Hydrological processes in the Amur Liman

Data collected in 2005–2009 are analyzed to study the main features of hydrological processes in the main part of the Amur estuary—the Amur Liman. Data on the morphological structure of the liman and the surge and tidal phenomena are analyzed. The variability of salinity field in different phases of river hydrological cycle is studied. Wind currents are shown to have an appreciable effect on the water exchange and river runoff distribution between the seas of Japan and Okhotsk in the ice-free season. In summer, the Amur runoff enters the Sea of Okhotsk. The main features of the structure of liman water in summer are identified. The northern part of the estuary is freshened by river runoff and partially mixed; it has a two-layer structure. A salt wedge forms at the northern exit from the liman into the Sea of Okhotsk, and strong water stratification is observed there.     

The Rate of Oxygen Release from Freshwater Bodies

The annual regimes of estimated rates of oxygen and carbon dioxide exchange between water surface and the atmosphere was compared for two water bodies with different sizes and hydroecological conditions: the deep oligotrophic Lake Baikal and the small mesotrophic–eutrophic Mozhaisk Reservoir with water exchange rate 150 times greater than that of Baikal. The obtained, very large, differences between the rates of gas evasions and invasions in the lake and the reservoir allow the rates of these processes to be used as integral characteristics for the parameterization of the self-purification capacity of freshwater bodies from organic pollutants.     

Water quality and fisheries in the Mersey estuary, England: A historical perspective

The Mersey estuary, NW England, once had a prolific fishery but in the aftermath of the industrial revolution water quality and fisheries declined and the Mersey became infamous as one of the most polluted rivers in Europe. Until relatively recently, almost all industrial and domestic effluents were discharged without treatment resulting in abominable fouling of the shoreline, and long anoxic reaches in the upper estuary during the summer. In addition, there were unknown biological impacts resulting from a complex mixture of dangerous substances present in the river. Over 1000 million pound has been spent to remedy this situation and there is unequivocal evidence that this has had the desired effect. Dissolved oxygen is now generally >60% saturation, salmon are now found at the tidal-limit and the estuary is becoming ever more popular for sea angling. The river is no longer an embarrassing liability but is now perceived as an important asset in the economic regeneration of this region of the United Kingdom.     

Regularities of hydrological processes in the Chesapeake Bay (USA): Case study of a classical estuary

The main regularities of hydrological and hydrological-environmental processes occurring within the complex estuary, the Chesapeake Bay and the mouths of its tributaries, are discussed. The peculiarities of the estuary morphological structure, including the structures of tidal and net currents, salinity and water turbidity fields and their variability, the environmental conditions, and their human-induced changes. Using the Chesapeake Bay as an example, it became possible to reveal the basic features of classical estuaries subject to a considerable impact of river runoff and featuring mixing of river and sea water and moderate stratification of the water mass. It is shown that the regularities of hydrological processes in the Chesapeake Bay are typical of many mouth water bodies of estuarine type (inlets, drowned river valleys, lagoons, and tidal estuaries proper).     

Die gaschromatographische Bestimmung von Diethylentriaminpentaessigsäure in Oberflächenwasser

Gaschromatographic Determination of Diethylenetriaminepentaacetic Acid in Surface Water. A method for the determination of diethylenetriaminepentaacetic acid (DTPA) is reported. The determination is based on the preconcentration on a strong base anion exchange resin, esterification with n-propanol and following gaschromatographic separation using a N-selective detector. The sensitivity of the method, including enrichment, is 1 μg/L in river water. The identity of DTPA in river water was proved by mass spectrography. The method can be used also for the quantitative determination of nitrilotriacetic acid (NTA), ethylenediaminetetraacetic acid (EDTA), cyclohexanediaminetetraacetic acid (CDTA) and ethyleneglycolbis-(2-aminoethylether)-N,N,N′,N′-tetraacetic acid (EGTA). The method was used to examine river water. An investigation along the river Rhine, taking grab samples from January and february 1992 showed that DTPA was present in some sampling places in similiar concentrations as NTA and EDTA.     

太湖流域太浦河周边区域突发水污染潜在风险评估

太浦河是太湖流域重要跨省界河流,沿岸区域污染源众多,下游分布重要水源地,存在突发水污染潜在风险,迫切需要开展区域污染源潜在风险评估,为突发水污染事件的风险防控提供科学依据.本研究通过太浦河周边区域的污染源调研,明确污染源的空间分布与污染源强,确定评估区域的主要污染物（化学需氧量、氨氮、锑、重金属铬、油品、危险化学品）,综合考虑污染源、河流水文、沿岸社会经济等因素,筛选突发水污染潜在风险评估指标,构建评估指标体系,评估突发水污染事件的综合风险,识别太浦河周边区域的主要突发水污染潜在风险源.研究结果表明：太浦河周边区域的高突发水污染风险区呈现片状或斑块状分布,主要包括大型污水处理厂区域、大型工业企业区域、加油站和危险化学品仓库集中分布区、太浦河沿岸工业企业区域、水源地周边工业企业区域,总面积为22 km²,占太浦河污染源风险评估范围总面积的1.4%,是突发水污染事件防控的重点区域.     

Cadmium and manganese distributions in the Hudson River estuary: interannual and seasonal variability

Surface waters collected along the salinity gradient of the Hudson River estuary in four cruises between 1995 and 1997 were size-fractionated into particulate (>0.45 μm), ‘dissolved' (<0.45 μm), colloidal (10 kDa, 0.45 μm) and low molecular weight (<10 kDa) phases. Dissolved Cd concentrations (range: 0.11–1.19 nM) in surface waters of the estuary appear to have decreased fourfold (from an average of 2.36 to 0.61 nM) over a 23-year period, since the initial analysis of samples collected in the 1970s by Klinkhammer and Bender [Estuar. Coastal Shelf Sci. 12 (1981) 629–643]. This interannual decline reflects improvement in sewage treatment and the elimination of industrial Cd sources to the Hudson River estuary. In contrast, dissolved Mn levels (range: 0.033–1.46 μM) have remained relatively constant over the same period of time, suggesting that anthropogenic sources have very limited impact on Mn concentrations in the estuary. The concentrations of both Cd and Mn appeared to strongly depend on the season and/or river discharge. The highest concentrations were detected under low freshwater discharge, implying that limited hydraulic flushing allows a build-up of metals in the water column. Although the decline in Cd levels within the estuary reflects a reduction in the magnitude of anthropogenic inputs, mass balance estimates indicated that current sources of Cd to the estuary include sewage discharges (in the lower estuary around Manhattan) and diagenetic remobilization from industrial Cd deposited in sediments nearly 2 decades ago (in the upper estuary near Foundry Cove). Moreover, under low river discharge, the sources considered in our model (sewage, riverine input, atmospheric deposition, and benthic fluxes) could account for no more than 60% of the Cd exported from the lower estuary to the ocean. This suggests that undefined sources such as ground water and inputs from other watersheds (e.g., Long Island Sound and Newark Bay) may potentially influence the water quality of the New York Harbor. The size-fractionated metal concentrations indicated that most of the traditionally defined ‘dissolved' Cd and Mn consisted of <10 kDa molecular weight species. High molecular weight colloidal species of Mn accounted for about 50% of the dissolved fraction at the riverine end-member and <5% at intermediate and high salinities. Colloidal Cd accounted for <6% of the dissolved phase throughout the estuary. Unlike the non-conservative excess (relative to ideal dilution of river water and seawater) of dissolved Mn observed along the estuary, high molecular weight colloidal Mn appeared to be removed at the head of the estuary. The small contribution of colloidal Cd and Mn to the ‘dissolved' phase suggests that remobilization from suspended particulate phases and/or from sediments occurs through the formation of small molecular weight species.     

The influence of river discharge on tidal damping in alluvial estuaries

The tidal range, the difference between high water level and low water level, along an alluvial estuary can be described by Savenije's analytical equation [Journal of Hydrology 243 (2001) 205-215] analytical equation. This equation was derived from the complete St Venant equations in a Lagrangian reference frame. In the derivation of that equation the effect of river discharge was disregarded. Measurements in the Schelde Estuary show that this assumption is only valid in the lower part of the estuary, but that in the upper part the river discharge has an influence on tidal damping. In the downstream part of the estuary, where the cross-sectional area is large compared to the cross-sectional area of the river, it is correct to disregard the river discharge. However, in the upstream part of the estuary, where the cross-sectional area approaches that of the river, the fresh water discharge gains importance over the tidal flow and affects the tidal range. In this paper, the derivation of the analytical equation is expanded to include the effect of the river discharge. It is demonstrated that the river discharge can have a considerable influence on tidal damping in the upper reach of the estuary. The river discharge affects tidal damping primarily through friction. A critical point along the estuary is the point where there is a single slack, upstream of which the fresh water velocity is larger than the tidal velocity. The location of this point varies with the river discharge. From that point onwards the effect of river discharge on damping is dominant. It is the point where the estuary becomes primarily of riverine character.     

Formation of surface water quality in the basin of the upper reaches of the ural river under technogenic transformation of the environment

The natural conditions and the anthropogenic factors governing the formation of the environmental-hydrochemical situation in the rivers of the upper part of Ural R. basin are analyzed. Pollution transport is partially taking place under the conditions of hampered water exchange, caused by the structure of river channels and runoff regulation. The study confirms the uneven distribution of heavy metal concentrations in river water in different seasons, which is mostly due to differences in river runoff characteristics. The long duration and the high intensity of anthropogenic impact have considerably weakened the stability of river systems.     

State of heterotrophic bacterioplankton of Yenisei estuary and the zone of Ob–Yenisei discharge in autumn in relation with environmental factors

In September 2011, variations of the total abundance of bacteria were studied, including, for the first time, the abundance of bacteria with intact membranes and active electron transport chains, as well as chlorophyll a concentrations and some hydrological and hydrochemical characteristics of water in Yenisei estuary and the zone of Ob–Yenisei river discharge. The study found abundant, viable, and actively functioning bacterioplankton to exist in the region. The absolute values of all microbiological characteristics were found to decrease with the distance from the freshened waters of Yenisei estuary toward the seawater of the Ob–Yenisei river discharge, while the percentage of bacteria with intact membranes and actively functioning microorganisms in bacterioplankton increased in the same direction. Positive correlations were found to exist between the values of all examined microbiological characteristics and the concentration in water of chlorophyll a, silicium, organic nitrogen, and oxygen, as well as water temperature. The same biological characteristics showed negative correlations with water salinity and phosphates. The spatial distribution of bacteria in the examined water body was supposed to be due mostly to the intensity of hydrodynamic processes, rather than the biogenic matter content of water.     

Temporal and spatial variability in the Guadalquivir estuary: a challenge for real-time telemetry

Meteorological, hydrological, and hydrodynamic data for 3 years (2008–2010) have been used to document and explain the temporal and spatial variability of the physical–biogeochemical interactions in the Guadalquivir River Estuary. A real-time, remote monitoring network has been deployed along the course of the river between its mouth and Seville to study a broad range of temporal scales (semidiurnal, diurnal, fortnightly, and seasonal). This network consists of eight hydrological monitoring stations capable of measuring temperature, conductivity, dissolved oxygen, turbidity, and chlorophyll fluorescence at four depths. In addition, six stations have been deployed to study hydrodynamics, obtaining 20-cell water column current profiles, and there is a meteorological station at the river mouth providing data for understanding atmospheric interactions. Completing this data-gathering network, there are several moorings (tide gauges, current/wave sensors, and a thermistor chain) deployed in the estuary and river mouth. Various sources of physical forcing, such as wind, tide-associated currents, and river discharge, are responsible for the particular temporal and spatial patterns of turbidity and salinity found in the estuary. These variables force the distribution of biogeochemical variables, such as dissolved oxygen and chlorophyll fluorescence. In particular, episodes of elevated turbidity (when suspended particle matter concentration >3,000 mg/l) have been detected by the network, together with episodes of declining values of salinity and dissolved oxygen. All these patterns are related to river discharge and tidal dynamics (spring/neap and high/low tide).     

Assessments of Potential Spatial‐temporal Variations in Phosphorus Distribution and Fractionation in River Bed Sediments

Sediment characteristics influence the distribution and bioavailability of phosphorus (P) in river sediments. In this study, we analyzed different P fractions in the sediments of the Bronx River, New York City, NY, using sequential extraction. The results showed that the average P pool rank order was HCl?P > NaOH?P > NaHCO₃?P > residue?P, and their relative proportions were 3.7: 2.0: 1.4: 1 in sediments collected in 2006, while HCl?P > NaOH?P > residue?P > NaHCO₃?P, with their relative proportions of 27.8:6.2:2.7:1 in the sediments obtained in 2007. The strong correlation between microbial P and organic P (OP), along with the changes in microbial P over time indicate that most of the OP in the river bed sediments is potentially bioavailable. The sediment transport, deposition, assimilation, the exchange of P between sediments and water columns, the land use changes, raw sewer discharge, gas spill, construction, fertilizer application, etc., as well as the hydro‐climatic changes could result in the spatial and temporal variations in P bioavailability in the river bed sediments. The estimations of P pools and their bioavailability in river bed sediments could help determine the spatial and temporal variations in P transport and impacts of land use on water quality, in turn, help regulate P in the river's watershed.     

Beschaffenheitslängsschnitt eines Flußgebietes mittels Regressionsanalyse

Following a general representation of the regression analysis, especially concerning the relations between flow and concentrations of matter and loads, these relations are represented and discussed for the suspended solids, nitrate concentration, chloride content and oxygen concentration for seven sections of the Spree river. There result clear connections to the structure and utilizations of all of the parts of the river basin. Finally, the covering of the total river basin by models of water quality management in the form of regression, self-purification and eutrophication models-and their coupling is represented.     

Development of a three‐dimensional watershed modelling system for water cycle in the middle part of the Heihe rivershed,in the west of China

A three‐dimensional numerical modelling system is developed to study transformation processes of water resources in alluvial fan and river basin along the middle reaches of the Heihe River Basin, Northwest China, an arid and semi‐arid region. Integrating land utilization, remote sensing and geographic information systems, we have developed a numerical modelling system that can be used to quantify the effects of land use and anthropogenic activities on the groundwater system as well as to investigate the interaction between surface water and groundwater. Various hydraulic measurements are used to identify and calibrate the hydraulic boundary conditions and spatial distributions of hydraulic parameters. In the modelling study, various water exchanges and human effects on the watershed system are considered. These include water exchange between surface water and groundwater, groundwater pumping, lateral water recharges from mountain areas, land utilization, and infiltration and evaporation in the irrigation and non‐irrigation areas. The modelling system provides a quantitative method to describe spatial and temporal distributions and transformations between various water resources, and it has application to other watersheds in arid and semi‐arid areas. Copyright © 2011 John Wiley & Sons, Ltd.     

Metal contents in Porites corals: Anthropogenic input of river run-off into a coral reef from an urbanized area, Okinawa

In order to monitor pollutants from urban areas to coral reefs, metal contents in Porites coral samples collected from the Hija River mouth and at nearby sites from the estuary were analyzed. The corals were cleaned by oxidative and reductive treatments to effectively eliminate detritus and organic materials. Metal-to-calcium (Me/Ca) ratios in the samples were determined by ICP-MS. Filtered samples of river water were also measured similarly for metal concentrations. The extent of anthropogenic contribution by riverine input was assessed by comparing the Me/Ca values in corals to those of Rukan-sho, an unpolluted coral reef. High riverine inputs of Mn, Cd, Zn and Ag were observed from Me/Ca values in the coral samples. Manganese in the coral samples showed strong dependence on salinity, varying inversely to the distance from terrestrial sources. Considering a lead background of 25.0 nmol/mol measured in the Rukan-sho corals, Pb/Ca in corals of the Hija River estuary that are two and three times higher may indicate lead enrichment in the river mouth. Because Pb is only moderately high in the Hija River water compared to its concentration in surface seawater, lead may have accumulated in the estuarine water and sediments, resulting in an elevated concentration of lead available for coral uptake.     

Scales and magnitude of hyporheic,river–aquifer and bank storage exchange fluxes

Many studies have investigated the exchange processes that occur between rivers and groundwater systems and have successfully quantified the water fluxes involved. Specifically, these exchange processes include hyporheic exchange, river–aquifer exchange (groundwater discharge and river loss) and bank storage exchange. Remarkably, there are relatively few examples of field studies where more than one exchange process is quantified, and as a consequence, the relationships between them are not well understood. To compare the relative magnitudes of these common exchange processes, we have collected data from 54 studies that have quantified one or more of these exchange flux types. Each flux value is plotted against river discharge at the time of measurement to allow the different exchange flux types to be compared. We show that there are positive relationships between the magnitude of each exchange flux type and increasing river discharge across the different studies. For every one order of magnitude increase in river discharge, the hyporheic, river–aquifer and bank storage exchange fluxes increase by factors of 2.7, 2.9 and 2.5, respectively. On average, hyporheic exchange fluxes are almost an order of magnitude greater than river–aquifer exchange fluxes, which are, in turn, approximately four times greater than bank storage exchange fluxes for the same river discharge. Unless measurement approaches that can distinguish between different types of exchange flux are used, there is potential for hyporheic exchange fluxes to be misinterpreted as river–aquifer exchange fluxes, with possible implications for water resource management decisions. Copyright © 2015 John Wiley & Sons, Ltd.     

Using hydrologic and hydraulically derived geometric parameters of perennial rivers to determine minimum water requirements of ecological habitats (case study: Mazandaran Sea Basin—Iran)

This paper studies one of the most important problems of dry countries that are confronted with water deficit and the competition of rivals to allocate water. Some common methods have been investigated for computing the minimum water requirement to save a river's biological activity. After a discussion of the currently used method in Iran (the Tenant Method), the application of some other methods, which are known as Hydraulic and Hydrological Methods, is illustrated. The case study is a river in the northern part of Iran and this research addresses the critical situation of this river in near future regarding the planned anthropogenic alteration and its consequences. It has been shown that the application of environmental water allocation methods that have no background in a region could be misleading. The first proposed method is the Texas Method, in which flexibility in water allocation helps to develop an integrated river management paradigm in the study area. The second preferred method is a Hydraulic Method, by which the implementation of morphological parameters or flow geometrical properties could sustain physical habitat within an acceptable range in terms of depth, width, velocity, and bed shear stress. In the case study, the Maximum Curvature Method was superior to the Slope Method. The investigation revealed that using a widely recommended slope of 1 for the discharge‐wetted perimeter function can lead to an overestimated and unacceptable discharge. The Tenant Method in respect to minimum environmental flow requirement yielded the weakest result, and it has been illustrated that its application might impose irrecoverable shock to the ecosystem. The Flow Duration Curve Method (the Q₉₅ Method), in spite of its subjectivity, showed more compatibility with the river's condition in comparison with the Tenant Method. Copyright © 2011 John Wiley & Sons, Ltd.     

Spatial and Temporal Variability of Biogenic Elements Flow and Water Quality in a Small River

Regularities of the formation of biogenic elements flow and water quality in the Istra River (downstream of the Istrinskoye Reservoir) and its tributaries are revealed. Temporal variability in water quality parameters is shown to be closely related to fluctuations in the river water abundance, whereas spatial variability is determined by different intensity of anthropogenic load on river watersheds. It was found that the mean annual (for the period of 1991–1995) concentrations of nitrogen and phosphorus mineral compounds do not always meet the requirements of drinking water supply. A method of estimating the environmental state of the main river, taking into account biogenic elements input from its basin is suggested.     

Evolution of particle size and concentration in the Rhône river mixing zone: : influence of salt flocculation

The salt induced flocculation phenomenon is often proposed as a major mechanism influencing the deposition of the suspended matter near the mouth of major rivers. However, depending on the particular mixing conditions between fresh water and marine water and on suspended solids (SS) reactivity, salt induced aggregation may be a minor factor controlling fast deposition of SS. This work combines field studies and laboratory experiments in order to assess the importance of salt induced flocculation in the case of the saltwedge estuary of the Rhône river. Sampling of the mixing zone has been performed in contrasted hydrodynamic conditions from a low water discharge period (500 m³ s⁻¹) to a small flood event (2400 m³ s⁻¹) for particle counting and salinity measurements. Through laboratory experiments, it is shown that the Rhône river particulate matter has a poor average reactivity regarding salt induced flocculation. Considering the hydrodynamics of the estuary, we show that the evolution of the concentration of larger particles (>5 μm) can be explained by settling and dilution. In contrast, the smallest measured fraction (2–5 μm) shows a more complex behavior and settling processes alone cannot explain the observed particle concentrations during the field studies. Four hypotheses are discussed for explaining the 2–5 μm particle concentration evolutions.     

Changes in Hydrochemical Characteristics of Water Bodies in the Southern Aral Region

Based on the hydrochemical characteristics of water bodies in the northwestern part of the southern Aral Sea region, limnic ecosystems are shown to be liable to anthropogenic changes. The dynamics of the salinity, ionic composition, oxygen content of water, and nutrients under human impact on water bodies of the southern Aral Sea region are shown.