海水悬浮物浓度原位测量技术进展

海水悬浮物指海水中的悬浮颗粒物和浮游微生物等，对海水悬浮物浓度进行准确的测量具有重要的意义。海水悬浮物浓度测量技术，无论是传统方法（即现场采水），还是现代方法（即间接测量方式，包括光学法和声学法等）都有一定的不足。本文主要综述了几种海水悬浮物浓度间接测量方法、国内外有关海水原位过滤测量的技术研发进展及深海原位微孔过滤技术。最后，对海水悬浮物原位过滤技术的发展方向进行了探讨。     

渤海海峡悬浮体分布、通量及其季节变化

渤海海峡是渤黄海物质交换的重要通道,同时也是黄河入海泥沙向黄海搬运的必经路径。本文以2006—2009年渤海海峡8个站位四个季节的悬浮体、CTD数据为基础,将标准层悬浮体浓度数据与浊度数据对比获得高垂直分辨率的悬浮体浓度数据,分析其季节变化特征,并结合日均风场驱动的高精度数值模型模拟的渤海海峡流场,计算了四个季节渤海海峡悬浮体通量。结果表明,北黄海冷水团的入侵和退缩是渤海海峡温盐及其季节变化的重要特征之一,四季节流场特征均为"北进南出";渤海海峡中上层悬浮体浓度分布为海峡南部浓度高、北部浓度低,夏季海峡北部下层北黄海冷水团控制海域悬浮体浓度高于周围水体。春季、夏季、秋季、冬季悬浮体浓度依次增高。观测期间渤海海峡悬浮体的年净通量约为251.63万吨,其中输往黄海方向的悬浮体通量约占黄河年平均输沙量的4.27%。     

遥感技术在河口颗粒态总磷分布及扩散研究中的应用初探

以美国SeaStar卫星装载的SeaWiFS海洋水色遥感传感器作为遥感数据源,实测了光谱、海表温度、悬浮物含量、透明度、叶绿素浓度、颗粒态总磷含量等,建立了传感器悬浮物含量和颗粒态总磷含量的遥感信息提取模式,结果表明:(1)利用遥感技术估算的海水悬浮物的平均相对偏差为18.1%;(2)悬浮物在遥感图象上的分布和扩散趋势与实际吻合,并且在一定程度上反映了区域内海流运移路径;(3)颗粒态总磷含量在长江河口和杭州湾附近海域较高,由近岸向远岸迅速降低,与实际分布相符;(4)模型主要适用于河口等悬浮物含量高的Ⅱ类水休,对于以浮游植物为主的Ⅰ类水体应另外建立模式.     

Deep slope currents and suspended particle fluxes in and around the Foix submarine canyon (NW Mediterranean)

Deep slope currents and particulate matter concentrations were studied on the Barcelona continental margin in and around the Foix submarine canyon from May 1993 to April 1994. This year-long moored experiment revealed that near-bottom slope currents are strongly influenced by the bottom topography, being oriented along isobaths and along the canyon axis. The deep slope current fluctuations are controlled by the local inertial motion (18.3 h) and also by low-frequency oscillations at periods of 6–10 days, related to the passage of atmospheric pressure cells. Particulate matter concentrations recorded during the experiment do not show a clear seasonal variability, except outside the canyon, where significant peaks of particulate matter concentrations were recorded only during the winter-fall deployment. In addition, the temporal evolution of suspended particulate matter concentration is not linked to changes in the cross-slope or along-slope current components and did not show a clear relationship with river avenues or wave storm events. This suggests that suspended particulate matter exported from the shelf is dispersed on the slope by advective processes, which attenuate the signal of the shelf-slope sediment transfer. Mean particulate matter concentrations differed among sampling sites, but the magnitude of the mean horizontal suspended particle flux reflects a quite similar value in the whole study area, ranging from 2.53 to 4.05 mg m⁻² s⁻¹. These horizontal suspended particle fluxes are 27 (canyon head) to 360 (open slope) times higher than the settling particle fluxes measured at the same sampling sites, indicating that the suspended particulate transport on the Barcelona continental slope dominates over the settling particle fluxes, even inside the Foix submarine canyon.     

A large volume particulate and water multi-sampler with in situ preservation for microbial and biogeochemical studies

A new tool was developed for large volume sampling to facilitate marine microbiology and biogeochemical studies. It was developed for remotely operated vehicle and hydrocast deployments, and allows for rapid collection of multiple sample types from the water column and dynamic, variable environments such as rising hydrothermal plumes. It was used successfully during a cruise to the hydrothermal vent systems of the Mid-Cayman Rise. The Suspended Particulate Rosette V2 large volume multi-sampling system allows for the collection of 14 sample sets per deployment. Each sample set can include filtered material, whole (unfiltered) water, and filtrate. Suspended particulate can be collected on filters up to 142 mm in diameter and pore sizes down to 0.2 μm. Filtration is typically at flowrates of 2 L min⁻¹. For particulate material, filtered volume is constrained only by sampling time and filter capacity, with all sample volumes recorded by digital flowmeter. The suspended particulate filter holders can be filled with preservative and sealed immediately after sample collection. Up to 2 L of whole water, filtrate, or a combination of the two, can be collected as part of each sample set. The system is constructed of plastics with titanium fasteners and nickel alloy spring loaded seals. There are no ferrous alloys in the sampling system. Individual sample lines are prefilled with filtered, deionized water prior to deployment and remain sealed unless a sample is actively being collected. This system is intended to facilitate studies concerning the relationship between marine microbiology and ocean biogeochemistry.     

Light scattering and suspended particulate matter in the Arctic Ocean north of Ellesmere Island

Light scattering profiles and water samples for filtration of suspended particulate matter were obtained during fall, 1973, from Ice Island T-3, then located about 50 miles north of Ellesmere Island. The profiles reveal almost no variability in scattering, either in the water column, or in time during our two weeks of field work. Gravimetric analysis of the filtered suspended particulate matter shows that mass concentrations are low, averaging about 7g l^–1, and that they too remain very constant. The four water masses present in the Arctic Ocean could not be distinguished by our observations of light scattering and mass concentration of suspended particulates.     

Chemical determination of particulate nitrogen in San Francisco Bay. A comparison of two estimates

Particulate nitrogen was measured by both the ultra-violet light-catalyzed peroxide method and the high temperature combustion method. The difference between values obtained with the two methods (combustion minus UV) was found to be linearly correlated with the concentration of total suspended particulate matter (SPM) in the sample. The slope of this correlation was taken to be the concentration of refractory nitrogen associated with the suspended matter, which may be ammonium ions fixed in lattices of clay minerals or organic nitrogen compounds did not vary significantly with SPM, location, water depth or salinity. Refractory nitrogen concentration were possibly related to concentrations of chlorophyll a and to cruise date, but in neither case was the evidence conclusive. Based on the indirect evidence presented, the UV method appears to provide a good measure of biologically reactive nitrogen in this system.     

三峡截流后长江口秋季TSM、POC和PN的分布特征

基于2004年11—12月长江口56个站位的悬浮体调查资料,分析了长江口区悬浮体总量(TSM)、颗粒有机碳(POC)和颗粒氮(PN)质量浓度的平面分布特征,探讨该区TSM及颗粒有机质的物质来源和三峡截流对长江三角洲的影响。结果表明,表、底层TSM与POC、PN质量浓度之间存在显著的正线性相关关系并都呈现出南高北低的格局,说明了长江悬浮颗粒物入海后主要沿东南方向输运。POC、PN质量分数与POC、PN的质量浓度不同,它们与TSM质量浓度对数有负相关关系。由于河口区底质再悬浮作用显著,TSM和POC、PN质量浓度呈现表层低、底层高的特点。长江口悬浮体主要来自长江径流和底质沉积物的再悬浮。与三峡截流前数据的对比表明,截流对目前长江口区的TSM和POC尚未造成明显的影响。     

Chemical studies on organic matter and carbon cycle in the ocean

Chemistry of organic materials of the suspended and sinking particles, and the evaluation of the particulate materials for the carbon cycle of the ocean are described in this paper. Organic carbon (POC) and nitrogen (PON) of the suspended particles collected from various areas of the North through South Pacific were determined with considerably high variabilities in their concentration. Higher values of the POC and PON were obtained in the surface water of the higher latitudinal areas of both northern and southern hemispheres and the equatorial Pacific, while the lower values of these organic elements were measured in the middle latitudinal areas of the Pacific. These facts clearly indicate that inorganic nutrients supply to the surface water layers from the underlying water is primarily determinative factor to govern the concentration of the POC and PON in the surface water layer. POC and PON concentrations in the intermediate through deep waters, however, are much less variable in time and space. Carbohydrates, free and combined amino acids and lipid materials were major organic constituents of the suspended particles. The organic composition of the particles was extensively variable in region, time and depth. Such change in the organic composition was mainly caused by the production and decay of the free and combined amino acids, lipid materials and water extractable carbohydrate. Sinking particle which has high sinking rate over 100 m day⁻¹ and can be collected only by sediment trap, also consists of carbohydrates, free and combined amino acids and lipid materials. A detailed analysis of the particle indicate that the sinking particle was much different from the suspended particle from the intermediate through deep waters in terms of the abundance of the biologically susceptible organic materials such as unsaturated hydrocarbon, fatty acid and water extractable carbohydrate often found in phytoplankton. These facts clearly indicate that the sinking particle plays an important role on the vertical transport of the biologically susceptible organic materials from the surface water to the deep water. Vertical flux of organic materials in various water depths was extensively measured in the North Pacific and Antarctic Ocean using the depth-series sediment trap system to collect the sinking particles from various depths of the waters. Regional and seasonal variabilities of the organic carbon flux at the various depths were obviously observed, however the attenuation rate of the organic carbon flux in the intermediate through deep water was not changed so much irrespective of the sampling time and region. The time-series sediment trap system was also using to determine the seasonal variation of the organic carbon flux. An average organic carbon flux at 1 km depth from this trap system was almost comparable to the amount of organic carbon degraded in the water deeper than 1 km depth, which was calculated from oxygen consumption rate of the deep water. Thus, it is clear that the sinking particle must play an important role in the carbon cycle of the deep water.     

Stable Isotopic Composition of Particulate Organic Carbon in the Caspian Sea

The data on the isotopic composition of particulate organic carbon (δ¹³C_POC) in the Caspian Sea water in summer–autumn 2008, 2010, 2012, and 2013 are discussed in the paper. These data allowed as to reveal the predominant genesis of organic carbon in suspended particulate matter of the active seawater layer (from 0 to 40 m). The δ¹³C_POC =–27‰ (PDB) and δ¹³C_POC =–20.5‰ (PDB) values were taken as the reference data for terrigenous and planktonogenic organic matter, respectively. Seasonal (early summer, late summer, and autumn) variations in the composition of suspended particulate matter in the active sea layer were revealed. A shift of δ¹³C_POC towards greater values was seen in autumn (with a slight outburst in the development (bloom) of phytoplankton) in comparison with summer (with large accumulations and an extraordinary phytoplankton bloom confined to the thermocline area). The seasonal dynamics of autochthonous and allochthonous components in the suspended particulate matter of the Middle and Southern Caspian Sea was studied with the use of data on the concentration of particulate matter and chlorophyll a, the phytoplankton biomass and the POC content.     

Correcting the errors from variable sea salt retention and water of hydration in loss on ignition analysis: Implications for studies of estuarine and coastal waters

The standard technique of determining the concentrations of total suspended solids (TSSs), particulate inorganic matter (PIM), and particulate organic matter (POM) by filtration with glass fiber filters is subject to an error or bias from sea salt plus water of hydration retention, when applied to saline waters. The sea salt plus water of hydration retention by the filters occurs even after washing the filter with 300 ml of deionized water, a greater volume than any wash recommended in the literature. We determined that the mass retention on a glass fiber filter, at a given salinity, is essentially constant, no matter the volume of seawater passed through the filter. We also determined that the sea salt plus water of hydration retention on glass fiber filters is directly proportional to the salinity of the seawater filtered. Sea salt plus water of hydration retention causes an overestimate of TSS; sea salt retention causes an overestimate of PIM; volatilization of water of hydration causes an overestimate of POM. Thus a correction curve is required for sea salt and water of hydration errors in the determination of TSS and PIM. Corrected POM comes from the difference between the two. Also, filter blanks (procedural control filters), run with deionized (DI) water rather than the seawater sample, are required to correct for possible filter mass loss during the analysis. We demonstrate correction curves for sea salt plus water of hydration retention for Whatman GF/F filters, 47 mm diameter, utilizing the methods of the APHA Manual, Standard Methods for the Examination of Water and Wastewater. Application of other glass fiber filter types or an analytical technique differing significantly from that employed here requires a different correction curve for retention of sea salt and water of hydration. These methods can be used to reanalyze older data on PIM, POM, and TSS.We apply these corrections to PIM and POM data from the northern Gulf of Mexico and examine the interactions of these filter corrections with corrections for structural water volatilization from suspended clay minerals in the determinations of PIM and POM. We analyze published data on PIM and POM determinations and their application to remote sensing. We conclude that sea salt and water of hydration retention on filters has an adverse effect on remote-sensing algorithms inverting radiance reflectance to estimate concentrations of suspended matter.     

Latitudinal distribution and origin of particulate silica in the surface water of the North Pacific

The concentrations of particulate silica and inorganic suspended matter in the surface water of the North Pacific were determined. The concentration of particulate silica depends on latitude, and increases with increasing degree of the north latitude. The concentration of inorganic suspended matter shows a similar distribution pattern, but it is of much smaller magnitude. There exists a high positive correlation between the concentrations of particulate silica and nutrients. On the other hand, a weak negative correlation is found between the concentrations in surface seawater of particulate silica and radioactive ²¹⁰Pb which originate chiefly from precipitation and dry fallout. This evidence suggests that the particulate silica in the sea is mainly of biogenic origin and the contribution of nonbiogenic silica, i.e., of terrestrial origin, is small.     

潮间带水沙多层位同步测量系统应用的初步研究

利用水压、光电转换原理研制成的多层位水沙同步测量系统(WCT系统)不仅可测量潮间带水位随时间的变化系列、同一层位的浊度及流速，还可以同步观测这些参数在潮间带水流剖面不同层位上的变化。野外对比试验表明，WCT系统获得的流速值与直读式流速仪的测量结果基本一致，平均相对误差为14．52％；悬沙传感器经野外现场率定获得悬沙浓度，平均相对误差为21．96％，精度比室内率定提高—倍以上。悬沙粒径是影响悬沙浓度测量精度的主要因素。此外，自然环境(如海水温盐度)的变化及仪器本身的特性也可能影响到测量结果。因此，WCT系统在潮间带的水位、流速和悬沙浓度的观测和边界层研究方面有相当潜力。     

太平洋悬浮体特征及近底雾状层(雾浊层)探讨

2005年在太平洋12个测站分层采集了悬浮体水样及连续的水体温度、盐度、深度等数据.利用水体悬浮体含量在垂向上的分布特征初步分析了大洋雾状层的特点,并讨论了水体中悬浮体颗粒物质的来源,对不同海洋环境中悬浮体分布进行了对比,发现大洋水体中悬浮体含量总体很小,一般不超过0.30mg/dm3,但在一定水层内悬浮体含量相对较高,形成雾状层.雾状层在大洋内广泛分布,一般以表层雾状层和近底雾状层形式存在.大洋水体中悬浮体颗粒物来源广泛.表层雾状层的形成主要受透光层内生物作用的影响,而底质沉积物的再悬浮是影响底部雾状层形成的重要因素.因受水体物理海洋环境和物质来源的影响,不同区域水体中悬浮体含量不同,雾状层的分布不同.海山顶部受水流及岩石基底影响雾状层分布不明显,海山底部与开辟区洋盆海域雾状层更普遍.开辟区东西区由于物源差异水体中悬浮体含量差别明显,靠近火山喷口的西区水体中悬浮体含量明显高于东区的.     

关于定量监测悬浮泥沙浓度方法的回顾和展望

获取近岸水体中悬浮物浓度及相关信息对于理解和管理海洋环境相当重要。历史上对于悬浮物浓度的监测往往通过费时费力的出海观测,而这种观测具有很大的局限性,每次观测只能获取一个站位的信息。为了更快更有效的获得即时悬浮物浓度相关信息,很多新的监测手段及相关科技被开发及应用。各种机载,卫星载遥感设各被用于获得及时,全面的沉积物信息...     

Slope transport of suspended particulate matter on the Aquitanian margin of the Bay of Biscay

Spatial and temporal characteristics of the water masses and the dispersion of the suspended particulate matter were investigated using current meter, hydrographic and nephelometric observations, gathered during the ECOFER experiment (1989–1991) in the Cap-Ferret Canyon on the Aquitanian margin of the Bay of Biscay. While characteristics of the deep water masses were stable from one year to another, large hydrographic change in the upper 500 m related to winter renewal induced by poleward advection of warm and saline water along the continental slope. The slope circulation and seasonal eddy activity appear as important dynamical mechanisms that control the entrainment and the dispersion of the suspended particulate matter from the neritic domain to the deep ocean. A predominantly northward along-slope current with occasional reversal characterizes this circulation. The nephelometric structures also showed seasonal changes in the overall suspended particulate matter content, but recurrent features, such as the presence of intermediate nepheloid layers at the shelf-break depth and various depths along the slope (∼500, 1000 and 2000 m), were observed. These nepheloid layers extended off the slope to about 10–30 km, but especially laterally along the slope. Their presence indicated that suspended particulate matter exchanges between the shelf and the slope occurred mainly in the head of the canyon and along the southern open slope. The intermediate nepheloid layers around 500 m depth detached from the slope particularly in regions where the bottom slope is close to critical for the M₂ internal tide.     

Nepheloid layer distribution in the Benguela upwelling area offshore Namibia

The distribution of nepheloid layers across the outer shelf and upper continental slope off Namibia was studied during a cruise with R.V. Meteor in late austral summer 2003. Optical measurements, carried out with a transmissometer and a backscattering fluorometer, are correlated with suspended particulate matter (SPM) and particulate organic carbon (POC) values from water sample filtration. Conductivity-temperature-depth and oxygen data are used to relate the nepheloid layers to hydrographic structures. The particle content of surface water at the continental slope is controlled primarily by the offshore extension of highly productive upwelling filaments. A pronounced bottom nepheloid layer (BNL) covers the entire area of study with maximum intensity above the outer shelf and at the shelf break—an area where erosional forces dominate. The detachment of this BNL at the shelf break feeds a major intermediate nepheloid layer (INL) at 25.5°S. This INL is positioned at 250–400 m depth, at the lower boundary of an oxygen minimum zone, and is likely connected to the poleward flow of South Atlantic Central Water (SACW) across the shelf break. Together, these strong subsurface nepheloid layers are indicators of intensive lateral particle transport from the outer shelf towards a depocenter of organic matter on the upper continental slope.     

2013年夏秋季黄、渤海悬浮颗粒物及粒径分布特征研究

悬浮颗粒物及粒径是水质重要参数,其分布特征研究有助于加深对海洋生态环境的了解。利用2013年6月和2013年11月LISST-100观测数据,研究了黄、渤海区域悬浮物粒径和浓度的分布情况,浓度分布整体上呈现近岸高远岸低的状况,粒径分布呈现近岸细远岸粗的特征,季节分布特征明显;通过典型断面分析,悬浮物粒径和浓度随着水深变化明显,连续站数据分析结果表明大风对底层颗粒物的再悬浮作用显著,潮流对悬浮物的时空分布有着重要影响;水体衰减系数随着体积浓度变化明显;此外,还研究了悬浮颗粒物粒径Junge分布在黄、渤海区域的适用性。     

The behavior of iron,manganese and silicon in the Peconic River estuary,New York

The behavior of dissolved and particulate iron and manganese and dissolved silicon has been studied as a function of chlorinity in the Peconic River estuary, New York. This study sought to identify important geochemical processes in a relatively pristine estuary facing increasing anthropogenic impact.Dissolved iron behaved in the classical non-conservative manner exhibiting removal of nearly 80% at very low chlorinities, while particulate iron increased by a corresponding amount over the same chlorinity range. Dissolved manganese was enriched by up to 200% over its predicted concentration at low and intermediate chlorinities by desorption from suspended particulates and by a probable benthic flux. Dissolved silicon was enriched by up to 100% at low and intermediate chlorinities also from a probable benthic flux. These fluxes were estimated to be 5 μg cm^?2 day^?1 for dissolved manganese and 70 μg cm^?2 day^?1 for dissolved silicon.The quantity of both particulate iron and manganese increased at high chlorinities due to an influx of suspended inorganic particulates. In the intermediate to high chlorinity region, oxidation of sediment-derived manganese is believed to contribute to the observed increase in particulate manganese.Total iron was essentially conservative throughout most of the estuary, while total manganese was non-conservative presumably due to extensive remobilization of dissolved manganese from the sediments.