Chemistry of the nightside ionosphere of Venus

We have constructed a one-dimensional model of the nightside ionosphere of Venus in which it is assumed that the ionization is maintained by day-to-night transport of atomic ions. Downward fluxes of O⁺, C⁺ and N⁺ in the ratios measured on the dayside at high altitudes are imposed at the upper boundary of the model (about 235 km). We discuss the resulting sources and sinks of the molecular ions NO⁺,CO⁺,N₂⁺,CO₂⁺ and O₂⁺. As the O⁺ flux is increased, the peak density of O⁺ increases proportionally and the altitude of the peak decreases. The O₂⁺ peak density is approximately proportional to the square root of the O⁺ flux and the peak rises as the O⁺ flux increases. NO⁺ densities near the peak are relatively unaffected by changes in the O⁺ flux. If the ionosphere is maintained mostly by transport, the ratio of the peak densities of O⁺ and O₂⁺ indicates the downward flux ofO⁺, independent of the absolute magnitudes of the densities. The densities of mass-28 ions are, however, still considered to be the most sensitive indicator of the importance of electron precipitation. We examine here the inbound and outbound portions of six early nightside orbits with low periapsis and use data from the Pioneer Venus orbiter ion mass spectrometer, the retarding potential analyzer and the electron temperature probe to determine the relative importance of ion transport and electron precipitation. For most of the orbits, precipitation is inferred to be of low to moderate importance. Only for orbit 65, which was the first nightside orbit published by Taylor et al. [J. geophys. Res. 85, 7765 (1980)] and for the inbound portion of orbit 73 does the ionization structure appear to be greatly affected by electron precipitation.     

An auroral F-region study using in situ measurements by the Atmosphere Explorer-C satellite

On 14 July 1974 the Atmosphere Explorer-C satellite flew through an aurora at F-region altitudes just after local midnight. The effects of the particle influx are clearly evident in the ion densities, the 6300 Å airglow, and the electron and ion temperatures. This event provided an opportunity to study the agreement between the observed ion densities and those calculated from photochemical theory using in situ measurements of such atmospheric parameters as the neutral densities and the differential electron energy spectra obtained along the satellite track. Good agreement is obtained for the ions O₂⁺, NO⁺ and N₂⁺ using photochemical theory and measured rate constants and electron impact cross sections. Atomic nitrogen densities are calculated from the observed [NO⁺]/[O₂⁺] ratio. In the region of most intense electron fluxes (20 erg cm⁻² sec⁻¹) at 280 km, the N density is found to be between 2 and 7 × 10⁷ cm⁻³. The resulting N densities are found to account for approx. 60% of the production of N⁺ through electron impact on N and the resonant charge exchange of O⁺(²P) with N(⁴S). This reaction also provides a significant source of O(¹S) in the aurora at F-region altitudes. In the region of intense fast electron influx, the reaction with atomic nitrogen is found to be the main loss of O⁺(²P).     

The winter anomaly in ionospheric absorption and the D-region ion chemistry

A detailed analysis of the D-region ion composition measurements performed by Zbinden et al. (1975), during a winter day of high ionospheric absorption, has been carried out. The study examines the interactive mesosphere-D-region processes which occur in such anomalous conditions and their implication for water cluster ion chemistry. Two clustering regimes for NO⁺ have been observed in the data. Association with N₂ is identified as the dominant process below 76 km. Between 76 and 78 km altitude the effective loss rate of NO⁺ drops by two orders of magnitude. Above 77 km, the three-body reaction NO⁺ + CO₂+M→NO⁺CO₂+M seems to be the main NO⁺ loss. A mesospheric temperature profile could be derived from the ion composition data. This indicates the presence of a strong inversion above 76 km altitude. The wavelike structure obtained, is shown to be consistent with in situ winter temperature measurements. The sharp suppression of the N₂ association reaction could, thus, be explained by an increase in the collisional break-up of the NO⁺N₂ ion because of the enhanced temperature. In conclusion, our study indicates that, besides the increase in the production of NO⁺ and O₂⁺, due to an enhancement in the minor ionizable constituents, an additional thermal mesosphere-D-region interaction seems necessary to explain this winter anomalous ion composition data.     

Combined mass spectrometric composition measurements of positive and negative ions in the lower ionosphere—I. Positive ions

Recent improvements in rocket-borne mass spectrometer technology have made it possible to measure lower ionospheric ions with greater sensitivity and to extend the measurements to lower heights. The improvements made to the instrument and positive ion results from a flight of this instrument will be reported here. In addition to the previously known ions, such as NO⁺(H₂O)_n and H⁺(H₂O)_n, new ion species were found. The total fractional count rate of these ions was found to be constant with height indicating an upper altitude source. Possible identifications of these ions are proposed along with possible production mechanisms.     

Rocket measurements of the 6300 Å and 3914 Å dayglow features

Rocket results are presented on the OI 6300 Å line and on the N₂⁺ 3914 Å band in the dayglow. An altitude range of 78–335 km is covered. Theoretical interpretations are given, using results of simultaneous measurements of electron density and electron temperature. The apparent brightness of the 6300 Å line at the base of the emitting region is found to be 13 kR, of which 5.5 kR are ascribed to excitation through the Schumann-Runge dissociation of O₂ by the solar UV radiations, 0.55 kR to the dissociative recombination of O₂⁺ and NO⁺ ions, and 0.03 kR to the excitation of O by thermal electrons. An additional source of excitation above 280 km is suggested. The deactivation of O(¹D) by O₂(X³Σ_g⁻) is found to be appreciable below 200 km, and its rate coefficient is estimated to be 2 × 10⁻¹⁰ cm³/sec. The apparent brightness of the 3914 Å band at the base of the emitting region is found to be 6.5 kR, decreasing to 3.2 kR at 330 km. Assuming that fluorescent scattering of solar radiation is the mechanism involved the distribution of N₂⁺ ions is calculated. The rate coefficients for the loss of these ions are hence calculated.     

Ionospheric scale height from the refraction of satellite signals

Accurate observations of the elevation angle of arrival of 20 MHz signals from the polar orbiting satellite Beacon-B for a 20 month period have provided transmission ionograms which may be reduced to give H_p, the scale height at the peak of the ionosphere. Noon seasonal averages of H_p are 1.35 (in winter) to 1.55 (in summer) times greater than the scale height obtained from bottom-side ionograms. A comparison of scale height at the peak with routine measurements of total content and peak electron density indicates that the O⁺/H⁺ transition level is above 1000 km during the day but comes down to about 630 km on winter nights. A predawn peak in the overall scale height (∝ total content/peak density) is caused by a lowering of the layer to a region of increased recombination and is magnified in winter by low O⁺/H⁺ transition levels. After sunrise in winter and equinoxes the overall scale height is less than the scale height at the peak, implying an outwards flux of ionisation which lasts for about three hours. The summer evening increase in ƒ₀F2 requires both a cooling and a raising of the layer for its occurrence.     

A study of F2 region night-time vertical ionization fluxes at millstone hill

Vertical fluxes of ionization in the F2 region have been measured by the incoherent scatter technique over Millstone Hill in 1969. The results obtained near midnight for the region above h_maxF2 have been examined to determine whether there is a significant flux of ionization from the magnetosphere to the ionosphere that serves to maintain the F-layer. It is found that H⁺ ions are a minor constituent over the altitude range in which useful measurements can be made, so that any conclusion must rest upon properly interpreting the observed O⁺ fluxes. By selecting periods when the layer did not appear to be decaying rapidly it was hoped to find cases where the O⁺ flux did not vary with altitude in the range 500 h 800 km (i.e. where losses are unimportant), since this would imply that the flux is of magnetospheric origin.

While three cases exhibited this behaviour, the majority exhibited a decrease in the O⁺ flux with height, indicating that the layer was descending. Attempts to correct for this were made, and the average flux from the magnetosphere was estimated as 3 × 10⁷ el/cm²/sec. This is in fair agreement with other recent estimates, and implies that at this latitude the ionosphere is not maintained solely by the magnetospheric flux. Moreover, large increases in flux that could give rise to nocturnal increases in the total content of the layer do not appear to have been seen.     

A theoretical study of the time-dependent behaviour of O in the mid-latitude plasmasphere

The behaviour of O²⁺ at L = 3 in the plasmasphere is studied. Starting with a low O²⁺ flux-tube content to characterize post-magnetic-storm conditions the time-dependent equations of continuity and momentum for O²⁺ are solved to give densities and fluxes for a period of several days using both sunspotmaximum and sunspot-minimum parameters. Our results show large amounts of O²⁺ near the equator at sunspot maximum but relatively little at sunspot minimum, and emphasize the key role of the collisional process between O²⁺ and O⁺. It is the combined effects of O²⁺---O ⁺ collisions and thermal diffusion that lead to the large O²⁺ densities near the equator at sunspot maximum. Both of these mechanisms have less influence at sunspot minimum. At sunspot maximum the O⁺ layer acts as a collisional barrier below the O²⁺ production region preventing O²⁺ from sinking towards regions of high recombination rate. In this production region the effects of thermal diffusion are small and upward flow of O²⁺ results from the action of the O²⁺ pressure gradient and the polarization electric field. When the upward flowing O²⁺ reaches regions in which thermal diffusion has a strong influence it is accelerated to even higher altitudes. The O ⁺ barrier is so effective that the diurnal variation of the O⁺ layer is reflected in the diurnal variation of O²⁺ near the equator at sunspot maximum. Our sunspot maximum results also indicate that certain types of temperature profiles are more likely to enhance equatorial O²⁺ densities. The existence of large temperature gradients below 1000 km altitude does not help the flow of O²⁺ towards the equator. The associated changes in the O⁺ layer lead to more O²⁺-O ⁺collisions and a smaller O²⁺ thermal-diffusion coefficient, the latter being sensitive to the ratio n(H⁺)/n(O⁺).     

C-type shocks in the interstellar medium: profiles of CH+ and CH absorption lines

We have computed optical absorption-line profiles of CH⁺ and CH, as predicted by a model of a C-type shock propagating in a diffuse interstellar cloud. Both these species are produced in the shock wave in the reaction sequence that is initiated by C⁺(H₂, H)CH⁺. Whilst CH⁺ flows at the ion speed, CH, which forms in the dissociative recombination reaction CH⁺₃(e⁻, H₂)CH, flows at a speed which is intermediate between those of the ions and the neutrals. The predicted velocity shift between the CH⁺ and CH line profiles is found to be no more than approximately 2 km s⁻¹, which is smaller than has previously been assumed. We also investigate OH and HCO⁺, finding that the correlation between their column densities, recently observed in the diffuse interstellar medium, can be reproduced by the model.     

Nightside ionosphere of Venus

Venera 9, 10 measurements of the nightside ionospheric profile and the night airglow were used for investigating ionosphere formation processes. The upper ionospheric layer may be formed by HeI 584 Å radiation; the lower layer by meteorite ionization. Upper limits on the electron energy flux, <4 × 10⁸eV cm⁻² s⁻¹, the helium ion flux <10⁷ cm⁻² s⁻¹, the nitric oxide mixing ratio, <1.5 × 10⁻⁴ and the atomic sulphur mixing ratio, <10⁻⁶, are deduced for ionospheric altitudes.     

Hydrogen atoms and ions in the thermosphere and exosphere

The distribution of atomic hydrogen in the thermosphere and exosphere is computed taking into account the upward flow which balances the escape flux. Because of the upward flow the number-density gradient is much steeper than it would be in a static atmosphere. Attention is drawn to the fact that the ratio of the amount of hydrogen above the 100 or 110km levels to the amount of hydrogen above the 200 or 300 km levels is a sensitive measure of the temperature of the exosphere. The evidence on the absolute abundance of atomic hydrogen is examined. It is concluded that the number density at the 120km level is probably about 5 × 10⁵/cm³. The Ly. absorption line at this level is beyond the linear part of the curve of growth.

Consideration is also given to the steady-state distributions of O⁺ and H⁺ ions. In the lower part of the exosphere the number density of O⁺ ions falls with increase in altitude (the associated scale height being twice that of the O atoms) and the number density of H⁺ ions rises at the same rate (as was first pointed out by Dungey). The altitude at which the number densities of O⁺ and H⁺ ions become equal is calculated on various assumptions regarding the temperature and hydrogen content of the exosphere. It is found to be about 1200 km when the temperature is 1250° K and the hydrogen content corresponds to the number density cited near the end of the preceding paragraph. The gradient of the predicted electrondensity distribution at several Earth radii is much less than that deduced from whistler studies.

The passage from charge transfer to diffusive equilibrium is discussed in an Appendix.     

Satellite beacon measurements of protonospheric fluxes

The ionospheric and protonospheric regions of the plasmasphere, which are dominated by the O⁺ and H⁺ ionic species, respectively, interact by means of proton fluxes within tubes of magnetic force. The present study is concerned with the determination of these fluxes by the beacon satellite technique as used in the ATS-6 experiment in relation to three observing sites: Boulder, Colorado; Lancaster, U.K.; and Fairbanks, Alaska. From plasmasphere models based on solutions of the time dependent O⁺ and H⁺ momentum and continuity equations, it is shown that the time differential of the “residual content” as measured at Lancaster, provides a good estimate of the protonospheric flux at 4000km altitude in the L = 1.8 magnetic shell under quite geomagnetic conditions. The effect of the neutral thermospheric wind on the protonospheric flux is also investigated. Fluxes determined by the beacon technique for the period from September 1975 to July 1976 are shown, and these are compared with typical results derived from other techniques.     

Effects of greatly increased O loss in the ionospheric F-region

A model of the ionosphere and plasmasphere is used to study some of the signatures of an idealized SAID (subauroral ion drift) event in the nightside ionosphere. A closed subauroral tube of plasma is considered under solar maximum atmospheric conditions and the westward velocity of 3 km s⁻¹ persists for 30 min. By pursuing, in turn, calculations in which plasma diffusion is suppressed and in which chemical loss of O⁺ is suppressed, the signatures of O⁺ chemistry alone and of field-aligned diffusion alone during the SAID event can be elucidated. Both chemical loss and transport contribute to the decay of the F-layer. Results from full calculations (including both chemistry and transport) demonstrate strong chemical-transport interaction.     

The upper ionospheres of Jupiter and Saturn

We use a 1-D chemical diffusive model, in conjunction with the measured neutral atmospheric structure, to analyze the Voyager RSS electron density, n_e, profiles for the ionospheres of Jupiter and Saturn. As with previous studies we find serious difficulties in explaining the n_e measurements. The model calculates ionospheres for both Jupiter and Saturn with n_e peaks of 10 times the measured peaks at altitudes which are 900–1000 km lower than the altitude of peaks in the RSS electron densities. Based on our knowledge of neutral atmospheric structure, ionization sources, and known recombination mechanisms it seems that, vibrational excitation of H₂ must play some role in the conversion of slowly radiatively recombining H⁺ ions to the relatively more rapidly recombining H₂⁺ and H₃⁺ ions. In addition, vertical ion flow induced by horizontal neutral winds or electric fields probably also play some role in maintaining the plasma peaks observed both for Jupiter and Saturn to be at high altitudes. For the ionosphere of Saturn, the electron densities are affected by a putative influx of H₂O molecules, Φ_H2O, from the rings. To reproduce the RSS V2 exit n_e results model requires an influx of Φ_H2O 2 × 10⁷ molecules cm⁻² s⁻¹ without invoking H_2f vibrational excitation. To maintain the model n_e peak at the measured altitude vertical plasma drift maintained by meridional winds or vertical electric fields is required. The amounts of H₂O are consistent with earlier estimates of Connerney and Waite (1984) and do not violate any observational constraints.     

Twilight effects of solar ionizing radiation

The absorption of solar ionizing radiation during twilight is investigated. Ion production rates are obtained as a function of altitude and twilight intensities and altitude profiles of emissions arising from the fluorescence of solar ionizing radiation are calculated for various solar depression angles. For an atmosphere with an exospheric temperature of 750°K, the predicted overhead intensity from fluorescence of the O⁺(²P — ²D) lines at 7319–7330 diminishes from 175 R at dusk to 10 R at a solar depression angle of 10°. The predicted overhead intensities from fluorescence of the N₂⁺ Meinel and first negative systems are respectively about 175 R and 20 R at dusk diminishing to respectively 1.5 R and 0.1 R at a solar depression angle of 10°.

It is suggested that a charge transfer reaction of O⁺²D in N₂ is a significant source of N₂⁺ ions. This reaction offers a possible explanation for the high apparent rotational temperatures in the first negative system observed by Broadfoot and Hunten. Other excitation and ionization mechanisms are briefly discussed.     

Interpreting vertical plasma drift in the mid-lattitude ionosphere using ionosonde measurements

Measurements of the density at the F₂ peak (N_mF₂) were obtained by the Boulder, Colorado, ionosonde as part of the SUNDIAL-86 campaign. The measurements were made during a period of low to moderate geomagnetic activity following a “disturbed” day. These measurements were then used to estimate the height of the F₂ peak (h_mF₂). A three-dimensional time-dependent model of Earth's ionosphere was used to calculate N_mF₂ and h_mF₂ using the vertical plasma drift as a free parameter. Since the plasmasphere-ionosphere exchange flux can remain upward during the night for these conditions, different feasible flux scenarios were inputed to the ionospheric model. These different flux scenarios had a large effect on the “induced” vertical plasma drifts required to match the measurements (i.e. at times greater than a factor of 2 in speed or a difference in direction). Futhermore, uncertainty in the O⁺---O collision frequency changes the required vertical plasma drift at night. Despite knowledge of h_mF₂, interpretation of the vertical plasma drifts as meridional neutral winds is compromised by a lack of knowledge of the plasmasphere-ionosphere exchange flux following disturbed days.     

Dissociation of the benzene molecule by ultraviolet and soft X-rays in circumstellar environment

Benzene molecules, present in the proto-planetary nebula CRL 618, are ionized and dissociated by ultraviolet (UV) and X-ray photons originated from the hot central star and by its fast wind. Ionic species and free radicals produced by these processes can lead to the formation of new organic molecules. The aim of this work is to study the photoionization and photodissociation processes of the benzene molecule, using synchrotron radiation and time-of-flight mass spectrometry. Mass spectra were recorded at different energies corresponding to the vacuum UV (21.21 eV) and soft X-ray (282–310 eV) spectral regions. The production of ions from the benzene dissociative photoionization is here quantified, indicating that C₆H₆ is more efficiently fragmented by soft X-ray than UV radiation, where 50 per cent of the ionized benzene molecules survive to UV dissociation while only about 4 per cent resist to X-rays. Partial ion yields of H⁺ and small hydrocarbons, such as  C₂H⁺₂, C₃H⁺₃, C₄H⁺₂  , are determined as a function of photon energy. Absolute photoionization and dissociative photoionization cross-sections have also been determined. From these values, half-life of benzene molecule due to UV and X-ray photon fluxes in CRL 618 was obtained.     

First model of negative ion composition in the troposphere

A chemical model of negative ions in the troposhere (0–15 km) is presented. This model is an extension of the negative ion composition model in the lower stratosphere (Kawamoto and Ogawa, 1984, Planet. Space Sci. 32, 1223) with some modifications. The computed result shows that the predominant ions are NO₃⁻HNO₃H₂O below 10km and NO⁻₃(HNO₃)₂ above 10km, and that the fractional abundance of cluster ions having a HSO⁻₄ core increases with height below 12km and decreases with height above it. The ions having CO⁻₃ cores are at most 2% in fractional abundance. The other kinds of negative ions are far smaller in fractional abundance than the NO⁻₃, HSO⁻₄ and CO⁻₃ core ions. The result is compared with the two mass spectrometric observed results (Heitmann and Arnold, 1983, Nature, Lond. 306, 747; Perkins and Eisele, 1984, J. geophys. Res. 89, 9649). The problems on the tropospheric negative ions which arose are discussed.     

Helium ions in the mid-latitude plasmasphere

An initial study of the behaviour of He⁺ ions in the mid-latitude plasmasphere is carried out by solving the time-dependent equations of continuity and momentum. Starting with a low He⁺ tube content, results are obtained for a period of 8 days. In the topside ionosphere there is an upflow of He⁺ during the day and downflow at night, for the sunspot maximum conditions considered. The downflow at night differs from the behaviour of H⁺ for these atmospheric conditions. However, little of the He⁺ produced in the daytime is lost by recombination at night; it is suggested that the supply of He⁺ to the mid-latitude plasmasphere is, in effect, an escape process for neutral helium.     

Deep echelle spectrophotometry of S 311, a Galactic H ii region located outside the solar circle

We present echelle spectrophotometry of the Galactic H  ii region S 311. The data have been taken with the Very Large Telescope Ultraviolet-Visual Echelle Spectrograph in the 3100–10 400 Å range. We have measured the intensities of 263 emission lines; 178 are permitted lines of H⁰, D⁰ (deuterium), He⁰, C⁰, C⁺, N⁰, N⁺, O⁰, O⁺, S⁺, Si⁰, Si⁺, Ar⁰ and Fe⁰; some of them are produced by recombination and others mainly by fluorescence. Physical conditions have been derived using different continuum- and line-intensity ratios. We have derived He⁺, C⁺⁺ and O⁺⁺ ionic abundances from pure recombination lines as well as abundances from collisionally excited lines for a large number of ions of different elements. We have obtained consistent estimations of t ² applying different methods. We have found that the temperature fluctuations paradigm is consistent with the T _e(He  i ) versus T _e(H  i ) relation for H  ii regions, in contrast with what has been found for planetary nebulae. We report the detection of deuterium Balmer lines up to Dδ in the blue wings of the hydrogen lines, whose excitation mechanism seems to be continuum fluorescence.