Observations of nitric acid perturbations in the winter Arctic stratosphere: Evidence for PSC sedimentation

Gaseous nitric acid (HNO3) and hydrogene fluoride (HF) have been measured in the winter Arctic stratosphere using balloon- and aircraft-based Ion Molecule Reaction Mass Spectrometry (IMRMS) instruments. Strong HNO3 perturbations were found in 1993 and 1995 which may indicate nitrification around 11-13 km and denitrification around 20 km altitude. Most likely these perturbations were caused by sedimentation of HNO3 containing aerosols followed by aerosol evaporation at lower altitudes.     

拉萨地区1998年夏季臭氧总量及垂直廓线的观测研究

该文根据1998年6~10月上旬在拉萨地区进行的臭氧总量及臭氧垂直廓线的观测结果, 并结合同期同纬度其他两个臭氧站数据资料, 证实了以拉萨地区为代表的青藏高原在夏季存在“臭氧低谷”的现象.分析表明, 地基和卫星观测的臭氧总量有一定误差. Umkehr观测反演结果表明夏季拉萨地区平流层臭氧分布和同纬度其他地区相比略有不同; 在对流层, 探空资料显示了该地区对流层臭氧有低值分布的特征.     

In situ Measurement of H2O and CH4 with Telecommunication Laser Diodes in the Lower Stratosphere: Dehydration and Indication of a Tropical Air Intrusion at Mid-Latitudes

Telecommunication laser diodes emitting near 1.39 m and 1.65 m in combination with direct-differential absorption spectroscopy are efficient tools to monitor in situ stratospheric H₂O andCH₄ with a good precision error (a few percents), a high temporal resolution (ranging from 10 ms to 1 s), a large dynamic range in the concentration measurements (four orders of magnitude) and a high selectivity in the analyte species. To illustrate the capability of laser probing technique, we report balloonborne H₂Oand CH₄ simultaneous measurements obtained on October 2001 atmidlatitudes (43° N). The H₂O vertical profile achieved with the lasersensor in the lower stratosphere is compared with the H₂O data yielded by a balloonborne frost-point hygrometer. The total hydrogen mixing ratio in the lower stratosphere, 2[CH₄] + [H₂O], appears to beconstant at 7.5 ± 0.1 ppmv. Nevertheless, an unexpected largedehydration of 0.5 ppmv was detected by both the laser sensor and thehygrometer between 16 km and 23 km. We suspect the occurrence of a tropicalair intrusion into mid-latitudes. We support this interpretation using a high-resolution advection model for potential vorticity.     

Ozone Vertical Profile Characteristics over Qinghai Plateau Measured by Electrochemical Concentration Cell Ozonesondes

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A study of the vertical distribution of methyl chloride (CH3Cl) in the midlatitude stratosphere

The vertical distribution of the CH₃Cl mixing ratio in the stratosphere has been measured from samples collected during two balloon flights on the 21 October 1982 and 10 September 1983. Measurements were made with two analytical techniques that were also employed for previous analyses of stratospheric samples: gas chromatography (GC) and a gas chromatograph/mass spectrometer (GC/MS) combination. The results from all balloon flights performed to date are combined to derive an average experimental profile of CH₃Cl at midlatitudes. The profile shows that the CH₃Cl mixing ratio decreases by about one order of magnitude between 20 and 30 km altitude. A comparison of the new observations with model profiles reveals discrepancies in the lower stratosphere that amount to a factor of about 3. Possible causes for these discrepancies are discussed.     

Cumulus mergers in the maritime continent region

Summary We examine a family of tall (up to 20 km) cumulonimbus complexes that develop almost daily over an adjacent pair of flat islands in the Maritime Continent region north of Darwin, Australia, and that are known locally as Hectors. Nine cases observed by a rawinsonde network, surface observations (including radiation and soil measurements), the TRMM/TOGA radar, and one day of aircraft photography are used to analyse the development, rainfall, surface energy budgets, and vertical structure of these convective systems.The systems undergo convective merging which is similar to that observed in previous Florida studies and is multiplicative in terms of rainfall. About 90% of the total rainfall comes from the merged systems, which comprise less than 10% of convective systems, and this has implications for the manner in which tropical rainfall is parameterised in largerscale numerical models. By comparison to the West Indies, GATE, and Florida, the Hector environment contains a weaker basic flow, with less vertical shear. The main thermodynamic difference is that the Darwin area has an unstable upper troposphere and very high tropopause. Numerical modelling results support earlier observations of updraughts in excess of 30 ms^–1 in this region, but show that only modest convective drafts are experienced below the freezing level (5 km).The surface fluxes over the islands are estimated from a Monash University study to be mainly in latent form from evapotranspiration, with a Bowen ratio only slightly larger than that commonly observed over oceans. These surface fluxes are crucial to the development of a suitable mixed layer to support deep convection. The flux estimates agree with the observed changes below the cloud base and provide sufficient information for calculations of the bounds on precipitation efficiency. Of particular interest are the observations of Hector development on a day when the islands were under a dense cirrus overcast. We find that the islands still provide sufficient net sensible and latent heat fluxes to initiate convection.With 10 Figures     

The APE-THESEO Tropical Campaign: An Overview

The APE-THESEO campaign was held from 15 February to 15 March 1999 from the Seychelles in the western Indian Ocean. APE-THESEO stands for Airborne Platform for Earth observation — (contribution to) the Third European Stratospheric Experiment on Ozone. The campaign aimed to study processes controlling the low water content of the stratosphere, including the mechanisms of cloud formation in the tropical tropopause region, and transport processes, studied using measurements of long-lived trace gases and ozone.Two aircraft were used: the high-altitude research aircraft, M-55 Geophysica, which can fly up to 21 km, and the Falcon of the Deutsches Zentrum für Luft- und Raumfahrt, a tropospheric aircraft. Seven flights were performed, including the first simultaneous in situ and remote sensing of sub-visible cirrus clouds, the first interception of sub-visible cirrus using in-flight guidance from a path-finding aircraft, and guided descent of a high-altitude research aircraft into the anvil cloud at the top of a tropical cyclone. In this paper we describe the payload used, the objectives for each flight, and the meteorological conditions encountered. First results show that a new type of cloud, which we have dubbed ultra-thin tropical tropopause cloud (UTTC), has been observed frequently, and observed to cover areas of 10⁵ km². The frequent coincidence of the tropopause and hygropause implies that the western Indian Ocean played an important role in the dehydration of the lower tropical stratosphere during the season of the mission. UTTCs, sub-visible cirrus, and visible cirrus, have all been implicated in the observed dehydration. Tracer measurements indicate little mixing of stratospheric air into the upper tropical troposphere.     

Measurements of stratospheric chlorine monoxide (ClO) from groudbased FTIR observations

Infrared absorption features due to ClO in the lower stratosphere have been identified from groundbased solar absorption spectra taken from Aberdeen, U.K. (57° N, 2° W) on 20 January 1995. A vertical column abundance of 3.42 (±0.47)×10¹⁵ molec cm^-2 has been derived from 13 independent absorption features in the P and R branches of the (0–1) vibration-rotation band of ³⁵ClO, spanning the spectral region 817–855 cm^-1. The observed absorption features are consistent with very high levels of ClO (approximately 2.6 parts per billion by volume (ppbv)) in the altitude range 16–22 km. A comparison of this profile with a 3D chemical transport model profile indicates the observation was made inside the polar vortex and shows good qualitative agreement but the model underestimates the concentrations of ClO. Simultaneous measurements of other species were made including HCl, HF and ClONO₂. These columns yield a value for HCl+ClONO₂+ClO of 7.02±0.65×10¹⁵ molec cm^-2. This is lower than the total inorganic chlorine (ClO _y ) column of 10.7±1.6×10¹⁵ molec cm^-2 estimated from mean measured (HCl+ClONO₂)/HF ratios together with in-vortex HF measurements. The discrepancy is probably due to significant amounts of the ClO dimer (Cl₂O₂) in the lower part of the stratosphere. The measurements of highly elevated levels of ClO are used to estimate O₃ loss rates at the 400, 475 and 550 K levels making assumptions about the probable distribution of ClO and Cl₂O₂. These are compared with loss rates derived from ozone sonde data.     

SWIFT-DASH: Spatial Heterodyne Spectroscopy Approach to Stratospheric Wind and Ozone Measurement

Abstract

Passive wind measurements using Doppler shifts from atmospheric emissions were well demonstrated by the Wind Imaging Interferometer (WINDII) and the High Resolution Doppler Imager (HRDI) instruments on the National Aeronautics and Space Administration's (NASA's) Upper Atmosphere Research Satellite, operated from 1991 to 2005. For WINDII these emissions were from visible region upper atmospheric airglow in the altitude range from 80 to 300?km. Application of the same technique in the stratosphere requires using thermal emission from a minor constituent, and an ozone line near 1133?cm^?1 (about 8.8?μm) has been identified as a suitable target line. The WINDII method employed a Doppler Michelson Interferometer, in which the wind is measured from phase shifts of a single spectral line. Isolating a single ozone spectral line is a major challenge but using Spatial Heterodyne Spectroscopy (SHS) offers a way to resolve a number of interferogram spectral components (fringes) within a narrow spectral range. The instrument is a Michelson interferometer similar to WINDII but one in which the two mirrors are replaced by diffraction gratings. A developmental instrument capable of measuring the phase shifts from several ozone lines within a spectral range of 4?cm^?1 has been designed, built, and operated in the laboratory. Simulated retrievals using the measurement parameters of this instrument demonstrate the capability of wind measurement with an accuracy better than 3?m?s^?1 over an altitude range of 24 to 60?km. The retrieval employs four spectral lines for wind and three fringe frequencies for ozone concentration (of about 30 possible), each of which provides an optimal measurement for a particular altitude range. Ozone concentrations are also provided with an accuracy better than 10% from 20 to 50?km. Further detailed tests of this instrument are planned for the future. This work is supported by the Canadian Space Agency.     

A wind-tunnel study of turbulent flow close to regularly arrayed rough surfaces

Recent observations of flux-gradient anomalies in atmospheric flow close to forests, and similar rough surfaces, prompted a wind-tunnel investigation in which cross-wire anemometry was used to study the vertical development and horizontal variability of adiabatic flow over five regularly arrayed rough surfaces, encompassing a 32-fold range of roughness concentration . The roughness elements were cylinders, 6 mm in both height and diameter.Below a layer in which the velocity profile is semi-logarithmic, two surface influences upon the mean velocity field can be distinguished: wake diffusion and horizontal inhomogeneity. The wake diffusion effect causes non-dimensional vertical velocity gradients to be smaller than in the semi-logarithmic region; at least for elements with aspect ratios l/h 1, it is governed by the transverse dimension l of the roughness elements, and is observed when z > h + 1.5l (where z is height above the underlying surface, and h is the height of the roughness elements). A simple diffusivity model successfully describes the horizontally averaged velocity profiles in the region of wake influence, despite conceptual disadvantages. The horizontal inhomogeneity of the flow is negligible when z > h + D (D being the inter-element spacing), and does not entirely mask the wake diffusion effect except over very sparsely roughened surfaces ( 0.02). A criterion for negligibility of both effects, and hence for applicability of conventional turbulent diffusivity theory for momentum, is z > h + 1.5D. These results are compared with atmospheric data, and indicate that wake diffusion may well cause some underestimation of the zero-plane displacement d over typical vegetated surfaces.     

Assessing 4D-VAR for dynamical mapping of coastal high-frequency radar in San Diego

The problem of dynamically mapping high-frequency (HF) radar radial velocity observations is investigated using a three-dimensional hydrodynamic model of the San Diego coastal region and an adjoint-based assimilation method. The HF radar provides near-real-time radial velocities from three sites covering the region offshore of San Diego Bay. The hydrodynamical model is the Massachusetts Institute of Technology general circulation model (MITgcm) with 1 km horizontal resolution and 40 vertical layers. The domain is centered on Point Loma, extending 117 km offshore and 120 km alongshore. The reference run (before adjustment) is initialized from a single profile of T and S and is forced with wind data from a single shore station and with zero heat and fresh water fluxes. The adjoint of the model is used to adjust initial temperature, salinity, and velocity, hourly temperature, salinity and horizontal velocities at the open boundaries, and hourly surface fluxes of momentum, heat and freshwater so that the model reproduces hourly HF radar radial velocity observations. Results from a small number of experiments suggest that the adjoint method can be successfully used over 10-day windows at coastal model resolution. It produces a dynamically consistent model run that fits HF radar data with errors near the specified uncertainties. In a test of the forecasting capability of the San Diego model after adjustment, the forecast skill was shown to exceed persistence for up to 20 h.     

Ballon-borne and aircraft infrared measurements of ethane (C2H6) in the upper troposphere and lower stratosphere

Quantitative infrared measurements of ethane (C₂H₆) in the upper troposphere and lower stratosphere are reported. The results have been obtained from the analysis of absorption features of the ₉ band at 12.2 m, which have been identified in high-resolution ballon-borne and aircraft solar absorption spectra. The ballon-borne spectral data were recorded at sunset with the 0.02 cm^-1 resolution University of Denver interferometer system from a float altitude of 33.5 km near Alamogordo, New Mexico, on 23 March 1981. The aircraft spectra were recorded at sunset in July 1978 with a 0.06 cm^-1 resolution interferometer aboard a jet aircraft at 12 km altitude, near 35°N, 96°W. The balloon analysis indicates the C₂H₆ mixing ratio decreased from 3.5 ppbv near 8.8 km to 0.91 ppbv near 12.1 km. The results are consistent with the colum value obtained from the aircraft data.     

Chlorine-hydrocarbon photochemistry in the marine troposphere and lower stratosphere

A one-dimensional photochemical model was used to explore the role of chlorine atoms in oxidizing methane and other nonmethane hydrocarbons (NMHCs) in the marine troposphere and lower stratosphere. Where appropriate, the model predictions were compared with available measurements. Cl atoms are predicted to be present in the marine troposphere at concentrations of approximately 10³ cm^-3, mostly as a consequence of the reaction of OH with HCl released from sea spray. Despite this low abundance, our results indicate that 20 to 40% of NMHC oxidation in the troposphere (0–10 km) and 40 to 90% of NMHC oxidation in the lower stratosphere (10–20 km) is caused by Cl atoms. At 15 km, NMHC-Cl reactions account for nearly 80% of the PAN produced.The model was also used to test the longstanding hypothesis that NOCl is an intermediate to HCl formation from sea salt aerosols. It was found that the NOCl concentration required (10 ppt) would be incompatible with field observations of reactive nitrogen and ozone abundance. Chlorine nitrate (ClONO₂) and methyl nitrate (CH₃ONO₂) were shown to be minor components of the total NO _y abundance. Heterogeneous reactions that might enhance photolysis of halocarbons or convert ClONO₂ to HOCl or Cl₂ were determined to be relatively unimportant sources of Cl atoms. Specific and reliable measurements of HCl and other reactive chlorine species are needed to better assess their role in tropospheric chemistry.     

On the Temporal and Spatial Structure of Troposphere-to- Stratosphere Transport in the Lowermost Stratosphere over the Asian Monsoon Region during Boreal Summer

This study produced a novel characterization of the troposphere-to-stratosphere transport(TST) over the Asian monsoon region during boreal summer,using a comprehensive analysis of 60-day backward trajectories initialized in the stratosphere.The trajectory datasets were derived from the high-resolution Lagrangian particle dispersion model(FLEXPART) simulation driven by the wind fields acquired from the National Center for Environmental Prediction(NCEP).The results indicate that the distribution of residence time(tTST) of tropopause-crossing trajectories in the lowermost stratosphere represents a horizontal signature of the Asian summer monsoon.Vertically,the distribution of tTST can be roughly separated into two layers:a consistent lower layer with tTST <5 days forming a narrow band,corresponding to a layer～3 km thick following the location of the tropopause,and an upper layer at a larger distance from the local tropopause.The maximum residence time was～20 days,especially within the Asian high anticyclone consistent with its confinement effects.In general,the overall geographical distribution of dehydration points was not coincident with the location of tropopause crossing.TST trajectories,which were initialized in the stratosphere,underwent their Lagrangian cold points mostly in the tropics and subtropics 1-4 days after the TST event;they were characterized by a wide range of temperature differences,with a mean value of 3-12 K.The vertical extent of the influence of tropospheric intrusion on the Asian monsoon region in the stratosphere exhibited a peak at～16.5-18.5 km,and the uppermost height was～21 km.     

Upper Limit of Iodine Oxide in the Lower Stratosphere

It has been suggested that iodine oxides, IOx, could play a significant role in the ozone destruction in the lower stratosphere. To investigate this suggestion, spectra from nine SAOZ uv-visible spectrometer balloon flights were examined for the IO absorption signature between 405 and 450 nm. IO was not detected, either at mid- or high latitude, in the morning or the evening, in summer or winter. An upper limit of 0.2 parts per trillion by volume (pptv) at 20 km and 0.1 pptv at 15 km at the 95% confidence level (2), was derived from the best measurements at 90° SZA at sunset and sunrise. Since a photochemical model shows that 70% of inorganic iodine should be in the form IO at that time, it is concluded that unless iodine chemistry is different from that assumed at the moment, the role of iodine in stratospheric ozone depletion is small.     

Assessing 4D-VAR for dynamical mapping of coastal high-frequency radar in San Diego

The problem of dynamically mapping high-frequency (HF) radar radial velocity observations is investigated using a three-dimensional hydrodynamic model of the San Diego coastal region and an adjoint-based assimilation method. The HF radar provides near-real-time radial velocities from three sites covering the region offshore of San Diego Bay. The hydrodynamical model is the Massachusetts Institute of Technology general circulation model (MITgcm) with 1 km horizontal resolution and 40 vertical layers. The domain is centered on Point Loma, extending 117 km offshore and 120 km alongshore. The reference run (before adjustment) is initialized from a single profile of T and S and is forced with wind data from a single shore station and with zero heat and fresh water fluxes. The adjoint of the model is used to adjust initial temperature, salinity, and velocity, hourly temperature, salinity and horizontal velocities at the open boundaries, and hourly surface fluxes of momentum, heat and freshwater so that the model reproduces hourly HF radar radial velocity observations. Results from a small number of experiments suggest that the adjoint method can be successfully used over 10-day windows at coastal model resolution. It produces a dynamically consistent model run that fits HF radar data with errors near the specified uncertainties. In a test of the forecasting capability of the San Diego model after adjustment, the forecast skill was shown to exceed persistence for up to 20 h.     

Measurements of fluctuations of vertical wind velocity,temperature and radio-refractive index above the sea

Mean spectra of vertical wind velocity, temperature, and humidity and co-spectra of vertical turbulent heat and moisture fluxes are reported, normalized in terms of the similarity theory of Monin-Obukhov. The measurements were made in April 1967 at light-house Alte Weser at a height of 30 m above the German Bight. Ten spectra measured under conditions of moderate instability (z/L –0.08) have been used for the evaluation of a mean spectral curve. The humidity fluctuations have been determined from simultaneous turbulence measurements of temperature and radiorefractive-index, which were obtained by a microwave refractometer.Similar to the BOMEX measurements discussed by Phelps and Pond (1971) our results also show a dissimilarity between the fluctuations of temperature and humidity. Accordingly, in the range of lower and higher natural frequencies, significant differences were present between the co-spectra of the vertical heat and moisture fluxes, although the mean peak frequencies of both the fluxes nearly correspond to that of the mean vertical wind-velocity spectrum (f _m 0.35).     

Application of the Priestley-Taylor evaporation model to assess the influence of soil moisture on the evaporation from a large weighing lysimeter and class a pan

The influence of soil moisture on evaporation from a 6-m grass-covered lysimeter and from Class A pans was assessed for one summer using the -parameter of the Priestley-Taylor evaporation model appropriate for the individual surfaces computed on a daily basis. Net radiation over the pan was estimated from above-grass measurements using a correlation established between the two, using measurements made in the previous two summers. Changes in heat storage of the water were considered in the derivation of for the pan. A unique relationship for the particular conditions of the site was determined between the for the lysimeter and soil moisture, approaching 1.29 at soil moisture near field capacity, but decreasing to as low as 0.5 for dry soil. The corresponding relationship for the pan showed more scatter, but this was improved by using 5-day running means of evaporation and stratifying the data in terms of wind speed to yield a family of curves. Values for at wet soil conditions varied from 1.07 for 100 km day^–1 wind run to 1.17 for 250 km day^–1 wind run. For each curve, values of increased by about 20%; as the soil dried. The relationships may be used to reduce observed Class A pan evaporation to equivalent values for wet-soil conditions and to estimate near-surface soil moisture and actual evapotranspiration for this particular site. Extension of the technique to other areas requires derivation of similar relationships appropriate for those other locations     

Retrieval of tropospheric co profiles using correlation radiometer: I. retrieval experiments for a clear atmosphere

This paper discusses the retrieval scheme associated with the gas correlated radiometer- MOPITT which will be on board of EOS-AM1 to measure the global vertical profiles of car-bon monoxide. The vertical resolution and retrieval errors caused by errors in the temperature profiles and in the surface temperature have been assessed. The main results are: a. Assuming the noise equivalent radiance (NER) of 1.8 × 105 W m-2 sr-1, the surface tem?perature can be deduced from the wide band signals with uncertainly less than 1 K, and the atmospheric term of the modulated signal can be deduced with errors almost equal to the NER which does not significantly increase errors in the retrieved CO profiles. b. With typical uncertainty in temperature profiles, errors in the retrieved profiles at lati-? tudes lower than 70o are generally less than 20% with the first guess of 100 ppbv. (If a better first guess was used, the errors may decrease). c. By incorporating the total column CO amount derived from the reflected solar radiation in 2.3 μm spectral region into the retrieval, the accuracy of the retrieved CO profile below 6 km may be greatly improved. d. In the retrieval experiment with 10 CO profiles representing the typical CO profiles, the r.m.s. relative / absolute errors of the retrieved CO profiles are about 10% / 15-20 ppbv.