托云火山群的火山地质特征及其构造意义

结合托云盆地新生代火山岩的卫星影像解译与野外验证成果，发现托云盆地内的7个火山口和棋盘式走滑断裂系统，首次提出了托云火山群的概念．这些火山口可以划分成中心式火山和溢流玄武岩2种类型，形成的火山机构包括塌陷破火山口、火山颈和锥状岩席．火山岩主要为碱性玄武岩，部分玄武岩中可见橄榄岩类等深源岩石包体和普通辉石等矿物巨晶．因此，托云盆地新生代火山岩具有幔源岩浆的性质，断裂构造活动为其上升就位提供通道，火山岩应是由多个火山口近于同时喷发形成的，不具有由上、下两套火山岩系构成的双层结构．     

玄武质岩石的单颗粒锆石U-Pb年龄谱

报道了托云、东浮山、羊角、雪花山和山旺5处新生代玄武岩的SHRIMP锆石U-Pb测年结果。位于西南天山造山带的托云新生代玄武岩的14个测点年龄值十分发散,最大值与最小值分别为857.1和203.4Ma,它们与其余4件玄武岩样品49个SHRIMP锆石测点年龄一同构筑了涵盖各个地质时期几乎贯穿整个地质时间的复杂年龄谱。位于华北克拉通中部区域南太行山造山带的东浮山、羊角和雪花山新生代玄武岩3件样品累计36个锆石测点形成的锆石年龄谱相对简单,其中35个测点的年龄集中在1719.9～2641.6Ma,唯一的古生代年龄(311.3Ma)出现在雪花山玄武岩7.1测点。位于华北克拉通东部裂谷带内山旺玄武岩6件样品27个测点的单颗粒锆石年龄构筑的锆石年龄谱形成3个集中时间段,分别为新太古代—古元古代(2595.4～1852.2Ma)、古生代(385.8～271.1Ma)和中生代(109.4Ma)。3个年龄谱中大部分单颗粒锆石U-Pb年龄均能在各自所处区域内发现与之对应的岩浆-热事件,部分单颗粒锆石年龄可能暗示所在区域至今未发现的岩浆热事件,托云、东浮山-羊角-雪花山、山旺新生代玄武岩的复杂单颗粒锆石年龄谱再造了各自所处区域的地质演化史。3个锆石年龄谱的复杂程度与各自区域地表出露岩浆岩的规模和期次复杂程度相关,天山造山带内岩浆岩发育,托云玄武岩锆石年龄普最复杂,记录了天山造山带的演化,而华北克拉通中部区域南太行山造山带地表零星出露岩浆岩,东浮山-羊角-雪花山玄武岩的锆石年龄普最简单。处于后期遭受破坏改造的华北克拉通东部裂谷带内的山旺玄武岩的单颗粒锆石年龄谱,其复杂程度明显低于托云玄武岩的年龄谱,而又高于东浮山-羊角-雪花山玄武岩的年龄谱。鉴于玄武质岩浆同化混染围岩过程中能量消耗和地球化学印记以及玄武质岩浆上升的耗时限制,认为托云、东浮山、羊角、雪花山和山旺新生代玄武岩中具有复杂年龄信息的锆石捕掳晶不是玄武质岩浆在快速上升过程中从围岩中捕获的,而是在岩石圈拆沉过程中进入软流圈地幔中,随着具原生岩浆性质的玄武质岩浆喷发到达地表。     

西南天山新生代造山岩浆作用响应——以皮羌盆地新生代火山岩为例

新疆西南天山皮羌盆地是一个新生代火山构造盆地。盆地内出露4个古火山颈和大量岩墙,部分岩墙与火山颈相连。运用岩相学、岩石地球化学测试分析法研究皮羌盆地内火山岩,研究表明,火山岩具原生岩浆性质,及碱玄岩、碧玄岩和玄武岩岩石组合特征。火山岩产于板内造山带环境,为幔源部分熔融产物,无明显结晶分异。结合托云盆地新生代火山岩岩石地球化学探讨西南天山岩浆触发机制,认为岩石圈局部拆沉作用是触发本区岩浆活动主要机制。     

中天山东段中元古代晚期—古生代构造-热事件:SHRIMP锆石年代学证据

星星峡杂岩是中天山构造带东段出露的最老岩石,主要岩性为斜长角闪岩和各种副变质岩,并被中—新元古代花岗片麻岩和古生代片麻岩所侵位。文中利用SHRIMP定年方法,对星星峡杂岩的一个片岩和侵入其中的一个花岗片麻岩样品进行了锆石U-Pb测年。其中片岩样品中的碎屑锆石给出1800、1530和1200Ma3组大约年龄,表明其源区不仅包括古元古代和中元古代早期还含有中元古代晚期的地壳物质。在这些碎屑锆石中,最年轻的年龄为(1189±65)Ma,与该区中元古代大约1200Ma岛弧岩浆活动相近,可代表其沉积时的最大年龄。同时获得约910和470Ma的两组较年轻年龄;前者解释为变质年龄,后者为岩浆扰动年龄,与花岗质片麻岩样品的侵位时代相一致。中天山构造带东段的中元古代晚期岩浆(大约1200Ma)和变质作用(大约910Ma)的发生时间与华南、南极洲东部、澳大利亚南部和北美西南部所报道的格林维尔期增生-造山事件在时间上接近,表明中天山构造带东段与Rodinia超大陆的汇聚过程密切相关。     

吉林色洛河群的重新认识

色洛河群出露于吉林省色洛河-华集岭一带,位于华北克拉通北缘东段,长期以来一直被认为是中新元古代地层。最近的野外调查和定年研究表明,它包含了时代、成因、构造样式、变质程度不同的变质地层和变形的花岗岩,作为一个岩石地层单位已不合适,应予解体。原划分的色洛河群至少由4部分组成：新太古代变质火山-沉积地层（锆石SHRIMP年龄为2 517~2 534 Ma）、晚古生代变质火山-沉积地层（英安岩锆石 SHRIMP年龄为 252 Ma）、二叠纪片麻状杂岩体（锆石SHRIMP年龄为260 Ma）和侏罗纪糜棱岩化花岗岩（锆石SHRIMP年龄为168 Ma）。前人在色洛河一带定义的色洛河岩群为一套变质火山-沉积岩系,可能是形成于晚古生代的一套地层,也可能是由不同时代的构造岩片构成的构造杂岩。     

松辽盆地北部存在前寒武纪基底的证据

目前对松辽盆地是否存在前寒武纪结晶基底的认识存在分歧。笔者对松辽盆地北部早白垩世火山岩中锆石SHRIMP定年研究过程中,在多个样品中发现了古老锆石,其年龄表明这些锆石主要形成于前寒武纪,并且认为它们可能来源于盆地北部深层的基底岩石,是火山喷发过程中捕获的。锆石年龄大致可分为3组:(1848±34)Ma、(1600±29)Ma和(1293±41)Ma,指示了盆地基底在古元古代和中元古代期间经历的多次构造-岩浆作用事件,由此认为松辽盆地北部存在前寒武纪基底。     

广东北部碎斑熔岩加里东期锆石SHRIMP 年龄的首获及其地质意义

赣南- 粤北燕山期火山岩较为发育,并可分为下、中、上三个不同时期的火山岩系,但分布于粤北司前-赣南南迳 一带的火山岩一直缺乏可靠的同位素年龄。河口破火山口构造碎斑熔岩的锆石具有清晰的震荡环带,Th/U 比值高,属典型 的岩浆成因锆石。锆石SHRIMP U-Pb 测年结果显示,14 颗锆石15 个测点的年龄变化范围较小,为410~473 Ma,加权平均 年龄为（443.6±5.4）Ma,MSWD 为1.3,代表了碎斑熔岩的成岩年龄。根据国际地层表,河口破火山口构造碎斑熔岩形成 于晚奥陶世末期-早志留世初期,属加里东期火山活动的产物。河口破火山口构造碎斑熔岩加里东期锆石SHRIMP U-Pb 年 龄的首获,证明司前-南迳一带存在加里东期火山岩,这为赣南-粤北加里东期岩浆作用和花岗岩型铀矿成因的研究提供 了新的窗口。     

皮羌盆地新生代基性岩浆活动的年代学及其地质意义

塔里木盆地西北部卷入了西南天山新生代板内造山活动,以发育一系列北东向展布的断层和断层相关褶皱为特征,但该区新生代构造变形的原因尚存在争议。文中以皮羌盆地为例报道了新生代火成岩的地质特征和测年结果,认为构造变形是对幔源岩浆活动的浅部响应,与印度 亚洲大陆碰撞没有必然的联系。皮羌盆地出露有大量的新生代基性岩墙和4个古火山颈,岩墙群整体走向NNW和NNE,产状近于直立,侵入于新生界湖相沉积地层中。火山颈相玄武岩锆石SHRIMP U Pb定年结果为46 Ma,全岩K Ar等时线封闭年龄为(455±613) Ma,表明岩浆活动发生在始新世中期。岩浆活动时间比逆冲推覆构造启动时间(约24 Ma)早约22 Ma。按热传导模式估算,在此期间来自深部热源的热传递距离约为25 km。假定深部热源为底侵或内侵幔源岩浆,新生代岩浆活动可能是塔里木盆地西北部大规模构造变形的触发机制。     

新疆东部哈尔里克山闪长岩锆石SHRIMP U-Pb定年及其地质意义

新疆东部哈尔里克山出露大量闪长岩和花岗岩岩体。一般认为,该区晚古生代岩浆活动中,闪长岩形成比较早,花岗岩形成比较晚。对其中一个闪长岩中的锆石进行SHRIMP U-Pb定年,获得了316±3 Ma的206Pb/238U表面年龄。结合岩体及锆石的矿物学特征,该年龄被解释为代表了哈尔里克山晚古生代岩浆初始侵入活动的时间。通过与前人从博格达山和哈尔里克山获得的岩浆活动年代学资料的比较研究,得出的结论是博格达山与哈尔里克山晚古生代岩浆初始侵入活动的时间大体相同,都发生在该区地壳形成演化的后碰撞阶段;由此进一步推论哈尔里克山晚石炭世期间的构造背景与博格达山基本相同,为与康古尔塔格一带洋岩石圈板块向北俯冲有关的板缘伸展环境下的滞后弧后盆地或者是后碰撞伸展环境下的火山沉积盆地。     

华北克拉通北缘崇礼—赤城地区的红旗营子(岩)群:一套晚古生代的变质杂岩

分布在华北克拉通北缘中段崇礼—赤城地区的红旗营子(岩)群主要由变质表壳岩、晚古生代的闪长质—石英闪长质片麻岩和古元古代—新太古代的变质岩残片或残块组成。利用SHRIMP和LA-ICPMS法对红旗营子(岩)群变质表壳岩的锆石同位素年代学研究表明,变质表壳岩样品中除大量古元古代—新太古代的锆石年龄信息外,还有许多中元古代—晚古生代的锆石,且均有晚古生代甚至早中生代的多阶段变质作用的记录。这些证据表明红旗营子(岩)群并非早前寒武纪岩石建造,而是一套晚古生代的变质杂岩。红旗营子(岩)群周围侵入体的锆石U-Pb测年表明岩浆作用与变质作用具有较好的相关性,它们与中亚造山带多阶段的俯冲、碰撞造山和后造山伸展事件相关。由于红旗营子杂岩中含有晚古生代退变榴辉岩和变质方辉橄榄岩,这可能意味着华北克拉通北缘的冀北地块在晚古生代早期曾经从华北克拉通上裂开,在中亚造山带古亚洲洋板块俯冲作用的影响下又重新拼合,红旗营子杂岩代表华北克拉通北缘的冀北地块与华北克拉通在晚古生代重新拼合的俯冲碰撞拼贴带。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

Mountains,nations, parks,and conservation

Between 1985 and 1991, two new mountain protected areas (MTNPA) covering more than 35,000 km² and based on participatory management models — the Makalu-Barun National Park and Conservation Area, Nepal, and Qomolangma Nature Preserve, Tibet Autonomous Region — were successfully established through the collaborative efforts of Woodlands Mountain Institute and conservationists in China and Nepal. Characteristics common to both projects include the importance of establishing (1) effective rationales, (2) local support constituencies, (3) a senior advisory group, (4) a task force, (5) linkages between conservation and development, and (6) fund raising mechanisms. The lessons derived from the experiences of Woodlands Mountain Institute are of significant value to others in preserving MTNPA. Increased collaboration and communication between all interested in conservation, however, will remain a critical component for expanding mountain protected area coverage to throughout the world.     

Regional distribution of Al,B, Ba,Ca, K,La, Mg,Mn, Na,P, Rb,Si, Sr,Th, U and Y in terrestrial moss within a 188,000 km2 area of the central Barents region: influence of geology,seaspray and human activity

Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km² area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).     

NEW SET OF LOW CONCENTRATION STANDARDS FOR LA, CE, SM, YB, LU, Y, SC, V, NB AND TA IN SILICATES

We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al₂O₃-SiO₂ ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses.