Origin of pockmarks and chimney structures on the flanks of the Storegga Slide,offshore Norway

Seafloor pockmarks and subsurface chimney structures are common on the Norwegian continental margin north of the Storegga Slide scar. Such features are generally inferred to be associated with fluid expulsion, and imply overpressures in the subsurface. Six long gravity and piston cores taken from the interior of three pockmarks were compared with four other cores taken from the same area but outside the pockmarks, in order to elucidate the origins and stratigraphy of these features and their possible association with the Storegga Slide event. Sulfate gradients in cores from within pockmarks are less steep than those in cores from outside the pockmarks, which indicates that the flux of methane to the seafloor is presently smaller within the pockmarks than in the adjacent undisturbed sediments. This suggests that these subsurface chimneys are not fluid flow conduits lined with gas hydrate. Methane-derived authigenic carbonates and Bathymodiolus shells obtained from a pockmark at >6.3 m below the seafloor indicate that methane was previously available to support a chemosynthetic community within the pockmark. AMS ¹⁴C measurements of planktonic Foraminifera overlying and interlayered with the shell-bearing sediment indicate that methane was present on the seafloor within the pockmark prior to 14 ka ¹⁴C years b.p., i.e., well before the last major Storegga Slide event (7.2 ka ¹⁴C years b.p., or 8.2 ka calendar years b.p.). These observations provide evidence that overpressured fluids existed within the continental margin sediments off Norway during the last major advance of Pleistocene glaciation.     

A pockmark field in the Patras Gulf (Greece) and its activation during the 14/7/93 seismic event

During a recent oceanographical-geophysical survey carried out in the southeastern part of the Gulf of Patras in Western Greece for the construction of an outfall, an active pockmark field was found. The pockmark field was formed in soft layered Holocene silts. The pockmarks are associated with acoustic anomalies attributed to gas-charged sediments. The pockmarks vary in size and shape from 25 to 250 m in diameter and from 0.5 to 15 m in depth and are among the largest and deepest observed in the world.

On July 14th, 1993, during the survey, a major earthquake of magnitude 5.4 on the Richter scale occurred in the area. During the 24 hour period prior to the earthquake the bottom water temperature anomalously increased on three occasions, whilst for a few days after the earthquake it was noted that the majority of the pockmarks were venting gas bublles.

It is considered that the three abrupt sea-water temperature increases were probably the result of upward migrating high-temperature gas bubbles in the water column. It is further suggested that the earthquake was the triggering mechanism and that the gas expulsion was caused by the reduction in the pore volume in the sediments resulting from changes in the stress regime prior to the earthquake. Therefore, it can be suggested that in seismic areas adjacent to pockmark fields, earthquake prediction may be achieved by monitoring the water temperature and/or the rate of gas venting in the pockmark field.

Our analysis indicates that the pockmark field in the Patras Gulf has formed slowly during the Holocene by continuous gas venting, which is periodically being interrupted by short-duration events of enhanced gas seepage triggered by earthquakes.     

‘Bulls-eye’ pockmarks and polygonal faulting in the Lower Congo Basin: Relative timing and implications for fluid expulsion during shallow burial

This study describes a new type of pockmark association from the Lower Congo Basin offshore West Africa, consisting of up to 8 stacked paleopockmarks separated by intervals of drape and onlap fill. The stacked paleopockmarks occur within the depocentres of polygonally-faulted Plio-Pleistocene sediments and are distributed evenly in the downslope parts of two salt mini-basins. The majority of the stacked pockmarks initiated synchronously in the late Pliocene (~ 3 Ma) with a subordinate initiation phase in the mid Pliocene (~ 4 Ma). The primary agents in pockmark formation are interpreted to be pore water expelled during early-stage compaction together with biogenic methane. Bottom simulating reflections (BSRs) associated with free gas overlain by gas hydrates are currently found in the area. It is speculated that biogenic methane accumulated within and below a clathrate cap, which was repeatedly breached, forming pockmarks at discrete horizons separated by intervals of draping sedimentation. The mid and late Pliocene pockmark initiations appear to coincide with sea-level falls following periods of relatively stable highstand conditions. Several subsequent pockmark horizons may similarly correlate with subsequent sea-level falls during the late Pliocene and early Pleistocene. The stacked paleopockmarks are completely surrounded by polygonal faults and consistently occur within polygonal fault cells that crosscut the succession containing the stacked pockmarks. Early-stage compaction and dewatering of the Pliocene sediments thus preceded polygonal faulting, providing a constraint on the conditions leading to polygonal faulting of the fine-grained host sediments. The relationship documented here is interpreted as due to the presence of a hydrate cap in the Plio-Pleistocene mini-basins which may have retarded the normal compaction processes and facilitated pockmark formation by allowing the build up of gas hydrate and free gas in the basin centres. The relative timing and spatial relationships implies that fluids expelled due to polygonal faulting were not implicated in pockmark formation in this area.     

南海礼乐盆地海底麻坑地貌及成因分析

本文基于高分辨率多波束测深和浅地层剖面数据，首次对南海礼乐盆地南部坳陷海底麻坑进行了系统的识别研究。共识别出各类麻坑81个，其中麻坑直径最大约2.4 km，坑深最大约157 m。麻坑种类多样:按平面形态主要分为圆形、椭圆形、拉长形和新月形麻坑；按组合方式分为孤立麻坑、链状麻坑和复合麻坑；按直径分为正常麻坑和大型麻坑。区域内发育多条大型海底峡谷，峡谷侵蚀引起两侧地层稳定性降低，气体储层遭受破坏，泄露的气体沿断层或气烟囱等喷发出海底形成麻坑。而因麻坑生成时剥蚀的沉积物质与周围水体混合并逐渐发展成浊流，在一定程度上促进海底峡谷向下延伸。研究区内单个麻坑的平面形态最初为圆形或椭圆形，之后由于重力流和峡谷侵蚀的影响，逐渐发展成拉长形或新月形，麻坑之间也会发生组合形成复合麻坑。链状麻坑与冲沟的形成联系密切，沿垂直于等深线方向展布的链状麻坑在重力流的冲刷下，发育成底部平坦的麻坑冲沟。对比分析全球其他海域麻坑，发现海底麻坑尺寸与水深关系密切，在深水区域更容易发育大型麻坑。     

Experimental investigation of the hydrodynamics in pockmarks using particle tracking velocimetry

Water tank experiments were performed in order to investigate the behaviour of currents in pockmarks. A particle-seeded flow was visualised and quantified with the aid of the particle tracking velocimetry technique. The employed analogue pockmark is a 1:100 idealised scale model of a natural pockmark, while the highest Reynolds number in the experiments was one order of magnitude smaller than in nature. Interaction of the flow with the pockmark geometry resulted in an upwelling current downstream of the pockmark centre, along with enhanced water turbulence in the depression. Scaling-up the experimental measurements, it is found that the upwelling would be capable of preventing the settling of particles as large as very fine sand. Furthermore, the increased turbulence would support the suspended fine material, which can thus be transported away before settling. The net effect for a variable-direction near-bed current over long periods of time would be to winnow the settling sediments and reduce the sedimentation rate in pockmarks. These mechanisms may be responsible for the observed lack of sediment infill and the typical presence of relatively coarser sediments inside pockmarks compared to the surrounding bed. In contrast, sediments transported as bedload are likely to be deposited in pockmarks because of the weakening of near-bed currents as well as lateral flow convergence associated with the upwelling. Bedload, however, may not be the dominant mode of sediment transport in areas covered by cohesive sediments, where pockmarks are found.     

Sedimentary and structural control on pockmark development—evidence from the Nyegga pockmark field, NW European margin

The Nyegga region, located at water depths of about 600–800 m on the NW European continental margin, contains more than 200 pockmarks. Recently collected TOPAS seismic profiles and EM1002 bathymetric records now provide high-resolution information on their seabed and shallow sub-seabed geological setting. The identified pockmarks are up to 15 m deep, between 30 m and 600 m across and reach a maximum area of ca. 315,000 m². The pockmarks are sediment-empty features. They do not have any preferred direction of orientation and show large variations in their shape. The pockmarks are restricted to a <16.2 cal. ka old sediment unit. This unit comprises sandy mud and is characterised by sedimentation rates of ca. 1 mm/year. The pockmarks are localised over a thick late Plio-Pleistocene prograding sediment package and a polygonal faulted Miocene-Oligocene ooze-rich unit. The late Plio-Plistocene deposits host bottom simulating reflectors, indicative of gas hydrate-bearing sediments. Inspection of the newly collected high-resolution dataset, combined with previously analysed sediment cores and 2D multichannel seismic profiles, reveals that the Nyegga pockmark field does not show any strong relationship between seabed features, sub-seabed structures and the sedimentary setting. This suggests a more complex evolution history of the Nyegga pockmark field then previously thought.     

Pockmarks in the inner Oslofjord,Norway

Multibeam bathymetric surveys of the Inner Oslofjord, Norway have revealed a high density of pockmarks in the 179-km² inner fjord area, which contains over 500 pockmarks of varying size, typically 20–50 m in diameter and 2–10 m deep. These pockmarks have been investigated with a variety of techniques, including acoustic subbottom profiling, sedimentological and geochemical analyses of cores, remotely operated vehicle observation, and morphometry. Both the distribution and shapes of the pockmarks suggest that they are related to structures in the bedrock underlying relatively thin (<50 m) unconsolidated glacial and postglacial sediments. The data provide no direct indication of a particular mode of pockmark formation, but release of large amounts of biogenic, shallow methane seems unlikely. Several lines of evidence point to a continuous process of pockmark formation followed by inactivity, with some pockmarks recently active whereas others have been inactive for a considerable time. Some pockmarks are characterised by coarse sediment in their centres. The density, variety and easy access make this pockmark field an ideal model area for pockmark research. John S. Gray is deceased.     

Geophysical exploration of an active pockmark field in the Bay of Concarneau,southern Brittany,and implications for resident suspension feeders

About a decade ago, a large field of pockmarks (individual features up to 30 m in diameter and <2 m deep) was discovered in water depths of 15–40 m in the Bay of Concarneau in southern Brittany along the French Atlantic coast, covering an overall area of 36 km² and characterised by unusually high pockmark densities in places reaching 2,500 per square kilometre. As revealed by geophysical swath and subbottom profile data ground-truthed by sediment cores collected during two campaigns in 2005 and 2009, the confines of the pockmark field show a spectacular spatial association with those of a vast expanse of tube mats formed by a benthic community of the suspension-feeding amphipod Haploops nirae. The present study complements those findings with subbottom chirp profiles, seabed sonar imagery and ultrasonic backscatter data from the water column acquired in April 2011. Results show that pockmark distribution is influenced by the thickness of Holocene deposits covering an Oligocene palaeo-valley system. Two groups of pockmarks were identified: (1) a group of large (>10 m diameter), more widely scattered pockmarks deeply rooted (up to 8 ms two-way travel time, TWTT) in the Holocene palaeo-valley infills, and (2) a group of smaller, more densely spaced pockmarks shallowly rooted (up to 2 ms TWTT) in interfluve deposits. Pockmark pore water analyses revealed high methane concentrations peaking at ca. 400 μl/l at 22 and 30 cm core depth in silty sediments immediately above Haploops-bearing layers. Water column data indicate acoustic plumes above pockmarks, implying ongoing pockmark activity. Pockmark gas and/or fluid expulsion resulting in increased turbidity (resuspension of, amongst others, freshly settled phytoplankton) could at least partly account for the strong spatial association with the phytoplankton-feeding H. nirae in the Bay of Concarneau, exacerbating impacts of anthropogenically induced eutrophication and growing offshore trawling activities. Tidally driven hydraulic pumping in gas-charged pockmarks represents a good candidate as large-scale short-term triggering mechanism of pockmark activation, in addition to episodic regional seismic activity.     

Acoustic evidence of shallow gas accumulations and active pockmarks in the ?zmir Gulf, Aegean sea

Based on high-resolution Chirp seismic, multibeam bathymetry and side scan sonar data collected in the ?zmir Gulf, Aegean Sea in 2008 and 2010, gas-related structures have been identified, which can be classified into three categories: (1) shallow gas accumulations and gas chimneys, (2) mud diapirs, and (3) active and inactive pockmarks. On the Chirp profiles, shallow gas accumulations were observed along the northern coastline of the outer ?zmir Gulf at 3-20 m below the seabed. They appear as acoustic turbidity zones and are interpreted as biogenic gas accumulations produced in organic-rich highstand fan sediments from the Gediz River. The diapiric structures are interpreted as shale or mud diapirs formed under lateral compression due to regional counter-clockwise rotation of Anatolian microplate. Furthermore, the sedimentary structure at the flanks suggests a continuous upward movement of the diapirs. Several pockmarks exist close to fault traces to the east of Hekim Island; most of them were associated with acoustic plumes indicating active degassing during the survey period in 2008. Another Chirp survey was carried out just over these plumes in 2010 to demonstrate if the gas seeps were still active. The surveys indicate that the gas seep is an ongoing process in the gulf. Based on the Chirp data, we proposed that the pockmark formation in the area can be explained by protracted seep model, whereby sediment erosion and re-distribution along pockmark walls result from ongoing (or long lasting) seepage of fluids over long periods of time. The existence of inactive pockmarks in the vicinity, however, implies that gas seepage may eventually cease or that it is periodic. Most of the active pockmarks are located over the fault planes, likely indicating that the gas seepage is controlled by active faulting.     

The spatial pattern and drainage cell characteristics of a pockmark field,Nile Deep Sea Fan

Over 25,300 seabed pockmarks were mapped from the Rosetta Channel region of the Western Nile Deep Sea Fan (NDSF) using concurrent High Resolution 2D, Chirp profiler and multibeam bathymetry data which spans the Holocene–Pleistocene period. Within the region, a pockmark field containing >13,800 pockmarks was analysed using spatial statistics to determine the distribution of pockmarks within the field. Pockmarks within the field are small (∼16 m diameter), shallow (∼0.5 m deep) circular depressions which formed within the last ∼ 6500 years. The fluid source for the field is identified as an accumulation/generation of gas beneath a hemipelagic seal c. 20–40 ms beneath the seabed. The position of the pockmarks is shown to be unrelated to the depth to the fluid source and an irregular high amplitude acoustic anomaly which is tentatively interpreted as a possible carbonate precipitate of biogenic microbial activity. Statistical spatial analysis of the field confirms the distribution of pockmarks is not random. An exclusion zone surrounding each individual pockmark is identified. The exclusion zone is a unique minimum radius around each pockmark which is not penetrated by any other pockmark. The exclusion zone works in unison with Self-Organised Criticality (SOC) in determining the spatial distribution of pockmarks within the field. The exclusion zone is interpreted as a pockmark “drainage cell”. A conceptual model for a pockmark drainage cell is proposed whereby pockmark formation dissipates a radius/area of fluid and overpressure, thereby preventing the formation of another pockmark within that cell. Consequently, pockmarks are observed to separate or produce anti-clustering tendencies within the field.     

Pockmarks off Big Sur, California

A pockmark field was discovered during EM-300 multi-beam bathymetric surveys on the lower continental slope off the Big Sur coast of California. The field contains ∼1500 pockmarks which are between 130 and 260 m in diameter, and typically are 8-12 m deep located within a 560 km² area. To investigate the origin of these features, piston cores were collected from both the interior and the flanks of the pockmarks, and remotely operated vehicle observation (ROV) video and sampling transects were conducted which passed through 19 of the pockmarks. The water column within and above the pockmarks was sampled for methane concentration. Piston cores and ROV collected push cores show that the pockmark field is composed of monotonous fine silts and clays and the cores within the pockmarks are indistinguishable from those outside the pockmarks. No evidence for either sediment winnowing or diagenetic alteration suggestive of fluid venting was obtained. ¹⁴C measurements of the organic carbon in the sediments indicate continuous sedimentation throughout the time resolution of the radiocarbon technique (∼45?000 yr BP), with a sedimentation rate of ∼10 cm per 1000 yr both within and between the pockmarks. Concentrations of methane, dissolved inorganic carbon, sulfate, chloride, and ammonium in pore water extracted from within the cores are generally similar in composition to seawater and show little change with depth, suggesting low biogeochemical activity. These pore water chemical gradients indicate that neither significant accumulations of gas are likely to exist in the shallow subsurface (∼100 m) nor is active fluid advection occurring within the sampled sediments. Taken together the data indicate that these pockmarks are more than 45?000 yr old, are presently inactive, and contain no indications of earlier fluid or gas venting events.     

舟山群岛东部青浜岛海域海底麻坑地貌及其成因分析

海底麻坑是由地层中流体向海底快速喷发或缓慢渗漏所形成的一种凹陷地貌,对其形态及成因机理进行深入研究具有重要意义。本研究基于高分辨率多波束地形、侧扫声纳、浅地层剖面及多道地震探测数据,对舟山群岛东部青浜岛海域发育的麻坑及其微地貌进行研究,分析表明:研究区发育有3个大型麻坑,并受到NE—SW向底流的改造而出现不同程度沿此方向的拉长,呈新月形或拉长形。麻坑侧壁呈现西陡东缓、西高东低的特征。3个大型麻坑内部发育有小的次级单元麻坑,或形成复合麻坑和链状麻坑等。麻坑之下地层出现声学浑浊等浅层气特征反射。在麻坑内外分别钻孔取样进行烃类气体的同位素分析,结果表明形成麻坑的流体为生物成因的甲烷气。研究区3个大型麻坑是在台风活动诱发下,由第四系地层中的甲烷气猛烈喷溢形成,而麻坑微地貌则是在随后发生的海底浅层气小规模缓慢逃逸形成的。     

Pockmark-like depressions near the Goliat hydrocarbon field,Barents Sea: Morphology and genesis

Pockmarks are observed worldwide along the continental margins and are inferred to be indicators of fluid expulsion. In the present study, we have analysed multibeam bathymetry and 2D/3D seismic data from the south-western Barents Sea, in relation to gas hydrate stability field and sediment type, to examine pockmark genesis. Seismic attributes of the sediments at and beneath the seafloor have been analysed to study the factors related to pockmark formation. The seabed depths in the study area are just outside the methane hydrate stability field, but the presence of higher order hydrocarbon gases such as ethane and/or propane in the expelled fluids may cause localised gas hydrate formation. The selective occurrence of pockmarks in regions of specific seabed sediment types indicates that their formation is more closely related to the type of seabed sediment than the source path of fluid venting such as faults. The presence of high acoustic backscatter amplitudes at the centre of the pockmarks indicates harder/coarser sediments, likely linked to removal of soft material. The pockmarks show high seismic reflection amplitudes along their fringes indicating deposition of carbonates precipitated from upwelling fluids. High seismic amplitude gas anomalies underlying the region away from the pockmarks indicate active fluid flow from hydrocarbon source rocks beneath, which is blocked by overlying less permeable formations. In areas of consolidated sediments, the upward flow is limited to open fault locations, while soft sediment areas allow diffused flow of fluids and hence formation of pockmarks over a wider region, through removal of fine-grained material.     

Physical experimental study on the formation mechanism of pockmark by aeration

Abstract

As one of the common geological disasters on the seafloor, the occurrence of pockmarks often indicates the existence of submarine fluid. And the formation of the pockmarks is generally attributed to the soil carried away by the fluid. The research established physical model test and found: (1) The pockmark formed after aeration, and particle gradation changed in the center area of the pockmark where coarse particle (particle size/0.25?mm) increased obviously and fine particle (particle size ≤0.075?mm) decreased significantly; (2) Comparing the volume of the pockmark with the volume of the soil extracted by siphon, it can be found that the volume of the pockmark was much larger than the loss of soil, and the difference reached its peak when the inflation pressure was 20?kPa; (3) Comparing the cone resistance of the soil in the surface and boundary, it can be found that the resistance of the center and marginal soil was much bigger than the outside, and the cone resistance of the boundary was also improved greatly. The research considered that the formation of pockmark was not only related to the soil being carried away by the bottom current, but also the consolidation by vibration existed.     

Microbially mediated methane and sulfur cycling in pockmark sediments of the Gdansk Basin, Baltic Sea

In the Russian sector of the Gdansk Basin (Baltic Sea), high organic matter influx fuels microbial processes resulting in the formation of reduced sediments with elevated methane concentrations. Investigated areas of geoacoustic anomalies (～245 km²) were found to contain three distinct geomorphologic structures (pockmarks), with a total area of ～1 km². Methane anomalies recorded in the water above one of these pockmarks were traced as high as 10 m above the bottom. In pockmark sediments, sulfate reduction and anaerobic oxidation of methane (AOM) occurred at high rates of 33 and 50 µmol dm^?3 day^?1, respectively. Integrated over 0–180 cm sediment depths, AOM exceeded methanogenesis almost tenfold. High AOM rates resulted from methane influx from deeper sediment layers. The δ¹³C signature of methane carbon (?78.1 to ?71.1‰) indicates the biogenic origin of pockmark methane. In pockmark sediments, up to 70% of reduced sulfur compounds was possibly produced via AOM.     

Linking a linear pockmark train with a buried Palaeozoic structure: a case study from the St. Lawrence Estuary

The 15-km-long Matane pockmark train belongs to a series of NNE-striking alignments of pockmarks mapped on the seafloor of the St. Lawrence Estuary. It includes 109 pockmarks that show a complete transition from well-defined, relatively deep (up to 8.6 m), crater-like depressions to subtle, partly buried morphological features, suggesting that pockmarks have formed at different periods along the whole alignment and that the location of fluid release has changed through time. On seismic profiles, pockmarks are characterized by vertical seismic chimneys that root in the (fractured?) hinge zone of an open anticline within the autochthonous Palaeozoic rocks of the St. Lawrence Platform. In absence of a geochemical characterization of expelled gas, the relationship between the Matane pockmark train and the anticline in a domain characterized by mature source rocks is the strongest evidence for the genetic link between pockmarks and the release of gas from an active hydrocarbon system or a reservoir located in the Palaeozoic succession.

北黄海海底麻坑群形态的定量研究及控制因素

本文基于高分辨率多波束水深数据和反向散射强度数据，对北黄海海底麻坑群的形态参数进行定量研究，结合水深、地形坡度和后向散射强度的变化准确界定了麻坑的轮廓，识别出圆形、椭圆形、拉长型麻坑共282个，并在ArcGIS软件中对其形态参数进行了分析计算，麻坑的平均长轴1.36 km，短轴0.78 km，直径0.94 km，面积0.88 km2，平均周长3.82 km，长宽比1.83，深度0.3~2.5 m，平均面积密集度13%，麻坑的剖面形态有麻坑边缘凹陷、中部有明显凸起（W1型），麻坑边缘凹陷、中部略凸起（W2型），麻坑中部单纯凹陷（V型），分别集中分布在麻坑群的北部、南部、西部。麻坑的平面规模大、深度小的原因与地层中形成麻坑的游离气体浓度较小有关，也可能受到了地震、海啸等外力的诱发。麻坑的长轴优势走向为ENE-WSW、NNE-SSW，底流对其形状的塑造起了较大作用，部分麻坑成串排列，形成串珠状的麻坑链，其排列方式受到海底古河道、古潟湖等沉积地层结构的控制。海底麻坑群发育区反向散射强度为-60~-71 dB，麻坑内部较麻坑外部平均高5 dB，可能为麻坑内部气体泄漏引起海底沉积物被剥蚀后残留下的粗颗粒物质或海底生物活动留下的遗迹导致的。     

Shallow plumbing systems inferred from spatial analysis of pockmark arrays

This study describes and analyses an extraordinary array of pockmarks at the modern seabed of the Lower Congo Basin (offshore Angola), in order to understand the fluid migration routes and shallow plumbing system of the area. The 3D seismic visualization of feeding conduits (pipes) allowed the identification of the source interval for the fluids expelled during pockmark formation. Spatial statistics are used to show the relationship between the underlying (polarised) polygonal fault (PPFs) patterns and seabed pockmarks distributions. Our results show PPFs control the linear arrangement of pockmarks and feeder pipes along fault strike, but faults do not act as conduits. Spatial statistics also revealed pockmark occurrence is not considered to be random, especially at short distances to nearest neighbours (<200 m) where anti-clustering distributions suggest the presence of an exclusion zone around each pockmark in which no other pockmark will form. The results of this study are relevant for the understanding of shallow fluid plumbing systems in offshore settings, with implications on our current knowledge of overall fluid flow systems in hydrocarbon-rich continental margins.     

Authigenic carbonates from active methane seeps offshore southwest Africa

The southwest African continental margin is well known for occurrences of active methane-rich fluid seeps associated with seafloor pockmarks at water depths ranging broadly from the shelf to the deep basins, as well as with high gas flares in the water column, gas hydrate accumulations, diagenetic carbonate crusts and highly diverse benthic faunal communities. During the M76/3a expedition of R/V METEOR in 2008, gravity cores recovered abundant authigenic carbonate concretions from three known pockmark sites—Hydrate Hole, Worm Hole, the Regab pockmark—and two sites newly discovered during that cruise, the so-called Deep Hole and Baboon Cluster. The carbonate concretions were commonly associated with seep-benthic macrofauna and occurred within sediments bearing shallow gas hydrates. This study presents selected results from a comprehensive analysis of the mineralogy and isotope geochemistry of diagenetic carbonates sampled at these five pockmark sites. The oxygen isotope stratigraphy obtained from three cores of 2–5?m length indicates a maximum age of about 60,000–80,000?years for these sediments. The authigenic carbonates comprise mostly magnesian calcite and aragonite, associated occasionally with dolomite. Their very low carbon isotopic compositions (–61.0?<?δ¹³C ‰ V-PDB?<?–40.1) suggest anaerobic oxidation of methane (AOM) as the main process controlling carbonate precipitation. The oxygen isotopic signatures (+2.4?<?δ¹⁸O ‰ V-PDB?<?+6.2) lie within the range in equilibrium under present-day/interglacial to glacial conditions of bottom seawater; alternatively, the most positive δ¹⁸O values might reflect the contribution of ¹⁸O-rich water from gas hydrate decomposition. The frequent occurrence of diagenetic gypsum crystals suggests that reduced sulphur (hydrogen sulphide, pyrite) from sub-seafloor sediments has been oxidized by oxygenated bottom water. The acidity released during this process can potentially induce the dissolution of carbonate, thereby providing enough Ca²⁺ ions for pore solutions to reach gypsum saturation; this is thought to be promoted by the bio-irrigation and burrowing activity of benthic fauna. The δ¹⁸O–δ¹³C patterns identified in the authigenic carbonates are interpreted to reflect variations in the rate of AOM during the last glacial–interglacial cycle, in turn controlled by variably strong methane fluxes through the pockmarks. These results complement the conclusions of Kasten et al. in this special issue, based on authigenic barite trends at the Hydrate Hole and Worm Hole pockmarks which were interpreted to reflect spatiotemporal variations in AOM related to subsurface gas hydrate formation–decomposition.     

Formation mechanism of large pockmarks in the subaqueous Yellow River Delta

Abstract

We have identified large pockmarks in an area of approximately 0.3?km² in the subaqueous Yellow River Delta in the Chengdao Sea. Gas eruption channels not been identified in the sediment layers in this area, and the formation mechanism of these large pockmarks remains unknown. To study the formation mechanism of these large pockmarks, we constructed a layered silty sediment model composed of appropriate geological materials. Then, we calculated the stress, displacement, and excess pore pressure in the layered silty sediment from the surface to a depth of 10?m using the Biot theory. A comparative analysis of the calculated results and the data measured in the field was then performed. Based on these results, we established a new formation mechanism for the large pockmarks. With the occurrence of storm waves, two extreme areas of displacement and excess pore pressure appeared in the layered silty sediment. These extreme values increased quickly in the seabed during the continuous action of storm waves. When the excess pore pressure surpassed the effective stress, the top silty layer instantly liquefied and then reconsolidated. Then, when the pore pressure of the interface position exceeded the effective stress produced by the overlying sediment, the sediments experienced “sand boil” damage. With the repeated action of strong waves, the boundary of the pockmark continued to expand, forming a large and stable pockmark. This work is of great value for further understanding and mitigating marine geologic hazards, such as coastal erosion, silt deposition, and unstable sediment, in the subaqueous Yellow River Delta.