“寨背式”离子吸附型稀土矿床多类型稀土矿化及其成因

赣南寨背离子吸附型稀土矿床产于寨背复式花岗岩体的风化壳中,自20世纪80年代发现以来一直以轻稀土型开采,近年在轻稀土型花岗岩风化壳中发现了重稀土矿。为了探讨轻稀土型花岗岩风化过程中重稀土元素的迁移、分馏和富集机制,本文选择了区内三个具有代表性的风化壳钻孔(ZK1、ZK2和ZK4)对其进行了全相和离子交换相稀土元素地球化学研究。结果显示：钻孔ZK4中离子交换相稀土含量介于14.90×10^-6～835.8×10^-6之间,并富集轻稀土(LREE/HREE=2.28～10.78);钻孔ZK1中离子交换相稀土含量达1470×10^-6(9件样品均值),具有从轻稀土型向重稀土型过渡的配分特征(LREE/HREE=1.30～1.65),并且剖面自上而下显示轻、重稀土逐渐富集的趋势;钻孔ZK2中离子交换相稀土含量为492.4×10^-6(8件样品均值),自上而下稀土配分类型从轻稀土型过渡至重稀土型(LREE/HREE=0.43～2.25),且轻稀土富集在全风化层上部而重稀土则富集在下部。三个钻孔的Nb/Ta和Zr/Hf...     

山东沂水雪山岩体和林家官庄岩体的同位素年代学

研究了山东沂水地区的两个太古宙花岗岩类岩体,雪山岩体是花岗闪长岩-花岗岩体。林家官庄岩体属奥长花岗岩-英云闪长岩系列。稀土元素均具轻稀土富集型的分配型式。分别具轻微到明显,和轻微负Eu异常。用质谱计双带源逐层蒸发法进行了单颗粒锆石的详细定年。确定了雪山岩体侵入时代为2530Ma(2531,2532).林家官庄岩体的侵入时代为2507Ma,两个岩体都形成于新太古代。雪山岩体中还发现了年龄为2910Ma的继承性锆石。推测这种错石来自于表壳岩包体。     

Rare Earth Element Geochemistry of Late Palaeozoic Coals in North China

Instrumental Neutron Activation Analysis (INAA) was done to determine the abundances of rare earth elements (REE) of 58 samples of Late Palaeozoic Carboniferous-Permian coals and related rocks in North China. Detailed study of REE geochemistry shows that the ∑REE of most coals studied in this paper is in a normal range between 30×10-6 and 80×10-6 with a mean of 56×10-6. The REE in the Taiyuan Formation in the northern part of North China are much richer than those in the southern part. This is due to the shorter distance to the source area in the north. Moreover, the IREE is in positive correlation to coal ash, especially closely related to the content of clay minerals <2μm in size. This reveals that most REE were carried by terrigenous clastic materials, especially fine clay minerals. In the coals the light REE (LREE) are much richer than the heavy REE (HREE), and the LREE/HREE ratio in coals generally varies from 2 to 8. The LREE/HREE ratio of high-ash, low-sulphur coals is higher than that of lo     

华北地台北缘鞍山白家坟奥长花岗岩地球化学特征、锆石U-Pb年龄及意义

太古宙TTG岩石的成因及年代学研究是理解前板块构造和板块构造开始及其演化过程的关键,是陆壳增生的重要标志,为太古宙地质体研究的热点和难点之一。对鞍山地区的白家坟岩体进行了地球化学研究和锆石U-Pb测年。数据结果显示,该岩体具有正片麻岩特征,Si、Na含量高,TFeO、MgO、CaO含量低,轻、重稀土元素分异程度低,且具有一定变化。稀土元素总量偏低(12.6×10~(-6)～119.34×10~(-6)),LREE/HREE值为8.98～13.11。微量元素富集K、Rb、Ba,亏损Nb、Ce、Zr、Sm、Ti、Y、Yb;K/Rb平均值为229.37,Rb/Sr平均值为0.58,Ba/Sr平均值为3.28,Y/Nb平均值为3.36。表明该岩体为岩浆作用的产物,也有部分为壳内再循环的产物或受到陆壳物质影响。测得~(207)Pb/~(206)Pb年龄加权平均值为3816±14Ma,锆石具有清晰的振荡环带结构,所有核部锆石分析点的Th/U值在0.05～0.54之间,具有岩浆锆石的特点,代表了白家坟奥长花岗质岩石的结晶时代。3613～3651Ma和3331Ma两组年龄数据代表早太古代的一次岩浆事件及重要的陆壳增生时期的热事件。     

浙东南松阳县枫坪组沉积岩碎屑锆石年代学及地质意义

利用激光剥蚀电感耦合等离子质谱技术(LA-ICP-MS)对浙东南松阳县枫坪组地层底部的细砂岩进行了锆石U-Pb定年及稀土元素分析。样品中大部分碎屑锆石具有较好的振荡环带且Th/U值大于0. 1,表明其为岩浆成因。碎屑锆石中稀土元素含量变化范围较大,(La/Yb)_N值为0～0. 29,LREE/HREE值为0. 003×10~(-6)～0. 977×10~(-6),表明样品中锆石的轻、重稀土元素分异程度较小且重稀土元素相对富集,具有轻稀土元素含量低、重稀土元素含量高的左倾模式且具有负Eu异常、正Ce异常的特征,表明碎屑锆石主要以岩浆锆石为主,同时存在少量的变质锆石。碎屑锆石U-Pb测年结果表明,最年轻的锆石年龄为193 Ma,显示枫坪组沉积岩成岩年龄不晚于193 Ma。碎屑锆石年龄可分为4组,分别为2 461～1 743 Ma、887 Ma、435和422 Ma、330～193 Ma。碎屑锆石的主要年龄区间分别与已知的构造-岩浆热事件时间相对应(吕梁期、晋宁期、加里东期和印支-海西期),表明本区的构造岩浆活动与中国大地构造运动相一致,并具有幕式发展的特征。通过对枫坪组沉积岩碎屑锆石U-Pb年龄的系统分析并与可能物源区的年代学对比研究,认为枫坪组沉积岩物质来源主要是周边出露的中条期侵入岩体和浙东南出露的印支期花岗岩体。     

Geochemical Charactristics and Genesis of Topaz—Bearing Porphyries in Yangbin Area of Taishun County,Zhejiang Province

The host rocks of the porphyry tin deposits in the Yangbin area are principally topaz-bearing porphyry dikes about 2 km long and 2–20m wide. Three lithologie types are identified for the dikes: topaz-bearing potassium feldspar granitic porphyry, topaz-bearing monzonitic granitic porphyry and topaz-bearing quartz porphyry. The content of topaz in the rocks ranges from 10 to 20 vol.%. Porphyritic texture is characteristic, with quartz, potassium feldspar and albite as main phenocryst minerals. The phenocryst occupies 10–20 vol% of the rocks. The rock groundmass consists of subhedral topaz, quartz and protolithionite. Topaz has a unit-cell parameter b=8.797 (Å), and F:OH=1.92:0.18, indicating a F-rich variety formed at high temperature. The topaz-bearing porphyries occurring in this area are strongly peraluminous (A/NKC=1.574–12.94), with high ratios of F/Cl (146–303) and Rb/Sr (5–122). They are rich in incompatible elements (Sn, 313 × 10^?6–1042 × 10^?6; W, 6 × 10^?6–218 × 10^?6; Nb, 27 × 10^?6–54 × 10^?6), but poor in compatible elements (Sr, 10 × 10^?6–28 × 10^?6; Ba, 58 × 10^?6–73 × 10^?6; V, 3 × 10^?6–12 × 10^?6, Cl, 150 × 10^?6–226 × 10^?6). The rocks are also characterized by high total REE amount (281.69 × 10^?6–319.76 × 10^?6), with strong Eu depletion (δEu=0.01–0.03) and low ratio of LREE/HREE (0.78–0.84). In summary, the authors propose an idea of S-type genesis for the topaz-bearing porphyries with tin mineralization, instead of I-type.     

江西足洞和关西花岗岩的稀土元素地球化学及矿化特征

足洞和关西岩体分别为花岗岩风化壳离子吸附型重、轻稀土矿床的原岩。足洞岩体的∑REE¹⁾为264ppm,LREE/HREE²⁾值为0.81-024,平均的钇对∑REE占有率为35.8-54.5%。这主要是由于岩浆结晶演化及晚期有交代钠长石化、白云母化和萤石-氟碳钙钇矿化的结果。这些蚀变产生了钇族稀土氟碳酸盐、硅酸盐和砷酸盐等内生矿化作用。     

浙江八面山萤石矿床稀土元素地球化学特征及成因探讨

对浙江八面山萤石矿床中不同类型萤石矿石和围岩样品的稀土元素的系统分析表明,细粒萤石矿石的ΣREE〈39×10-6,LREE为14.36×10-6～34.24×10-6,HREE0.96×10-6～2.04×10-6,Y〈3×10-6;巨晶萤石矿石中的ΣREE3.62×10-6～20.81×10-6,LREE2.71×10-6～17.67×10-6,HREE0.24×10-6～1.49×10-6;而围岩花岗岩的ΣREE460.29×10-6,LREE225.97×10-6,HREE91.32×10-6,Y＆gt;140×10-6;沉积岩中的ΣREE20.22×10-6、LREE16.11×10-6、HREE1.61×10-6。矿石与围岩中沉积岩的稀土总量、轻稀土、重稀土和Y的含量接近,与花岗岩的稀土总量、轻稀土、重稀土和Y元素含量相差悬殊。萤石矿石的稀土分布型式主要为轻稀土富集型,（La/Yb）N通常多数大于8,在8.07～17.26间,δEu值在0.45～1.30,δCe在0.89～1.14间,Ce、Eu基本不显异常。矿石与围岩的稀土地球化学研究显示,八面山萤石矿床为受地层、岩体与断裂共同控制＂三位一体＂的低温热液型矿床。     

Zircon U–Pb and Molybdenite Re–Os Ages of the Lakange Porphyry Cu–Mo Deposit,Gangdese Porphyry Copper Belt,Southern Tibet,China

The Lakange porphyry Cu–Mo deposit within the Gangdese metallogenic belt of Tibet is located in the southern–central part of the eastern Lhasa block, in the Tibetan Tethyan tectonic domain. This deposit is one of the largest identified by a joint Qinghai–Tibetan Plateau geological survey project undertaken in recent years. Here, we present the results of the systematic logging of drillholes and provide new petrological, zircon U–Pb age, and molybdenite Re–Os age data for the deposit. The ore‐bearing porphyritic granodiorite contains elevated concentrations of silica and alkali elements but low concentrations of MgO and CaO. It is metaluminous to weakly peraluminous and has A/CNK values of 0.90–1.01. The samples contain low total REE concentrations and show light REE/heavy REE (LREE/HREE) ratios of 17.51–19.77 and (La/Yb)_N values of 29.65–41.05. The intrusion is enriched in the large‐ion lithophile elements (LILE) and depleted in the HREE and high field‐strength elements (HFSE). The ore‐bearing porphyritic granodiorite yielded a Miocene zircon U–Pb crystallization age of 13.58 ± 0.42 Ma, whereas the mineralization within the Lakange deposit yielded Miocene molybdenite Re–Os ages of 13.20 ± 0.20 and 13.64 ± 0.21, with a weighted mean of 13.38 ± 0.15 Ma and an isochron age of 13.12 ± 0.44 Ma. This indicates that the crystallization and mineralization of the Lakange porphyry were contemporaneous. The ore‐bearing porphyritic granodiorite yielded zircon εHf(t) values between ?3.99 and 4.49 (mean, ?0.14) and two‐stage model ages between 1349 and 808 Myr (mean, 1103 Myr). The molybdenite within the deposit contains 343.6–835.7 ppm Re (mean, 557.8 ppm). These data indicate that the mineralized porphyritic granodiorite within the Lakange deposit is adakitic and formed from parental magmas derived mainly from juvenile crustal material that partly mixed with older continental crust during the evolution of the magmas. The Lakange porphyry Cu–Mo deposit and numerous associated porphyry–skarn deposits in the eastern Gangdese porphyry copper belt (17–13 Ma) formed in an extensional tectonic setting during the India–Asia continental collision.     

河北滦平周台子条带状铁矿地质特征、围岩时代及其地质意义

河北滦平县周台子铁矿位于华北克拉通北缘,是产于前寒武纪单塔子群变质岩系中的鞍山式铁矿,具有条带状铁建造(BIF)特征。矿石主要呈条带状构造,有的呈条纹和致密块状构造。矿石类型主要以石英磁铁矿型为主,含铁介于30%~35%。前寒武纪变质岩是矿床的主要围岩,出露有黑云母(角闪)斜长片麻岩和斜长角闪岩,局部见花岗片麻岩。原岩恢复表明,黑云母(角闪)斜长片麻岩的原岩为英安岩-流纹岩,斜长角闪岩原岩为玄武岩。花岗片麻岩的SiO₂含量大于56%,MgO含量小于3%,Al₂O₃含量大于15%,Sr含量大于500×10^-6,Yb含量均小于1.9×10^-6,轻重稀土元素分异明显,重稀土元素强烈亏损,并且Eu负异常不明显,表明该片麻岩具埃达克质岩石的地球化学特征。锆石U-Pb定年结果显示出几组年龄,分别是2512±21Ma, 2452±9.6Ma,2394±55Ma。大体看,2512Ma代表了火山喷发和周台子铁矿BIF沉淀年龄,2452Ma左右的锆石年龄代表了TTG质花岗片麻岩的侵位结晶年龄,2394Ma锆石年龄代表了周台子铁矿经历了一次变质作用,并对原有的岩石和矿石进行了改造。锆石Hf同位素特征显示斜长角闪岩和TTG质片麻岩的岩浆源区受到过古老地壳物质的混染。周台子铁矿构造环境可能是与裂谷有关的张性环境。     

大兴安岭中北段早白垩世爱林源花岗岩的成因:锆石U-Pb年代学、地球化学及Hf同位素制约

大兴安岭绰尔地区爱林源岩体锆石U-Pb年代学、地球化学及Lu-Hf同位素分析结果显示,爱林源岩体的岩石类型主要为二长花岗岩,两个样品LA-ICP-MS锆石U-Pb定年结果分别为132 Ma和137 Ma,为早白垩世岩浆作用产物。地球化学数据显示二长花岗岩具有高硅、富钾、贫铁、贫镁的特点,具有中等-弱铕异常(Eu/Eu*)=0.46~1.07,∑REE为54.11×10~(-6)~191.42×10~(-6),LREE/HREE=11.38~18.03,轻重稀土元素分馏作用明显[(La/Yb)_N=12.12~23.52],相对富集大离子亲石元素(Rb、Ba、K),亏损高场强元素(Nb、Ta、Ti)及P元素等。锆石Lu-Hf同位素特征显示样品锆石ε_(Hf)(t)值均为正值(分别为3.9~7.9和2.9~8.0),并且具有较年轻的Hf二阶段模式年龄(t_(DM2)=709~942 Ma,677~1 001 Ma)。结合区域地质研究,笔者认为花岗质岩浆由新生地壳物质的部分熔融形成,可能与古太平洋板块俯冲兴安地块有关。     

辽北西丰地区宝兴岩体LA-ICP-MS锆石U-Pb年龄及岩石地球化学特征

宝兴岩体位于华北板块北缘陆缘活动带东段,岩性为花岗闪长岩,LA-ICP-MS锆石~(206)Pb/~(238)U年龄加权平均值为235.0±1.3Ma,属于中三叠世。岩石的K_2O/Na_2O平均值为1.07,属高钾钙碱性系列;富集大离子亲石元素,亏损高场强元素,具有活动陆缘钙碱性岩系特征;稀土元素总量平均值为147×10~(-6),稀土元素配分曲线右倾,属具中等负Eu异常的轻稀土元素富集、重稀土元素亏损型。通过岩石学、岩石地球化学及年代学研究,结合邻区构造演化研究,认为中三叠世研究区在伸展作用下岩石圈进行拆沉,从而形成大规模的岩浆活动。     

甘肃北山大山头南基性-超基性杂岩体SHRIMP锆石U-Pb定年及其地质意义

大山头南铜镍矿化基性-超基性杂岩体位于北山褶皱带东段,侵位于长城系古硐井群变质岩中。岩相分带明显,主要包括花岗闪长岩-闪长岩相、辉长岩-橄榄苏长辉长岩相和橄榄二辉岩-纯橄岩相。铜镍矿化主要赋存于橄榄二辉岩-纯橄岩相中。岩石化学特征显示K2O、Na2O、TiO2含量较低,Mg#值介于0.74~0.85之间,MgO/FeOT的值介于1.6~3.1之间,属于铁质镁铁-超镁铁岩;AFM图解显示该岩体具拉斑玄武岩的演化趋势;稀土元素总量较低,介于6.37×10-6~37.51×10-6之间;稀土元素标准化配分曲线表现为轻稀土元素稍富集的右倾型,LREE/HREE比值介于3.03~4.11之间,轻重稀土发生了明显的分馏;采用SHRIMP锆石U-Pb方法,获得杂岩体辉长岩中锆石U-Pb年龄为374.3±3 Ma(MSWD=0.92),表明该岩体侵位于中晚泥盆世,与形成大型镍矿床的黑山岩体年龄一致,形成于洋壳俯冲阶段。该年龄的获得不仅对北山乃至中亚造山带地质构造演化具有重要意义,而且也为北山褶皱带东段铜镍找矿提供了新的方向。     

Uncoupled U/Pb and REE response in zircon during the transformation of eclogite to mafic and intermediate granulite (Blanský les,Bohemian Massif)

An eclogite–mafic granulite occurs as a rare boudin within a felsic kyanite–K‐feldspar granulite in a low‐strain zone. Its boundary is marked by significant metasomatism–diffusional gain of potassium at the centimetre‐scale, and probable infiltration of felsic melt on a larger scale. This converted the eclogite–mafic granulite into an intermediate‐composition, ternary‐feldspar‐bearing granulite. Based on inclusions in garnet, the peak P–T conditions of the original eclogite are 18 kbar at 850–950 °C, with later matrix re‐equilibration at 12 kbar and 950 °C. Four samples from the transition of the eclogite–mafic granulite through to the intermediate granulite were studied. In the eclogite, REE patterns in the garnet core show no Eu anomaly, compatible with crystallization in the absence of plagioclase and consistent with eclogite facies conditions. Towards the rim of garnet, LREE decrease, and a weak negative Eu anomaly appears, reflecting passage into HP granulite facies conditions with plagioclase present. The rims of garnet next to ternary feldspar in the intermediate granulite show the lowest LREE and deepest Eu anomalies. Zircon from the four samples was analysed by LASS (laser ablation–split‐stream inductively coupled plasma–mass spectrometry). It shows U–Pb ages from 404 ± 4.0 to 331 ± 3.3 Ma, with a peak at 340 ± 4.0 Ma corresponding to the likely exhumation of the rocks to 12 kbar. Older ages from zircon with steep HREE patterns indicate the minimum age of the protolith, and ages <360 ± 4.0 Ma are interpreted to correspond to the eclogite facies metamorphism. Only some zircon grains ≤350 ± 4.0 Ma have flat HREE patterns, suggesting that these are primarily modified protolith grains, rather than new zircon crystallized in the eclogite‐ or granulite facies. The metasomatic processes that converted the eclogite–mafic granulite to an intermediate granulite may have facilitated zircon modification as zircon in the intermediate granulite has flat HREE and ages of 340 ± 4.0 Ma. The difference between the oldest and youngest ages with flat REE patterns indicates a 16 ± 5.6 Ma period of zircon modification in the presence of garnet.     

内蒙古宝日拉锦乌拉钠闪石花岗岩特征

宝日拉锦乌拉钠闪石花岗岩岩体位于大兴安岭中段东坡,形成于早白垩世晚期或更晚些.钠闪石花岗岩富SiO₂（含量为71.63%~77.35%）,富碱（ALK=4.94%~9.17%）,贫铝、镁、钙.钠闪石花岗岩的稀土元素总量极高,其中钠闪石钾长花岗岩的稀土总量在271.77×10^-6~701.77×10^-6之间,而钠闪石二长花岗岩中的稀土元素总量在2938×10^-6~6933.2×10^-6之间.轻、重稀土元素比值在1.63~7.49之间,大部分在2~5之间,稀土配分曲线为略呈右倾的“V”字形,说明轻、重稀土元素的分馏程度较差.δEu值极低,在0.016~0.035之间,说明该岩石的Eu负异常极为明显.研究区出露的钠闪石花岗岩形成于板块内部非造山的相对稳定的构造环境.     

Coexistence of a Fluid Phase with Granitic Magma: Geochemical Characteristics of REE and Cu in Miyako Granite and in Scheelite-bearing Aplitic Veins at the Yamaguchi Cu-W Skarn Deposit, Iwate, Japan

Abstract: The North granitic body of the Miyako pluton is located in the Northern Kitakami belt, Northeast Japan. The formation of the scheelite–chalcopyrite–magnetite–bearing aplitic veins and scheelite–chalcopyrite–magnetite–bearing Yamaguchi skarn deposit was closely associated with the formation of the Miyako plutons. Petrographic facies of the North granitic body vary from quartz diorite in marginal zone (zone A), to tonalite and granodiorite (zone B), and to granite (zone C) in the central. The large numbers of aplitic veins distributed around the Yamaguchi mining area are divided into two groups: barren and scheelite–mag–netite–chalcopyrite–bearing aplitic veins. The latter cut massive clinopyroxene skarns of the Yamaguchi deposit, and are composed of plagioclase, K‐feldspar and titanite. Some plagioclase crystals have dusty cores with irregularly shaped K‐feldspar flakes, and clear rims of albite. Textures of plagioclase in the mineralized aplitic veins are different from the idiomorphic textures with sharp plagioclase crystal boundaries that occur in the North granitic body and barren aplitic veins. These textural data suggest that the mineralized aplitic veins were formed from hydrothermal fluid. Changes in the contents of major and minor (Rb, Sr, Sc, Co, Th, U) elements in the North Miyako granitic body are similar to those of zoned plutons formed by typical magmatic differentiation processes. On the other hand, concentrations of REE, especially middle to heavy REE, of granitic rocks in zone C and barren aplitic veins are significantly lower than those of granitic rocks in zones A and B. The hypothetical chondrite‐normalized REE patterns, calculated assuming fractional crystallization from zone B granitic melt, suggest that REE concentrations of the residual melt increased with the degree of fractional crystallization, and changed into a pattern with enriched LREE and strongly negative Eu anomaly. However, the REE patterns of granitic rocks in zone C are different from the hypothetical patterns. Moreover, the REE patterns of magnetite–scheelite–chalcopyrite aplitic veins are quite different from those of granitic rocks. The Cu contents of granitic rocks in the North Miyako body increase from zone A (5–26 ppm) to zone B (10–26 ppm), and then clearly decrease to zone C (5–7 ppm) and drastically increase to the barren aplitic veins (39–235 ppm). Concentrations of Cu in the mineralized aplitic veins are also higher than those of the granitic rocks in zone C. The decrease in REE and Cu contents of granitic rocks from zone B to zone C is not a result of simple magmatic fractional differentiation. Fluid inclusions in quartz from mineralized aplitic veins contain 3.3 wt% NaCl equivalent and 5.8 wt% CO₂. It was also demonstrated experimentally that the removal of MREE and HREE by fluid from melt enabled the formation of complexes of REE and ligands of OH^‐ and CO₃^2‐. Based on the possibility that the melt of the granitic rocks of zone C and the mineralized aplitic veins coexisted with CO₂‐bearing fluid, it is thought that REE were extracted from the melt to the CO₂‐bearing fluid, and that the REE in the mineralized aplitic veins were transported by the CO₂‐bearing fluid. It is likely that the low HREE and Cu contents of the granitic rocks in zone C could have been caused by the removal of those elements from the granitic melt by the fluid coexisting with the melt. The expelled materials could have been the sources of scheelite–magnetite–chalcopyrite–bearing aplitic veins and copper mineralization of the Yamaguchi Cu‐W skarn deposit.     

北秦岭烟镇岩体的锆石U-Pb定年、地球化学特征及构造背景

烟镇岩体是北秦岭燕山期酸性侵入岩之一,它的岩石成因及深部动力学过程研究可为区域构造演化提供新的约束。对烟镇岩体黑云母二长花岗岩样品YZ04进行了LA-ICP-MS锆石U-Pb定年,30个测点中有23个测点的同位素比值位于²⁰⁷Pb/²³⁵U-²⁰⁶Pb/²³⁸U一致线上,它们的年龄值形成了复杂锆石年龄谱,7个年龄组依次为2 421 Ma、1 821 Ma、1 063 Ma、942.6 Ma、817.6 Ma、～145.0 Ma和～131 Ma,区域上均存在与之对应的岩浆热事件。最年轻的一组14颗锆石的加权平均年龄131.3±0.6 Ma,表明烟镇岩体形成时代为早白垩世早期。烟镇岩体具有高硅、碱及贫镁、钙的特征,属于高钾钙碱性系列。烟镇岩体样品富集大离子亲石元素,亏损高场强元素Nb、Ta,在微量元素蛛网图上显示明显的Nb、Ta、P及Ti负异常。烟镇岩体的稀土配分模式具有右倾平滑、轻稀土富集及重稀土亏损及无明显负Eu异常等特征,（La/Yb）_N范围为7.97～49.19,其La_N-（La/Yb）_N成分投点趋势表明源区组成和部分熔融程度控制了烟镇岩体的成分变异。烟镇岩体具有高Sr、低Y的特征,属于埃达克岩,它是加厚大陆下地壳的部分熔融形成的,部分熔融源区的残余相矿物包括石榴石、金红石,且无（富钙）斜长石残留。烟镇岩体是～131 Ma区域岩石圈拆沉作用的产物,这也是形成锆石年龄谱的深部控制因素,华北克拉通燕山期岩石圈巨大减薄效应波及到北秦岭地区。     

北黄海盆地花岗斑岩锆石U-Pb年代学、地球化学及其地质意义

北黄海盆地X1和X2钻井岩心揭示上侏罗统中有侵入的花岗质岩石,镜下鉴定其为花岗斑岩。对花岗斑岩进行了主量、微量和稀土元素测试分析,样品的Si O2含量介于70.22%~71.88%之间,K2O/Na2O比值介于0.95~1.68之间,A/CNK比值介于0.75~1.12之间,有高钾钙碱性、弱碱质-偏铝质性质。微量元素组成富集Rb、Th、U等元素,相对亏损Nb、Eu、Sr等元素。稀土总量较高(∑REE=50.38×10-6~162.27×10-6),轻稀土(LREE)相对富集(LREE/HREE=6.86~25.43,(La/Yb)N=10.06~57.76),具有明显的Eu负异常(?Eu=0.65~0.83)。样品的Th含量高,与Rb呈正相关性,综合主量元素特征(A/CNK1.1),判别其为I型花岗岩。LA-ICP-MS锆石U-Pb测年结果表明X1井花岗斑岩年龄为110±1 Ma,X2井花岗斑岩年龄108±1 Ma、107±1 Ma,形成于早白垩世晚期。结合区域构造背景及岩石地球化学特征认为,北黄海盆地花岗斑岩形成于板块碰撞后的伸展构造背景。     

北秦岭东段二郎坪群火山岩锆石的LA-ICP-MS U-Pb定年及其地质意义

利用阴极发光（CL）技术和LA-ICP-MS原位分析方法,对北秦岭东段军马河、湾潭和湍河3个地区的二郎坪群基性火山岩进行了系统的锆石U Pb年代学研究。CL图像分析结果显示,三地火山岩中的锆石皆呈自形 半自形柱状形态和微弱的、宽的振荡环带结构。微量元素分析揭示,所有锆石都具有较高的稀土总量、重稀土和Th、U含量（ΣREE为(397.7~7 941.6)×10-6;ΣHREE为(376.7~7 774.2)×10-6;Th为(107.9~5 824.2)×10-6;U为(89.3~3 841.9)×10-6）以及轻稀土亏损、重稀土明显富集的左倾稀土配分曲线型式,所有锆石的Th/U比值皆大于0.4,显示典型岩浆锆石特征。LA-ICP-MS定年结果获得3地基性火山岩的形成年龄分别为(463±1.8) Ma、(475±1.5) Ma和(473±1.3) Ma,三者在误差范围内一致,表明北秦岭二郎坪群基性火山岩的形成时代为463~475 Ma。系统的岩石学和地球化学研究显示,二郎坪群火山岩具有弧后盆地火山岩的地球化学特征。研究获得的二郎坪基性火山岩463~475 Ma的结晶年龄明显晚于其南侧北秦岭超高压榴辉岩的原岩年龄(（791±6) Ma）以及变质年龄（(502±11) Ma）,而且榴辉岩的地球化学特征显示为板内玄武岩,也与二郎坪火山岩不同,因而指出北秦岭超高压榴辉岩与二郎坪火山岩没有直接成因联系。     

Geochemistry, Geochronology and Lu-Hf Isotopes of Peraluminous Granitic Porphyry from the Walegen Au Deposit, West Qinling Terrane

Walegen Au deposit is closely correlated with granitic intrusions of Triassic age, which are composed of granite and quartz porphyries. Both granite porphyry and quartz porphyry consist of quartz, feldspar and muscovite as primary minerals. Weakly peraluminous granite porphyry(A/CNK=1.10–1.15) is enriched in LREE, depleted in HREE with Nb-Ta-Ti anomalies, and displays subduction-related geochemistry. Quartz porphyry is strongly peraluminous(A/CNK=1.64–2.81) with highly evolved components, characterized by lower TiO_2, REE contents, Mg~#, K/Rb, Nb/Ta, Zr/Hf ratios and higher Rb/Sr ratios than the granite porphyry. REE patterns of quartz porphyry exhibit lanthanide tetrad effect, resulting from mineral fractionation or participation of fluids with enriched F and Cl. LAICP-MS zircon U-Pb dating indicates quartz porphyry formed at 233±3 Ma. The ages of relict zircons from Triassic magmatic rocks match well with the detrital zircons from regional area. In addition, ε_(Hf)(t) values of Triassic magmatic zircons from the granite and quartz porphyries are -14.2 to -9.1(with an exception of +4.1) and -10.8 to -8.6 respectively, indicating a crustal-dominant source. Regionally, numerous Middle Triassic granitoids were previously reported to be formed under the consumption of Paleotethyan Ocean. These facts indicate that the granitic porphyries from Walegen Au deposit may have been formed in the processes of the closing of Paleotethyan Ocean, which could correlate with the arc-related magmatism in the Kunlun orogen to the west and the Qinling orogen to the east.