On the origin of eucrites and diogenites

Eleven eucrites have been analysed for major, minor and some trace (K, Sr, Zr, Y, Ba and Ni) constituents. These data are interpreted in terms of an igneous fractionation model according to which the observed enrichment trends of various elements in eucrite liquids are considered to be indicative of the simultaneous fractionation of plagioclase and pyroxene. Serra de Magéand Moore County are representatives of the cumulates thus formed. The achondrite Binda, a monomict breccia of howarditic composition, is interpreted as a possible precursor to the eucrite liquids. The derivation of a parent eucrite liquid from material of this composition could have occurred by fractionation of orthopyroxene. Diogenites are considered to represent the orthopyroxenites thus formed. The original liquid from which Binda and the eucrites were derived must, in terms of this model, have been more mafic than Binda.     

Magnetic anisotropy of HED and Martian meteorites and implications for the crust of Vesta and Mars

We investigate the petrofabric of crustal rocks from Mars and Vesta through the measurement of the anisotropy of the magnetic susceptibility (AMS) of achondrites. Previous data are integrated with new measurements to obtain a dataset that provide macroscopic information about the magnetic fabric of 41 meteorites of the howardite–eucrite–diogenite clan (HED, falls only) and 16 Martian meteorites. The interpretation takes into account the large contribution of paramagnetism to the magnetic susceptibility of these meteorites. We use a model that allows the computation of the anisotropy degree of the population of ferromagnetic grains and provides a quantitative proxy for the degree of shape preferential orientation of these grains in HED and Martian meteorites. The results also provide quantitative information about the shape of the magnetic fabric (prolate, oblate).In HED achondrites, the ductile FeNi grains are sensitive strain recorders and our magnetic fabric data provide the first quantitative insights to the strain history of the crustal rocks of Vesta. Most HED achondrites are breccias but display a strong and spatially coherent magnetic anisotropy, indicating that intense deformation of FeNi grains took place after brecciation. The average fabric of eucrites, howardites is oblate (i.e. the texture is foliated) whereas the fabric of diogenites is more neutral. The howardite results suggest the existence of an isotropic fraction of ferromagnetic minerals that can be ascribed to the presence of carbonaceous chondrite clasts that have preserved their original magnetic fabric. In this hypothesis, howardites have an intensity of petrofabric very similar to eucrites and diogenites. Thermal metamorphism (itself possibly impact-related) plus lithostatic compaction occurring after brecciation appears as the best candidate to explain the observed petrofabric in eucrites and diogenites, whereas compaction by hypervelocity impacts may be reponsible for the fabric of howardites.Martian meteorites may still possess their primary magmatic fabric. Among Martian meteorites, basaltic shergottites and nakhlites display an oblate fabric (foliated texture) with only limited variations among each group. Olivine–phyric shergottites have a neutral fabric that points to a different petrogenesis. Nakhlites have weaker fabric intensity than shergottites. The fabric intensity is comparable to what is classically observed in terrestrial volcanic and plutonic rocks.     

Sweet chestnut (Castanea sativa) leaves as a bio-indicator of volcanic gas,aerosol and ash deposition onto the flanks of Mt Etna in 2005–2007

Sweet chestnut leaves (Castanea sativa) collected from the flanks of Mt Etna volcano in 2005–2007 were analysed by inductively-coupled plasma mass spectrometry to investigate the spatial and temporal variability of element concentrations. The aim of this work was to determine whether these leaves are a bio-indicator for volcanic gas, aerosol and ash deposition and to gain new insights into the environmental effects of quiescent and eruptive volcanic plumes. Results show a positive correlation between sample variability in the concentration of elements in Castanea sativa and enrichment factors of elements in the plume. The spatial and temporal variability of chalcophilic elements (As, Cd, Cu, Mo, Tl, Zn) is consistent with prevailing winds transporting eruptive plumes to the south-east of the summit, resulting in enhanced plume deposition onto the flanks of the volcano. Similar spatial and temporal variability was found for the halide-forming elements (Cs, K, Rb) and intermediate elements (Al, Co, Mn). The spatial variability of chalcophilic, intermediate and halide-forming elements during quiescent periods was diminished (relative to eruptive periods) and could not be explained by plume deposition. In contrast, the concentrations of lithophilic elements (Ba, Ca, Mg, Sr) did not show any clear spatial variability even during eruptive periods. Comparisons between enrichment factors for elements in Castanea sativa and literature values for enrichment factors of the volcanic plume, groundwater and lichen were made. Whilst Castanea sativa offers insights into the spatial and temporal variability of deposition, the species may not be a bio-indicator for plume composition due to biological fractionation.     

黄山茶叶品质与产地地质背景关系探讨

本文通过对黄山茶叶的实地调查,从地学角度分析了黄山茶叶的地质背景对土壤中元素组合、土壤类型的影响,探讨了茶叶主要品质与产地地质背景的关系,分析了茶叶优异的品质与地质背景条件的相关性。确定出黄山毛峰生长的土壤是在特定的青白口纪邓家组变石英砂岩、变粉砂岩、板岩风化而成的粗骨土,太平猴魁是在特定志留纪康山组长石石英砂岩、粉砂岩、泥岩风化而成红壤土、粗骨土,这些土壤为茶树生长提供了大量的营养物质,特别是有益的微量元素对提高茶叶品质起到了重要作用。     

40Ar-39Ar chronology of isolated phases from Bununu and Malvern howardites

High resolution⁴⁰Ar-³⁹Ar age spectra have been measured on plagioclase and glass from two howardites. Both the plagioclase and glass from the gas-rich Bununu howardite show well-defined age plateaux, yielding distinct ages of 4.42 ± 0.04 and 4.24 ± 0.05 AE, respectively. These age patterns are rather well behaved and are interpreted as representing the distinct times of formation of plagioclase from igneous processes and of glass fragments produced by impact on the meteorite body. The release pattern for the glass from the heavily shocked Malvern howardite is undulating at low and intermediate temperatures but does have a high-temperature plateau. Its age spectrum indicates little apparent diffusion loss, but rather an extensive redistribution of either⁴⁰Ar during the shock event or of³⁹Ar during the neutron irradiation or both. The total K-Ar age of Malvern glass is 3.64 ± 0.04 AE and the high-temperature plateau is 3.73 ± 0.05 AE. The age spectrum of the Malvern plagioclase has an intermediate temperature “plateau” at 3.80 AE that represents 20% of the total⁴⁰Ar content and increases towards a high-temperature plateau at 4.29 ± 0.04 AE containing 26% of the total gas release. It seems likely that the event which formed the Malvern glass also reset part of the plagioclase. The distinct histories observed for the different phases of these howardites are consistent with their formation from a regolith. The present results along with similar young ages for igneous clasts from Kapoeta clearly show that the regoliths were extant on the parent bodies of howardites and that they were subjected to violent impact events at least as recently as 3.7 AE ago.     

Etude géochimique des éléments condensés au cours du réfroidissement de la phase gazeuse volcanique: Etna 1976

On Mount Etna, in June 1976, sublimates were collected on the wall of a silicatube. Temperatures of deposition were recorded along the tube and the atomic composition has been analysed by neutronic activation. It is possible with this technique to know the temperature of condensation or sublimation for the different elements. These results should help to better understand the magma/gas relationship.     

The influence of roughness geometry and Shields parameter on flow resistance in gravel-bed channels

The spatial variability of bed particles of a gravel-bed channel is analysed and treated experimentally in order to simulate the effects of the arrangement of coarse bed elements on the flow resistance law. For the studied bed patterns, characterized by the concentration Γ of coarser elements arranged on the bed layer, a particle arrangement parameter α is proposed. The α parameter is useful for estimating the intercept b₀ of the semi-logarithmic flow resistance law deduced by flume measurements carried out for the hydraulic condition of large-scale and transition roughness. The differences between the experimental friction factor parameter values and the ones calculated by the proposed semi-logarithmic relationship are explained by the ratio between the Shields parameter and its critical value. The analysis shows that estimates of the friction factor parameter are not improved by introducing the Froude number into the flow resistance law. © 1997 by John Wiley & Sons, Ltd.     

The petrochemistry and significance of jogimardi traps,chitaldrug schist belt,Mysore

Forty-two samples of the Jogimardi trap from Chitaldrug schist belt, Mysore, were analysed for their major elements. It is inferred that the Jogimardi trap is a submarine lava flow of eugeosynclinal environment. The composition of the suite varies from tholeiitic basalt to andesite and spilite. The original magma, which was probably tholeiitic in nature, might have given rise to this association due to varying and incomplete degree of spilitisation, which in turn seems to be related to the short period of contact between metasomatic liquid and the tholeiitic flows. The suite bears the imprint of low grade metamorphism of green schist facies. This resulted in the development of mineral assemblage comprising chlorite, epidote and plagioclase but without bringing about any change in the original basaltic texture. At and near the contact with granite, the tholeiitic lava was converted into orthoamphibolite, most probably due to granitie intrusion.     

An approach to the intercalibration of benthic ecological status assessment in the North Atlantic ecoregion, according to the European Water Framework Directive

The European Water Framework Directive (WFD) establishes a framework for the protection and improvement of transitional and coastal waters; its final objective is to achieve at least 'good water status' for all waters, by 2015. The WFD requires Member States (MSs) to assess the Ecological Status (ES) of water bodies. This assessment will be based upon the status of the biological, hydromorphological and physico-chemical quality elements, by comparing data obtained from monitoring networks to reference (undisturbed) conditions, and then deriving an Ecological Quality Ratio (EQR). One of the biological quality elements to be considered is the benthic invertebrate component and some structural parameters (composition, diversity and disturbance-sensitive taxa) must be included in the ES assessment. Following these criteria, several approaches to benthic invertebrate assessment have been proposed by MSs. The WFD requires that these approaches are intercalibrated. This contribution describes the comparison of the different methodologies proposed by United Kingdom, Spain, Denmark and Norway. Results show a high consistency between the approaches, both with regard to determining the EQR and boundary settings for the ES.     

AN OPTIMIZED PROCEDURE FOR SEISMIC DESIGN OF TORSIONALLY UNBALANCED STRUCTURES

This paper develops an optimized procedure for the design of torsionally unbalanced structures subjected to earthquake loading, considering both the serviceability and the ultimate limit states. An optimal design eccentricity expression, in the form of design charts, and an optimal overstrength factor equation, are proposed. Results show that the recommended design procedure can result in nearly equal performance of both the rigid edge and the flexible edge elements. For a wide combination of primary system parameters, the responses of both edge elements are consistently lower than, or in the neighbourhood of, the response of the corresponding torsionally balanced reference model. The proposed procedure retains simplicity and can be easily implemented (with certain limitations) in design practice. It also has the added advantages of requiring the structure to be analysed only once for each limit state in each principal direction (as opposed to twice, in existing code torsional provisions), and results in a significantly lower overstrength factor, compared with the overstrength factors corresponding to the torsional provisions of seismic codes in the United States and Canada. The proposed procedure is also applicable to torsionally unbalanced structures with and without transverse resisting elements. © 1997 John Wiley & Sons, Ltd.     

On the chemical composition of the Moon,Jupiter, meteorites and Am stars

If surface anomalies in the composition of the metallic-line A stars (Am stars) are due to a precipitation of planet-like bodies (planetoids) on them, then one should expect a correlation to exist between the overabundance of heavier-than-iron elements on these stars and their “standard” abundances in the solar system (since chondrites provide the “standard” level for these elements). However, an anticorrelation was revealed.Nevertheless, this fact supports the original suggestion on the origin of the metallicism of A stars, and can easily be explained within the author's hypothesis on the formation of the Sun from matter escaping from the proto-Jupiter. During the terminal stages of mass transfer, the matter was strongly depleted in refractories (forming the rocky core of Jupiter). Therefore the composition of the meteorites formed should not coincide with the primary composition of the matter. Thus the Sun's outer layers may also have a distorted composition. The author concludes that it is desirable to revise the “standard” abundances of elements heavier than iron.From a comparison of the surface composition of Am stars with the composition of lunar anorthosites and that of rocks in the upper zones of the Skaergaard intrusion (Greenland), the Am phenomenon may be seen to result from a precipitation of large geochemically differentiated planetoids onto a star. Such planetoids (including the Moon) condense in the cooled envelope of the primary component of a close binary stellar system.     

Feasibility of signal enhancement with multiple grounded‐wire sources for a frequency‐domain electromagnetic survey

Frequency‐domain electromagnetic methods with a grounded‐wire source are powerful tools in geophysical exploration. However, the signal may be too weak to guarantee the quality of survey data in complex electromagnetic environments, especially when the receiver is located in the air for the newly developed grounded‐source airborne frequency‐domain electromagnetic method. In this paper, a signal enhancement method with multiple sources is proposed to solve this problem. To evaluate the signal enhancement effect, we compared the signals generated by a single source and multiple sources with equal electric moment. The signal differences caused by synchronisation error and separation distance between source elements were analysed, and the methods to achieve maximum signal were introduced. Besides, we discussed the interaction between adjacent source elements to ensure the system safety, including the changes in output current and the safe distance between two sources using a dual‐source model. Lastly, a comprehensive field experiment was designed and conducted to test the multiple‐source method. The data processing results are comparable for single and dual sources, and the signal‐to‐noise ratio of dual source is higher in the field test. The subsurface resistivity structure at the test site is consistent with the previous controlled‐source audio‐frequency magnetotellurics method. These results show that signal enhancement with multiple sources is feasible. This study provides guidance to the application of multiple sources in field surveys when the survey environment is complex and rigorous.     

Siderophile element fractionation in enstatite chondrites

The concentration of 10 to 15 siderophile elements was determined in the magnetic and non-magnetic portions of Abee (E4) and Hvittis (E6). The results indicate that, with the exception of Cu, W and Fe, all elements are strongly concentrated in the metal phase. Unlike ordinary chondrites, the metal phase of Abee and Hvittis consists exclusively of kamacite, which is very homogeneous and shows no systematic variation in composition with grain size.Differences in siderophile element content between Abee and Hvittis can be accounted for exclusively by differences in metal content and composition. These differences reflect different degrees of refractory siderophile loss, metal-silicate fractionation and loss of moderately volatile elements. The Ir/Ni ratio is 25% lower in Abee than in Hvittis, indicating that more Ir (Os, Pt, etc.) was lost from Abee during the refractory element fractionation. Abee and the other E4–5 members have also lost no metal and are not depleted in moderately volatile elements. In Abee the non-refractory elements Fe to Ge are present in CI ratios, and this meteorite has also Ir/Re ratios ?CI.These differences, which are recorded in the composition of the metal phase, make a straightforward genetic relationship between the two enstatite chondrite groups difficult to accept. In particular, the different Ir/Ni ratios, which were established very early in the chemical history of these chondrites, at the time of the refractory element fractionation, force us to conclude that E4–5 and E6 chondrites evolved from two different reservoirs, and that exchange of material among them never occurred. However, members of both groups have similar cosmic ray exposure ages suggesting derivation from the same parent body, which poses some interesting problems.     

Effects of hydrological processes on the chemical composition of riverine suspended sediment in the Zhujiang River,China

The chemical composition of riverine suspended sediment is the integration of the weathering crust minerals, soil organic matter and erosion agency within a specific drainage basin, which has been largely disturbed by the human activities. Selected metal elements of the riverine suspended sediment in the Zhujiang River were analysed using inductively coupled plasma–atomic emission spectrometry (ICP–AES) in three different hydrological phases from 1997 to 1998 at Makou and Sanshui hydrographic gauge stations, located at the lower reaches of the two main tributaries of the Zhujiang River, i.e. the Xijiang and the Beijing Rivers respectively. Organic carbon and nitrogen were also analysed using a conventional element analyser. The results demonstrate that the chemical composition of the riverine suspended sediment show obvious variability in different hydrological phases, which closely correlate to the organic matter content in suspended sediment. Intensified erosion in the flood phase results in lower concentration of the organic matter than that in the lower water level phase. The riverine suspended sediment with rich organic matter in the lower water level phase adsorbs some metal elements from the river water. Copyright © 2003 John Wiley & Sons, Ltd.     

Fish bile as a biomarker for metal exposure

Fish accumulate several trace elements in muscle, gills and liver, however studies also indicate that metals can be excreted through bile. Since metal contamination leads to modifications in bile composition, biliary excretion offers an alternative way to evaluate the presence of trace-elements. Bile is easier to obtain than other organs and presents a simpler matrix, making it easier for chemical pre-treatment. To verify if bile can be useful as a biomonitoring tool for metal contamination, liver and bile trace element concentrations were determined and correlated. The Artificial Neural Networks statistical technique was used to verify if liver trace-element quantification could be substituted by bile analysis. Results show that significant correlations were obtained between trace elements in bile and liver and the ANN validated the hypothesis that certain trace-elements in bile could be utilized instead of liver trace-elements. Further studies in this field are of interest to further validate this biomarker.     

Evolution of metal pollution in the golden horn (Turkey) sediments between 1912 and 1987.

The Golden Horn is a heavily polluted water body in a large metropolitan area with a population of approximately 10 million. A 3-m long undisturbed core sample was collected in the Golden Horn, from research vessel RV Knorr, during the third leg of the joint Turkish--American Black Sea expedition in 1989. The core was sliced and dated using the 210Pb isotope technique. The bottom of the core corresponds to the year 1912. Each slice was analysed for major, minor and trace elements by inductively coupled plasma emission spectrometry (ICP). The masses of the measured elements can account for approximately half of the sediment mass. The lithophilic elements Li, K, Rb, Mg, Ca, Ba, Al, La, Ti, V, Mn, Fe, Co and Ni account for more than 90% of the elemental mass and do not show any change in their concentrations between 1912 and 1987. Although anthropogenic elements Mo, Zn, Cr, Cu, Ag, and Cd account for a minute fraction of the elemental mass, their concentrations increase along the core, signifying human influence on chemical composition of the Golden Horn Sediments. Lead was enriched at the bottom of the core suggesting pollution of Golden Horn sediments by this element even at the beginning of the century, but observed concentrations of the remaining anthropogenic elements, at the bottom of the core, can be explained by sedimentary material. Concentrations of pollution-derived elements do not change significantly between 1912 and 1950, but their concentrations increase sharply in the second half of the century. A factor analysis applied to the data set has shown that the inorganic fraction of the Golden Horn sediments includes crustal, marine and two anthropogenic components. One of the anthropogenic components is attributed to the discharges from an iron and steel plant. The second anthropogenic component, which accounted for a larger fraction of system variance, is due to discharges from industries, particularly metalwork plants.     

Katla volcano,Iceland: magma composition,dynamics and eruption frequency as recorded by Holocene tephra layers

The Katla volcano in Iceland is characterized by subglacial explosive eruptions of Fe–Ti basalt composition. Although the nature and products of historical Katla eruptions (i.e. over the last 1,100 years) at the volcano is well-documented, the long term evolution of Katla’s volcanic activity and magma production is less well known. A study of the tephra stratigraphy from a composite soil section to the east of the volcano has been undertaken with emphasis on the prehistoric deposits. The section records ∼8,400 years of explosive activity at Katla volcano and includes 208 tephra layers of which 126 samples were analysed for major-element composition. The age of individual Katla layers was calculated using soil accumulation rates (SAR) derived from soil thicknesses between ¹⁴C-dated marker tephra layers. Temporal variations in major-element compositions of the basaltic tephra divide the ∼8,400-year record into eight intervals with durations of 510–1,750 years. Concentrations of incompatible elements (e.g. K₂O) in individual intervals reveal changes that are characterized as constant, irregular, and increasing. These variations in incompatible elements correlate with changes in other major-element concentrations and suggest that the magmatic evolution of the basalts beneath Katla is primarily controlled by fractional crystallisation. In addition, binary mixing between a basaltic component and a silicic melt is inferred for several tephra layers of intermediate composition. Small to moderate eruptions of silicic tephra (SILK) occur throughout the Holocene. However, these events do not appear to exhibit strong influence on the magmatic evolution of the basalts. Nevertheless, peaks in the frequency of basaltic and silicic eruptions are contemporaneous. The observed pattern of change in tephra composition within individual time intervals suggests different conditions in the plumbing system beneath Katla volcano. At present, the cause of change of the magma plumbing system is not clear, but might be related to eruptions of eight known Holocene lavas around the volcano. Two cycles are observed throughout the Holocene, each involving three stages of plumbing system evolution. A cycle begins with an interval characterized by simple plumbing system, as indicated by uniform major element compositions. This is followed by an interval of sill and dyke system, as depicted by irregular temporal variations in major element compositions. This stage eventually leads to a formation of a magma chamber, represented by an interval with increasing concentrations of incompatible elements with time. The eruption frequency within the cycle increases from the stage of a simple plumbing system to the sill and dyke complex stage and then drops again during magma chamber stage. In accordance with this model, Katla volcano is at present in the first interval (i.e. simple plumbing system) of the third cycle because the activity in historical time has been characterized by uniform magma composition and relatively low eruption frequency.     

Variations in Cr content of magnetite from the upper zone of the Bushveld Complex — evidence for heterogeneity and convection currents in magma chambers

Mineral separates of pure magnetite from the upper zone of the Bushveld Complex have been analysed for Cr. Detailed sampling within layers of massive magnetite indicates that the Cr content frequently shows an extremely rapid but regular depletion with height (for example, by a factor of seven over 85 cm of massive magnetite), with sudden reversals of variable magnitude. Rayleigh Law fractionation, from a homogeneous liquid of the volume now seen as cumulate rocks overlying the sampled horizons, cannot satisfy these observed concentration gradients. A diffusion-controlled crystallization model is preferred. In another vertical section of massive magnetite the Cr content remains constant with increasing height, and is interpreted as indicating a steady state situation where the rate of depletion of Cr by magnetite fractionation is balanced by the rate of diffusive addition into the crystallization zone. Reversals in Cr content sometimes occur in the middle of pure magnetite layers and are attributed to convective overturn in the magma chamber. These results provide geochemical support for the model of convection cells and bottom crystallization in large magma reservoirs as proposed by Jackson [20]. Depletion of compatible elements in this bottom layer causes chemical inhomogeneity in the magma.Sections, composed of several layers of magnetite sandwiched between magnetite-bearing gabbro, have also been studied. In one case, a steady decrease in Cr content with increasing height in the separated magnetite was observed; in another, several irregular reversals were found. There appears to be no systematic relation between convection cycles, the depletion in Cr and the formation of pure magnetite layers, indicating that the chemical composition of the magma does not control the production of monomineralic layers. The fluctuating pressure model envisaged by Cameron [16] for the formation of such layers is entirely consistent with these data.     

Thermochemical convection in the mantle with oceanic crust recirculation

Basalts of mid-ocean ridges are depleted in incompatible elements that have passed into the continental crust. Basalts of hot spots (oceanic islands and igneous provinces) have a chemical composition close to the primary uniform mantle and are even somewhat enriched in incompatible elements. At present, for explaining the reason for this difference, there are different qualitative schemes of differentiation and mixing of substance in the mantle. In the present work, the results of numerical modeling of the two-component thermochemical convection in the mantle are given. They quantitatively demonstrate with which parameters in the mantle the layers of different chemical composition can remain unchanged. Models with different density contrasts and with variable viscosity are examined. The times of the partial mixing of layers depending on the values of these parameters are calculated. For retaining the stratified mantle for two Ga, the density contrast must be more than 2%. If the layer D″ contains a substance of the primary composition, then, its upper boundary can be the place of origin of the plumes that feed the hot spots of the Earth. The enrichment in the incompatible elements and the variety of the chemical composition of hot spots can be explained by the mixing of the substance of the slowly eroded D″ layer and the oceanic crust accumulated in it.     

Geochemical features of rare-earth elements in surface and subsurface waters in the field of the Albynskoe Gold-Bearing Placer,Amur oblast

The distribution and fractionation of rare-earth elements (REE) are studied in the surface and subsurface waters and rocks of the Albynskoe Gold-Bearing Placer. The obtained data show the rocks of the placer to be enriched with rare-earth elements and to feature the predominance of light lanthanides over heavy ones. Groundwater show an equality between the groups of light and heavy lanthanides, while in the surface waters the concentration of light REE is much higher than that of heavy ones, thus reflecting the composition of the drained ore rocks. The leaching of rare-earth elements from rocks by atmospheric water is intensified by agents produced by microorganisms in their vital activity.