Hydrochemical Conditions at the Lena River in August 2018

Oceanology - The information is presented on hydrochemical studies performed in August 2018 at the middle and lower reaches of the Lena River from Yakutsk to Kyusyur settlements. The studies...     

Peculiar features of the thermohaline and hydrochemical water structure in the southeastern Laptev Sea

The thermohaline and hydrochemical characteristics of the Lena River’s estuarine zone were investigated in the Buor-Khaya Bay and the southeastern Laptev Sea in September of 2005. A tongue of river water with high nutrient content and increased turbidity was identified in the bay. It is shown that the two-layer structure in the bay is disturbed by warm freshwater lenses. The strong vertical stratification in the shelf zone results in sharply contrasting characteristics of the surface and bottom waters. It is established that the concentrations of biogenic elements regularly change depending on the thermohaline characteristics of the waters and their stratification degree. Stagnant bottom waters with low dissolved oxygen contents and high concentrations of phosphates, nitrates, and ammonium are recorded in the eastern part of the bay. The bottom waters have different hydrochemical characteristics due to their different origin.     

Distribution and sinking rates of phytoplankton, detritus, and particulate biogenic silica in the Laptev Sea and Lena River (Arctic Siberia)

Concentrations and sinking rates of particulate biogenic silica (BSi), chlorophyll a (chl a) and phaeopigments (phae) (< 3 μm, 3–10 μm, > 10 μm and total), as well as the abundances of the major phytoplankton species, were studied during September 1991 in the Eastern Laptev Sea and the lower Lena River (Siberian Arctic). The highest chl a concentrations were found in two major “new” production regimes of the study area: (1) a deep chl a maximum (5.8 mg chl a m⁻³) (formed by the diatom Chaetoceros socialis) at 30 m depth on the outer shelf of the northern Laptev Sea, and (2) in the Lena River, where the phytoplankton community was dominated by fresh water diatoms (1.5 to 4.5 mg chl a m⁻³). Elevated chl a concentrations were also found in the river plume phytoplankton community (dominated by brackish water diatoms), NE of the Lena delta. In the Laptev Sea, the low chl a (0.1 to 3 mg chl a m⁻³) and high phae concentrations (0.5 to 14 mg phae m⁻³) indicated that the phytoplankton community (dominated by picoplanktic algae and nanoflagellates) was already senescent and affected by grazing losses. Biogenic silica values were highest in the Lena River (4 to 17 μM) as compared to the low values found in the Laptev Sea (0.3 to 4 μM). The large chl a size fraction, phae and BSi in the Lena River samples revealed the highest measured sinking rates (1.4, 2.3, and 1.5 m d⁻¹, respectively). The formation of a strong halocline, decreasing turbulence, and possible nutrient deficiency resulted in death, disintegration and rapid sedimentation of fresh water diatoms. This was accompanied by a decrease in the BSi concentration and growth of the picoplanktic size fraction (< 3 μm) in the estuarine mixing zone (Gulf of Buorkhaya). Only a minor part of BSi was bound to intact diatom cells (< 3%) in the surface layer, most of which being apparently associated with detrital particles. In the Lena River, approximately 12% of the total silica was bound to BSi fraction, yet elsewhere in the Laptev Sea and in the estuarine mixing zone the BSi:total silica ratio was ≤ 5%. Thus, the results reflected the successional stage of a late summer phytoplankton community, characterized by dominance of small autotrophs and patchy distribution of senescent diatoms no longer able to affect the relative high levels of dissolved silica supplied by the Lena River.     

Hydrochemistry of the Tumen River Estuary,Sea of Japan

The hydrological and hydrochemical parameters of the Tumen River estuary were collected at 13 stations in May and October 2015. Vertical temperature, conductivity, dissolved oxygen, chlorophyll fluorescence, and turbidity profiles were obtained. Water was sampled from the surface and bottom layer. The water samples were analyzed for major ions, pH, salinity, concentrations of dissolved oxygen, major nutrients, dissolved organic carbon, humic matter, and δ¹⁸О and δD isotopes. This estuary is attributed to microtidal type with a flushing time of about 10 h. A phytoplakton bloom occurred in the top layer of the estuary. For surface horizons, the hydrochemical parameters show a linear correlation with salinity. In the bottom horizons, all these parameters, except for major ions and δ¹⁸О and δD isotopes, reveal substantial nonconservative behavior. The nonconservative behavior of the hydrochemical parameters in the bottom waters was mainly caused by degradation of the phytoplankton biomass at the water/sediment interface. Hypoxic conditions were established in the bottom waters of the estuary in May.     

Methane in Water and Bottom Sediments in Three Sections in the Kara and Laptev Seas

The methane content in water and bottom sediments was measured in vertical sections: Lena River Delta–continental slope (the Laptev Sea), Taimyr Peninsula–Voronin Trough, and along the Novaya Zemlya Archipelago. The methane concentrations varied from 2.5 to 70 nmol/L and from 590 to 2600 nmol/L in the water column and sediments, respectively. Most of the surface water samples showed oversaturation in methane (up to 19-fold, fourfold on average), which determined the water–atmosphere direction of methane fluxes, which amounted to 1–400 mol/km² day (52 mol/km² day on average).     

Hydrochemical Structural Patterns of the Lena River–Laptev Sea Mixing Zone in the Autumn Period

Oceanology - This study was based on data obtained during the cruise 63 of the R/V Akademik Mstislav Keldysh in September 2015. We examine the features of the hydrochemical structure of the Lena...     

O abundance and dissolved silicate in the Lena delta and Laptev Sea (Russia)

Water samples from the Lena River and stratified Laptev Sea (northeastern Siberia) have been analyzed to determine their stable oxygen isotope composition (¹⁸O/¹⁶O). Measurements at the Lena River reference station give a δ¹⁸O value of −18.9‰ in both surface and bottom waters. In the brackish water surface plume, a nearly perfect correlation is found between δ¹⁸O and chlorinity

δO=−18.9+0.7C1⁻(n=15; r=0.999)

A few values lie distinctly below this correlation; they all correspond to surface samples collected in the semi-enclosed Buorkhaya Gulf, and they most likely reveal the occurrence of ‘old’ water masses. Some of the δ¹⁸O values in the deep waters collected in the same zone also fall below the surface-plume correlation line.Dissolved silicate concentrations exhibit a large variability. However, when they are related to the different water masses identified using oxygen isotope data, a more coherent picture is obtained. Concentrations in the surface plume decrease more or less regularly from 50 to 72 μmol in the Lena River, to 7 μmol at the ‘marine’ end-member (Cl⁻ = 14 g l⁻¹). Dissolved silicate results in the Buorkhaya Gulf are quite distinct, with a clear deficiency in the surface waters, and an excess in the deep waters.These δ¹⁸O and dissolved silicate variations are discussed in relation to the hydrology and the biological productivity of the investigated area.     

Shallow-Water Gasohydrothermal Vents of Ushishir Volcano and the Ecosystem of Kraternaya Bight (The Kurile Islands)

Abstract. A marine ecosystem in the crater of the Ushishir Volcano (Kraternaya Bight, Yankich Island, the Kuriles) showing gasothcrmal activity was studied for hydrographical, hydrochemical, and biological characteristics. Maximal changes in chemical and biological characteristics were observed in the surface water layer of 0–5 m. This layer had higher water temperature, was saturated with volcanogcnic carbon dioxide (up to 2000 10^-6 torr), ovcrsaturatcd with oxygen (up to 200 %), and contained high concentrations of chlorophyll a. Hydrogen sulfide was found in the surface water layer and at a depth of 15 m in the area of maximal effect of volcanic effluents.
The planktonic community is characterized by high rates of production and destruction of organic matter only in the 0–5 m layer. Daily vertical migrations of the ciliatc Mesodinium rubrum were observed, which caused "red tides".
Bacterial, algobacterial, and diatom mats developed on the bottom of the bight in the zone of gasohydrothermal vents and in areas of volcanic water seeping. The rate of organic matter production in algobacterial mats reached 33.4g C-rrr²-d^-l, chcmolithotrophy predominating. Bottom settlements had high population density and great animal biomass, which reached 10 kg m^-2 in gasohydrothermal fields. They obtain sufficient energy from primary production of microphy-tobenthos, algobacterial, and bacterial mats. Bcnthic species dominant in the bight were not found off the Ushishir Islands.
Some species of macrobenthos inhabiting the Kraternaya Bight differ markedly in size and biomass from the same species found beyond the bight.     

夏季黄东海颗粒有机碳的分布特征

根据2006年6～7月对黄东海大面调查的资料,分析研究了黄东海颗粒有机碳(particulate organic carbon,POC)的浓度和分布特征。结果表明,夏季黄东海POC的浓度范围是6.07～2 204.17μg.L-1,平均浓度为147.15μg.L-1。POC整体上呈现近岸浓度较高、远岸浓度较低,北部浓度较高,南部浓较低的分布特点;在长江口外及浙江近岸海区存在POC的高值区,特别是长江口外,表层和底层POC浓度很高,这主要是受到长江陆源输入的重要影响。在垂直分布上,南黄海区POC的浓度分布整体上呈现上层水体浓度较低,下层水体浓度较高的特点,这主要是受底质再悬浮的影响。而东海区呈现近岸POC浓度较高,离岸POC浓度较低的特点,这主要是受长江冲淡水输入的影响。     

Seasonal Dynamics of Biogeochemical Processes in the Water Column of the Northeastern Black Sea

Integrated studies on the hydrochemistry and water column rates of microbial processes in the eastern sector of the Black Sea along a standard 100-miles transect off Gelendzhik from the coast to the central part of the sea at water depths of 100–2170 m show that a series of warm winters and the absence of intense convective winter mixing resulted in a relatively low content of suspended particulate matter (SPM), particulate organic carbon (POC), and nutrients in the water column in March 2009. The relatively high SPM concentrations and the presence of isotopically light POC at the offshore station are indicative of the supply of terrigenous material from land and low contributions of phytoplanktonic organic matter to the composition of SPM. This may explain the low rates of biogeochemical processes in the water column near the coast. The surface layer at deep-water stations is dominated by isotopically heavy phytoplanktonic organic matter. This suggests that the supply of terrigenous material from land was insufficient in offshore deep-water areas. Therefore, warm winters and insufficient nutrient supply do not prevent photosynthesis in the photic layer of the deep-water zone, which generates organic substrates for heterotrophic aquatic communities. The results of isotopic analysis of POC, measurements of the rates biogeochemical processes, and the hydrochemical characteristics of the water column can be used to determine the nature and seasonal variability of the POC composition.     

珠江口夏季水体中的氮和磷

根据1999年7月17～28日于珠江口现场调查和实验的资料,研究夏季水体中氮、磷的分布、形态变化和初级生产力的限制因素.结果表明该海域氮含量高,N/P属于世界上高值区之一.从河口向外海运输过程中,氮和磷的形态和浓度均有剧烈的变化.虽然氮在中途中有新源的补充;但由于外海水的入侵稀释、生物吸收和形态变化的迁移作用,NO₃-和可溶无机氮的浓度总的变化趋势仍是随盐度增大而大幅度地降低,以至珠江口外出现N/P低于16.由于夏季水体层化稳定,在表、底层其生物地球化学变化方向相反,PO₄3的浓度变化互成镜像关系并可按盐度分为3段不同特征的反应区.初级生产力的限制因素在大部分区域是磷,但从口门至最大浑浊带和口外区则分别是浊度(或光照)及可溶无机氮.现场培养实验再现了真光层和底层氮和磷的生物地球化学过程差异并表明磷的循环和再生比氮迅速;在可溶无机氮浓度大且高N/P的海域,磷的再生可成为水华的引发因素,而氮被耗尽却是水华消亡的原因.总体上夏季该区水体氮的迁出率比磷高.于水体层化稳定的区域,氮和磷的生物地球化学作用在真光层以浮游生物吸收占优势、在下层以有机物的降解和可溶无机态的再生为主,当层化消失、上下水体充分混合则可完成循环.     

北极拉普捷夫海夏、秋季颗粒有机碳的分布与来源

随着全球变暖的加剧,北极陆架边缘海碳的源汇过程对全球碳循环的影响及其气候环境效应日益显著。拉普捷夫海作为北冰洋典型的陆架边缘海,在大河、海冰、海洋初级生产力及海岸侵蚀的影响下,该区沉积有机碳的来源、输运和埋藏等过程独具特色。本文基于2018年中俄第二次北极联合科考获得的悬浮颗粒物样品和水文资料,研究了夏末秋初拉普捷夫海颗粒有机碳的分布特征、来源及其影响因素。结果表明,颗粒有机碳（POC）的浓度位于35.27～1 185.58 μg/L之间,平均为172.65 μg/L。受河流输入、海岸侵蚀和海洋初级生产力的影响,表层POC浓度分布呈现近岸高、远岸低趋势;底层POC浓度分布主要受控于沉积再悬浮作用,高浓度POC出现在勒拿河三角洲的东部区域。总悬浮颗粒物浓度与POC浓度总体呈显著正相关,显示出其对POC空间分布的直接影响,且两者在底层中的相关性要高于表层,表明不同层位的POC可能存在来源差异。研究区POC的δ13C值处于?31.03‰～?25.79‰之间,表层δ13C值较底层明显偏负,且部分站位的δ13C值甚至低于周边陆源有机碳的端元,这反映了可能除陆源输入的贡献外,近海浮游植物直接利用大量陆源有机质降解产生的溶解无机碳的过程也对该区域POC的供应和来源解析具有重要的影响。     

长江口及其邻近海区环流和温、盐结构动力学研究III 温度结构

数值模拟结果表明: 冬季长江口及其邻近海区温度分布为近岸低, 外海高; 近岸和海底地形变化缓慢区温度呈垂直均匀分布, 海底地形变化显著的陡坡区生成温度锋; 外海深水区的中上层温度低且呈垂直均匀分布, 底层温度高并形成弱的分层。春季, 近岸温度高、外海低; 近岸温度大致呈垂直均匀分布, 外海出现明显分层; 长江口以北温度表层低、底层高; 长江口及其以南表层和底层温度低, 而中层高; 陡坡区至外海生成温度锋, 随着温度锋自陡坡至外海的下移,锋面以上温度逐渐变为垂直均匀分布, 而锋面以下温度却大致呈水平均匀分布。夏季, 海区的温度分布和春季一样, 为近岸高、外海低; 长江口及其以南近岸浅水区温度呈垂直均匀分布; 长江口以北和长江口及其以南的外海温度自表层至底层由高变低且大致呈水平均匀分布, 并在表层至次表层生成强温跃层, 跃层强度随水深增加迅速减弱, 深底层温度几乎呈均匀分布且保持低温特征。秋季, 海区的温度分布与冬季相同, 也为近岸低, 外海高; 在长江口以北, 近岸温度为表层高, 底层低; 外海底层温度低且大致呈水平均匀分布, 而底层以上温度高且大致呈垂直均匀分布; 长江口及其以南, 近岸温度呈垂直均匀分布, 陡坡至外海的表层至底层生成弱的温度锋,随温度锋自陡坡至外海的下移, 锋面以上温度逐渐变为垂直均匀分布, 长江口以南陡坡区的底层温度几乎呈均匀分布。     

黄河三角洲海底土波致再悬浮研究

在现代黄河三角洲采集土样,制备室内水槽试验的底床,施加波浪作用,观测波致悬沙含量的变化规律,分析不同波高、作用时间对单位面积底床再悬浮量的影响,及波浪停止作用后悬浮泥沙的静水沉降规律。研究发现,在水深一定条件下底床再悬浮量呈现随波高增大而增大的特性,两者线性拟合的相关性很好;在一定波高的波浪连续作用下,约5 000~6 000个波周期底床再悬浮过程完成;在波浪作用初始阶段底层悬沙含量与中上层的相差很大,悬沙含量垂线结构呈斜线型,稳定阶段的悬沙浓度垂向结构呈准直线型,底层与表层含沙量比值为0.98~1.25,整个水层含量分布均匀;静水沉降过程中当悬沙含量大于1 g/dm3,悬沙含量(SSC)呈现出随时间指数衰减的规律,悬沙浓度与沉降通量呈线性关系。研究结果对认识黄河水下三角洲泥沙运移规律具有一定的科学意义。     

Distribution of trace and major elements in sediment and pore waters of the Lena Delta and Laptev Sea

Sediment cores collected during the SPASIBA expedition in 1991 were analysed for their trace- and major element concentrations. Leachable (0.1 N HCl) as well as residual concentrations were determined. Fe and Mn were measured in the interstitial waters to characterize redox conditions. Lateral distribution patterns of solid phase Cu, Cd, Ni, Pb and Zn show a small increase in concentration from the Lena Delta in seaward direction. In general concentrations of these metals are very low and similar to natural background values. With some exceptions, solid phase profiles with depth of all investigated elements do not show strong variations. No enrichment of Pb and Zn in surface layers was found. Remobilization processes and transport of particles enriched in Mn are responsible for Mn accumulation in a particular area. Pore-water concentrations of dissolved Mn in the latter sediments are very high (> 700 μM) and suggest strong Mn reduction directly below the sediment-water interface. In contrast to Mn, the depth profiles of Cd show a surface layer with lower concentrations and an increase deeper down the sediment. The C/N ratio in the sediment decreases from 13 in the Lena mouth to 9 in the more marine part of the Laptev Sea. Surface sediments in the Laptev Sea are very uniform and homogeneous and show only small concentration gradients.     

西南黄海2018年夏季溶解氧分布特征及其影响因素的初步分析

利用2018年夏季在西南黄海的现场调查资料,分析了海温、盐度和溶解氧(dissoloved oxygen,DO)分布特征.海区西侧的江苏沿海有明显的冷水带,冷水带对应表层较高的DO浓度.在海区南侧的长江口附近,盐度由南向北升高,上部海水DO浓度高,下部海水DO浓度低.综合现场观测数据、CCMP (Cross Calib...     

Coastal currents adjacent to the Caeté Estuary,Pará Region,North Brazil

We examined and compared tidal currents and water column structure between a near-shore station (12 km from the coast) and an offshore station (32 km from the coast) adjacent to the Caeté River, Pará Region, Brazil. Although the coastal system of Pará is largely influenced by local tides and wind, we found substantial differences in the dominant forcing agents between stations. Water column dynamics at the near-shore station were largely affected by local tidal processes, while differences between surface and bottom layer flows also indicated the importance of gravitational circulation at this station and a substantial influence of the adjacent Caeté River discharge. In comparison, at the offshore station, water column structure was largely influenced by a semi-diurnal tidal flow, an along-coastal current flow (mainly associated with the North Brazil Current) and the dynamics of local wind flow. The near-shore station at low tide showed a high level of stratification; at high tide such stratification was reduced. In comparison, stratification was only apparent within the upper 6 m at the offshore station, the rest of the water column was relatively well-mixed. The stratification within Station 1 at low tide was a result of the bi-directional movement of water discharged from the Caeté River, with lower salinity surface water and high salinity bottom water resulting in an estuarine-like circulation environment. The spatial variability and lack of correlation in current flow and water column structure between the near-shore and offshore stations suggest that a flow field resulting from differences in local circulation, tidal variability and wind persistence separate areas. We argue that this separation may indicate that the offshore station is located in a transition region between the Caeté River waters and the local coastal area.     

2012年春季渤海中部及邻近海域叶绿素a与环境因子的分布特征

分析了2012年春季渤海中部及其邻近海域32个站点叶绿素a和环境因子的空间分布特征及其相互关系。结果发现:渤海中部靠近黄河口邻近水域相对于其他水域,呈现出相对较高的水温和较低的盐度,这与黄河淡水输入以及近岸水深相对较浅有密切关系。营养盐浓度在空间分布上表现为黄河口附近海域较高,在垂直分布上表现为中、底层高于表层,显示出黄河水输入与沉积物营养盐再释放的影响;此外,营养盐浓度与结构显示,渤海海域存在明显的磷和硅限制,磷限制尤其严重。叶绿素a浓度的空间分布显示,表层叶绿素a浓度的高值区出现在渤海湾湾口处,而中层与底层的叶绿素a浓度高值区出现在渤海中部。主成分分析结果表明,磷酸盐和温度是影响表层叶绿素a浓度的重要因素,而中、底层叶绿素a浓度主要受磷酸盐的影响。     

Identification of local upwelling zones in the Bering Sea using hydrochemical parameters

Based on the data for the oxygen in the surface layer of the Bering Sea, the areas of pronounced undersaturation (down to 75–80% and below) were distinguished in the surface layer of the Bering Sea. The low percentage values as such of the oxygen saturation might be sustained at the sites of quasi-stationary upwellings. However, in this case, the surface layer should be characterized by decreased temperature and increased salinity as related to the surrounding waters, as well as by increased concentrations of nutrients (phosphates, nitrates, and silicon). The corresponding tests showed that most of the distinguished “patches” of oxygen undersaturation were verified by the oceanological parameters; i.e., these were local upwellings. Some of them were studied quite thoroughly (even with the mechanisms proposed for the formation of steady water lifting), particularly in the area of the Aleutian Islands. However, there are some poorly studied areas (so-called questionable ones) at which the low oxygen content is not confirmed by the hydrochemical parameters (plainly, they are not available); this requires more profound and detailed study.