Monitoring Large-Scale Tests for Nuclear Waste Disposal

Two large-scale “in situ” demonstration experiments and their instrumentation are described. The first test (FEBEX Experiment) involves the hydration of a compacted bentonite barrier under the combined effect of an inner source of heat and an outer water flow from the confining saturated granite rock. In the second case, the progressive de-saturation of Opalinus clay induced by maintained ventilation of an unlined tunnel is analyzed. The paper shows the performance of different sensors (capacitive cells, psychrometers, TDR’s) and a comparison of fill behaviour with modelling results. The long term performance of some instruments could also be evaluated specially in the case of FEBEX test. Capacitive sensors provide relative humidity data during long transient periods characterised by very large variations of suction within the bentonite.     

Singaporeans in China: transnational women elites and the negotiation of gendered identities

The burgeoning literature on transnationalism involving skilled migrants--based largely on the view from the developed world--have generally paid little heed to “elite” women and the reproductive sphere. We argue that women play many roles in elite transnational migration streams and must be given full consideration as part of the “transnational elite.” Attention is given to the way women--both “tied” and “lead” migrants--negotiate gendered identities as they participate in Singapore's regionalisation process, a state-driven initiative to extend the national economy by leveraging on growth in the region. Empirical material for the paper is mainly based on in-depth interviews with married women who were part of a larger project involving interviews with 150 Singaporeans who had lived, or were living, in China. In examining the movements through transnational space between Singapore and China, it is clear that patriarchal norms continue to shape women's understandings of their own identities vis--vis men's. Singapore women who move as accompanying spouses (the majority) find themselves giving up careers to focus on their domestic role in China (in the absence of access to “suitable” paid domestic service), and are not so much “deskilled” but “re-domesticated”. The exceptional few women who ventured into China as entrepreneurs experienced considerable strain holding together geographically separate spheres of productive and reproductive work across the transnational terrain. Both sets of “stories” alert us to the need to include “elite” women--whether accompanying spouses or independent entrepreneurs--in our understanding of “transnational elites.” This will contribute to the urgent task of ensuring that both productive and reproductive work are valorized in equal measure in conceptualizing transnationalism.     

Landscape governance: The “politics of scale” and the “natural” conditions of places

Governance has become an iridescent concept in recent years. The term is widely used in almost all social-science disciplines as well as in the political process. The intention of this paper is not so much to clarify these sometimes vague meanings but to highlight some characteristics of environmental governance connected with the restructuring of the spatial dimensions of politics. It starts from the assumption that the quest for multi-level decision making is particularly pressing for environmental governance. However, multi-level governance raises concern about the constitution of various spatial levels and their relationships with each other, as discussed under the term of “politics of scale”. Moreover, it is argued that for environmental governance the spatial reference is strongly connected with another challenge, which concerns the question of how to deal with the biophysical conditions of particular places. The term landscape governance is introduced to tackle this question without referring to an ontologically given space. Thus, landscape governance deals with the interconnections between socially constructed spaces (the politics of scale) and “natural” conditions of places. For this task, the concept of societal relationships with nature is introduced and applied to the term “landscape” as a bridging concept between social and natural sciences. The paper illustrates the approach of landscape governance with examples of problem-oriented interdisciplinary research at the UFZ-Centre for Environmental research in Leipzig, Germany.     

Arsenic distribution in the environment: The effects of scale

The distribution of As in a variety of sample materials was studied at different scales, from continental to local, combining published data sets with the aim of delineating the impact and relative importance of geogenic vs. anthropogenic As sources. Geochemical mapping of As with a variety of sample materials demonstrates that variation is high at all scales (local to continental) – from sample densities of 400 sites per km² to 1 site per 5000 km². Different processes govern the As distribution at different scales. A high sample density is needed to reliably detect mineralisation or contamination in soil samples. In both cases the impact on the much larger geochemical background variation is limited to a local scale. Distribution patterns in geochemical maps on the sub-continental to continental scale are dominated by natural variation. Given that the geochemical background is characterised by a high variation at all scales, it appears impossible to establish a reliable single value for “good soil quality” or a “natural background concentration” for As for any sizeable area, e.g., for Europe. For such a differentiation, geochemical maps at a variety of scales are needed.     

FUNMIG Integrated Project results and conclusions from a safety case perspective

The scope of the FUNMIG Integrated Project (IP) was to improve the knowledge base on biogeochemical processes in the geosphere which are relevant for the safety of radioactive waste repositories. An important part of this project involved the interaction between data producers (research) and data users (radioactive waste management organisations in Europe). The aim thereof was to foster the benefits of the research work for performance assessment (PA), and in a broader sense, for the safety case of radioactive waste repositories. For this purpose a specifically adapted procedure was elaborated. Thus, relevant features, events and processes (FEPs) for the three host rock types, clay, crystalline and salt, were taken from internationally accepted catalogues and mapped onto each of the 108 research tasks conducted during the FUNMIG project by a standardised procedure. The main outcome thereof was a host-rock specific tool (Task Evaluation Table) in which the relevance and benefits of the research results were evaluated both from the PA and research perspective. Virtually all generated data within FUNMIG are related to the safety-relevant FEP-groups “transport mechanisms” and “retardation”.     

THM analysis of a large‐scale heating test incorporating material fabric changes

Engineered barriers are basic elements in the design of repositories for the isolation of high‐level radioactive waste. This paper presents the thermo‐hydro‐mechanical (THM) analysis of a clay barrier subjected to heating and hydration. The study focuses on an ongoing large‐scale heating test, at almost full scale, which is being carried out at the CIEMAT laboratory under well‐controlled boundary conditions. The test is intensely instrumented and it has provided the opportunity to study in detail the evolution of the main THM variables over a long period of time. Comprehensive laboratory tests carried out in the context of the FEBEX and NF‐PRO projects have allowed the identification of the model parameters to describe the THM behaviour of the compacted expansive clay. A conventional THM approach that assumes the swelling clay as a single porosity medium has been initially adopted to analyse the evolution of the test. The model was able to predict correctly the global THM behaviour of the clay barrier in the short term (i.e. for times shorter than three years), but some model limitations were detected concerning the prediction of the long‐term hydration rate. An additional analysis of the test has been carried out using a double structure model to describe the actual behaviour of expansive clays. The double structure model explicitly considers the two dominant pore levels that actually exist in the FEBEX bentonite and it is able to account for the evolution of the material fabric. The simulation of the experiment using this enhanced model provides a more satisfactory reproduction of the long‐term experimental results. It also contributes to a better understanding of the observed test behaviour and it provides a physically based explanation for the very slow hydration of the barrier. Copyright © 2011 John Wiley & Sons, Ltd.     

Suction-controlled experiments on Boom clay

The understanding of the thermo-hydro-mechanical behaviour of a clay barrier is needed for the prediction of its final in situ properties after the hydration and thermal transient in a radioactive waste repository.

As part of the CEC 1990–1994 R&D programme on radioactive waste management and storage, the CEA (Fr), CIEMAT (Sp), ENRESA (Sp), SCK · CEN (B), UPC (Sp) and UWCC (UK) have carried out a joint project on unsaturated clay behaviour (Volckaert et al., 1996). The aim of the study is to analyse and model the behaviour of a clay-based engineered barrier during its hydration phase under real repository conditions. The hydro-mechanical and thermo-hydraulic models developed in this project have been coupled to describe stress/strain behaviour, moisture migration and heat transfer. A thermo-hydraulic model has also been coupled to a geochemical code to describe the migration and formation of chemical species.

In this project, suction-controlled experiments have been performed on Boom clay (B), FoCa clay (Fr) and Almeria bentonite (Sp). The aim of these experiments is to test the validity of the interpretive model developed by Alonso and Gens (Alonso et al., 1990), and to build a database of unsaturated clay thermo-hydro-mechanical parameters. Such a database can then be used for validation exercises in which in situ experiments are simulated.

The Boom clay is a moderately swelling clay of Rupellian age. It is studied at the SCK · CEN in Belgium as a potential host rock for a radioactive waste repository. In this paper, suction-controlled experiments carried out on Boom clay by SCK · CEN are described. SCK · CEN has performed experiments to measure the relation between suction, water content and temperature and the relation between suction, stress and deformation. The applied suction-control techniques and experimental setups are detailed. The results of these experiments are discussed in the perspective of the model of Alonso and Gens. The influence of temperature on water uptake was rather small. The measured swelling-collapse behaviour can be explained by the Alonso and Gens model.     

Numerical modeling of reservoirs or pipes in groundwater seepage

In groundwater studies, the numerical modeling of complex boundary conditions can be made easier by considering reservoirs and pipes as “reservoir” finite elements, which can store or release large volumes of water at almost constant hydraulic head. The numerical code to be used must solve the complete conservation equation with unlinked functions for the water retention curve and the unsaturated hydraulic conductivity, and the ability to describe these as step functions. Four examples illustrate the performance of the “reservoir” element: reservoir pumping, laboratory variable-head permeability test, vertical flow in an open borehole, and pumping test with well storage.     

Processing map and well log data for geological and soil surveys

Design of a system which accepts geological maps or soil maps, together with corresponding well logs and produces interpretation maps, is described. The major aim was to get a processing program that would be useful at an operational scale that avoids the use of special purpose graphics hardware. This was achieved by using segment encoding of lines and by treatment of mapped units as basic graphical units (atoms). The system operation was split into an input phase and a processed phase. Input- and file-building require some technical experience, but are a one-time affair, whereas subsequent processing requires less (graphical) resources and experience, but is of a repetitive nature. When writing processing programs, emphasis was placed on ease of adding options. Clever improvements of efficiency (e.g., disk traffic) were not deemed worthwhile or even wise. Two driving forces behind the project required the programs reported here. First was the observation that digital data can be used only if appropriate programs are readily available to produce required results without need for large investments in hardware. Second was the idea that digital tools could be most effective if they allow the end-user (customer) to interact directly with the full base of data without recourse to technical experts. The resulting system is operational and running on a VAX 11/750, coded in FORTRAN.     

Antimony in the environment: Lessons from geochemical mapping

The distribution of Sb in a variety of sample materials, including soils, plants and surface water, was studied at different scales, from continental to local, combining published data sets with the aim of delineating the impact and relative importance of geogenic vs. anthropogenic Sb sources. Geochemical mapping demonstrates that variation is high at all scales – from the detailed scale with sample densities of many sites per km² to the continental-scale with densities of 1 site per 5000 km². Different processes govern the Sb distribution at different scales. A high sample density of several samples per km² is needed to reliably detect mineralisation or contamination in soil samples. Median concentrations are so low for Sb in most sample materials (below 1 mg/kg in rocks and soils, below 0.1 mg/kg in plants, below 0.1 μg/L in surface water) that contamination is easier to detect than for many other elements. Distribution patterns on the sub-continental to continental-scale are, however, still dominated by natural variation. Given that the geochemical background is characterised by a high variation at all scales, it appears impossible to establish a reliable single value for “good soil quality” or a “natural background concentration” for Sb for any sizeable area, e.g., for Europe. For such a differentiation, geochemical maps at a variety of scales are needed.     

Domesticating home anchored work: Negotiating flexibility when bringing ICT based work home in rural communities

Based on a study of people conducting ICT based work from home in Scotland and Norway, the article analyses how work is negotiated and integrated with non-paid activities in the household and local community. The article fills a gap in that it focuses on rural contexts rather than the urban work life often depicted in literature on flexibility and work. When work is brought home, a domestication process takes place whereby practices of work are negotiated and integrated into everyday life, sometimes changing common perceptions of where and when work is “in” or “out of place”. While working from home is common in rural areas, the study shows that ICT based knowledge related work is still seen as relatively “out of place”. Drawing on the domestication concept, the study shows how community norms about accessibility, interaction and where to be at certain times, had to be renegotiated when this type of work was conducted from home. Imbued in these negotiations were subtly often tacitly communicated moral conceptions on what constitutes good parenthood (in particular motherhood) as well as “real” work. Both men and women reported benefits in terms of combining family and work obligations when working from home, but the tendency was still for traditional gender patterns to be reproduced. Women tended to fit work around the needs of the children, whereas men saw themselves first and foremost workers. Following the concept “doing gender” some challenged these patterns, but did so carefully in relation to the work organisation as well as the community. The impact of communities in regulating home anchored work suggests there may be a need for communities to take on a more active domestication process as more people conduct ICT based work with the home as the base, opening up the moral and normative geographies for when work is “in” or “out of place”.     

How to speak for aquifers and people at the same time: Environmental justice and counter-network formation at a hazardous waste site

A common source of conflict at hazardous waste sites in the US Environmental Protection Agency’s Superfund program is the accuracy of scientific investigations and representations produced to inform cleanup decisions. Liable firms often produce these technical representations themselves, and communities surrounding sites frequently argue that such “voluntary” investigations are compromised by conflicts of interest. In order to challenge the representations of powerful firms, locally situated actors often develop trans-local connections with expertise and equipment concentrated at distant centers of calculation. Although some interpret the spatial politics of such connecting in terms of “jumping scales,” another important spatial dimension of this network construction is differential positioning. In a conflict over groundwater models at the St. Regis Superfund Site in Minnesota, the counter-network that emerged to challenge the owner’s representations of the site positioned some actors as “outsiders” and others as “insiders.” This differential positioning enabled the counter-network to balance the need to demonstrate the reliability and impartiality of its claims with the requirement to maintain its accountability to local public interests. I argue that these requirements result from the prevalent view of the science-policy interface, which assumes a rigid separation between science and politics. Nonetheless, the conflict over groundwater at St. Regis reveals how at the science-policy interface, speaking for things and speaking for people are thoroughly entangled.     

Behavior of monopile foundations under cyclic lateral load

This paper describes the development and application of design charts for monopile foundations of offshore wind turbines in sandy soil under long-term cyclic lateral load. It outlines a numerical model, working with a numerical concept, which makes the calculation of accumulated displacements based on cyclic triaxial test results possible, and it describes important factors affecting the deformation response of a monopile to cyclic lateral loads. The effects of pile length, diameter and loading state on the accumulation rate of lateral deformation are presented and design charts are given, in which a normalized ultimate lateral resistance of a pile is used. For monopiles with very large diameter, the suitability of the “zero-toe-kick” and “vertical tangent” design critera for determining the required embedded length is discussed.     

Sustainability schizophrenia or “actually existing sustainabilities?” toward a broader understanding of the politics and promise of local sustainability in the US

As an approach to development, many see capitalism as reaching across an enormous range of scholarly domains and political interests. For some time geographers and others have begun to conceptualize capitalism as less of a system of intrinsic economic logic and more a collection of social and discursive relationships. By bringing capitalism into the “discursive world” these commentators and others have provided the theoretical ground for an exploration of alternative economic forms, especially those that are more socially and ecologically just. This paper makes an argument for putting sustainable development through the same theoretical scrutiny. Drawing on examples from the US we recruit the concept of “actually existing sustainabilities” from Altvater’s concept “actually existing socialisms” as an entry point to this conversation. Our purpose is to show that the potential for sustainability in the US exists in current local policies and practices if we rethink how we frame it.     

The Escanaba Trough, Gorda Ridge hydrothermal system: Temporal stability and subseafloor complexity

The composition and temperature of vent fluids sampled from the active hydrothermal system in Escanaba Trough, Gorda Ridge in 2000 and 2002 remain unchanged from the only time this field was previously sampled, in 1988. ODP Leg 169 drilled nine bore holes at this site in 1996, some within meters of the vents, yet this disturbance has not impacted the measured compositions or temperatures of the fluids exiting at the seafloor. The fluids have maximum measured temperatures of 218°C and contain ∼20% more chloride than local ambient seawater. Our interpretation is that the fluid compositions are generated by supercritical phase separation of seawater, with much of the water-rock reaction occurring within the ∼400m thick sedimentary section that overlies the basalt at this site. The ODP drilling results provide information on the mineralogy and composition of materials below the seafloor, as well as direct constraints not typically available on the physical conditions occurring below the seafloor hydrothermal system. Calculations utilizing geochemical modeling software suggest the fluids are close to saturation with a suite of minerals found subsurface, suggesting equilibrium between the fluids and substrate. These results provide an explanation for why the fluids have remained chemically stable for 14 yrs. The pore water data from drilling suggest that the hydrology and chemistry of the hydrothermal system are much more complex within the sediment cover than would be expected from the surface manifestations of the hydrothermal system. While the pore waters have chloride contents both greater and less than the local seawater, only fluids with higher chloride contents vent at the seafloor. Our calculations suggest that at the current conditions the “brines” (fluids with chlorinity greater than seawater) are actually less dense than the “vapors” (fluids with chlorinity less than seawater). These density relationships may provide an explanation for why the “brines” are now venting preferentially to the “vapors,” a situation opposite to what is usually observed or inferred.     

Internal architecture of the soft sediment cover of the South-Aquitaine shelf (Bay of Biscay): A record of high frequency sea level variations?

Very high-resolution seismic profiles highlighted three main depositional sequences of several hundred meters thick on the South-Aquitaine shelf. The youngest one, the soft sedimentary cover (U1), is presented in this article. It is composed of six seismic units deposited during the Late Quaternary and corresponds to a repetition of a sequence type. The sequence type is formed in four phases: an erosional unconformity (S), a sub-unit “a”, an internal erosional unconformity (St) and a sub-unit “b”. The first phase begins with the erosional unconformity (S), which could be formed during the sea level fall. The second phase is the deposition of the sub-unit “a”, likely during the sea level lowstand and the early sea level rise. Its acoustic facies is generally chaotic with small channels and could be filled by coarse or heterogeneous sediments. The third phase is the formation of a plane and high amplitude unconformity (St) which could be correlated with a transgressive or a wave ravinement surface. The fourth phase corresponds to the deposition, probably during the sea level rise, of the sub-unit “b” which is characterized by subparallel reflections.     

State visions, landscape, and disease: Discovering malaria in Argentina, 1890-1920

Recently, geographers and other scholars have reappraised the state’s spatial properties, roles, and strategies. According to these interpretations, modern states seek to control their subjects and coordinate economic development through various “rational” and “scientific” strategies that involve the standardization, transformation, and bureaucratization of space, territory, and landscape. Through this process social relations are increasingly configured through state discourses and institutions. The role of public health institutions in the development of state spatialities has been relatively underappreciated. This paper explores the establishment and early action of a malaria control campaign in Northwest Argentina, in the early twentieth century. I make three arguments: first, in creating a malaria control program, the Argentine state did not merely respond to a given “social fact” but rather was the key participant in constructing the “malaria problem”. Second, in response to this problem the Argentine state created a new technical-administrative territory, “the malarious zone”, which encompassed several provinces and defined the federal government’s jurisdiction for public health action. Finally, state actors came to understand the malaria problem, and potential solutions to it, through specific “rational” practices of the modern state: surveying, mapping, measurement, and statistical compilation. In its early years, the malaria campaign did not so much control the disease itself, as much as establish control over the “malaria question”, making it indisputably a state project.     

Identifying “free” and “bound” lipid fractions in stalagmite samples: An example from Heshang Cave,Southern China

Stalagmites are good archives for paleoecological change, as they are easy to date, and contain multiple environmental proxy records, including climatic records from oxygen isotopes. Lipid biomarkers preserved within stalagmites have recently been used to investigate changes in the overlying soil and vegetation. However, the understanding of lipid records from stalagmites is still at an early stage, and is hindered by the low abundances of lipids preserved and the complexity of the organic matter signal. Here the first results of a sequential extraction procedure are presented, that enables examination of the distribution patterns of “free” (solvent extraction) and “bound” (including physically bound within the calcite matrix and chemically bound to macromolecules) lipids in a stalagmite from southern China. In both groups the dominant compounds are saturated fatty acids, which are an order of magnitude more abundant in the “bound” phase. n-alkanes and n-alcohols chiefly appear in the “free” lipids. In contrast, 3-hydroxy acids are predominantly released under strong acid reflux conditions, suggesting a principal input from bacterial membrane compounds. A direct comparison between the present results and the published data from an Ethiopian stalagmite shows significant differences in the lipid signals from separate sites, with a stronger microbial signal in the Chinese sample. This preliminary investigation of lipid distributions in different modes highlights the importance of microbial geochemical processes in karst systems and supports the use of stalagmites in paleoecological reconstruction.     

Should political ecology be Marxist? A case for Gramsci’s historical materialism

This paper investigates some aspects of political ecology’s relation to Marxism, specifically its ties to Marxism’s “historical materialism”. I argue Gramsci is an essential feature in the reinvigoration of that relation, and that political ecology should be Marxist, if by Marxist we mean Gramscian. I focus on the concept of hegemony, arguing that Gramsci’s historical materialism, in contrast to the Engelsian tradition within which most materialism is snared, allows us to take account of both moments in Gramsci’s hegemony, the “economic” and the “ethicopolitical”.     

Immobilization of Ni by Al-modified montmorillonite: A novel uptake mechanism

The sorption capacity of montmorillonite clay minerals for small cations, such as Ni²⁺, can be greatly enhanced by modifying the clay mineral with Al(III). In this study, the mechanisms of Ni uptake by Al-modified montmorillonite were studied using extended x-ray absorption fine structure (EXAFS) spectroscopy of powders and polarized EXAFS spectroscopy of self-supporting clay films to delineate the binding structure of Ni formed as a function of the reaction conditions. Analysis of powder EXAFS spectra of wet pastes, collected from Ni-treated Al-modified montmorillonites reacted at pH 5-8, 25°C or 80°C (to accelerate the reaction process), and reaction times ranging from 1 month to 9 yrs, showed that Ni was surrounded on average by 6 O atoms at a distance of 2.05 Å and 6 Al atoms at 3.01 Å, suggesting the incorporation of Ni into a gibbsite-like structure. Only at pH 8, Ni-containing precipitates were congruently formed. Polarized EXAFS spectroscopy of self-supporting Ni-reacted Al-modified montmorillonite clay films showed a pronounced angular dependency of the spectra of the Ni-doped gibbsite, indicating that the orientation of this Ni-doped gibbsite coincided with the layering of the montmorillonite. Data analysis suggested that Ni is included slightly above and below the vacant octahedral sites of the postulated interstitial gibbsite monolayer. This newly identified mechanism of metal uptake by Al-modified montmorillonite provides a large metal sorption capacity and, because the metal is included in a monolayer gibbsite or gibbsite “islands” formed in the interstitial space of the clay mineral, it potentially leads to a permanent sequestration of the metal from the environment.