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1.
Carbon and hydrogen isotopic characteristics of natural gases from the Luliang and Baoshan basins in Yunnan Province, China 总被引:2,自引:1,他引:2
XU Yongchang LIU Wenhui SHEN Ping WANG Wanchun WANG Xiaofeng Tenger YAN Yaomin & LIU Ruobin . Lanzhou Center of Oil & Gas Resources Institute of Geology Geophsics Chinese Academy of Sciences Lanzhou China . Research Institute of Petroleum Exploration Production SINOPEC Beijing China . South Branch of Petroleum Exploration Production Company SINOPEC Kuming China 《中国科学D辑(英文版)》2006,49(9):938-946
The Luliang and Baoshan basins are two small ba- sins in Yunnan Province. In the recent ten years or so, there have been found a number of natural gas pools of commercial importance in the two basins. Although the gas pools are small in size, the natural … 相似文献
2.
Expeditions to Muztagata (in the eastern Pamirs) during the summer seasons of 2002 and 2003 collected precipitation samples
and measured their oxygen isotopes. The δ
18O in precipitation displays a wide range, varying from −17.40‰ to +1.33‰ in June-September 2002 and from −22.31‰ to +4.59‰
in May-August 2003. The δ
18O in precipitation correlates with the initial temperature of precipitation during the observing periods. The positive correlation
between δ
18O and temperature suggests that δ
18O can be used as an indicator of temperature in this region. The δ
18O values in fresh-snow samples collected from two snow events at different elevations on the Muztagata Glacier show a strong
“altitude effect”, with a ratio of nearly −0.40% per 100 m from 5500 m to 7450 m. 相似文献
3.
Jennifer L. Lewicki George E. Hilley Laura Dobeck Bruno D. V. Marino 《Bulletin of Volcanology》2012,74(1):135-141
Use of eddy covariance (EC) techniques to map the spatial distribution of diffuse volcanic CO2 fluxes and quantify CO2 emission rate was tested at the Horseshoe Lake tree-kill area on Mammoth Mountain, California, USA. EC measurements of CO2 flux were made during September–October 2010 and ranged from 85 to 1,766 g m−2 day−1. Comparative maps of soil CO2 flux were simulated and CO2 emission rates estimated from three accumulation chamber (AC) CO2 flux surveys. Least-squares inversion of measured eddy covariance CO2 fluxes and corresponding modeled source weight functions recovered 58–77% of the CO2 emission rates estimated based on simulated AC soil CO2 fluxes. Spatial distributions of modeled surface CO2 fluxes based on EC and AC observations showed moderate to good correspondence (R
2 = 0.36 to 0.70). Results provide a framework for automated monitoring of volcanic CO2 emissions over relatively large areas. 相似文献
4.
13C of 367 C3 herbaceous plants was measured in loess area in northern China. Their δ13C values vary between −21.7%. and −30.0%., with a mean of −26.7%.. In the center of Loess Plateau (semimoist area) with annual
precipitation of 400–600 mm, the δ13
C values of C3 herbaceous plants range from −24.4%. to −28.5%., with a mean of −27.5%.. In the west of Loess Plateau (semiarid and arid
area) with annual precipitation less than 400 mm, they range between −21.7%. and −30.0%., with a mean of −26.2%.. Annual precipitation
is the main factor that makes δ13C values of C3 herbaceous plants in the west greater than those in the central Loess Plateau. The composition of δ13C in C3 plants increases with deceasing annual precipitation, and the mean change is −49%./100 mm. 相似文献
5.
Time-dependent CO<Subscript>2</Subscript> variations in Lake Albano associated with seismic activity
Lake Albano (Alban Hills volcanic complex, Central Italy) is located in a densely populated area near Rome. The deep lake
waters have significant dissolved CO2 concentrations, probably related to sub-lacustrine fluid discharges fed by a pressurized CO2-rich reservoir. The analytical results of geochemical surveys carried out in 1989–2010 highlight the episodes of CO2 removal from the lake. The total mass of dissolved CO2 decreased from ∼5.8 × 107 kg in 1989 to ∼0.5 × 107 kg in 2010, following an exponential decreasing trend. Calculated values of both dissolved inorganic carbon and CO2 concentrations along the vertical profile of the lake indicate that this decrease is caused by CO2 release from the epilimnion, at depth <9 m, combined with (1) water circulation at depth <95 m and (2) CO2 diffusion from the deeper lake layers. According to this model, Lake Albano was affected by a large CO2 input that coincided with the last important seismic swarm at Alban Hills in 1989, suggesting an intimate relationship between
the addition of deep-originated CO2 to the lake and seismic activity. In the case of a CO2 degassing event of an order of magnitude larger than the one that occurred in 1989, the deepest part of Lake Albano would
become CO2-saturated, resulting in conditions compatible with the occurrence of a gas outburst. These results reinforce the idea that
a sudden CO2 input into the lake may cause the release of a dense gas cloud, presently representing the major volcanic threat for this
densely populated area. 相似文献
6.
Fraser Goff Gary M. McMurtry Dale Counce James A. Simac Alfredo R. Roldán-Manzo David R. Hilton 《Bulletin of Volcanology》2000,62(1):34-52
2 and approximately 85% SO2 of the total sulfur gas. Relative amounts of He, Ar, and N2 show a distinct hot-spot signature ( ). The δ13C–CO2 is approximately −3.6‰ and δ34ST is approximately +3.3‰. The δD/δ18O of fumarole H2O indicates steam separation from local meteoric waters whose estimated minimum mean residence time from 3H analyses is ≤40 years. Fumarolic activity at Alcedo is controlled by a caldera-margin fault containing at least seven hydrothermal
explosion craters, and by an intracaldera rhyolite vent. Two explosion craters which formed in 1993–1994 produce approximately
15 m3/s of steam, yet discharge temperatures are ≤97°C. Water content of the total gas is 95–97 mol.%, noncondensible gas is 92–98 mol.%
CO2, and sulfur gas is dominated by H2S. Relative amounts of He, Ar, and N2 show extensive mixing between hot spot and air or air-saturated meteoric water components but the average . The δ13C–CO2 is approximately −3.5‰ and δ34ST is approximately −0.8‰. The δD/δ18O of fumarole steam indicates separation from a homogeneous reservoir that is enriched 3–5‰ in 18O compared with local meteoric water. 3H indicates that this reservoir water has a maximum mean residence time of approximately 400 years and empirical gas geothermometry
indicates a reservoir temperature of 260–320°C. The intracaldera hydrothermal reservoir in Alcedo is probably capable of producing
up to 150 MW; however, environmental concerns as well as lack of infrastructure and power users will limit the development
of this resource.
Received: 19 April 1999 / Accepted: 23 October 1999 相似文献
7.
An estimated average CO2 output from Etna's summit craters in the range of 13±3 Mt/a has recently been determined from the measured SO2 output and measured CO2/SO2 molar ratios. To this amount the CO2 output emitted diffusely from the soil (≈ 1 Mt/a) and the amount of CO2 dissolved in Etna's aquifers (≈ 0.25 Mt/a) must be added. Data on the solubility of CO2 in Etnean magmas at high temperature and pressure allow the volume of magma involved in the release of such an amount of
this gas to be estimated. This volume of magma (≈ 0.7 km3/a) is approximately 20 times greater than the volume of magma erupted annually during the period 1971–1995. On the basis
of C-isotopic data of CO2 collected in the Etna area and of new hypotheses on the source of Mediterranean magmas, significant contributions of CO2 from non-magmatic sources to the total output from Etna are unlikely. Such large outputs of CO2 and also of SO2 from Etna could be due to an anomalously shallow asthenosphere beneath the volcano that allows a continuous escape of gases
toward the surface, even without migration of magma.
Received: 7 August 1996 / Accepted: 9 November 1996 相似文献
8.
Young-Joo Lee 《中国科学D辑(英文版)》2006,49(8):872-880
Serious interest has been directed toward natural gas hydrate as a potential energy resource; factor in global climate change, and submarine geohazard since naturally occurring gas-hydrate deposits were found in the 1960s. Hydrate Ridge, Cascadia convergent mar- gin, is characterized by abundant methane hydrates at and below the seafloor, active venting of fluids and gases, chemosynthetic communities, and some of the highest methane oxidation rates ever found in the ma-rine environment. All of… 相似文献
9.
Di Chen JianPing Yuan ShiPing Xu XiaoGang Zhou Yan Zhang XiaoMing Xu ZhiWen Zou GuRen Zhang JiangHai Wang 《中国科学D辑(英文版)》2009,52(5):655-659
Two types of Hepialus larvae with different diets were distinguished in the Sejila Mountain, Tibetan Plateau based on the stable carbon isotope
data of the host Hepialus larva of Cordyceps sinensis and its closely adjacent tender plant roots and humus fractions. Type I is the larva chiefly fed by soil humus, and characterized
by the δ 13C values of −22.6‰ to −23.4‰, and more than −23.4‰ in its heads. Type II is the larva chiefly fed by tender plant roots, and
characterized by the δ 13C values of −24.6‰ to −27.6‰, and less than −24.6‰ in its heads. Our result has exceeded the traditional understanding that
their food sources only come from the tender plant roots, and may provide evidence for choosing cheap and high-quality foods
and further establishing artificial habitats in their large-scale reproduction.
Supported by the National Key Technology R & D Program (Grant No. 2007BAI32B05) 相似文献
10.
Approximately 20 km south of Mt. Etna craters, at the contact between volcanic and sedimentary formations, three mud volcanoes
discharge CO2-rich gases and Na–Cl brines. The compositions of gas and liquid phases indicate that they are fed by a hydrothermal system
for which temperatures of 100–150 °C were estimated by means of both gas and solute geothermometry. The hydrothermal system
may be associated with CO2-rich groundwaters over a large area extending from the central part of Etna to the mud volcanoes. Numerous data on the He,
CH4, CO2 composition of the gases of the three manifestations, sampled over the past 5 years, indicate clearly that variations are
due to separation processes of a CO2-rich gas phase from the liquid. The effects of these processes have to be taken into account in the interpretation of the
monitoring data collected for the geochemical surveillance of Etna volcano.
Received: 4 September 1995 / Accepted: 14 February 1996 相似文献
11.
A laboratory inorganic carbonate precipitation experiment at high pH of 8.96 to 9.34 was conducted, and the boron isotopic
fractionations of the precipitated carbonate were measured. The data show that boron isotopic fractionation factors (αcarb-3) between carbonate and B(OH)3 in seawater range 0.937 and 0.965, with an average value of 0.953. Our results together with those reported by Sanyal and
collaborators show that the αcarb-3 values between carbonate and B(OH)3 in solution are not constant but are negatively correlated with the pH of seawater. The measured boron isotopic compositions
of carbonate precipitation (δ11Bcarb) do not exactly lie on the best-fit theoretical δ11B4-pH curves and neither do they exactly parallel any theoretical δ11B4-pH curves. Therefore, it is reasonable to argue that a changeable proportion of B(OH)3 with pH of seawater should also be incorporated into carbonate except for the dominant incorporation of B(OH)4
− in carbonate. Hence, in the reconstruction of the paleo-pH of seawater from boron isotopes in marine biogenic carbonates,
the use of theoretical boron isotopic fractionation factor (α4−3) between B(OH)4
− and B(OH)3 is not suitable. Instead, an empirical equation should be established.
Supported by National Natural Science Foundation of China (Nos. 40573013 and 40776071), State Key Laboratory of Loess and
Quaternary Geology, Institute of Earth Environment, Chinese Academy of Sciences (Grant No SKLLQG0502) and State Key Laboratory
of Environmental Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences 相似文献
12.
Discrimination of abiogenic and biogenic alkane gases 总被引:5,自引:0,他引:5
JinXing Dai CaiNeng Zou ShuiChang Zhang Jian Li YunYan Ni GuoYi Hu Xia Luo ShiZhen Tao GuangYou Zhu JingKui Mi ZhiSheng Li AnPing Hu Chun Yang QingHua Zhou YanHua Shuai Ying Zhang ChengHua Ma 《中国科学D辑(英文版)》2008,51(12):1737-1749
We have combined the analytical data of the carbon isotope distribution pattern, R/Ra and CH4/3He values of abiogenic and biogenic (referring to the thermogenic and bacterial or microbial) alkane gases in China with those of alkane gases from USA, Russia, Germany, Australia and other countries. Four discrimination criteria are derived from this comparative study: 1) Carbon isotopic composition is generally greater than -30‰ for abiogenic methane and less than -30‰ for biogenic methane; 2) Abiogenic alkane gases have a carbon isotopic reversal trend (δ 13C1> δ 13C2> δ 13C3> δ 13C4) with δ 13C1>-30‰ in general; 3) Gases with R/Ra >0.5 and δ 13C11 δ 13C2>0 are of abiogenic origin; 4) Gases (meth- ane) with CH4/3He≤106 are of abiogenic origin, whereas gases with CH4/3He≥1011 are of biogenic origin. 相似文献
13.
Michael P.RICHARDS 《中国科学D辑(英文版)》2009,52(1):85-92
Despite great achievements in the origins of domestic pigs made by the methods of zooarchaeology and molecular biology, how
to scientifically distinguish the domesticated pigs from wild boars during the early stage of pig domestication is still poorly
understood. Compared to wild boar’s diets which come from the natural environment, the diets of domestic pigs are more easily
influenced by human feeding activities. Therefore, in principle, exploration of the dietary differences among pigs and under-standing
the impact on pig diets fed by humans can have great potential to differentiate between wild boars and domesticated pigs.
To reveal dietary differences among pigs and distinguish the domesticated pigs from wild boars based on comparison with the
diets of humans and other animals, we analyzed the carbon and nitrogen stable isotopes of human bones from Xiaojingshan Site
and animal bones from Yuezhuang Site, both of which belong to Houli Culture in Shandong Province and date to about 8500-7500
years ago. The mean δ13C value ((−17.8 ± 0.3)‰) and δ15N value ((9.0±0.6)‰) in human collagen indicate that although millet agriculture began it was not the main subsistence strategy
as millets are typical of C4 plants and that humans made a living mainly by gathering, hunting or raising some domesticated animals. The δ13C value (−16.1‰) and δ15N value (6.9‰) in the bovine suggest that C3 plants were dominant in its diet with some C4 plants complemented. The fish has lower δ13C value (−24.9‰) and higher δ15N value (8.8‰) than the bovine, which is the characteristic of the isotopic values from Eurasian freshwater fish. Based on
the differences in carbon and nitrogen isotope values, the pigs can be divided into three groups. A group, composed of two
pigs, has low δ13C values (−18.1‰, −20.0‰) and low δ15N values (4.7‰, 6.0‰). B group, only one pig, has the highest δ13C value (−10.6‰) and mediate δ15N value (6.4‰). As for the C group, also only one pig, low δ13C value (−19.0‰) and the highest δ15N value (9.1‰) are observed. Previous studies on the stable isotopes from modern or ancient wild boars’ bones have suggested
that C3 plants are predominated in their diets and that their δ15N values are close to those in herbivores and far from those in carnivores. Based on the comparison with the isotope values
from humans, the wild boars and the domestic pigs from Xipo Site in Henan 6000-5500 years ago and Kangjia Site in Shaanxi
4500-4000 years ago, we conclude that A pig group belongs to wild boars while B and C groups can be attributed to domesticated
pigs.
Supported by Max-Planck Society and Chinese Academy of Sciences, Knowledge Innovation Program of the Chinese Academy of Sciences
(Grant No. KJCX3.SYW.N12), National Natural Science Foundation of China (Grant No. 40702003) and President Funding of Graduate
University of Chinese Academy of Sciences 相似文献
14.
Carbon isotopic studies of individual lipids in organisms from the Nansha sea area, China 总被引:2,自引:0,他引:2
DUAN Yi SONG Jinming & ZHANG Hui . Lanzhou Institute of Geology Chinese Academy of Sciences Lanzhou China . School of Geology Lanzhou University Lanzhou China . Institute of Oceanology Chinese Academy of Sciences Qingdao China 《中国科学D辑(英文版)》2004,47(7):593-598
Sediments contain abundant lipid compounds in general, which are used as biomarker compounds to study organic matter sources and reconstruct the pa-laeoenvironments[1—7]. However, lipid compounds in sediments are generally a mixture of various genetic components so that it is difficult to correctly decouple their biological sources only by the results of bio-chemical researches. Carbon isotopic studies of indi-vidual sedimentary lipid compounds can discover their genetic information, which pr… 相似文献
15.
Antonella Longo Paolo Papale Melissa Vassalli Gilberto Saccorotti Chiara P. Montagna Andrea Cassioli Salvatore Giudice Enzo Boschi 《Bulletin of Volcanology》2012,74(4):873-880
Many volcanic eruptions are shortly preceded by injection of new magma into a pre-existing, shallow (<10 km) magma chamber,
causing convection and mixing between the incoming and resident magmas. These processes may trigger dyke propagation and further
magma rise, inducing long-term (days to months) volcano deformation, seismic swarms, gravity anomalies, and changes in the
composition of volcanic plumes and fumaroles, eventually culminating in an eruption. Although new magma injection into shallow
magma chambers can lead to hazardous event, such injection is still not systematically detected and recognized. Here, we present
the results of numerical simulations of magma convection and mixing in geometrically complex magmatic systems, and describe
the multiparametric dynamics associated with buoyant magma injection. Our results reveal unexpected pressure trends and pressure
oscillations in the Ultra-Long-Period (ULP) range of minutes, related to the generation of discrete plumes of rising magma.
Very long pressure oscillation wavelengths translate into comparably ULP ground displacements with amplitudes of order 10−4–10−2 m. Thus, new magma injection into magma chambers beneath volcanoes can be revealed by ULP ground displacement measured at
the surface. 相似文献
16.
Dajing Cu-Sn-Ag-Pb-Zn ore deposit, in the Inner Mongolia Autonomous Region of China, is a fissure-filling hydrothermal ore
deposit. The δD values of quartz-hosted inclusion water are centered at −100%.– −130%.. The δ34S values of sulfide ore minerals and δ13
C values of carbonate gangue minerals vary from −0.3%. to 2.6%. and from −2.9%. to −7.0%., respectively. Integrated isotopic
data point to two major contributions to the mineralizing fluid that include a dominant meteoric-derived groundwater, and
sulfur and carbon species from hypogene magma. Linear trends are exhibited on the gaseous H2O versus CO2 plot, and plots of CO, N2, CH4, and C2H6. It is shown by quantitative simulation that magma degassing cannot explain the linear trends. Hence, these linear trends
are interpreted in terms of mixing of CO2-rich magmatic fluid with meteoric-derived groundwater. The groundwater circulated in Paleozoic sedimentary rocks and absorbed
CO, N2, CH4, C2H6 and radiogenic Ar from organic matter. Cooling effects resulting from mixing have caused the precipitation of ore minerals. 相似文献
17.
Distribution and significance of C~_(40) alkanes in the extracts of Cretaceous source rocks from the Songliao Basin 总被引:2,自引:0,他引:2
Feng ZiHui Fang Wei Zhang JuHe Li ZhenGuang Huang ChunYan Wang Xue Zhao QinLing Huo QiuLi 《中国科学D辑(英文版)》2007,50(10):1510-1520
Source rock extracts and crude oils from the Songliao Basin were analyzed by high-temperature gas chromatography (HTGC), gas chromatography-mass spectrometry (HTGC-MS) and gas chromatography-isotope ratio-mass spectrometry (GC-IRMS), for high molecular-weight alkanes. The distributions of n-alkanes in the Nenjiang Formation extracts are in the C14―C63 range; a bimodal distribution occurs in the C-21 and C21―40 regions. The C30―C37 n-alkanes are accompanied by C29―C35 hopanes, whereas the high molecular-weight C45―C47 n-alkanes co-occur with abundant isoalkanes, alkylcyclohexanes and alkylcyclopentanes. The high δ 13C values of the n-alkanes and the microscopic maceral compositions indicate a highly diversified organic source input for the Nenjiang Formation source rocks, ranging from aquatic plants, blue alge-bacteria, to land plant material. In contrast, n-alkanes in the rock extracts of the Qingshankou Formation are characterized by a single modal distribution, with relatively low abundances of C29―C35 hopanes, but high molecular-weight isoalkanes, alkylcyclohexanes and alkylcyclopentanes. The relatively low δ 13C values of C22―C44 n-alkanes and organic material compositions indicate that the source rocks in the Qingshankou Formation contain dominantly type I algal organic matter. The relative abundance of C 40 compounds in source rocks changes little at low maturity stage, but decreases drastically at higher maturity levels, with a concurrent reduction in the odd/even carbon predominance. In crude oils, in contrast, the relative abundance of C 40 compounds appears to relate closely with the oil source and oil viscosity. 相似文献
18.
The sorption of Eu species onto nano-size silica-water interfaces is investigated at pH range of 1―8.5 and the initial Eu
concentrations (CEu) of 2×10−5, 2×10−4 and 2×10−3 M using fluorescence spectroscopy. The sorption rate of Eu is initially low, but significantly increases at pH > 4. For the
initial CEu of 2×10−5, 2×10−4 and 2×10−3 M, the dissolved Eu species are completely sorbed onto silica-water interfaces at pH = 4.75, −5.8 and 6.6, respectively,
with the respective sorption densities of −1.58×10−8, 1.58×10−7 and 1.58×10−6 mol/m2. The sorbed Eu species at pH < 6 is aquo Eu3+, which is sorbed onto silica-water interfaces as an outer-sphere complex at pH < 5, but may be sorbed as an inner-sphere
bidentate complex at 5 < pH < 6, due to the decrease of the NH2O to −6 at pH = 6. At pH = 6 – 8, Eu(OH)2+, Eu(CO3)+and Eu(CO3)2
− form in the solutions, and Eu(CO3)+is dominant at pH = −7.5. These ions may be sorbed onto silica-water interfaces as inner-sphere bidentate complexes or multi-nuclear
pre-cipitates. 相似文献
19.
JiaZhu Li GuoAn Wang XianZhao Liu JiaMao Han Min Liu XiaoJuan Liu 《中国科学D辑(英文版)》2009,52(11):1714-1723
Variations in carbon isotopic ratios (δ
13C) of C3 plants and distribution of C4 plants were investigated along an altitudinal transect on the eastern slope of Mount Gongga, and the environmental effects
on them were discussed. It is shown that plants with C4 photosynthetic pathway mainly occur at altitudes below 2100 m a.s.l., suggesting that the low summer temperature is responsible
for the distributional pattern. In addition, δ
13C of C3 plants increases with elevation at the region above 2000 m a.s.l. with the characteristics of humid climate, and the increase
rate in δ
13C for C3 plants is about 1.3% per kilometer. Temperature determines the altitudinal trend of δ
13C. 相似文献
20.
Tao Zhen Shen ChengDe Gao QuanZhou Sun YanMin Yi WeiXi Li YingNian 《中国科学D辑(英文版)》2007,50(7):1103-1114
High-resolution sampling, measurements of organic carbon contents and 14C signatures of selected four soil profiles in the Haibei Station situated on the northeast Tibetan Plateau, and application
of 14C tracing technology were conducted in an attempt to investigate the turnover times of soil organic carbon and the soil-CO2 flux in the alpine meadow ecosystem. The results show that the organic carbon stored in the soils varies from 22.12×104 kg C hm−2 to 30.75×104 kg C hm−2 in the alpine meadow ecosystems, with an average of 26.86×104 kg C hm−2. Turnover times of organic carbon pools increase with depth from 45 a to 73 a in the surface soil horizon to hundreds of
years or millennia or even longer at the deep soil horizons in the alpine meadow ecosystems. The soil-CO2 flux ranges from 103.24 g C m−2 a−1 to 254.93 gC m−2 a−1, with an average of 191.23 g C m−2 a−1. The CO2 efflux produced from microbial decomposition of organic matter varies from 73.3 g C m−2 a−1 to 181 g C m−2 a−1. More than 30% of total soil organic carbon resides in the active carbon pool and 72.8%281.23% of total CO2 emitted from organic matter decomposition results from the topsoil horizon (from 0 cm to 10 cm) for the Kobresia meadow. Responding to global warming, the storage, volume of flow and fate of the soil organic carbon in the alpine meadow
ecosystem of the Tibetan Plateau will be changed, which needs further research.
Supported by the National Natural Science Foundation of China (Grant Nos. 40231015, 40471120 and 40473002) and the Guangdong
Provincial Natural Science Foundation of China (Grant No. 06300102) 相似文献