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1.
At the Midway, Utah, USA fish hatchery, a groundwater development program was conducted to help transition the facility from surface to groundwater in response to contamination by whirling disease, which is caused by a trout parasite. The unconfined aquifer system that provided the hatchery water became infected through the recharge of infected irrigation water obtained from the Provo River. Whirling disease was first discovered in Utah in 1991 at a private fish farm. Infected fish from the farm quickly infected many of Utah’s waterways and infected the hatchery in 2000. Because the parasite completes its life cycle in multiple organisms and can survive for decades in a variety of harsh environments, a comprehensive study of the hydrostratigraphy and hydrodynamics at the hatchery was critical in order to understand the hazard and avoid further contamination. Drilling revealed the presence of a shallow unconfined (surface to 10 m) and two deeper confined aquifer systems (~20–35 m and >40 m bgs). Confinement is related to tufa layers, detected both by drilling and reflection seismology. The tufa layers are associated with past discharge of the thermal system. Vertical leakage is apparent from upward hydraulic head gradients and incrementally increasing unconfined aquifer discharge into downstream on-site drainage canals. High-resolution seismic profiles reveal small-offset faults that provide pathways for upward flow. Analysis of water quality data demonstrates an inverted geochemical gradient in that apparent 14C ages, solute concentrations, and temperatures decrease with depth. The origin of the inverted geochemical gradient is related to mixing of upwelling thermal, high-TDS waters with cold, low-TDS systems several kilometers up-gradient from the hatchery. Thermal upwelling appears to be fault controlled. Up-gradient of the hatchery, near-surface groundwater mixes with a larger proportion of thermal groundwater than does deeper groundwater. As these mixed systems flow toward the hatchery, a major locus of groundwater discharge, they are segregated into confined and unconfined compartments. Our study requires integration of hydrological, geochemical, and geophysical strategies in order to understand a complex natural hazard and thus may serve as a model for other similarly complex hydrological environments.  相似文献   

2.
重庆金佛山泉水地球化学特征及其空间分布意义   总被引:2,自引:1,他引:1       下载免费PDF全文
2006年7月和9月在重庆金佛山地区选取22个地下水出露的泉点.对泉水的地球化学性质进行详细调查。利用野外和实验室测量手段得到了主要阴离子和阳离子浓度与物理化学参数。分析得知:研究区泉水的水化学类型为Ca-HCO_3和Ca、Mg-HCO_3;结合地质和地貌背景把它们分为6个泉群,分别讨论各泉群的空间分布意义;估算泉水方解石(SI_C)、白云石(SI_D)和石膏(SI_G)的饱和指数,即可反映地层岩性、地形和地下水的运移时间对水质的影响,该区地下水基本上是来自大气降水的下渗.没有深部含水层的上升混合.这些泉水的地球化学特征以及它们的空间分布规律能够很好地反映区内地质状况.该研究可以为金佛山地区地下水资源的调查和环境保护提供基础数据。  相似文献   

3.
The systematic sampling of the chemical composition of the groundwater from five karst springs (including an overflow spring) and one outflowing borehole have permitted to determine distinctive chemical changes in the waters that reflect the geochemical processes occurring in a carbonate aquifer system from southern Spain. The analysis of the dissolution parameters revealed that geochemical evolution of the karst waters basically depends on the availability of the minerals forming aquifer rocks and the residence time within the aquifers. In the three proposed scenarios in the aquifers, which include the preferential flow routines, the more important geochemical processes taking place during the groundwater flow from the recharge to the discharge zones are: CO2 dissolution and exsolution (outgassing), calcite net dissolution, calcite and dolomite sequential dissolution, gypsum/anhydrite and halite dissolution, de-dolomitization and calcite precipitation. A detailed analysis of the hydrochemical data set, saturation indices of the minerals and partial pressure of CO2 in the waters joined to the application of geochemical modelling methods allowed the elaboration of a hydrogeochemical model of the studied aquifers. The developed approach contributes to a better understanding of the karstification processes and the hydrogeological functioning of carbonate aquifers, the latter being a crucial aspect for the suitable management of the water resources.  相似文献   

4.
Quantitative analysis of springs   总被引:1,自引:0,他引:1  
Growing demand for groundwater resources and stringent environmental concerns has led to large groundwater investigations, including characterization of aquifer systems that are hydraulically connected to springs. A pumping test is one of the most reliable means of quantifying hydraulic characteristics and the response of natural springs to pumping because it yields results that, in general, are representative of a larger area than are results from a single point observation. Recharge to the aquifer sustaining discharge from springs must be evaluated prior to the utilization of springs. The spring hydrograph is analyzed, as the shape of a hydrograph is a reflection of the response of the aquifer to recharge. The form and rate of recession provide significant information on the storage, lithological composition, and structural characteristics of the aquifer system sustaining the spring. Water tracing techniques have been developed and used over a period of centuries to delineate catchment boundaries, estimate groundwater flow velocities, determine areas of recharge, and identify sources of pollution of spring water.  相似文献   

5.
A hydrogeologic conceptual model that improves understanding of variability in aquitard integrity is presented for a fractured sedimentary bedrock unit in the Cambrian-Ordovician aquifer system of midcontinent North America. The model is derived from multiple studies on the siliciclastic St. Lawrence Formation and adjacent strata across a range of scales and geologic conditions. These studies employed multidisciplinary techniques including borehole flowmeter logging, high-resolution depth-discrete multilevel well monitoring, fracture stratigraphy, fluorescent dye tracing, and three-dimensional (3D) distribution of anthropogenic tracers regionally. The paper documents a bulk aquitard that is highly anisotropic because of poor connectivity of vertical fractures across matrix with low permeability, but with ubiquitous bed parallel partings. The partings provide high bulk horizontal hydraulic conductivity, analogous to aquifers in the system, while multiple preferential termination horizons of vertical fractures serve as discrete low vertical hydraulic conductivity intervals inhibiting vertical flow. The aquitard has substantial variability in its ability to protect underlying groundwater from contamination. Across widespread areas where the aquitard is deeply buried by younger bedrock, preferential termination horizons provide for high aquitard integrity (i.e. protection). Protection is diminished close to incised valleys where stress release and weathering has enhanced secondary pore development, including better connection of fractures across these horizons. These conditions, along with higher hydraulic head gradients in the same areas and more complex 3D flow where the aquitard is variably incised, allow for more substantial transport to deeper aquifers. The conceptual model likely applies to other fractured sedimentary bedrock aquitards within and outside of this region.  相似文献   

6.
Measured concentrations of environmental tracers in spring discharge from a karst aquifer in the Shenandoah Valley, USA, were used to refine a numerical groundwater flow model. The karst aquifer is folded and faulted carbonate bedrock dominated by diffuse flow along fractures. The numerical model represented bedrock structure and discrete features (fault zones and springs). Concentrations of 3H, 3He, 4He, and CFC-113 in spring discharge were interpreted as binary dilutions of young (0–8  years) water and old (tracer-free) water. Simulated mixtures of groundwater are derived from young water flowing along shallow paths, with the addition of old water flowing along deeper paths through the model domain that discharge to springs along fault zones. The simulated median age of young water discharged from springs (5.7  years) is slightly older than the median age estimated from 3H/3He data (4.4  years). The numerical model predicted a fraction of old water in spring discharge (0.07) that was half that determined by the binary-dilution model using the 3H/3He apparent age and 3H and CFC-113 data (0.14). This difference suggests that faults and lineaments are more numerous or extensive than those mapped and included in the numerical model.  相似文献   

7.
The impact of groundwater withdrawals on the interaction between multi-layered aquifers with different water qualities in the Viterbo geothermal area (central Italy) was studied. In this area, deep thermal waters are used to supply thermal spas and public pools. A shallow overlying aquifer carries cold and fresh water, used for irrigation and the local drinking-water supply. Starting with a conceptual hydrogeological model, two simplified numerical models were implemented: a steady-state flow model of the entire groundwater system, and a steady-state flow and heat transport model of a representative area, which included complex interactions between the aquifers. The impact of increased withdrawals associated with potential future development of the thermal aquifer must be considered in terms of the water temperature of the existing thermal sources. However, withdrawals from the shallow aquifer might also influence the discharge of thermal sources and quality of the water withdrawn from the shallow wells. The exploitation of the two aquifers is dependent on the hydraulic conductivity and thickness of the intervening aquitard, which maintains the delicate hydrogeological equilibrium. Effective methods to control this equilibrium include monitoring the vertical gradient between the two aquifers and the residual discharge of natural thermal springs.  相似文献   

8.
Increased groundwater withdrawals for the growing population in the Rio Grande Valley and likely alteration of recharge to local aquifers with climate change necessitates an understanding of the groundwater connection between the Jornada del Muerto Basin and the adjoining and more heavily used aquifer in the Mesilla Basin. Separating the Jornada and Mesilla aquifers is a buried bedrock high from Tertiary intrusions. This bedrock high or divide restricts and/or retards interbasin flow from the Jornada aquifer into the Mesilla aquifer. The potentiometric surface of the southern Jornada aquifer near part of the bedrock high indicates a flow direction away from the divide because of a previously identified damming effect, but a groundwater outlet from the southern Jornada aquifer is necessary to balance inputs from the overall Jornada aquifer. Differences in geochemical constituents (major ions, δD, δ18O, δ34S, and 87Sr/86Sr) indicate a deeper connection between the two aquifers through the Tertiary intrusions where Jornada water is geochemically altered because of a geothermal influence. Jornada groundwater likely is migrating through the bedrock high in deeper pathways formed by faults of the Jornada Fault Zone, in addition to Jornada water that overtops the bedrock high as previously identified as the only connection between the two aquifers. Increased groundwater withdrawals and lowering of the potentiometric surface of the Jornada aquifer may alter this contribution ratio with less overtopping of the bedrock high and a continued deeper flowpath contribution that could potentially increase salinity values in the Mesilla Basin near the divide.  相似文献   

9.
《Applied Geochemistry》1998,13(2):143-153
The Cretaceous Chalk [Ulster White Limestone Formation (UWLF)] in Northern Ireland has been diagenetically altered to a hard, low porosity, low matrix-permeability rock. It subcrops extensive beneath thick horizontal Tertiary Basalt lavas, but has a restricted strip of outcrop (approximately 80 km2) around the periphery of the overlying igneous rock. Despite its nature and location, numerous springs issue from the Chalk and are used for public and local supply, although little is known about the origin of the groundwater or the type of flow within the Chalk. We have addressed these unknowns using hydrogeochemical data from both rock types and surface stream waters, and fluorescent dye tracing. We have demonstrated that leakage recharge from the basalt to the Chalk accounts for less than 20% of the total water issuing from the Chalk springs using geochemical mass balance of conservative species and discharge data. The majority of the discharge derives from streams coming off the basalt and entering sink holes in the Chalk aquifer. Field and water tracing evidence shows that groundwater flow in the Chalk is dominated by conduit and fissure flow near to the outcrop areas. Karstification has been widespread near outcrop but has not ocurred in the sub-basalt region. Beneath the basalts, the Chalk exhibits different hydraulic properties due to the reduced recharge and dissolution potential that has prevented extensive development of fissure permeability in the UWLF. The Chalk aquifer thus appears to be strongly zoned in terms of the source of water, flow regime and recharge rate.  相似文献   

10.
Karstic aquifers are considered as the main sources of groundwater in the northeast of Rudbar, Iran. The present study was conducted to evaluate the hydrogeological properties of karstic springs in this region. For this purpose, saturation indices (SI values) were calculated using the geochemical PHREEQC model for a number of minerals in the groundwater in the karstic aquifer. Moreover, AqQA-RockWare software packages were used to prepare hydrogeochemical plots for the aquifer, using which the sources of the ions in the water were identified. The origin of bicarbonate, calcium, and magnesium ions in water was determined using chloro-alkaline indices. Moreover, through plotting a Piper diagram for spring water samples, it was discovered that water type of all springs is the Ca-HCO3 type, confirming the karstic characteristic of springs in the area. A Durov diagram also suggests that the water composition of the springs is of the bicarbonate type with the dominant Ca cation, suggesting the calcareous effects of the region on the quality of groundwater and exhibiting a single source for the springs. The calculated saturation indices show that most of the water samples are undersaturated with respect to calcite, dolomite, and CO2. The stable isotopes (δ18O and δ2H) and deuterium excess values were used to get information about transport pathways in groundwater, atmospheric moisture, and the degree of interaction between these reservoirs. The degree of karstification of the recharge area of the karst aquifer was determined to be 5.5 from an analysis of the hydrograph Sefidab Spring.  相似文献   

11.
Based on the long-term monitoring data of rainfall, groundwater levels, groundwater abstraction, spring flow rates and groundwater quality, an assessment has been undertaken of the sustainable yield of a karst aquifer system in Shandong Province, northern China, to maintain perennial outflow of the karst springs while meeting water demands. One of the fundamental indicators for sustainable yield of groundwater is identified as maximum allowable water-level drawdown. A regional three-dimensional finite-difference numerical model has been developed to optimize the schemes associated with well fields and their locations and sustainable yields, in the Jinan spring catchment and its adjacent karst groundwater catchments, with the aim of maintaining the water level higher than the allowable lowest water level of 27.5?m above sea level. Furthermore, measures necessary to move towards sustainable use of the karst groundwater are outlined, drawing on contingency plans of water-source replacement and artificial recharge, dual water supply (based in water quality), use of the spring waters themselves, and groundwater quality protection.  相似文献   

12.
. A groundwater tracing study was conducted on the Mitchell Plain of southern Indiana to aid in the design of a karst groundwater monitoring program for a proposed landfill facility. Fluorescein and rhodamine WT dyes were introduced into sinkholes at the project site. On-site fluorometric analyses and concentration-dependent sampling were utilized at springs and a local stream for data resolution while minimizing delays between tracing events. As a result of this investigation, springs including a submerged spring that drain groundwater from the site have been identified and two groundwater monitoring stations have been established. The submerged spring was discovered in the streambed at intersections between prominent joints and solution-enlarged bedding-plane partings. It could not have been identified readily during a typical karst hydrogeologic inventory, nor would it have been detected by analyzing charcoal dye receptors with a spectrofluorophotometer.  相似文献   

13.

The Mio-Pliocene aquifer of the coastal sedimentary basin of Benin is the most exploited aquifer for water supply to the urbanised region in the southern part of the country. The population explosion is putting increasing pressure on quantitative and qualitative aspects of the groundwater resources. Preventing groundwater contamination caused by surface waters requires a thorough understanding of surface-water/groundwater interactions, especially the interactions between the Mio-Pliocene aquifer and surface waters. This study aimed to investigate the interactions between groundwater and surface waters along the major rivers (Sô River and Ouémé Stream) and brooks in the Ouémé Delta. Field campaigns identified 75 springs located in the valleys which feed the rivers, and thus maintain their base flow. The piezometric results indicated, through flow direction assessment, that the Mio-Pliocene aquifer feeds Ouémé Stream and Sô River. Chemical analyses of groundwater and surface waters show similar chemical facies, and changes in the chemical composition in groundwater are also observed in the surface waters. Moreover, the isotopic signatures of surface waters are similar to those of the groundwater and springs, which led to the identification of potential groundwater discharge areas. As a result of groundwater discharge into surface waters, the fraction of groundwater in the surface water is more than 66% in the brooks, regardless of the season. In the Ouémé Stream and Sô River, the fraction of groundwater is 0–21% between June and September, while from October to March it is 47–100%.

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14.
Large karstic springs in east-central Florida, USA were studied using multi-tracer and geochemical modeling techniques to better understand groundwater flow paths and mixing of shallow and deep groundwater. Spring water types included Ca–HCO3 (six), Na–Cl (four), and mixed (one). The evolution of water chemistry for Ca–HCO3 spring waters was modeled by reactions of rainwater with soil organic matter, calcite, and dolomite under oxic conditions. The Na–Cl and mixed-type springs were modeled by reactions of either rainwater or Upper Floridan aquifer water with soil organic matter, calcite, and dolomite under oxic conditions and mixed with varying proportions of saline Lower Floridan aquifer water, which represented 4–53% of the total spring discharge. Multiple-tracer data—chlorofluorocarbon CFC-113, tritium (3H), helium-3 (3Hetrit), sulfur hexafluoride (SF6)—for four Ca–HCO3 spring waters were consistent with binary mixing curves representing water recharged during 1980 or 1990 mixing with an older (recharged before 1940) tracer-free component. Young-water mixing fractions ranged from 0.3 to 0.7. Tracer concentration data for two Na–Cl spring waters appear to be consistent with binary mixtures of 1990 water with older water recharged in 1965 or 1975. Nitrate-N concentrations are inversely related to apparent ages of spring waters, which indicated that elevated nitrate-N concentrations were likely contributed from recent recharge.The online version of the original article can be found at  相似文献   

15.
Several natural and anthropogenic tracers have been used to evaluate groundwater residence time within a karstic limestone aquifer in southeastern New Mexico, USA. Natural groundwater discharge occurs in the lower Pecos Valley from a region of karst springs, wetlands and sinkhole lakes at Bitter Lakes National Wildlife Refuge, on the northeast margin of the Roswell Artesian Basin. The springs and sinkholes are formed in gypsum bedrock that serves as a leaky confining unit for an artesian aquifer in the underlying San Andres limestone. Because wetlands on the Refuge provide habitat for threatened and endangered species, there is concern about the potential for contamination by anthropogenic activity in the aquifer recharge area. Estimates of the time required for groundwater to travel through the artesian aquifer vary widely because of uncertainties regarding karst conduit flow. A better understanding of groundwater residence time is required to make informed decisions about management of water resources and wildlife habitat at Bitter Lakes. Results indicate that the artesian aquifer contains a significant component of water recharged within the last 10–50 years, combined with pre-modern groundwater originating from deeper underlying aquifers, some of which may be indirectly sourced from the high Sacramento Mountains to the west.  相似文献   

16.
Large karstic springs in east-central Florida, USA were studied using multi-tracer and geochemical modeling techniques to better understand groundwater flow paths and mixing of shallow and deep groundwater. Spring water types included Ca–HCO3 (six), Na–Cl (four), and mixed (one). The evolution of water chemistry for Ca–HCO3 spring waters was modeled by reactions of rainwater with soil organic matter, calcite, and dolomite under oxic conditions. The Na–Cl and mixed-type springs were modeled by reactions of either rainwater or Upper Floridan aquifer water with soil organic matter, calcite, and dolomite under oxic conditions and mixed with varying proportions of saline Lower Floridan aquifer water, which represented 4–53% of the total spring discharge. Multiple-tracer data—chlorofluorocarbon CFC-113, tritium (3H), helium-3 (3Hetrit), sulfur hexafluoride (SF6)—for four Ca–HCO3 spring waters were consistent with binary mixing curves representing water recharged during 1980 or 1990 mixing with an older (recharged before 1940) tracer-free component. Young-water mixing fractions ranged from 0.3 to 0.7. Tracer concentration data for two Na–Cl spring waters appear to be consistent with binary mixtures of 1990 water with older water recharged in 1965 or 1975. Nitrate-N concentrations are inversely related to apparent ages of spring waters, which indicated that elevated nitrate-N concentrations were likely contributed from recent recharge.An erratum to this article can be found at  相似文献   

17.
Presence of springs in karst terranes provides a unique opportunity to study the rather complex, multi-porosity, and multi-permeability system. When springs are used to evaluate the integrity of storage facilities for hazardous materials or waste disposal facilities constructed in karst areas, the spatial heterogeneity of karst aquifers makes intra-spring comparisons preferred statistical tests. One of the commonly used statistical tests is water quality control procedure such as Shewhart-CUSUM control charts. Appropriate application of the water quality control procedure to intra-spring monitoring depends on whether the assumptions can be justified about the aquifer that drains to the spring and the dataset collected at the spring. Violation of the assumptions would render the statistical tests invalid, which may result in a failure of the groundwater monitoring program. In intra-spring monitoring, it is the temporal variations of water quality at a karst spring need to be addressed, whereas the water quality at the spring is closely associated with the characteristics of the aquifer. The example datasets presented in the paper indicate that both false negative and false positive detections can occur if the temporal variation is not well characterized.  相似文献   

18.

Springs located at the historical sites of Wadi Araba (Eastern Desert of Egypt) and emerging from the escarpments of the Northern and Southern Galala Plateaus were investigated. A combination of methods, including hydrochemistry, stable and radioisotope composition, and structural analyses based on satellite data, provided information about the structure of the subsurface and the derived groundwater flow paths. Satellite images reveal karst features within the northern plateau, e.g. conical landforms. Karstic caves were documented along both escarpments. Chemical analysis of floodwater from Wadi Araba indicates higher concentrations of terrestrial salts compared to floodwaters from central and southern parts of the desert. δ18O and δ2H signatures in spring waters resemble those of floodwater and fall on the global meteoric water line, confirming their fast infiltration with minor influence of evaporation. The aquifer feeding the springs of the Northern Galala Plateau has low retention and the springs dry out quickly, even after heavy rainfall. Contrastingly, 3H activities in springs emerging from the Southern Galala Plateau refer to much slower subsurface passage. With respect to 3H content (3.8 TU) in recent flood waters, the spring water at Southern Galala Plateau contains about 40% recently recharged groundwater. However, its largest spring—the St. Antony spring—discharges water with a radiocarbon age of about 15,000 years. In combination with this spring’s constant and high discharge over a period of several months, that age estimate suggests a large reservoir with moderate to high retention.

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19.
Thermal waters at the Godavari valley geothermal field are located in the Khammam district of the Telangana state, India. The study area consists of several thermal water manifestations having temperature in the range 36–76 °C scattered over an area of ~35 km2. The thermal waters are Na–HCO3 type with moderate silica and TDS concentrations. In the present study, detailed geochemical (major and trace elements) and isotope hydrological investigations are carried out to understand the hydrogeochemical evolution of these thermal waters. Correlation analysis and principal component analysis (PCA) are performed to classify the thermal waters and to identify the different geochemical processes controlling the thermal water geochemistry. From correlation matrix, it is seen that TDS and EC of the thermal springs are mainly controlled by HCO3 and Na ions. In PCA, thermal waters are grouped into two distinct clusters. One cluster represents thermal waters from deeper aquifer and other one from shallow aquifer. Lithium and boron concentrations are found to be similar followed by rubidium and caesium concentrations. Different ternary plots reveal rock–water interaction to be the dominant mechanism for controlling trace element concentrations. Stable isotopes (δ18O, δ2H) data indicate the meteoric origin of the thermal waters with no appreciable oxygen-18 shift. The low tritium values of the samples originating from deeper aquifer reveal the long residence time (>50 years) of the recharging waters. XRD results of the drill core samples show that quartz constitutes the major mineral phase, whereas kaolinite, dolomite, microcline, calcite, mica, etc. are present as minor constituents. Quartz geothermometer suggests a reservoir temperature of 100 ± 20 °C which is in good agreement with the values obtained from K–Mg and Mg-corrected K–Mg–Ca geothermometers.  相似文献   

20.
The Janah alluvial aquifer is located in southern Iran with an arid climate. The type of groundwater in this aquifer is dominantly of sodium chloride and total dissolved solid of groundwater samples range from 1.63 to 335 g/L which confirms that groundwater quality has been severely degraded by salinization. Hydrogeochemical and isotopic investigations were conducted to identify the source of salinity. Total dissolved solids and major ion concentrations were measured at 51 selected sampling sites including springs, wells and surface waters. In addition stable isotopic composition (oxygen-18 and deuterium) was measured in 6 sampling points.The study indicates that the sources of salinity of the Janah aquifer include dissolution of salt diapir and evaporite rocks, a geothermal spring and intrusion of the river water which function individually or together in different parts of the aquifer. Based on the hydrogeochemical and geological studies conceptual flow models were prepared for different parts of the aquifer which illustrate how each source of salinity deteriorates the quality of the alluvial aquifer. We proposed few remediation methods including construction of cemented channel and sealed basins to improve groundwater quality. These methods would prevent infiltration of low quality water into the alluvial aquifer.  相似文献   

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