Stratigraphy of Quaternary inner-shelf sediments in Tai O Bay, Hong Kong, based on ground-truthed seismic profiles

High-resolution boomer profiles from Tai O Bay, Hong Kong SAR, were ground-truthed using ten discontinuously sampled boreholes penetrating bedrock with a maximum length of 82.1 m. The relationship between depth below seabed and seismic profiles was established through the measurement of two borehole compressional-wave velocity profiles. In departure from previous interpretations, nine Quaternary seismic units were identified, which can be divided into eight systems tracts formed by cycles of fourth-order sea-level fluctuations dating back at least to marine isotope stage (MIS) 7 (ca. 190–245 ka). These consist of two lowstand systems tracts, two transgressive systems tracts, and four highstand systems tracts. Secondary unconformities within the highstand deposits are interpreted to document fifth-order sea-level fluctuations. Lowstand deposits are less common because, as soon as the sea level drops by a few metres, Tai O Bay becomes sub-aerially exposed, leading to widespread non-deposition or erosion. At the same time, extensive fluvial erosion and channel incision take place. Filling of the fluvial channels occurs during rising sea level. Lowstand sediments (if present) are generally landslide deposits laid down on a basal alluvial plain. Uncorrected accelerator mass spectrometry (AMS) radiocarbon dates of mollusc shells show that the depositional environment was marine since 6.2 ka, becoming gradually more brackish as a result of progradation of the Pearl River delta. The computed average sedimentation rate for the period 6.2–4.1 ka is 4.4 m/1,000 year, and approximately 1 m/1,000 year since 4.1 ka.     

Activity of the turbidite levees of the Celtic–Armorican margin (Bay of Biscay) during the last 30,000 years: Imprints of the last European deglaciation and Heinrich events

High-resolution sedimentological and micropaleontological studies of several deep-sea cores retrieved from the levees of the Celtic and Armorican turbidite systems (Bay of Biscay — North Atlantic Ocean) allow the detection of the major oscillations of the British–Irish Ice Sheet (BIIS) and ‘Fleuve Manche’ palaeoriver discharges over the last 30,000 years, which were mainly triggered by climate changes.Between 30 and 20 cal ka, the turbiditic activity on the Celtic–Armorican margin was weak, contrasting with previous stratigraphic models which predicted a substantial increase of sediment supply during low sea-level stands. This low turbidite deposit frequency was most likely the result of a weak activity of the ‘Fleuve Manche’ palaeoriver and/or of a reduced seaward transfer of sediments from the shelf to the margin. However, two episodes of turbiditic activity increase were detected in the Celtic–Armorican margin, during Heinrich events (HE) 3 and 2. This strengthening of the turbiditic activity was triggered by the meltwater releases from European ice sheets and glaciers favouring the seaward transfer of subglacial material, at least via ‘Fleuve Manche’ palaeoriver.At around 20 cal ka, a significant increase of turbidite deposit frequency occurred as a response to the onset of the last deglaciation. The retreat of the European ice sheets and glaciers induced a substantial increase of the ‘Fleuve Manche’ palaeoriver discharges and seaward transfer of continentally-derived material into the Armorican turbidite system. The intensification of the turbiditic activity on the Celtic system was directly sustained by the widespread transport of subglacial sediments from the British–Irish Ice Sheet (BIIS) to the Celtic Sea via the Irish Sea Basin. A sudden reduction of turbiditic activity in the Armorican system, between ca. 19 and 18.3 cal ka, could have been triggered by the first well known abrupt sea-level rise (‘meltwater pulse’, at around 19 cal ka) favouring the trapping of sediment in the ‘Fleuve Manche’ palaeoriver valleys and the decrease of the seaward transfer of continentally-derived material.The maximum of turbiditic activity strengthening in the Celtic–Armorican margin, between ca. 18.3 and 17 cal ka, was induced by the decay of European ice sheets and glaciers producing the most extreme episode of the ‘Fleuve Manche’ palaeoriver runoff and a great seaward transfer of subglacial material into the Bay of Biscay. Between ca. 17.5 and 16 cal ka, the turbiditic activity significantly decreased in both Celtic and Armorican turbidite systems in response to a global re-advance of glaciers and ice sheets in Europe. The last episode of ice sheet retreat, between ca. 16 and 14 cal ka, is well expressed in the Celtic system by a new increase of the turbiditic activity. The major episode of sea-level rise at around 14 cal ka (‘Meltwater Pulse 1A’), precluding the seaward transfer of sediments, induced the end of turbiditic activity in both the Celtic and the Armorican system.Although two main phases of global sea-level rise seem to have had an effect on the Celtic–Armorican margin, this work proposes the BIIS retreat and associated riverine discharges as the main trigger mechanisms of the turbiditic activity in this region during the last 30,000 years.     

Stratigraphy of sediments from the Håkon Mosby Mud Volcano Area

Studies of four gravity cores from the Håkon Mosby Mud Volcano area have shown the existence of three lithologic–stratigraphic units: I – brown clay (0–10?ka), II – gray clay (10–30?ka) and III – gray silt (30–61?ka). The units reflect different paleographic sedimentation and conditions, including the influence of mud volcanic activity. Two periods of mud volcanic activity can probably be discerned: 10–30?ka and Recent. The coexistence of Pleistocene and Late Pliocene benthic foraminifera suggests that the source depth of the volcano is located below the Pliocene–Pleistocene boundary.     

中国东海和南黄海沿海平原MIS 3晚期海侵层的动力模拟研究

Abundant evidences of higher sea levels from Jiangsu and Fujian coasts have proved a marine transgression event during 30–40 ka BP, suggesting that there was a stage with high sea level and a warm climate when ice sheets shrank in the Northern Hemisphere. The duration of 30–40 ka BP spanned a period in the late Marine Isotope Stage 3(MIS 3) and was in nature an interstadial epoch during the Last Glacial period of the Quaternary. Different from the glacial period with a cold climate, this marine transgression considered as a penultimate higher sea level during the Quaternary remains a puzzle that why the evidence is contrary to the Quaternary glacial theory. It is important to understand sea level rise for these areas sensitively responding to the global changes in the future. To recognize the key issues on sea level changes, the eustatic sea level(H_S) was defined as the glaciation-climateforced sea levels, and the relative sea level change(H_R) was defined as that a sea level record was preserved in sediment that experienced multiple secondary actions of land and sea effects. On the basis as defined above, we constructed multi-level models of climate-driven glacio-eustatic changes and land-sea systems. By integrating data sets from eight borehole cores and prescribing the boundary conditions, we simulated the changes of HS and HR in the East China Sea and southern Yellow Sea areas in the late MIS 3. The marine transgression strata from the borehole core data was identified at ca. 30 m below present sea level as a result of the collective influence of ice melting water, neotectonic subsidence, sediment compaction and terrestrial sediment filling since ca. 35 ka ago,whereas the simulated relative sea-levels turned out to be –26.3––29.9 m a.s.l. The small error involved in the simulation results of ±(2.5–4.5) m demonstrated the credibility of the results. Our results indicated that sea level change in the late MIS 3 was dominated by glacial effects, in which the eustatic sea-level was between –19.2––22.1m a.s.l. The study sheds light on the nature of sea-level changes along the east coast of China in the late MIS 3 and contributes to understanding the characteristics of marine transgression under the effects of multiple complex land-sea interactions.     

Hydrodynamic variations and correlations with Quaternary sea-level change on a rocky coast in Corsica, Western Mediterranean

The stratigraphy of Quaternary marine sediments in Corsica is summarised: Holocene (Versilian) deposits occur at 2–5m and last interglacial sediments (Tyrrhenian Stage) from 2 to 10–15m altitude. Locally, two older deposits, up to 30–40m above present sea-level, indicate the first transgressive phase of the last interglacial stage, and the penultimate interglacial stage.Sections are described where Quaternary hydrodynamic conditions were different from present ones in the same locality. At some sites which are high energy at present, sand deposits and sandstones provide evidence of low or medium energy conditions during the last interglacial and the penultimate interglacial stages. These variations correlate with sea-level changes, particularly at Cala d'Ancone, where sedimentation occurred during the transgressive phase of the interglacial stage, and where cementation terminated during the subsequent regressive phase.The occurrence of pebbles in localities where low energy conditions prevail at present, probably represent fluvial material reworked by wave action, during the last as well as the penultimate interglacial stages.Local variations in hydrodynamic intensity correlate with sea-level changes along the western Corsican shore, although general energy conditions remained constant throughout the interglacial stages.     

Biomarker records,organic carbon accumulation,and river discharge in the Holocene southern Kara Sea (Arctic Ocean)

Within the Russian–German research project on “Siberian River Run-off (SIRRO)” dealing with freshwater discharge and its influence on biological, geochemical, and geological processes in the Kara Sea, sedimentological and organic-geochemical investigations were carried out on two well-dated sediment cores from the Yenisei Estuary area. The main goal of this study was to quantify terrigenous organic carbon accumulation based on biomarker and bulk accumulation rate data, and its relationship to Yenisei river discharge and climate change through Holocene times. The biomarker data in both cores clearly indicate the predominance of terrigenous organic matter, reaching 70–100 and 50–80% of total organic carbon within and directly north of the estuary, respectively. During the last ca. 9 cal ka b.p. represented in the studied sediment section, siliciclastic sediment and (terrigenous) organic carbon input was strongly influenced by postglacial sea-level rise and climate-related changes in river discharge. The mid-Holocene Climatic Optimum is documented by maximum river discharge between 8.2 and 7.3 cal ka b.p. During the last 2,000 years, river discharge probably decreased, and accumulation of both terrigenous and marine organic carbon increased due to enhanced coagulation of fine-grained material.     

Higher plant n-alkane average chain length as an indicator of petrogenic hydrocarbon contamination in marine sediments

The n-alkane average chain length (ACL) is the weight-averaged number of carbon atoms of the higher plant C₂₅–C₃₃ n-alkanes. The abundance of individual n-alkanes from higher plant sources generally increases with increasing carbon number in coastal marine sediments around Taiwan, but this trend is reversed for petrogenic hydrocarbons. The ACL would potentially be lowered if petrogenic hydrocarbons were added to sediments containing biogenic hydrocarbons alone. To test this idea, a marine environment off southwestern Taiwan known to contain both biogenic and petrogenic hydrocarbons and two nearby rivers were selected for investigating possible difference in ACL values between their sediments. The average CPI of C₂₅–C₃₃ n-alkanes was 4.08 ± 2.04 (range 1.90–8.96, n = 15) for the river sediments and 1.70 ± 0.16 (range 1.43–1.97, n = 15) for the marine sediments. The ACL of C₂₅–C₃₃ n-alkanes for river sediments ranged from 29.2 to 30.5 (average 29.9 ± 0.4), and for marine sediments from 28.4 to 29.3 (average 28.9 ± 0.3). The ACL difference between marine and river sediments was significant (Student's t test at 99% confidence) although it appeared small. It is suggested that the ACL can be an additional indicator for detection of petrogenic hydrocarbons in coastal marine sediments.     

Postglacial depositional environments and sedimentation rates in the Norwegian Channel off southern Norway

Based on seismic profiles, multibeam bathymetry and sediment cores, an improved understanding of the deglaciation/postglacial history of the southern part of the Norwegian Channel has been obtained. The Norwegian Channel Ice Stream started to recede from the shelf edge ca. 15.5 ka BP (¹⁴C ages are used throughout). Approximately 500–1000 years later the ice margin was located east of the deep Skagerrak trough. At that time, the Norwegian Channel off southern Norway had become a large fjord-like embayment, surrounded by the grounded ice sheet along the northern slope and possibly stagnant ice remnants at the southern flank. The Norwegian Channel off southern Norway has been the main sediment trap of the North Sea, and south of Egersund more than 200 m of sediments have been deposited since the start of the deglaciation. Five seismic units are mapped. The oldest unit E occurs in some of the deepest troughs, and was deposited immediately after the ice became buoyant. Unit D is acoustically massive and comprises mass-movement deposits in eastern Skagerrak and south of Egersund. Unit C (in the channel southwest of Lista/Egersund) is interpreted to comprise mainly bottom current deposits derived from palaeo-rivers, e.g. Elben. During deposition of unit C (ca. 14.5–13 ka BP), there was limited inflow of Atlantic water. A change in depositional environment at ca. 13 ka BP is related to an increased inflow of saline water and more open hydrographic circulation. Widely distributed, acoustically stratified clays of unit B were deposited ca. 13–10 ka BP. The Holocene Unit A shows a depositional pattern broadly similar to that of unit B.     

High-resolution sediment echosounding off Peru: Late Quaternary depositional sequences and sedimentary structures of a current-dominated shelf

About 6000 km of both bathymetric and high-resolution acoustic profiles were acquired on the shelf and upper slope offshore Peru between 9° S and 14° S. Two new sediment echosounder systems – SEL-96 and SES-2000DS – provided details of the sedimentary structures of the Quaternary sequences within the Sechura-Salaverry, Huacho and Pisco Basins. To a great extent, the poleward undercurrent determines the distribution of sediments. The undercurrent has generated numerous erosional unconformities, it has winnowed hardgrounds and has created mudwaves common between 250 m and 400 m water depth. Distinct subbottom reflectors within sedimentary units represent hiatuses due to periods of intensified winnowing or non-deposition. Erosional unconformities usually marked by pronounced reflectors suggest shifts of the undercurrent system related to climatic changes and eustatic variations of sea level. On a larger scale, the stacked prograding depositional sequences reflect the sea-level cycles of the Middle Pleistocene to the Holocene. Based on the stratigraphy of our piston cores and that of Ocean Drilling Program (ODP) Site 680, the depositional sequences limited by extended unconformities were assigned to oxygen isotope stages 1 to 7. Other sedimentary structures are small straight channels that were conduits for downslope sediment transport. Deformed sediments associated with synsedimentary normal faults result from creep movements indicating beginning slope failure.     

Late Holocene sea-level rise in Tampa Bay: Integrated reconstruction using biomarkers,pollen, organic-walled dinoflagellate cysts,and diatoms

A suite of organic geochemical, micropaleontological and palynological proxies was applied to sediments from Southwest Florida, to study the Holocene environmental changes associated with sea-level rise. Sediments were recovered from Hillsborough Bay, part of Tampa Bay, and studied using biomarkers, pollen, organic-walled dinoflagellate cysts and diatoms. Analyses show that the site flooded around 7.5 ka as a consequence of Holocene transgression, progressively turning a fresh/brackish marl-marsh into a shallow, restricted marine environment. Immediately after the marine transgression started, limited water circulation and high amounts of runoff caused stratification of the water column. A shift in dinocysts and diatom assemblages to more marine species, increasing concentrations of marine biomarkers and a shift in the Diol Index indicate increasing salinity between 7.5 ka and the present, which is likely a consequence of progressing sea-level rise. Reconstructed sea surface temperatures for the past 4 kyrs are between 25 and 26 ° C, and indicate stable temperatures during the Late Holocene. A sharp increase in sedimentation rate in the top ∼50 cm of the core is attributed to human impact. The results are in agreement with parallel studies from the area, but this study further refines the environmental reconstructions having the advantage of simultaneously investigating changes in the terrestrial and marine environment.     

Erosional shelf ridges in the mid-eastern Yellow Sea

In the mid-eastern Yellow Sea, closely spaced high-resolution seismic profiles and a 44-m-long sediment core (YSDP-104) were analyzed to reveal the internal structures and stratigraphy of the shelf ridges currently shaped by tidal currents. Three depositional sequences (sequences I, II and III in descending order) can be recognized. Sequence III, the substratum of the ridges, consists of coarse-grained sediments in the lower part (non-marine deposits) and tide-influenced muddy sediments in the upper part (probable transgressive to highstand systems tract). Sequence II represents internal ridge sediments, similar in character to sequence III, but is demarcated by an undulatory ridge topography. According to radiocarbon dating of marine muds, these sequences range in age from 47,000 to 28,000 years B.P., representing two cycles of short-term sea-level fluctuations during oxygen isotope stage 3. Sequence I consists mostly of late-Holocene transgressive sand veneer on the ridge surface. It also includes minor amounts of early-Holocene muddy sediments occasionally underlying the sand. Most of the ridges are presently undergoing erosion by tidal currents, forming widespread sand dunes on the entire surface.     

Age,regional variation,and shallowest occurrence of S1 sapropel in the northern Aegean Sea

Thirteen gravity cores taken off northern Greece contain the S1 sapropel, as a single layer in cores from water depths <250 m and usually as a double layer in cores from deeper water. Total thickness of the sapropel layer is proportional to thickness of sediment between the sapropel and an 18 ka seismic marker. These observations suggest that the sapropel is not diachronous. Five AMS radiocarbon dates of molluscs and echinoderms indicate an age of 6.4–9.2 ka for the S1 sapropel, considerably younger than previous age estimates in the northern Aegean Sea of 9–13 ka, which were based on bulk sample dating techniques.     

Erosional shelf ridges in the mid-eastern Yellow Sea

In the mid-eastern Yellow Sea, closely spaced high-resolution seismic profiles and a 44-m-long sediment core (YSDP-104) were analyzed to reveal the internal structures and stratigraphy of the shelf ridges currently shaped by tidal currents. Three depositional sequences (sequences I, II and III in descending order) can be recognized. Sequence III, the substratum of the ridges, consists of coarse-grained sediments in the lower part (non-marine deposits) and tide-influenced muddy sediments in the upper part (probable transgressive to highstand systems tract). Sequence II represents internal ridge sediments, similar in character to sequence III, but is demarcated by an undulatory ridge topography. According to radiocarbon dating of marine muds, these sequences range in age from 47,000 to 28,000 years B.P., representing two cycles of short-term sea-level fluctuations during oxygen isotope stage 3. Sequence I consists mostly of late-Holocene transgressive sand veneer on the ridge surface. It also includes minor amounts of early-Holocene muddy sediments occasionally underlying the sand. Most of the ridges are presently undergoing erosion by tidal currents, forming widespread sand dunes on the entire surface.     

Tracking the last sea-level cycle: seafloor morphology and shallow stratigraphy of the latest Quaternary New Jersey middle continental shelf

Seafloor geomorphology and surficial stratigraphy of the New Jersey middle continental shelf provide a detailed record of sea-level change during the last advance and retreat of the Laurentide ice sheet (120 kyr B.P. to Present). A NW–SE-oriented corridor on the middle shelf between water depths of 40 m (the mid-shelf “paleo-shore”) and 100 m (the Franklin “paleo-shore”) encompasses 500 line-km of 2D Huntec boomer profiles (500–3500 Hz), an embedded 4.6 km² 3D volume, and a 490 km² swath bathymetry map. We use these data to develop a relative stratigraphy. Core samples from published studies also provide some chronological and sedimentological constraints on the upper <5 m of the stratigraphic succession.The following stratigraphic units and surfaces occur (from bottom to top): (1) “R”, a high-amplitude reflection that separates sediment >46.5 kyr old (by AMS ¹⁴C dating) from overlying sediment wedges; (2) the outer shelf wedge, a marine unit up to 50 m thick that onlaps “R”; (3) “Channels”, a reflection sub-parallel to the seafloor that incises “R”, and appears as a dendritic system of channels in map view; (4) “Channels” fill, the upper portion of which is sampled and known to represent deepening-upward marine sediments 12.3 kyr in age; (5) the “T” horizon, a seismically discontinuous surface that caps “Channels” fill; (6) oblique ridge deposits, coarse-grained shelly units comprised of km-scale, shallow shelf bedforms; and (7) ribbon-floored swales, bathymetric depressions parallel to modern shelf currents that truncate the oblique ridges and cut into surficial deposits.We interpret this succession of features in light of a global eustatic sea-level curve and the consequent migration of the coastline across the middle shelf during the last 120 kyr. The morphology of the New Jersey middle shelf shows a discrete sequence of stratigraphic elements, and reflects the pulsed episodicity of the last sea-level cycle. “R” is a complicated marine/non-marine erosional surface formed during the last regression, while the outer shelf wedge represents a shelf wedge emplaced during a minor glacial retreat before maximum Wisconsin lowstand (i.e., marine oxygen isotope stage 3.1). “Channels” is a widespread fluvial subarial erosion surface formed at the late Wisconsin glacial maximum 22 kyr B.P. The shoreline migrated back across the mid-shelf corridor non-uniformly during the period represented by “Channels” fill. Oblique ridges are relict features on the New Jersey middle shelf, while the ribbon-floored swales represent modern shelf erosion. There is no systematic relationship between modern seafloor morphology and the very shallowly buried stratigraphic succession.     

Apparent copper complexation capacity and conditional stability constants in north atlantic waters

Surface water samples were collected in the north Atlantic Ocean in July–August 1983. Their apparent complexation capacity for copper (CC_Cu) was determined on board, using differential pulse anodic stripping voltammetry under clean room conditions. Measurements were carried out by direct titrations as well as after equilibration of copper spikes. CC_Cu and conditional stability constants (K′) were calculated, by means of three different methods, which are compared.On the basis of salinity, temperature, silicate and phosphate concentrations the following surface waters could be distinguished: North Atlantic Drift (I), East Greenland Current (II), Labrador Current (III) and Gulf Stream waters (IV, V). CC_Cu and K′ were found to differ between these waters. The range of values for CC_Cu and their mean values given in parentheses, as calculated from van den Berg plots for waters I–IV are: I, 53–65 (59); II, 47–66 (55); III, 37–53 (45); IV, 20–42 (33) nM Cu. The range and mean values for log K′ are: I, 8.23–8.33 (8.28); II, 7.89–8.11 (7.98); III, 8.40–8.41 (8.41); IV, 7.90–8.21 (8.06).Information on complexation kinetics extracted from the titration curve revealed that k_f^′ is area-specific. The complexation rate constant in the northern part (Area I) is about two times larger than that in the southern area IV, (3.6 ± 0.3) and (2.2 ± 0.2) × 10⁴s⁻¹M⁻¹ Cu, respectively.Preliminary results for deep water samples suggest smaller but still existent CC_Cu and higher K′ than those found for surface waters.     

Distribution of the Neogene Utsira Sand and the succeeding deposits in the Viking Graben area, North Sea

The sandy quartzose parts of the Utsira Formation, the Middle Miocene to mid Pliocene Utsira Sand, extends north–south along the Viking Graben near the UK/Norwegian median line for more than 450 km and 75–130 km east–west. The Utsira Sand is located in basin-restricted seismic depocentres, east of and below prograding sandy units from the Shetland Platform area with Hutton Sands. The Utsira Sand reaches thicknesses up to ca. 300 m in the southern depocentre and 200 m in the two northern depocentres with sedimentation rates up to 2–4 cm/ka. Succeeding Plio–Pleistocene is divided into seismic units, including Base Upper Pliocene, Shale Drape, Prograding Complex and Pleistocene. The units mainly consist of clay, but locally minor sands occur, especially at toes of prograding clinoforms (bottom-set sands) and in the Pleistocene parts, and the total thickness covering the Utsira Sand is in most places more than 800 m, but thins towards the margins.     

Using sediment geochemistry to infer temporal variation of methane flux at a cold seep in the South China Sea

Release of methane from the seafloor throughout the world's oceans and the biogeochemical processes involved may have significant effects on the marine sedimentary environment. Identification of such methane release events in marine sediment records can hence provide a window into the magnitude of ancient seeps. Here, we report on analysis of the geochemical composition of samples in a 12.3 m long sediment core (DH-5) collected from a seep site in the South China Sea (SCS). Our aim has been to investigate whether the evidence for the presence of methane release event within sediments is discernible from solid-phase sediment geochemistry. We show that sedimentary total sulfur (TS), δ³⁴S values of chromium reducible sulfur (δ³⁴S_CRS) along with total organic carbon (TOC) and total inorganic carbon (TIC) content can be used to infer the presence of methane release events in cold seep settings. At least three methane release events were identified in the studied core (Unit I at 400–550 cm, Unit II at 740–820 cm, and Unit III at 1000–1150 cm). According to the characteristic of redox-sensitive elements (eg., Mo, U and Mn), we suggest that methane flux has been changed from relatively high (Unit I) to low (Unit II and III) rates. This inference is supported by the coupled occurrence of ³⁴S-enriched sulfides in Unit II and III. AMS ¹⁴C dates from planktonic foraminifera in Unit I suggest that high methane flux event occurred at ∼15.4–24.8 kyr BP, which probably resulted in locally-focused aerobic methane oxidation. Overall, our results suggest that TS, TOC, TIC and δ³⁴S_CRS have potential for identifying present and fossil methane release events in marine sediments.     

Evaluation of atmospheric transport as a nonpoint source of polycyclic aromatic hydrocarbons in marine sediments of the Eastern Mediterranean

Coastal marine sediment, air and seawater samples were collected at six sampling stations in the Eastern Mediterranean Sea distant from pollutant point sources. All sediment samples were analyzed to determine polycyclic aromatic hydrocarbon (PAH), black carbon (BC) and organic carbon (OC) contents. The PAH contents of gaseous and seawater samples of the study were determined in order to evaluate the role of air–sea exchange as PAH nonpoint source to the marine sediments. The average concentration of the total PAHs (∑PAHs) in the sediments varied from 2.2 to 1056.2 ng g⁻¹ dry weight. The average BC and OC contents varied from 0.3 to 5.6 and from 2.9 to 21.4 mg g⁻¹ dry weight, respectively. ∑PAH concentration in the marine atmosphere varied from 20.0 to 83.2 ng m⁻³. Air–water exchange flux (F_A–W) estimation has indicated air transport as a significant source of PAHs to pristine marine sediments of Eastern Mediterranean. In addition, the significant correlation between the PAHs and the organic and soot carbon content further suggests the importance of atmospheric input of PAHs to the sediments.     

Seismic stratigraphy of the quaternary Yellow River delta,Bohai Sea,eastern China

The upper 40 m of stratigraphy of the Yellow River (Huang He) subaqueous delta has been well documented, but the nature of the underlying strata is currently unknown at high-resolution. To address this deficiency we used a Geopulse seismic system to image shallow sedimentary deposits up to 120 m deep on the Yellow River delta. High-resolution seismic reflection images were processed with a series of specific techniques (e.g. swelling attenuation, dynamic s/n filter; f-x deconvolution, predictive deconvolution dipscan stack), and used with borehole data to investigate the Quaternary offshore sequences in the Yellow River (Huang He) delta. Repetitive sequences were observed and interpreted as containing layers of transgressive and regressive deposits. Six seismic transgressive and regressive cycles are identified. Unit M₆F–C₆F correlates with a relative sea-level rise (173–157 ka) and fall (231–173 ka), while Unit M₅F–C₅F is associated with a relative sea-level rise (124–100 ka) and fall (157–124 ka). Unit M₄F–C₄F spans a period of sea-level fall at 100–87 ka, followed by a rise at 87–76 ka. Unit M₃F–C₃F is a transgressive–regressive cycle dated as 76–58 ka. Unit M₂F–C₂F correlates with relative sea level fall at 58.2–36 ka and subsequent rise at 36–22 ka. Unit M₁F–C₁F was deposited during relative sea level fall (22–18 ka), followed by a rise, especially since 8.5 ka.     

Accumulation rate and heavy metal pollution in Osaka Bay sediments

The accumulation rates of sediment cores in Osaka Bay have been determined by using²¹⁰Pb dating technique. In the upper 10 cm²¹⁰Pb_ex contents show a constant value with depth. The accumulation rates below the homogeneous layer of sediments ranging from 0.12 to 0.61cm y^–1 (0.067–0.34 g cm^–2 y^–1) were obtained. The higher contents of Zn, Cu, Pb and Cr were observed in the upper 10 to 30 cm of sediments. Assuming that the increment of heavy metal content in sediments is due to anthropogenic origin, the amount of anthropogenic input of heavy metals into sediments were estimated to be 1,300–2,700g cm^–2 for Zn, 150 – 480 for Cu, 360 – 410 for Pb and 320 – 480 for Cr. The increment appears to start about 100 years ago. In surfical sediments most of heavy metal contents exceeded the background content, and then most part of Osaka Bay is polluted by heavy metals.