Timing of the final closure of the Proto-Tethys Ocean: Constraints from provenance of early Paleozoic sedimentary rocks in West Kunlun,NW China

Collision can be subdivided into “soft” and “hard” types, with the “soft” collision occurring after double-sided oceanic subduction and the “hard” collision after single-sided oceanic subduction. Although two types of collision involve different geodynamics and generate distinct petrological assemblages, whether they can preserve distinct records of detrital zircons remains unclear. This study confirms “soft” collision between the north Western Kunlun terrane (NKT) and the south Western Kunlun terrane (SKT) after the closure of the Proto-Tethys Ocean. We further compare detrital zircon Hf isotope compositions of the “soft” collision with those of the “hard” collision related to the amalgamation of Rodinia in southern Tarim. Our results show that the NKT is characterized by dominant ca. 800 Ma zircons, whereas the SKT is featured by ca. 244 Ma, ca. 440 Ma, and ca. 620 Ma zircons. As such, sample 17WP53 deposited at 431 Ma in the NKT displays a dominant peak at ca. 500 Ma, indicating minor material exchange between the NKT and the SKT at ca. 431 Ma. Given the 420–405 Ma North Kudi granites displaying geochemical features of within-plate granites formed at a post-orogenic stage, we infer that the final closure of the Proto-Tethys Ocean occurred at 431–420 Ma along Western Kunlun. Moreover, zircon ε_Hf(t) data indicate that the “soft” collision between the NKT and the SKT during the amalgamation of Gondwana produced ca. 40% of juvenile crustal materials, whereas the “hard” collision related to the formation of Rodinia generated ca. 12% of juvenile crustal materials. More juvenile materials generated in the “soft” collision may be attributed to complete detachment and sinking of a oceanic slab.     

Isotopic analysis of the super-large Shuangjianzishan Pb–Zn–Ag deposit in Inner Mongolia,China: Constraints on magmatism,metallogenesis, and tectonic setting

The super-large Shuangjianzishan Pb–Zn–Ag deposit is a newly discovered deposit located in the Huanggang–Ganzhuermiao polymetallic metallogenic belt of Inner Mongolia, NE China. The deposit's resource includes 0.026 Mt Ag, 1.1 Mt Pb, and 3.3 Mt Zn. The deposit is controlled by a NW-trending ductile shear zone and NE- and NW-trending faults in black pelite assigned to the lower Permian Dashizhai Formation. LREE enrichment, HREE depletion, Nb, Ta, P, and Ti depletion, and Zr and Hf enrichment characterize felsic magmatic rocks in the Shuangjianzishan Pb–Zn–Ag district. The ages of porphyritic monzogranite, rhyolitic crystal–vitric ignimbrite, and porphyritic granodiorite are 254–252, 169, and 130 Ma, respectively. Pyrite sampled from the mineralization has Re–Os isochron ages of 165 ± 7 Ma, which suggest the mineralization is associated with the ca. 169 Ma magmatism in the Shuangjianzishan district.Zircons extracted from the porphyritic granodiorite yield ε_Hf(t) values of − 11.34 to − 1.41, with t_DM2 dates of 1275–1901 Ma. The ε_Hf(t) values of zircons in the rhyolitic crystal–vitric ignimbrite and the ore-bearing monzogranite porphyry are 7.57–16.23 and 10.18–15.96, respectively, and their t_DM2 ages are 177–733 and 257–632 Ma, respectively. Partial melting of depleted mantle resulted in the formation of the ca. 254–252 Ma ore-bearing porphyritic monzogranite and the ca. 169 Ma rhyolitic crystal–vitric ignimbrite; dehydration partial melting of subducted oceanic crust resulted in the formation of the ca. 130 Ma porphyritic granodiorite. The porphyritic monzogranite was emplaced during the late stages of closure of the Paleo-Asian Ocean during the transformation from a collisional to extensional tectonic setting. The ca. 170 and ca. 130 Ma magmatism and mineralization in the Shuangjianzishan district are related to subduction of the Mongolia–Okhotsk Ocean and subduction of the Paleo-Pacific Ocean Plate, respectively.     

Gold mineralization in the Jiangnan Orogenic Belt of South China: Geological,geochemical and geochronological characteristics,ore deposit-type and geodynamic setting

Located in the southeastern margin of the Yangtze Block and generally interpreted as the Neoproterozoic collisional product of the Yangtze with the Cathaysia Blocks of South China, the Jiangnan Orogenic Belt (JOB) contains a number of gold (Au) (-polymetallic) ore deposits and mineral showings, mostly hosted by Neoproterozoic low-grade metamorphic volcaniclastic and sedimentary rocks. The mineralization styles mainly include auriferous quartz veins and disseminated mineralization in altered mylonite and cataclasite that are developed along shear zones, fracture zones and inter- or intra-formational fault zones closely related to regional folding and shearing deformation. Three gold mineralizing epochs are recognized in the JOB. The ca. 423–397 Ma mineralization was associated with the early Paleozoic tectonothermal event(s), which induced widespread emplacement of Silurian S-type granites, low-grade metamorphism and enrichment of gold in the Neoproterozoic rocks (i.e., forming Au source beds). The second Au mineralization epoch, occurring at ca. 176–170 Ma (Jurassic), was related to the subduction of the Paleo-Pacific plate beneath the South China continental margin. The third and most important Au mineralization epoch took place at ca. 144–130 Ma (early Cretaceous), when a Basin-and-Range tectonic pattern was developed, characterized by NE–NNE-trending strike-slip faults, granitic domes and metamorphic core complexes (MCC), and basins filled with red bed lithologies. C, H, O, He-Ar, S and Pb isotopic and fluid-inclusion data suggest that the ore fluids were predominantly metamorphic and/or magmatic, with variable input of mantle-derived fluids and the progressive involvement of meteoric waters in the later stages of mineralization. Ore materials were mostly contributed by the Neoproterozoic source beds, plus a possible contribution from mantle- or magma-derived components. The Au (-polymetallic) deposits in the JOB, particularly those formed in the early Cretaceous, share many geological and geochemical features with the orogenic-type and Carlin-type deposits. In the context of tectonic evolution of South China, the gold mineralization in the JOB may be considered an “intracontinental reactivation type”, characterized by synchronous development of Au–polymetallic mineralization, reactivation of stuctures developed in Neoproterozoic metamorphic rocks, and widespread granite emplacement in the late Mesozoic.     

Geodynamic setting of Mesozoic magmatism in NE China and surrounding regions: Perspectives from spatio-temporal distribution patterns of ore deposits

North-eastern China and surrounding regions host some of the best examples of Phanerozoic juvenile crust on the globe. However, the Mesozoic tectonic setting and geodynamic processes in this region remain debated. Here we attempt a systematic analysis of the spatio-temporal distribution patterns of ore deposits in NE China and surrounding regions to constrain the geodynamic milieu. From an evaluation of the available geochronological data, we identify five distinct stages of ore formation: 240–205 Ma, 190–165 Ma, 155–145 Ma, 140–120 Ma, and 115–100 Ma. The Triassic (240–205 Ma) magmatism and associated mineralisation occurred during in a post-collisional tectonic setting involving the closure of the Paleo-Asian Ocean. The Early-Mid Jurassic (190–165 Ma) events are related to the subduction of the Paleo-Pacific Ocean in the eastern Asian continental margin, whereas in the Erguna block, these are associated with the subduction of the Mongol–Okhotsk Ocean. From 155 to 120 Ma, large-scale continental extension occurred in NE China and surrounding regions. However, the Late Jurassic magmatism and mineralisation events in these areas evolved in a post-orogenic extensional environment of the Mongol–Okhotsk Ocean subduction system. The early stage of the Early Cretaceous events occurred under the combined effects of the closure of the Mongol–Okhotsk Ocean and the subduction of the Paleo-Pacific Ocean. The widespread extension ceased during the late phase of Early Cretaceous (115–100 Ma), following the rapid tectonic changes resulting from the Paleo-Pacific Oceanic plate reconfiguration.     

Spatial–temporal relationships of Mesozoic volcanic rocks in NE China: Constraints on tectonic overprinting and transformations between multiple tectonic regimes

LA-ICP-MS zircon U–Pb ages and geochemical data are presented for the Mesozoic volcanic rocks in northeast China, with the aim of determining the tectonic settings of the volcanism and constraining the timing of the overprinting and transformations between the Paleo-Asian Ocean, Mongol–Okhotsk, and circum-Pacific tectonic regimes. The new ages, together with other available age data from the literature, indicate that Mesozoic volcanism in NE China can be subdivided into six episodes: Late Triassic (228–201 Ma), Early–Middle Jurassic (190–173 Ma), Middle–Late Jurassic (166–155 Ma), early Early Cretaceous (145–138 Ma), late Early Cretaceous (133–106 Ma), and Late Cretaceous (97–88 Ma). The Late Triassic volcanic rocks occur in the Lesser Xing’an–Zhangguangcai Ranges, where the volcanic rocks are bimodal, and in the eastern Heilongjiang–Jilin provinces where the volcanics are A-type rhyolites, implying that they formed in an extensional environment after the final closure of the Paleo-Asian Ocean. The Early–Middle Jurassic (190–173 Ma) volcanic rocks, both in the Erguna Massif and the eastern Heilongjiang–Jilin provinces, belong chemically to the calc-alkaline series, implying an active continental margin setting. The volcanics in the Erguna Massif are related to the subduction of the Mongol–Okhotsk oceanic plate beneath the Massif, and those in the eastern Jilin–Heilongjiang provinces are related to the subduction of the Paleo-Pacific Plate beneath the Eurasian continent. The coeval bimodal volcanic rocks in the Lesser Xing’an–Zhangguangcai Ranges were probably formed under an extensional environment similar to a backarc setting of double-direction subduction. Volcanic rocks of Middle–Late Jurassic (155–166 Ma) and early Early Cretaceous (145–138 Ma) age only occur in the Great Xing’an Range and the northern Hebei and western Liaoning provinces (limited to the west of the Songliao Basin), and they belong chemically to high-K calc-alkaline series and A-type rhyolites, respectively. Combined with the regional unconformity and thrust structures in the northern Hebei and western Liaoning provinces, we conclude that these volcanics formed during a collapse or delamination of a thickened continental crust related to the evolution of the Mongol–Okhotsk suture belt. The late Early Cretaceous volcanic rocks, widely distributed in NE China, belong chemically to a low- to medium-K calc-alkaline series in the eastern Heilongjiang–Jilin provinces (i.e., the Eurasian continental margin), and to a bimodal volcanic rock association within both the Songliao Basin and the Great Xing’an Range. The volcanics in the eastern Heilongjiang–Jilin provinces formed in an active continental margin setting related to the subduction of the Paleo-Pacific Plate beneath the Eurasian continent, and the bimodal volcanics formed under an extensional environment related either to a backarc setting or to delamination of a thickened crust, or both. Late Cretaceous volcanics, limited to the eastern Heilongjiang–Jilin provinces and the eastern North China Craton (NCC), consist of calc-alkaline rocks in the eastern Heilongjiang–Jilin provinces and alkaline basalts in the eastern NCC, suggesting that the former originated during subduction of the Paleo-Pacific Plate beneath the Eurasian continent, whereas the latter formed in an extensional environment similar to a backarc setting. Taking all this into account, we conclude that (1) the transformation from the Paleo-Asian Ocean regime to the circum-Pacific tectonic regime happened during the Late Triassic to Early Jurassic; (2) the effect of the Mongol–Okhotsk suture belt on NE China was mainly in the Early Jurassic, Middle–Late Jurassic, and early Early Cretaceous; and (3) the late Early Cretaceous and Late Cretaceous volcanics can be attributed to the subduction of the Paleo-Pacific Plate beneath the Eurasian continent.     

Geology,geochronology and geochemistry of large Duobaoshan Cu-Mo-Au orefield in NE China: Magma genesis and regional tectonic implications

Duobaoshan is the largest porphyry-related Cu-Mo-Au orefield in northeastern(NE)Asia,and hosts a number of large-medium porphyry Cu(PCDs),epithermal Au and Fe-Cu skarn deposits.Formation ages of these deposits,from the oldest(Ordovician)to youngest(Jurassic),have spanned across over 300 Ma.No similar orefields of such size and geological complexity are found in NE Asia,which reflects its metallogenic uniqueness in forming and preserving porphyry-related deposits.In this study,we explore the actual number and timing of magmatic/mineralization phases,their respective magma genesis,fertility,and regional tectonic connection,together with the preservation of PCDs.We present new data on the magmatic/mineralization ages(LA-ICP-MS zircon U-Pb,pyrite and molybdenite Re-Os dating),whole-rock geochemistry,and zircon trace element compositions on four representative deposits in the Duobaoshan orefield,i.e.,Duobaoshan PCD,Tongshan PCD,Sankuanggou Fe-Cu skarn,and Zhengguang epithermal Au deposits,and compiled published ones from these and other mineral occurrences in the orefield.In terms of geochronology,we have newly summarized seven magmatic phases in the orefield:(1)Middle-Late Cambrian(506-491 Ma),(2)Early and Middle Ordovician(485-471 Ma and~462 Ma),(3)Late Ordovician(450-447 Ma),(4)Early Carboniferous and Late-Carboniferous to Early Permian(351-345 and 323-291 Ma),(5)Middle-Late Triassic(244-223 Ma),(6)Early-Middle and Late Jurassic(178-168 Ma and~150 Ma),and(7)Early Cretaceous(~112 Ma).Three of these seven major magmatic phases were coeval with ore formation,including(1)Early Ordovician(485-473 Ma)porphyry-type Cu-Mo-(Au),(2)Early-Middle Triassic(246-229 Ma)porphyry-related epithermal Au-(Cu-Mo),and(3)Early Jurassic(177-173 Ma)Fe-Cu skarn mineralization.Some deposits in the orefield,notably Tongshan and Zhengguang,were likely formed by more than one mineralization events.In terms of geochemistry,ore-causative granitoids in the orefield exhibit adakite-like or adakite-normal arc transitional signatures,but those forming the porphyry-/epithermal-type Cu-Mo-Au mineralization are largely confined to the former.The varying but high Sr/Y,Sm/Yb and La/Yb ratios suggest that the ore-forming magmas were mainly crustal sourced and formed at different depths(clinopyroxene-/amphibole-/garnet-stability fields).The adakite-like suites may have formed by partial melting of the thickened lower crust at 35-40 km(for the Early Ordovician arc)and>40 km(for the Middle-Late Triassic arc)depths.The Early Jurassic Fe-Cu skarn orecausative granitoids show an adakitic-normal arc transitional geochemical affinity.These granitoids were likely formed by partial melting of the juvenile lower crust(35-40 km depth),and subsequently modified by assimilation and fractional crystallization(AFC)processes.In light of the geological,geochronological and geochemical information,we proposed the following tectonometallogenic model for the Duobaoshan orefield.The Ordovician Duobaoshan may have been in a continental arc setting during the subduction of the Paleo-Asian Ocean,and formed the porphyry-related deposits at Duobaoshan,Tongshan and Zhengguang.Subduction may have ceased in the latest Ordovician,and the regional tectonics passed into long subsidence and extension till the latest Carboniferous.This extensional tectonic regime and the Silurian terrestrial-shallow marine sedimentation had likely buried and preserved the Ordovician Duobaoshan magmatic-hydrothermal system.The south-dipping Mongol-Okhotsk Ocean subduction from north of the orefield had generated the Middle-Late Triassic continental arc magmatism and the associated Tongshan PCD and Zhengguang epithermal Au mineralization(which superimposed on the Ordovician PCD system).The Middle Jurassic closure of Mongol-Okhotsk Ocean in the northwestern Amuria block(Erguna terrane),and the accompanying Siberia-Amuria collision,may have placed the Paleo-Pacific subduction system in NE China(including the orefield)under compression,and formed the granodiorite-tonalite and Fe-Cu skarn deposits at Sankuanggou and Xiaoduobaoshan.From the Middle Jurassic,the consecutive accretion of Paleo-Pacific arc terranes(e.g.,Sikhote-Alin and Nadanhada)onto the NE Asian continental margin may have gradually distant the Duobaoshan orefield from the subduction front,and consequently arc-type magmatism and the related mineralization faded.The minor Late Jurassic and Cretaceous unmineralized magmatism in the orefield may have triggered mainly by the far-field extension led by the post-collisional(Siberia-Amuria)gravitational collapse and/or Paleo-Pacific backarc-basin opening.     

浙东南晚中生代花岗岩的锆石U-Pb年代学、地球化学及其地质意义

浙东南地区（江绍断裂带东南）是位于华南东北部濒太平洋的沿海地区,是理解古太平洋板块俯冲作用的重要地区。本次研究选取岩坦、梁弄、新铺3个典型的岩体进行岩相学、锆石年代学和地球化学研究,并结合前人对该地区花岗岩体的研究结果,探讨古太平洋板块俯冲与岩浆活动之间的关系。LA-ICP-MS锆石U-Pb定年结果显示：新铺花岗岩的年龄为(145.8±1.4) Ma,表明浙东南地区晚侏罗世仍存在岩浆活动的记录;梁弄花岗岩和岩坦花岗岩的形成时代分别为（106.2±1.4）和（94.7±1.4） Ma,代表早白垩世晚期典型的岩浆活动。地球化学特征上,3个岩体均富SiO₂、Al₂O₃,具有高的A/CNK,属高钾钙碱性花岗岩;稀土元素球粒陨石标准化分布型式图中具显著的负Ｅu异常,稀土元素总量偏低;微量元素原始地幔标准化分布型式图中富集Rb、Cs、U、Th、Pb,亏损Ba、Sr、Nb、Ti,为典型的壳源型花岗岩。结合已有的资料,本次研究表明,新铺花岗岩形成在由侏罗纪挤压向白垩纪伸展转变的构造背景下,梁弄花岗岩和岩坦花岗岩形成在岩石圈减薄的伸展构造背景下,它们形成均受到了古太平洋板块俯冲作用的影响。     

A possible transition from island arc to continental arc magmatism in the eastern Jiangnan Orogen,South China: Insights from a Neoproterozoic (870–860 Ma) gabbroic–dioritic complex near the Fuchuan ophiolite

The Fuchuan ophiolite belt in the eastern Jiangnan Orogen of South China provides important constraints on the tectonic setting and evolution of the Neoproterozoic suture zone between the Yangtze and Cathaysia blocks. Combined UPbHf isotopic and REE analysis of zircon from gabbroic and dioritic samples of the Shexian complex, located 10 km southwest of the main Fuchuan ophiolite body, indicate that the complex crystallized at ca. 870–860 Ma with a large variation of zircon ε_Hf(t) values from − 4.80 to + 13.30. Whole-rock geochemistry reveals that the magma mainly experienced fractionation of olivine, clinopyroxene and plagioclase and was partly affected by crustal contamination, which resulted in elevated Th/Nb, Th/La and La/Sm ratios, as well as the scattered ε_Hf(t) values. The most mafic and least contaminated sample shows MORB affinity and was probably formed by partial melting of a depleted subduction-metasomatized mantle wedge. Other samples exhibit arc-like signatures and were probably modified by both melt- and fluid-related subduction metasomatism. The emplacement of the Shexian complex corresponds to the time that subduction switched from a ca. 1000–880 Ma intra-oceanic island arc to a 870–830 Ma continental arc along the southeastern Yangtze Block. The sequence of igneous rocks associated with this continental arc resemble those preserved in forearc Tethyan ophiolites, with magma evolving from ca. 870–860 Ma MORB to ca. 860–850 Ma arc tholeiite and ca. 830 Ma boninite. Arc magmatism concluded with the final assembly of the Yangtze and Cathaysia blocks at 830–800 Ma.     

Tectonic evolution of a composite collision orogen: An overview on the Qinling–Tongbai–Hong'an–Dabie–Sulu orogenic belt in central China

The formation of collisional orogens is a prominent feature in convergent plate margins. It is generally a complex process involving multistage tectonism of compression and extension due to continental subduction and collision. The Paleozoic convergence between the South China Block (SCB) and the North China Block (NCB) is associated with a series of tectonic processes such as oceanic subduction, terrane accretion and continental collision, resulting in the Qinling–Tongbai–Hong'an–Dabie–Sulu orogenic belt. While the arc–continent collision orogeny is significant during the Paleozoic in the Qinling–Tongbai–Hong'an orogens of central China, the continent–continent collision orogeny is prominent during the early Mesozoic in the Dabie–Sulu orogens of east-central China. This article presents an overview of regional geology, geochronology and geochemistry for the composite orogenic belt. The Qinling–Tongbai–Hong'an orogens exhibit the early Paleozoic HP–UHP metamorphism, the Carboniferous HP metamorphism and the Paleozoic arc-type magmatism, but the three tectonothermal events are absent in the Dabie–Sulu orogens. The Triassic UHP metamorphism is prominent in the Dabie–Sulu orogens, but it is absent in the Qinling–Tongbai orogens. The Hong'an orogen records both the HP and UHP metamorphism of Triassic age, and collided continental margins contain both the juvenile and ancient crustal rocks. So do in the Qinling and Tongbai orogens. In contrast, only ancient crustal rocks were involved in the UHP metamorphism in the Dabie–Sulu orogenic belt, without involvement of the juvenile arc crust. On the other hand, the deformed and low-grade metamorphosed accretionary wedge was developed on the passive continental margin during subduction in the late Permian to early Triassic along the northern margin of the Dabie–Sulu orogenic belt, and it was developed on the passive oceanic margin during subduction in the early Paleozoic along the northern margin of the Qinling orogen.Three episodes of arc–continent collision are suggested to occur during the Paleozoic continental convergence between the SCB and NCB. The first episode of arc–continent collision is caused by northward subduction of the North Qinling unit beneath the Erlangping unit, resulting in UHP metamorphism at ca. 480–490 Ma and the accretion of the North Qinling unit to the NCB. The second episode of arc–continent collision is caused by northward subduction of the Prototethyan oceanic crust beneath an Andes-type continental arc, leading to granulite-facies metamorphism at ca. 420–430 Ma and the accretion of the Shangdan arc terrane to the NCB and reworking of the North Qinling, Erlangping and Kuanping units. The third episode of arc–continent collision is caused by northward subduction of the Paleotethyan oceanic crust, resulting in the HP eclogite-facies metamorphism at ca. 310 Ma in the Hong'an orogen and low-P metamorphism in the Qinling–Tongbai orogens as well as crustal accretion to the NCB. The closure of backarc basins is also associated with the arc–continent collision processes, with the possible cause for granulite-facies metamorphism. The massive continental subduction of the SCB beneath the NCB took place in the Triassic with the final continent–continent collision and UHP metamorphism at ca. 225–240 Ma. Therefore, the Qinling–Tongbai–Hong'an–Dabie–Sulu orogenic belt records the development of plate tectonics from oceanic subduction and arc-type magmatism to arc–continent and continent–continent collision.     

Palaeozoic collision between the North and South China blocks,Triassic intracontinental tectonics,and the problem of the ultrahigh-pressure metamorphism

The Qinling–Dabie Belt represents the boundary between the North and South China blocks (NCB, SCB, respectively), where ultrahigh-pressure (UHP) rocks are widespread. A structural study in eastern Qinling and zircon LA ICPMS dating of the migmatites that form the core of the Central Qinling Unit allows us to argue that continental collision occurred in the Silurian, before 400 Ma. In the Late Palaeozoic, from the Devonian to the Permian, the northern margin of SCB experienced a continental rifting. From the Late Permian to Middle Triassic, northward continental subduction of SCB is responsible for the development of a high-pressure metamorphism. The age of the UHP metamorphism remains unsettled yet. A two-time genesis, Early Palaeozoic and Early Triassic, is often preferred, but a single Palaeozoic age followed by a Triassic resetting cannot be ruled out.     

Partitioning of the Cretaceous Pan-Yangtze Basin in the central South China Block by exhumation of the Xuefeng Mountains during a transition from extensional to compressional tectonics?

The formation of a series of intermountain basins is likely to indicate a geodynamic transition, especially in the case of such basins within the central South China Block (CSCB). Determining whether or not these numerous intermountain basins represent a division of the Cretaceous Pan-Yangtze Basin by exhumation of Xuefeng Mountains, is key to understanding the late Mesozoic to early Cenozoic tectonics of the South China Block (SCB). Here we present apatite fission track (AFT) data and time–temperature modeling in order to reconstruct the evolution history of the Pan-Yangtze Basin. Fourteen rock samples were taken from a NE–SW-trending mountain–basin system within the CSCB, including, from west to east, the Wuling Mountains (Wuling Shan), the south and north Mayang basins, the Xuefeng Mountains (Xuefeng Shan) and the Hengyang Basin. Cretaceous lacustrine sequences are well preserved in the south and north Mayang and Hengyang basins, and sporadically crop out in the Xuefeng Mountains, whereas Paleogene piedmont proluvial–lacustrine sequences are only found in the south Mayang and Hengyang basins. AFT results indicate that the Wuling and Xuefeng mountains underwent rapid denudation post-84 Ma, whereas the south and north Mayang basins were more slowly uplifted from 67 and 84 Ma, respectively. Following a quiescent period from 32 to 19 Ma, both the mountains and basins have been rapidly denuded since 19 Ma. Both the AFT data and sedimentary facies changes suggest that the Cretaceous deposits that cover the south–north Mayang and Hengyang basins through to the Xuefeng Mountains define the Cretaceous Pan-Yangtze Basin. Integrating our results with tectonic background for the SCB, we propose that rollback subduction of the paleo-Pacific Plate produced the Pan-Yangtze Basin, which was divided into the south–north Mayang and Hengyang basins by the abrupt uplift and exhumation of the Xuefeng Mountains from 84 Ma to present, apart from a period of tectonic inactivity from 32 to 19 Ma. This late Late Cretaceous to Paleogene denudation resulted from movement on the Ziluo strike–slip fault, which formed due to intra-continental compression most likely associated with the Eurasia–Indian plate subduction and collision. Sinistral transpression along the Ailao Shan–Red River Fault at 34–17 Ma probably transformed this compression to the extrusion of the Indochina Block, and produced the quiescent window period from 32 to 19 Ma for the mountain–basin system in the CSCB. Therefore, the initiation of exhumation of the Xuefeng Mountains at 84 Ma indicates a switch in tectonic regime from Cretaceous extension to late Late Cretaceous and Cenozoic compression.     

Genesis of the Maka Pb-Zn-W deposit in southeastern Yunnan" Constraints from sphalerite Rb-Sr dating,cassiterite U-Pb dating and in -situ S,Pb isotopes of sulfideSCIEI北大核心CSCD

马卡铅锌钨矿床地处云南省马关县与麻栗坡县的南温河交界处,位于燕山晚期老君山复式花岗岩体北缘。野外地质调查发现,该矿床主要发育矽卡岩型、石英脉型铅锌矿化和萤石石英脉型白钨矿化,但它们的形成机制仍缺乏系统研究。本文通过闪锌矿Rb-Sr、锡石原位U-Pb同位素定年和硫化物原位S、Pb同位素分析,厘定了马卡矿床不同类型铅锌矿化年龄,并探讨了其成矿物质来源及成因机制。矽卡岩型和石英脉型铅锌矿石中闪锌矿分别获得了88.9±1.9Ma(MSWD=4.5)和85.18±0.72Ma(MSWD=1.2)的Rb-Sr等时线年龄,同时获得石英脉型铅锌矿石中锡石LA-ICP-MS U-Pb年龄为84.3±4.7Ma(MSWD=0.66)。结果指示锌、锡矿化时代为晚白垩世,矽卡岩型和石英脉型铅锌矿化分别与该区广泛出露的老君山花岗岩(-90Ma)和花岗斑岩年龄(80-86Ma)一致。矿石硫化物原位硫同位素测试结果显示,δ34S值范围为2.53‰-9.65‰,均值为4.7‰,与老君山花岗岩中硫化物硫同位素组成(4.07‰)相似,表明硫主要来源于老君山花岗岩,少部分源自沉积地层;原位铅同位素组成特征也表明矿石铅主要源自老君山花岗岩。综合研究认为,老君山花岗岩体南北缘地区具有相似的成矿地质条件。马卡矿床的形成主要与燕山晚期老君山复式花岗岩体有关,可能经历了与花岗岩有关的矽卡岩型矿化和与花岗斑岩有关的热液充填、交代成矿过程。     

中亚造山带东部岩浆热液矿床时空分布特征及其构造背景

中亚造山带东部是古亚洲洋构造域、鄂霍茨克洋构造域和古太平洋构造域复合叠加区域,矿产资源丰富。本文收集2000—2014年公开发表文献中岩浆热液矿床约1 200个同位素年龄数据,整理出201个较为可靠的年龄数据,通过数字化编图,揭示成矿的时空分布特征及形成背景。结果显示:中亚造山带东部成矿作用始于寒武纪,出现6个重要成矿期:510~473、373~330、320~253、250~210、210~167、155~100 Ma。510~473 Ma(峰值507 Ma),矿床主要分布在大兴安岭—小兴安岭—张广才岭和北山地区,零星发育热液脉型和斑岩型铁铜金钨矿床,与古亚洲洋开始俯冲及微陆块碰撞拼合有关。373~330 Ma(峰值372Ma),矿床主要分布在南蒙古奥尤陶勒盖地区,发育超大型斑岩型铜金矿床,形成于古亚洲洋俯冲环境。320~253 Ma,矿床主要分布在大兴安岭南段,发育少量斑岩型铜矿床和造山型金矿床;其中,298 Ma在大兴安岭南段首次出现以钼为主的斑岩型矿床,指示该区板块俯冲增生向拼贴转变逐渐过渡。250~210 Ma(峰值244 Ma),在蒙古—鄂霍茨克造山带东侧额尔古纳—中蒙古地块主要形成斑岩型铜矿床,可能与蒙古—鄂霍茨克洋俯冲有关;以东地区,主要在大兴安岭南段和辽远地块形成斑岩型钼矿床,在张广才岭发育岩浆熔离型铜镍矿床,反映了古亚洲洋闭合后伸展环境。210~167 Ma(峰值170 Ma),在蒙古—鄂霍茨克造山带西侧乌兰巴托西北部发育造山型-斑岩型金矿床,其东侧额尔古纳地区形成斑岩型铜钼矿床,可能与蒙古—鄂霍茨克洋俯冲碰撞有关;在吉黑东部—张广才岭—小兴安岭—大兴安岭,发育斑岩型钼铜矿床和矽卡岩型铅锌钨金矿床组合,可能属于古太平洋板块向西俯冲成矿体系。155~100 Ma(峰值136 Ma),中亚造山带东部整体处于伸展环境;其中,155~120 Ma在额尔古纳地区主要发育浅成低温热液型银铅锌矿床和造山型金矿床,大兴安岭北段发育斑岩型钼矿床,可能反映了额尔古纳地区和大兴安岭北段受蒙古—鄂霍茨克洋碰撞后伸展环境控制,而在吉黑东部形成浅成低温热液型金矿床,大兴安岭南段发育热液脉型-矽卡岩型锡矿床,可能受古太平洋板块向北俯冲弧后伸展的控制;120~100 Ma沿着华北克拉通和佳蒙陆块边缘发育浅成低温热液型-斑岩型金钼矿床。本研究综合岩浆热液矿床时空分布和矿床类型,进一步揭示了古亚洲洋构造域控制中亚造山带东部古生代成矿作用持续到晚二叠世(到早三叠世),并在晚三叠世叠加古太平洋构造域成矿体系,而额尔古纳—中蒙古地块成矿作用在三叠纪开始主要受蒙古—鄂霍茨克洋构造域限定,并持续到早白垩世早期。     

Thermochronological record of Middle–Late Jurassic magmatic reheating to Eocene rift-related rapid cooling in the SE South China Block

We investigate the Mesozoic–Cenozoic thermal history of the Daxi region (central SE South China Block) to evaluate the influence of the subduction of the Paleo-Pacific oceanic plate beneath the SE South China Block along the block's southeast margin on the tectonothermal evolution of the upper plate. We apply a multi-chronological approach that includes U-Pb geochronology on zircon, ⁴⁰Ar/³⁹Ar dating on muscovite and biotite from granitic rocks as well as fission-track and (U-Th-Sm)/He analyses on zircon and apatite from granitic and sedimentary rocks. The Heping granite, located in the Daxi region, has a magmatic age of ca. 441 Ma. The biotite ⁴⁰Ar/³⁹Ar ages of ca. 193 Ma for the Early Jurassic Shibei granite and ca. 160 Ma for the Late Jurassic Fogang granite, respectively, reflect magmatic cooling. The Triassic Longyuanba granite yielded a muscovite ⁴⁰Ar/³⁹Ar age of ca. 167 Ma, recording heating to ≥ 350 °C induced by nearby intrusion of Middle Jurassic granites. Zircon fission-track and (U-Th-Sm)/He ages from Lower Carboniferous–Lower Jurassic sandstones (140–70 Ma) record continuous cooling during the Cretaceous that followed extensive Middle–Late Jurassic magmatism in the Daxi region. Cretaceous cooling is related to exhumation in an extensional tectonic setting, consistent with lithospheric rebound due to foundering and rollback of the subducted Paleo-Pacific oceanic plate. Apatite fission-track (53–42 Ma) and (U-Th-Sm)/He ages (43–36 Ma), and thermal modelling document rapid cooling in the Paleocene–Eocene, which temporally coincides with continental rifting in the SE South China Block in the leadup to the opening of the South China Sea.     

Phanerozoic continental growth and gold metallogeny of Asia

The Asian continent formed during the past 800 m.y. during late Neoproterozoic through Jurassic closure of the Tethyan ocean basins, followed by late Mesozoic circum-Pacific and Cenozoic Himalayan orogenies. The oldest gold deposits in Asia reflect accretionary events along the margins of the Siberia, Kazakhstan, North China, Tarim–Karakum, South China, and Indochina Precambrian blocks while they were isolated within the Paleotethys and surrounding Panthalassa Oceans. Orogenic gold deposits are associated with large-scale, terrane-bounding fault systems and broad areas of deformation that existed along many of the active margins of the Precambrian blocks. Deposits typically formed during regional transpressional to transtensional events immediately after to as much as 100 m.y. subsequent to the onset of accretion or collision. Major orogenic gold provinces associated with this growth of the Asian continental mass include: (1) the ca. 750 Ma Yenisei Ridge, ca. 500 Ma East Sayan, and ca. 450–350 Ma Patom provinces along the southern margins of the Siberia craton; (2) the 450 Ma Charsk belt of north-central Kazakhstan; (3) the 310–280 Ma Kalba belt of NE Kazakhstan, extending into adjacent NW Xinjiang, along the Siberia–Kazakhstan suture; (4) the ca. 300–280 Ma deposits within the Central Asian southern and middle Tien Shan (e.g., Kumtor, Zarmitan, Muruntau), marking the closure of the Turkestan Ocean between Kazakhstan and the Tarim–Karakum block; (5) the ca. 190–125 Ma Transbaikal deposits along the site of Permian to Late Jurassic diachronous closure of the Mongol–Okhotsk Ocean between Siberia and Mongolia/North China; (6) the probable Late Silurian–Early Devonian Jiagnan belt formed along the margin of Gondwana at the site of collision between the Yangtze and Cathaysia blocks; (7) Triassic deposits of the Paleozoic Qilian Shan and West Qinling orogens along the SW margin of the North China block developed during collision of South China; and (8) Jurassic(?) ores on the margins of the Subumusu block in Myanmar and Malaysia. Circum-Pacific tectonism led to major orogenic gold province formation along the length of the eastern side of Asia between ca. 135 and 120 Ma, although such deposits are slightly older in South Korea and slightly younger in the Amur region of the Russian Southeast. Deformation related to collision of the Kolyma–Omolon microcontinent with the Pacific margin of the Siberia craton led to formation of 136–125 Ma ores of the Yana–Kolyma belt (Natalka, Sarylakh) and 125–119 Ma ores of the South Verkhoyansk synclinorium (Nezhdaninskoe). Giant ca. 125 Ma gold provinces developed in the Late Archean uplifted basement of the decratonized North China block, within its NE edge and into adjacent North Korea, in the Jiaodong Peninsula, and in the Qinling Mountains. The oldest gold-bearing magmatic–hydrothermal deposits of Asia include the ca. 485 Ma Duobaoshan porphyry within a part of the Tuva–Mongol arc, ca. 355 Ma low-sulfidation epithermal deposits (Kubaka) of the Omolon terrane accreted to eastern Russia, and porphyries (Bozshakol, Taldy Bulak) within Ordovican to Early Devonian oceanic arcs formed off the Kazakhstan microcontinent. The Late Devonian to Carboniferous was marked by widespread gold-rich porphyry development along the margins of the closing Ob–Zaisan, Junggar–Balkhash, and Turkestan basins (Amalyk, Oyu Tolgoi); most were formed in continental arcs, although the giant Oyu Tolgoi porphyry was part of a near-shore oceanic arc. Permian subduction-related deformation along the east side of the Indochina block led to ca. 300 Ma gold-bearing skarn and disseminated gold ore formation in the Truong Son fold belt of Laos, and along the west side to ca. 250 Ma gold-bearing skarns and epithermal deposits in the Loei fold belt of Laos and Thailand. In the Mesozoic Transbaikal region, extension along the basin margins subsequent to Mongol–Okhotsk closure was associated with ca. 150–125 Ma formation of important auriferous epithermal (Balei), skarn (Bystray), and porphyry (Kultuminskoe) deposits. In northeastern Russia, Early Cretaceous Pacific margin subduction and Late Cretaceous extension were associated with epithermal gold-deposit formation in the Uda–Murgal (Julietta) and Okhotsk–Chukotka (Dukat, Kupol) volcanic belts, respectively. In southeastern Russia, latest Cretaceous to Oligocene extension correlates with other low-sulfidation epithermal ores that formed in the East Sikhote–Alin volcanic belt. Other extensional events, likely related to changing plate dynamics along the Pacific margin of Asia, relate to epithermal–skarn–porphyry districts that formed at ca. 125–85 Ma in northeastmost China and ca. 105–90 Ma in the Coast Volcanic belt of SE China. The onset of strike slip along a part of the southeastern Pacific margin appears to correlate with the giant 148–135 Ma gold-rich porphyry–skarn province of the lower and middle Yangtze River. It is still controversial as to whether true Carlin-like gold deposits exist in Asia. Those deposits that most closely resemble the Nevada (USA) ores are those in the Permo-Triassic Youjiang basin of SW China and NE Vietnam, and are probably Late Triassic in age, although this is not certain. Other Carlin-like deposits have been suggested to exist in the Sepon basin of Laos and in the Mongol–Okhotsk region (Kuranakh) of Transbaikal.     

Provenance and paleogeography of the Early Paleozoic basin in the northern Yangtze Block: Constraints from detrital zircon U-Pb-Hf data

The Proto-Tethys was a significant post-Rodinia breakup ocean that eventually vanished during the Paleozoic. The closure timing and amalgamation history of numerous microblocks within this ocean remain uncertain, while the Early Paleozoic strata on the northern margin of the Yangtze Block archive valuable information about the evolution of the Shangdan Ocean, the branch of the Proto-Tethys. By comparing the detrital zircon U-Pb-Hf isotopic data from Cambrian, Ordovician, and Silurian sedimentary rocks in the northern Yangtze Block with adjacent blocks, it was found that detrital zircons in Cambrian strata exhibit a prominent age peak at ∼ 900–700 Ma, which indicates that the primary source of clastic material in the basin was the uplifted inner and margin regions of the Yangtze Block. In the Silurian, abundant detrital material from the North Qinling Block was transported to the basin due to the continuous subduction and eventual closure of the Shangdan Ocean. This process led to two distinct age peaks at ∼500–400 Ma and ∼900–700 Ma, indicating a bidirectional provenance contribution from both the North Qinling Block and the Yangtze Block. This shift demonstrates that the initial collision between these two blocks occurred no later than the Silurian. The northern Yangtze Basin transitioned from a passive continental margin basin in the Cambrian to a peripheral foreland basin in the Silurian. Major blocks in East Asia, including South Tarim, North Qilian, North Qinling, and North Yangtze, underwent peripheral subduction and magmatic activity to varying degrees during the late Early Paleozoic, signifying the convergence and rapid contraction of microplates within northern Gondwana and the Proto-Tethys Ocean. These findings provide new insights on the tectonic evolution of the Proto-Tethys Ocean.     

河北张三营富铌碱长花岗岩和花岗斑岩锆石U-Pb年代学及其地质意义

张三营富铌碱长花岗岩位于华北克拉通北缘中段,文章对该花岗岩和与其伴生的花岗斑岩进行锆石LA-ICP-MS U-Pb定年研究,结果表明富铌碱长花岗岩可能是岩浆多期次聚集作用下形成,结晶年龄约为141 Ma,其晚期分异形成的花岗斑岩均形成于132～124 Ma;张三营富铌碱长花岗岩是早白垩世古太平洋板块俯冲折返作用相关的伸展体制下形成的.研究揭示,除海西期和印支期外,燕山晚期也是华北克拉通北缘铌钽成矿的重要时期,燕山晚期的碱性岩和过铝质花岗岩将成为本区稀有金属找矿的新方向.     

Early Mesozoic tectono-magmatic activity and mineralization in Northeast China: evidence from Re–Os to U–Pb studies of the Taipingchuan porphyry Cu–Mo deposit in the Derbugan metallogenic belt

The Taipingchuan Cu–Mo deposit is a recently discovered large porphyry deposit located in the north of the Derbugan metallogenic belt of northeastern China. The geochronological data of the deposit yielded a Late Triassic zircon U–Pb age of 202 ± 6 Ma from a granodiorite porphyry that hosts the Cu–Mo mineralization. Measured Re–Os isotopes of seven disseminated molybdenite samples yielded an isochron age of 200 ± 5 Ma with mean square of weighted deviates of 2.7, while those of seven veinlet molybdenite samples also produced an isochron age of 200.1 ± 2.5 Ma and mean square of weighted deviates of 3.3. These isochron ages show that a Cu–Mo mineralization event occurred at ca. 200 Ma. Based on regional tectonic evolution, we propose that the Late Triassic Cu–Mo mineralization of the host porphyry in the Derbugan metallogenic belt was mainly associated with the subduction of the Mongol–Okhotsk Ocean slab under the Ergun block, contrary to previous suggestion that it was related to the subduction of the Mesozoic Palaeo-Pacific plate.     

SHRIMP U-Pb zircon geochronology and Nd-Sr isotopic study of the Mamianshan Group: implications for the Neoproterozoic tectonic development of southeast China

Northwestern Fujian contains abundant well-studied Precambrian basement, and was a composite terrane in Cathaysia during the Neoproterozoic; however, its magmatic activity, petrogenesis, and tectonic evolution remain controversial. This article focuses on the geochronology and geochemistry of the Neoproterozoic Group in order to resolve the above problems. We provide new SHRIMP U-Pb zircon dating for the Mamianshan Group: 851.9 ± 9.2 to 825.5 ± 9.8 Ma for the Longbeixi Formation, 796.5 ± 9.3 Ma for the Dongyan Formation, and 756.2 ± 7.2 Ma for the Daling Formation. These ages document the existence of Neoproterozoic magmatism in the northwestern Cathaysia Block. Dongyan Nd-Sr isotopic data show that mafic amphibolite schists, mafic greenschists, and quartzofeldspathic schists were derived from a more depleted mantle (initial ε_Nd ? +5.5 and ⁸⁷Sr/⁸⁶Sr ratio 0.703409643), a mixture of depleted mantle and crustal components (initial ε_Nd ? ?1 and ⁸⁷Sr/⁸⁶Sr ratio 0.702045282–0.704147714), and late Palaeoproterozoic continental crustal materials (initial ε_Nd < ?1 and ⁸⁷Sr/⁸⁶Sr ratio 0.71083603), respectively. These new data, together with previous studies, suggest a bi-subduction-collision orogenic model for the Neoproterozoic evolution of the Yangtze and Cathaysia blocks. Our plate tectonic scenario involves earlier NW-dipping subduction during 1.0 Ga–860 Ma along the southeastern margin of the Yangtze Block and later NW-dipping subduction near the northwestern margin of the Cathaysia Block starting at ca. 850 Ma. The 796.5 ± 9.3 Ma age of the volcanic Dongyan Formation suggests that the final assembly of the Yangtze and Cathaysia blocks probably occurred after ca. 800 Ma. The 756.2 ± 7.2 Ma age of the Daling Formation indicates that post-orogenic extensional magmatism took place after 800 Ma along the northwestern margin of Cathaysia.     

Early to Middle Jurassic (ca. 182–164 Ma) fractionated granitoids in the Korean Peninsula: Implication for the tectonomagmatic history of East Asia

The Jurassic granitoids (200–164 Ma) are distributed in the Korean Peninsula due to the Paleo-Pacific plate subduction. Early Jurassic (200–182 Ma) granitoids are mainly distributed in the southern Korean Peninsula. By contrast, Early to Middle Jurassic (182–164 Ma) granitoids are distributed in the central Korean Peninsula. In this study, we report detailed petrology, zircon U–Pb ages, and whole-rock geochemistry from the Seoul–Uijeongbu and Pocheon–Gimhwa pluton units in the central Korean Peninsula. The Seoul–Uijeongbu unit is dominated by biotite granite, with minor porphyritic biotite and garnet-biotite granite while the Pocheon–Gimhwa unit consists of biotite granite and porphyritic biotite granite, garnet-biotite granite, and two-mica granite. Zircon U–Pb age from those granites gives 180–167 Ma. The granitoids in the Pocheon-Gimhwa unit formed through fractional crystallization from biotite granite and porphyritic biotite granite to garnet-biotite granite, and two-mica granite based on gradually decreasing their Nb/Ta, Zr/Hf, and Eu/Eu* ratios. The strongly fractionated granitoids are garnet-biotite granite and two-mica granite. The LILE enrichment, Ta–Nb, Sr–P, and Eu–Ti troughs, and Ba depletion in most granitoids are similar to those of granitoids due to the subduction in the arc environment. Thus, these Jurassic granitoids (180–167 Ma) are mainly peraluminous granites with moderate crystal fractionation corresponding to I-type granite. Alkali feldspar granite associated with ore mineralization occurs in the Gwanaksan pluton from the southwestern Seoul–Uijeongbu unit. The alkali feldspar granite displays distinct negative Eu anomaly with high contents of Rb, Hf, Cs, and Nb compared with other granites. These characteristics imply that alkali feldspar granite experienced strong hydrothermal activity leading to feldspar ore mineralization compared to the other granites. The formation of a wide range of moderately evolved peraluminous granitoids is presumed to be related to rapid flat-subduction during 182–164 Ma, and the mineralization-related alkali feldspar granite indicates the termination of Jurassic granitoid magmatism in the central Korean Peninsula.