Geochemical and isotopic characteristics of volcanic rocks from the northern East China Sea shelf margin and the Okinawa Trough

Volcanic rocks both from the northern East China Sea (NECS) shelf margin and the northern Okinawa Trough are subalkaline less aluminous,and lower in High Field Strength Elements (HFSE).These rocks are higher in Large Ion Lithophile Elements (LILE),thorium and uranium contents,positive lead anomalies,negative Nb-Ta anomalies,and enrichment in Light Rare Earth Elements (LREE).Basalts from the NECS shelf margin are akin to Indian Ocean Mid-Ocean Ridge Basalt (MORB),and rhyolites from the northern Okinawa Trough have the highest 207 Pb/ 204 Pb and 208 Pb/ 204 Pb ratios.The NECS shelf margin basalts have lower 87 Sr/ 86 Sr ratios,ε N d and σ 18 O than the northern Okinawa Trough silicic rocks.According to 40 K– 40 Ar isotopic ages of basalts from the NECS shelf margin,rifting of the Okinawa Trough may have been active since at least 3.65–3.86 Ma.The origin of the NECS shelf margin basalt can be explained by the interaction of melt derived from Indian Ocean MORB-like mantle with enriched subcontinental lithosphere.The basalts from both sides of the Okinawa Trough may have a similar origin during the initial rifting of the Okinawa Trough,and the formation of basaltic magmas closely relates to the thinning of continental crust.The source of the formation of the northern Okinawa Trough silicic rocks was different from that of the middle Okinawa Trough,which could have been generated by the interaction of basaltic melt with an enriched crustal component.From the Ryukyu island arc to East China,the Cenozoic basalts have apparently increasing trends of MgO contents and ratios of LREE to Heavy Rare Earth Elements (HREE),suggesting that the trace element variabilities of basalts may have been influenced by the subduction of the Philippine Sea plate,and that the effects of subduction of the Philippine Sea plate on the chemical composition of basaltic melts have had a decreasing effect from the Ryukyu island arc to East China.     

泰国湾西部表层沉积物自生矿物分布及组成

Generation, morphology, and distribution of authigenic minerals directly reflect sedimentary environment and material sources. Surface sediments were collected from the western Gulf of Thailand during 2011–2012, and 159 samples were analyzed to determine detrital minerals. Authigenic minerals, including siderite, pyrite, and glauconite, are abundant whereas secondary minerals, such as chlorite and limonite, are distributed widely in the study area. Siderite has a maximum content of 19.98 g/kg and appears in three types from nearshore to continental shelf, showing the process of forming-maturity-oxidation. In this process, the Mn O content in siderite decreases, but Fe_2O_3 and Mg O content increase. Colorless or transparent siderite pellets are fresh grains generated within a short time and widely distributed throughout the region; high content appears in coastal area where river inputs are discharged. Translucent cemented double pellets appearing light yellow to red are mature grains; high content is observed in the central shelf. Red-brown opaque granular pellets are oxidized grains,which are concentrated in the eastern gulf. Pyrite is mostly distributed in the central continental shelf with an approximately north–south strip. Pyrite are mainly observed in foraminifera shell and distributed in clayey silt sediments, which is similar to that in the Yangtze River mouth and the Yellow Sea. The pyrite in the gulf is deduced from genetic types associated with sulfate reduction and organic matter decomposition. Majority of glauconite are granular with few laminar. Glauconite is concentrated in the northern and southern parts within the boundary of 9.5° to 10.5°N and is affected by river input diffusion. The distribution of glauconite is closely correlated with that of chlorite and plagioclase, indicating that glauconite is possibly derived from altered products of chlorite and plagioclase. The K_2O content of glauconite is low or absent, indicating its short formation time.     

鸭绿江河口西岸潮滩沉积对流域人类活动的响应

The response to the catchment changes of the sedimentary environment of the western intertidal flat of Yalu River Estuary was investigated by analyzing the vertical variations of the grain size of sediment cores,along with the hydrologic data and human activities in the catchment.The results demonstrated a stepwise decreasing trend for the variations of both the sediment load and water discharge into the sea,which could be divided into three stages as 1958–1970,1971–1990 and 1991–2009.Reservoir construction and the changes of catchment vegetation coverage turned out to be the two predominant contributors to the changes.There are four periods for the variation of the sensitive components of the sediment cores from 1940 to 2010,i.e.,1940–1950,1951–1980,1981–1990 and 1991–2010.The vertical distribution of grain size in the cores mainly varied with the changes of vegetation coverage in the catchment and reservoir construction from 1960 to 1980,whereas it varied depending on the intensity of water and soil erosion in the catchment from 1980 to 1990.Despite the further reduction of the water and sediment input into the sea from 1990 to 2009,this period was characterized by coarsening trends for the grain size of sediment in the estuarine intertidal flat and correspondingly,the significantly increased silt contents of the sensitive component.     

Ocean color products retrieval and validation around China coast with MODIS

Waters along China coast are very turbid with high concentrations of suspended sediment nearly all the time,especially at the Hangzhou Bay,the Changjiang (Yangtze) River Estuary and the shoal along Jiangsu Province.In these turbid and optically complex waters,the standard MODIS ocean color products tend to have invalid values.Because the water-leaving radiances in the near-infrared (NIR) are significant resulting from the strong scattering of suspended particles,the standard MODIS atmospheric correction algorithm often gets no results or produces significant errors.And because of the complex water optical properties,the OC3 model used in the standard MODIS data processing tends to get extremely high chlorophyll-a (Chl-a) concentrations.In this paper,we present an atmospheric correction approach using MODIS short wave infrared (SWIR) bands based on the fact that water-leaving radiances are negligible in the SWIR region because of the extreme strong absorption of water even in turbid waters.A regional Chl-a concentration estimation model is also constructed for MODIS from in situ data.These algorithms are applied to MODIS Aqua data processing in the China coastal regions.In situ data collected in the Yellow Sea and the East China Sea in spring and autumn,2003 are used to validate the performance.Reasonably good results have been obtained.It is noted that water-leaving reflectance in the NIR bands are significant in waters along the China coast with high sediment loadings.The satellite derived and in-situ reflectance spectra can match in the turbid waters along China coast,and there is relatively good linear relationship between satellite derived and in-situ reflectance.The RMSE value of Rrs(λ) is 0.0031 sr ?1 for all the nine ocean color bands (412 to 869 nm).The satellite-derived Chl-a value is in the reasonable range and the root mean square percentage difference is 46.1%.     

GEOCHEMICAL CHARACTERISTICS OF ARSENIC IN SEDIMENTS FROM BOHAI GULF

This paper deals with the geochemical characteristics of arsenic in sediments from Bohai Gulf. The arsenic in seawater, surface sediments and cores is determined. Also measured are other physical and chemical parameters, such as Ni, Fe, C, pH and Eh in sediments. The values of As range from 0.6 to 4.5 ppb in seawater, from 10.0 to 20.9 ppm in surface sediments and from 6.8 to 22.8 ppm in cores.The contents of As from south are higher than those from north. However the As in sediments is the element not affected by pollution.The adsorption and codeposition of Ferric oxide colloid are the major form of transference of As from seawater to sediments in Bohai Gulf.The valence state of As in sediments is HAsO42-     

上新世以来南海海水表层温度（SST）的变化

The reconstruction of sea surface temperature(SST) is a key issue in research on paleoceanography. The recently related studies are mainly concentrated on the Quaternary. The skeletons of a typical species of benthonic foraminifer(Amphistegina radiata) in the top 0–375.30 m interval of Well "Xike-1" reef core, Shidao Island, the Xisha Islands, are uniformly selected. The ratios of magnesium to calcium concentrations and other indicators are analyzed by an electron microprobe analysis(EMPA) with the purpose of estimating the paleo-SSTs since the Pliocene and further investigating the periodic change law of paleoclimate in the South China Sea(SCS).Meanwhile, the geologic significance of paleoclimatic events in the SCS is discussed with global perspectives. The results indicate that the paleo-SSTs reconstructed by the ratios of magnesium to calcium concentrations in the SCS show a general periodic trend of "high–low–high–low" in values changes since the Pliocene. By comparison,the fluctuations of reconstructed paleo-SSTs are much stronger in the Quaternary. Moreover, the variations of the ratios of magnesium to calcium concentrations in the A. radiata skeletons have recorded a series of major paleoclimatic events since the Pliocene, of which the Quaternary glaciation events and the Arctic ice cap forming events during the late Pliocene are more significant. Thus, using the changes of the ratios of magnesium to calcium concentrations in the A. radiata skeletons from Well "Xike-1" reef core to reflect the relative changes of paleo-SSTs is a relatively feasible and reliable way in the SCS, which is also proved by the correlation of drilling cores characteristics in this area.     

西太平洋海山年龄及地球化学:地幔过程及岩石成因

Research on seamounts provides some of the best constraints for understanding intraplate volcanism, and samples from seamounts reveal crucial evidence about the geochemical makeup of the oceanic mantle. There are still many seamounts in the West Pacific Seamount Province(WPSP) that have not been studied, meaning their ages and geochemistry remain unknown. A better understanding of these seamount trails and their evolutionary history, investigated with age and geochemistry data, will enable better understanding of the geological processes operating underneath the Pacific Ocean Plate. Here, new ~(40)Ar/~(39) Ar ages and trace element and Sr-Nd-Pb isotopic data for seven basalt rocks from four seamounts in the WPSP are provided. Chemically, these rocks are all Oceanic Island Alkali basalt(OIA type); analysis of olivine phenocrysts shows that the magmas experienced strong olivine fractionation and changed from olivine + plagioclase to olivine + plagioclase + clinopyroxene cotectic during their evolution. Rare earth element(REE) patterns and a spider diagram of the samples in this study show OIB(Ocean Island Basalt) like behavior. The range of ~(87)Sr/~(86) Sr values is from 0.704 60 to 0.706 24, the range of ~(206)Pb/~(204) Pb values is from 18.241 to 18.599, and the range of ~(143)Nd/~(144) Nd values is from 0.512 646 to 0.512 826; together, these values indicate magma sources ranging from EMI to EMII. Finally, new ~(40)Ar/~(39) Ar age data show that these seamounts formed at ～97 and ～106 Ma, indicating that some may have undergone the same formation processes as seamounts in the eastern part of the Magellan Seamount Trail, but other seamounts likely have different origins.     

Spatial and temporal variations of sedimented organic matter in Xiaohai Lagoon, Hainan Island

The characteristics of grain-size,total organic carbon(TOC) and total nitrogen(TN) contents,TOC/TN ratios,stable carbon isotope(δ13C) and 210 Pb dating were measured in six sediment cores from the Xiaohai Lagoon.The results show distinct spatial and temporal variations in sedimentation patterns.The sediments are dominated by clayey silt,sandy silt and by silty sand in the southern,middle lagoon and the northern lagoon,respectively.TOC and TN contents decline from south to north.Sedimentation rates,determined by 210 Pb dating,tend to decrease from south to middle.However,the determination of sedimentation rate in the north is difficult.These spatial variations are related to the variations in sediment sources and hydrodynamic conditions in the Xiaohai Lagoon.The variations of organic matter signatures can be divided into two stages in the cores from the southern and middle lagoon.Before 1988,the organic matter signatures are relatively stable.The contribution of terrestrial organic carbon sources varies between 60% and 85%.After 1988,the organic matter signatures demonstrate significant variations.TOC and TN contents increase rapidly,TOC/TN ratios decrease,δ13C values shift to higher and the contribution of terrestrial organic carbon sources decreases to 40%-50%.The contributions of phytoplankton organic matter have increased in the sediment since 1988.Increasing aquaculture activities have had a significant impact on organic matter signatures since 1988.The sedimentation rates have increased rapidly in the southern and middle lagoon since 1988 due to the anthropogenic activities which include aquaculture,mining and deforestation.These activities have caused eutrophication and increased siltation in the southern and middle lagoon.     

黄东海近代厌氧沉积物中鳀鱼鱼鳞沉积信息的空间分布及重建潜力

Many studies have revealed that anchovy has exhibited large variability in population size on decadal tim-escales. However, such works concerning anchovy population are mainly based on short historical catch records. In order to understand the causes of variability in fish stocks （natural and/or anthropogenic） and calibrate the error between catches and standing stocks, it is essential to develop long-term time series of fish stocks from the time when human impacts are minimal or negligible. Well preserved fish scales from sediment record are regarded as useful indicators revealing the history of fish population dynamics over the last centuries. Anchovy scales was first analyzed over the Yellow Sea and East China Sea and the largest abundance was found in the central South Yellow Sea where is regarded as the largest overwintering ground for Japanese anchovy （Engraulis japonicas）. Thus in the central South Yellow Sea, two cores covering the last 150 years were collected for estimating fish scale flux. The scale deposition rate （SDR） records show that the decadal scale SDRs were obviously coherent between cores with independent chronologies. Thecalibration of downcore SDRs to the standing stocks of anchovy further validated that SDR is a reliable proxy to recon-struct the long-term anchovy population dynamic in the central South Yellow Sea where anoxic conditions prevail in the sediment. When assembled with other productivity proxies, it would be expected that SDR could be associated with changes in oceanic productivity and may make a contribution to determine the forcing factors and elucidate the mechanism of the process in future.     

Rapid decrease in Antarctic sea ice in recent years

A 41-year Antarctic sea ice concentration(SIC) dataset derived from satellite passive microwave radiometers during the period of 1979–2019 has been used to analyze sea ice changes in recent decades. The trends of SIC and sea ice extent(SIE) are calculated during the periods of 1979–2019, 1979–2013, and 2014–2019. The trends show regionally dependent features. The SIC shows an increasing trend in most of the regions except the Bellingshausen Sea and Amundsen Sea(BA) during 1979–2019 and 1979–2013. The SIE trend shows a decreasing or decelerating trend in the period of 1979–2019((6 835±2 210) km2/a) compared with the 1979–2013 period((18 600±2 203) km~2/a). In recent years(2014–2019), the SIC and SIE have exhibited decreasing trends(–(34 567±3 521) km~2/month), especially in the Weddell Sea(WS) and Ross Sea(RS) during summer and autumn. The trends are related to regionally dependent causes. The analyses show that the SIC and SIE decreased in response to the warming trend of 2 m air temperature(T_(a-2m)) and have exhibited a good relationship with T_(a-2m) in summer and autumn in recent years. The sea ice decrease in the Antarctic is mainly caused by increases in absorbed energy and southward energy transportation in recent years, such as the increase in gained solar radiation and moist static energy from the south, which demonstrate notable regional characteristics. In the WS region, the local positive feedback from the additional absorbed solar radiation, resulting in warmer air and reduced sea ice, is the main reason for the sea ice decrease in recent years. The increase in southward energy transport has also favored a decrease in sea ice. In the RS region, the increase in southward-transported moist static energy has contributed to the decrease in sea ice, and the increases in cloud cover and longwave radiation have prevented sea ice growth.     

中太平洋CA海山玄武岩中斜长石化学成分特征及地质意义

在对CA海山玄武岩CAD21样品岩相学研究基础上,运用电子探针和X-荧光光谱法(XRF)对中太平洋CA海山斜长石斑晶中的环带、斜长石微晶和玄武岩中的硅酸盐进行了化学成分研究。CA海山玄武岩为地幔柱成因的板内玄武岩;斜长石斑晶具有环带结构,环带核部与边部为不连续消光,是不连续环带;环带核部为培长石,边部为拉长石,是岩浆演化过程中形成的正环带,其成因受岩浆演化过程中熔体组分及温、压条件的共同制约。斜长石斑晶核部、边部及斜长石微晶估算温度平均值分别为1 281,1 198和1 071 ℃,分别代表了岩浆源区、岩浆房及岩浆喷发温度,三者温度差值较小,这和洋岛玄武质岩浆的形成及喷发特点相吻合。     

冲绳海槽浮岩包裹体的测温试验

对浮岩中斜长石斑晶中的包裹体及玻璃基质中的包裹体首先进行双面光薄片的镜下观察，然后进行了系统的均化法与爆裂法测温试验。观察与试验结果表明：(1)斜长石中的包裹体均为玻璃质+气泡的两相包裹体，未发现气—液包裹体。固化包裹体为玻璃质，非晶质的固化包裹体外即是大量的气泡，特别是基质当中气泡更为发育，说明熔浆中含有丰富的挥发性组分，同时也说明包裹体形成于较浅的地质条件下。(2)长石中包裹体的均化温度不受包裹体特征不同的影响，均化温度分布范围从910—1250℃，峰值明显，计算的均化温度为Tz=(1081.4±177.9)℃，但还存在有高于1250℃的均化温度峰。包裹体均化法测试结果说明浮岩中斜长石的形成过程至少有两个阶段：第一阶段的岩浆温度在1200—1300℃左右，在此温度下形成的是An值较高的基性斜长石，同时结晶的还有辉石等矿物，斜长石结晶第二个阶段时的熔浆温度在1100℃以下，这一阶段持续的时间长，跨越的温度范围大，应是岩浆在近地表和岩浆喷出过程中的岩浆快速冷却期，同时伴随有矿物大规模晶出。(3)包裹体中的气相部分均聚合成圆形或近圆形，说明温度下降速度较快。斑晶斜长石中部分包裹体与基质玻璃中包裹体的形成温度是连续变化的，这一事实应该与冲绳海槽特殊的地质条件有关     

Newly discovered hydrothermal fields along the ultraslow-spreading Southwest Indian Ridge around 63°E

The ultraslow-spreading Southwest Indian Ridge(SWIR) to the east of the Melville fracture zone is characterized by very low melt supply and intensive tectonic activity. Due to its weak thermal budget and extremely slow spreading rate, the easternmost SWIR was considered to be devoid of hydrothermal activity until the discovery of the inactive Mt. Jourdanne hydrothermal field(27°51′S, 63°56′E) in 1998. During the COMRA DY115-20 cruise in2009, two additional hydrothermal fields(i.e., the Tiancheng(27°51′S, 63°55′E) and Tianzuo(27°57′S, 63°32′E)fields) were discovered. Further detailed investigations of these two hydrothermal sites were conducted by Chinese manned submersible Jiaolong in 2014–2015. The Tiancheng filed can be characterized as a lowtemperature(up to 13.2°C) diffuse flow hydrothermal field, and is hosted by fractured basalts with hydrothermal fauna widespread on the seafloor. The Tianzuo hydrothermal field is an inactive sulfide field, which is hosted by ultramafic rocks and controlled by detachment fault. The discovery of the three hydrothermal fields around Segment #11 which receives more melt than the regional average, provided evidence for local enhanced magmatism providing heat source to drive hydrothermal circulation. We further imply that hydrothermal activity and sulfide deposits may be rather promising along the easternmost SWIR.     

The morphotectonics and its evolutionary dynamics of the central Southwest Indian Ridge (49° to 51°E)

The morphotectonic features and their evolution of the central Southwest Indian Ridge （SWIR） are dis- cussed on the base of the high-resolution flfll-coverage bathyraetric data on the ridge between 49°-51°E. A comparative analysis of the topographic features of the axial and flank area indicates that the axial topogra- phy is alternated by the ridge and trough with en echelon pattern and evolved under a spatial-temporal mi- gration especially in 49°-50.17°E. It is probably due to the undulation at the top of the mantle asthenosphere, which is propagating with the mantle flow. From 50.17° to 50.7°E, is a topographical high terrain with a crust much thicker than the global average of the oceanic crust thickness. Its origin should be independent of the spreading mechanism of ultra-slow spreading ridges. The large numbers of volcanoes in this area indicate robust magmatic activity and may be related to the Crozet hot spot according to RMBA （residual mantle Bouguer anomaly）. The different geomorphological feature between the north and south flanks of the ridge indicates an asymmetric spreading, and leading to the development of the OCC （oceanic core complex）. The tectonic activity of the south frank is stronger than the north and is favorable to develop the OCC. The first found active hydrothermal vent in the SWIR at 37°47＇S, 49°39＇E is thought to be associated with the detach- ment fault related to the OCC.     

冲绳海槽浮岩中斑晶矿物结晶的P-T条件

本文利用多种地质温度计估算了冲绳海槽浮岩中斑晶矿物的结晶条件。结果表明:灰白色浮岩中的橄榄石、辉石、基性斜长石、磁铁矿等是在大约890℃和大约三十几km深的条件下结晶的。这些矿物之所以存在于SiO2含量高达70％的酸性浮岩中是由于在岩浆喷出地表之前发生了岩浆的混合作用。根据斑晶矿物的结晶深度,推测灰白色浮岩的初始岩浆来自地幔的熔融。     

Ferrobasalts from the Central Indian Ocean Basin

We report the occurrence of ferrobasalts recovered from the Central Indian Ocean Basin crust generated at the Southeast Indian Ridge during a phase of moderate to fast spreading accretion (～110–190?mm/yr, full rate).The rocks are rich in plagioclase, FeO* (13–19%), and TiO₂ (2.27–2.76%), poor in olivine and MgO (3.44–6.20%), and associated with topographic highs and increased amplitude magnetic anomalies corresponding to chrons A25 and A24. We suggest that secon dary eruptions from ancient N-MORB magma, which may have been trapped at a shallow depth in a horizon of neutral buoyancy, could have produced the ferrobasalts.     

Segmentation and Morphotectonic Variations Along a Super Slow-Spreading Center: The Southwest Indian Ridge (57° E-70° E)

Bathymetric data along the Southwest Indian Ridge (SWIR) between 57°E and 70° E have been used to analyze the characteristics of thesegmentation and the morphotectonic variations along this ridge. Higheraxial volcanic ridges on the SWIR than on the central Mid-Atlantic Ridge(MAR) indicate that the lithosphere beneath the SWIR axis that supportsthese volcanic ridges, is thicker than the lithosphere beneath the MAR. Astronger/thicker lithosphere allows less along-axis melt flow andenhances the large crustal thickness variations due to 3D mantle upwellings.Magmatic processes beneath the SWIR are more focused, producing segmentsthat are shorter (30 km mean length) with higher along-axis relief (1200 mmean amplitude) than on the MAR. The dramatic variations in the length andamplitude of the swells (8–50 km and 500–2300 m respectively),the height of axial volcanic ridges (200–1400 m) and the number ofvolcanoes (5–58) between the different types of segments identifiedon the SWIR presumably reflect large differences in the volume, focusing andtemporal continuity of magmatic upwelling beneath the axis. To the east ofMelville fracture zone (60°42 E), the spreading center isdeeper, the bathymetric undulation of the axial-valley floor is less regularand the number of volcanoes is much lower than to the west. The spreadingsegments are also shorter and have higher along-axis amplitudes than to thewest of Melville fracture zone where segments are morphologically similar tothose observed on the central MAR. The lower magmatic activity together withshorter and higher segments suggest colder mantle temperatures withgenerally reduced and more focused magma supply in the deepest part of thesurvey area between 60°42 E and 70° E. The non-transformdiscontinuities show offsets as large as 70 km and orientations up toN36° E as compared to the N0° E spreading direction. We suggest thatin regions of low or sporadic melt generation, the lithosphere neardiscontinuities is laterally heterogeneous and mechanically unable tosustain focused strike-slip deformation.     

西南印度洋中脊玄武岩地球化学特征及其对岩浆过程的指示意义

对采自西南印度洋中脊(SWIR)50°E附近5个站位的玄武岩样品进行了岩石学和元素地球化学研究。样品主量元素、TAS分类图解和AFM图解显示,SWIR研究区样品类型主要为低钾拉斑玄武岩。相对原始地幔SWIR区玄武岩具有Ba、Nb、Sr负异常,K表现为正异常。稀土元素分配模式均为左倾型,具有轻微的Eu、Ce正异常;SWIR区玄武岩都起源于上地幔,SWIR玄武岩则明显向EMⅡ端元偏移。SWIR玄武岩地幔源区相对最为富集,可能为DM和EMⅡ的混合源区,存在少量的陆壳成分。研究区玄武质岩浆起源深度为尖晶石橄榄岩区域处于中度还原环境下,经历了明显的橄榄石+单斜辉石+斜长石的分离结晶。     

Source and magmatic evolution of ocean island basalts from the Pohnpei Island,Northwest Pacific Ocean: Insights from olivine geochemistry

The compositional variability of ocean island basalts (OIBs) is thought to reflect partial melting of a lithologically-heterogeneous mantle source dominated by either pyroxenite or peridotite. The Pohnpei Island in Micronesia, which is associated with the Caroline hotspot, is suggested to have been generated from partial melting of a pyroxenite-rich mantle. To examine this hypothesis, we present new major- and trace-element compositions of olivine phenocrysts in basalts from the island. The olivines exhibit large systematic inter- and intra-crystalline compositional variability. In Sample DS1, olivines record compositional zonation, in which cores have relatively high Fo (77–85), Ni (550×10?6–2 392×10?6), and Fe/Mn ratios (66–82), whereas rims have lower Fo (71–78), Ni (526×10?6–1 537×10?6), and Fe/Mn ratios (51–62). By contrast, olivines within other samples preserve no clear compositional zonation, exhibiting similar or slightly lower Fo values (66–78), Ni contents (401×10?6–1 268×10?6), and Fe/Mn ratios (53–69) as the rims of zoned crystals. The distinct chemical contrast between the two different types of olivine suggests they formed in magma chambers at different depths. Analysis using forward petrological modeling and multi-element indicators (Fe/Mn, Zn/Fe, FC3MS (FeOT/CaO?(3×MgO/SiO₂)), Mn/Zn, and Ni/(Mg/Fe)) of whole-rock samples and high-Fo olivines is inconsistent with a pyroxenite-rich mantle source. We suggest these inconsistencies reflect an influence on the partition coefficients of Ni and Mn between olivine and liquid during melting at variable pressures and temperatures. In addition, magma recharge and mixing within the magmatic plumbing system can change the composition of olivine. We suggest that identification of the mantle source of OIBs in volcanic islands such as the Pohnpei Island using olivine geochemistry should be treated with caution.