A determination of the CH4, NO x and CO2 emissions from the Prudhoe Bay,Alaska oil development

In this paper we quantify the CH₄, CO₂ and NO _x emissions during routine operations at a major oil and gas production facility, Prudhoe Bay, Alaska, using the concentrations of combustion by products measured at the NOAA-CMDL observatory at Barrow, Alaska and fuel consumption data from Prudhoe Bay. During the 1989 and 1990 measurement campaigns, 10 periods (called events) were unambiguously identified where surface winds carry the Prudhoe Bay emissions to Barrow (approximately 300 km). The events ranged in duration from 8–48 h and bring ambient air masses containing substantially elevated concentrations of CH₄, CO₂ and NO _y to Barrow. Using the slope of the observed CH₄ vs CO₂ concentrations during the events and the CO₂ emissions based on reported fuel consumption data, we calculate annual CH₄ emissions of (24+/–8)×10³ metric tons from the facility. In a similar manner, the annual NO _x emissions are calculated to be (12+/–4)×10³ metric tons, which is in agreement with an independently determined value. The calculated CH₄ emissions represent the amount released during routine operations including leakage. However this quantity would not include CH₄ released during non-routine operations, such as from venting or gas flaring.     

GREENHOUSE GASES FROM DEFORESTATION IN BRAZILIAN AMAZONIA: NET COMMITTED EMISSIONS

Deforestation in Brazilian Amazonia is a significant source of greenhouse gases today and, with almost 90% of the originally forested area still uncleared, is a very large potential source of future emissions. The 1990 rate of loss of forest (13.8 × 10³ km²/year) and cerrado savanna (approximately 5 × 10³ km²/year) was responsible for releasing approximately 261 × 10⁶ metric tons of carbon (10⁶ t C) in the form of CO2, or 274–285 × 10⁶ t of CO2-equivalent C considering IPCC 1994 global warming potentials for trace gases over a 100-year horizon. These calculations consider conversion to a landscape of agriculture, productive pasture, degraded pasture, secondary forest, and regenerated forest in the proportions corresponding to the equilibrium condition implied by current land-use patterns. Emissions are expressed as net committed emissions, or the gases released over a period of years as the carbon stock in each hectare deforested approaches a new equilibrium in the landscape that replaces the original forest. For low and high trace gas scenarios, respectively, 1990 clearing produced net committed emissions (in 10⁶ t of gas) of 957–958 for CO2, 1.10–1.42 for CH₄, 28–35 for CO, 0.06–0.16 for N₂O, 0.74–0.74 for NO_x and 0.58–1.16 for non-methane hydrocarbons.     

Global Warming and Tropical Land-Use Change: Greenhouse Gas Emissions from Biomass Burning, Decomposition and Soils in Forest Conversion, Shifting Cultivation and Secondary Vegetation

Tropical forest conversion, shiftingcultivation and clearing of secondary vegetation makesignificant contributions to global emissions ofgreenhouse gases today, and have the potential forlarge additional emissions in future decades. Globally, an estimated 3.1×10⁹ t of biomasscarbon of these types is exposed to burning annually,of which 1.1×10⁹ t is emitted to the atmospherethrough combustion and 49×10⁶ t is converted tocharcoal (including 26–31×10⁶ t C of blackcarbon). The amount of biomass exposed to burningincludes aboveground remains that failed to burn ordecompose from clearing in previous years, andtherefore exceeds the 1.9×10⁹ t of abovegroundbiomass carbon cleared on average each year. Above-and belowground carbon emitted annually throughdecomposition processes totals 2.1×10⁹ t C. Atotal gross emission (including decomposition ofunburned aboveground biomass and of belowgroundbiomass) of 3.41×10⁹ t C year^-1 resultsfrom clearing primary (nonfallow) and secondary(fallow) vegetation in the tropics. Adjustment fortrace gas emissions using IPCC Second AssessmentReport 100-year integration global warming potentialsmakes this equivalent to 3.39×10⁹ t ofCO₂-equivalent carbon under a low trace gasscenario and 3.83×10⁹ t under a high trace gasscenario. Of these totals, 1.06×10⁹ t (31%)is the result of biomass burning under the low tracegas scenario and 1.50×10⁹ t (39%) under thehigh trace gas scenario. The net emissions from allclearing of natural vegetation and of secondaryforests (including both biomass and soil fluxes) is2.0×10⁹ t C, equivalent to 2.0–2.4×10⁹ t of CO₂-equivalent carbon. Adding emissions of0.4×10⁹ t C from land-use category changesother than deforestation brings the total for land-usechange (not considering uptake of intact forest,recurrent burning of savannas or fires in intactforests) to 2.4×10⁹ t C, equivalent to 2.4–2.9×10⁹ t of CO₂-equivalent carbon. The totalnet emission of carbon from the tropical land usesconsidered here (2.4×10⁹ t C year^-1)calculated for the 1981–1990 period is 50% higherthan the 1.6×10⁹ t C year^-1 value used by the Intergovernmental Panel on Climate Change. The inferred (= `missing') sink in the global carbonbudget is larger than previously thought. However,about half of the additional source suggested here maybe offset by a possible sink in uptake by Amazonianforests. Both alterations indicate that continueddeforestation would produce greater impact on globalcarbon emissions. The total net emission of carboncalculated here indicates a major global warmingimpact from tropical land uses, equivalent toapproximately 29% of the total anthropogenic emissionfrom fossil fuels and land-use change.     

Changes of cloud water chemical composition in the Western Sudety Mountains, Poland

The changing chemical composition of cloud water and precipitation in the Western Sudety Mountains are discussed against the background of air-pollution changes in the Black Triangle since the 1980s until September 2004. A marked reduction of sulphur dioxide emissions between the early 1990's and the present (from almost 2 million tons to around 0.2 million tons) has been observed, with a substantial decline of sulphate and hydrogen concentration in cloud water (SO₄²⁻ from more than 200 to around 70 μmol l^− 1; H⁺ from 150 to 50 μmol l^− 1) and precipitation (SO₄²⁻ from around 80 to 20–30 μmol l^− 1; H⁺ from around 60 to 10–15 μmol l^− 1) samples. At some sites, where fog/cloud becomes the major source of pollutants, deposition hot spots are still observed where, for example, nitrogen deposition can exceed 20 times the relevant critical load. The results show that monitoring of cloud water chemistry can be a sensitive indicator of pollutant emissions.     

Tropical deforestation and atmospheric carbon dioxide

Recent estimates of the net release of carbon to the atmosphere from deforestation in the tropics have ranged between 0.4 and 2.5 × 10¹⁵ g yr^–1. Two things have happened to require a revision of these estimates. First, refinements of the methods used to estimate the stocks of carbon in the vegetation of tropical forests have produced new estimates that are intermediate between the previous high and low estimates of carbon stocks. When these revised estimates were used here to calculate the emissions of carbon from deforestation, the new range was 1.0–2.0 × 10¹⁵ g C.Second, the previous range of estimates of flux was based on rates of deforestation in 1980. Myers' recent estimate of the rates of tropical deforestation in 1989 is about 90% higher than the rates just 10 years ago. When these recent rates were used to calculate the current net flux of carbon to the atmosphere, the range was between 1.6 and 2.7 × 10¹⁵ g C.Other uncertainties expanded this range, however, to 1.1–3.6 × 10¹⁵ g C yr^–1. Three factors contributed about equally to the expanded range: rates of deforestation, the fate of deforested lands (permanent or temporary clearing), and carbon stocks of forests, including anthropogenic reductions of carbon stocks within forests (thinning or degradation).     

CARBON EMISSIONS FROM MEXICAN FORESTS: CURRENT SITUATION AND LONG-TERM SCENARIOS

Estimates of carbon emissions from the forest sector in Mexico are derived for the year 1985 and for two contrasting scenarios in 2025. The analysis covers both tropical and temperate closed forests. In the mid-1980s, approximately 804,000 ha/year of closed forests suffered major perturbations, of which 668,000 ha was deforestation. Seventy-five percent of total deforestation is concentrated in tropical forests. The resulting annual carbon balance from land-use change is estimated at 67.0 × 10⁶ tons/year, which lead to net emissions of 52.3 × 10⁶ tons/year accounting for the carbon uptake in restoration plantations and degraded forest lands. This last figure represents approximately 40% of the country's estimated annual total carbon emissions for 1985–1987. The annual carbon balance from the forest sector in 2025 is expected to decline to 28.0 × 10⁶ t in the reference scenario and to become negative (i.e., a carbon sink), 62.0 × 10⁶ t in the policy scenario. A number of policy changes are identified that would help achieve the carbon sequestration potential identified in this last scenario.     

Sink Potential of Canadian Agricultural Soils

Net greenhouse gas (GHG) emissions from Canadian crop and livestock production were estimated for 1990, 1996 and 2001 and projected to 2008. Net emissions were also estimated for three scenarios (low (L), medium (M) and high (H)) of adoption of sink enhancing practices above the projected 2008 level. Carbon sequestration estimates were based on four sink-enhancing activities: conversion from conventional to zero tillage (ZT), reduced frequency of summerfallow (SF), the conversion of cropland to permanent cover crops (PC), and improved grazing land management (GM). GHG emissions were estimated with the Canadian Economic and Emissions Model for Agriculture (CEEMA). CEEMA estimates levels of production activities within the Canadian agriculture sector and calculates the emissions and removals associated with those levels of activities. The estimates indicate a decline in net emissions from 54 Tg CO₂–Eq yr^–1 in1990 to 52 Tg CO₂–Eq yr^–1 in 2008. Adoption of thesink-enhancing practices above the level projected for 2008 resulted in further declines in emissions to 48 Tg CO₂–Eq yr^–1 (L), 42 TgCO₂–Eq yr^–1 (M) or 36 Tg CO₂–Eq yr^–1 (H). Among thesink-enhancing practices, the conversion from conventional tillage to ZT provided the largest C sequestration potential and net reduction in GHG emissions among the scenarios. Although rates of C sequestration were generally higher for conversion of cropland to PC and adoption of improved GM, those scenarios involved smaller areas of land and therefore less C sequestration. Also, increased areas of PC were associated with an increase in livestock numbers and CH₄ and N₂O emissions from enteric fermentation andmanure, which partially offset the carbon sink. The CEEMA estimates indicate that soil C sinks are a viable option for achieving the UNFCCC objective of protecting and enhancing GHG sinks and reservoirs as a means of reducing GHG emissions (UNFCCC, 1992).     

Global distribution of natural freshwater wetlands and rice paddies,their net primary productivity,seasonality and possible methane emissions

A global data set on the geographic distribution and seasonality of freshwater wetlands and rice paddies has been compiled, comprising information at a spatial resolution of 2.5° by latitude and 5° by longitude. Global coverage of these wetlands total 5.7×10⁶ km² and 1.3×10⁶ km², respectively. Natural wetlands have been grouped into six categories following common terminology, i.e. bog, fen, swamp, marsh, floodplain, and shallow lake. Net primary productivity (NPP) of natural wetlands is estimated to be in the range of 4–9×10¹⁵ g dry matter per year. Rice paddies have an NPP of about 1.4×10¹⁵ g y^–1. Extrapolation of measured CH₄ emissions in individual ecosystems lead to global methane emission estimates of 40–160 Teragram (1 Tg=10¹² g) from natural wetlands and 60–140 Tg from rice paddies per year. The mean emission of 170–200 Tg may come in about equal proportions from natural wetlands and paddies. Major source regions are located in the subtropics between 20 and 30° N, the tropics between 0 and 10° S, and the temperate-boreal region between 50 and 70° N. Emissions are highly seasonal, maximizing during summer in both hemispheres. The wide range of possible CH₄ emissions shows the large uncertainties associated with the extrapolation of measured flux rates to global scale. More investigations into ecophysiological principals of methane emissions is warranted to arrive at better source estimates.     

Estimates of gross and net fluxes of carbon between the biosphere and the atmosphere from biomass burning

In order to estimate the production of charcoal and the atmospheric emissions of trace gases volatilized by burning we have estimated the global amounts of biomass which are affected by fires. We have roughly calculated annual gross burning rates ranging between about 5 Pg and 9 Pg (1 Pg = 10¹⁵ g) of dry matter (2–4 Pg C). In comparison, about 9–17 Pg of above-ground dry matter (4–8 Pg C) is exposed to fires, indicating a worldwide average burning efficiency of about 50%. The production of dead below-ground dry matter varies between 6–9 Pg per year. We have tentatively indicated the possibility of a large production of elemental carbon (0.5–1.7 Pg C/yr) due to the incomplete combustion of biomass to charcoal. This provides a sink for atmospheric CO₂, which would have been particularly important during the past centuries. From meager statistical information and often ill-documented statements in the literature, it is extremely difficult to calculate the net carbon release rates to the atmosphere from the biomass changes which take place, especially in the tropics. All together, we calculate an overall effect lof the biosphere on the atmospheric carbon dioxide budget which may range between the possibilities of a net uptake or a net release of about 2 Pg C/yr. The release of CO₂ to the atmosphere by deforestation projects may well be balanced by reforestation and by the production of charcoal. Better information is needed, however, to make these estimates more reliable.Now at the Max-Planck-Institute for Chemistry, Mainz, FRG.The National Center for Atmospheric Research is sponsored by the National Science Foundation.     

Meteorology and haze structure during AGASP-II,Part 1: Alaskan Arctic flights, 2–10 April 1986

The second Arctic Gas and Aerosol Sampling Program (AGASP-II) was conducted across the Alaskan and Canadian Arctic in April 1986, to study the in situ aerosol, and the chemical and optical properties of Arctic haze. The NOAA WP-3D aircraft, with special instrumentation added, made six flights during AGASP-II. Measurements of wind, pressure, temperature, ozone, water vapor, condensation nuclei (CN) concentration, and aerosol scattering extinction (b_sp) were used to determine the location of significant haze layers. The measurements made on the first three flights, over the Arctic Ocean north of Barrow and over the Beaufort Sea north of Barter Island, Alaska are discussed in detail in this report of the first phase of AGASP II. In the Alaskan Arctic the WP-3D detected a large and persistent region of haze between 960 and 750 mb, in a thermally stable layer, on 2, 8, and 9 April 1986. At its most dense, the haze contained CN concentrations >10,000 cm^–3 and b_sp of 80×10^–6 m^–1 suggesting active SO₂ to H₂SO₄ gas-to-particle conversion. Calculations based upon observed SO₂ concentrations and ambient relative humidities suggest that 10⁴–10⁵ small H₂SO₄ droplets could have been produced in the haze layers. High concentrations of sub-micron H₂SO₄ droplets were collected in haze. Ozone concentrations were 5–10 ppb higher in the haze layers than in the surrounding troposphere. Outside the regions of haze, CN concentrations ranged from 100 to 400 cm^–3 and b_sp values were about (20–40)×10^–6 m^–1. Air mass trajectories were computed to depict the air flow upwind of regions in which haze was observed. In two cases the back trajectories and ground measurements suggested the source to be in central Europe.     

The solubility and behaviour of acid gases in the marine aerosol

The following Henry's law constants (K _H/mol²kg^-2atm^-1) for HNO₃ and the hydrohalic acids have been evaluated from available partial pressure and other thermodynamic data from 0°–40°C, 1 atm total pressure: HNO ₃ , 40°C–5.85×10⁵; 30°C–1.50×10⁶; 25°C–2.45×10⁶; 20°C–4.04×10⁶; 10°C–1.15×10⁷; 0°C–3.41×10⁷. HF, 40°C–3.2; 30°C–6.6; 25°C–9.61; 20°C–14.0; 10°C–32.0; 0°C–76. HCl, 40°C–4.66×10⁵; 30°C–1.23×10⁶; 25°C–2.04×10⁶; 20°C–3.37×10⁶; 10°C–9.71×10⁶; 0°C–2.95×10⁷. HBr, 40°C–2.5×10⁸; 30°C–7.5×10⁸; 25°C–1.32×10⁹; 20°C–2.37×10⁹; 10°C–8.10×10⁹; 0°C–3.0×10¹⁰. HI, 40°C–5.2×10⁸; 30°C–1.5×10⁹; 25°C–2.5×10⁹; 20°C–4.5×10⁹; 10°C–1.5×10¹⁰; 0°C–5.0×10¹⁰. Simple equilibrium models suggest that HNO₃, CH₃SO₃H and other acids up to 10x less soluble than HCl displace it from marine seasalt aerosols. HF is displaced preferentially to HCl by dissolved acidity at all relative humidities greater than about 80%, and should be entirely depleted in aged marine aerosols.     

How long is coal's future?

Nearly all scenarios for future U.S. energy supply systems show heavy dependence on coal. The magnitude depends on assumptions as to reliance on nuclear fission, degree of electrification, and rate of GNP growth, and ranges from 700 million tons to 2300 million tons per year. However, potential climate change resulting from increasing atmospheric carbon dioxide concentrations may prevent coal from playing a major role. The carbon in the carbon dioxide produced from fossil fuels each year is about 1/10 the net primary production by terrestrial plants, but the fossil fuel production has been growing exponentially at 4.3% per year. Observed atmospheric CO₂ concentrations have increased from 315 ppm in 1958 to 330 ppm in 1974 - in 1900, before much fossil fuel was burned, it was about 290–295 ppm. Slightly over one-half the CO₂ released from fossil fuels is accounted for by the increase observed in the atmosphere; at present growth rates the quantities are doubling every 15–18 years. Atmospheric models suggest a global warming of about 2 K if the concentration were to rise to two times its pre-1900 value - enough to change the global climate in major (but largely unknown) ways. With the current rate of increase in fossil fuel use, the atmospheric concentration should reach these levels by about 2030. A shift to coal as a replacement for oil and gas gives more carbon dioxide per unit of energy; thus if energy growth continues with a concurrent shift toward coal, high concentrations can be reached somewhat earlier. Even projections with very heavy reliance on non-fossil energy (Neihaus) after 2000 show atmospheric carbon dioxide concentrations reaching 475 ppm.First presented to the symposium, Coal Science and our National Expectations, Annual Meeting of the American Association for the Advancement of Science, Boston, Massachusetts, February 20, 1976.     

Assessment of Major Pools and Fluxes of Carbon in Indian Forests

The major pools including phytomass, soil, litter, and fluxes of carbon (C)due to litterfall and landuse changes were estimated for Indian forests. Basedon growing stock-volume approach at the state and district levels, the Indianforest phytomass was estimated in the range of 3.8–4.3 PgC. The totalsoil organic pool in the top 1m depth was estimated as 6.8 PgC, usingestimated soil organic carbon densities and Remote Sensing (RS) based area byforest types. Based on 122 published Indian studies and RS-based forest area,the total litterfall carbon flux was estimated as 208.8 MgCha^–1 yr^–1.The cumulative net carbon flux (1880–1996) from Indian forests(1880–1996) due to landuse changes (deforestation, afforestation andphytomass degradation) was estimated as 5.4 PgC, using a simple book-keepingapproach. The mean annual net C flux due to landuse changes during1985–1996 was estimated as 9.0 TgC yr^–1. For the recentperiod, the Indian forests are nationally a small source with some regionsacting as small sinks of carbon as well. The improved quantification of poolsand fluxes related to forest carbon cycle is important for understanding thecontribution of Indian forests to net carbon emissions as well as theirpotential for carbon sequestration in the context of the Kyoto protocol.     

Isotopic Composition of Non-Methane Hydrocarbons in Emissions from Biomass Burning

The stable carbon isotope ratios of nonmethane hydrocarbons (NMHC) and methyl chloride emitted from biomass burning were determined by analyzing seven whole air samples collected during different phases of the burning process as part of a laboratory study of wood burning. The average of the stable carbon isotope ratios of emitted alkanes, alkenes and aromatic compounds is identical to that of the burnt fuel; more than 50% of the values are within a range of ±1.5 of thecomposition of the burnt fuel wood. Thus for the majority of NMHC emitted from biomass burning stable carbon isotope ratio of the burnt fuel a good first order approximation for the isotopic composition of the emissions. Of the more than twenty compounds we studied, only methyl chloride and ethyne differed in stable carbon isotope ratios by more than a few per mil from the composition of the fuel. Ethyne is enriched in ¹³C by approximately 20–30, and most of the variability can beexplained by a dependence on flame temperature. The ¹³C values decreaseby 0.019 /K (±0.0053/K) with increasing temperature. Methyl chloride is highly depleted in ¹³C, on average by25. However the results cover a wide range of nearly 30. Specifically, in two measurements with wood from Eucalyptus (Eucalyptus delegatensis) as fuel we observed the emission of extremely light methyl chloride (–68.5and–65.5). This coincides with higher than average emission ratiosfor methyl chloride (15.5 × 10^–5 and 18 ×10^–5 mol CH₃Cl/mol CO₂). These high emission ratios are consistent with the highchlorine content of the burnt fuel, although, due to the limited number of measurements, it would be premature to generalize these findings. The limited number of observations also prevents any conclusion on a systematic dependence between chlorine content of the fuel, emission ratios and stable carbon isotope ratio of methyl chloride emissions. However, our results show that a detailed understanding of the emissions of methyl chloride from chloride rich fuels is important for understanding its global budget. It is also evident that the usefulness of stable carbon isotope ratios to constrain the global budget of methyl chloride will be complicated by the very large variability of the stable carbon isotope ratio of biomass burning emissions. Nevertheless, ultimately the large fractionation may provide additional constraints for the contribution of biomass burning emissions to the atmospheric budget of methyl chloride.     

Potential Soil C Sequestration on U.S. Agricultural Soils

Soil carbon sequestration has been suggested as a means to help mitigate atmospheric CO₂ increases, however there is limited knowledge aboutthe magnitude of the mitigation potential. Field studies across the U.S. provide information on soil C stock changes that result from changes in agricultural management. However, data from such studies are not readily extrapolated to changes at a national scale because soils, climate, and management regimes vary locally and regionally. We used a modified version of the Intergovernmental Panel on Climate Change (IPCC) soil organic C inventory method, together with the National Resources Inventory (NRI) and other data, to estimate agricultural soil C sequestration potential in the conterminous U.S. The IPCC method estimates soil C stock changes associated with changes in land use and/or land management practices. In the U.S., the NRI provides a detailed record of land use and management activities on agricultural land that can be used to implement the IPCC method. We analyzed potential soil C storage from increased adoption of no-till, decreased fallow operations, conversion of highly erodible land to grassland, and increased use of cover crops in annual cropping systems. The results represent potentials that do not explicitly consider the economic feasibility of proposed agricultural production changes, but provide an indication of the biophysical potential of soil C sequestration as a guide to policy makers. Our analysis suggests that U.S. cropland soils have the potential to increase sequestered soil C by an additional 60–70 Tg (10¹²g) C yr^{– 1}, over present rates of 17 Tg C yr^–1(estimated using the IPCC method), with widespread adoption of soil C sequestering management practices. Adoption of no-till on all currently annually cropped area (129Mha) would increase soil C sequestration by 47 Tg C yr^–1. Alternatively, use of no-till on 50% of annual cropland, with reduced tillage practices on the other 50%, would sequester less – about37 Tg C yr^–1. Elimination of summer fallow practices and conversionof highly erodible cropland to perennial grass cover could sequester around 20 and 28Tg C yr^–1, respectively. The soil C sequestration potentialfrom including a winter cover crop on annual cropping systems was estimated at 40Tg C yr^–1. All rates were estimated for a fifteen-yearprojection period, and annual rates of soil C accumulations would be expected to decrease substantially over longer time periods. The total sequestration potential we have estimated for the projection period (83 Tg C yr^–1) represents about 5% of 1999total U.S. CO₂ emissions or nearly double estimated CO₂ emissionsfrom agricultural production (43 Tg C yr^–1). For purposes ofstabilizing or reducing CO₂ emissions, e.g., by 7% of 1990 levels asoriginally called for in the Kyoto Protocol, total potential soil C sequestration would represent 15% of that reduction level from projected 2008 emissions(2008 total greenhouse gas emissions less 93% of 1990 greenhouse gasemissions). Thus, our analysis suggests that agricultural soil C sequestration could play a meaningful, but not predominant, role in helping mitigate greenhouse gas increases.     

Heat island and oasis effects of vegetative canopies: Micro-meteorological field-measurements

Dry-bulb temperature, dew-point, wind speed, and wind direction were measured in and around an isolated vegetative canopy in Davis CA from 12 to 25 October 1986. These meteorological variables were measured 1.5 m above ground along a transect of 7 weather stations set up across the canopy and the upwind/downwind open fields. These variables were averaged every 15 minutes for a period of two weeks so we could analyze their diurnal cycles as well as their spatial variability. The results indicate significant nocturnal heat islands and daytime oases within the vegetation stand, especially in clear weather. Inside the canopy within 5 m of its upwind edge, daytime temperature fell by as much as 4.5 °C, whereas the nighttime temperature rose by 1 °C. Deeper into the canopy and downwind, the daytime drop in temperature reached 6 °C, and the nighttime increase reached 2 °C. Wind speed was reduced by ~ 2 ms^–1 in mild conditions and by as much as 6.7 ms^–1 during cyclonic weather when open-field wind speed was in the neighborhood of 8 ms^–1. Data from this project were used to construct correlations between temperature and wind speed within the canopy and their corresponding ambient, open-field values.With 10 Figures     

Nonmethane hydrocarbons in an oceanic atmosphere

C₂–C₆ Nonmethane hydrocarbons (NMHC) and radioactive continental tracers were measured during two oceanographic cruises, in June 1982 in the Mediterranean and Red Sea, and in November 1982 across the North Atlantic and South Pacific oceans. Typical concentrations in marine atmosphere are between 0.05 and 0.2 ppbv. Owing to their similar lifetimes, propane and radon-222 are found to be well correlated. This relationship establishes that propane is mainly produced over lands and enables us to estimate its continental source strength at about 60×10⁶ tons of carbon per year.Also at Université de Picardie     

Turbulent fluxes of momentum,heat and water vapor in the atmospheric surface layer at sea during ATEX

The vertical turbulent fluxes have been determined during the Atlantic Trade Wind Experiment (ATEX) both by direct and profile methods. The drag coefficient obtained from direct measurements was c _D = 1.39 × 10^–3. A distortion of the wind profile due to wave action could be demonstrated, this produced an increased drag coefficient estimated by the profile method. The dissipation technique using the downwind spectrum gave a lower drag coefficient of 1.26 × 10^–3, probably due to non-isotropic conditions (the ratio of vertical to downwind spectrum at high frequencies scattered considerably with an average of 1 instead of 4/3).From direct measurements, the sensible heat flux showed a poor correlation with the bulk parameter product U, contrary to the heat flux obtained from profiles. It is shown that this is due to the higher frequency part of the cospectrum, say above 0.25 Hz, which contributes more than 50 % of the total flux. Determination of the heat flux from temperature fluctuations by the dissipation method would be in agreement with the direct determination only if the corresponding Kolmogoroff constant were 2.1 instead of 0.8.For the vertical flux of water vapor obtained from profiles, the bulk transfer coefficient was 1.28 × 10^–3.This work was supported by the Deutsche Forschungsgemeinschaft, Schwerpunktprogramm Meeresforschung and later the Sonderforschungsbereich Meeresforschung Hamburg.     

A Local-Scale Study of the Trace Gas Emissions from Vegetation Burning around the Village of Dalun, Ghana, with Respect to Seasonal Vegetation Changes and Burning Practices

The annual trace gas emissions from a West African rural region were calculated using direct observations of gas emissions and burning practices, and the findings compared to the guidelines published by the IPCC. This local-scale study was conducted around the village of Dalun in the Northern Region of Ghana, near the regional capital of Tamale. Two types of fires were found in the region – agricultural fires andwildfires. Agricultural fires are intentionally set in order to remove shrub and crop residues; wildfires are mostly ignited by herders to remove inedible grasses and to promote the growth of fresh grass. An agricultural fire is ignited with a fire front moving against the wind (backfire), whereas a wildfire moves with the wind (headfire). Gas emissions (CO₂, CO and NO) weremeasured by burning eight experimental plots, simulating both headfires and backfires. A common method of evaluating burning conditions is to calculate modified combustion efficiency (MCE), which expresses the percentage of the trace gases released as CO₂. Modified combustion efficiency was95% in the wildfires burned as headfires, but only 90% in the backfires.The burned area in the study region was determined by classifying a SPOT HRV satellite image taken about two months into the dry season. Fires were classified as either old burned areas or new burned areas as determined by the gradient in moisture content in the vegetation from the onset of the dry season. Classified burned areas were subsequently divided into two classes depending on whether the location was in the cultivated area or in the rangeland area, this sub-classification thus indicating whether the fire had been burned as a backfire or headfire. Findings showed that the burned area was 48% of the total region, and that the ratio of lowland wildfiresto agricultural fires was 3:1. The net trace gas release from the classified vegetation burnings were extrapolated to 26–46×10⁸ gCO₂, 78–302×10⁶ g CO,17–156×10⁵ g CH₄,16–168×10⁵ g NMHC and 11–72×10³ NO_x. Calculation of the emissionsusing proposed IPCC default values on burned area and average biomass resulted in a net emission 5 to 10 times higher than the measured emission values. It was found that the main reason for this discrepancy was not the emission factorsused by the IPCC, but an exaggerated fuel load estimate.     

Fluxes of gases and particles above a deciduous forest in wintertime

Eddy-correlation measurements of the vertical fluxes of ozone, carbon dioxide, fine particles with diameter near 0.1 m, and particulate sulfur, as well as of momentum, heat and water vapor, have been taken above a tall leafless deciduous forest in wintertime. During the experimental period of one week, ozone deposition velocities varied from about 0.1 cm s^–1 at night to more than 0.4 cm s^-1 during the daytime, with the largest variations associated primarily with changes in solar irradiation. Most of the ozone removal took place in the upper canopy. Carbon dioxide fluxes were directed upward due to respiration and exhibited a strong dependence on air temperature and solar heating. The fluxes were approximately zero at air temperatures less than 5 °C and approached 0.8 mg m^–2 s^–1 when temperatures exceeded 15 °C during the daytime. Fine-particle deposition rates were large at times, with deposition velocities near 0.8 cm s^–1 when turbulence levels were high, but fluxes directed upward were found above the canopy when the surface beneath was covered with snow. Diffusional processes seemed to dominate fine-particle transfer across quasilaminar layers and subsequent deposition to the upper canopy. Deposition velocities for particulate sulfur were highly variable and averaged to a value small in magnitude as compared to similar measurements taken previously over a pine forest in summer.