Role of conduit shear on ascent of the crystal-rich magma feeding the 800-year-<Emphasis Type="SmallCaps">b.p.</Emphasis> Plinian eruption of Quilotoa Volcano (Ecuador)

We have characterized pumice products belonging to the climactic phase of the 800-year-b.p. Quilotoa eruption. Bulk rock compositions, petrography, mineral, and glass chemistry and textural investigations were performed on the three end-member pumice types, namely white, gray, and mingled pumices. All the investigated pumice clasts are dacites characterized by the same bulk rock composition and mineralogical assemblage, but glass compositions and bulk textures change according to different pumice types. White pumice has higher crystallinity (~48 wt%), abundant euhedral pheno/microphenocrysts, no groundmass microlites, the most evolved glass compositions (74–78 wt% SiO₂), and heterogeneous vesicle populations marked by deformed and highly coalesced vesicles with thin walls. Gray pumice exhibits lower crystallinity (29–36 wt%), abundant broken and/or resorbed crystals, ubiquitous groundmass phenocryst fragments and microlites, the widest range of glass compositions (69–78 wt% SiO₂), and quite homogeneous poorly deformed and coalesced vesicles with thicker walls. Mingled pumices are characterized by the alternation of bands or patches with white and gray pumice compositional and textural characteristics. We attribute heterogeneities in glass compositions and crystal and vesicle textures to processes occurring within volcanic conduits as magma is ascending to the surface. In particular, the above observations and results are consistent with an origin of a gray magma by heating of the original white magma in a strongly sheared region of the conduit because of a mechanism of viscous dissipation and crystal grinding and resorption at the conduit walls. The less viscous gray magma, therefore, would enable the onset and preservation of a high mass flux of the eruption otherwise difficult to explain for highly viscous crystal-rich dacitic magmas.Editorial responsibility: D. Dingwell     

The Plinian phase of the Campanian Ignimbrite eruption (Phlegrean Fields,Italy): evidence from density measurements and textural characterization of pumice

Textural characterization of pumice clasts from explosive volcanic eruptions provides constraints on magmatic processes through the quantification of crystal and vesicle content, size, shape, vesicle wall thickness and the degree of interconnectivity. The Plinian fallout deposit directly underlying the Campanian Ignimbrite (CI) eruption represents a suitable case to investigate pumice products with different textural characteristics and to link the findings to processes accompanying conduit magma ascent to the crater. The deposit consists of a lower (LFU) and upper (UFU) pumice lapilli bed generated by the sub-steady eruption of trachytic magma with <5 vol%. crystals and a peak discharge rate of 3.2×10 ⁸ kg/s. Density measurements were performed on samples collected from different stratigraphic intervals at the Voscone-type outcrop, and their textural characteristics were investigated at different magnifications through image analysis techniques. According to clast densities, morphologies and vesicle textures pumice clasts were classified into microvesicular (heterogeneous vesicles), tube (elongated/deformed vesicles) and expanded (coalesced/inflated vesicles).The combination of density data and textural investigations allowed us to characterize both representative areas and textural extremes of pumice products. Bulk vesicularity spans a broad interval varying from 0.46 to >0.90, with vesicle number density ranging from 10 ⁷–10 ⁸ cm ^-3. The degree of vesicle coalescence is high for all pumice types, with interconnected vesicles generally representing more than 90% of the bulk vesicle population. The results show a high degree of heterogeneous textures among pumice clasts from both phases of the eruption and within each eruption phase, the different pumice types and also within each single pumice type fragment. The origin of pumice clasts with different textural characteristics is ascribed to the development of conduit regions marked by different rheological behavior. The conclusions of this study are that vesicle deformation, degree of coalescence and intense shear at the conduit walls play a major role on the degassing process, hence affecting the entire conduit dynamics.     

Complex changes in eruption dynamics during the 79 AD eruption of Vesuvius

The 79 AD eruption of Vesuvius included 8 eruption units (EU1–8) and several complex transitions in eruptive style. This study focuses on two important transitions: (1) the abrupt change from white to gray pumice during the Plinian phase of the eruption (EU2 to EU3) and (2) the shift from sustained Plinian activity to the onset of caldera collapse (EU3 to EU4). Quantification of the textural features within individual pumice clasts reveals important changes in both the vesicles and groundmass crystals across each transition boundary. Clasts from the white Plinian fall deposit (EU2) present a simple story of decompression-driven crystallization followed by continuous bubble nucleation, growth and coalescence in the eruptive conduit. In contrast, pumices from the overlying gray Plinian fall deposit (EU3) are heterogeneous and show a wide range in both bubble and crystal textures. Extensive bubble growth, coalescence, and the onset of bubble collapse in pumices at the base of EU3 suggest that the early EU3 magma experienced protracted vesiculation that began during eruption of the EU2 phase and was modified by the physical effects of syn-eruptive mingling-mixing. Pumice clasts from higher in EU3 show higher bubble and crystal number densities and less evidence of bubble collapse, textural features that are interpreted to reflect more thorough mixing of two magmas by this stage of the eruption, with consequent increases in both vesiculation and crystallization. Pumice clasts from a short-lived, high column at the onset of caldera collapse (EU4) continue the trend of increasing crystallization (enhanced by mixing) but, unexpectedly, the melt in these clasts is more vesicular than in EU3 and, in the extreme, can be classified as reticulite. We suggest that the high melt vesicularity of EU4 reflects strong decompression following the partial collapse of the magma chamber.Editorial responsibility: D.B. Dingwell     

Submarine silicic volcanism of the Healy caldera,southern Kermadec arc (SW Pacific): I – volcanology and eruption mechanisms

The submarine Healy volcano (southern Kermadec arc), with a 2-2.5 km wide caldera, is pervasively mantled with highly vesicular silicic pumice within a water depth of 1,150-1,800 m. Pumices comprise type 1 white-light grey pumice with ⢾ mm vesicles and weak-moderate foliation, type 2 grey pumice with millimetre-scale laminae, flow banded foliation, including stretched vesicles ⣗ mm in length, and a minor finely vesicular type 3 pumice. All types are sparsely porphyritic, with undevitrified glassy groundmass (68-70% SiO₂), which is microlite and lithic free. Coexisting pyroxenes yield magma temperatures of ~950 °C. Pumice density is А.5 g cm^-3 and vesicularity is 78-83%. Vesicle size distributions for types 1 and 2 pumice, range from ~20 µm to >20 mm, with a strong power-law relation (with d=-2.5ǂ.4) for vesicles <1-2 mm. Larger vesicles have variable size modes. The vesicle size distribution and packing indicates rapid magma decompression and ascent. Consideration of the pressure dependent, solubility of H₂O at a magma temperature of 𙧶 °C and water content of Ж wt%, with pumice petrography and vesicle granulometry, strongly suggests a pyroclastic eruption. Reconstructions of the submarine edifice between water depths of 1,000 and 550 m constrain the ambient hydrostatic pressure to ~6-9 MPa. Pressures >~9 MPa will limit vesicularity to less than the observed 78-83%, whereas pressure <~6 MPa require a more shallower reconstruction of the edifice and larger-volume syn-eruptive collapse. Uniformly high vesicularity is interpreted as evidence of insulation within an eruption column comprising steam and hot pyroclasts. Most pyroclasts cool, condensing and ingesting water into steam-inflated vesicles, and then sink. Progression into pyroclastic mode would expand the eruption column, displace ambient water, reduce the hydrostatic load, and further promote vesiculation and fragmentation. Pyroclasts within the column would quench at these reduced pressures. We argue that Healy eruptions deeper than ~1,000 m cannot be pyroclastic. Volumes for the lower and upper bounds of edifice size are 2.36 and 3.58 km³, respectively, but do not account for intra-caldera pumice fill. These volumes are considered to be predominantly primary eruption output, as shown by a dearth of accessory lithics in all pumice, yielding (at an average 81% vesicularity) eruptive pumice volumes of between 10 and 15 km³. Some pyroclasts may have risen to the sea surface and be a correlative of the sea-rafted Loisels pumice; the latter occurs in some New Zealand Holocene beach sequences and has a estimated age of 590ᇤ calendar years.     

Transitions between fall phases and pyroclastic density currents during the AD 79 eruption at Vesuvius: building a transient conduit model from the textural and volatile record

The magmatic phase of the AD 79 eruption of Vesuvius produced alternations of fall and pyroclastic density current (PDC) deposits. A previous investigation demonstrated that the formation of several PDCs was linked with abrupt increases in the proportion of denser juvenile clasts within the eruptive column. Under the premise that juvenile clast density is controlled by vesiculation processes within the conduit, we investigate the processes responsible for these variations at or close to fragmentation levels. Pumice textures (vesicle sizes, numbers, and connectivity combined with crystal textures) from the AD 79 PDC deposits are compared to those from interbedded fall samples. Both PDC and fall deposits preserve textures that represent a full spectrum of degassing and outgassing processes, from bubble nucleation to collapse. Combining the textural and volatile (groundmass H₂O) data, we derive a conduit model that satisfies all the textural and physical observations made for this phase of the eruption: lateral vesicularity/density stratifications are produced by maturing of bubble textures with superimposed localized shearing of bubble-rich magmas, which enhance outgassing of H₂O. The incorporation of denser slower-moving magma from the conduit margins (??lateral magma density gradient??) is likely to be responsible for the higher abundances of dense juvenile pumice that triggered partial column collapses. We also illustrate how variations in the fragmentation depth (tapping a ??vertical magma density gradient??) can be responsible for variations in erupted clast density distributions, and potentially in the extent of degassing/outgassing.     

Heterogeneous pumice populations in the 2.08-Ma Cerro Gal��n Ignimbrite: implications for magma recharge and ascent preceding a large-volume silicic eruption

Triggering mechanisms of large silicic eruptions remain a critical unsolved problem. We address this question for the ~2.08-Ma caldera-forming eruption of Cerro Galán volcano, Argentina, which produced distinct pumice populations of two colors: grey (5%) and white (95%) that we believe may hold clues to the onset of eruptive activity. We demonstrate that the color variations correspond to both textural and compositional variations between the clast types. Both pumice types have bulk compositions of high-K, high-silica dacite to low-silica rhyolite, but there are sufficient compositional differences (e.g., ~150?ppm lower Ba at equivalent SiO₂ content and 0.03?wt.% higher TiO₂ in white pumice than grey) to suggest that the two pumice populations are not related by simple fractionation. Trace element concentrations in crystals mimic bulk variations between clast types, with grey pumice containing elevated Ba, Cu, Pb, and Zn concentrations in both bulk samples (average Cu, Pb, and Zn concentrations are 27, 35, and 82 in grey pumice vs. 11, 19, and 60 in white pumice) and biotite phenocrysts and white pumice showing elevated Li concentrations in biotite and plagioclase phenocrysts. White and grey clasts are also texturally distinct: White pumice clasts contain abundant phenocrysts (44?C57%), lack microlites, and have highly evolved groundmass glass compositions (76.4?C79.6?wt.% SiO₂), whereas grey pumice clasts contain a lower percentage of phenocrysts/microphenocrysts (35?C49%), have abundant microlites, and have less evolved groundmass glass compositions (69.4?C73.8?wt.% SiO₂). There is also evidence for crystal transfer between magma producing white and grey pumice. Thin highly evolved melt rims surround some fragmental crystals in grey pumice clasts and appear to have come from magma that produced white pumice. Furthermore, based on crystal compositions, white bands within banded pumice contain crystals originating in grey magma. Finally, only grey pumice clasts form breadcrusted surface textures. We interpret these compositional and textural variations to indicate distinct magma batches, where grey pumice originated from an originally deeper, more volatile-rich dacite recharge magma that ascended through and mingled with the volumetrically dominant, more highly crystalline chamber that produced white pumice. Shortly before eruption, the grey pumice magma stalled within shallow fractures, forming a vanguard magma phase whose ascent may have provided a trigger for eruption of the highly crystalline rhyodacite magma. We suggest that in the case of the Cerro Galán eruption, grey pumice provides evidence not only for cryptic silicic recharge in a large caldera system but also a probable trigger for the eruption.     

Structure and physical characteristics of pumice from the climactic eruption of Mount Mazama (Crater Lake), Oregon

The vesicularity, permeability, and structure of pumice clasts provide insight into conditions of vesiculation and fragmentation during Plinian fall and pyroclastic flow-producing phases of the ~7,700 cal. year B.P. climactic eruption of Mount Mazama (Crater Lake), Oregon. We show that bulk properties (vesicularity and permeability) can be correlated with internal textures and that the clast structure can be related to inferred changes in eruption conditions. The vesicularity of all pumice clasts is 75-88%, with >90% interconnected pore volume. However, pumice clasts from the Plinian fall deposits exhibit a wider vesicularity range and higher volume percentage of interconnected vesicles than do clasts from pyroclastic-flow deposits. Pumice permeabilities also differ between the two clast types, with pumice from the fall deposit having higher minimum permeabilities (~5᎒^-13 m²) and a narrower permeability range (5-50᎒^-13 m²) than clasts from pyroclastic-flow deposits (0.2-330᎒^-13 m²). The observed permeability can be modeled to estimate average vesicle aperture radii of 1-5 µm for the fall deposit clasts and 0.25-1 µm for clasts from the pyroclastic flows. High vesicle number densities (~10⁹ cm^-3) in all clasts suggest that bubble nucleation occurred rapidly and at high supersaturations. Post-nucleation modifications to bubble populations include both bubble growth and coalescence. A single stage of bubble nucleation and growth can account for 35-60% of the vesicle population in clasts from the fall deposits, and 65-80% in pumice from pyroclastic flows. Large vesicles form a separate population which defines a power law distribution with fractal dimension D=3.3 (range 3.0-3.5). The large D value, coupled with textural evidence, suggests that the large vesicles formed primarily by coalescence. When viewed together, the bulk properties (vesicularity, permeability) and textural characteristics of all clasts indicate rapid bubble nucleation followed by bubble growth, coalescence and permeability development. This sequence of events is best explained by nucleation in response to a downward-propagating decompression wave, followed by rapid bubble growth and coalescence prior to magma disruption by fragmentation. The heterogeneity of vesicle sizes and shapes, and the absence of differential expansion across individual clasts, suggest that post-fragmentation expansion played a limited role in the development of pumice structure. The higher vesicle number densities and lower permeabilities of pyroclastic-flow clasts indicate limited coalescence and suggest that fragmentation occurred shortly after decompression. Either increased eruption velocities or increased depth of fragmentation accompanying caldera collapse could explain compression of the pre-fragmentation vesiculation interval.     

Insights into eruption dynamics from textural analysis: the case of the May, 2008, Chaitén eruption

The May, 2008, Chaitén (southern Chile) eruption was characterized by several explosive events, each associated with plumes which reached up to about 19?km above sea level on May 6. A study of the textural and physical features of the juvenile clasts erupted during the climactic phase of the 2008 eruption of Chaitén is presented. Pumice clasts show unimodal density distribution (main mode at 600?kg/m³), average vesicularity of about 69?%, a glassy groundmass with no microcrystals, and vesicles with dimension between ～1?μm and ～2?mm. They also show a unimodal vesicle size distribution with most frequent vesicle size in the range 0.05–0.08?mm and an estimated vesicle number density of 1.3?±?0.5?×?10⁵?mm^?3 related to a rapid nucleation event produced during the late phases of magma rise. This is confirmed by the absence of microcrystals that could otherwise have delayed vesicle formation and allowed the magma to maintain a low viscosity and a supersaturation in volatiles. Vesiculation and fragmentation were triggered by a sudden decompression of the melt associated with the opening of the volcanic conduit (～10?MPa?s^?1).     

Changes in eruptive style during the A.D. 1538 Monte Nuovo eruption (Phlegrean Fields, Italy): the role of syn-eruptive crystallization

The Monte Nuovo eruption is the most recent event that occurred at Phlegrean Fields (Italy) and lasted from 29 September to 6 October 1538. It was characterized by 2 days of quasi-sustained phreatomagmatic activity generating pumice-bearing pyroclastic density currents and forming a 130-m-high tuff cone (Lower Member deposits). The activity resumed after a pause of 2 days with two discrete Vulcanian explosions that emplaced radially distributed, scoria-bearing pyroclastic flows (Upper Member deposits). The juvenile products of Lower and Upper Members are, respectively, phenocryst-poor, light-coloured pumice and dark scoria fragments with K-phonolitic bulk compositions, identical in terms of both major and trace elements. Groundmass is formed by variable proportions of K-feldspar and glass, along with minor sodalite and Fe-Ti oxide present in the most crystallized samples. Investigations of groundmass compositions and textures were performed to assess the mechanisms of magma ascent, degassing and fragmentation along the conduit and implications for the eruptive dynamics. In pumice of the Lower Member groundmass crystal content increases from 13 to 28 vol% from the base to the top of the sequence. Products of the Upper Member consist of clasts with a groundmass crystal content between 30 and 40 vol% and of totally crystallized fragments. Crystal size distributions of groundmass feldspars shift from a single population at the base of the Lower Member to a double population in the remaining part of the sequence. The average size of both populations regularly increases from the Lower to the Upper Member. Crystal number density increases by two orders of magnitude from the Lower to the Upper Member, suggesting that nucleation dominated during the second phase of the eruption. The overall morphological, compositional and textural data suggest that the juvenile components of the Monte Nuovo eruption are likely to record variations of the magma properties within the conduit. The different textures of pumice clasts from the Lower Member possibly reflect horizontal gradients of the physical properties (P, T) of the ascending magma column, while scoriae from the second phase are thought to result from the disruption of a slowly rising plug crystallizing in response to degassing. In particular, crystal size distribution data point to syn-eruptive degassing-induced crystallization as responsible for the transition in eruptive style from the first to the second phase of the eruption. This mechanism not only has been proved to profoundly affect the dynamics of dome-forming calc-alkaline eruptions, but may also have a strong influence in driving the eruption dynamics of alkaline magmas of intermediate to evolved compositions.Editorial responsibility: J. Donnelly-Nolan     

Modeling of the ascent of magma during the plinian eruption of Vesuvius in A.D. 79

The ascent of magma during the A.D. 79 eruption of Vesuvius was studied by a steady-state, one-dimensional, and nonequilibrium two-phase flow model. The gas exsolution process was modeled by assuming a chemical equilibrium between the exsolved and dissolved gas, whereas the magma density and viscosity were modeled by accounting for the crystal content in magma. The exsolution, density, and viscosity models consider the effect of different compositions of the white and gray magmas. By specifying the conduit geometry and magma composition, and employing the model to search for the maximum discharge rate of magma which is consistent with the specified geometry and magma composition, the model was then used to establish the two-phase flow parameters along the conduit. It was found that for all considered conditions the magma pressure in the conduit decreases below the lithostatic pressure near the magma fragmentation level, and that in the deep regions of the conduit the white magma pressure is larger and the gray magma pressure is lower than the lithostatic one. The exsolution and fragmentation levels were found to be deeper for the white than for the gray magma, and the changing composition during the eruption causes an increase of the exit pressure and decrease of the exit gas volumetric fraction. The model also predicted a minimum conduit diameter which is consistent with the white and gray magma compositions and mass flow-rates. The predictions of the model were shown to be consistent with column collapses during the gray eruption phase, large presence of carbonate lithics in the gray pumice fall deposit, and magma-water interaction during a late stage of the eruption.     

Abrupt transitions during sustained explosive eruptions: examples from the 1912 eruption of Novarupta, Alaska

Plinian/ignimbrite activity stopped briefly and abruptly 16 and 45 h after commencement of the 1912 Novarupta eruption defining three episodes of explosive volcanism before finally giving way after 60 h to effusion of lava domes. We focus here on the processes leading to the termination of the second and third of these three episodes. Early erupted pumice from both episodes show a very similar range in bulk vesicularity, but the modal values markedly decrease and the vesicularity range widens toward the end of Episode III. Clasts erupted at the end of each episode represent textural extremes; at the end of Episode II, clasts have very thin glass walls and a predominance of large bubbles, whereas at the end of Episode III, clasts have thick interstices and more small bubbles. Quantitatively, all clasts have very similar vesicle size distributions which show a division in the bubble population at 30 μm vesicle diameter and cumulative number densities ranging from 10⁷–10⁹ cm^–3. Patterns seen in histograms of volume fraction and the trends in the vesicle size data can be explained by coalescence signatures superimposed on an interval of prolonged nucleation and free growth of bubbles. Compared to experimental data for bubble growth in silicic melts, the high 1912 number densities suggest homogeneous nucleation was a significant if not dominant mechanism of bubble nucleation in the dacitic magma. The most distinct clast populations occurred toward the end of Plinian activity preceding effusive dome growth. Distributions skewed toward small sizes, thick walls, and teardrop vesicle shapes are indicative of bubble wall collapse marking maturation of the melt and onset of processes of outgassing. The data suggest that the superficially similar pauses in the 1912 eruption which marked the ends of episodes II and III had very different causes. Through Episode III, the trend in vesicle size data reflects a progressive shift in the degassing process from rapid magma ascent and coupled gas exsolution to slower ascent with partial open-system outgassing as a precursor to effusive dome growth. No such trend is visible in the Episode II clast assemblages; we suggest that external changes involving failure of the conduit/vent walls are more likely to have effected the break in explosive activity at 45 h.     

A COMPARATIVE STUDY ON THE CHARACTERISTICS OF TWO STAGES OF FALLOUT PUMICES DEPOSITS FROM THE MILLENNIUM ERUPTION OF TIANCHI VOLCANO IN CHANGBAISHAN AREA

Tianchi volcano in Changbaishan area is located at the border between China and Democratic People's Republic of Korea, and is one of the most dangerous volcanoes in China. It has experienced several explosive eruptions in late Pleistocene and Holocene, i.e. 50000aBP eruption, 946 AD eruption, 1668 AD eruption, 1702 AD eruption, 1903 AD eruption. Especially, the 946 AD eruption(also known as "Millennium eruption")of this volcano is considered to be one of the largest volcanic eruptions in the world in the past 2000a. The eruption history and strata sequence of Tianchi volcano have long been the focus of attention. The stratigraphic unit division of fallout deposits in the past millennium is controversial, especially for the heterogeneous trachytic pumices(erupted from the Yuanchi stage)above the off-white pumices(erupted from the Chifeng stage). In this paper, through the detailed field exploration and strata comparation, it was found that there was no depositional interval between the two stage eruptions, or the interval was not long, and thus, it is believed that two stages of fallout pumice should be classified into the Millennium eruption. The off-white fallout pumices in Chifeng stage are relatively homogeneous, with angular shape, normal grading and good sorting. The median size(Md_Φ)and the sorting coefficient(σ_Φ)of Chifeng pumice are in the range of -4.25~-1.3 and 0.93~1.53, respectively. The eruption of Yuanchi stage is in pulsing pattern, and the strata show interbedding of rich khaki pumice layer and rich black pumice layer. The pumices with angular shape show inconspicuous grain grading and good sorting. The median size(Md_Φ)and the sorting coefficient(σ_Φ)of Yuanchi pumice are in the range of -2.55~-0.6 and 1~1.68, respectively. Both the granularities of the pumice particles from two stages are normally distributed and fall into the air-fall field in the median diameter versus sorting diagram. The pumices from 50000aBP and pyroclastic flow of Millennium eruption were also shown in the diagram. Phenocrysts in pumices are mainly feldspar and pyroxene, but the phenocrysts with obvious resorbed characteristic in Yuanchi black pumice are bigger, and the phenocryst contents are a little higher than those in others. Feldspar content in off-white pumice in Chifeng stage was 0.24%~1.77%, that in khaki pumice in Yuanchi stage was 0.2%~7.5%, and that in black pumice in Yuanchi stage was 3.02%~8.0%. The phenocrysts in Chifeng pumice are broken, which represents more violent explosion. The vesicles inside the pumice also reflect the intensity of the eruption. The Chifeng pumices have large, continuous vesicles and thin vesicle walls. The Yuanchi khaki pumices have continuous vesicles but thicker vesicle wall than the Chifeng pumices. The vesicularity is the lowest and the vesicle walls are the thickest in the black pumices in Yuanchi stage, indicating the eruption strength become weaker from Chifeng stage to Yuanchi stage. The Chifeng pumices with SiO₂ content of 69.12~72.71wt%, K₂O content of 4.33~4.52wt%, Na₂O content of 5.26~5.39wt%, Al₂O₃ content of 10.32~11.99wt%, CaO content of 0.29~0.95wt%, MgO content of 0.11~0.51wt%, TiO₂ content of 0.23~0.43wt% are comendite in composition. The pumices from 50000aBP eruption are comendite in composition, and their SiO₂ content(65.56~68.28wt%)is slightly lower than Chifeng pumices. The Yuanchi khaki pumices with SiO₂ content of 62.14~63.29wt%, K₂O content of 5.35~5.7wt%, Na₂O content of 5.35~5.62wt%, Al₂O₃ content of 15.00~15.59wt%, CaO content of 1.06~1.61wt%, MgO content of 0.25~0.57wt%, TiO₂ content of 0.4~0.64wt% belong to trachyte in composition, and are close to the composition of the black pumices on the Tianwen Peak. The Yuanchi black pumices are also trachyte in composition, but have obviously lower SiO₂(59.51~60.59wt%), K₂O(4.39~4.84wt%), and Na₂O(4.94~5.08wt%)content, and higher Al₂O₃(15.81~16.42wt%), CaO(2.78~3.66wt%), MgO(1.43~1.9wt%), TiO₂(1.04~1.4wt%)content than the khaki pumices. The above results show that the eruptive intensity of the Yuanchi stage is weaker than that of the Chifeng stage and the several magmatic compositions of pumices from the Millennium eruption reveal a complex magma system under the Tianchi volcano. The magma layers with different compositions may exist in the magma chamber contemporaneously. At Chifeng stage, only the upper comendite magma erupted, but the magma below erupted in the pulsing pattern at the Yuanchi stage.     

Volcanological evolution of the Rivi–Capo Volcanic Complex at Salina,Aeolian Islands: magma storage processes and ascent dynamics

Critical to understanding explosive eruptions is establishing how accurately representative pyroclasts are of processes during magma vesiculation and fragmentation. Here, we present data on densities, and vesicle size and number characteristics, for representative pyroclasts from six silicic eruptions of contrasting size and style from Raoul volcano (Kermadec arc). We use these data to evaluate histories of bubble nucleation, coalescence, and growth in explosive eruptions and to provide comparisons with pumiceous dome carapace material. Density/vesicularity distributions show a scarcity of pyroclasts with ～65–75 % vesicularity; however, pyroclasts closest to this vesicularity range have the highest bubble number density (BND) values regardless of eruptive intensity or style. Clasts with vesicularities greater than this 65–75 % “pivotal” vesicularity range have decreasing BNDs with increasing vesicularities, interpreted to reflect continuing bubble growth and coalescence. Clasts with vesicularities less than the pivotal range have BNDs that decrease with decreasing vesicularity and preserve textures indicative of processes such as stalling and open system degassing prior to vesiculation in a microlite-rich magma, or vesiculation during slow ascent of degassing magma. Bubble size distributions (BSDs) and BNDs show variations consistent with 65–75 % representing the vesicularity at which vesiculating magma is most likely to undergo fragmentation, consistent with the closest packing of spheres. We consider that the observed vesicularity range may reflect the development of permeability in the magma through shearing as it flows through the conduit. These processes can act in concert with multiple nucleation events, generating a situation of heterogeneous bubble populations that permit some regions of the magma to expand and bubbles to coalesce with other regions in which permeable networks are formed. Fragmentation preserves the range in vesicularity seen as well as any post-fragmentation/pre-quenching expansion which may have occurred. We demonstrate that differing density pyroclasts from a single eruption interval can have widely varying BND values corresponding to the degree of bubble maturation that has occurred. The modal density clasts (the usual targets for vesicularity studies) have likely undergone some degree of bubble maturation and are therefore may not be representative of the magma at the onset of fragmentation.     

On magma fragmentation by conduit shear stress: Evidence from the Kos Plateau Tuff,Aegean Volcanic Arc

Large silicic explosive eruptions are the most catastrophic volcanic events. Yet, the intratelluric mechanisms underlying are not fully understood. Here we report a field and laboratory study of the Kos Plateau Tuff (KPT, 161 ka, Aegean Volcanic Arc), which provides an excellent geological example of conduit processes that control magma vesiculation and fragmentation during intermediate- to large-scale caldera-forming eruptions. A prominent feature of the KPT is the occurrence of quite unusual platy-shaped tube pumice clasts in pyroclastic fall and current deposits from the early eruption phases preceding caldera collapse. On macroscopic and SEM observations, flat clast faces are elongated parallel to tube vesicles, while transverse surfaces often occur at ~ 45° to vesicle elongation. This peculiar pumice texture provides evidence of high shear stresses related to strong velocity gradients normal to conduit walls, which induced vesiculation and fragmentation of the ascending magma. Either an increasing mass discharge rate without adequate enlargement of a narrow central feeder conduit or a developing fissure-like feeder system related to incipient caldera collapse provided suitable conditions for the generation of plate tube pumice within magma volumes under high shear during the pre-climactic KPT eruption phases. This mechanism implies that the closer to the conduit walls (where the stronger are the velocity gradients) the larger was the proportion of plate vs. conventional (lensoid) juvenile fragments in the ascending gas–pyroclast mixture. Consequently, plate pumice clasts were mainly entrained in the outer portions of the jet and convecting regions of a sustained, Plinian-type, eruption column, as well as in occasional lateral blast currents generated at the vent. As a whole, plate pumice clasts in the peripheral portions of the column were transported at lower altitudes and deposited by fallout or partial collapse closer to the vent relative to lensoid ones that dominated in the inner column portions. The plate tube pumice proportion decreased abruptly up to disappearance during the emplacement of the main pyroclastic currents and lithic-rich breccias related to extensive caldera collapse at the eruption climax, as a consequence of an overall widening of the magma feeder system through the opening of multiple conduits and eruptive vents, along with fissure erosion, concomitant to the disruption of the collapsing block.     

Bimodal Density Distribution of Cryptodome Dacite from the 1980 Eruption of Mount St. Helens,Washington

The explosion of a cryptodome at Mount St. Helens in 1980 produced two juvenile rock types that are derived from the same source magma. Their differences-color, texture and density-are due only to vesicularity differences. The vesicular gray dacite comprises bout 72% of the juvenile material; the black dacite comprises the other 28%. The density of juvenile dacite is bimodally distributed, with peaks at 1.6 g cm^-3 (gray dacite) and 2.3 g cm^-3 (black dacite). Water contents, deuterium abundances, and the relationship of petrographic structures to vapor-phase crystals indicate both rock types underwent pre-explosion subsurface vesiculation and degassing. The gray dacite underwent a second vesiculation event, probably during the 18 May explosion. In the subsurface, gases probably escaped through interconnected vesicles into the permeable volcanic edifice. We suggest that nonuniform degassing of an initially homogeneous magma produced volatile gradients in the cryptodome and that these gradients were responsible for the density bimodality. That is, water contents less than about 0.2–0.4 wt% produced vesicle growth rates that were slow in comparison to the pyroclast cooling rates; greater water contents produced vesicle growth rates that were fast in comparison to cooling rates. In this scheme, the dacite densities are bimodally distributed simply because, following decompression on 18 May 1980, one clast population vesiculated while the other did not. For clasts that did vesiculate, vesicle growth continued until it was arrested by fragmentation.     

Petrologic constraints on the decompression history of magma prior to Vulcanian explosions at the Soufrière Hills volcano,Montserrat

A series of 88 Vulcanian explosions occurred at the Soufrière Hills volcano, Montserrat, between August and October, 1997. Conduit conditions conducive to creating these and other Vulcanian explosions were explored via analysis of eruptive products and one-dimensional numerical modeling of magma ascent through a cylindrical conduit. The number densities and textures of plagioclase microlites were documented for twenty-three samples from the events. The natural samples all show very high number densities of microlites, and > 50% by number of microlites have areas < 20 μm². Pre-explosion conduit conditions and decompression history have been inferred from these data by comparison with experimental decompressions of similar groundmass compositions. Our comparisons suggest quench pressures < 30 MPa (origin depths < 2 km) and multiple rapid decompressions of > 13.75 MPa each during ascent from chamber to surface. Values are consistent with field studies of the same events and statistical analysis of explosion time-series data. The microlite volume number density trend with depth reveals an apparent transition from growth-dominated crystallization to nucleation-dominated crystallization at pressures of ∼ 7 MPa and lower. A concurrent sharp increase in bulk density marks the onset of significant open-system degassing, apparently due to a large increase in system permeability above ∼ 70% vesicularity. This open-system degassing results in a dense plug which eventually seals the conduit and forms conditions favorable to Vulcanian explosions. The corresponding inferred depth of overpressure at 250–700 m, near the base of the dense plug, is consistent with depth to center of pressure estimated from deformation measurements. Here we also illustrate that one-dimensional models representing ascent of a degassing, crystal-rich magma are broadly consistent with conduit profiles constructed via our petrologic analysis. The comparison between models and petrologic data suggests that the dense conduit plug forms as a result of high overpressure and open-system degassing through conduit walls.     

Vesiculation of high fountaining Hawaiian eruptions: episodes 15 and 16 of 1959 Kīlauea Iki

The 1959 summit eruption of Kīlauea volcano produced the highest recorded Hawaiian fountain in Hawai‘i. Quantitative analysis of closely spaced samples from the final two high-fountaining episodes of the eruption result in a fine-scale textural study of pyroclasts and provide a record of postfragmentation processes. As clast vesicularity increases, the vesicle number density decreases and vesicle morphology shifts from small and round to larger and more irregular. The shift in microtexture corresponds to greater degrees of postfragmentation expansion of clasts with higher vesicularity. We suggest the range of clast morphologies in the deposit is related to thermal zonation within a Hawaiian fountain where the highest vesicularity clasts traveled in the center and lowest traveled along the margins. Vesicle number densities are greatest in the highest fountaining episode and therefore scale with intensity of activity. Major element chemical analyses and fasciculate crystal textures indicate microlite-rich zones within individual clasts are portions of recycled lava lake material that were incorporated into newly vesiculating primary melt.     

Crystallization of microlites during magma ascent: the fluid mechanics of 1980–1986 eruptions at Mount St Helens

Eruptions of Mount St Helens (Washington, USA) decreased in intensity and explosivity after the main May 18, 1980 eruption. As the post-May 18 eruptions progressed, albitic plagioclase microlites began to appear in the matrix glass, although the bulk composition of erupted products, the phenocryst compositions and magmatic temperatures remained fairly constant. Equilibrium experiments on a Mount St Helens white pumice show that at 160 MPa water pressure and 900°C, conditions deduced for the 8 km deep magma storage zone, the stable plagioclase is An₄₇. The microlites in the natural samples, which are more albitic, had to grow at lower water pressures during ascent. Isothermal decompression experiments reported here demonstrate that a decrease in water pressure from 160 to 2 MPa over four to eight days is capable of producing the albitic groundmass plagioclase and evolved melt compositions observed in post-May 18 1980 dacites. Because groundmass crystallization occurs over a period of days during and after decreases in pressure, microlite crystallization in the Mount St Helens dacites must have occurred during the ascent of each magma batch from a deep reservoir rather than continuously in a shallow holding chamber. This is consistent with data on the kinetics of amphibole breakdown, which require that a significant portion of magma vented in each eruption ascended from a depth of at least 6.5 km (160 MPa water pressure) in a matter of days. The size and shape of the microlite population have not been studied because of the small size of the experimental samples; it is possible that the texture continues to mature long after chemical equilibrium is approached. As the temperature, composition, crystal content and water content of magma in the deep reservoir remained approximately constant from May 1980 to at least March 1982, the spectacular decrease in eruption intensity during this period cannot be attributed to changes in viscosity or density of the magma. Simple fluld mechanical considerations indicate, however, that the observed changes in mass flux of magma can be modelled by a five-fold decrease in conduit radius from 35 to 7 m, produced perhaps by plating of magma along the conduit walls. The decreased ascent rates which accompanied the decrease in conduit radius can explain the change from closed-system to open-system degassing and the shift from explosive to effusive eruptions during 1980.     

Spongy pahoehoe in Hawaii: A study of vesicle-distribution patterns in basalt and their significance

A well-defined pahoehoe lava type that is very common medially and distally in Hawaii is characterized by a high concentration and fairly uniform distribution of spherical or near-spherical vesicles. Measurements of vesicle sizes and concentrations have been made on ten of these spongy pahoehoe lava flow-units. The vesicles increase in size toward the middle, accompanied by a moderate increase in lava porosity. The close approach to bilateral symmetry on either side of the horizontal median plane and the common occurrence of a median gas blister shows that no significant upward movement of vesicles occurred, suggesting that the lava possessed a yield strength and was more or less static. Olivine phenocrysts when present are, however, concentrated in the lower half of the same flow units, showing that the lava previously lacked a significant yield strength. The vesicles are regarded as early, inherited from the vent, but the size characteristics of the vesicle population are a late-formed feature. Vesicles grew in static lava mostly by coalescence, and it is postulated that coalescence was promoted by the presence of abundant diktytaxitic voids which punctured the walls of contiguous vesicles. Zones in which the vesicle concentration is lower and the vesicles are larger and strongly deformed interrupt the symmetry of some spongy pahoehoe units, and gas blisters higher than the median plane occur in many examples. These zones are interpreted to result from late-stage shearing, and point to a mechanism by which vesicles may be eliminated from a lava.     

Estimating silicic lava vesicularity with thermal remote sensing: a new technique for volcanic mapping and monitoring

 Remote monitoring of active lava domes provides insights into the duration of continued lava extrusion and detection of potentially associated explosive activity. On inactive flows, variations in surface texture ranging from dense glass to highly vesicular pumice can be related to emplacement time, volatile content, and internal structure. Pumiceous surface textures also produce changes in thermal emission spectra that are clearly distinguishable using remote sensing. Spectrally, the textures describe a continuum consisting of two pure end members, obsidian and vesicles. The distinct spectral features of obsidian are commonly muted in pumice due to overprinting by the vesicles, which mimic spectrally neutral blackbody emitters. Assuming that this energy combines linearly in direct proportion to the percentage of vesicles, the surface vesicularity can be estimated by modeling the pumice spectrum as a linear combination of the glass and blackbody spectra. Based on this discovery, a linear retrieval model using a least-squares fitting approach was applied to airborne thermal infrared data of the Little Glass Mountain and Crater Glass rhyolite flows at Medicine Lake Volcano (California) as a case study. The model produced a vesicularity image of the flow with values from 0 to ∼70%, which can be grouped into three broad textural classes: dense obsidian, finely vesicular pumice, and coarsely vesicular pumice. Values extracted from the image compare well with those derived from SEM analysis of collected samples as well as with previously reported results. This technique provides the means to accurately map the areal distributions of these textures, resulting in significantly different values from those derived using aerial photographs. If applied to actively deforming domes, this technique will provide volcanologists with an opportunity to monitor dome-wide degassing and eruptive potential in near-real-time. In July 1999 such an effort will be possible for the first time when repetitive, global, multispectral thermal infrared data become available with the launch of the Advanced Spaceborne Thermal Emission and Reflectance Radiometer (ASTER) instrument aboard the Earth Observing System satellite. Received: 25 June 1998 / Accepted: 14 December 1998