Partizansky base-metal skarn deposit, Dal’negorsk ore district, Russia: Stages of ore formation, mineral assemblages, and typomorphism of fahlore

As indicated by mineralogical, geochemical, and structural-textural data, the base-metal skarn ore at the Partizansky deposit was formed during two stages (base-metal skarn and silver-sulfosalt), which were separated by intrusion of basaltic dikes. The bulk of the base-metal ore was deposited at the first stage, which comprises four sequential mineral assemblages: skarn-silicate, quartz-arsenopyrite, productive galena-sphalerite, and pyrrhotite-pyrite-chalcopyrite. The mineralization of the second stage was mainly confined to the upper margins of orebodies and pertains to the sulfosalt-galena-chalcopyrite assemblage, which was super-imposed on minerals of the first stage. The vertical mineralogical-geochemical zoning of the deposit is telescopic (related to the formation of the late silver-sulfosalt mineralization) and facies (typical of the early skarn and base-metal assemblages). The zoning of the skarn-silicate assemblage is expressed in the metasomatic replacement of skarn by quartz and calcite in the uppermost zone of skarn bodies and is emphasized by variation of the mineral composition throughout the skarn column, for instance, by the distinct updip enrichment of hedenbergite in manganese. The vertical zoning of the productive assemblage is emphasized by variations in the ratio of sphalerite to galena (the Pb/Zn ratio in the ore increases upward from 0.1 to 1), changes in mineral assemblages, and compositional variation of major ore-forming and minor minerals. In particular, galena from the deep levels is extremely enriched in Bi and Ag, while that from the upper levels is almost completely devoid of isomorphic admixtures. Fahlore displays updip enrichment in Sb, Ag, and Fe and corresponding depletion in Cu and Zn. The vertical chemical variations in fahlore are caused by the specific geological setting of ore deposition, the composition of the ore-forming solutions, and the physicochemical conditions of their transportation and ore deposition.     

Mercury in the Broken Hill (N.S.W., Australia) lead-zinc-silver lodes

In the Pb-Zn-Ag lodes at Broken Hill, significant Hg remains located in sphalerite and in tetrahedrite inclusions in galena, despite prograde granulite facies regional metamorphism that has resulted in recrystallization of the ore. The stratigraphically uppermost No. 3 lens has the highest Hg content, with sphalerite and galena concentrates containing up to 149,000 ppb and 198,000 ppb Hg, respectively, in Ag-Sb-rich parts of the lode.The No. 2 and 1 lenses and A lode have generally low Hg contents, but narrow tetrahedrite-rich sections contain up to 83,000 ppb Hg in sphalerite concentrates and 82,000 ppb in galena concentrates. The stratigraphically lowermost B lode has a moderately high Hg content with sphalerite concentrates containing from 4400 to 41,000 ppb Hg and galena concentrates from 30 to 21,000 ppb Hg.Programmed heating determinations showed Hg in sphalerite concentrates to be contained principally in the sphalerite structure, with subordinate amounts in tetrahedrite inclusions. Mercury in galena concentrates is almost wholly contained in tetrahedrite inclusions, with lesser amounts in dyscrasite and pyrargyrite.Piercement bodies show increased Pb, Ag, Sb, As and Hg contents due to preferential migration of galena and tetrahedrite. The Hg content of sphalerite in these bodies is approximately doubled relative to the source lode, and the Hg content of galena concentrates is increased sevenfold, due to an increase of tetrahedrite inclusions.Coarse-grained sulfide-gangue pods and pegmatites, which reflect partial melting and remobilization of parts of the lode, have a mean Hg content less than the same volume of host lode. Within these bodies Hg is strongly partitioned into sphalerite, which contains from 14,000 to 33,000 ppb Hg, whereas galena contains only from 10 to 570 ppb Hg, due to the absence of Hg-bearing tetrahedrite inclusions.Within the lode environment, trace amounts of Hg in veins formed during retrograde metamorphism are located in sphalerite which contains up to 29,000 ppb Hg.The presence of significant amounts of Hg in Ag-Sb-As minerals in a siderite-rich vein within the main lode and in the Consols lode (located 700 m from the main lode) indicates that Hg remains associated with these elements over a wide range of conditions.In the wall rocks, there is no Hg halo which is exclusive of disseminated sulfide minerals. Under high-grade regional metamorphism, trace amounts of Hg in the Broken Hill lode are retained within pre-metamorphism host minerals. However, mobilization of Hg does take place in veins associated with retrograde metamorphism after localized breakdown of tetrahedrite.     

河南西峡石板沟金矿成矿流体地球化学及矿床成因讨论

石板沟金矿是近年在豫西南发现的一个剪切带容矿的脉状金矿。根据流体包裹体地球化学研究,分析了矿床成矿流体地球化学特征,讨论了金的沉淀机制和矿床成因。构造蚀变岩型金矿的形成主要与热液蚀变作用有关,石英脉型金矿的形成,则可能主要与岩浆热液与变质热液的混合作用有关。矿质主要源自晋宁期岩浆岩,成矿流体和热能主要来自海西期花岗岩。矿床为剪切带容矿的中低温热液金矿床。     

皇城山银矿床矿物找矿标型性研究

论文给出了包括皇城山银矿床地质概况、银矿石建造矿物找矿标型性和皇城山矿物热电动势标型特征等系统资料。银矿石建造矿物标型性的主要特点是银矿物种复杂,共生金属矿物和脉石矿物富含银。论文提供了皇城山辉银矿、闪锌矿、方铅矿、黄铁矿、蓝辉铜矿、铜蓝和石英的化学成分找矿标型特征。基于皇城山黄铁矿和方铅矿热电动势资料,论文还讨论了矿体下部界线问题。本文的研究结果有助于银矿床的地质调查、找矿和勘探工作。     

夏塞银多金属矿床中硫化物和硫盐系列矿物特征及其意义

夏塞矿主档是大型的热液脉型银多金属矿床,通过对大量矿石光（薄）片观察和电子探针分析表明,除主要（方铅矿、富铁闪锌矿）和次要（黄铁矿、毒砂、磁黄铁矿、黄铜矿等）硫化物外,硫盐毓硫物十分发育,主要有Ｃｕ－Ｓｂ－Ａｇ硫盐（黝铜矿、含银黝铜矿和银黝铜矿）、Ｓｂ－Ａｇ硫盐（深红银矿、辉锑银矿）、Ｐｂ－Ｓｂ硫盐（脆硫锑铅矿、硫锑铅矿）和Ｂｉ－Ｐｂ硫盐（斜方辉饿铅矿）。此外,尚有少（微）量黄锡矿、锡石、自然饿和银金矿等。银的硫盐硫物和硫化物（辉银矿）乃是获得银的主要工业矿物,这些硫盐毓矿物常与硫化物伴生,多沿方铅矿、富铁闪锌矿、黄铁矿等的解理、裂隙或粒间产出,这些研究结果不仅有助于了解矿化作用过程,而且为矿床评价,组分综合利用和选冶提供重要依据。     

新疆尼勒克县加曼特金矿床地质及流体包裹体研究

新疆尼勒克县加曼特金矿床产于下石炭统大哈拉军山组的一套中酸性火山岩中,矿体受火山-次火山机构控制,呈脉状、透镜状产出。流体包裹体岩相学、显微测温及激光拉曼显微探针分析表明:流体包裹体为气液两相或纯液相的水溶液,属NaCl-H2O体系;均一温度主要集中在180～260℃,盐度为在(0.2～12.5)wt%NaCl.eqv,密度为0.49～0.97 g/cm3,表现为低温、低盐度、低密度的特点。因此,加曼特金矿的矿床地质和成矿流体特征总体属于中低温热液脉状矿床,可能属于斑岩型与浅成低温热液型之间的过渡型。     

Metamorphic-hydrothermal parkerite and associated minerals in the Noril’sk ore field

In the Noril’sk ore field, parkerite is a characteristic mineral of sulfide ore that metamorphosed under conditions of zeolite and prehnite-pumpellyite facies and of arsenide-calcite veins. The mineral occurs in ores containing bornite, anhydrite, magnetite, mackinawite (3–5 wt % Ni), valleriite, calcite, ankerite, native silver, native bismuth, violarite, Te-rich bismutohauchecornite, cupropentlandite enriched in Fe, Pd-rich breithauptite (1.5–2.5 wt % Pd), galena enriched in Cu (3.8 wt % Cu), and Ni arsenides and antimonides. Parkerite occurs in those place, where the primary ores have contained pockets and veins of graphic galena and chalcopyrite aggregates with associated Pt-Pd-Au-Ag minerals. Parkerite metacrysts in galena and Fe-Cu-Ni sulfides contain 6–16 and up to 5 wt % Pb, respectively. Parkerite rims replacing PGM aggregates and galena contain 1–3 wt % Pb. In calcite veins hosted in metamorphosed sulfide ores, parkerite is associated with native silver and bismuth, maucherite, cobaltite, chalcocite, and uraninite. Parkerite from these veins contains up to 0.5 wt % Pb. Thus, the Pb and Bi contents in parkerite basically depend on those of replaced minerals. Rare bismutohauchecornite is associated with parkerite.     

浙江安吉多金属矿床金银赋存状态及银矿物特征研究

安吉矿区是以热液型铅锌铜为主的多金属矿床,工程样化验结果显示,各类矿石均含有高品位的银,可以独立划分银矿体。岩矿显微鉴定、SEM/EDS及EPMA分析结果表明,矿区中的Pb、Zn和Cu主要以方铅矿、闪锌矿、黄铜矿形式存在,银与这些硫化物有密切的依存关系。对数十个典型矿石光薄片进行了研究,发现矿区多数铅锌铜矿石中金、银主要以类质同像形式存在于方铅矿、闪锌矿、黄铜矿、黄铁矿等硫化物中,金、银含量分别达0.03%~0.57%和0.02%~3%。而热液脉型铅锌矿石中的银主要以两种独立银矿物(硫锑铜银矿和银锑黝铜矿)的形式,在方铅矿之中呈粒状、短柱状、叶片状、树枝状、不规则状发育,单颗粒粒度多在10~60μm之间,少数可达100μm,集合体粒度可达200μm。另外这两种独立银矿物之中还存在类质同像形式的金,据统计,金、银含量分别达0.14%~0.35%和10.98%~69.12%。因此,方铅矿为银独立矿物的主要载体之一,且富方铅矿的矿石中更容易发现独立银矿物。     

安徽池州许桥银矿地质特征及矿区深部找矿方向

许桥银矿床位于长江中下游成矿带安庆-贵池矿集区东南部,矿床银储量达到中型规模,成矿岩体为分水岭石英闪长岩,矿体主要呈似层状赋存于分水岭岩体北东侧奥陶系仑山组、汤山组地层层间裂隙中;矿石矿物主要为黄铁矿、闪锌矿、方铅矿、黝铜矿、黄铜矿、辉银矿、自然银,脉石矿物为石英、碳酸盐矿物;矿石组构以自形-他形晶结构、交代结构、稀疏浸染状构造和网脉状构造为主;围岩蚀变类型主要有硅化、碳酸盐化、矽卡岩化、绿泥石化等;许桥银矿床成矿作用经历了两个成矿期：热液期和表生期,热液期又可分为三个成矿阶段,即为矽卡岩阶段、石英-硫化物阶段及碳酸盐-硫化物阶段;成矿流体早期以岩浆热液为主、晚期混有大气降水的流体演化特征;成矿物质主要来源于岩浆热液,地层贡献了部分矿质;成矿温度为中低温（208～259℃）,矿床类型为中低温热液银多金属矿床,并指明了矿区深部找矿方向。     

江西银山铅锌矿床闪锌矿与石英流体包裹体的对比研究

赣东北地区是我国重要的铜铅锌金银多金属矿集区,银山铅锌(银)铜(金)多金属矿床是赣东北地区一个重要的大型次火山热液型多金属矿床。银山铅锌矿发育有闪锌矿-方铅矿-石英脉,前人研究认为金属矿物与脉石矿物为伴生关系,但是没有强调它们的成因上的联系。本次研究开展了矿石矿物中闪锌矿和伴生脉石矿物中石英的流体包裹体对比研究。通过详细的岩相学观察、显微测温、显微激光拉曼探针工作,对伴生石英脉和闪锌矿内原生包裹体,伴生石英脉中的晚期微细石英脉和闪锌矿内部次生包裹体进行流体特征的对比研究。研究结果显示,伴生石英脉原生流体包裹体比闪锌矿的原生包裹体的平均均一温度高约30℃,明显富集CH₄、N₂、CH₄、CO₂等挥发份,伴生石英脉中的晚期微细石英脉流体包裹体比闪锌矿次生包裹体的平均均一温度高23℃。闪锌矿原生包裹体与想伴生的早期石英脉在平均均一温度有所差别,气相成分差异明显,均表明矿石矿物与伴生脉石矿物可能形成于不同的地质环境,具有不同的温度和流体成分。     

西藏新嘎果铅锌矿床矽卡岩矿物及金属矿物特征

新嘎果矿床是西藏冈底斯成矿带北缘矽卡岩多金属成矿带的一个典型矽卡岩型铅锌矿床。矽卡岩矿体主要呈层状、似层状产于下白垩统塔克那组地层中。电子探针测试结果表明,矽卡岩矿物主要为钙铝榴石、钙铁辉石和绿帘石,少量的硅灰石、密绿泥石等,构成典型的钙质矽卡岩。金属矿物主要为闪锌矿、方铅矿、磁黄铁矿、黄铜矿、黄铁矿,少量的白铁矿、毒砂、自然铋、斜方辉铅铋矿、辉砷镍矿等。该矿床中石榴子石成分特征指示成矿环境是变化的,在早期进变质阶段由氧化环境向还原环境转变,而晚期退变质阶段由氧化环境向还原环境转变。金属矿物中闪锌矿主要为铁闪锌矿,表明其形成于中高温环境。而含铋的矿物主要为自然铋、斜方辉铅铋矿和方铅矿,并且在这些矿物中Ag和Bi的含量呈正相关性,指示铋对银的富集可能起着重要的作用;此外,铋也是新嘎果矿床重要的伴生有用元素,具有较高的综合利用价值。     

First occurrence of Pd-bearing galena (Sedova Zaimka copper–nickel mineralization,Western Siberia)

The paper presents data on the chemical composition and mineral association of Pd-bearing galena, discovered in hydrothermal–metasomatic sulfide Cu–Ni ores of the Sedova Zaimka mineralization (Western Siberia). In the Sedova Zaimka mineralization, galena is an accessory mineral and occurs in association with pyrrhotite, pentlandite, chalcopyrite, sphalerite, argentopentlandite, tsumoite, and native bismuth. The Pd contents in galena are 0.5–0.9 wt %. Palladium occurs in galena in the form of isomorphic impurities and is not related to microinclusions of Pd-bearing minerals.     

内蒙古额仁陶勒盖银矿床地球化学研究

额仁陶勒盖银矿床位于内蒙古新巴尔虎右旗境内.燕山晚期本区受太平洋板块的边缘影响,额尔古纳断裂带复活,产生强烈的花岗质岩浆活动.综合岩石的常量元素、微量元素、稀土元素及氧、锶同位素等证据表明花岗质岩浆为壳幔混合作用的产物.由花岗岩体向东依次排列Ⅰ、Ⅱ、Ⅲ和Ⅳ号矿带,其中Ⅱ、Ⅲ为主矿带,上述矿带在矿带规模、矿脉的矿石组成、矿石的结构构造和矿物成分、流体包裹体成分和均一温度等诸方面存在明显的水平分带;同时,各矿带均显示一样的矿石类型的垂向分带,即地表是氧化矿石（次生氧化富集带）,向下是石英脉-硅化带,深部是硫化物-蚀变岩型矿石带.不同类型矿石的流体包裹体成分一致,均为H₂O-CO₂-Ca²⁺-Na⁺-K⁺-SO₃^2--Cl^-型成矿流体,说明它们有相同的来源.氧同位素表明,大气水在成岩成矿过程中起重要作用,大气水的作用使矿液量大增.含氧大气水的加入还有以下两方面的作用：（1）可能发生OH^-取代Cl^-,从而使与岩浆平衡的富矿流体及其后形成的成矿热液Cl^-大增,提高了萃取岩浆及围岩中银的能力;（2）导致成矿流体的氧化-还原条件及酸碱度的变化.成矿各阶段形成的石英脉型矿石中的稀土元素、微量元素及氧、氢、硫、铅同位素特征表明,花岗岩、石英斑岩与矿石之间存在着显著的物源上的联系.由于石英斑岩是花岗质岩浆成岩期的最后产物,分异作用导致银在成岩期及期后成矿热液中富集.因此,石英斑岩是矿床的直接母岩.地表大气水在成岩和成矿作用的全过程中起重要作用.     

Silver-Bearing and Associated Minerals in El Zancudo Deposit, Antioquia, Colombia

The occurrence and the chemical compositions of ore minerals (especially the silver‐bearing minerals) and fluid inclusions of the El Zancudo mine in Colombia were investigated in order to analyze the genetic processes of the ore minerals and to examine the genesis of the deposit. The El Zancudo mine is a silver–gold deposit located in the western flank of the Central Cordillera in Antioquia Department. It consists mainly of banded ore veins hosted in greenschist and lesser disseminated ore in porphyritic rocks. The ore deposit is associated with extensive hydrothermally altered zones. The ores from the banded veins contain sphalerite, pyrite, arsenopyrite, galena, Ag‐bearing sulfosalts, Pb‐Sb sulfosalts, and minor chalcopyrite, electrum, and native silver. Electrum is included within sphalerite, pyrite, and arsenopyrite, and is also partially surrounded by pyrite, arsenopyrite, sphalerite, and tetrahedrite. Native silver is present in minor amounts as small grains in contact with Ag‐rich sulfosalts. Silver‐bearing sulfosalts are argentian tetrahedrite–freibergite solid solution, andorite, miargyrite, diaphorite, and owyheeite. Pb‐Sb sulfosalts are bournonite, jamesonite, and boulangerite. Two main crystallization stages are recognized, based on textural relations and mineral assemblages. The first‐stage assemblage includes sphalerite, pyrite, arsenopyrite, galena and electrum. The second stage is divided into two sub‐stages. The first sub‐stage commenced with the deposition and growth of sphalerite, pyrite, and arsenopyrite. These minerals are characterized by compositional growth banding, and seem to have crystallized continuously until the end of the second sub‐stage. Tetrahedrite, Pb‐Cu sulfosalts, Ag‐Sb sulfosalt, and Pb‐Ag‐Sb sulfosalts crystallized from the final part of the first sub‐stage and during the whole second sub‐stage. However, one Pb‐Ag‐Sb sulfosalt, diaphorite, was formed by a retrograde reaction between galena and miargyrite. The minimum and maximum genetic temperatures estimated from the FeS content of sphalerite coexisting with pyrite and the silver content of electrum are 300°C and 420°C, respectively. These estimated genetic temperatures are similar to, but slightly higher than the homogenization temperatures (235–350°C) of primary fluid inclusions in quartz. The presence of muscovite in the altered host rocks and gangue suggest that the pH of the hydrothermal solutions was close to neutral. Most of the sulfosalts in this deposit have previously been attributed as the products of epithermal mineralization. However, El Zancudo can be classified as a xenothermal deposit, in view of the low pressure and high temperature genetic conditions identified in the present study, based on the mineralogy of sulfosalts and the homogenization temperatures of the fluid inclusions.     

Mineralogy,Sulfur Isotope and Fluid Inclusion Studies of Hydrothermal Ore at the Hakurei Deposit,Bayonnaise Knoll,Izu‐Bonin Arc

Sulfide and sulfate ore samples collected from the Hakurei deposit of the Bayonnaise knoll were examined for the occurrence and chemical composition of minerals, including the sulfur isotopes and the microthermometry of fluid inclusions. Massive sulfide ore, mineralized volcanic rock, and anhydrite ore occur in descending order, from the seafloor to the bottom of the cored sample. The massive sulfide ore is dominated by sphalerite and accompanied by tennantite, chalcopyrite, and pyrite with lesser amounts of galena, enargite, and covellite. Amorphous silica is commonly precipitated on the surface of the sulfide minerals. As‐bearing minerals such as tennantite, enargite, and luzonite are common, while galena and Sb‐rich tetrahedrite are scarce. The mineral abundance and chemical composition of the minerals differs from that found in chimneys of the deposit. The sulfur isotope compositions in the minerals are +3.1–5.2‰ for sulfides and +19.6–21.8‰ for sulfate minerals. The homogeneous nature of the sulfur isotopes suggests that sulfur incorporated in the Hakurei deposit came from the reduction of aqueous sulfate in seawater.     

胶东西北部黄埠岭金矿床两期次叠加成矿

黄埠岭金矿床位于胶东西北部招莱金矿带,产于北东向黄埠岭-凤凰山断裂的上盘,由18条大小不一的金矿脉组成。研究表明,北东向断裂控制早期中深成金矿成矿,北北东向断裂控制晚期浅成金矿成矿。早晚两期金矿化不同,早期中深成金矿以石英、黄铁矿、辉钼矿、银金矿、自然金、黄铜矿、闪锌矿和方铅矿等组合为特征,晚期浅成金矿以石英、方解石、银金矿、自然银、硫盐矿物和胶黄铁矿等组合为特征。早晚两期成矿叠加部位构成矿区内富矿段。     

云南镇康芦子园铅锌铁多金属矿床矿石矿物特征及成因分析

镇康芦子园铅锌铁多金属矿床属大型铅锌铁矿床,对矿床矿石矿物的系统研究表明,矿石主要金属硫化物有闪锌矿、方铅矿、黄铜矿、黄铁矿。根据矿床地质特征、矿物共生组合及相互穿插关系,认为成矿主要分为热液成矿期和表生期,矿床是与燕山期隐伏岩体有关的岩浆热液型矿床。     

翠宏山铁多金属矿床成矿流体包裹体及硫同位素特征

对翠宏山铁多金属矿床成矿早期阶段钨钼矿体中的石英、成矿晚期阶段铅、锌、铜矿体中的萤石流体包裹体特征及均一温度、盐度的研究表明,从早期钨钼成矿阶段至晚期铅、锌、铜成矿阶段,侵入体内接触带至外接触带,经历了一个温度剧降和盐度显著增加的过程。钨钼成矿阶段成矿流体主要为岩浆热液流体,成矿过程为单一的成矿流体冷却过程; 在晚期铅、锌、铜成矿阶段,来自岩浆中的温度较高的热流体与围岩地层中的大气降水等低温、高盐度流体混合,使成矿流体温度剧降和盐度增高,导致铅、锌、铜等成矿物质的沉淀。辉钼矿和方铅矿的δ34S ( × 10-3 ) 测试结果表明,侵入体内接触带钨钼矿体的成矿物质主要来自岩浆热液; 围岩地层中铅、锌、铜矿体的成矿物质,除岩浆热液来源外,部分可能来自雨水对地层中硫酸盐岩中硫及其他成矿物质的淋滤。     

江西冷水坑矿田下鲍Ag-Pb-Zn矿床地质特征及银的赋存状态研究

下鲍大型Ag-Pb-Zn矿床位于江西冷水坑矿田西南部。矿床地质研究表明,成矿作用可以分三个阶段:(Ⅰ)闪锌矿-黄铁矿阶段;(Ⅱ)方铅矿-闪锌矿-银矿物阶段;(Ⅲ)黄铁矿-石英(方解石)阶段。岩矿石光薄片鉴定和电子探针分析表明,下鲍矿床主要金属硫化物为闪锌矿、方铅矿、黄铁矿及银矿物。电子探针分析显示,银主要以独立银矿物形式存在,金属硫化物中不可见银极少。银矿物种类主要为螺状硫银矿和自然银,呈裂隙银赋存于铁锰碳酸盐中或呈粒间银分布于铁锰碳酸盐粒间和早期硫化物晶隙间;另有少量硫银锡矿、含银黝铜矿、淡红银矿、金银矿及深红银矿、硫砷铜银矿等银矿物,呈亚显微粒状赋存于铁锰碳酸盐粒间或呈固溶体分离结构赋存于方铅矿、闪锌矿等硫化物中。主要银矿物大量赋存于铁锰碳酸盐中,表明银矿化与铁锰碳酸盐可能存在成因联系。     

胶东三山岛金矿床黄铁矿原位微区微量元素特征及对矿床成因的指示

胶东地区是我国最大金成矿聚集区,其金矿床的成因长期以来一直存在很大争议,三山岛金矿床是胶东地区最大的金矿床,通过采用LA-ICP-MS分析不同阶段黄铁矿中微量元素组成,可以探讨成矿流体演化及成矿物质来源。根据野外地质特征及岩相学观察,结合SEM结构分析将三山岛金矿床的黄铁矿分为3个阶段,6个亚类,即黄铁绢英岩化带(Py1)中包裹大量绢云母和石英的Py1-a和表面光滑的Py1-b,石英—黄铁矿±菱铁矿脉(Py2)中富含矿物包裹体的Py2-a和与菱铁矿共生且表面光滑的Py2-b,石英—多金属硫化物脉(Py3)中有很多细粒多金属硫化物包裹体的Py3-a和表面光滑的Py3-b。3个阶段黄铁矿晶格中金含量均很低,大部分小于1×10^-6,金主要以可见金形式存在。从早阶段到晚阶段黄铁矿中Au与Ag,Cu,Pb,Sb有较好的正相关性,且含量有逐渐增加的趋势。最早阶段黄铁矿中Co+Ni的含量很高(最高为9268×10^-6),反映了早期黄铁矿可能来源于岩浆岩源区,后期Co/Ni值逐渐降低,暗示了成矿流体温度逐渐降低。结合地质特征和黄铁矿微量元素研究,表明三山岛金矿床成矿物质可能来源于深部岩浆热液储库,通过地震泵机制沿断裂构造多次侵位成矿。