1994 COMPILATION OF ANALYTICAL DATA FOR MINOR AND TRACE ELEMENTS IN SEVENTEEN GSJ GEOCHEMICAL REFERENCE SAMPLES, "IGNEOUS ROCK SERIES"

Analytical data for minor and trace elements published or communicated to us, on seventeen GSJ (Geological Survey of Japan) reference samples, "Igneous rock series" received up to April 1994 are compiled. The data were evaluated statistically in consideration of analytical methods. Based on the selected available data, 1994 recommended and proposed values for 65 minor and trace elements are presented.     

1986 Values for Fifteen GSJ Rock Reference Samples, "Igneous Rock Series"

During the five-year period (April 1981 - March 1986), a series of fifteen rock reference samples, "Igneous rock series", has been prepared by the Geological Survey of Japan (GSJ). Based on the data available (published and communicated), consensus values for major, minor and trace elements have been derived; these values are presented for this second series of samples as well as for the first series of two samples, Granodiorite JG-1 and Basalt JB-1.     

MAJOR, TRACE AND RARE-EARTH ELEMENTS IN FOURTEEN GSJ REFERENCE SAMPLES. DETERMINATION BY X-RAY FLUORESCENCE SPECTROMETRY AND INDUCTIVELY COUPLED PLASMA OPTICAL EMISSION SPECTROMETRY

Major and trace elements have been determined by wavelength dispersive X-ray fluorescence and by inductively coupled plasma optical emission spectroscopy (ICP-OES), in the Geological Survey of Japan Igneous rock series, using a routine sample preparation technique including lithium borate fusion. Samples were analysed for 10 majors elements and the following trace elements: Ba, Co, Cr, Ga, Nb, Sc, Sr, V, Y, Zn and Zr. The rare-earth elements were determined only by ICP-OES following separation by ion exchange. In most cases, results compared well with published values.     

NEUTRON ACTIVATION ANALYSIS OF FIFTEEN GSJ IGNEOUS ROCK REFERENCE SAMPLES

Fifteen rock reference samples "Igneous rock series" issued by the Geological Survey of Japan were analysed for up to 31 elements by neutron activation analysis (NAA); 14 MeV-NAA for Si and Al, fission track method for U, radiochemical and instrumental NAA for rare-earth elements, and instrumental NAA for the remaining elements, with reactor neutrons for the latter three. The present results are compared with published values.     

准噶尔盆地腹部陆西地区二叠系-石炭系火山岩地球化学特征及构造背景分析

通过对准噶尔盆地腹部陆西地区基底二叠系佳木河组-石炭系107个火山岩样品的全岩元素分析表明,其中38.7%属钙碱性系列,碱性系和强碱性系列占61.3%.该区火山岩不仅在纵向上分异、演化特征明显,在平面上也存在明显的分区分带性.研究表明,陆西地区火山岩喷发的构造环境具有岛弧体系特征,同时由于火山岩的主量元素和微量元素均具有明显的大陆稳定构造区派生的碱性火山岩特征,说明其岩浆源深度较大,可能为上地幔或洋壳物质在高等选择性熔融条件下形成.因此盆地腹部陆西地区火山岩的喷发环境应该是在岛弧发展后期,属于岛弧近大陆一侧、在地壳增厚的环境下喷发.     

TRACE ELEMENT DETERMINATIONS FOR USGS BASALT BHVO-1 AND NIST STANDARD REFERENCE MATERIALS 278, 688 AND 694 BY INDUCTIVELY COUPLED PLASMA-MASS SPECTROMETRY

Results are presented for 26 to 30 trace elements determined in four rock reference materials of geochemical interest: USGS Basalt BHVO-1, Rhyolite Obsidian NIST 278, Basalt NIST688, and Phosphate Rock NIST694. Determinations were made by inductively coupled plasma mass spectrometry (ICP-MS). Good agreement was obtained among solution standard comparison and standard addition analytical techniques, and among samples prepared with different dissolution methods. Generally good agreement was obtained between determined trace element values and values reported in the literature.     

湘东南汝城盆地火山岩的元素地球化学及源区性质讨论

湘东南汝城盆地火山岩系由辉绿岩、玄武岩和玄武质火山碎屑岩组成 ,属于低钾拉斑玄武岩系。玄武岩全岩K Ar年龄为 ( 12 8 4± 4 2 )Ma ,辉绿岩全岩K Ar年龄为 ( 112 1±3 2 )Ma。元素地球化学分析表明火山岩系具有同一岩浆源区 ,其形成以部分熔融方式为主。岩石微量元素出现大离子亲石元素Rb、Ba、Th、U的富集和高场强元素Ta、Nb、Ti的亏损。强不相容元素含量的比值表明岩浆源区明显偏离原始地幔组分 ,具有富集型地幔的特征。岩浆源区主要受到地壳物质混染以及来自消减残留板片析出流体的交代改造作用。     

甘肃昌马地区早寒武世地层中辉绿质次火山岩地球化学特征及构造背景

利用已有的资料,将昌马平头山一带早寒武世地层中的辉绿质次火山岩时代限定为早寒武世,辉绿质次火山岩主量元素以高钠、镁、钛,低钾为特征,属钠质碱性系列,稀土总量（∑REE）较低,轻、重稀土分馏作用明显,无铕异常,球粒陨石标准化配分曲线具平滑的特征,N-MORB标准化蛛网图上,呈现大离子亲石元素（LILE）富集,微量元素值约...     

Mass change calculations in altered rock series

A technique is presented whereby precursors of altered rocks in a fractionated rock series can be identified, and changes in chemical components, mass and volume accurately calculated. The procedure utilizes elements with high degrees of immobility in hydrothermal and associated interactive water-rock systems. Igneous rock series, and sedimentary and metamorphic rocks with primary continuity of chemical composition, are amenable to this treatment. In the procedure for igneous rocks, best-fit fractionation lines are established for an immobile igneous compatible-incompatible element pair, the latter element functioning as the fractionation monitor. Alteration paths are linear and pass through the origin. Intersections of the fractionation and alteration lines yield the immobile element concentrations in the precursors to the altered rocks; mobile components are determined from fractionation lines and monitor values. Total mass changes are proportional to the displacement of altered samples from the fractionation line. Masses of other elements in an altered sample (reconstructed values) are recalculated to the concentration of the monitor element in the precursor. Chemical changes are the differences between the calculated precursor compositions and the reconstructed altered rock compositions. Errors are mainly a function of the positioning of the fractionation lines.     

中甸晚三叠世图姆沟组岩石化学与构造环境

本文对中甸东部晚三叠世图姆沟组深水浊积岩和弧火山岩、微量和稀土元素进行研究,投点多落入再旋回造山带物源区;微量和稀土元素与图解中多接近大陆岛弧区;常量元素分析与相关图解接近活动大陆边缘和大陆岛弧环境,与火山岩的大地构造环境具有相同的结论。图姆沟组为甘孜—理塘洋盆向西俯冲消减,中甸褶皱带东缘由被动大陆边缘转化为活动大陆边缘过程中形成的岛弧火山—沉积岩系。     

南堡凹陷沉积岩化学元素分布特征及多元统计方法研究

对南堡凹陷Ed₁亚段、Ng_下、Ng_上、Nm_底地层的75个沉积岩样品进行了主量、微量元素分析,结果表明粒度效应造成砂岩和泥岩元素丰度明显不同,砂岩除富集K、Na、Sr、Ba、Si外,其余元素均较泥岩亏损.根据地层垂向上元素丰度由高—低—高的变化规律,可将这4个亚段分为Ed₁、Ng_下和Ng_上、Nm_底3个阶段,与凹陷构造演化特征响应.因子分析、聚类分析等多元统计方法表明,表生环境中元素具有不同的迁移富集规律,Ca、Na、Sr等具有较强的活动性,Zr、Hf等少数元素则在粗粒级中含量较高,而其余元素则多在黏土粒级中富集.元素在表生环境中地球化学行为的不同主要受化学结构特征控制,沉积环境对其也有影响.     

电弧蒸发回收装置及其在化探样品分析中的应用

为解决天然样品中元素的赋存状态及样品粒度对粉末法光谱分析的影响,本文根据苏联文献中的不完整资料,解决了设计上、材料选择上和工作条件选择上等一系列技术问题,重新设计制造了“电弧蒸发回收”装置。该装置采用电弧蒸发和静电集尘回收原理,使各种复杂的天然物质转变为简单的氧化物,回收物的粒径可达0.1μm以下。该装置不仅适用于中高含量范围,也适用于痕量元素样品的预处理。经该装置预处理的样品与撒样法和ICP粉末法相结合均取得了较好的分析效果。     

NEW REFERENCE SAMPLES OF MAGMATIC ROCKS: QUARTZ DIORITE SKD-1 AND SVIATONOSSITE SSV-1

The preparation and study of the two rock reference samples, Quartz Diorite SKD-1 and Sviatonossite SSv-1, are described, along with mineralogical and petrographic features. After its homogeneity studies, the two samples were analysed by seventy-five former USSR laboratories in the framework of an interlaboratory analytical program. The two samples have been certified respectively for 41 and 39 major, minor and trace elements; additionally, values are proposed for about 20 trace elements. The compiled data on the two samples are presented as an Appendix. Both the samples, processed in about 280 kg, form now part of the set of eight magmatic rock reference samples prepared by the Institute of Geochemistry in Irkutsk.     

云南白马寨镍矿区煌斑岩地球化学Ⅰ.主要元素和微量元素

云南白马寨镍矿区煌斑岩呈岩墙和岩脉穿切矿区各时代地层、基性-超基性岩和矿体，为成矿期后产物；采自矿区不同中段和不同产状的煌斑岩具有相似矿物组合，岩石类型均为云煌岩；岩石化学特征表明岩石均为钾质-富钾质钙碱性煌斑岩；微量元素配分模式为相似的“骆峰型”，与MORB相比，富集LILE和HPSE；REE配分模式为相似的LREE富集型；主要元素和微量元素与镁指数(M值)之间存在一定的相关关系；在La—La／Sm图中样品既有水平分布趋势、也有倾斜分布趋势。总体上，该区煌斑岩为相同岩浆源区的产物，源区地幔部分熔融程度和岩浆结晶分异作用对岩石主要元素和微量元素地球化学性质均有一定的影响。比较老王寨金矿区煌斑岩形成地质背景、岩石类型、主要元素和微量元素地球化学特征，认为两地区煌斑岩地幔源区具有相同或相似、的性质。     

阿尔金地块南西缘钙碱性侵入岩带特征及其地质意义

阿尔金地块南西缘钙碱性侵入岩带由余个大小不等的花岗岩体组成,其岩石类型主10要有石英闪长岩、英云闪长岩、花岗闪长岩、二长花岗岩。对带内有代表性岩体的岩石矿物学、岩石化学、微量元素、稀土元素及同位素地球化学研究表明,其属钙碱性系列,具有同源岩浆演化特征,其形成环境为活动大陆边缘。花岗闪长岩全岩—等时线年龄为,确定为晚震RbSr575 Ma旦世产物。这一发现,对于深入研究阿尔金地块活动机制,再造震旦期造山过程有一定作用。     

广西中峰、牛塘界、大湾等地花岗岩(类)微量元素特征

本文根据1:5万中峰公社幅及百里村幅区调资料,系统地采集了2080个岩石样品,用光谱半定量测定了22个元素。对不同时代不同期次花岗岩中微量元素的分布特征进行了研究,并对其含矿性进行了评价。     

香山群辉绿岩地球化学特征及其构造背景

现有地质资料分析,把发育于香山群第三亚群辉绿岩时代下限定为早古生代。辉绿岩主元素以高钠、镁,低钾、钛为特征。稀土总量(∑REE)较低,轻、重稀土分馏作用不明显;基本不显示Eu异常,球粒陨石标准化配分曲线具有平缓的特征。与原始地幔相比,微量元素值约是原始地幔标准值的2~10倍,大离子亲石元素(LILE)相对亏损,高场强元素(HFSE)分布平坦且不分异;N-MORB标准化蛛网图上,呈现大离子亲石元素(LILE)富集特征。地球化学特征表明:辉绿岩属于大洋拉斑玄武岩系列,显示了伸展作用的构造背景。另外,结合岩石学、沉积背景和同构造期岩套特征分析,再次验证了在中晚寒武世,阿拉善地块南缘与鄂尔多斯地块西南缘具离散型大陆边缘性质。     

X射线荧光光谱法测定高锶高钡的硅酸盐样品中主量元素

用百分总和检查硅酸盐岩石全分析数据的质量是分析工作者的传统做法,但对于微量元素含量较高的样品,采用X射线荧光光谱法(XRF)进行测定,如果不考虑微量元素的含量及其对主量元素基体效应的影响,往往会使主量元素含量更加偏离真实值。本文针对Sr、Ba含量较高的硅酸盐样品,通过人工配制标准样品,扩大了Sr、Ba校准曲线的定量范围,主量元素校准中加入Sr、Ba的基体校正系数,达到了主量元素定量更加准确可靠的实际效果。采用此方法分析国家标准物质,各主量元素的精密度(RSD)均小于2%;分析不参加回归的标准物质和人工配制的标准样品,主量元素的测量值与标准值(或参考值)基本一致。该方法可以满足硅酸盐的测定要求,主量元素各项结果的加和能够达到《地质矿产实验室测试质量管理规范》的一级标准(99.3%～100.7%)。     

中国东部地壳元素丰度与岩石平均化学组成研究

迄今我们习用的地壳化学元素丰度和岩石平均化学组成的文献值大多是收集的汇编数据,不少微量元素特别是贵金属等难测元素的丰度所依据的样品的代表性和测试质量难以考证,其值存在着颇大的不确定度。本研究立足于实测资料,在中国东部系统采集了各类火成岩和变质杂岩体及各时代的标准地层剖面岩石样品28253个,组合成2718个分析样。采用中子活化等15种可靠分析方法测试,以国家一级标准物质作质量监控。求得的华北地台地壳、中国东部上地壳和出露地壳及各类岩石的78种化学元素丰度,显著改善了地壳和岩石的化学元素丰度,填补了多种岩石微量元素丰度的空白。     

新疆卡乌留克塔格铁磷矿地质及地球化学研究

卡乌留克塔格铁磷矿,赋存于塔里木地台北缘库鲁克塔格断隆南侧的基性-超基性杂岩体内低品位特大型矿床.通过对该矿床含矿杂岩体特征、杂岩体岩石化学组成、微量元素、稀土元素组成与矿床特征以及铁、磷选矿试验研究并对铁、磷、钛、稀土元素综合利用前景的分析.认为含磷岩石相属偏碱性铁质岩系列;杂岩体中主微量元素明显不和谐,岩石中不相容...