inert, thus will not be involved in chemical reactions during geological processes. Also due to the low concentration of He in the atmosphere and the low solubility of He in aqueous fluids, the atmosphere-derived He is unlikely to significantly affect He abundances and isotopic ratios of crustal fluids, ensures that He production should have the typical crust ³He/⁴He ratios. The ³He/⁴He ratios of fluid inclusions in pyrite from the deposit range from 0.06 to 0.12 Ra, while the ⁴⁰Ar/³⁶Ar ratios range from 6631 to 11441. We infer that the ore-forming fluids could have been exsolved from a granitic magma. The oxygen and hydrogen isotope compositions of the ore-forming fluids (1.5‰ ≤ δ¹⁸O_H2O ≤ 7.8‰; –72‰ ≤ δD ≤ –117‰) indicate they were derived from a granitic magma. Four pyrite samples from the gold deposit yield a precise Re–Os isochron age of 534 ± 13 Ma. Given that the post-collisional granites in northern and central Madagascar were derived by melting of sub-continental lithospheric mantle and formed between 537 and 522 Ma, we can state that the gold metallogenesis was coeval with the crystallization age of these parental magmas. These data could be accounted for the formation of the Maevatanana gold deposit. First, the shear zones hosting the deposit formed around 2.5 Ga, when the Madagascan micro-continental blocks collided with other continental blocks, triggering large-scale tectono-magmatic activity and forming NNW–SSE trending shear zones. The gold mineralization at Maevatanana is coeval with the crystallization age of the Cambrian post-collisional A-type granitoid plutons in northern and central Madagascar, implying that this deposit is associated with extensional collapse of the East African Orogen. This extension in turn induced asthenospheric upwelling, melting of sub-continental lithospheric mantle. These magmas underplated the lower crust, generating voluminous granitic magmas by partial melting of the lower crust. The mixing magma during tectono-thermal reactivation of the East African Orogen produced large volumes of volatiles that extracted gold from the granitic magma and produced Au–S complexes (e.g., Au(HSO₃)²⁻). The shear zones, which were then placed under extensional collapse of the East African Orogen in the Cambrian, formed favorable pathways for the magmatic ore-forming fluids. These fluids then precipitated gold-sulfides that form the Maevatanana gold deposit.     

Mineral assemblages,fluid evolution,and genesis of polymetallic epithermal veins,Glojeh district,NW Iran

The Glojeh district contains silver- and base metal-rich epithermal veins and is one of the most highly mineralized locations in the Tarom-Hashtjin metallogenic province, northwestern Iran. It consists of four major epithermal veins, which are located in the South Glojeh and North Glojeh areas. Alteration in the Glojeh district consists of propylitic, sericitic, and argillic assemblages, as well as extensive silicification. The ore-bearing veins comprise three paragenetic stages: (1) early Cu-Au-As-Sb-Fe-bearing minerals, (2) middle stage Pb-Zn-Cu-Cd-Ag-bearing minerals, and (3) late hematite-Ag-Bi-Au-Pb mineralogy. The veins are best classified as the product of an early high-sulfidation hydrothermal system, which was overprinted by an intermediate sulfidation system that was rich in Ag and base metals. Hematite is locally altered to goethite in zones of as much as 40 m in width during supergene alteration and the goethite is an important exploration tool. Fluid inclusions from the early, middle, and late stages, respectively, have salinities and homogenizations temperatures ranging from 5 to 11 wt.% NaCl eq. and 220 °C to 340 °C, to 1 to 8 wt.% NaCl eq. and 200 °C to 290 °C and finally to. 0.1 to 2 wt.% NaCl eq. and 150 °C to 200 °C. The oxygen isotope values in quartz range from 8.8 to 13.3‰ and most calculated fluid δ¹⁸O values are between 4 and 8‰, suggesting a magmatic fluid with some meteoric water contamination. Sulfur isotope values for chalcopyrite, pyrite, sphalerite, and galena are mainly − 7.3 to + 1.3‰ and − 0.3 to + 8.4‰ for North Glojeh and South Glojeh, respectively. Sulfur isotope data suggest a magmatic origin. Boiling, isothermal mixing, and dilution are the main mechanisms for ore deposition in the Glojeh veins. Recent ⁴⁰Ar/³⁹Ar age measurements of 42.20 ± 0.34 Ma and 42.56 ± 1.47 Ma for the North Glojeh and South Glojeh veins, respectively, overlap with the 41.87 ± 1.58 Ma age of the Goljin intrusion in the northern part of the district, which we interpret as the main heat source controlling the hydrothermal systems.     

Late Cenozoic fluvial dynamics of the River Tana,Kenya, an uplift dominated record

The Late Cenozoic development of the River Tana in Kenya has been reconstructed for its central reach near its confluence with the River Mutonga, which drains the Mount Kenya region. Age control for this system has been provided by K–Ar and Ar–Ar dating. Between 3.21 and 2.65 Ma a major updoming occurred, in relation to the formation of the Kenyan rift valley. The tilting related to this doming has been reconstructed from lava flows that preserve former river gradients. Linear projection of these trends to the current rift valley rim suggests a net updoming of the eastern Gregory Rift valley by at least ∼1 km during 3.21–2.65 Ma. In contrast, since 2.65 Ma the Tana system has been mainly subject to relatively minor epeirogenic uplift. Changing climatic conditions combined with continuing uplift yielded a typical staircase of strath terraces with at least 10 distinct levels. A more detailed reconstruction of the incision rates since 215 ka has been made, by correlating mineralogically fingerprinted volcaniclastic Tana deposits with dated tephras in a lake record. These volcaniclastic sediments were deposited during glacial periods, contemporaneous with lahars. The reconstructed incision rates for the three youngest terraces are ∼0.1–0.2 mm a⁻¹, thus considerably faster than the overall average rate of valley incision since the Mid-Pliocene, of 0.06 mm a⁻¹. A plausible uplift history has been reconstructed using the estimated ages of the Tana terraces and marine terraces on the Indian Ocean coastline. The result suggests an increase in the rate of incision by the River Tana at ∼0.9 Ma, an observation typical in most European river terrace staircases. The reconstructed Late Quaternary development of Tana valley indicates that a similar Quaternary uplift mechanism has operated in both Europe and East Kenya, suggesting a globally applicable process.     

Age and origin of uranium mineralization in the Camie River deposit (Otish Basin,Québec,Canada)

The Camie River uranium deposit is located in the southeastern part of the Paleoproterozoic Otish Basin (Québec). The uranium mineralization consists of disseminated and vein uraninite and brannerite precipitated close to the unconformity between Paleoproterozoic fluviatile, pervasively altered, sandstones and conglomerates of the Matoush Formation and the underlying sulfide-bearing graphitic schists of the Archean Hippocampe greenstone belt. Diagenetic orange/pink feldspathic alteration of the Matoush Formation consists of authigenic albite cement partly replaced by later orthoclase cement, with the Na₂O content of clastic rocks increasing with depth. Basin-wide green muscovite alteration affected both the Matoush Formation and the top of the basement Tichegami Group. Uraninite with minor brannerite is mainly hosted by subvertical reverse faults in basement graphitic metapelites ± sulfides and overlying sandstones and conglomerates. Uranium mineralization is associated with chlorite veins and alteration with temperatures near 320 °C, that are paragenetically late relative to the diagenetic feldspathic and muscovite alterations. Re-Os geochronology of molybdenite intergrown with uraninite yields an age of 1724.0 ± 4.9 Ma, whereas uraninite yields an identical, although slightly discordant, 1724 ± 29 Ma SIMS U-Pb age. Uraninite has high concentrations in REE with flat REE spectra resembling those of uraninite formed from metamorphic fluids, rather than the bell-shaped patterns typical of unconformity-related uraninite. Paragenesis and geochronology therefore show that the uranium mineralization formed approximately 440 million years after intrusion of the Otish Gabbro dykes and sills at ∼2176 Ma, which constrains the minimum age for the sedimentary host rocks. The post-diagenetic stage of uraninite after feldspathic and muscovite alterations, the paragenetic sequence and the brannerite-uraninite assemblage, the relatively high temperature for the mineralizing event (∼320 °C) following the diagenetic Na- and K-dominated alteration, lack of evidence for brines typical of unconformity-related U deposits, the older age of the Otish Basin compared to worldwide basins hosting unconformity-related uranium deposits, the large age difference between basin fill and mineralization, the older age of the uranium oxide compared to ages for worldwide unconformity-related U deposits, and the flat REE spectra of uraninite do not support the previous interpretation that the Camie River deposit is an unconformity-associated uranium deposit. Rather, the evidence is more consistent with a PaleoProterozoic, higher-temperature hydrothermal event at 1724 Ma, whose origin remains speculative.