Isotope fractionation and concentration measurements of Zn in meteorites determined by the double spike,IDMS‐TIMS techniques

Abstract– The isotope fractionation of Zn in meteorites has been measured for the first time using thermal ionization mass spectrometry and a double spiking technique. The magnitude of δZn ranged from ?0.29 to +0.38‰ amu^?1 for five stone meteorites whereas the iron meteorite Canyon Diablo displays δZn of 1.11 ± 0.11‰ amu^?1. The results for chondrites in this work can be divided into positive and negative δZn, supporting a previous proposal that chondrites are a mixture of materials from two different temperature sources. The Zn isotope fractionation present in meteorites may represent a primordial heterogeneity formed in the early solar system. An anomalous isotopic composition of Zn obtained for the Redfields iron meteorite suggests large‐scale inherited isotope heterogeneity of the protosolar nebula, or the presence of a parent body that has formed within its own isotopically anomalous reservoir. These anomalies are in the same direction but smaller than nuclear field shift effects observed in chemical exchange reactions. The isotope dilution mass spectrometry (IDMS) technique was used to measure Zn concentration, yielding a range from 20.1 μg g^?1 to 302 μg g^?1 in five stone meteorites and from 0.019 to 26 μg g^?1 in seven iron meteorites. The IDMS‐measured abundance of Zn in Orgueil is 302 ± 14 μg g^?1 and should be considered for future compilations of the abundance of Zn in the solar system.     

Oxygen isotope systematics of chondrule olivine,pyroxene, and plagioclase in one of the most pristine CV3Red chondrites (Northwest Africa 8613)

We performed in situ oxygen three‐isotope measurements of chondrule olivine, pyroxenes, and plagioclase from the newly described CV_Red chondrite NWA 8613. Additionally, oxygen isotope ratios of plagioclase in chondrules from the Kaba CV3_OxB chondrite were determined to enable comparisons of isotope ratios and degree of alteration of chondrules in both CV lithologies. NWA 8613 was affected by only mild thermal metamorphism. The majority of oxygen isotope ratios of olivine and pyroxenes plot along a slope‐1 line in the oxygen three‐isotope diagram, except for a type II and a remolten barred olivine chondrule. When isotopic relict olivine is excluded, olivine, and low‐ and high‐Ca pyroxenes are indistinguishable regarding Δ¹⁷O values. Conversely, plagioclase in chondrules from NWA 8613 and Kaba plot along mass‐dependent fractionation lines. Oxygen isotopic disequilibrium between phenocrysts and plagioclase was caused probably by exchange of plagioclase with ¹⁶O‐poor fluids on the CV parent body. Based on an existing oxygen isotope mass balance model, possible dust enrichment and ice enhancement factors were estimated. Type I chondrules from NWA 8613 possibly formed at moderately high dust enrichment factors (50× to 150× CI dust relative to solar abundances); estimates for water ice in the chondrule precursors range from 0.2× to 0.6× the nominal amount of ice in dust of CI composition. Findings agree with results from an earlier study on oxygen isotopes in chondrules of the Kaba CV chondrite, providing further evidence for a relatively dry and only moderately high dust‐enriched disk in the CV chondrule‐forming region.     

Tungsten isotopes in bulk meteorites and their inclusions—Implications for processing of presolar components in the solar protoplanetary disk

We present high precision, low‐ and high‐resolution tungsten isotope measurements of iron meteorites Cape York (IIIAB), Rhine Villa (IIIE), Bendego (IC), and the IVB iron meteorites Tlacotepec, Skookum, and Weaver Mountains, as well as CI chondrite Ivuna, a CV3 chondrite refractory inclusion (CAI BE), and terrestrial standards. Our high precision tungsten isotope data show that the distribution of the rare p‐process nuclide ¹⁸⁰W is homogeneous among chondrites, iron meteorites, and the refractory inclusion. One exception to this pattern is the IVB iron meteorite group, which displays variable excesses relative to the terrestrial standard, possibly related to decay of rare ¹⁸⁴Os. Such anomalies are not the result of analytical artifacts and cannot be caused by sampling of a protoplanetary disk characterized by p‐process isotope heterogeneity. In contrast, we find that ¹⁸³W is variable due to a nucleosynthetic s‐process deficit/r‐process excess among chondrites and iron meteorites. This variability supports the widespread nucleosynthetic s/r‐process heterogeneity in the protoplanetary disk inferred from other isotope systems and we show that W and Ni isotope variability is correlated. Correlated isotope heterogeneity for elements of distinct nucleosynthetic origin (¹⁸³W and ⁵⁸Ni) is best explained by thermal processing in the protoplanetary disk during which thermally labile carrier phases are unmixed by vaporization thereby imparting isotope anomalies on the residual processed reservoir.     

Chondrule and metal grain size sorting from jet flows

Abstract— We examine the size sorting of chondrules and metal grains within the context of the jet flow model for chondrule/CAI formation. In this model, chondrules, CAIs, AOAs, metal grains, and related components of meteorites are assumed to have formed in the outflow region of the innermost regions of the solar nebula and then were ejected, via the agency of a bipolar jet flow, to outer regions of the nebula. We wish to see if size sorting of chondrules and metal grains is a natural consequence of this model. To assist in this task, we used a multiprocessor system to undertake Monte Carlo simulations of the early solar nebula. The paths of a statistically significant number of chondrules and metal grains were analyzed as they were ejected from the outflow and travelled over or into the solar nebula. For statistical reasons, only distances ≤3 AU from the Sun were examined. Our results suggest that size sorting can occur provided that the solar nebula jet flow had a relatively constant flow rate as function of time. A constant flow rate outflow produces size sorting, but it also produces a sharp size distribution of particles across the nebula and a metal‐rich Fe/Si ratio. When the other extreme of a fully random flow rate was examined, it was found that size sorting was removed, and the initial material injected into the flow was simply spread over most of the the solar nebula. These results indicate that the outflow can act as a size and density classifier. By simply varying the flow rate, the outflow can produce different types of proto‐meteorites from the same chondrule and metal grain feed stock. As a consequence of these investigations, we observed that the number of particles that impact into the nebula drops off moderately rapidly as a function of distance r from the Sun. We also derive a corrected form of the Epstein stopping time.     

Outward transport of CAIs during FU‐Orionis events

Abstract— Evidence from meteorites shows that the first solids to form in the solar system, calcium‐aluminum‐rich inclusions (CAIs), were transported outward from the Sun by several AU in the early solar system. We introduce a new concept of levitation and outward transport of CAIs at the surface of protoplanetary disks. Thermal radiation from the disk and the Sun can cause particles to levitate above the disk and drift outward through a process known as photophoresis. During normal conditions this process only works for dust‐sized particles but during high luminosity events like FU‐Orionis outbursts, the process can provide an efficient lift and transport of CAIs from within the inner 1 AU to a distance of several AU from the Sun. This might explain why CAIs, believed to have formed close to the Sun, are common in meteorites believed to come from the outer asteroid belt but are rare or absent in samples from the inner solar system. Since the process only works during the FU‐Orionis event and only for particles up to cm‐size, it may also explain why the CAIs we find in meteorites appear to have formed within a short period of time and why they rarely exceed cm size.     

Extraterrestrial amino acids and L‐enantiomeric excesses in the CM2 carbonaceous chondrites Aguas Zarcas and Murchison

The abundances, distributions, enantiomeric ratios, and carbon isotopic compositions of amino acids in two fragments of the Aguas Zarcas CM2 type carbonaceous chondrite fall and a fragment of the CM2 Murchison meteorite were determined via liquid chromatography time‐of‐flight mass spectrometry and gas chromatography isotope ratio mass spectrometry. A suite of two‐ to six‐carbon aliphatic primary amino acids was identified in the Aguas Zarcas and Murchison meteorites with abundances ranging from ~0.1 to 158 nmol/g. The high relative abundances of α‐amino acids found in these meteorites are consistent with a Strecker‐cyanohydrin synthesis on these meteorite parent bodies. Amino acid enantiomeric and carbon isotopic measurements in both fragments of the Aguas Zarcas meteorites indicate that both samples experienced some terrestrial protein amino acid contamination after their fall to Earth. In contrast, similar measurements of alanine in Murchison revealed that this common protein amino acid was both racemic (D ≈ L) and heavily enriched in ¹³C, indicating no measurable terrestrial alanine contamination of this meteorite. Carbon isotope measurements of two rare non‐proteinogenic amino acids in the Aguas Zarcas and Murchison meteorites, α‐aminoisobutyric acid and D‐ and L‐isovaline, also fall well outside the typical terrestrial range, confirming they are extraterrestrial in origin. The detections of non‐terrestrial L‐isovaline excesses of ~10–15% in both the Aguas Zarcas and Murchison meteorites, and non‐terrestrial L‐glutamic acid excesses in Murchison of ~16–40% are consistent with preferential enrichment of circularly polarized light generated L‐amino acid excesses of conglomerate enantiopure crystals during parent body aqueous alteration and provide evidence of an early solar system formation bias toward L‐amino acids prior to the origin of life.     

Oxygen isotopic and chemical zoning of melilite crystals in a type A Ca‐Al‐rich inclusion of Efremovka CV3 chondrite

Abstract– Different oxygen isotopic reservoirs have been recognized in the early solar system. Fluffy type A Ca‐Al‐rich inclusions (CAIs) are believed to be direct condensates from a solar nebular gas, and therefore, have acquired oxygen from the solar nebula. Oxygen isotopic and chemical compositions of melilite crystals in a type A CAI from Efremovka CV3 chondrite were measured to reveal the temporal variation in oxygen isotopic composition of surrounding nebular gas during CAI formation. The CAI is constructed of two domains, each of which has a core‐mantle structure. Reversely zoned melilite crystals were observed in both domains. Melilite crystals in one domain have a homogeneous ¹⁶O‐poor composition on the carbonaceous chondrite anhydrous mineral (CCAM) line of δ¹⁸O = 5–10‰, which suggests that the domain was formed in a ¹⁶O‐poor oxygen isotope reservoir of the solar nebula. In contrast, melilite crystals in the other domain have continuous variations in oxygen isotopic composition from ¹⁶O‐rich (δ¹⁸O = ?40‰) to ¹⁶O‐poor (δ¹⁸O = 0‰) along the CCAM line. The oxygen isotopic composition tends to be more ¹⁶O‐rich toward the domain rim, which suggests that the domain was formed in a variable oxygen isotope reservoir of the solar nebula. Each domain of the type A CAI has grown in distinct oxygen isotope reservoir of the solar nebula. After the domain formation, domains were accumulated together in the solar nebula to form a type A CAI.     

The abundance and isotopic composition of Cd in iron meteorites

Cadmium is a highly volatile element and its abundance in meteorites may help better understand volatility‐controlled processes in the solar nebula and on meteorite parent bodies. The large thermal neutron capture cross section of ¹¹³Cd suggests that Cd isotopes might be well suited to quantify neutron fluences in extraterrestrial materials. The aims of this study were (1) to evaluate the range and magnitude of Cd concentrations in magmatic iron meteorites, and (2) to assess the potential of Cd isotopes as a neutron dosimeter for iron meteorites. Our new Cd concentration data determined by isotope dilution demonstrate that Cd concentrations in iron meteorites are significantly lower than in some previous studies. In contrast to large systematic variations in the concentration of moderately volatile elements like Ga and Ge, there is neither systematic variation in Cd concentration amongst troilites, nor amongst metal phases of different iron meteorite groups. Instead, Cd is strongly depleted in all iron meteorite groups, implying that the parent bodies accreted well above the condensation temperature of Cd (i.e., ≈650 K) and thus incorporated only minimal amounts of highly volatile elements. No Cd isotope anomalies were found, whereas Pt and W isotope anomalies for the same iron meteorite samples indicate a significant fluence of epithermal and higher energetic neutrons. This observation demonstrates that owing to the high Fe concentrations in iron meteorites, neutron capture mainly occurs at epithermal and higher energies. The combined Cd‐Pt‐W isotope results from this study thus demonstrate that the relative magnitude of neutron capture‐induced isotope anomalies is strongly affected by the chemical composition of the irradiated material. The resulting low fluence of thermal neutrons in iron meteorites and their very low Cd concentrations make Cd isotopes unsuitable as a neutron dosimeter for iron meteorites.     

Non-thermal water loss of the early Mars: 3D multi-ion hybrid simulations

In this study we analyze the non-thermal loss rates of O⁺, O₂⁺ and CO₂⁺ ions over the last 4.5 billion years (Gyr) in the Martian history by using a 3D hybrid model. For this reason we derived the past solar wind conditions in detail. We take into account the intensified particle flux of the early Sun as well as an Martian atmosphere, which was exposed to a sun's extreme ultraviolet (EUV) radiation flux 4.5 Gyr ago that was 100 times stronger than today. Furthermore, we model the evolution of the interplanetary magnetic field by a Weber & Davis solar wind model. The ‘external’ influences of the Sun's radiation flux and solar wind flux lead to the formation of an ionospheric obstacle by photoionization, charge exchange and electron impact. For the early Martian conditions we could show that charge exchange was the dominant ionization mechanism. Several hybrid simulations for different stages in the evolution of the Martian atmosphere, at 1, 2, 5, 10, 30 and 100 EUV, were performed to analyze the non-thermal escape processes by ion pick-up, momentum transfer from the solar wind to the ionosphere and detached ionospheric plasma clouds. Our results show a non-linear evolution of the loss rates. Using mean solar wind parameters the simulations result in an oxygen loss equivalent to the depth of a global Martian ocean of about 2.6 m over the last 4.5 Gyr. The induced magnetic field strength could be increased up to about 2000 nT. A simulation run with high solar wind density results in an oxygen loss of a Martian ocean up to 205 m depth during 150 million years after the sun reached the zero age mean sequence (ZAMS).     

X-ray emission from young stars and implications for the early solar system

Recent observations of soft X-ray emission from solar-type stars obtained with the Einstein X-Ray Observatory indicate that X-ray luminosity is inversely correlated with stellar age. If this result is applied to the Sun and if X-ray emission is a valid indicator of other manifestations of solar activity, then past solar wind and flare levels can be inferred. It can qualitatively explain the excess xenon and nitrogen found in the lunar regolith compared to the level expected from the comteporary solar wind. X-Ray emission from T Tauri and other low-mass pre-main-sequence stars is both highly luminous and variable, indicating the presence of flares ～4 × 10³ times stronger than the largest flares seen in the contemporary Sun. The proton flux from such solar flares during the 10⁶ to 10⁷-year pre-main-sequence phase would be sufficient to account for the ²⁶Al anomaly n meteorites.     

New triple oxygen isotope data of bulk and separated fractions from SNC meteorites: Evidence for mantle homogeneity of Mars

We report precise triple oxygen isotope data of bulk materials and separated fractions of several Shergotty–Nakhla–Chassigny (SNC) meteorites using enhanced laser‐assisted fluorination technique. This study shows that SNCs have remarkably identical Δ¹⁷O and a narrow range in δ¹⁸O values suggesting that these meteorites have assimilated negligibly small surface materials (<5%), which is undetectable in the oxygen isotope compositions reported here. Also, fractionation factors in coexisting silicate mineral pairs (px‐ol and mask‐ol) further demonstrate isotopic equilibrium at magmatic temperatures. We present a mass‐dependent fractionation line for bulk materials with a slope of 0.526 ± 0.016 (1SE) comparable to the slope obtained in an earlier study (0.526 ± 0.013; Franchi et al. 1999). We also present a new Martian fractionation line for SNCs constructed from separated fractions (i.e., pyroxene, olivine, and maskelynite) with a slope of 0.532 ± 0.009 (1SE). The identical fractionation lines run above and parallel to our terrestrial fractionation line with Δ¹⁷O = 0.318 ± 0.016‰ (SD) for bulk materials and 0.316 ± 0.009‰ (SD) for separated fractions. The conformity in slopes and Δ¹⁷O between bulk materials and separated fractions confirm oxygen isotope homogeneity in the Martian mantle though recent studies suggest that the Martian lithosphere may potentially have multiple oxygen isotope reservoirs.     

Can lightning produce significant levels of mass‐independent oxygen isotopic fractionation in nebular dust?

Based on recent evidence that oxide grains condensed from a plasma will contain oxygen that is mass‐independently fractionated compared to the initial composition of the vapor, we present a first attempt to evaluate the potential magnitude of this effect on dust in the primitive solar nebula. This assessment relies on previous studies of nebular lightning to provide reasonable ranges of physical parameters to form a very simple model to evaluate the plausibility that lightning could affect a significant fraction of nebular dust and that such effects could cause a significant change in the oxygen isotopic composition of solids in the solar nebula over time. If only a small fraction of the accretion energy is dissipated as lightning over the volume of the inner solar nebula, then a large fraction of nebular dust will be exposed to lightning. If the temperature of such bolts is a few percent of the temperatures measured in terrestrial discharges, then dust will vaporize and recondense in an ionized environment. Finally, if only a small average decrease is assumed in the ¹⁶O content of freshly condensed dust, then over the last 5 Myr of nebular accretion the average Δ¹⁷O of the dust could increase by more than 30 per mil. We conclude that it is possible that the measured “slope 1” oxygen isotope line measured in meteorites and their components represents a time‐evolution sequence of nebular dust over the last several million years of nebular evolution where ¹⁶O‐rich materials formed first, then escaped further processing as the average isotopic composition of the dust gradually became increasingly depleted in ¹⁶O.     

The termination of the solar wind

It has previously been suggested that the solar wind might terminate at distances of 5 AU to 20 AU from the Sun, and that the solar wind might be drastically slowed down by charge exchange and photoionization of interstellar hydrogen atoms which approach the Sun. However, recent satellite measurements of resonantly scattered Lyman alpha radiation, together with pulsar dispersion and Faraday rotation measures, imply very small values for the interstellar hydrogen density (0.05 cm⁻³) and magnetic field strength (3 μG). As a result, the solar wind is not expected to be slowed down by more than about 30% inside the termination distance, which is expected to be about 100 AU.     

Photochemical fractionation of16O in the space medium modeled by resonance excitation of CO by H-Lyman α

Inferences about the formation of primordial matter in our solar system rest on analysis of the earliest preserved materials in meteorites, of the structure of the solar system today, and of matter in evolving stellar systems elsewhere.The isotope distribution in meteorites suggests that molecular excitation processes similar to those observed today in circumstellar regions and dark interstellar clouds were operating in the early solar nebula. Laboratory model experiments together with these observations give evidence on the thermal state of the source medium from which refractory meteoritic dust formed. They indicate that resonance excitation of the broad isotopic bands of molecules such as¹²C¹⁶O, MgO, O₂, AlO, and OH by strong UV line sources such as H-L, MgII, H, and CaII may induce selective reactions resulting in the anomalous isotopic composition of oxygen and possibly other elements in refractory oxide condensates in meteorites.     

Evidence for lithium and boron from star‐forming regions implanted in presolar SiC grains

Abstract— We report the first measurements of lithium and boron isotope ratios and abundances measured in “gently separated” presolar SiC grains. Almost all analyses of presolar SiC grains since their first isolation in 1987 have been obtained from grains that were separated from their host meteorite by harsh acid dissolution. We recently reported a new method of “gently” separating the grains from meteorites by using freeze‐thaw disaggregation, size, and density separation to retain any nonrefractory coatings or alteration to the surfaces of the grains that have been acquired in interstellar space. Nonrefractory coats or amorphized surfaces will almost certainly be removed or altered by the traditional acid separation procedure. High Li/Si and B/Si ratios of up to ～10^?2 were found implanted in the outer 0.5 μm of the grains dropping to ～10^?5 in the core of the grains. ⁷Li/⁶Li and ¹¹B/¹⁰B ratios indistinguishable from solar system average values were found. Analyses obtained from SiC grains from the acid dissolution technique showed isotope ratios that were the same as those of gently separated grains, but depth profiles that were different. These results are interpreted as evidence of implantation of high velocity (1200–1800 km s^?1) Li and B ions into the grains by shock waves as the grains traveled through star‐forming regions some time after their condensation in the outflow of an AGB star that was their progenitor. The results are in line with spectroscopic measurements of Li and B isotope ratios in star‐forming regions and may be used to infer abundances and isotopic sources in these regions.     

Solar system isotopic anomalies: Supernova neighbor or presolar carriers?

I evaluate several nuclear and chemical problems related both to the recent scenario suggesting that the known isotopic anomalies in the solar system have resulted from a supernova near the protosolar nebula and to the model of extinct presolar carriers. Major features include: (1) Large quantities of extinct ²⁴⁸Cm and ³⁶Cl are predicted from the Cameron-Truran model of a minor injection about 10⁶ yr before condensation; (2) an extinct-carrier model of ²⁶Mg is set forth in detail with a solid chemistry picture of the early solar system; (3) a major thermonuclear supernova responsible for ²⁶Al, ²⁴⁴Pu, and ⁴⁰K would have to have occurred several million years (3 m.y.) before condensation and contributed a large fraction of the major stable chemical elements; (4) carbon isotope families are to be expected if the oxygen isotope families are due to a late injection of ¹⁶O; (5) the Earth and E meteorites may have condensed primarily in a carbon-rich nebula existing before admixtures of a major late ¹⁶O-rich mixture; (6) the extinct-presolar-carrier model is the single best explanation of all anomalies.     

Interaction of relativistic dust grains with the solar radiation field

The effects of the solar radiation field on the propagation of relativistic dust grains are evaluated. It is concluded that relativistic iron grains with energies 10¹⁹ eV will melt in the solar radiation field before they reach the Earth's orbit around the Sun. However iron grains with lower energies will reach the Earth's orbit but grains travelling from the direction of the Sun will melt. This directional anisotropy or fingerprint may be used to search for relativistic dust grains in the primary cosmic rays. The fact that no significant solar system anisotropy has been detected places constraints on the hypothesis that the initiating particles of the extensive air showers are relativistic iron grains.     

The effects of disk building on the distributions of refractory materials in the solar nebula

Abstract– Refractory materials, such as calcium‐aluminum‐rich inclusions (CAIs) and crystalline silicates, are widely found in chondritic meteorites as well as comets, taken as evidence for large‐scale mixing in the solar nebula. Most models for mixing in the solar nebula begin with a well‐formed protoplanetary disk. Here, we relax this assumption by modeling the formation and evolution of the solar nebula during and after the period when it accreted material from its parent molecular cloud. We consider how disk building impacts the long‐term evolution of the disk and the implications for grain transport and mixing within it. Our model shows that materials that formed before infall was complete could be preserved in primitive bodies, especially those that accreted in the outer disk. This potentially explains the discovery of refractory objects with low initial ²⁶Al/²⁷Al ratios in comets. Our model also shows that the highest fraction of refractory materials in meteorites formed around the time that infall stopped. Thus, we suggest that the calcium‐aluminum‐rich inclusions in chondrites would be dominated by the population that formed during the transition from class I to class II stage of young stellar objects. This helps us to understand the meaning of t = 0 in solar system chronology. Moreover, our model offers a possible explanation for the existence of isotopic variations observed among refractory materials—that the anomalous materials formed before the collapse of the parent molecular cloud was complete.     

Noble gases and meteorites

Abstract— Noble gases repeatedly have served to widen the scope of meteorite research. During the first half century of such measurements, the emphasis was on the determination of U, Th/He-gas retention ages of iron meteorites, which is the most unsuitable class of meteorites for such studies. With the realization that the He in these meteorites results from the interaction of cosmic rays with meteoritic matter, meteorites became to be used as “the poor man's space probe” that yielded information on the constancy in time and space of the cosmic radiation. Another widening of scope came with the discovery of extremely high noble gas contents in the outermost layers of the individual grains that make up stony meteorites. These gases are of solar origin; they have been implanted as low-energy solar wind (SW) or as solar energetic particles (SEP) into the grains before their compaction. Presently they offer the only opportunity to precisely measure the isotopic composition of solar matter and to learn about potential changes of the Sun in time. Stony meteorites of the “carbonaceous” variety contain “stardust” that carries the undiluted nucleosynthesis products of individual stars that yield incredibly detailed information concerning the parameters that prevailed during the synthesis.     

Oxygen isotopic compositions and origins of calcium‐aluminum‐rich inclusions and chondrules

Abstract— Primary minerals in calcium‐aluminum‐rich inclusions (CAIs), Al‐rich and ferromagnesian chondrules in each chondrite group have δ¹⁸O values that typically range from ?50 to +5%0. Neglecting effects due to minor mass fractionations, the oxygen isotopic data for each chondrite group and for micrometeorites define lines on the three‐isotope plot with slopes of 1.01 ± 0.06 and intercepts of ?2 ± 1. This suggests that the same kind of nebular process produced the ¹⁶O variations among chondrules and CAIs in all groups. Chemical and isotopic properties of some CAIs and chondrules strongly suggest that they formed from solar nebula condensates. This is incompatible with the existing two‐component model for oxygen isotopes in which chondrules and CAIs were derived from heated and melted ¹⁶O‐rich presolar dust that exchanged oxygen with ¹⁶O‐poor nebular gas. Some FUN CAIs (inclusions with isotope anomalies due to fractionation and unknown nuclear effects) have chemical and isotopic compositions indicating they are evaporative residues of presolar material, which is incompatible with ¹⁶O fractionation during mass‐independent gas phase reactions in the solar nebula. There is only one plausible reason why solar nebula condensates and evaporative residues of presolar materials are both enriched in ¹⁶O. Condensation must have occurred in a nebular region where the oxygen was largely derived from evaporated ¹⁶O‐rich dust. A simple model suggests that dust was enriched (or gas was depleted) relative to cosmic proportions by factors of ～10 to >50 prior to condensation for most CAIs and factors of 1–5 for chondrule precursor material. We infer that dust‐gas fractionation prior to evaporation and condensation was more important in establishing the oxygen isotopic composition of CAIs and chondrules than any subsequent exchange with nebular gases. Dust‐gas fractionation may have occurred near the inner edge of the disk where nebular gases accreted into the protosun and Shu and colleagues suggest that CAIs formed.