南秦岭及邻区大陆动力成矿系统 及成矿系列特征与找矿方向

以南秦岭及邻区为例, 从大陆岩石圈地幔尺度上探讨了早古生代以来４ 种大陆动力学成矿系统及其１４ 种不同的成矿系列, 并指出了具有重要经济价值的主要成矿系列及今后的找矿方向。在早古生代大陆岩石圈地幔垂向构造扩展动力成矿系统中, 陆缘主动裂谷盆地中, 陆缘主动裂谷盆地中Ｎｉ－Ｖ－Ｍｏ－Ａｕ－Ｕ－Ｓｅ等是主要成矿系列。晚古生代岩石圈地幔俯冲收缩导生大陆壳伸展形成的伸展动力学成矿系统中, 形成的４种成矿系列是具有重大经济价值的主要成矿系列。印支期陆陆碰撞造山期形成的含金剪切型金成矿系列及燕山期－ 喜马拉雅期陆内造山期热泉型金矿成矿系列中, 常形成大型－超大型金矿矿集区。     

三江特提斯复合造山与成矿作用研究进展

国家973规划项目"三江特提斯复合造山与成矿作用"实施3年来,在成矿动力学背景、增生造山成矿系统、碰撞造山成矿系统、构造体制转换与复合叠加成矿作用、成矿预测理论和勘查技术集成等方面取得了重要进展。(1)厘定了原特提斯、古特提斯、新特提斯和陆陆碰撞等一系列重要的区域构造-岩浆事件及其动力学背景,提出存在较大规模的燕山期构造-岩浆-成矿事件。(2)划分了被动边缘盆地型、活动边缘多岛弧盆型和大洋盆地型3个VMS型Cu-Pb-Zn成矿子系统,确立了玉龙和格咱-香格里拉斑岩型Cu矿带印支期岩浆作用的贡献及俯冲岛弧构造环境。(3)沉积岩容矿Pb-Zn-Cu-Ag多金属矿床的形成贯穿于印-亚大陆碰撞的三个演化阶段,成矿年代由南向北逐渐变新;它包括2套子系统:脉状Cu成矿系统,与变质流体活动有关,成矿物质来自深部地壳和浅部沉积地层的混合;Pb-Zn(-Cu-Ag)成矿系统,与盆地流体活动有关,成矿物质主要来自沉积地层。(4)金沙江-哀牢山斑岩型Cu(Au)成矿系统形成于35Ma左右,受控于印-亚大陆碰撞导致的地壳增厚。(5)造山型Au成矿系统主要发育在哀牢山金矿带,三期金成矿作用发生于~62Ma、~35Ma和28Ma左右,分别受控于印-亚碰撞早期的强烈汇聚挤压、早-晚期转换构造动力学体制。(6)区域存在3期重要构造体制转换事件:增生造山→碰撞造山、主碰撞→晚碰撞和晚碰撞→后碰撞,前两者控制区域斑岩铜矿带、沉积岩容矿多金属矿带和造山型金矿带,后者控制了沱沱河盆地中的Pb-Zn矿床。(7)最典型的叠加成矿系统为VMS 型Cu-Pb-Zn与斑岩型Cu叠加成矿系统,主要发育于羊拉-红山-普朗-铜厂沟矿集区、云县-景谷、江达-维西和昌宁-孟连成矿带。(8)探索成矿预测理论与方法,并选择羊拉-红山-普朗-铜厂沟矿集区为重点地区,开展隐伏矿体预测工作,取得找矿进展。本专辑论文基本覆盖了上述各个方面的研究进展,论文涉及4个主题:成矿动力学背景、增生造山成矿系统、碰撞造山成矿系统、构造体制转换与复合叠加成矿作用。     

柴达木周缘金属矿床成因类型、成矿规律与成矿系列

位处青藏高原东北部、古亚洲构造域与特提斯构造域结合部位的柴达木盆地周缘地区,是一个具有复杂构造演化历史的多旋回复合造山区.同时,该区也是我国重要的、极富潜力的金属成矿带.在综合分析以往多年工作成果基础之上,较系统总结研究了区域成矿地质构造背景、区域构造演化、主要矿床类型、区域成矿规律与成矿系列.结果表明:该区地质构造演化主要经历了前寒武纪古陆形成、早古生代造山、晚古生代—早中生代造山和中新生代叠复造山等4个构造旋回.其中,早古生代和晚古生代—早中生代构造旋回与区内金属成矿关系密切;总结出6个主要矿床成因类型,分属于拉伸裂解构造背景的喷气-沉积矿床组合(包括VMS型、SEDEX型)和与造山过程有关的造山矿床组合(包括斑岩型、矽卡岩型、热液脉型、造山带型金矿等);该区成矿作用具有多期、多矿种和多类型的特点,初步总结划分出5个金属矿床成矿系列,即与新元古代—寒武纪裂解有关的铜多金属矿床成矿系列、与奥陶—志留纪裂解有关的铜钴铅锌多金属矿床成矿系列、与晚加里东陆-陆碰撞有关的金多金属矿床成矿系列、与晚古生代裂解有关的铜多金属矿床成矿系列、与晚华力西—印支期造山有关的铁铜铅锌金多金属矿床成矿系列.     

云贵高原-造山带-沉积盆地的构造演化与成岩成矿作用(代序)

云贵高原-造山带-沉积盆地的构造演化与金属矿产形成有密切关系。近南北向乌蒙山造山带和扬子地块西缘元古宙造山带(元古宙基底构造层)为元古宙铁铜和铁氧化物铜金型(IOCG)矿床集中区。在东缘滇黔桂晚古生代陆缘拉分盆地中,形成了铅锌银-金汞锑等低温热液金属矿床集中区。在个旧-文山一带形成了锡铜钨-多金属成矿集中区,并伴生铷铯铟等稀散元素。在西侧云南楚雄中新生代沉积盆地中,形成了砂岩型铜矿床集中区等。北侧四川-重庆一带形成了天青石矿床成矿集中区。这些金属矿床集中区形成与云贵高原-造山带-沉积盆地经历了多期次构造演化过程中,形成了特殊的矿田(床)构造有密切关系。这些特殊的大陆构造样式、构造组合、构造-流体-成岩成矿作用和碱性铁质基性岩类侵位的多重耦合作用,值得今后开展深入研究,为今后矿山深部找矿预测和大陆深部构造研究提供科学依据。     

祁连山新元古代——早古生代火山作用与铁-铜多金属成矿

祁连山造山带新元古代—早古生代是板块构造演化与成矿的最重要时段,铁、铜多金属矿产资源丰富,成矿作用与新元古代—早古生代火山作用密切相关。根据矿床产出构造位置,将祁连山铁、铜多金属矿床分为4类:大陆裂谷型铁(铜)矿床、岛弧-岛弧裂谷型铜多金属矿床、陆缘裂谷型铜多金属矿床、扩张脊型铜矿床。镜铁山铁(铜)型矿床是新元古代大陆裂谷火山作用过程中热水沉积作用的产物;东沟铜矿为晚寒武世大洋扩张脊火山作用的产物;白银矿田铜多属矿床是奥陶纪与岛弧-岛弧裂谷火山作用的产物;石居里铜矿是晚奥陶纪弧后扩张脊有关火山作用的产物;红沟铜矿则是晚奥陶世陆缘裂谷火山作用的产物。     

三江特提斯复合造山与成矿作用

三江特提斯构造带作为全球特提斯构造在中国大陆最典型的发育地区,经历了复杂而完整的演化历史:从晚前寒武纪—早古生代泛大陆解体与原特提斯洋形成,经古特提斯多岛弧盆系发育与古生代—中生代增生造山/盆山转换,到新生代印度-亚洲大陆碰撞与叠加改造,完好地记录了超级大陆裂解→增生→碰撞的完整演化历史和大陆动力学过程,可谓是中国大陆构造演化的典型缩影。复合造山和叠加转换导致了三江特提斯域复杂的成矿演化,主要表现为:①在构造转换阶段,于元古代刚性基底基础上发育大量叠加改造型矿床,具有独特的金属组合(Sn-Cu,Sn-Pb-Zn,Fe-Cu等);②火山成因块状硫化物(VMS)矿床伴随特提斯岩石圈演化,连续发育于陆缘裂谷(Cu)→初始洋盆(Cu-Zn)→大洋岛弧(Cu-Zn-Pb)→弧间裂谷或弧后盆地(Pb-Zn-Ag)→弧-陆碰撞裂陷盆地(Cu-Pb-Zn)等阶段及诸环境;③特提斯阶段的岛弧型斑岩Cu矿被碰撞造山阶段的大陆型斑岩Cu矿所取代;④世界级规模的金属成矿带和巨型矿床,在新生代碰撞造山期爆发式产生。尽管已有的研究从整体上勾画出了三江特提斯域的基本构造特征和成矿面貌,但仍有许多重要问题尚未解决:①三江复合造山带构造叠加、...     

晚古生代—中三叠世右江盆地的格局和转换

晚古生代—中三叠世右江盆地是在夷平的南华加里东造山带基础上再生裂陷的大陆边缘盆地,该盆地的形成与金沙江—哀牢山古特提斯洋盆关系密切,是一个具有台地与台间海槽相间结构的大陆边缘裂谷盆地。右江盆地自早泥盆世埃姆斯晚期开始裂陷,到石炭纪盆地与越北地块之间出现一个与古特提斯洋相关的局限小洋盆或深海盆。至二叠纪,该洋盆开始向西南俯冲于越北地块之下,形成活动大陆边缘。早三叠世晚期以后,随着该洋盆的闭合和碰撞造山,在凭祥、那坡等地出现同碰撞型的火山活动,右江盆地也于中三叠世转变为以复理石为特征的前陆盆地。因此右江盆地经历了裂谷盆地(早泥盆世晚期—晚泥盆世)、被动大陆边缘(早石炭世—早三叠世)、前陆盆地(中三叠世)的构造演化阶段。     

扬子地台北缘大型超大型重晶石矿床成矿作用的讨论

本区地壳演化分：太古—早元古代构造基底形成、中晚元古代大陆边缘、早古生代裂谷形成与晚古生代海槽演化四个阶段。重晶石矿床成矿作用有火山喷流作用、大陆边缘沉积作用与裂谷带多种成矿作用的叠加,是形成大型超大型重晶石矿床重要特征。本区寻找重晶石矿前景是乐观的。     

四川省会东县金锁桥铁金矿床控矿因素及矿床成因

<正>四川省会东县金锁桥铁金矿床位于杨子地台西缘川滇黔铜多金属成矿带,地处环太平洋构造域和特提斯构造域的结合部位,川滇黔菱形地块之会理-昆明裂陷带。该区经历了自早元古代弧后盆地、早中元中代拗拉槽、中元古代陆内裂谷、中晚元古代大陆边缘陆弧体、晚元古代后造山裂谷、古生代块断升降、地裂运动及中生代前陆盆地和山间断陷等漫长的地史演化,是以前震旦系变质岩作基底、古生代海相沉积作盖层的长期隆起地带,具地槽型变质岩系活动带及地台沉积。构成了本区良好的成矿     

复合造山和复合成矿系统:三江特提斯例析

提出复合造山定义,认为复合造山指多期次造山以及其它类型壳幔过程(裂谷作用、地幔柱活动、克拉通减薄等)在同一构造带先后发生或者多类型过程同时同位发生的地质事件;复合造山是大洋闭合-大陆拼贴过程的必然演化结果、地质历史时期普遍存在的地质过程,其具有不同属性板块拼接、多条蛇绿岩套与岛弧带并列、构造格架继承与改造、物质活化与循环运动以及构造体制转换突出等特征;复合造山带成矿时代长,类型多样,金属富集强度大,大型矿集区集中。复合成矿系统指在特定时-空域中,不同时期多种成矿作用或者同一时期不同成矿作用复合形成的成矿系统。复合成矿表现为成矿物质继承改造或成矿作用融合交叉,导致成矿元素多幕式富集,成矿空间广,成矿强度大,成矿概率增加。复合成矿系统分为多期复合和同期复合两类。复合造山驱动了复合成矿系统的形成,其是中国区域成矿典型特色。复合造山和复合成矿系统在特提斯构造带最为典型,中国西南三江造山带是典型解剖区。构建了古生代与中生代原-古-中-新特提斯洋闭合引发的增生造山和新生代印度-欧亚大陆汇聚导致的碰撞造山过程,厘定了增生造山海底喷流型Cu-Pb-Zn-Ag、增生-碰撞造山岩浆热液型CuMo-Sn-W、碰撞造山盆地卤水-岩浆热液型Pb-Zn-Ag-Cu和碰撞造山斑岩-矽卡岩型Au-Cu-Mo四类典型复合成矿系统。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.