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1.
We report the oxygen isotope composition of olivine and orthopyroxene phenocrysts in lavas from the main magma types at Mt
Shasta and Medicine Lake Volcanoes: primitive high-alumina olivine tholeiite (HAOT), basaltic andesites (BA), primitive magnesian
andesites (PMA), and dacites. The most primitive HAOT (MgO > 9 wt%) from Mt. Shasta has olivine δ18O (δ18OOl) values of 5.9–6.1‰, which are about 1‰ higher than those observed in olivine from normal mantle-derived magmas. In contrast,
HAOT lavas from Medicine Lake have δ18OOl values ranging from 4.7 to 5.5‰, which are similar to or lower than values for olivine in equilibrium with mantle-derived
magmas. Other magma types from both volcanoes show intermediate δ18OOl values. The oxygen isotope composition of the most magnesian lavas cannot be explained by crustal contamination and the trace
element composition of olivine phenocrysts precludes a pyroxenitic mantle source. Therefore, the high and variable δ18OOl signature of the most magnesian samples studied (HAOT and BA) comes from the peridotitic mantle wedge itself. As HAOT magma
is generated by anhydrous adiabatic partial melting of the shallow mantle, its 1.4‰ range in δ18OOl reflects a heterogeneous composition of the shallow mantle source that has been influenced by subduction fluids and/or melts
sometime in the past. Magmas generated in the mantle wedge by flux melting due to modern subduction fluids, as exemplified
by BA and probably PMA, display more homogeneous composition with only 0.5‰ variation. The high-δ18O values observed in magnesian lavas, and principally in the HAOT, are difficult to explain by a single-stage flux-melting
process in the mantle wedge above the modern subduction zone and require a mantle source enriched in 18O. It is here explained by flow of older, pre-enriched portions of the mantle through the slab window beneath the South Cascades. 相似文献
2.
Sara Auer Ilya Bindeman Paul Wallace Vera Ponomareva Maxim Portnyagin 《Contributions to Mineralogy and Petrology》2009,157(2):209-230
Klyuchevskoy volcano, in Kamchatka’s subduction zone, is one of the most active arc volcanoes in the world and contains some
of the highest δ18O values for olivines and basalts. We present an oxygen isotope and melt inclusion study of olivine phenocrysts in conjunction
with major and trace element analyses of 14C- and tephrochronologically-dated tephra layers and lavas spanning the eruptive history of Klyuchevskoy. Whole-rock and groundmass
analyses of tephra layers and lava samples demonstrate that both high-Mg (7–12.5 wt% MgO) and high-Al (17–19 wt% Al2O3, 3–6.5 wt% MgO) basalt and basaltic andesite erupted coevally from the central vent and flank cones. Individual and bulk
olivine δ18O range from normal MORB values of 5.1‰ to values as high as 7.6‰. Likewise, tephra and lava matrix glass have high-δ18O values of 5.8–8.1‰. High-Al basalts dominate volumetrically in Klyuchevskoy’s volcanic record and are mostly high in δ18O. High-δ18O olivines and more normal-δ18O olivines occur in both high-Mg and high-Al samples. Most olivines in either high-Al or high-Mg basalts are not in oxygen
isotopic equilibrium with their host glasses, and Δ18Oolivine–glass values are out of equilibrium by up to 1.5‰. Olivines are also out of Fe–Mg equilibrium with the host glasses, but to a lesser
extent. Water concentrations in olivine-hosted melt inclusions from five tephra samples range from 0.4 to 7.1 wt%. Melt inclusion
CO2 concentrations vary from below detection (<50 ppm) to 1,900 ppm. These values indicate depths of crystallization up to ~17
km (5 kbar). The variable H2O and CO2 concentrations likely reflect crystallization of olivine and entrapment of inclusions in ascending and degassing magma. Oxygen
isotope and Fe–Mg disequilibria together with melt inclusion data indicate that olivine was mixed and recycled between high-Al
and high-Mg basaltic melts and cumulates, and Fe–Mg and δ18O re-equilibration processes were incomplete. Major and trace elements in the variably high-δ18O olivines suggest a peridotite source for the parental magmas. Voluminous, highest in the world with respect to δ18O, and hydrous basic volcanism in Klyuchevskoy and other Central Kamchatka depression volcanoes is explained by a model in
which the ascending primitive melts that resulted from the hydrous melt fluxing of mantle wedge peridotite, interacted with
the shallow high-δ18O lithospheric mantle that had been extensively hydrated during earlier times when it was part of the Kamchatka forearc. Following
accretion of the Eastern Peninsula terrains several million years ago, a trench jump eastward caused the old forearc mantle
to be beneath the presently active arc. Variable interaction of ascending flux-melting-derived melts with this older, high-δ18O lithospheric mantle has produced mafic parental magmas with a spectrum of δ18O values. Differentiation of the higher δ18O parental magmas has created the volumetrically dominant high-Al basalt series. Both basalt types incessantly rise and mix
between themselves and with variable in δ18O cumulates within dynamic Klyuchevskoy magma plumbing system, causing biannual eruptions and heterogeneous magma products.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
3.
We have conducted high pressure (to 3 kbar), water saturated melting experiments on an andesite (62 wt% SiO2) and a basaltic andesite (55 wt% SiO2) from western Mexico. A close comparison between the experimental phase assemblages and their compositions, and the phenocryst
assemblages of the lavas, is found in water saturated liquids, suggesting that the CO2 content was minimal in the fluid phase. Thus the historic lavas from Volcan Colima (with phenocrysts of orthopyroxene, augite,
plagioclase, and hornblende) were stored at a temperature between 950–975 °C, at a pressure between 700–1500 bars, and with
a water content of 3.0–5.0 wt%. A hornblende andesite (spessartite) from Mascota, of nearly identical composition but with
only amphibole phenocrysts, had a similar temperature but equilibrated at a minimum of 2000 bars pressure with a dissolved
water content of at least 5.5 wt% in the liquid. Experiments on the basaltic andesite show that the most common natural phenocryst
assemblages (olivine, ±augite, ±plagioclase) could have precipitated at temperatures from 1000–1150 °C, in liquids with a
wide range of dissolved water content (∼2.0–6.0 wt%) and a corresponding pressure range. A lava of the same bulk composition
with phenocrysts of hornblende, olivine, plagioclase, and augite is restricted to temperatures below 1000 °C and pressures
below 2500 bars, corresponding to <5.5 wt% water in the residual liquid. Although there is some evidence for mixing in the
andesites (sporadic olivine phenocrysts), the broad theme of the history of both lava types is that the phenocryst assemblages
for both the andesitic magmas and basaltic andesitic magmas are generated from degassing and reequilibration on ascent of
initially hydrous parents containing greater than 6 wt% water. Indeed andesitic magmas could be related to a basaltic andesite
parent by hornblende-plagioclase fractionation under the same hydrous conditions.
Received: 10 December 1996 / Accepted: 21 August 1997 相似文献
4.
S. N. Feldstein Rebecca A. Lange Torsten Vennemann James R. O'Neil 《Contributions to Mineralogy and Petrology》1996,126(1-2):51-66
Complete chemical analyses, including ferric and ferrous iron, H2O contents and δD values for 16 phlogopite and biotite and 2 hornblende separates are presented. Samples were obtained from
volcanic rocks from four localities: (1) phlogopite phenocrysts from minette lavas from the western Mexico continental arc,
(2) biotite and hornblende phenocrysts from andesite lavas from Mono Basin, California, (3) phlogopite and biotite from clinopyroxenite
nodules entrained in potassic lavas from the East African Rift, Uganda, and (4) phlogopite phenocrysts from a wyomingite lava
in the Leucite Hills, Wyoming. The Fe2O3 contents in the micas range from 0.8 to 10.5 wt%, corresponding to 0.09 to 1.15 Fe3+ per formula unit (pfu). Water contents vary from 1.6 to 3.0 wt%, corresponding to 1.58 to 3.04 OH pfu, significantly less
than would be expected for a site fully occupied by hydroxyl. Cation- and anion-based normalization procedures provide accurate
mineral formulae with respect to most cations and anions, but are unable to generate accurate estimates of Fe3+/FeT, and overestimate OH at the expense of O on the hydroxyl site. These inaccuracies are present despite acceptable adjusted
totals and stoichiometric calculated site occupancies. The phlogopite and biotite phenocrysts in arc-related lavas from western
Mexico and eastern California have the highest Fe3+/FeT ratios (56–87%), reflecting high magmatic oxygen fugacities (ΔNNO = +2 to +5), in contrast to those from Uganda (25–40%)
and the Leucite Hills (23%). There is no correlation between the OH content and the Fe3+/FeT ratio in the micas. Values of KMg/Fe2+D (± 2σ errors) were calculated for three phlogopite-olivine pairs (0.12 ± 0.12, 0.26 ± 0.14, 0.09 ± 0.12), two biotite-hornblende
pairs (0.73 ± 0.08 and 1.22 ± 0.10) and a single phlogopite-augite pair (1.15 ± 0.12). Values of KF/OHD for two biotite and
hornblende pairs could not be determined without significant error because of the extremely low F contents (< 0.2 wt%) of
the four phases. The δD values obtained in this study encompass a large range (−137 to −43‰). The phlogopite and biotite separates
from Uganda have δD values of −70 to −49‰, which overlap those believed to represent “primary” mantle. There is a larger range
in δD values (−137 to −43‰) for phlogopite phenocrysts from western Mexico minette lavas, although their range in δ18O values (5.2–6.2‰) is consistent with “normal” mantle. It is unlikely, therefore, that the variable δD values reflect heterogeneity
in the mantle source region of the minette magmas. Nor can the extremely low δD values reflect degassing of H2 or H2O since almost 100% loss of dissolved water in the magma is required, an unrealistic scenario given the stability of the hydrous
phenocrysts. The very low δD values of the Mascota minette phlogopites require that the hydrogen be introduced from an external
source (e.g., meteoric water). Whatever the process responsible for the observed hydrogen isotope composition, it had no effect
on the δ18O value, f
O
2, a
H
2O or bulk composition of the host magmas.
Received: 5 January 1995 / Accepted: 19 March 1996 相似文献
5.
The bulk (post-eruptive) wt% FeO concentration in each of 11 phenocryst-poor (<5%) andesite and dacite (60–69 wt% SiO2) lavas from different monogenetic vents in the Mexican arc has been measured by titration, in duplicate. The results match,
within analytical error, the wt% FeO content of the magmas during phenocryst growth (pre-euptive), which were calculated on
the basis of oxygen fugacity and temperature results from Fe–Ti two-oxide oxygen barometry. The average deviation between
the pre- and post-eruptive FeO concentrations is ±0.15 wt%. Application of the plagioclase-liquid hygrometer shows that at
the time of phenocryst growth, these 11 magmas contained from ~3–8 wt% H2O, which was extensively degassed upon eruption. There is no evidence that degassing of ≤8 wt% H2O changed the oxidation state of these magmas. Calculations of pre-eruptive and post-eruptive oxygen fugacity values relative
to the Ni-NiO buffer (in terms of log10 units) for the 11 samples span a similar range; pre-eruptive ∆NNO = −0.9 to +0.7 and post-eruptive ∆NNO = −0.4 to +0.8. The
data further show that extensive groundmass (closed-system) crystallization had no affect on bulk Fe3+/Fe2+ ratios. Finally, there is no systematic variation in the range of pre-eruptive Fe3+/FeT values of the samples as a function of SiO2 concentration (i.e., differentiation). Therefore, the results of this study indicate that the elevated Fe3+/FeT ratios of arc andesites and dacites, compared with magmas erupted in other tectonic settings, cannot be attributed to the
effects of (1) degassing of H2O, (2) closed-system crystallization, and/or (3) differentiation effects, but instead must be inherited from their parental
source rocks (i.e., mantle-derived arc basalts). 相似文献
6.
The Aurora volcanic field, located along the northeastern margin of Mono Lake in the Western Great Basin, has erupted a diverse
suite of high-K and shoshonitic lava types, with 48 to 76 wt% SiO2, over the last 3.6 million years. There is no correlation between the age and composition of the lavas. Three-quarters of
the volcanic field consists of evolved (<4 wt% MgO) basaltic andesite and andesite lava cones and flows, the majority of which
contain sparse, euhedral phenocrysts that are normally zoned; there is no evidence of mixed, hybrid magmas. The average eruption
rate over this time period was ∼200 m3/km2/year, which is typical of continental arcs and an order of magnitude lower than that for the slow-spreading mid-Atlantic
ridge. All of the Aurora lavas display a trace-element signature common to subduction-related magmas, as exemplified by Ba/Nb
ratios between 52 and 151. Pre-eruptive water contents ranged from 1.5 wt% in plagioclase-rich two-pyroxene andesites to ∼6
wt% in a single hornblende lamprophyre and several biotite-hornblende andesites. Calculated oxygen fugacities fall within
–0.4 and +2.4 log units of the Ni-NiO buffer. The Aurora potassic suite follows a classic, calc-alkaline trend in a plot of
FeOT/MgO vs SiO2 and displays linear decreasing trends in FeOT and TiO2 with SiO2 content, suggesting a prominent role for Fe-Ti oxides during differentiation. However, development of the calc-alkaline trend
through fractional crystallization of titanomagnetite would have caused the residual liquid to become so depleted in ferric
iron that its oxygen fugacity would have fallen several log units below that of the Ni-NiO buffer. Nor can fractionation of
hornblende be invoked, since it has the same effect as titanomagnetite in depleting the residual liquid in ferric iron, together
with a thermal stability limit that is lower than the eruption temperatures of several andesites (∼1040–1080°C; derived from
two-pyroxene thermometry). Unless some progressive oxidation process occurs, fractionation of titanomagnetite or hornblende
cannot explain a calc-alkaline trend in which all erupted lavas have oxygen fugacites ≥ the Ni-NiO buffer. In contrast to
fractional crystallization, closed-system equilibrium crystallization will produce residual liquids with an oxygen fugacity
that is similar to that of the initial melt. However, the eruption of nearly aphryic lavas argues against tapping from a magma
chamber during equilibrium crystallization, a process that requires crystals to remain in contact with the liquid. A preferred
model involves the accumulation of basaltic magmas at the mantle-crust interface, which solidify and are later remelted during
repeated intrusion of basalt. As an end-member case, closed-system equilibrium crystallization of a basalt, followed by equilibrium
partial melting of the gabbro will produce a calc-alkaline evolved liquid (namely, high SiO2 and low FeOT/MgO) with a relative f
O
2 (corrected for the effect of changing temperature) that is similar to that of the initial basalt. Differentiation of the
Aurora magmas by repeated partial melting of previous underplates in the lower crust rather than by crystal fractionation
in large, stable magma chambers is consistent with the low eruption rate at the Aurora volcanic field.
Received: 7 July 1995 / Accepted: 19 April 1996 相似文献
7.
Vadim S. Kamenetsky Andrey A. Gurenko 《Contributions to Mineralogy and Petrology》2007,153(4):465-481
The origin of compositional heterogeneities among the magmas parental to mid-ocean ridge basalts (MORB) was investigated using
a single rock piece of the olivine-phyric basalt from 43°N, Mid-Atlantic Ridge (AII D11-177). The exceptional feature of this
sample is presence of very primitive olivine crystals (90–91 mol% Fo) that are significantly variable in terms of CaO (0.15–0.35 wt%).
A population of low-Ca olivine (0.15–0.25 wt% CaO) is also notably distinct from high-Ca olivine population in AII D11-177,
and primitive MORB olivine in general, in having unusual assemblage of trapped mineral and glass inclusions. Mineral inclusions
are represented by high-magnesian (Mg# 90.7–91.1 mol%) orthopyroxene and Cr-spinel, distinctly enriched in TiO2 (up to 5 wt%, c.f. <1 wt% in common MORB spinel). Glass inclusions associated with orthopyroxene and high-Ti Cr-spinel have
andesitic compositions (53–58 wt% SiO2). Compared to the pillow-rim glass and “normal” MORB inclusions, the Si-rich glass inclusions in low-Ca olivine have strongly
reduced Ca and elevated concentrations of Ti, Na, K, P, Cl, and highly incompatible trace elements. Strong variability is
recorded among glass inclusions within a single olivine phenocrysts. We argue that the observed compositional anomalies are
mineralogically controlled, and thus may arise from the interaction between hot MORB magmas and crystal cumulates in the oceanic
crust or magma chamber. 相似文献
8.
Fluid history of UHP metamorphism in Dabie Shan, China: a fluid inclusion and oxygen isotope study on the coesite-bearing eclogite from Bixiling 总被引:32,自引:1,他引:31
Yilin Xiao Jochen Hoefs Alfons M. van den Kerkhof Jens Fiebig Yongfei Zheng 《Contributions to Mineralogy and Petrology》2000,139(1):1-16
This paper characterizes late Holocene basalts and basaltic andesites at Medicine Lake volcano that contain high pre-eruptive
H2O contents inherited from a subduction related hydrous component in the mantle. The basaltic andesite of Paint Pot Crater
and the compositionally zoned basaltic to andesitic lavas of the Callahan flow erupted approximately 1000 14C years Before Present (14C years b.p.). Petrologic, geochemical and isotopic evidence indicates that this late Holocene mafic magmatism was characterized by H2O contents of 3 to 6 wt% H2O and elevated abundances of large ion lithophile elements (LILE). These hydrous mafic inputs contrast with the preceding
episodes of mafic magmatism (from 10,600 to ∼3000 14C years b.p.) that was characterized by the eruption of primitive high alumina olivine tholeiite (HAOT) with low H2O (<0.2 wt%), lower LILE abundance and different isotopic characteristics. Thus, the mantle-derived inputs into the Medicine
Lake system have not always been low H2O, primitive HAOT, but have alternated between HAOT and hydrous subduction related, calc-alkaline basalt. This influx of hydrous
mafic magma coincides temporally and spatially with rhyolite eruption at Glass Mountain and Little Glass Mountain. The rhyolites
contain quenched magmatic inclusions similar in character to the mafic lavas at Callahan and Paint Pot Crater. The influence
of H2O on fractional crystallization of hydrous mafic magma and melting of pre-existing granite crust beneath the volcano combined
to produce the rhyolite. Fractionation under hydrous conditions at upper crustal pressures leads to the early crystallization
of Fe-Mg silicates and the suppression of plagioclase as an early crystallizing phase. In addition, H2O lowers the saturation temperature of Fe and Mg silicates, and brings the temperature of oxide crystallization closer to
the liquidus. These combined effects generate SiO2-enrichment that leads to rhyodacitic differentiated lavas. In contrast, low H2O HAOT magmas at Medicine Lake differentiate to iron-rich basaltic liquids. When these Fe-enriched basalts mix with melted
granitic crust, the result is an andesitic magma. Since mid-Holocene time, mafic volcanism has been dominated primarily by
hydrous basaltic andesite and andesite at Medicine Lake Volcano. However, during the late Holocene, H2O-poor mafic magmas continued to be erupted along with hydrous mafic magmas, although in significantly smaller volumes.
Received: 4 January 1999 / Accepted: 30 August 1999 相似文献
9.
Dawnika L. Blatter Ian S. E. Carmichael 《Contributions to Mineralogy and Petrology》1998,132(2):121-138
Approximately 150 km west of Mexico City in the central part of the Mexican Volcanic Belt (MVB) near Zitácuaro, Mexico, young
volcanism has produced shield volcanoes, large volume silicic deposits, and fault-related basalt and andesite lava flows and
cinder cones. This paper concerns a small cluster of Pleistocene andesite cones and flows which can be separated into two
distinct groups: high-magnesium andesites (>6% MgO, 57–59% SiO2), conveniently called basaltic andesites, with phenocrysts of orthopyroxene and augite, or augite and olivine; and andesites
(60–62% SiO2, <4.6% MgO), which have phenocrysts of orthopyroxene and augite, and ghosts of relict hornblende. Remarkably, plagioclase
phenocrysts are absent, and evenly distributed but sparse (0.5–3.5%) quartz xenocrysts are present in all the lavas. In order
to establish the conditions under which early crystallizing plagioclase is suppressed in these lavas, water saturated experiments
up to 3 kbars were performed on one of the basaltic andesites. The conditions required to reproduce the phenocryst assemblages
(either olivine + augite or opx + augite) are temperatures in excess of 1000 °C, with water saturated liquids (>3 wt%) at
pressures of about 1 kbar. Compared to basaltic andesites of western Mexico, the Zitácuaro basaltic andesites have ∼2 wt%
lower Al2O3 concentrations, which causes plagioclase to precipitate at significantly lower temperatures, and it therefore follows the
crystallization sequence: olivine, augite, and orthopyroxene. Based on ubiquitous quartz xenocrysts, with glassy rhyolitic
inclusions, a reasonable conclusion is that substantial mixing of a quartz-bearing rhyolitic magma with a parental basaltic
andesite has occurred at low pressure (shallow depth), and this would account for the low Al2O3 concentrations in the Zitácuaro basaltic andesites. Whatever the mechanism of incorporation, the quartz xenocrysts are evidence
of contamination of basaltic magma with more siliceous material, thus making it difficult to use these magmas as indicators
of mantle melting processes.
Received: 29 July 1997 / Accepted: 29 January 1998 相似文献
10.
Oxygen isotope constraints on the petrogenesis of the Sybille intrusion of the Proterozoic Laramie Anorthosite Complex 总被引:2,自引:0,他引:2
The origin of monzonitic intrusions that are associated with Proterozoic massif-type anorthosite complexes is controversial.
A detailed oxygen isotope study of the Sybille intrusion, a monzonitic intrusion of the Laramie Anorthosite Complex (Wyoming),
indicates that either derivation from a basaltic magma of mantle origin with a metasedimentary component (∼20%) incorporated
early in its magmatic history, or a partial melt of lower crustal rocks is consistent with the data. The oxygen isotope compositions
of plagioclase, pyroxene and zircon from the Sybille monzosyenite, the dominant rock type in the Sybille intrusion, were analyzed
in order to establish the isotopic composition of the source of the magma. Plagioclase δ18O values range from 6.77 to 9.17‰. We interpret the higher plagioclase δ18O values (average 8.69 ± 0.30‰, n = 19) to be magmatic in origin, lower plagioclase δ18O values (average 7.51 ± 0.44‰, n = 22) to be the result of variable subsolidus alteration, and pyroxene δ18O values (average 6.34 ± 0.38‰, n = 19) to be the result of closed-system diffusional exchange during cooling. Low magnetic zircons, which have been shown
to retain magmatic oxygen isotope values despite high grade metamorphism and extensive subsolidus hydrothermal alteration,
have δ18O values (7.40 ± 0.24‰, n = 11) which are consistent with our interpretation of the plagioclase and pyroxene results. Oxygen isotope data from all
three minerals indicate that the magmatic oxygen isotope composition of the Sybille intrusion is enriched in 18O relative to the composition of average or “normal” mantle-derived magmas. This enrichment is approximately twice the oxygen
isotope enrichment that could result from closed-system fractionation, rendering a closed-system, comag- matic petrogenetic
model between the Sybille intrusion and the mantle-derived anorthositic lithologies of the Laramie Anorthosite Complex improbable.
Received: 7 April 1998 / Accepted: 19 January 1999 相似文献
11.
Nearly contemporaneous eruption of alkaline and calc-alkaline lavas occurred about 900 years BP from El Volcancillo paired vent, located behind the volcanic front in the Mexican Volcanic Belt (MVB). Emission of hawaiite (Toxtlacuaya) was immediately followed by calc-alkaline basalt (Río Naolinco). Hawaiites contain olivine microphenocrysts (Fo67–72), plagioclase (An56–60) phenocrysts, have 4–5 wt% MgO and 49.6–50.9 wt% SiO2. In contrast, calc-alkaline lavas contain plagioclase (An64–72) and olivine phenocrysts (Fo81–84) with spinel inclusions, and have 8–9 wt% MgO and 48.4–49.4 wt% SiO2. The most primitive lavas in the region (Río Naolinco and Cerro Colorado) are not as primitive as parental melts in other arcs, and could represent either (a) variable degrees of melting of a subduction modified, garnet-bearing depleted mantle source, followed by AFC process, or (b) melting of two distinct mantle sources followed by AFC processes. These two hypotheses are evaluated using REE, HFSE, and Sr, Os and Pb isotopic data. The Toxtlacuaya flow and the Y & I lavas can be generated by combined fractional crystallization and assimilation of gabbroic granulite, starting with a parental liquid similar to the Cerro Colorado basalt. Although calc-alkaline and alkaline magmas commonly occur together in other areas of the MVB, evidence for subduction component in El Volcancillo magmas is minimal and limited to <1%, which is a unique feature in this region further from the trench. El Volcancillo lavas were produced from two different magma batches: we surmise that the injection of calc-alkaline magma into an alkaline magma chamber triggered the eruption of hawaiites. Our results suggest that the subalkaline and hawaiitic lavas were formed by different degrees of partial melting of a similar, largely depleted mantle source, followed by later AFC processes. This model is unusual for arcs, where such diversity is usually explained by melting of heterogeneous (enriched and depleted) and subduction-modified mantle. 相似文献
12.
Yuenyong Panjasawatwong Leonid V. Danyushevsky Anthony J. Crawford Keith L. Harris 《Contributions to Mineralogy and Petrology》1995,118(4):420-432
An experimental investigation of plagioclase crystallization in broadly basaltic/andesitic melts of variable Ca# (Ca/(Ca+Na)*100)
and Al# (Al/(Al+Si)*100) values and H2O contents has been carried out at high pressures (5 and 10 kbar) in a solid media piston-cylinder apparatus. The H2O contents of glasses coexisting with liquidus or near-liquidus plagioclases in each experiment were determined via an FTIR
spectroscopic technique. This study has shown that melt Ca# and Al#, H2O content and crystallization pressure all control the composition of liquidus plagioclase. Increasing melt Ca# and Al# increase
An content of plagioclase, whereas the effect of increasing pressure is the opposite. However, the importance of the role
played by each of these factors during crystallization of natural magmas varies. Melt Ca# has the strongest control on plagioclase
An content, but melt Al# also exerts a significant control. H2O content can notably increase the An content of plagioclase, up to 10 mol % for H2O-undersaturated melts, and 20 mol % for H2O-saturated melts. Exceptionally calcic plagioclases (up to An100) in some primitive subduction-related boninitic and related rocks cannot be attributed to the presence of the demonstrated
amounts of H2O (up to 3 wt %). Rather, they must be due to the involvement of extremely refractory (CaO/Na2O>18) magmas in the petrogenesis of these rocks. Despite the refractory nature of some primitive MORB glasses, none are in
equilibrium with the most calcic plagioclase (An94) found in MORB. These plagioclases were likely produced from more refractory melts with CaO/Na2O = 12–15, or from melts with exceptionally high Al2O3(>18%). Magmas of appropriate compositions to crystallize these most calcic plagioclases are sometimes found as melt inclusions
in near liquidus phenocrysts from these rocks, but are not known among wholerock or glass compositions. The fact that such
melts are not erupted as discrete magma batches indicates that they are effectively mixed and homogenized with volumetrically
dominant, less refractory magmas. The high H2O contents (∼ 6 wt%) in some high-Al basaltic arc magmas may be responsible for the existence of plagioclases up to An95 in arc lavas. However, an alternative possibility is that petrogenesis involving melts with abnormally high CaO/Na2O values (> 8) may account for the presence of highly anorthitic plagioclases in these rocks.
Received: 31 August 1993 / Accepted: 20 May 1994 相似文献
13.
A. A. Gurenko Thor H. Hansteen Hans-Ulrich Schmincke 《Contributions to Mineralogy and Petrology》1996,124(3-4):422-435
Picritic units of the Miocene shield volcanics on Gran Canaria, Canary Islands, contain olivine and clinopyroxene phenocrysts
with abundant primary melt, crystal and fluid inclusions. Composition and crystallization conditions of primary magmas in
equilibrium with olivine Fo90-92 were inferred from high-temperature microthermometric quench experiments, low-temperature microthermometry of fluid inclusions
and simulation of the reverse path of olivine fractional crystallization based on major element composition of melt inclusions.
Primary magmas parental for the Miocene shield basalts range from transitional to alkaline picrites (14.7–19.3 wt% MgO, 43.2–45.7
wt% SiO2). Crystallization of these primary magmas is believed to have occurred over the temperature range 1490–1150° C at pressures
≈5 kbar producing olivine of Fo80.6-90.2, high-Ti chrome spinel [Mg/ (Mg+Fe2+)=0.32–0.56, Cr/(Cr+Al)=0.50–0.78, 2.52–8.58 wt% TiO2], and clinopyroxene [Mg/(Mg+Fe)=0.79–0.88, Wo44.1-45.3, En43.9-48.0, Fs6.8-11.0] which appeared on the liquidus together with olivine≈Fo86. Redox conditions evolved from intermediate between the QFM and WM buffers to late-stage conditions of NNO+1 to NNO+2. The
primary magmas crystallized in the presence of an essentially pure CO2 fluid. The primary magmas originated at pressures >30 kbar and temperatures of 1500–1600° C, assuming equilibrium with mantle
peridotite. This implies melting of the mantle source at a depth of ≈100 km within the garnet stability field followed by
migration of melts into magma reservoirs located at the boundary between the upper mantle and lower crust. The temperatures
and pressures of primary magma generation suggest that the Canarian plume originated in the lower mantle at depth ≈900 km
that supports the plume concept of origin of the Canary Islands.
Received: 23 October 1995/Accepted: 21 February 1996 相似文献
14.
Elliot Hildner Andreas Klügel Folkmar Hauff 《Contributions to Mineralogy and Petrology》2011,162(4):751-772
The 1995 eruption of Fogo (Cape Verde Islands) differed from previous eruptions by the occurrence of evolved lavas, the SW-orientation
of vents, and pre-eruptive seismicity between Fogo and the adjacent (~20 km) island of Brava. We have conducted a thermobarometric
and chemical study of this eruption in order to reconstruct its magma plumbing system and to test for possible connections
to Brava. The bimodal eruption produced basanites (5.2–6.7 wt% MgO) and phonotephrites (2.4–2.8 wt% MgO) that are related
by fractional crystallization. Clinopyroxene-melt-barometry of phenocrysts yields pressure ranges of 460–680 MPa for the basanites
and 460–520 MPa for the phonotephrites. Microthermometry of CO2-dominated fluid inclusions in olivine and clinopyroxene phenocrysts yields systematically lower pressure ranges of 200–310 MPa
for basanites and 270–470 MPa for phonotephrites. The combined data indicate pre-eruptive storage of the 1995 magmas within
the lithospheric mantle between 16 and 24 km depth. During eruption, the ascending magmas stalled temporarily at 8–11 km depth,
within the lower crust, before they ascended to the surface in a few hours as indicated by zonations of olivine phenocrysts.
Our data provide no evidence for magma storage at shallow levels (<200 MPa) or lateral magma movements beneath the Fogo-Brava
platform. Sr–Nd–Pb isotope ratios of samples from Brava differ significantly from those of the 1995 and older Fogo lavas,
which rules out contamination of the 1995 magmas by Brava material and indicates different mantle sources and magma plumbing
systems for both islands. 相似文献
15.
Mineral chemistry of submarine lavas from Hilo Ridge, Hawaii: implications for magmatic processes within Hawaiian rift zones 总被引:10,自引:0,他引:10
Huai-Jen Yang Frederick A. Frey David A. Clague Michael O. Garcia 《Contributions to Mineralogy and Petrology》1999,135(4):355-372
The crustal history of volcanic rocks can be inferred from the mineralogy and compositions of their phenocrysts which record
episodes of magma mixing as well as the pressures and temperatures when magmas cooled. Submarine lavas erupted on the Hilo
Ridge, a rift zone directly east of Mauna Kea volcano, contain olivine, plagioclase, augite ±orthopyroxene phenocrysts. The
compositions of these phenocryst phases provide constraints on the magmatic processes beneath Hawaiian rift zones. In these
samples, olivine phenocrysts are normally zoned with homogeneous cores ranging from ∼ Fo81 to Fo91. In contrast, plagioclase, augite and orthopyroxene phenocrysts display more than one episode of reverse zoning. Within each
sample, plagioclase, augite and orthopyroxene phenocrysts have similar zoning profiles. However, there are significant differences
between samples. In three samples these phases exhibit large compositional contrasts, e.g., Mg# [100 × Mg/(Mg+Fe+2)] of augite varies from 71 in cores to 82 in rims. Some submarine lavas from the Puna Ridge (Kilauea volcano) contain phenocrysts
with similar reverse zonation.
The compositional variations of these phenocrysts can be explained by mixing of a multiphase (plagioclase, augite and orthopyroxene)
saturated, evolved magma with more mafic magma saturated only with olivine. The differences in the compositional ranges of
plagioclase, augite and orthopyroxene crystals between samples indicate that these samples were derived from isolated magma
chambers which had undergone distinct fractionation and mixing histories. The samples containing plagioclase and pyroxene
with small compositional variations reflect magmas that were buffered near the olivine + melt ⇒Low-Ca pyroxene + augite +
plagioclase reaction point by frequent intrusions of mafic olivine-bearing magmas. Samples containing plagioclase and pyroxene
phenocrysts with large compositional ranges reflect magmas that evolved beyond this reaction point when there was no replenishment
with olivine-saturated magma. Two of these samples contain augite cores with Mg# of ∼71, corresponding to Mg# of 36–40 in
equilibrium melts, and augite in another sample has Mg# of 63–65 which is in equilibrium with a very evolved melt with a Mg#
of ∼30. Such highly evolved magmas also exist beneath the Puna Ridge of Kilauea volcano. They are rarely erupted during the
shield building stage, but may commonly form in ephemeral magma pockets in the rift zones.
The compositions of clinopyroxene phenocryst rims and associated glass rinds indicate that most of the samples were last equilibrated
at 2–3 kbar and 1130–1160 °C. However, in one sample, augite and glass rind compositions reflect crystallization at higher
pressures (4–5 kbar). This sample provides evidence for magma mixing at relatively high pressures and perhaps transport of
magma from the summit conduits to the rift zone along the oceanic crust-mantle boundary.
Received: 8 July 1998 / Accepted: 2 January 1999 相似文献
16.
Susanne M. Straub Ana Lillian Martin-Del Pozzo 《Contributions to Mineralogy and Petrology》2001,140(4):487-510
Tephra lapilli from six explosive eruptions between April 1996 and February 1998 at Popocatepetl volcano (=Popo) in central
Mexico have been studied to investigate the causes of magma diversification in thick-crusted volcanic arcs. The tephra particles
are sparsely porphyritic (≈5 vol%) magnesian andesites (SiO2=58–65 wt%; MgO=2.6–5.9 wt%) that contain phenocrysts of NiO-rich (up to 0.67 wt% NiO) magnesian olivine (Fo89–91 cores) with inclusions of Cr-spinel (cr#=59–70), orthopyroxene (mg#=63–76), clinopyroxene (mg#=68–86), intermediate to sodic
plagioclase (An33–66), and traces of amphibole. Major and trace element systematics indicate magma mixing. The liquid mg#melt ratios inferred from the ferromagnesian phenocrysts suggest the existence of a mafic (mg#melt ≈ 72–76) and an evolved component magma (mg#melt ≈ 35–40). These component magmas form a hybrid magnesian andesite with an intermediate range of mg#melt=50–72. The mafic end member (mg#melt ≈ 72–75) is saturated with olivine and spinel and crystallizes at temperatures ≈1170–1085 °C with oxygen fugacities close
to the fayalite–magnetite–quartz buffer and elevated water contents of several wt% H2O. A likely location of crystallization is at lower crustal levels, possibly at the Moho. Olivine is followed by high-mg#
clinopyroxene which could start to crystallize during magma ascent. At depths of ≈4 to 13 km, the mafic magma mixes with an
evolved composition containing low-mg# clino- and orthopyroxene and plagioclase at a temperature of ≈950 °C. The repetitive
ascent of batches of mafic magmas spaced days to weeks apart implies multiple episodes of crystallization and magma mixing.
The tephra is similar to the Popo magnesian andesites, suggesting similar generic processes for the common lavas of the volcano.
The advantage of the tephra is that it can be used to reconstruct the composition of the mafic magma. Building on the elemental
systematics of the tephra and a comparison to the near-primary basalts from the surrounding monogenetic fields, we infer that
the Popo mafic end member is a magnesian andesite with variable, but high SiO2 contents of ≈55–62 wt% and near-primary characteristics, such as high-mg#melt of 72–75, FeO*/MgO ratios <1 (if extrapolated to an mg#melt of 72–75), and high Ni contents (=200 ppm Ni). This model implies that the typical elemental signature of the Popo andesites,
such as the low CaO, Al2O3, FeO*, high Na2O contents, and the depletion in high-field strength elements (e.g., P, Zr, Ti), are mantle source phenomena. Thus, determining
the elemental budget of the magnesian andesite, as it is prior to the modifications by crustal differentiation, is central
to quantifying the subcrustal mass fluxes beneath Popo.
Received: 13 December 1999 / Accepted: 11 August 2000 相似文献
17.
From basalt to dacite: origin and evolution of the calc-alkaline series of Salina, Aeolian Arc, Italy 总被引:1,自引:1,他引:0
The island of Salina comprises one of the most distinct calc-alkaline series of the Aeolian arc (Italy), in which calc-alkaline,
high-K calc-alkaline, shoshonitic and leucite-shoshonitic magma series are developed. Detailed petrological, geochemical and
isotopic (Sr, Nd, Pb, O) data are reported for a stratigraphically well-established sequence of lavas and pyroclastic rocks
from the Middle Pleistocene volcanic cycle (430–127 ka) of Salina, which is characterized by an early period of basaltic volcanism
(Corvo; Capo; Rivi; Fossa delle Felci, group 1) and a sequence of basaltic andesites, and andesites and dacites in the final
stages of activity (Fossa delle Felci, groups 2–8). Major and trace element compositional trends, rare earth element (REE)
abundances and mineralogy reveal the importance of crystal fractionation of plagioclase + clinopyroxene + olivine/ orthopyroxene ± titanomagnetite ± amphibole ± apatite
in generating the more evolved magma types from parental basaltic magmas, and plagioclase accumulation in producing the high
Al2O3 contents of some of the more evolved basalts. Sr isotope ratios range from 0.70410 to 0.70463 throughout the suite and show
a well-defined negative correlation with 143Nd/144Nd (0.51275–0.51279). Pb isotope compositions are distinctly radiogenic with relatively large variations in 206Pb/204Pb (19.30–19.66), fairly constant 207Pb/204Pb (15.68–15.76) and minor variations in 208Pb/204Pb ratios (39.15–39.51). Whole-rock δ18O values range from +6.4 to +8.5‰ and correlate positively with Sr isotope ratios. Overall, the isotopic variations are correlated
with the degree of differentiation of the rocks, indicating that only small degrees of crustal assimilation are overprinting
the dominant evolution by crystal–liquid fractionation (AFC-type processes). The radiogenic and oxygen isotope composition
of the Salina basalts suggests derivation from primary magmas from a depleted mantle source contaminated by slab-derived fluids
and subducted sediments with an isotopic signature of typical upper continental crust. These magmas then evolved further to
andesitic and dacitic compositions through the prevailing process of low-pressure fractional crystallization in a shallow
magma reservoir, accompanied by minor assimilation of crustal lithologies similar to those of the Calabrian lower crust.
Received: 29 November 1999 / Accepted: 16 April 2000 相似文献
18.
Michelle L. Coombs John C. Eichelberger Malcolm J. Rutherford 《Contributions to Mineralogy and Petrology》2000,140(1):99-118
Between 1953 and 1974, approximately 0.5 km3 of andesite and dacite erupted from a new vent on the southwest flank of Trident volcano in Katmai National Park, Alaska,
forming an edifice now known as Southwest (or New) Trident. Field, analytical, and experimental evidence shows that the eruption
commenced soon after mixing of dacite and andesite magmas at shallow crustal levels. Four lava flows (58.3–65.5 wt% SiO2) are the dominant products of the eruption; these contain discrete andesitic enclaves (55.8–58.9 wt% SiO2) as well as micro- and macro-scale compositional banding. Tephra from the eruption spans the same compositional range as
lava flows; however, andesite scoria (56–58.1 wt% SiO2) is more abundant relative to dacite tephra, and is the explosively erupted counterpart to andesite enclaves. Fe–Ti oxide
pairs from andesite scoria show a limited temperature range, clustered around 1000 °C. Temperatures from grains found in dacite
lavas possess a wider range; however, cores from large (>100 μm) magnetite and coexisting ilmenite give temperatures of ∼890 °C,
taken to represent a pre-mixing temperature for the dacite. Water contents from dacite phenocryst melt inclusions and phase
equilibria experiments on the andesite imply that the two magmas last resided at a water pressure of 90 MPa, and contained
∼3.5 wt% H2O, equivalent to 3 km depth if saturated. Unzoned pyroxene and sodic plagioclase in the dacite suggest that it likely underwent
significant crystallization at this depth; highly resorbed anorthitic plagioclase from the andesite suggests that it originated
at greater depths and underwent relatively rapid ascent until it reached 3 km, mixed with dacite, and erupted. Diffusion profiles
in phenocrysts suggest that mixing preceded eruption of earliest lava by approximately one month. The lack of a compositional
gap in the erupted rock suite indicates that thorough mixing of the andesite and dacite occurred quickly, via disaggregation
of enclaves, phenocryst transfer from one magma to another, and direct mixing of compositionally distinct melt phases.
Received: 22 September 1999 / Accepted: 4 April 2000 相似文献
19.
The Edgecumbe volcanic field is a Holocene volcanic province located on Kruzof Island, SE Alaska. Exposed within the 260 km2 field are basalt, andesitic basalt, andesite, dacite and rhyodacite. The rhyodacites were erupted after the basalts and before
the andesites. The volcanics, which are Al-rich (14–18 wt%) and lack an iron enrichment trend, range from tholeiites (47 wt%
SiO2) through rhyodacites (72%), but a compositional gap of approximately 9 wt% separates the dacites and rhyodacites. Initial
87Sr/86Sr ranges from 0.70297 in the basalts to 0.70440 in a pyroxene andesite. δ
18O increases across the suite: 5.8‰ to 7.9‰. Plagioclase (An32–86) is the dominant phenocryst in all but one lava. Olivine (Fo58–86) occurs in the basic lavas (<53 wt% SiO2), but is replaced by orthopyroxene (En43–73) and clinopyroxene (En31Wo41-En48Wo40) in the more siliceous volcanics. In the basalts and rhyodacites, plagioclase is weakly zoned, but extreme zoning (<30 mole%
An) is characteristic of phenocrysts in the intermediate lavas. Fractionation of the observed phenocryst assemblages could
not have produced the more silicous volcanics. Instead they were generated by partial melting of intrusive basement (87Sr/86Sr=0.70487; δ
18O: 8.7–9.3) by basaltic magma and subsequent assimilation. Mass balance calculations show the rhyodacites are almost pure
partial melt (<5% basaltic component) whereas the intermediate lavas contain between 30 and 60% partial melt. 相似文献
20.
Brian R. Jicha Garret L. Hart Clark M. Johnson Wes Hildreth Brian L. Beard Steven B. Shirey John W. Valley 《Contributions to Mineralogy and Petrology》2009,157(2):189-207
Strontium, Nd, Pb, Hf, Os, and O isotope compositions for 30 Quaternary lava flows from the Mount Adams stratovolcano and
its basaltic periphery in the Cascade arc, southern Washington, USA indicate a major component from intraplate mantle sources,
a relatively small subduction component, and interaction with young mafic crust at depth. Major- and trace-element patterns
for Mount Adams lavas are distinct from the rear-arc Simcoe volcanic field and other nearby volcanic centers in the Cascade
arc such as Mount St. Helens. Radiogenic isotope (Sr, Nd, Pb, and Hf) compositions do not correlate with geochemical indicators
of slab-fluids such as (Sr/P)
n
and Ba/Nb. Mass-balance modeling calculations, coupled with trace-element and isotopic data, indicate that although the mantle
source for the calc-alkaline Adams basalts has been modified with a fluid derived from subducted sediment, the extent of modification
is significantly less than what is documented in the southern Cascades. The isotopic and trace-element compositions of most
Mount Adams lavas require the presence of enriched and depleted mantle sources, and based on volume-weighted chemical and
isotopic compositions for Mount Adams lavas through time, an intraplate mantle source contributed the major magmatic mass
of the system. Generation of basaltic andesites to dacites at Mount Adams occurred by assimilation and fractional crystallization
in the lower crust, but wholesale crustal melting did not occur. Most lavas have Tb/Yb ratios that are significantly higher
than those of MORB, which is consistent with partial melting of the mantle in the presence of residual garnet. δ
18O values for olivine phenocrysts in Mount Adams lavas are within the range of typical upper mantle peridotites, precluding
involvement of upper crustal sedimentary material or accreted terrane during magma ascent. The restricted Nd and Hf isotope
compositions of Mount Adams lavas indicate that these isotope systems are insensitive to crustal interaction in this juvenile
arc, in stark contrast to Os isotopes, which are highly sensitive to interaction with young, mafic material in the lower crust. 相似文献