Speciation of heavy metals in airborne particles, road dusts, and soils along expressways in China

This study analyzed the concentrations and chemical forms of Zn,Cu,Pb,Sb,Cd and Mn in airborne particles,road dusts and soils collected along three expressways in Jiangxi Province,China,with different traffic densities,and identified the levels and sources of heavy metal contamination.The concentrations of Zn,Cu,Pb,Sb,and Cd except Mn in airborne particles,road dusts and soils were all in direct proportion to traffic volume.Cd concentrations were low compared with other metals.For instance,the concentrations of Zn,Cu,Pb,Sb,Mn and Cd were 6.6,0.7,2.2,0.1,0.1 and 0.1μg·m-3in PM10along the Changjiu Expressway,792.8,241.4,248.3,9.6,340.5and 8.0 mg·kg-1in road dusts,and 201.1,143.2,59.5,9.5,338.9 and 2.3 mg·kg-1in soils,respectively,but in the case of the ratio of concentration to the environmental background value,most serious contamination was caused by Cd.The sources of the heavy metals were judged by comparisons of the chemical forms of the heavy metals in different environmental media.Pb and Mn in airborne particles were both derived from traffic;Pb in road dusts and soils resulted mainly from the use of leaded gasoline in the past;and Mn in road dusts and soils was derived from parent rocks.Zn,Cu,Sb and Cd in airborne particles,road dusts and soils were derived primarily from traffic,and differences in chemical forms of the heavy metals in different media were due to the interaction between heavy metals in airborne particles and organic matter and other surfaces in road dusts and soils.We also discussed the change of chemical forms of heavy metals in particles of different sizes and under different weather conditions.Bioavailability of heavy metals in airborne particles was much higher than that in road dusts and soils,especially Pb(0.676 in airborne particles,0.159 in road dusts and 0.095 in soils).     

中国北方不同成煤时代煤中金属矿点(床)分布及资源前景

在特定环境下，煤中能够富集锗、镓、锂、稀土等金属元素。我国北方煤炭资源丰富，已发现大量的煤-金属矿点（床），并且这些矿点（床）的分布展现出一定的时空特征:石炭-二叠纪煤中金属主要以镓、锂富集矿点为主，主要分布在华北赋煤区北部煤田及山西平朔、晋城等矿区；早-中侏罗世煤，以镓富集为主，主要集中在新疆准东、吐哈盆地，青海木里等煤田，二连盆地早侏罗世煤发现煤-稀土异常，是很好的找矿线索；早白垩世煤主要以二连盆地、海拉尔盆地煤中锗矿点为主。我国北方聚煤期时间跨度大，聚煤环境多样，含煤盆地类型多样，聚煤期和成煤后北方频繁剧烈的大地构造演化过程、多样的煤岩类型，能为煤中不同微量元素的富集提供物质来源、迁移条件与通道和沉积聚集条件，具有良好的煤中金属资源前景。建议进一步加强煤中，尤其是煤矸石、粉煤灰中金属矿点（床）资源的调查研究工作，为煤中金属资源赋存与预测提供参考，并加强金属的提取利用技术研究，同时通过制定资源保护政策，加强对煤中金属资源的保护。      

贵州省开阳县钼镍钒矿的基本特征

本文从已有资料入手,以典型矿点为例子,结合系统的采样工作,分析了开阳县境内牛蹄塘组含矿岩系及矿床基本特征,认为开阳县境内的牛蹄塘组有两个岩石组合类型,即硅质磷块岩、炭质页岩、黄铁矿、白云岩组合和硅质磷块岩、炭质页岩组合;牛蹄塘组黑色岩系内的钼镍钒富集有一定的规律性,硅质磷块岩、炭质页岩组合中的钼镍钒含量普遍较高,钼镍矿层厚度较稳定,品位较高;并认为今后在开阳找寻钼镍钒矿的主要靶区是翁昭背斜及龙水的牛蹄塘组。     

鄂尔多斯盆地下白垩统含水层储水岩石特征与介质结构研究

本文采用沉积学与水文地质学交叉研究的思路,对鄂尔多斯盆地下白垩统含水层储水岩石特征与含水介质结构进行了研究。下白垩统是由宜君-洛河、华池-环河、罗汉洞-泾川三套含水岩组组成的一个厚达1300m、具多层结构的巨型碎屑岩地下水系统,发育以长石砂岩、长石石英砂岩为主的多类型储水砂岩,其沉积形成于以河流、沙漠为主的多种陆相沉积环境。由于受沉积、成岩及后期剥蚀等作用的控制,各含水岩组储水岩石的类型、厚度及分布,以及储水空间的类型和发育程度、储水孔隙介质结构均有明显变化;在与其它水文地质条件的共同影响下,下白垩统地下水赋存和富集条件总体呈现"盆地北好南差、北部上好下差、南部下好上差"的宏观分布规律。     

安徽宁国地区岩-土系统元素迁移及其农业地质环境效应

通过多条基岩-土壤剖面和区域性土壤地球化学样品的微量元素丰度测试,分析了宁国地区不同基岩类型地球化学元素在岩石和土壤中分布的基本特点,表明同一地层的岩-土系统在不同地点有基本相同的元素迁移规律,导致土壤中的微量元素分布特征受控于其下地质单位的空间分布,植物生长必需的微量营养元素Fe、Mn、Cu、Mo、Zn、B6种元素表现出在南华纪-寒武纪地层中向土壤强烈富集的趋势．岩-土系统元素迁移特点对宁国市天目山区重要名优特产品-山核桃的生长环境产生重要影响,该区主导性名特优产品-山核桃,应该选择南沱组、兰田组、杨柳岗组、华严寺组、西阳山组等地层出露的地段种植才能产生好的经济效益．     

近40a来江河源区生态环境变化的气候特征分析

利用月气象资料,对过去40a江河源气候变化特征进行分析,并与全球、全国、青藏高原进行了比较.结果表明:江河源区气温具有增暖趋势,近40a两地年平均气温分别增加约0.8℃和0.7℃,为高原异常变暖区.黄河源区变暖的主要特征是最低气温变暖,日照时数增加;最低、最高气温的显著变暖,以及较黄河源区增加更长的日照时数是长江源区变暖的主要特征.长江源区冬季变暖的作用不是主要的,春季、夏季和秋季的变暖作用比冬季还要大;黄河源区的变暖也并不主要是冬季变暖造成的,秋季变暖的作用与其相当,其它季节的变暖作用也不能忽视.近40a来江河源区降水量略有增加,主要体现在20世纪80年代中后期以来春季与冬季降水量的明显增加,夏季降水量虽然总体上没有明显变化,且局地夏季降水量呈持续减少趋势.与全球、全国以及高原区对比显示,江河源区对全球气候变暖的响应最敏感,变暖首先从长江源和整个高原发端,之后15a.黄河源和全国才进入显著温暖期.黄河源与长江源北部降水量的增加表明,气候变暖有利于高原增加降水量.     

中国铁路风沙防治的研究进展

基于中国沙区铁路的发展历程,系统分析了铁路沙害类型、特点以及风沙防治方案、措施和技术体系。针对我国沙区地域特征和铁路沙害类型,作为个例分类剖析了途径流沙地表、高寒环境与戈壁大风区铁路风沙危害与防治技术取得的成效和面临的问题。结合目前我国沙区铁路的发展趋势,从理论研究和工程防沙实践出发,提出复杂地形、特殊环境铁路沙害是今后风沙工程学领域的重点和理论研究趋势,也是沙区铁路沙害防治的关键和难点。     

Synoptic patterns leading to hailstorm in Chaharmahal and Bakhtiari province,Iran

The purpose of this study was to extract the synoptic patterns of 500 mb geopotential height and the sea level pressure leading to form hail in Chaharmahal and Bakhtiari province, Iran. To this end, at first, we explored hail occurrence in different areas of the province under investigation. Then, using sea level pressure and 500 mb geopotential height data, the patterns of hail occurrence were investigated through hierarchical clustering and Ward’s method. The level of 500 mb patterns resulting in hail formation in the area include: (1) settlement of a cut-off low pressure blocking in Turkey and Iran’s position in downstream of trough and injection of humidity coming from the Red Sea; (2) settlement of low ridge in northern Europe and Iran lying in downstream of the trough and injection of humidity of the Mediterranean Sea; (3) settlement of a cut-off low pressure in east of Europe and Iran lying in downstream of the trough; and (4) settlement of a deep trough in the Mediterranean Sea, formation of an omega-shaped blocking in Northern Europe and Iran lying in downstream of the trough. At sea level, the following patterns have caused hail formation in Chaharmahal and Bakhtiari province: (1) settlement of low pressure in Iran and Russia accompanying high pressure in Taklimakan Desert and east of Europe; (2) settlement of low pressure in Iran and high pressure in Egypt, northern Europe, and Taklimakan Desert; and (3) settlement of low pressure in Iran, Saudi Arabia and south of Italy and high pressure in Egypt and Siberia.     

内蒙古东部两大沙地土壤理化特性沙漠化演变规律的比较

为了了解不同地带沙地土壤理化特性沙漠化演变规律的差异及其机制,研究比较了科尔沁沙地和呼伦贝尔沙地土壤理化特性的沙漠化演变特征,得到以下结论:沙漠化过程中,2个沙地的土壤黏粉粒含量均大幅度下降,沙粒含量明显增加,但科尔沁沙地土壤机械组成的变化幅度要大于呼伦贝尔沙地,而且前者黏粉粒主要释放期早于后者;科尔沁沙地土壤温度趋于...     

青藏高原新生代构造岩相古地理演化及其对构造隆升的响应

在系统分析青藏高原新生代98个残留盆地类型、形成构造背景、岩石地层序列的基础上, 对青藏高原古新世—始新世、渐新世、中新世及上新世构造岩相古地理演化特征进行了讨论: (1)古新世—始新世: 松潘—甘孜和冈底斯带为大面积构造隆起蚀源区.塔里木东部、柴达木、羌塘、可可西里地区主体表现为大面积的构造压陷湖盆-冲泛平原沉积.高原西部和南部为新特提斯海.(2)渐新世: 冈底斯—喜马拉雅和喀喇昆仑大范围沉积缺失, 指示上述地区大面积隆升.沿雅江自东向西古河形成(大竹卡砾岩).西昆仑和松潘—甘孜地区仍为隆起蚀源区.塔里木、柴达木、羌塘、可可西里地区主体表现为大面积构造压陷湖盆沉积.塔里木西南部为压陷盆地滨浅海沉积.渐新世末塔里木海相沉积结束.(3)中新世: 约23 Ma时高原及周边不整合面广布, 标志高原整体隆升.塔里木、柴达木及西宁—兰州、羌塘、可可西里等地区主体表现为大面积的构造压陷湖盆沉积; 约18~13 Ma高原及周边出现中新世最大湖泊扩张期.约13~10 Ma期间, 藏南南北向断陷盆地形成, 是高原隆升到足够高度开始垮塌的标志.(4)上新世: 除可可西里—羌塘、塔里木、柴达木等少数大型湖盆外, 大部分地区为隆起剥蚀区.由于上新世的持续隆升和强烈的断裂活动, 使大型盆地的基底抬升被分割为小盆地, 湖相沉积显著萎缩, 进入巨砾岩堆积期, 是高原整体隆升的响应.高原从古近纪的东高西低格局, 经历了新近纪全区的不均衡隆升和坳陷, 最终铸就了西高东低的地貌格局, 青藏作为一个统一的高原发生了重大的地貌反转事件.      

Sources and contamination characteristics of PAHs in environmental media in a karst underground river system (southern China)

The aim of this study was to determine the sources and contamination characteristics of polycyclic aromatic hydrocarbons (PAHs) in various environmental media in a karst underground river system. For this purpose, air, underground river water, sediment, and soil samples were collected from a typical underground river in southern China in the dry and wet seasons of 2013–2014, and the compositional spectra, distribution, and ratio characteristics of 16 PAHs were determined for comparative analysis. The results show that three 2–3-ring PAHs (naphthalene, phenanthrene, and fluoranthene) mainly occur in air and underground river water. In sediments and soils, 4–6-ring PAHs are the main components. The PAH concentrations in the air in the wet season are clearly greater than those in the dry season, while it is the opposite in the underground water. Seasonal differences in the concentration of PAHs in the sediments and soils are minor. The concentrations of PAHs in the environmental media overall showed variation in the following order: upstream < midstream < downstream, and this is related to pollutant discharge, adsorption, etc. The main source of PAHs in the upstream area is the combustion of grass, wood, and coal, while it is petroleum in the midstream area, and combustion of grass, wood, coal, and petroleum near the outlet of the underground river. It is necessary to change the energy structure in the study area, improve the efficiency of environmental protection facilities, reduce the emission in vehicle exhaust, and control pollution by PAHs at their sources.     

沉积盆地流体活动及其成岩响应

盆地流体活动通过改变成岩场的温压和孔隙水介质条件,进而影响到盆地内成岩作用序列、水—岩相互作用以及储层孔隙变化。对于碎屑岩而言,流体活动仅能导致母岩中少部分矿物的溶蚀以及孔隙内溶解与沉淀作用发生,富含二氧化碳和有机酸的流体活动为次生孔隙发育提供条件,超压环境下流体幕式释放既可导致超压体内次生孔隙的发育,又可以导致热流体活动影响区域内浅部储层的成岩异常;对于碳酸盐岩而言,由于碳酸盐岩具有很强的溶解性,盆地流体活动导致碳酸盐岩储层组构及空间发生巨大的变化,其中天水的下渗以及与深部热液或热流体沿断裂或裂缝释放均可导致碳酸盐岩成分、组构、储集空间发生根本性变化,故与盆地流体活动密切相关的风化壳型岩溶储层和构造热液白云岩储层构成碳酸盐岩中最为重要的储层类型。然而,盆地流体活动及其成岩响应研究仍存在许多亟待解决的难点问题,急待深入的研究探索。     

Abundance and distribution of ichthyoplankton in Narragansett Bay, Rhode Island, 1989–1990

An ichthyoplankton survey (18 stations in seven sampling sectors) was conducted in Narragansett Bay in 1990 to provide information on abundance, distribution, and seasonal occurrence of eggs and larvae of estuarine fishes, including seasonal migrants. An additional goal was to examine changes in species composition, abundance, and distribution occurring since the last baywide survey in 1972–73. The taxonomic composition of eggs and larvae in 1990 (41 species in 25 families from 684 plankton samples) and in 1972–73 (43 species in 28 families from 6900 samples) was similar. Maximum abundance of fish eggs occurred in June and larvae in July, minimum abundance in September to February. Species diversity was greatest in May–July and lowest during January in both surveys. However, egg and larval densities in 1990 were considerably lower than in 1972–73. Bay anchovy, tautog, and cunner accounted for 86% of the eggs and 87% of the larvae in the bay in 1990. These three species accounted for only 55% of the eggs and 51% of the larvae in 1972–73, with menhaden accounting for another 18% of the eggs and 34% of the larvae. Searobins, scup, and butterfish eggs were common in 1973 (19%) but rare in 1990 (2%). Ichthyoplankton abundance for several of the most abundant species was significantly lower (p<0.05) in the Providence River, upper bay, and Greenwich Bay in 1990 than in 1972–73. Density of fish eggs and larvae in the lower portions of the bay was lower in 1990 for some species but not others. Distribution data suggested a general down-bay shift in density in 1990. *** DIRECT SUPPORT *** A01BY085 00015     

CMIP5多模式对中国及各分区气温和降水时空特征的预估

利用7个参加耦合模式比较计划第五阶段(CMIP5)的全球气候模式模拟数据,在RCP4.5、RCP8.5两种排放情景下,从年、季、月尺度上对中国以及中国的7个区域的气温和降水进行未来情景预估分析。分析结果表明:2010~2099年,两种情景下中国的气温增加明显,并呈现出春弱秋冬(尤其是一、八、九、十一、十二月)强的特征,北部(N)、西北东部(ENW)、西北西部(WNW)、西藏(Tibet)的升温趋势高于其他地区。RCP8.5情景下的气温线性趋势值大部分都高于RCP4.5情景下的值。在RCP4.5情景下,2060~2099年东北部(NE)呈现降温。两种情景下,全国降水量也呈增加趋势,呈现由东南向西北递减的地理分布,并表现出冬弱春夏强的季节变化特征。西北西部(WNW)在全年降水偏少,春夏季黄河以北降水趋势较小,降水大值中心在长江以南地区,尤其是在五、六、七、八月份。秋季,在RCP4.5、RCP8.5情景下SE降水线性趋势分别低于或等于全国平均水平,东北部(NE)、北部(N)、西北东部(ENW)的降水线性趋势略高。在2010~2039年,在RCP8.5情景下西南(SW)的降水减少。     

Progress of Research on Wind-blown Sand Prevention and Control of Railways in China

Based on the development of railways in desert areas of China, the types, characteristics, schemes, measures and technical systems of wind-sand disaster prevention and control were systematically analyzed in this paper. In view of the regional characteristics of sandy areas and the genres of railway sand damage in China, the results achieved and problems faced of wind-sand hazard and prevention technology in quicksand surface, plateau cold region and Gobi gale area were discussed as a case study. Combined with the expanding trend of railways in desert zone in China at present, starting from the theoretical research and the practice of sand control in engineering, it was proposed that the railway sand harm of complicated terrain and special environment is the key research direction in the field of wind-sand engineering in the future, which is also the crucial and difficult point in the protection and control of railway sand hazard in sandy zones.     

中国陆域天然气水合物调查研究主要进展

我国是世界上既有海域水合物也有陆域水合物的少数几个国家之一。中国地质调查局高度重视陆域水合物调查研究,2016年正式设立“陆域天然气水合物资源勘查与试采工程”,通过对我国重点冻土区开展地质、地球物理和钻探调查,研发有效的陆域水合物调查、钻探和资源评价技术,初步摸清资源家底,评价资源潜力。自2002年开始探索性调查以来,已在青海省发现木里天然气水合物产地1处、昆仑山垭口盆地和乌丽地区疑似产地2处及系列找矿线索,评价出南祁连盆地、羌塘盆地及漠河盆地三大成矿远景区、12个成矿区带,资源潜力巨大; 在祁连山木里地区成功实施单直井和水平对接井试采,并取得了陆域天然气水合物成矿理论、勘采技术、环境调查和平台建设系列成果。以上成果有力推进了我国天然气水合物资源勘查试采进程,支撑国务院将天然气水合物设为第173个新矿种,初步形成“海陆并举、资环并重”的良好局面。     

北京市表层土壤中PAHs含量特征及来源分析

土壤,作为城市中最重要的环境介质,承担了较高多环芳烃(PAHs)的环境负荷,开展土壤PAHs分布特征及来源分析研究,可以为污染风险防控、环保政策制定提供支撑.为研究北京市不同功能区土壤环境中PAHs的含量、组成及来源,本文在北京市主城区进行了大范围采样,同时针对工业区、农业种植区、水源保护区及居民区等不同功能区进行了分...     

富集铊汞砷的生物是滥木厂铊矿床找矿和铊矿区污染的标志

滥木厂铊矿区植物和动物中Ｔｌ、Ｈｇ、Ａｓ含量变化总的趋势是以Ｈｇ最高,Ｔｌ次之,Ａｓ最低为特点。它们明显受生物赖以生存的地质地球化学和生物地球化学环境制约,尤其是矿区水、土壤和岩、矿石中高背景Ｔｌ、Ｈｇ、Ａｓ含量制约。矿区生物中Ｔ１、Ｈｇ、Ａｓ含量异常高,不难看出,矿区生物中Ｔ１、Ｈｇ、Ａｓ含量的高低,不仅是判别矿区污染程度的标志,也是找矿,特别是找盲矿体的标志。     

中国贵金属矿床的基本成矿规律与找矿方向

通过对近年来贵金属矿床勘查进展及其主要类型、主要成矿时代、主要矿集区等的分析与归纳,总结了中国金矿床、银矿床和铂族元素矿床的基本成矿规律,并提出它们各自的找矿方向。中国金矿床类型多,主要形成于中生代和新生代,集中在胶东、辽东、华北地台边缘、小秦岭、阿尔泰、金沙江-红河断裂带、台湾和东南沿海、滇黔桂、陕甘川及长江、黑龙江等主要水系的上游,金矿的找矿方向包括:①老矿区的"探边摸底"和"攻深找盲";②新矿集区的典型研究与采选冶技术改进;③综合利用技术的创新将使相当多的表外矿变为当前可开采的矿床;④新区勘查;⑤加强成矿系列、成矿体系和成矿规律的研究,以理论指导找矿并综合评价。中国银矿以伴生银矿为主,主要形成于中生代和新生代,变质岩、岩浆岩和沉积岩均可容矿,造山带和盆地区的构造破碎带尤其值得重视。当前需要加强对锰矿区含银性和Mn异常区的研究,尤其是中国东部中新生代盆地区断裂带与Mn、Ag化探异常吻合地区,应该综合评价。中国铂族元素矿床可以分为岩浆型、沉积型和热液型三大类,可形成于从前寒武纪到新生代的各个时代,至少构成8个重要成矿远景区(带),重点放在康滇地轴和二叠纪末期峨眉地幔柱影响到的地区,但华北地台老基底中的原生矿及其周边的砂矿不可忽视。     

滇池湖滨带叶绿素a与营养盐空间分布特征

为探讨滇池湖滨带叶绿素a与营养盐空间分布特征及其对滇池水体富营养化的影响,在滇池湖滨带设置21个采样点进行水质调查,采集滇池水样,分析测定总氮(TN)、总磷(TP)、化学需氧量(CODCr)、叶绿素a(Chla)和悬浮固体(SS)。结果表明:滇池湖滨带水体TN、TP、CODCr、Chla、SS浓度均值的空间分布存在差异,叶绿素a空间分布呈现北高南低,西高东低的趋势。滇池湖滨带的北部和东部水体Chla与TN极显著相关,TN具有强变异性。南部和西部TN与CODCr、TP显著相关,南部Chla与营养盐空间变异性较小,污染风险相对较小。按照"一区一策"的原则,滇池北部和东部湖滨带富营养化以控制TN的水平为主,南部、西部的富营养化防控则需要控制整体营养盐元素浓度。