The Close Association Between Oxidized Magmas and Porhyry Deposits

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Relationships Between the North China Plate and the Tarim Plate

The relationships and boundary between the North China and Tarim plates have been unclear for a long time ; however, the two plates occupy a prominent position in the formation and evolution of the continental lithosphere of China. It is proposed that the Engger Us ophiolitic melange zone discovered recently north of Alaxa is a typical suture between the two plates. The ophiolitic melange zone is composed mainly of a mixture of fragments of ancient oceanic crust and sedimentary rocks of active and passive continental margins. The melange may be divided into tectonic inclusions and matrix. The suture extends northeastwards into the Republic of Mongolia and probably westwards to meet the Altun fault. With the Engger Us ophiolitic melange zone as the boundary the Alaxa area may be divided into two parts: the northern part (AN ) belongs to the Tarim plate, while the southern part (AS) the North China plate. Geological evidence shows that the two plates were amalgamated in the Late Permian or a bit later.     

Interdiffusion of Na,K,and Ca Between Granitic Melts and NaCl Liquid

This study is aimed at determining the diffusion coefficient of net-work modifiers (mainly Na, K, and Ca) in a two-phase melt-NaCl system, in which the melts are granitic and the system is NaCl-rich in composition. The diffusion coefficients of Na, K, and Ca were measured at the temperatures of 750 – 1400°C, pressures of 0.001 × 10⁸ – 2 × 10⁸ Pa, and initial H₂O contents of 0 wt% –6.9 wt% in the granitic melts. The diffusion coefficients of Fe and Mg were difficult to resolve. In all experiments a NaCl melt was present as well. In the absence of H₂O, the diffusion of net-work modifiers follows an Arrhanious equation at 1 × 10⁵ Pa: lgD_ca=−3. 88−5140/T, lgD_k =−3. 79−4040/T, and lgD_Na, =−4.99−3350/T, where D is in cm² /s andT is in K. The diffusion coefficients of Ca, Na, K, and Fe increase non-linearly with increasing H₂O content in the melt. The presence of about 2 wt% H₂O m the melt will lead to a dramatical increase in diffusivity, but higher H₂O content has only a minor effect. This change is probably the result of a change in the melt structure when H₂O is present. The diffusion coefficients measured in this study are significantly different from those in previous works. This may be understood in terms of the “transient two-liquid equilibrium” theory. Element interdiffusion depends not only on its concentration, but also on its activity co-efficient gradient, which is reflected by the distribution coefficient, of the two contacting melts.     

Adsorption of Pentachlorophenol onto Oxide and Clay Minerals： Surface Reaction Model and Environmental Implications

The adsorption of pentachlorophenol （PCP） onto quartz, kaolinite, illite, montmorillonite and iron oxides has been investigated by batch equilibrium techniques. The pH-dependent isotherms are curves with peak values, the position of which is at about pH = 5-6 depending on the mineral species. Based on distribution of both speciation of surface hydroxyls on minerals and PCP in solution a surface reaction model involving surface complexation and surface electrostatic attraction is presented to fit the pH-dependent isotherms, and both reaction constants are calculated. The results show that on quartz and phyllosilicate minerals the predominant adsorption reaction is surface complexation, meanwhile both of surface electrostatic attraction and surface complexation are involved on the iron oxide minerals. The reaction constants of surface electrostatic adsorption are usually one to three orders in magnitude, larger than that of surface complexation. The concentration-dependent isotherms can be well fitted by Langmnir equation with the correlation coefficient R〉0.93 for kaolinite and iron oxides. The maximum adsorption is found in the order： hematite 〉 lepidocrocite 〉 goethite 〉 kaolinite 〉 quartz 〉 montmorillonite ≈ illite, which can be interpreted by consideration of both reaction mechanism and surface hydroxyl density. The significant adsorption of PCP onto mineral surfaces suggests that clay and iron oxide minerals will play an important role as HIOCs are adsorbed in laterite or latertoid soil, which is widespread in South China.     

Between outside and inside? Prison visiting rooms as liminal carceral spaces

This paper suggests that although carceral space seems to be sharply demarcated from the outside world, the prison wall is in fact more porous than might be assumed. The paper critiques Goffman’s theory of the ‘total institution’ by deploying a geographical engagement with liminality to theorise prison visiting rooms as spaces in which prisoners come face-to-face with persons and objects which come from and represent their lives on the ‘outside’. Drawing on a specific empirical example from recent research into imprisonment in the contemporary Russian prison system, it uses the example of visiting suites designed for long term ‘residential’ visits to explore the ways in which visiting spaces act as a space of betweenness where a metaphorical threshold-crossing takes place between outside and inside. The paper specifically explores the expression of that betweenness in the materiality of visiting, and in the destabilisation of rules and identities in visiting space. It contests the sense of linear transformation with which liminal spaces have previously been associated, suggesting that rather than spaces of linear transition from one state to another, liminal spaces can constitute a frustratingly repetitive, static or equilibriating form of transformation which is cumulative rather than immediate, and relates this suggestion to the wider study of prison visitation.     

The Boundary Between Gondwana and Pacifica and the Suturing Ages of Their Allied Terranes in Southwestern China

Two terranes formed since the Late Palaeozoic can be distinguished in southwestern China. One is charac-terized by the Permo-Carboniferous ice-rafted marine gravel-bearing clastic formation and the cold-water faunaof the Gondwana facies, including the Gangmar Co, Lhasa, Sa' gya, Tengchong and Baoshan terranes and theother is marked by the Upper Palaeozoic of the Yangtze type with the Cathaysian flora and the Pacific-typefusulinids, comprising the Changning-Menglian, Shuangjiang-Lancang, Qamdo and Bayan Har terranes. TheLongmu Co-Shuanghu-Dengqen-North Lancang River-Kejie-Mengding suture zone between the two groups ofterranes is the boundary between Gondwana and Pacifica in southwestern China. On the grounds of thesedimentary formation and successive southwestward migration of the Asian nonmarine Jurassic-Cretaceousendemic bivalves, the ages of the suture and some terranes to the southwest of the suture zone are discussed.The Baoshan terrane and the Nyainrong-Sog terrane in the Lhasa composite terrane were firstly pieced togeth-er with the Asian continent in the early Early Jurassic. The northern Tibet-western Yunnan microplate, in-cluding the Gangmar Co, Lhasa and Tengchong terranes, collided with the Asian continent at the end of theEarly Cretaceous Neocomian.     

Similarities Between Granites on the East and West Coasts of the Pacific Ocean

The traditional idea proposes that granites on the east and west coasts of the Pacific Ocean are different. According to field investigations of the geology of the western United States coupled with the authors' long-term studies on granites in South China, granites both in eastern China and in the western United States are similar.     

Slope Instability Zonation: a Comparison Between Certainty Factor and Fuzzy Dempster–Shafer Approaches

This paper presents a comparison between two methodologies for the evaluation of slope instability and the production of instability maps, using a probabilistic approach and a hybrid possibilistic and credibilistic approach. The first is the Certainty Factor method, and the second is based on Fuzzy Logic integrated with the Dempster–Shafer theory. These methodologies are applied to the 1 : 50,000 scale Fabriano (Marche, Italy) geological map sheet. The results are represented as histograms where the accuracy of the prediction is shown, and the comparison of the results of the methods is discussed.     

Research on Relationship Between Fluorine in Tap Water and That in Urine of Chinese Residents

In this study, the relationship between fluorine in drinking water and that in urine of urban residents in China is assessed. Fluorine concentrations in tap water and those in urine show a good correlation with a linear regression coefficient of 0. 9798, indicating that the fluorine concentrations in big cities under investigation are extremely low, and the main source of fluorine is tap water. The weather effect on the intake amount of fluorine is also discussed. When air temperature is above 15℃, people would intake more fluorine through drinking water with the rise of air temperature. When temperature is below 15℃, no remarkable relationship is observed between air temperature and the intake amount of fluorine. This phenomenon indicates that the main source of fluorine in China is tap water instead of foodstuff.     

Water–Rock Interactions: An Investigation of the Relationships Between Mineralogy and Groundwater Composition and Flow in a Subtropical Basalt Aquifer

A holistic study of the composition of the basalt groundwaters of the Atherton Tablelands region in Queensland, Australia was undertaken to elucidate possible mechanisms for the evolution of these very low salinity, silica- and bicarbonate-rich groundwaters. It is proposed that aluminosilicate mineral weathering is the major contributing process to the overall composition of the basalt groundwaters. The groundwaters approach equilibrium with respect to the primary minerals with increasing pH and are mostly in equilibrium with the major secondary minerals (kaolinite and smectite), and other secondary phases such as goethite, hematite, and gibbsite, which are common accessory minerals in the Atherton basalts. The mineralogy of the basalt rocks, which has been examined using X-ray diffraction and whole rock geochemistry methods, supports the proposed model for the hydrogeochemical evolution of these groundwaters: precipitation + CO₂ (atmospheric + soil) + pyroxene + feldspars + olivine yields H₄SiO₄, HCO₃ ⁻, Mg²⁺, Na⁺, Ca²⁺ + kaolinite and smectite clays + amorphous or crystalline silica + accessory minerals (hematite, goethite, gibbsite, carbonates, zeolites, and pyrite). The variations in the mineralogical content of these basalts also provide insights into the controls on groundwater storage and movement in this aquifer system. The fresh and weathered vesicular basalts are considered to be important in terms of zones of groundwater occurrence, while the fractures in the massive basalt are important pathways for groundwater movement.     

Reaction textures and P–T conditions of Opx-Crd gneisses from Karimnagar, Andhra Pradesh, India

Summary The Karimnagar granulite terrain is an integral part of the Eastern Dharwar Craton (EDC). It has received much interest because of the only reported granulite facies rocks in the EDC. These granulites contain quartz-free sapphirine-spinel-bearing granulites, kornerupine – bearing granulites, mafic granulites, orthopyroxene-cordierite gneisses, charnockites, amphibolites, dolerite dykes, granite gneisses, quartzites and banded magnetite quartzite. The orthopyroxene-cordierite gneisses occur as enclaves within granite-gneiss in association with banded magnetite quartzites, charnockites and amphibolites. The observed reaction textures, spectacular as they are, have an extraordinary information content within a tiny domain. Coronas, symplectites and resorption textures are of particular interest as they reflect discontinuous or continuous reactions under changing physical conditions. The main mineral assemblages encountered in these gneisses are orthopyroxene – cordierite – biotite – plagioclase – perthite – quartz and garnet – orthopyroxene – cordierite – biotite – quartz – plagioclase – perthite ± sillimanite. Multiphase reaction textures in conjunction with mineral chemical data in the KFMASH system indicate the following reactions: Based on chemographic relationships and petrogenetic grids in the K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O (KFMASH) system, a sequence of prograde (early stage), isothermal decompression (middle stage) and retrograde (late stage) reactions (‘back reactions’ and hydration reactions) are inferred. Relatively lower P–T estimates (0.35 GPa/550–750 °C) obtained from the different geothermobarometers are attributed to late Fe–Mg re-equilibration during cooling. Therefore, the convergence method has been applied to retrieve simultaneously the P–T conditions of the thermal peak of metamorphism. The near thermal peak condition of metamorphism estimated by the convergence method are 850 °C/0.62 GPa. The P–T estimates define a retrograde trajectory with substantial decompression.     

Experimental Study of the Melting Reaction and Genetic Mechanism of Mineral Phase Transformation in Granulite Facies Metamorphism

The high-temperature and high-pressure experiment on natural block rock indicates that dehydration-melting of hydrous biotite (Bi) and partial melting of felsic minerals in garnet-biotite-plagioclase gneiss are mainly controlled by temperature, while mineral phase transformation is not only controlled by temperature-pressure conditions but also genetically associated with hydrous mineral dehydration-melting and partial melting of felsic minerals. According to the characteristics of biotite dehydration-melting and garnet transformation reaction, three stages may be distinguished: (1) when the experimental temperature is 700℃, biotite transforms to ilmenite (Ilm) + magnetite (Mt) + H2O and garnet to magnetite (Mt); (2) when the temperature is 730-760℃, biotite is dehydrated and melted and transformed into K2O-rich melt + Ilm + Mt, and garnet, into hypersthene (Hy) + cordierite (Crd); (3) when the temperature is up to or higher than 790℃, biotite is dehydrated and melted and transformed into melt + Hy +     

Genetic Analogy Between Sediment—Hosted Gold Deposits and Sediment—Hosted Copper Deposits in Southwest China

The sediment-hosted copper deposits according to the authors‘ study were formed from connate formation water during the post-sedimentary or diagenetic stage while the sediment-hosted disseminated gold deposits are unanimously considered to be of post-sedimentary hydrothermal origin.Therefore,apart from their own individulities.These two types of deposits must share some characters in common.Comparisons are attempted,in this paper,between the sediment-hosted copper deposits in southwest China and the Triassic sediment-hosted disseminated gold deposits in the Yunnan-Guizhou-Guangxi Triangle in terms of geological and geochemical features.     

Genetic Relationship Between the Shapinggou Porphyry Molybdenum and the Polymetallic Vein Deposits, Jinzhai County, Anhui Province

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Relationship Between the Geometric Parameters of Rock Fractures,the Size of Percolation Clusters and REV

Modeling fractured rocks with numerical methods requires some derived parameters, among which the fracture network connectivity and the size of the representative elementary volume (REV) are both of crucial importance. Percolation and REV analyses were made by the RepSim code. The program uses input parameters such as fractal dimension of the fracture midpoints (D _c), length exponent (E) and relative dip (α ^r) data. For percolation analysis, the relative sizes of the largest percolation clusters have been calculated by stochastic realizations of the simulated fracture networks with different parameter triplets. Furthermore, fracture networks can be classified into three major types on the basis of their (E,D _c,α ^r) parameters. For the REV calculations, the porosity of the generated fracture network was calculated. The derived REV size of a fracture network depends essentially on input parameters and shows a decreasing tendency with increasing D and E and vice versa. The method mentioned above was tested on both metamorphic samples of the Pannonian Basin and Variscan granitoid rocks of the Mórágy Complex. Percolation values predicted for the Mórágy granite are highly sensitive to alterations in the input parameters. The amphibolite bodies displayed a modeled fracture network with 80 to 90% of all fractures being interconnected, while the largest achievable percolation cluster size of gneiss is less than 10%. The REV size of the amphibolite is about 20 m as a result of connected fractures filling the whole body, while gneiss has lower porosity and higher REV (approximately 70 m).     

Discrimination Study on Fluid—Rock Interaction Between Metallogenic and Non—Metallogenic Sections in a Shear Zone

Discriminations in a local chemical,fluidal,mechanical and thermal processes in a shear zone will lead to metallogenic differentiation in a local section.This paper,based on the general geological setting of the Shibangou gold deposit in Xixia,Henan,deals with petrological and petrochemical samples of altered rocks in the metallogenic section and of mylonites in the non-metallogenic section of a selected shear zone.The discriminations in fluid-rock interaction and petrological mass balance between altered rocks near the orebody and mylonites in the shear zone are discussed as well.The results show that the petrological volume of altered rocks in the metallogenic section of the shear zone is almost always dilatant and the mylonite volume in the non-metallogenic section is almost always lost.Major elements in altered rocks from the metallogenic section and in mylonites from the non-metallogenic section always show a tendency of being enriched and depleted,respectively.Fluid-rock ratios in the mylonites(Nu=93.68-468.40)are larger than those of the altered rocks(NC(Ⅳ）^s=36.11-216.67).The gain and loss of major and trace elements from the altered rocks and mylonites in the shear zone are a composite process to be imported and exported by percolating fluids as well as of the loss and dilatancy of rock volume.     

The Relationship Between Mineralogical Characteristics and Isotopic Composition of Sphalerite,as Exemplified by the Huxu Deposit,China

The relationship between mineralogical characteristics and isotopic composition of sulfides has not received its proper share of attention from geologists, although many references are available concerning the application of sulfur isotopes to geological problems. Located in the vicinity of the contact region between the Yangtze Platform and the South China Caledonian Folding Zone, the Huxu deposit is hosted in a structural zone in quartz-diorite-porphyrite emplaced in Jurassic volcanic rocks. Sphalerite and galena are the principal ore minerals in the deposit. (1) Sphalerite is highly variable in color and this variation can be related to its chemical composition and sulfur isotopic characters. Dark colored sphalerites are poor in Zn and Ni, rich in Pb, Cu, Fe, Ag and Au and have high δ³⁴S values, while the opposite is true for light-colored ones. (2) δ³⁴S of sphalerite is negatively correlated with the contents of Zn and Ni and positively correlated with the contents of Pb, Cu, Ag and Au, with the absolute values of the correlation coefficients being greater than 0.7. The above two characters suggest that the sulfur isotopic composition of sphalerite is controlled not only by the physicochemical conditions under which the mineral was formed, but also by mineralogical characteristics of the host mineral. (3) Apparent correlations exist among the constituent elements in the sphalerite. For example, Zn is negatively correlated with Cu, Pb, Fe, Ag and Au and positively correlated with Ni. (4) Sphalerites of the same color in the same hand specimen always show similar characters with respect to trace element and sulfur isotopes. (5) Two distinct trends of evolution can be recognized between Zn and Cu, Zn and Pb, Zn and Ag and between these elements on one hand and δ³⁴S on the other, reflecting that the ore-forming solutions may have resulted from mixing of fluids of different origins. (6) Pb is uniformly distributed in sphalerite and shows positive correlations with Cu, Fe, Ag and δ³⁴S, suggesting isomorphic substitution in the sphalerite lattice. This project was financially supported by the Open Laboratory of Ore Deposit Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences.     

Comparison Between Stress and Strain Quantities of the Failure–Deformation Process of Fennoscandian Hard Rocks Using Geological Information

The aim of this paper was to compare the stress and strain quantities that are related to the failure–deformation process of hard rock. The data used here was obtained from laboratory uniaxial compression tests performed on different types of Fennoscandian hard rocks. The failure–deformation process quantities were compared at each deformation stage and for each single specimen. Moreover, geological information such as the rock origin process and the rock characteristics of the specimens were studied and linked to the stress and strain quantities. The purpose was to investigate the influence of the rock origin process and rock characteristics on these quantities. The main results of this study showed that the normalized crack damage lateral strain (ε _3cd/ε _3p ) and the volumetric strain (ε _crv?ci and ε _v?cd) quantities were strongly affected by the grain size. The normalized and volumetric quantities are weakly dependent on the mineral composition.