In situ stress field evaluation of deep marine tight sandstone oil reservoir: A case study of Silurian strata in northern Tazhong area,Tarim Basin,NW China

Deep marine tight sandstone oil reservoirs are the subject of considerable research around the world. This type of reservoir is difficult to develop due to its low porosity, low permeability, strong heterogeneity and anisotropy. A marine tight sandstone oil reservoir is present in the Silurian strata in the northern Tazhong area of the Tarim Basin, NW China, at a depth of more than 5000 m. The porosity is between 6% and 8%, and the gas permeability is between 0.1 and 1 × 10⁻³ μm². The features of this type of reservoir include the poor effects of conventional fracturing modifications and horizontal wells, which can lead to stable and low levels of production after staged fracturing. Here, we conduct a comprehensive evaluation of the mechanical properties of the rock and the in situ stress of the target tight sandstones by using numerous mechanical and acoustic property tests, conducing crustal stress analysis and using data from thin section observations. The dispersion correction technique is used to transform velocity at the experimental high frequency (1 MHz) to velocity at the logging frequency (20 kHz). The logging interpretation models of the transverse wave offset time, mechanical parameters and in situ stress are calculated, and each model represents a high precision prediction. Simulating the in situ stress field of the Silurian strata using a three-dimensional finite element method demonstrates that the average error between the simulation result and the measured value is less than 6%. The planar distribution of each principal stress is mainly controlled by the burial depth and fault distribution. By conducting in situ stress orientation analysis for the target layer via the analysis of paleomagnetism, borehole enlargement, fast shear wave orientation and stress field simulation, we show that the direction of the maximum horizontal stress is N45E. In this paper, a typical and successful comprehensive evaluation of the stress field of the deep tight sandstone oil reservoir is provided.     

天然气水合物降压开采过程中储层应力规律分析

为了研究天然气水合物降压开采过程的储层应力及其稳定性，运用线性多孔弹性力学和岩石力学知识，考虑水合物储层原始应力、孔隙压力、渗流附加应力及降压开采水合物过程中水合物饱和度的变化，建立了降压开采天然气水合物储层的力学模型，结合墨西哥湾某处水合物藏的基本参数，对降压开采水合物储层应力变化和开采过程的储层稳定性进行研究。结果表明：井底压力是影响水合物储层应力变化的关键因素之一；渗流附加应力在一定程度上减小了储层的应力；水合物分解储层应力发生变化，储层应力在井壁处的波动最大，井壁处是整个储层所受轴向偏应力最大的位置，因此井壁处是优先发生剪切破坏的位置；为了储层的稳定性，降压开采水合物生产压差应小于2.19 MPa。     

Simulation of paleotectonic stress fields and quantitative prediction of multi-period fractures in shale reservoirs: A case study of the Niutitang Formation in the Lower Cambrian in the Cen'gong block,South China

Reservoirs where tectonic fractures significantly impact fluid flow are widespread. Industrial-level shale gas production has been established from the Lower Cambrian Niutitang Formation in the Cen'gong block, South China; the practice of exploration and development of shale gas in the Cen'gong block shows that the abundance of gas in different layers and wells is closely related to the degree of development of fractures. In this study, the data obtained from outcrop, cores, and logs were used to determine the developmental characteristics of such tectonic fractures. By doing an analysis of structural evolution, acoustic emission, burial history, logging evaluation, seismic inversion, and rock mechanics tests, 3-D heterogeneous geomechanical models were established by using a finite element method (FEM) stress analysis approach to simulate paleotectonic stress fields during the Late Hercynian—Early Indo-Chinese and Middle-Late Yanshanian periods. The effects of faulting, folding, and variations of mechanical parameters on the development of fractures could then be identified. A fracture density calculation model was established to determine the quantitative development of fractures in different stages and layers. Favorable areas for shale gas exploration were determined by examining the relationship between fracture density and gas content of three wells. The simulation results indicate the magnitude of minimum principal stress during the Late Hercynian — Early Indo-Chinese period within the Cen'gong block is −100 ∼ −110 MPa with a direction of SE-NW (140°–320°), and the magnitude of the maximum principal stress during the Middle-Late Yanshanian period within the Cen'gong block is 150–170 MPa with a direction of NNW-SSE (345°–165°). During the Late Hercynian — Early Indo-Chinese period, the mechanical parameters and faults play an important role in the development of fractures, and fractures at the downthrown side of the fault are more developed than those at the uplifted side; folding plays an important role in the development of fractures in the Middle-Late Yanshanian period, and faulting is a secondary control. This 3-D heterogeneous geomechanical modelling method and fracture density calculation modelling are not only significant for prediction of shale fractures in complex structural areas, but also have a practical significance for the prediction of other reservoir fractures.     

Microfabric and rock properties of experimentally compressed silt-clay mixtures

Oedometric mechanical compaction tests were performed on brine-saturated synthetic samples consisting of silt-clay mixtures to study changes in microfabric and rock properties as a function of effective stress. The silt consisted of crushed quartz (∼100%) with grain size range between 4 and 40 μm, whereas the clay consisted of 81% kaolinite, 14% mica/illite and 5% microcline of grain size between 0.4 and 30 μm. Five sample pairs ranging in composition from pure silt to pure clay were compacted to 5 and 50 MPa effective stress respectively. SEM studies were carried out to investigate microfabric changes in the mechanically compacted silt-clay mixtures. The degree of alignment of the different minerals present (quartz, mica/illite and kaolinite) were computed by using an image analysis software. Experimental compaction have measured the changes in the rock properties such as porosity and velocity as a function of effective stress for different mixtures of clay and silt. Clay-rich samples showed a higher degree of mineral orientation and lower porosity compared to silt-dominated samples as a function of effective stress. Pure clay sample had 11% porosity at 50 MPa effective stress whereas the pure silt sample retained about 29% porosity at the same effective stress. The experiments showed that low porosity down to 11% is possible by mechanical compaction only. A systematic increase in strain was observed in the silt-clay mixtures with increasing clay content but the porosity values found for the 50:50 silt-clay mixture were lower than that of 25:75 silt-clay mixture. No preferential mineral orientation is expected before compaction owing to the high initial porosity suggesting that the final fabric is a direct result of the effective stress. Both P- and S-wave velocities increased in all silt-clay mixtures with increasing effective stress. The maximum P- and S-wave velocities were observed in the 25:75 silt-clay mixture whereas the minimum Vp and Vs were recorded in the pure silt mixture. At 50 MPa effective stress P- wave velocities as high as 3 km/s resulted from experimental mechanical compaction alone. The results show that fine-grained sediment porosity and velocity are dependent on microfabric, which in turn is a function of grain size distribution, particle shape, sediment composition and stress. At 5 MPa effective stress, quartz orientation increased as a function of the amount of clay indicating that clay facilitate rotation of angular quartz grains. Adding clay from 25% to 75% in the silt-clay mixtures at 50 MPa effective stress decreased the quartz alignment. The clay mineral orientation increased by increasing both the amount of clay and the effective stress, the mica/illite fabric alignment being systematically higher than that of kaolinite. Even small amount of silt (25%) added to pure clay reduced the degree of clay alignment significantly. This study demonstrates that experimental compaction of well characterized synthetic mudstones can be a useful tool to understand microfabric and rock properties of shallow natural mudstones where mechanical compaction is the dominant process.     

Estimation of seismic velocities and gas hydrate concentrations: A case study from the Shenhu area,northern South China Sea

In the Shenhu area of the northern South China Sea (SCS), canyon systems and focused fluid flow systems increase the complexity of the gas hydrate distribution in the region. It also induces difficulties in predicting the hydrate reservoir characteristics and quantitatively evaluating reservoir parameters. In this study, several inversion methods have been executed to estimate the velocities of strata and gas hydrate concentrations along a profile in the Shenhu area. The seismic data were inverted to obtain the reflection coefficient of each stratum via a spectral inversion method. Stratigraphic horizons were then delineated by tracking the inverted reflectivities. Based on the results of spectral inversion, a low-frequency velocity field of the strata was constructed for acoustic impedance inversion. Using a new iterative algorithm for acoustic impedance inversion, reflection coefficients were converted into velocities, and the velocity variations of the strata along a 2D seismic line were then obtained. Subsequently, gas hydrate saturations at well SH2 were estimated via the shale-corrected resistivity method, the chloride ion concentration method and three different rock physics models. The results were then compared to determine the optimal rock physics model, and the modified Wood equation (MWE) was found to be appropriate for this area. Finally, the inverted velocities and MWE were used to predict the distribution and concentrations of gas hydrates along the seismic line. The estimated spatial distribution of gas hydrates is consistent with that from sonic logging and resistivity data at well SH2, and with the drilling results. Therefore, this method is applicable in areas with no well data, or with few wells, and provides an effective tool for predicting and evaluating gas hydrates using seismic data.     

一门新兴的边缘科学——火山岩储层地质学

石油工业持续稳定的发展要求不断有效地寻找勘探新领域、新地区和新类型。随着国内外火山岩油气藏的发现，火山岩储层作为一种特殊的油气储层类型越来越受人们的重视。20世纪90年代末期，石油地质学中出现了一门生命力很强的边缘学科——火山岩储层地质学，其任务是深入研究火山岩油气储层的宏观展布、内部结构、储层参数分布、孔隙结构等特征以及在火山岩油气田开发过程中储层参数的动态变化特征，为油气田勘探和开发服务。其研究内容包括储层地质特征、储层物理性质及储层非均质性、储层孔隙类型与空隙结构、孔隙演化模式及其控制因素、储层地质模型、储层敏感性、储层预测与储层综合评价7个方面。     

Seal rock deformation by polygonal faulting,offshore Uruguay

Due to a lack of borehole data, reservoir and seal rock presence in frontier basins is typically inferred from seismic reflection data. However, analysis of the geometry and kinematic development of polygonal fault systems (PFS), which almost exclusively form within very fine-grained strata, provides another, largely untested method to infer reservoir and seal rock presence. We here use very high-quality 3D seismic reflection data from offshore Uruguay and a range of quantitative GIS-based techniques to document the planform and cross-sectional characteristics of a basin-scale (>6400 km²) PFS, and to investigate the role that stratigraphic variations in the Tertiary deep-water host-rock have on its geometrical variability and kinematic development. We demonstrate that a series of likely sandstone-rich deep-water deposits occur at the base of and within the main PFS tier. The geometric characteristics and throw distribution on individual polygonal faults suggest these sandstone-rich deep-water deposits represent a mechanical barrier to fault propagation, thus influencing fault height and areal density and, in some cases, strike. We argue that in largely unexplored, deep-to ultra-deep water basins, such as those characterizing offshore Uruguay, the distribution and geometric attributes of PFS can be used to delineate sandstone-rich reservoir bodies. Furthermore, these characteristics may help exploration geoscientists better understand seal heterogeneity and quality in data-poor basins.     

Changes in physical properties of a reservoir sandstone as a function of burial depth – The Etive Formation,northern North Sea

Rock physical properties, like velocity and bulk density, change as a response to compaction processes in sedimentary basins. In this study it is shown that the velocity and density in a well defined lithology, the shallow marine Etive Formation from the northern North Sea increase with depth as a function of mechanical compaction and quartz cementation. Physical properties from well logs combined with experimental compaction and petrographic analysis of core samples shows that mechanical compaction is the dominant process at shallow depth while quartz cementation dominates as temperatures are increased during burial. At shallow depths (<2000–2500 m, 70–80 °C) the log derived velocities and densities show good agreement with results from experimental compaction of loose Etive sand indicating that effective stress control compaction at these depths/temperatures. This indicates that results from experimental compaction can be used to predict reservoir properties at burial depths corresponding to mechanical compaction. A break in the velocity/depth gradient from about 2000 m correlates with the onset of incipient quartz cementation observed from petrographic data. The gradient change is caused by a rapid grain framework stiffening due to only small amounts of quartz cement at grain contacts. At temperatures higher than 70–80 °C (2000–2500 m) the velocities show a strong correlation with quartz cement amounts. Porosity reduction continues after the onset of quartz cementation showing that sandstone diagenesis is insensitive to effective stress at temperatures higher than 70–80 °C. The quartz cement is mainly sourced from dissolution at stylolites reflected by the fact that no general decrease in intergranular volume (IGV) is observed with increasing burial depth. The IGV at the end of mechanical compaction will be important for the subsequent diagenetic development. This study demonstrates that mechanical compaction and quartz cementation is fundamentally different and this needs to be taken into consideration when analyzing a potential reservoir sandstone such as the Etive Formation.     

Seismic Characterisation of Gas-rich Near Surface Sediments in the Arkona Basin, Baltic Sea

Gas in sediments has become an important subject of research for various reasons. It affects large areas of the sea floor where it is mainly produced. Gas and gas migration have a strong impact on the environmental situation as well as on sea floor stability. Furthermore, large research programs on gas hydrates have been initiated during the last 10 years in order to investigate their potential for future energy production and their climatic impact. These activities require the improvement of geophysical methods for reservoir investigations especially with respect to their physical properties and internal structures. Basic relationships between the physical properties and seismic parameters can be investigated in shallow marine areas as they are more easily accessible than hydrocarbon reservoirs. High-resolution seismic profiles from the Arkona Basin (SW Baltic Sea) show distinct ‘acoustic turbidity’ zones which indicate the presence of free gas in the near surface sediments. Total gas concentrations were determined from cores taken in the study area with mean concentrations of 46.5 ml/l wet sediment in non-acoustic turbidity zones and up to 106.1 ml/l in the basin centre with acoustic turbidity. The expression of gas bubbles on reflection seismic profiles has been investigated in two distinct frequency ranges using a boomer (600–2600 Hz) and an echosounder (38 kHz). A comparison of data from both seismic sources showed strong differences in displaying reflectors. Different compressional wave velocities were observed in acoustic turbidity zones between boomer and echosounder profiles. Furthermore, acoustic turbidity zones were differently characterised with respect to scattering and attenuation of seismic waves. This leads to the conclusion that seismic parameters become strongly frequency dependent due to the dynamic properties of gas bubbles.     

Importance of vertical effective stress for reservoir quality in the Skagerrak Formation,Central Graben,North Sea

The complex fluvial sandstones of the Triassic Skagerrak Formation are the host reservoir for a number of high-pressure, high-temperature (HPHT) fields in the Central Graben, North Sea. All the reservoir sandstones in this study comprise of fine-grained to medium-grained sub-arkosic to arkosic sandstones that have experienced broadly similar burial and diagenetic histories to their present-day maximum burial depths. Despite similar diagenetic histories, the fluvial reservoirs show major variations in reservoir quality and preserved porosity. Reservoir quality varies from excellent with anomalously high porosities of up to 35% at burial depth of >3500 m below seafloor to non-economic with porosities <10% at burial depth of 4300 m below seafloor.This study has combined detailed petrographic analyses, core analysis and pressure history modelling to assess the impact of differing vertical effective stresses (VES) and high pore fluid pressures (up to 80 MPa) on reservoir quality. It has been recognised that fluvial channel sandstones of the Skagerrak Formation in the UK sector have experienced significantly less mechanical compaction than their equivalents in the Norwegian sector. This difference in mechanical compaction has had a significant impact upon reservoir quality, even though the presence of chlorite grain coatings inhibited macroquartz cement overgrowths across all Skagerrak Formation reservoirs. The onset of overpressure started once the overlying Chalk seal was buried deeply enough to form a permeability barrier to fluid escape. It is the cumulative effect of varying amounts of overpressure and its effect on the VES history that is key to determining the reservoir quality of these channelised sandstone units. The results are consistent with a model where vertical effective stress affects both the compaction state and subsequent quartz cementation of the reservoirs.     

赤水陆相碎屑岩天然气的成藏机理

贵州赤水地区的中浅层陆相碎屑岩油气勘探长期未引起充分重视。通过对实际资料的分析、对比、研究,认为陆相碎屑岩存在侏罗系和上三叠统须家河组两套烃源岩,具有一定的生烃潜力,但气源主要来自于下伏海相地层;沟通气源层与储层的断裂系统的存在对该区的油气成藏相当重要。赤水地区中浅层陆相碎屑岩气藏成藏模式属于深生浅聚成藏组合类型,具有多期运移聚集、喜山期调整成藏的特点。     

Tracing of deeply-buried source rock: A case study of the WC9-2 petroleum pool in the Pearl River Mouth Basin, South China Sea

The identification of a deeply-buried petroleum-source rock, owing to the difficulty in sample collection, has become a difficult task for establishing its relationship with discovered petroleum pools and evaluating its exploration potential in a petroleum-bearing basin. This paper proposes an approach to trace a deeply-buried source rock. The essential points include: determination of the petroleum-charging time of a reservoir, reconstruction of the petroleum generation history of its possible source rocks, establishment of the spatial connection between the source rocks and the reservoir over its geological history, identification of its effective source rock and the petroleum system from source to trap, and evaluation of petroleum potential from the deeply-buried source rock. A case study of the W9-2 petroleum pool in the Wenchang A sag of the Pearl River Mouth Basin, South China Sea was conducted using this approach. The W9-2 reservoir produces condensate oil and gas, sourced from deeply-buried source rocks. The reservoir consists of a few sets of sandstone in the Zhuhai Formation, and the possible source rocks include an early Oligocene Enping Formation mudstone and a late Eocene Wenchang Formation mudstone, with a current burial depth from 5000 to 9000 m. The fluid inclusion data from the reservoir rock indicate the oil and the gas charged the reservoir about 18–3.5 Ma and after 4.5 Ma, respectively. The kinetic modeling results show that the main stages of oil generation of the Wenchang mudstone and the Enping mudstone occurred during 28–20 Ma and 20–12 Ma, respectively, and that the δ¹³C₁ value of the gas generated from the Enping mudstone has a better match with that of the reservoir gas than the gas from the Wenchang mudstone. Results from a 2D basin modeling further indicate that the petroleum from the Enping mudstone migrated upward along the well-developed syn-sedimentary faults in the central area of the sag into the reservoir, but that the petroleum from the Wenchang mudstone migrated laterally first toward the marginal faults of the sag and then migrated upward along the faults into shallow strata. The present results suggest that the trap structure in the central area of the sag is a favorable place for the accumulation of the Enping mudstone-derived petroleum, and that the Wenchang mudstone-derived petroleum would have a contribution to the structures along the deep faults as well as in the uplifted area around the sag.     

Constitutive model for predicting stress-strain behavior of fine-grained sediments using shear-wave velocity

Abstract

The mechanical response of a sediment to an applied stress is significantly affected by variations of material properties, state conditions, and stress states. These stress state and conditions are utilized to infer input parameters for advanced soil constitutive models. Parameters such as void ratio and effective stresses have been readily inferred from shear-wave velocities under low-strain conditions. Thus, this research aimed to develop a shear-wave velocity-based constitutive model within a critical state soil mechanics framework to predict the undrained triaxial behavior of fine-grained sediments. Laboratory tests were performed for sediment samples ranging from silt-predominant to clay-predominant sediments. As result, a new two-term power function was developed that determined mean effective stress as a function of shear-wave velocity. By virtue of this new power function, the Original Cam Clay and Modified Cam Clay critical state models were adapted to estimate the stress-strain behavior and stress paths under undrained conditions, in terms of shear velocity. In addition, correlations were developed using the state and material properties to predict the input model parameters. The developed correlations allow broad application of the proposed framework to different sediment types in which clay and silt are the dominant deposits.     

Control of the stress field on shallow seafloor hydrothermal paths: A case study of the TAG hydrothermal field

The stress state and rock mechanical properties govern the growth of faults and fractures, which constitute shallow hydrothermal pathways and control the distribution of seafloor massive sulfide (SMS) mounds in the seafloor hydrothermal field. The stress field has an important influence on the formation and persistence of hydrothermal pathways. Based on multibeam bathymetric data from the Trans-Atlantic Geotraverse (TAG) field, we establish two three-dimensional geological models with different scales to simulate the stress field, which investigate the characteristics of hydrothermal pathways and associated SMS mounds. The simulation results show that oblique faults and fissures form in the tensile stress zone and that mounds, including active and inactive hydrothermal mounds form in the compressive stress zone. Fault activity, which is related to the stress field, affects the opening and closing of hydrothermal channels and changes the permeability structure of subseafloor wall rock. Therefore, the stress field controls the development and persistence of shallow hydrothermal pathways. The features of shallow hydrothermal pathways in the stress field can provide geomechanical information that is useful for identifying favorable zone for SMS deposit formation.     

西藏比如盆地生储盖条件分析

根据野外地质调查资料和采样测试分析，对比如盆地的生油岩、储集层、盖层条件及其生储盖组合特征进行了分析。认为盆地中发育的主要烃源岩有两套，岩石类型主要为板岩，有机质类型好，热演化程度高，以生气为主；储集层主要为碎屑岩，岩性以含砾砂岩、粉砂岩、中-细砂岩为主，属于低孔、低渗型；盖层较发育，岩性主要为泥晶灰岩、板岩，厚度大；最有利的生储盖组合型式为中上侏罗统拉贡塘组自生自储自盖式。     

A statistical damage constitutive model based on unified strength theory for embankment rocks

Abstract

Fluctuant marine and reservoir water levels are the main failure-inducing factors for embankment slopes. The soft embankment rocks, e.g., red-bed mudstone, eroded by the reservoir water level in the Three Gorges Reservoir area greatly influence the stability of the embankment slopes. In this study, unified strength theory was innovatively applied for damage evaluation and combined with the Weibull distribution to obtain the strength statistics of micro units. Additionally, one damage constitutive model and one damage evolution model considering the initial damage, strain softening and damage weakening were proposed. Then, a series of tests, e.g., modified cyclic wetting and drying test, triaxial compression test and modified numerical simulation test for reservoir embankment red-bed mudstone, were conducted to verify the feasibility of the proposed models. In addition, grey system theory was originally used to evaluate the effects of the Weibull distribution parameters (m and w) and the confining stress on the peak stress. Finally, the proposed model was tentatively applied to the modification of the limit failure height model of the bedded rock slopes. The verification implies that the proposed model results are consistent with the testing results, especially in the simulation of compaction, elastic deformation and strain softening and in the prediction of peak strength. The results from grey system theory analysis indicate that the micro unit strength parameter (w) has the most obvious effect on the strength. Moreover, the modified method based on the damage evolution model for calculating the limit failure height of the bedded rock slopes is conservative.     

Fracture and in-situ stress patterns and impact on performance in the Khuff structural prospects,eastern offshore Saudi Arabia

We characterized natural fractures and in-situ stresses for exploration and prospect evaluation in nine periclinal structural traps, in the Eastern Province of Saudi Arabia, where several major gas discoveries were made in the deeply buried, Permian–Triassic Khuff Formation. Borehole image logs, oriented cores, seismic, gravity-magnetic data, and dynamic observations were used in the study. Two fracture systems were identified: a younger, major system, which enhances reservoir permeability and an older, minor, fully mineralized system. The older system consists of subordinate northerly striking extensional mesofractures, including joints and faults, which are fully mineralized by anhydrite and calcite. This mineralization occurred during an early diagenetic-phase. This system acted as paleo-fluid conduits, facilitating the occlusion of matrix porosity and deteriorating the reservoir quality in the immediate vicinity of the fractures. The younger system is regionally dominant, and includes mesofractures with persistent strike ranging from NE–SW to ESE–WNW irrespective of local structure. These younger fractures are nearly parallel to the present day maximum horizontal in-situ stress and perpendicular to the minimum horizontal in-situ stress, which are dominated by the Zagros plate tectonics. The development of this system commenced during the convergence of the Arabian and Eurasian plates (Late Cretaceous to Cenozoic) and culminated during the continental collision. The fractures are predominantly extension joints and hybrid (extensional-shear) fractures, and were facilitated by increases in pore pressure due to the oil placement and the subsequent cracking of this oil into gas. Hydrocarbon migration into the Khuff reservoirs was crucial in slowing down diagenesis and preserving both fracture apertures and matrix porosity. Therefore, most of the fractures in this system tend to be partly mineralized, mainly by carbonates, and/or coated with hydrocarbons. These fractures show channel-type apertures that enhance permeability and productivity of the Khuff by up to two fold. The channel apertures can endure operational changes in reservoir pressure with little or no reduction of their permeability. Critically stressed open fractures have no major role. Geomechanical analyses show that they are estimated to occur under the upper limits of differential stresses, within the margin of error of stress estimates. The static and dynamic observations show the permeability and productivity enhancement follows mechanical layering patterns. Production and pressure profiles in individual wells indicate lack of vertical communication (seal breach) across the different reservoir units. Similar pre-production pressure and hydrocarbons across the Khuff reservoir units is the result of normalization over geological time. Hydrocarbon migration across the anhydrite seals happened via episodic paleoseismic pumping along faults with no sufficient vertical offset to permanently breach the reservoir seals.     

下扬子区海相中、古生界上油气成藏组合特征分析

下扬子地区海相上组合（主要为中生界、上古生界）经历了印支运动、燕山运动、喜马拉雅运动的叠加改造,生、储、盖油气成藏诸要素被改造调整,海相中、古生界油气成藏条件复杂。基于海相上油气组合的成藏演化过程与时空匹配的分析,可以认为上油气成藏组合具有良好的生、储、盖配置关系;三次油气的关键充注期后,基本没有经历大的油气破坏和改造作用;成藏要素在时空上有效配置,将是下扬子地区最有油气勘探前景的海相油气成藏组合。沿江地区,处于南北对冲前缘带,是海相地层的弱变形区,地层保存相对完整,成藏配置较好,发育“古生新储”、“古生古储”的油气藏,为下扬子地区最有利的勘探区域。     

Geochemical characteristics and isotopic reversal of natural gases in eastern Kopeh-Dagh,NE Iran

Natural gas samples from two gas fields located in Eastern Kopeh-Dagh area were analyzed for molecular and stable isotope compositions. The gaseous hydrocarbons in both Lower Cretaceous clastic reservoir and Upper Jurassic carbonate reservoir are coal-type gases mainly derived from type III kerogen, however enriched δD values of methane implies presence of type II kerogen related material in the source rock. In comparison Upper Jurassic carbonate reservoir gases show higher dryness coefficient resulted through TSR, while presence of C₁C₅ gases in Lower Cretaceous clastic reservoir exhibit no TSR phenomenon. Carbon isotopic values indicate gas to gas cracking and TSR occurrence in the Upper Jurassic carbonate reservoir, as the result of elevated temperature experienced, prior to the following uplifts in last 33–37 million years. The δ¹³C of carbon dioxide and δ³⁴S of hydrogen sulfide in Upper Jurassic carbonate reservoir do not primarily reflect TSR, as uplift related carbonate rock dissolution by acidic gases and reaction/precipitation of light H₂S have changed these values severely. Gaseous hydrocarbons in both reservoirs exhibit enrichment in C₂ gas member, with the carbonate reservoir having higher values resulted through mixing with highly-mature-completely-reversed shale gases. It is likely that the uplifts have lifted off the pressure on shale gases, therefore facilitated the migration of the gases into overlying horizons. However it appears that the released gases during the first major uplift (33–37 million years ago) have migrated to both reservoirs, while the second migrated gases have only mixed with Upper Jurassic carbonate reservoir gases. The studied data suggesting that economic accumulations of natural gas/shale gases deeper than Upper Jurassic carbonate reservoir would be unlikely.