共查询到18条相似文献,搜索用时 265 毫秒
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以Co(NO3)2.6H2O、Ni(CH3COO)2.4H2O和Mn(CH3COO)2.4H2O为原料,在氩气保护下用共沉淀法制备了分散均匀的前驱体[Co1/3Ni1/3Mn1/3]C2O4.xH2O,用TG/DSC对前驱体的热分解做了表征。前驱体与碳酸锂在乙醇-水的混合体系中均匀分散,50℃下真空干燥后于500℃下预烧,将得到的混合物压片,然后在空气中于700~1 000℃下煅烧12~24 h得到三元正极材料。将得到的样品进行XRD、电池充放电循环、循环伏安等表征和测试。结果表明,700~1 000℃合成的样品有好的晶型(六方晶系,α-NaFeO2),特别是900℃下合成的正极材料有较好的晶型、高的首次充放电容量,并具有良好的电化学性能。 相似文献
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南极洲万达盐湖水中悬浮物的流量 :水深 1 2m ,1 1 9 673mg/cm2 ·a;3 2m ,67 93mg/cm2 ·a;45m ,1 5 82mg/cm2 ·a;48m ,9 46mg/cm2 ·a ;60m ,1 3 5 5mg/cm2 ·a ;65m ,3 0 3 3mg/cm2 ·a。湖水悬浮物中粘土矿物主要为伊利石 ,含量 64~ 67% ,次为绿泥石 ,含量 2 5~ 3 0 % ,蒙脱石仅含 5 9~6 6% ,而高岭石含量极低。湖水悬浮物中痕量金属的含量 :水深 1 2m ,Cr 5 4 3 μg/g、Cu 1 1 9 3 μg/g、Ni 5 3 4μg/g、Co 2 3 9μg/g、Cd1 43 μg/g;3 2m ,Cr 44 9μg/g、Cu 1 1 8 7μg/g、Ni 5 0 2 μg/g、Co 1 9 4μg/g、Cd 1 5 1 μg/g;45m ,Cr 5 3 μg/g、Cu1 42 8μg/g、Ni 5 9 8μg/g、Co 1 9 8μg/g、Cd 1 83 μg/g ;60m ,Cr 1 3 2 μg/g、Cu 49 6μg/g、Ni 1 3 4μg/g;Co 4 3 μg/g、Cd 0 3 7μg/g ;65m ,Cr 7 4μg/g、Cu 1 7 6μg/g、Ni6 7μg/g、Co 2 4μg/g、Cd 0 3 6μg/g。悬浮物中痕量金属含量高低顺序 :Cu>Cr>Ni>Co >Cd。在水深 60m以上 ,悬浮物中痕量金属主要被束缚在硅酸盐、锰的氧化物及铁的氢氧化物悬浮物颗粒上 ,在水深 60m以下 ,则主要被束缚在硅酸盐矿物及有机质颗粒上。 相似文献
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采用甘氨酸-硝酸盐燃烧法,以硝酸锶、硝酸钙、钛酸丁酯和甘氨酸为原料合成了Ca0·3Sr0·7TiO3陶瓷粉体。对影响粉体特性的两个主要因素pH值和原料配比进行了讨论。XRD结果表明,所得粉体结晶好,纯度高。用所得粉体经1420℃烧结成瓷,介电频率特性测试结果表明,介电常数随频率单调递减,50kHz到10MHz范围内,介电常数基本稳定在140~150之间。介电损耗随着频率的增大先减小后增大,最小介电损耗在1MHz下为0·0243。 相似文献
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通过低温固相法制备了单质磷表面包覆LiCoO2超细粉体,研究了不同包覆量对LiCoO2粉体物理性能和电化学性能的影响。通过XRD、SEM研究了晶体结构、形貌等。分析表明包覆的粉体具有层状结构,表面光滑,粉体分布均匀,粒径分布在0.2~0.6μm之间。充放电循环测试表明:与LiCoO2相比,包覆磷后电压平台略有下降;当单质磷包覆量为5%时,正极材料LiCoO2的初始容量为173.3 mAh.g-1,50个循环后容量为143.2 mAh.g-1;在0.5C倍率下,正极材料LiCoO2初始容量144.0 mAh.g-1,100次循环后容量118.3 mAh.g-1,平均每次容量损失为0.18%。 相似文献
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以乙酸镁为镁源,用LiOH.H2O、Fe(NO3)3.9H2O、NH4H2PO4为原料通过水溶液法制备了掺杂Mg2+的LiFePO4/C正极材料。用XRD、SEM、恒流充放电测试、循环伏安(CV)和交流阻抗谱(EIS)方法,研究了Mg2+掺杂对LiFePO4/C的结构、形貌及电化学性能的影响。研究结果表明,Mg2+掺杂没有改变LiFePO4橄榄石型的结构;在0.1 C(1C=170 mAh.g-1)的充放电倍率下,Mg2+掺杂使正极材料首次放电比容量从153 mAh.g-1提高到159 mAh.g-1,经20循环次后,容量无损失;电化学交流阻抗显示,掺杂后材料阻抗Rct从463.1Ω减小到322.8Ω。 相似文献
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利用溶液共混法制备得到分子筛/石墨烯(RGO)复合电极材料。比较了分子筛(4A、13X、SBA-15)种类、煅烧温度以及分子筛与氧化石墨烯(GO)质量比等因素,对分子筛/RGO复合电极材料电化学性能的影响。采用X射线衍射(XRD)、孔径分析、扫描电镜(SEM)和电化学测试等分析方法考察了3种复合电极材料的结构、形貌及电化学性能。结果表明,RGO可以将4A很好地包覆,且4A均匀镶嵌在RGO层间并阻止RGO团聚,形成了三维空间导电网络结构,13X、SBA-15并不能完全被RGO包裹,RGO层间团聚现象仍较严重,不能形成三维导电网络结构。当分子筛与RGO质量比为6∶1,煅烧温度为320°C时,在4 A/g电流密度下,4A/RGO复合电极材料的比电容为450 F/g,而相应的13X/RGO、SBA-15/RGO复合电极材料的比电容分别为195、43 F/g。4A/RGO复合电极材料优异的超级电容性能可归于4A与RGO之间较强的协同效应。 相似文献
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根据宜昌站、汉口站和大通站的径流量数据,运用M-K检验和小波分析等方法,对1900年以来长江流域径流量的趋势和周期变化进行分析,探究径流量变化对厄尔尼诺?南方涛动(ENSO)和太平洋年代际振荡(PDO)的响应。结果表明:1900 年以来长江流域径流量呈显著的减少趋势,并具有2~8 a的年际周期变化和14~17 a的年代际周期变化。流域径流量与ENSO具有相同的2~8 a周期变化,在El Ni?o发生期,径流量较低,在La Ni?a发生期,径流量较高。14~17 a的周期变化与PDO相关,在暖位相期径流量偏少,在冷位相期径流量偏多。PDO影响着ENSO和径流量之间的相关性,在暖位相期,El Ni?o对径流量的影响增强,在冷位相期,La Ni?a对径流量的影响增强。因此,在分析和预测流域径流量长时间尺度上的变化时要综合考虑ENSO和PDO的影响。 相似文献
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Bent Hasholt 《Geografisk tidskrift / udgivet af Bestyrelsen for Det Kongelige danske geografiske selskab》2013,113(1):54-90
Karlsgårde Hydroelectric Power Station in SW Jylland had troubles with sedimentation in reservoir and canals. The extent of it has been measured and, throughout one year, monthly measurements were made of the bed load transport and of suspended load transport in the rivers flowing to the power station. A relation between discharge and bed load transport as well as between discharge and suspended load transport has been calculated. The amount of material transported during an “average year” has been found by means of duration curves. Some of the applied methods are described. The bed load transport was measured by various methods a.o. by measurement of the downstream advance of the bedforms. Fluorescent- coloured sand was used as tracer material. Its migration gave a qualitative impression of the intensity of the material transport which proved to be in good accordance with the other results. However, this method is too laborious for a quantitative determination of sediment transport. 相似文献
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北京市近郊区土壤镍的空间结构及分布特征 总被引:30,自引:1,他引:30
通过对北京市近郊区349处土壤的取样调查,利用地统计学方法研究了北京市土壤中镍的空问结构和分布特征。结果显示,镍的空间结构性较好,具有明显的可迁性特点,块金效应所占的比例较大;实验变异函数可用指数模型拟合,利用所得模型进行克立格插值得到土壤镍含量的分布图,发现北京市土壤中,镍的含量分布具有明显的西北低而东南高的趋势。与北京市土壤镍含量的背景值进行对比,全市土壤并不存在非常严重的镍污染,其空间分布主要受成土母质制约;但是人类活动、风向、河流等人文和自然条件对镍的空间结构和分布格局也有一定程度的影响。 相似文献
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Saltwater intrusion in the estuary area threatens the use of freshwater resources.If river discharge increases to a critical value,then saltwater intrusion frequency and salinity level decreases.In this study,long-term river discharge and tidal range data in the Yangtze River Estuary(YRE)and salinity data obtained in the upper South Branch of the YRE were used to analyze the characteristics of different variables and the basic law of their interactions.Two methods,namely,the material analysis method and empirical models,were applied to determine the critical river discharge for saltwater intrusion control.Results are as follows:(1)the salinity might exceed the drinking water standard of China when the river discharge was less than 30,000 m^3/s.Approximately 69%of salinity excessive days occurred when the river discharge was less than 15,000 m^3/s;(2)the tidal range in the YRE roughly varied in sinusoidal pattern with a 15-day cycle length.Exponential relationship existed between daily salinity(chlorinity)and daily mean tidal range.Combining these two features with the cumulative frequency statistics of tidal ranges,it was showed that notable saltwater intrusion occurred when the tidal range was more than 2.7 m at Qinglonggang station.Moreover,the critical discharge was found to be slightly higher than 11,000 m^3/s;(3)various of empirical models for salinity prediction could be chosen to calculate the critical discharge.The values obtained by different models were in the range of 11,000–12,000 m^3/s;(4)the proposed critical discharge to reduce notable saltwater intrusion was 11,500 m^3/s.After the Three Gorges Reservoir operation,the minimum river discharge into the YRE in 2008–2017 was below the critical discharge,thereby suggesting an increase in the minimum river discharge by reservoir regulation in drought periods. 相似文献