Benthic biogeochemical cycling of mercury in two contaminated northern Adriatic coastal lagoons

Previous research recognized most of the Northern Adriatic coastal lagoon environments as contaminated by mercury (Hg) from multiple anthropogenic sources. Among them, the Pialassa Baiona (P.B.) Lagoon, located near the city of Ravenna (Italy), received between 100 and 200 tons of Hg, generated by an acetaldehyde factory in the period 1957-1977. Further east, the Grado Lagoon has been mainly affected by a long-term Hg input from the Idrija mine (western Slovenia) through the Isonzo River since the 16th century. Hg cycling at the sediment-water interface (SWI) of the two lagoons was investigated and compared by means of an in situ benthic chamber, estimating diffusive Hg and Methyl-Hg fluxes in the summer season. Major chemical features in porewaters (Fe, Mn, H₂S, dissolved inorganic (DIC) and organic carbon (DOC), nutrients) and in the solid phase (C_org, N and S) were also explored to understand the general biogeochemical conditions of the system in response to benthic respiration. The daily integrated flux for the methylated Hg form was extremely low in P.B. Lagoon, accounting for only 7% of the corresponding flux calculated for the Grado Lagoon. Despite a higher sedimentary Hg content in the P.B. Lagoon (14.4-79.0 μg g⁻¹) compared to the Grado Lagoon (10.7-12.5 μg g⁻¹), the in situ fluxes of Hg in the two experimental sites appeared similar. A selective sequential extraction procedure was applied to the solid phase, showing that the stable crystalline mineral phase cinnabar (HgS) is the predominant Hg fraction (about 50%) in the Grado Lagoon surface sediments. Conversely, Hg mobilization and sequestration in the P.B. Lagoon is related to the extremely anoxic redox conditions of the system where the intense sulfate reduction, by the release of sulfur and the formation of sulfides, limits the metal recycling at the SWI and its availability for methylation processes. Thus, the environmental conditions at the SWI in the P.B. Lagoon seem to represent a natural “barrier” for the potential risk of Hg transfer to the aquatic trophic chain.     

Modeling the circulation in the Gulf of Tonkin, South China Sea

The circulation in the Gulf of Tonkin (Beibu Gulf) was studied using the Princeton Ocean Model, which was forced with the daily surface and lateral boundary fluxes for 2006 and 2007, as well as tidal harmonics and monthly climatological river discharges. In the southern Gulf, the vertically averaged circulation was anti-cyclonic in summer and changed to cyclonic in winter. Although it was highly correlated with the local wind, the southern gyre was driven primarily by the South China Sea (SCS) general circulation from the south. Flows in the Qiongzhou Strait that played a significant role in determining the circulation variability in the northeastern Gulf could be eastward or westward at any given day in summer or winter, but the seasonal mean current was eastward from late spring through summer and westward during the rest of the year, with an annual mean westward transport of ～0.1 Sv into the Gulf. Different water masses were distinguished at the surface with the warm and saline SCS water in the south, relatively fresh plume waters along the northern and western coasts of the Gulf, and the mixture of the two in between. At lower levels, two cold water masses were identified in the model, and each had T/S distributions qualitatively similar to the observations obtained in 2007. These two water masses were produced throughout the winter, sheltered from the surface warming by a thermocline as the season progressed, and eventually disappeared in late fall.     

Impact of different forcing factors on N:P balance in a semi-enclosed bay: The Gulf of Trieste (North Adriatic Sea)

The availability and partition of nitrogen (N) and phosphorus (P) in inorganic and organic compartments, as well as their stoichiometric ratio, are influenced by both physical and biological forcing factors. On this basis, the temporal and spatial dynamics in N:P atomic ratios in different compartments may provide information on the functioning of marine ecosystems. Here we explore the relative importance of water temperature, river inputs, wind mixing, stratification, ingression of nutrient-depleted Eastern Adriatic Current and phytoplankton biomass on concentrations and ratios between nitrogen and phosphorus in a semi-enclosed bay (the Gulf of Trieste), using data from monitoring programs carried out during 8 years. Water samples are first classified in 6 water types based on N:P ratios in different components, and then relationships between water type space-time distribution and a set of forcing factors is sought. Results show that the gulf is characterised by relatively stable N:P ratios in all compartments (about 23-26), always exceeding the classical Redfield ratio. In the surface layer, however, nitrogen and phosphorus dynamics are decoupled because of river input and plankton productivity, and a significant spatial and temporal variability is observed in terms of stoichiometric balance, nutrient concentrations and partition among the different pools. Deviations from stable N:P ratios follow a seasonal evolution. In spring, continental inputs alter inorganic nutrient compartments (N:P up to 115); later on, during the seasonal succession of biological processes (e.g. late spring phytoplankton blooms, summer increase in microbial activities and autumn phytoplankton blooms), a change is also seen in the organic dissolved and particulate pools. Multivariate statistical analysis suggests that, among the considered forcing factors, the most relevant in modulating the N:P stoichiometry in the Gulf of Trieste are river inputs and ingression of the Eastern Adriatic Current (acting in opposite directions) along with phytoplankton dynamics. During the whole period, besides variations in N:P stoichiometry, in the Gulf of Trieste dissolved organic matter represents the largest pool of N and P, which can provide a source of nutrients for the planktonic community alternative to inorganic nutrient.     

Response of salinity distribution around the Yellow River mouth to abrupt changes in river discharge

To investigate how salinity changes with abrupt increases and decreases in river discharge, three surveys were conducted along six sections around the Yellow River mouth before, during and after a water regulation event during which the river discharge was increased from ∼200 to >3000 m³ s⁻¹ for the first 3 days, was maintained at >3000 m³ s⁻¹ for the next 9 days and was decreased to <1000 m³ s⁻¹ for the final 4 days. The mean salinity in the Yellow River estuary area during the event varied ∼1.21, which is much larger than its seasonal variation (∼0.50) and interannual variation (∼0.05). Before the event, a small plume was observed near the river mouth. During the event, the plume extended over 24 km offshore in the surface layer in the direction of river water outflow. After the event, the plume diminished in size but remained larger than before the event. The downstream propagation of the plume (as in a Kelvin wave sense) was apparent in the bottom layer during the second survey and in both the surface and bottom layers during the third survey. The plume sizes predicted by the formulas from theoretical studies are larger than those we observed, indicating that factors neglected by theoretical studies such as the temporal variation in river discharge and vertical mixing in the sea could be very important for plume evolution. In addition to the horizontal variation of the plume, we also observed the penetration of freshwater from the surface layer into the bottom layer. A comparison of two vertical processes, wind mixing and tidal mixing, suggests that the impact of wind mixing may be comparable with that of tidal mixing in the area close to the river mouth and may be dominant over offshore areas. The change in Kelvin number indicates an alteration of plume dynamics due to the abrupt change in river discharge during the water regulation event.     

A model study of tide- and wind-induced mixing in the Columbia River Estuary and plume

A numerical simulation of circulation in the Columbia River estuary and plume during the summer of 2004 is used to explore the mixing involved as river water is transformed into shelf water. The model is forced with realistic river flow, tides, wind stress, surface heat flux, and ocean boundary conditions. Simulated currents and water properties on the shelf near the mouth are compared with records from three moorings (all in 72 m of water) and five CTD sections. The model is found to have reasonable skill; statistically significant correlations between observed and modeled surface currents, temperature, and salinity are all 0.42–0.72 for the mooring records. Equations for the tidally averaged, volume-integrated mechanical energy budget (kinetic and potential) are derived, with attention to the effects of: (i) Reynolds averaging, (ii) a time varying volume due to the free surface, and (iii) dissipation very close to the bottom. It is found that convergence of tidal pressure work is the most important forcing term in the estuary. In the far field plume (which has a volume 15 times greater than that of the estuary), the net forcing is weaker than that in the estuary, and may be due to either tidal currents or wind stress depending on the time period considered. These forcings lead to irreversible mixing of the stratification (buoyancy flux) that turns river water into shelf water. This occurs in both the plume and estuary, but appears to be more efficient (17% vs. 5%), and somewhat greater (4.2 MW vs. 3.3 MW), in plume vs. estuary. This demonstrates the importance of both wind and tidal forcing to watermass transformation, and the need to consider the estuary and plume as part of a single system.     

Tidal effects on estuarine circulation and outflow plume in the Chesapeake Bay

The response of the Chesapeake Bay to river discharge under the influence and absence of tide is simulated with a numerical model. Four numerical experiments are examined: (1) response to river discharge only; (2) response to river discharge plus an ambient coastal current along the shelf outside the bay; (3) response to river discharge and tidal forcing; and (4) response to river discharge, tidal forcing, and ambient coastal current. The general salinity distribution in the four cases is similar to observations inside the bay. Observed features, such as low salinity in the western side of the bay, are consistent in model results. Also, a typical estuarine circulation with seaward current in the upper layer and landward current in the lower layer is obtained in the four cases. The two cases without tide produce stronger subtidal currents than the cases with tide owing to greater frictional effects in the cases with tide. Differences in salinity distributions among the four cases appear mostly outside the bay in terms of the outflow plume structure. The two cases without tide produce an upstream (as in a Kelvin wave sense) or northward branch of the outflow plume, while the cases with tide produce an expected downstream or southward plume. Increased friction in the cases with tide changes the vertical structure of outflow at the entrance to the bay and induces large horizontal variations in the exchange flow. Consequently, the outflow from the bay is more influenced by the bottom than in the cases without tide. Therefore, a tendency for a bottom-advected plume appears in the cases with tide, rather than a surface-advected plume, which develops in the cases without tide. Further analysis shows that the tidal current favors a salt balance between the horizontal and vertical advection of salinity around the plume and hinders the upstream expansion of the plume outside the bay.     

Intertidal spring dynamics and coastal nutrient loading revealed through geophysics,drone surveys,and in-situ monitoring

Coastal eutrophication poses an increasing risk to ecosystem health due to enhanced nutrient loading to the global coastline. Submarine groundwater discharge (SGD) represents a significant pathway for nitrate-nitrogen (NO₃-N) transport to the coast, but diffusive SGD transport is difficult to monitor directly, given the low flux rates and expansive discharge areas. In contrast, focused SGD from intertidal springs can potentially be sampled and directly gauged, providing unique insight into SGD and associated contaminant transport. Basin Head is a coastal lagoon in Prince Edward Island, Canada that is a federally protected ecosystem. Nitrate-nitrogen is conveyed from agricultural fields in the contributing watershed to the eutrophic lagoon via intertidal groundwater springs and groundwater-dominated tributaries. We used several field methods to characterize groundwater discharge, nutrient loading, and in-channel mixing associated with intertidal springs. The tributaries and intertidal springs were gauged and sampled to estimate a representative summer nitrate load to the lagoon. Our analysis revealed that NO₃-N export to the lagoon through tributaries and springs throughout summer 2023 was on average 401 kg N/month, with the combined spring loading comparable in magnitude to the combined tributary loading. We collected thermal infrared and visual imagery using drone surveys and found spatial overlap between cold-water plumes from the spring discharge and macroalgae blooms, indicating the local thermal and ecosystem impacts of the focused SGD. We also mapped the electrical resistivity (salinity) distribution in the water column around one large spring with electromagnetic geophysics at different tidal stages to reveal the three-dimensional spring plume dynamics. Results showed that the fresher spring water floated above the saline lagoon water with the brackish plume oriented in the direction of the tidal current. Collectively, our multi-pronged field investigations help elucidate the hydrologic, thermal, and nutrient dynamics of intertidal springs and the cascading ecosystem impacts.     

Hydrodynamic characterization of the Arcachon Bay,using model-derived descriptors

A numerical model (MARS-2D) was developed, with the aim of describing the hydrodynamics that prevail in Arcachon Bay. Direct model results as well as derived mixing and transport time-scales (tidal prism, local and integrated flushing times, age of water masses), were used to understand the behaviour of water masses and exchanges between the Bay and its frontiers. Particular attention was paid to the processes that drive the hydrodynamics (tides, wind and rivers), in order to understand their respective influence.The Arcachon Bay hydrodynamic system appears primarily to be highly influenced by tides; secondarily, by winds. About two third of the lagoon total volume is flushed in and out at each tidal cycle, which represent a mean tidal prism of 384 millions of cubic meters. The percentage of seawater flushed out during the ebb, that returns into the lagoon during the following flood flow is very high (return flow factor=0.95). This pattern leads to calculated integrated flushing times (IFT) ranging from 12.8 to 15.9 days, respectively, for the winter 2001 and summer 2005 simulations (two contrasting climatological situations: in summer, light northwesterly winds and low discharges in the rivers and, in winter, stronger southwesterly winds and higher river flows). Moreover, it has been found that northerly and westerly winds tend to reduce the flushing time, whilst southerly and easterly winds tend to hinder the renewal of the water in the Bay. The behaviour of the waters originating from the two main rivers of the lagoon, was studied also by means of the mean age assessment, under varying conditions of river flow and wind regime.     

Modelling the impact of a La Niña event on a South West Pacific Lagoon

In view of increasing environmental awareness and biodiversity conservation, understanding the main forcing mechanism driving biogeochemical cycles in coral reefs and lagoon coastal areas is a priority. La Ni?a events cause unbalanced situations in the Equatorial Pacific and result in enhanced precipitation in South West Pacific coastal areas. We investigated the impact of heavy rainfalls during the 2008 La Ni?a event on the New Caledonia lagoon using a 3D coupled on-line hydrodynamic-biogeochemical model. Simulations and data showed that the whole lagoon was impacted by river inputs and stronger hydrodynamics, enhancing chlorophyll-a concentration by a factor between 1.7 and 1.9. The coupled model provided new insights into plume transport, highlighting that eastern plumes can be advected northwards or can reach the South West Lagoon, depending on the balance between regional, tide-induced, and wind-induced surface currents. It also provided a synoptic view of lagoon biogeochemical-hydrodynamic response, when remote sensing data are not available due to cloud coverage.     

A buoyant plume adjacent to a headland—Observations of the Elwha River plume

Small rivers commonly discharge into coastal settings with topographic complexities - such as headlands and islands - but these settings are underrepresented in river plume studies compared to more simplified, straight coasts. The Elwha River provides a unique opportunity to study the effects of coastal topography on a buoyant plume, because it discharges into the Strait of Juan de Fuca on the western side of its deltaic headland. Here we show that this headland induces flow separation and transient eddies in the tidally dominated currents (O(100 cm/s)), consistent with other headlands in oscillatory flow. These flow conditions are observed to strongly influence the buoyant river plume, as predicted by the “small-scale” or “narrow” dynamical classification using Garvine's (1995) system. Because of the transient eddies and the location of the river mouth on the headland, flow immediately offshore of the river mouth is directed eastward twice as frequently as it is westward. This results in a buoyant plume that is much more frequently “bent over” toward the east than the west. During bent over plume conditions, the plume was attached to the eastern shoreline while having a distinct, cuspate front along its westernmost boundary. The location of the front was found to be related to the magnitude and direction of local flow during the preceding O(1 h), and increases in alongshore flow resulted in deeper freshwater mixing, stronger baroclinic anomalies, and stronger hugging of the coast. During bent over plume conditions, we observed significant convergence of river plume water toward the frontal boundary within 1 km of the river mouth. These results show how coastal topography can strongly influence buoyant plume behavior, and they should assist with understanding of initial coastal sediment dispersal pathways from the Elwha River during a pending dam removal project.     

Fates of dissolved and particulate materials from the Mississippi river immediately after discharge into the northern Gulf of Mexico,USA, during a period of low wind stress

In June 2003, we conducted a two-part field exercise to examine biogeochemical characteristics of water in the lower Mississippi river during the 4 days prior to discharge and in the Mississippi river plume over 2 days after discharge. Here we describe the fates of materials immediately after their discharge through Southwest Pass of the Mississippi delta into the northern Gulf of Mexico. Changes in surface water properties immediately after discharge were much larger and more rapid than changes prior to discharge. Total suspended matter (TSM) declined, probably due to sinking, dissolved macronutrients were rapidly diminished by mixing and biological uptake, and phytoplankton populations increased dramatically, and then declined. This decline appeared to begin at salinities of approximately 10 and was nearly complete by 15. A large increase in dissolved organic carbon (DOC) occurred over approximately the same salinity range. Weak winds (<2 m s⁻¹) during and preceding this cruise apparently led to the formation of an extensive but thin freshwater lens from the river. This lens spread widely without much mixing, and the bloom of phytoplankton that occurred between discharge and a salinity of 10 was probably a freshwater community seeded from the lower river. Phytoplankton bloomed for a period of about 1–2 days, then declined dramatically, apparently releasing large amounts of DOC. Macronutrients from the river were utilized by the river phytoplankton community in the extensive freshwater lens. This contrasted with the more typical situation in which river nutrients stimulate a marine phytoplankton bloom at salinities in the mid-20s. We concluded that the direct effects of dissolved and particulate bio-reactive materials discharged by the Mississippi river were spatially restricted at this time to low-salinity water, at least as surface phenomena. After being transported through the lower river essentially unaltered, these materials were biogeochemically processed within days and tens of km. More generally, the mixing rate of plume water with receiving oceanic water has profound effects on the food web structure and biogeochemical cycling in the plume.     

Horizontal patterns of water temperature and salinity in an estuarine tidal channel: Ria de Aveiro

This work presents results from two complementary and interconnected approaches to study water temperature and salinity patterns in an estuarine tidal channel. This channel is one of the four main branches of the Ria de Aveiro, a shallow lagoon located in the Northwest coast of the Iberian Peninsula. Longitudinal and cross-sectional fields of water temperature and salinity were determined by spatial interpolation of field measurements. A numerical model (Mohid) was used in a 2D depth-integrated mode in order to compute water temperature and salinity patterns. The main purpose of this work was to determine the horizontal patterns of water temperature and salinity in the study area, evaluating the effects of the main forcing factors. The field results were depth-integrated and compared to numerical model results. These results obtained using extreme tidal and river runoff forcing, are also presented. The field results reveal that, when the river flow is weak, the tidal intrusion is the main forcing mechanism, generating saline and thermal fronts which migrate with the neap/spring tidal cycle. When the river flow increases, the influence of the freshwater extends almost as far as the mouth of the lagoon and vertical stratification is established. Results of numerical modelling reveal that the implemented model reproduces quite well the observed horizontal patterns. The model was also used to study the hydrology of the study area under extreme forcing conditions. When the model is forced with a low river flow (1 m³ s⁻¹) the results confirm that the hydrology is tidally dominated. When the model is forced with a high river flow (1,000 m³ s⁻¹) the hydrology is dominated by freshwater, as would be expected in such an area.     

Sediment dispersal from a typical Mediterranean flood: The Têt River,Gulf of Lions

This paper describes an integrated study of a typical Mediterranean flood event in the Gulf of Lions. A flood with a 5-year return interval occurred in the Têt River basin and adjacent inner-shelf in the Gulf of Lions, northwest Mediterranean, during April 2004. Data were collected during this flood as part of event-response investigations of the EU-funded Eurostrataform (European Margin Strata Formation) project. Southeasterly storm winds led to a flood which directly modified the inner-shelf hydrodynamics. Sediment delivery to the coastal zone during this flood represented more than half of the mean annual discharge of the Têt River to the Gulf of Lions. This river transported a large amount of sand in suspension, representing 25% of the total suspended load, and as bedload representing 8% of the total load, during this event. Sand introduced in the nearshore was transported northwards during the peak storm and nourished a small delta. Fine sediments were separated from coarse sediments at the river mouth, and were advected southwards and seawards by the counter-clockwise general circulation. Fine-grained sediments were transported via a hypopycnal plume along the coast towards the southern tip of the Gulf of Lions and the Cap Creus canyon. The along-shore currents, which intensified from north to south of the Gulf of Lions, particularly between the Cap Creus promontory and the Cap Creus canyon, favoured the transfer of fine-grained sediments from the continental shelf of the Gulf of Lions towards the continental slope. Our results show that floods with a few-year return interval in small coastal rivers can play a significant role in the transport of sediments on microtidal continental margins and their export from the shelf through canyons.     

The attenuation of tidal and subtidal oscillations in the Patos Lagoon estuary

The single, long and narrow channel that usually connects choked coastal lagoons to the ocean can serve as a natural hydraulic low-pass filter that reduces or eliminates tidal and subtidal effects inside the lagoon. This study proposes an alternative method of estimating the attenuation of the tidal and subtidal oscillations throughout the Patos Lagoon estuary. The attenuation is estimated for conditions of contrasting river runoff and weather (summer and winter). A high-pass/low-pass filter (fast fourier transformation technique – FFT) is applied to time series of sea-surface elevation (SSE) measured at the mouth of the Patos Lagoon. The resulting high-frequency (tidal) and low-frequency (subtidal) signals are used in independent simulations to force the TELEMAC-2D model. Attenuation of the tidal and subtidal signals throughout the estuary is estimated by applying cross-spectral analysis between the model-generated SSE time series at different locations throughout the estuary and the filtered SSE time series measured at the mouth. Results from the proposed method suggest that: (1) the low-frequency (subtidal) oscillations are less attenuated and propagate further than the high-frequency (tidal) oscillations in the Patos Lagoon estuary; (2) the filtering capability of the Patos Lagoon estuary is expected to follow a seasonal pattern, although further investigations on an interannual time scale are recommended in order to confirm this hypothesis; (3) the influence of the oceanic boundary processes on the SSE dynamics of the lagoon is restricted to the lower estuary. Further inland, the local forcing generated by the wind and freshwater input is likely to be the main forcing effect controlling the dynamics of the system. The proposed method proved to be an efficient and alternative way of estimating the attenuation of energy in the tidal and subtidal bands throughout the access channel of a choked coastal lagoon located in an area of reduced tidal influence.Responsible Editor: Iris Grabemann     

The Consequences of the Oder Flood in 1997 on the Distribution of Polycyclic Aromatic Hydrocarbons (PAHs) in the Oder River Estuary

Changes in the levels and spatial distribution of polycyclic aromatic hydrocarbons (PAHs) as a consequence of the Oder flood in the summer of 1997 were investigated in surface water samples and fluffy layer material from the Oder Lagoon and the Pomeranian Bight. The measurements of the contaminants were complemented by satellite data to describe the spreading of the Oder flood discharge including the distribution of the particulate material. During the flood elevated levels of PAHs were discussed in the surface water and fluffy layer material of the Oder River Estuary in comparison to the average values in this region. These increased concentrations were attributed to flooding of municipal and industrial waste disposal areas in the drainage area of the Oder River. The meteorological conditions during the sampling period were characterized by predominant easterly winds, which guided the river plume along the German coast into the Arkona Sea, as verified by satellite observations. The highest concentrations of PAHs were observed near the mouth of the Swina and along the main direction of the river plume. Elevated concentrations of PAHs were also found in fluffy layer samples taken from the Oder Lagoon in late August. As derived from satellite data the eastern and the western parts of the lagoon differed in their SPM load during the entire flood period. The eastern part was covered by Oder water, while the western part contained a mixture of Oder Lagoon water. The highest concentrations of PAHs were not observed in the western part with the highest suspended matter values, but in the eastern part where the flood water entered the lagoon. Despite the significantly increased PAH levels measured during the flood, all measured concentrations were below the values that are considered to pose a risk to the ecosystem.     

Fine sediment and nutrient dynamics related to particle size and floc formation in a Burdekin River flood plume, Australia

The extreme 2010-2011 wet season resulted in highly elevated Burdekin River discharge into the Great Barrier Reef lagoon for a period of 200 days, resulting in a large flood plume extending >50km offshore and >100km north during peak conditions. Export of suspended sediment was dominated by clay and fine silt fractions and most sediment initially settled within ～10km of the river mouth. Biologically-mediated flocculation of these particles enhanced deposition in the initial low salinity zone. Fine silt and clay particles and nutrients remaining in suspension, were carried as far as 100km northward from the mouth, binding with planktonic and transparent exopolymer particulate matter to form large floc aggregates (muddy marine snow). These aggregates, due to their sticky nature, likely pose a risk to benthic organisms e.g. coral and seagrass through smothering, and also by contributing to increased turbidity during wind-induced resuspension events.     

Assessing the potential underestimation of sediment and nutrient loads to the Great Barrier Reef lagoon during floods

Much of the sediment and nutrient load to the Great Barrier Reef (GBR) lagoon happens during over bank floods, when discharge can be significantly underestimated by standard river gauges. This paper assesses the potential need for a flood load correction for 28 coastal rivers that discharge into the GBR lagoon. For each river, daily discharge was divided into flows above and below a 'flood' threshold to calculate the mean annual percentage flow above this threshold. Most GBR rivers potentially need a flood load correction as over 15% of their mean annual flow occurs above the minor flood level; only seven rivers need little/no correction as their flood flows were less than 5% of the mean annual flow. Improved assessment of the true load of materials to the GBR lagoon would be an important contribution to the monitoring and reporting of progress towards Reef Plan and associated marine load targets.     

The impact of organic pollution on the macrobenthic fauna of Dubai Creek (UAE)

Dubai Creek is a tidal marine intrusion bisecting Dubai within the United Arab Emirates (UAE). The creek extends 14km inland from its opening into the Arabian Gulf, with a narrow lower creek channel leading to a lagoon section in the upper creek. The creek contains numerous sources of organic pollution including sewage outlet flows and boat waste. A survey of the creek was performed, assessing organic pollution, water properties, and the benthic macrofaunal community. The upper creek was heavily polluted with macrofauna communities commonly associated with organic pollution and eutrophication, while the lower creek contained low pollution and relatively healthy macrofauna communities. There is little net tidal flow of water within the creek and residence time in the lagoon is high, which may account for the high organic pollution levels. However, some evidence of the pollution effect moving into the lower creek was found. The results are considered in light of current and historic organic loading within the creek and future developments in the area.     

Time-dependent plume front positioning and its dynamics coupled with seasonal river efflux

Ocean Dynamics - The time-dependent plume front positioning with respect to different tidal phases and its dynamics coupled with seasonal river efflux on the shelf off Kochi, southwest coast of...     

Composition, distribution and sources of polycyclic aromatic hydrocarbons in sediments of the Gulf of Trieste, Northern Adriatic Sea

The composition, distribution and the sources of polycyclic aromatic hydrocarbons (PAHs) in the surficial sediments of the Gulf of Trieste were investigated. To document the spatial PAH input, surficial sediment samples from 17 locations throughout the Gulf were analysed. The total PAH load determined in the surficial sediment samples are between 30 and 600 ng g-1, and were the highest in the immediate vicinity of the Port of Trieste. The PAH contents decline rapidly with increasing distance from the shore. The ratios of methylphenanthrenes/phenanthrene and methylpyrene/pyrene are sensitive indicators of the origin of PAH pollution in the Gulf which is mostly pyrolitic. The phenanthrene/anthracene ratio was used to determine the approximate location and distance from the source of PAH pollution, while 1-methy 1-7-isopropylphenanthrene (retene) was used as indicator for forest fires. A sediment depth profile indicates a major increase in the PAH concentrations after the First World War.