湖南沃溪钨-锑-金建造矿床同生成因的微量元素和硫同位素证据

对岩矿石和矿物的微量元素、稀土元素和硫同位素地球化学的研究表明,湖南沃溪钨-锑-金建造矿床系海底同生热水沉积作用的产物。矿石与围岩中微量元素和稀土元素含量的变化关系,反映了一种复杂的热液、海水以及陆源碎屑的联合影响。矿石及其中矿物(石英)的稀土元素配分模式可与许多沉积喷流型(sedex型)块状硫化物矿石及其共生的喷流岩相对比,暗示了两者具有相似的形成机理。矿石的硫同位素资料显示,生物成因硫与热液成因硫(下伏沉积柱中硫化物的溶解和/或部分海水硫酸盐的还原)共同参与了成矿作用过程。     

同生还是后生?——热液矿床成因研究中争论的焦点问题

秦岭地区钠长角砾岩型矿床、广西大厂锡多金属矿床、广东长坑金银矿床和广东大沟谷金矿床的成因长期存在着同生还是后生的争议.研究表明,这些矿床中的钠长石岩、硅质岩、重晶石岩、电气石岩不是热水沉积成因,而是后期流体结晶和热液交代形成,矿床不存在热水喷流同生沉积成矿作用.矿床成因研究应从多个方面综合考虑,野外宏观地质特征是基础,...     

半宽金矿床的物质来源及成因讨论

半宽金矿床的成矿物质具有多源性.微量元素特征显示金矿床的成矿物质来自混合岩.同位素研究表明含矿流体为岩浆成因,但有变质流体和天水的混合.稀土元素特征反映矿质来自下地壳或地幔,是下地壳物质重熔的结果,但受到上壳岩石的混染.矿床的成因为岩浆活化的金矿床.     

半宽金矿床的物质来源及成因讨论

半宽金矿床的成矿物质具有多源性。微量元素特征显示金矿床的成矿来自混合岩。同位素研究表明含矿流体为岩浆成因，但有变质流体和天水的混合。稀土元素特征反映矿质来自下地壳或地幔，是下地壳物质重熔的结果，但受到上壳岩石的混染，矿床的成因为岩浆活化的金矿床。     

辽宁北票二道沟金矿床地球化学特征及意义

针对金矿床的矿石和岩石稀土元素、矿物的微量元素、金矿物成色、硫同位素和石英包裹体测温等方面阐述了二道沟金矿床的地球化学特征,对其成矿物质来源及矿床成因进行了探讨.二道沟金矿床岩石和金矿石具有轻稀土富集、重稀土亏损、稀土元素分布模式总体呈向右倾斜的特征.金矿石稀土模式曲线与早白垩世岩石稀土模式曲线近似,表明金矿成矿与早白垩世岩浆活动密切相关,同时稀土元素参数也反映出成岩成矿物源的一致性.黄铁矿具有含As高及As/Sb和Co/Ni比值高的特点.金矿物成色为630~948,多数金矿物成色值大于800;δ³⁴S值大多数在-2‰~+3‰之间,变化区向狭窄,显示出岩浆成因的热液硫化物之特征.石英包裹体成矿温度为210~322℃.研究表明,二道沟金矿床金矿石和岩石是地幔岩浆同熔地壳经分异作用而形成,成岩成矿系同源演化系列的产物,成矿物质来源具有上地幔或下地壳的特征,反映该金矿床是中深成中温岩浆热液金矿床.     

华北陆台北缘金矿床的地球化学特征

据金矿床（点）的稀土元素和微量元素地球化学特征，结合金矿产出的地质构造特点，可将华北陆台北缘金矿床（岩金）划分为十种赋矿类型，运用金矿石及岩石铅同位素进行分区，为地体划分提供了佐证。     

西准噶尔乌什加嘎衣提金矿霏细斑岩脉及矿石等锆石U-Pb年龄、Hf同位素以及地球化学特征

什加嘎衣提金矿床是西准噶尔谢米斯台—沙尔布尔提成矿带迄今为止规模最大的金矿床,金资源量2 t,品位8×10-6。霏细斑岩脉的地质特征、成岩年代、地球化学特征对该地区的找矿工作具有重要意义。金矿体产于中酸性岩体与地层接触剪切带中,与霏细斑岩脉密切共生,主要发育硫化物石英脉型和蚀变岩型两种矿石类型,工业类型属石英脉—蚀变岩型金矿床。本文测得不含矿的霏细斑岩脉成岩年龄为429.1±1.6 Ma以及两期含矿的霏细斑岩脉的成岩成矿年龄为426.5±1.7 Ma和426.0±1.6 Ma,认为矿床形成时代为中—晚志留世。矿区的安山岩、二长岩、霏细斑岩脉、蚀变岩型金矿石和硫化物石英脉型金矿石具有相似的稀土元素配分和微量元素演化趋势,从前往后具有递进性演化的关系。矿区所有岩石均表现出富集轻稀土元素,亏损重稀土元素,轻重稀土元素分异明显,明显富集大离子亲石元素Rb、Ba、Th,相对亏损高场强元素Ti、Nb,不具有Eu、Ce异常等特征,显示出俯冲带岛弧岩浆的特点。霏细斑岩脉εHf(t)同位素（+8.86~+15.41）与区域岩体（+5~15.4）高度重叠,对应的二阶段年龄为429~844 Ma,略大于锆石年龄,表明成矿的岩浆热液来源于亏损地幔新增的年龄地壳,源区在地壳中存留时间较短。霏细斑岩脉和二长岩在岩石成因和构造判别图解上与区域I型花岗岩落入相同的区域,成因类型为高钾钙碱准铝值Ⅰ型花岗岩。综合地质、年代学、地球化学特征,认为矿床成因类型属岩浆热液型金矿床,是晚志留世古亚洲洋向南俯冲背景下与侵入岩同源岩浆活动演化分异的产物,并预测区域上具有寻找与I型花岗岩相关的多种类型的Au—Cu矿床。     

河南省南召县南庄铅锌矿床地质特征与成因分析

南庄铅锌矿床的矿体大多呈隐伏型,产于下古生界二郎坪群火神庙组石英角斑凝灰岩中.通过对矿床地质特征、矿石稀土元素和微量元素特征、同位素地球化学特征的综合分析研究,发现矿床具热水沉积特征和海水硫与幔源硫混合特性,成矿物质主要来源于上地幔,并混有造山带和上地壳的特征.基本确定该矿床属于弱变质作用改造的海底火山喷流型块状硫化物型矿床,建立了地层-岩性-蚀变-物探找矿标志.     

陕西凤县水磨坪金矿地质特征及控矿因素

陕西凤县水磨坪金矿为破碎带蚀变闪长玢岩型金矿床。通过对该矿床的地质特征、矿体特征、矿石特征等的分析研究,总结了控矿因素,探讨了矿床成因,认为近EW向断裂带控制了金矿体的产出与展布,印支期闪长玢岩脉金砷锑背景值较高,利于赋矿成矿。该矿床属晚古生代低温热液矿床,矿石工业类型为金多金属硫化物难选原生金矿石。     

陕西八卦庙金矿微量元素特征及成因

八卦庙金矿床是秦岭造山带的一种与深源热水喷流,岩浆热流体有关的中温热液矿床。本文系统总结了该矿床的微量元素地球化学特征,对矿石,钠长岩,钠长板岩,层间石英脉,节理石英脉和岩脉等能反映成矿流体作用痕迹的岩石进行微量元素测试,作相关分析。     

Anomalously silver-rich vein-hosted mineralisation in disseminated-style gold deposits,Jiaodong gold district,China

Structural measurements and geochemical analyses, including bulk and in situ pyrite geochemistry, sulfur isotopes, and whole-rock geochemistry, are presented for the No. 3 orebody of the Jiaojia gold deposit (JJ3), located in the Jiaodong district of northeast China. The JJ3 orebody is distinct from the main orebody of the Jiaojia deposit (JJ1) because it is characterised by steeply dipping sub-metric quartz-pyrite veins with up to 300 ppm of gold, whereas the JJ1 orebody represents an archetypal example of the disseminated and veinlet style mineralisation characteristic of regional faults in the Jiaodong district. Measurements on JJ3 veins and the host Jiaojia-Xincheng regional fault are consistent with development of mineralised, steeply dipping extension fractures during normal faulting, which produced the fault-hosted disseminated-style JJ1 orebody. Trace element geochemistry of pyrite in these veins shows that JJ3 pyrite is geochemically distinct from those of the main Jiaojia and Xincheng orebodies, being relatively enriched in Ag and Pb, as well as Ba, Bi, Te and Au, and relatively depleted in Cu and As. Enrichment in Ag and Pb is possibly related to infiltration of a saline hydrothermal fluid, as both are effectively transported as chloride complexes; however, depletion of Cu, which is also mobile as chloride complexes, requires a low temperature saline fluid where Cu is no longer soluble. The textural setting of the ore minerals suggests that these cooler fluids likely infiltrated during the waning stages of the hydrothermal system. The relative abundance of barite in the JJ3 orebody, which formed from late-stage oxidised magmatic–hydrothermal fluids, also supports the interpretation that the JJ3 orebody represents a late mineralisation event. The pervasive alteration surrounding the JJ3 orebody is K-feldspathic with a minor sericitic overprint, indicating an earlier higher temperature pervasive fluid flow event that was followed by low-temperature mineralising fluids. This interpretation implies that fracture dilation post-dated the earliest alteration, and that mineralisation and pervasive alteration in the JJ3 orebody are geochemically disconnected. Thus structural analysis is expected to be the most effective targeting method in future exploration for similar ore bodies.     

江南造山带万古金矿床含金硫化物组构与金沉淀机制SCIEI北大核心CSCD

万古金矿床位于江南造山带中部,赋存于新元古界冷家溪群浅变质岩系中,受NNE-NE向长沙-平江断裂带和近EW向九岭-清水韧性剪切带联合控制,金资源量约85t。其主要矿石类型为毒砂-黄铁绢英岩型和石英-硫化物脉型,其次为构造角砾岩型。毒砂和黄铁矿为该矿床主要的载金矿物,分布广泛。金成矿作用可分为四个阶段,I为乳白色石英-绢云母-白钨矿阶段;Ⅱ为烟灰色石英-绢云母-毒砂-黄铁矿-金阶段;Ⅲ为烟灰色石英-绢云母-黄铁矿-毒砂-多金属硫化物-金阶段;IV为乳白色石英-方解石阶段。其中,Ⅱ、Ⅲ为成矿主阶段。根据成矿主阶段毒砂电子探针分析结果,Ⅱ阶段毒砂中As的含量在42.19%~44.84%之间,均值为43.42%(n=56),Ⅲ阶段毒砂中As的含量在40.08%~43.36%之间,均值为42.08%(n=19)。通过毒砂温度计相图估算出Ⅱ、Ⅲ阶段的形成温度和硫逸度分别为364±21℃、319±22℃和10^(-9.7)~10^(-7)、10^(-11.5)~10_(-8.6)。电子探针数据揭示的载金毒砂和黄铁矿中不可见金含量分别为0.01%~0.66%和0.01%~0.11%。黄铁矿Au-As元素投点分布于金溶解度曲线两侧,说明其内金主要以纳米级颗粒和固溶体金或晶格金的形式赋存;其中Ⅱ阶段黄铁矿纳米级金颗粒占比为73.33%,多于Ⅲ阶段黄铁矿(67.80%)。以上数据说明在水岩反应过程中,围岩中的含铁矿物与成矿流体中的H;S发生反应,生成毒砂和黄铁矿。伴随着强烈的水岩反应,成矿温度和硫逸度降低,成矿Ⅱ阶段至Ⅲ阶段主要载金硫化物由毒砂转变为黄铁矿,强烈的硫化作用导致金-硫络合物失稳并释放金,金以置换的方式进入硫化物晶格或以显微-超显微金颗粒的形式沉淀,形成含金硫化物;即硫化作用是导致万古矿床不可见金沉淀的主导机制。     

Magma mixing and gold mineralization in the Maevatanana gold deposit,Madagascar

The Maevatanana gold deposit in Madagascar is hosted by Archean metamorphic rocks in quartz–sulfide veins that are structurally controlled by NNW–SSE trending shear zones. Fluid inclusion data show that the trapping conditions in quartz range from 0.87 to 2.58 kbar at temperatures of 269–362 °C. Laser Raman spectroscopy confirms that these inclusions consist of CO₂, SO₂, and H₂O. The δ³⁴S values of the pyrites range from 1.7‰ to 3.6‰, with an average of 2.25‰, supporting a magmatic origin. Noble gases (He, Ne, Ar, Ke, Xe) are chemically inert, thus will not be involved in chemical reactions during geological processes. Also due to the low concentration of He in the atmosphere and the low solubility of He in aqueous fluids, the atmosphere-derived He is unlikely to significantly affect He abundances and isotopic ratios of crustal fluids, ensures that He production should have the typical crust ³He/⁴He ratios. The ³He/⁴He ratios of fluid inclusions in pyrite from the deposit range from 0.06 to 0.12 Ra, while the ⁴⁰Ar/³⁶Ar ratios range from 6631 to 11441. We infer that the ore-forming fluids could have been exsolved from a granitic magma. The oxygen and hydrogen isotope compositions of the ore-forming fluids (1.5‰ ≤ δ¹⁸O_H2O ≤ 7.8‰; –72‰ ≤ δD ≤ –117‰) indicate they were derived from a granitic magma. Four pyrite samples from the gold deposit yield a precise Re–Os isochron age of 534 ± 13 Ma. Given that the post-collisional granites in northern and central Madagascar were derived by melting of sub-continental lithospheric mantle and formed between 537 and 522 Ma, we can state that the gold metallogenesis was coeval with the crystallization age of these parental magmas. These data could be accounted for the formation of the Maevatanana gold deposit. First, the shear zones hosting the deposit formed around 2.5 Ga, when the Madagascan micro-continental blocks collided with other continental blocks, triggering large-scale tectono-magmatic activity and forming NNW–SSE trending shear zones. The gold mineralization at Maevatanana is coeval with the crystallization age of the Cambrian post-collisional A-type granitoid plutons in northern and central Madagascar, implying that this deposit is associated with extensional collapse of the East African Orogen. This extension in turn induced asthenospheric upwelling, melting of sub-continental lithospheric mantle. These magmas underplated the lower crust, generating voluminous granitic magmas by partial melting of the lower crust. The mixing magma during tectono-thermal reactivation of the East African Orogen produced large volumes of volatiles that extracted gold from the granitic magma and produced Au–S complexes (e.g., Au(HSO₃)²⁻). The shear zones, which were then placed under extensional collapse of the East African Orogen in the Cambrian, formed favorable pathways for the magmatic ore-forming fluids. These fluids then precipitated gold-sulfides that form the Maevatanana gold deposit.     

内蒙古虎拉林地区砂金与岩金的关系

虎拉林地区砂、岩金矿的空间位置关系十分密切。在虎拉林河上中下游及虎拉林岩金矿分别采取样品，结果表明虎拉林河砂金粒度大，分选较差，磨圆度差；砂金形态总体上以粒状为主；溶蚀系数均值小于1。微量元素含量特征表明砂金的主要物质来源是近源，与岩金矿关系密切且具有继承性。虎拉林岩金矿床的矿石中自然金颗粒粗大，矿体的上部遭到剥蚀，虎拉林河砂金主要来源于虎拉林岩金矿床，砂金可作为岩金的找矿标志。自然金化学-结晶温度图表明砂金的原生Au源为中低温热液矿床。     

Transport and Concentration of Gold in Metamorphic—hosted Reworked Gold Deposits,China

Calculations based on the available thermodynamic data of AuCl ₂ ⁻ and Au (HS) ₂ ⁻ indicate that AuCl ₂ ⁻ is responsible for the transport and enrichment of gold during the stage of pre-concentration in the source bed while Au (HS) ₂ ⁻ is the main gold species involved in the formation of gold deposits in response to hydrothermal reworking. Acid chloride solutions witha _Cl ⁻ > 10° and sulfur-rich solutions with a_Σs in excess of 10⁻² are held as important criteria for gold enrichment in the source bed and for the formation of gold deposits by subsequent hydrothermal event, respectively.     

胶东中生代金成矿系统

胶东是我国最重要的金矿集区,其内已发现金矿床150余处,探明金资源储量4000余吨。虽然其金矿床数量众多、资源储量巨大、分布地域广泛、产出空间各异、矿化类型多样,但它们的成矿地球动力学背景、赋矿围岩环境与产出条件及其成矿作用特征总体一致:(1)胶东是一个主要由前寒武纪基底岩石和超高压变质岩块组成、中生代构造-岩浆作用发育的内生热液金矿集区,约130~110Ma的金成矿事件比区域变质作用晚约2000Myr;(2)区域金成矿系统形成于早白垩世的陆缘伸展构造背景,大规模金成矿事件发生在区域NW向伸展转换为NE向伸展后的NEE向挤压变形作用过程中,对应于中国东部岩石圈大规模减薄、华北克拉通破坏和大陆裂谷作用的高峰;(3)金矿床群聚于NNE向玲珑、鹊山和昆嵛山变质核杂岩周边,主要沿前寒武纪变质岩与中生代花岗岩体接触带形成的区域NE-NNE向拆离断层带分布;(4)控矿断裂带经历了早期的韧-脆性变形和晚期的脆性变形构造叠加,在三维空间上呈舒缓波状延展,控制了金矿体的侧伏和分段富集;(5)矿化样式以破碎带蚀变(砾)岩型、(硫化物-)石英脉型和复合脉带型为主,矿石普遍发育压碎、晶粒状和填隙结构,浸染状、细脉浸染状、网脉状、脉状、团块状和块状构造,反映其形成于韧-脆性→脆性变形环境;(6)矿石中金属矿物以黄铁矿、黄铜矿、方铅矿和闪锌矿为主,非金属矿物以石英、绢云母、钾长石、斜长石和方解石为主;金矿物以银金矿和自然金为主、含少量金银矿,主要以可见金的形式赋存于黄铁矿和石英裂隙中、含少量晶隙金和包体金;热液蚀变主要为黄铁矿化、硅化、钾长石化、绢云母化和碳酸盐化;成矿元素为Au-Ag(-Cu-Pb-Zn);呈现出中-低温蚀变矿化组合特征;(7)成矿流体为壳-幔混合来源,以壳源变质流体为主;成矿物质总体来源于中生代活化再造的前寒武纪变质基底岩石,并混入了少量浅部地壳和地幔组分。这种区域成矿特征的一致性,表明胶东金矿集区早白垩世大规模金成矿作用受控于统一的地质事件,属于后生的中-低温热液脉金成矿系统。这些金矿床具有明显的时空群聚分布特征,主要沿三个变质核杂岩周边的岩相接触带产出,且自西向东,金成矿作用年龄由老变新。据此,可划分为胶北隆起蚀变岩-石英脉型、苏鲁超高压变质带硫化物-石英脉型和胶莱盆地北缘蚀变砾岩型三个金成矿子系统。其矿化样式由浸染-细脉、细脉-网脉型和石英脉型→硫化物-石英脉型→蚀变(角)砾岩型变化,矿石结构、构造以细脉浸染状构造为主→环带结构与梳状构造→角砾状构造为特色,反映其成矿作用分别发生于脆-韧性转换带(约15km)→脆性张剪性断裂带→脆性角砾岩带(约5km)环境;矿化、蚀变规模和强度逐渐减弱,成矿物质中浅部壳源组分逐渐增多,可能与其矿床定位空间越来越远离源区有关;成矿温度和压力依次降低、成矿流体中大气降水和/或盆地卤水贡献逐渐增大,与其成矿深度越来越浅、成矿构造环境越来越偏张性的变化趋势一致。这种成矿特征的区域规律性变化反映至少在拆离断层韧-脆性转换带附近→脆性角砾岩带之间的地壳剖面中、在不同的垂向深度上连续成矿。胶东中生代金成矿系统的上述特征明显区别于典型的"与侵入岩有关的金矿"和"造山型金矿",也不同于全球其它已知的金矿床类型,不能被已有成矿模式所涵盖。为合理解释胶东中生代金成矿系统独特的地质与成矿特征,我们提出新的"胶东型金矿"成矿模式,指出古太平洋Izanagi俯冲板片的回转作用可能是引起区域前寒武纪变质基底岩石中成矿物质大规模活化再造的主要驱动机制,成矿流体主体来源于俯冲板片变质脱水,金可能主要以Au(HS)2-络合物的形式在流体中沿拆离断层系输运,在韧-脆性转换带附近→脆性角砾岩带,由于构造空间急剧增大、成矿流体的温度和压力突然降低,CO2、H2S逸出和硫化作用导致Au(HS)2-等金络合物失稳分解,金大规模沉淀富集成矿。     

Remobilization of gold from a chalcopyrite-pyrite mineralization Hamash gold mine,Southeastern Desert,Egypt

Pyrite, chalcopyrite, and gold occur in quartz veins in granitic rocks and as scattered and disseminated impregnations in shear zones of the highly altered metavolcanics in the Hamash area, Southeastern Desert, Egypt. The minerals are associated in part with pyrrhotite, digenite, tetrahedrite, chalcocite, bornite, and covellite. Pyrite occurs in two forms: (1) idio- to hypidiomorphic coarse crystals with inclusions of preexisting sulfides, and (2) fine-crystalline aggregates. Chalcopyrite occurs in three forms: (1) idiomorphic coarse crystals, (2) fine-crystalline microinclusions, and (3) xenomorphic relicts. Three genetic phases of sulfide mineralization were identified. They are related to the successive cooling of the crystallizing solutions. Gold was hosted in the older sulfide minerals during a high-temperature disorder phase. Native gold was formed during the latest, decreasing-temperature phase through remobilization of auriferous pyrite. Microprobe analysis confirmed that gold and copper are relatively enriched in the late pyrite. Identified surface-alteration products include goethite, limonite, gold, carbonates, and sulfates of iron and copper.     

胶东玲珑金矿区碲化物形成条件及其对金富集过程的约束SCIEI北大核心CSCD

胶东地区探明金储量超过5000t,是我国最重要的金矿集区。玲珑金矿区位于胶东西北部招-平断裂北段,具有典型含金石英脉矿床的特征。矿区部分矿段产出富碲铋化物的明金矿石,是研究富碲铋化物金矿床成因和金超级富集机制的理想对象。通过显微岩相学观察、扫描电镜及电子探针分析,首次对胶东玲珑金矿区富碲铋化物明金矿石的矿物组合和形成机制进行了较为详细的研究。玲珑金矿区含明金矿石中的金矿物主要为含银自然金,成色整体较高,平均为894。共发现了五种与自然金共生的碲化物,分别是辉碲铋矿、碲铋矿、碲银矿、碲铋银矿和碲镍矿,其中辉碲铋矿含量最多。通过矿物共生组合研究及物理化学条件分析,确定成矿流体的碲逸度范围为-12.6相似文献   

甘肃礼县-岷县成矿带西段寨上金矿床中自然金的发现及成因意义

位于西秦岭礼(县)-岷(县)成矿带西段的寨上金矿床是近年发现的一个大型微细浸染型金矿。在研究甘肃寨上金矿床物质组分的过程中,采用显微镜观察、电子探针扫描、化学分析等综合分析技术发现了显微自然金颗粒。矿石中的自然金颗粒形态多样,粒度变化较大(5～150μm)。电子探针分析结果显示,自然金中Au=88.23%～92.73%,Ag=7.41%～9.08%,为含银自然金,成色905～926。金的载体矿物有砷黄铁矿、方铅矿、碲汞矿、铁白云石等。金的嵌布类型有粒间金、裂隙金和连生金3种。赋矿围岩中含Fe碳酸盐矿物溶解释放出Fe和溶解Fe的大量硫化物化,可能是寨上金矿床中存在显微可见自然金的最重要因素。     

The Physico—Chemical Conditions for Mobilization of Gold in Mobin Gold Deposit,Southwest Hunan,China

Experiments on water-rock interaction were carried out on wall-rock samples fromtheMobin gold deposit,Southwest Hunan,China ,with the aim of determining the optimum physical and chemical conditions for the mobilization of gold in solution.Results indicate that gold is most easily mobilized from the wall rock-tuffaceous slate of the Mobin Deposit.Mobi-lization is optimized if fluids are neutral to slightly alkaline and contain both chlorine and sul-phur ions at the concentration and composition of about[0.25M(NH4)2 1M NaCl].The amount of gold leached from the tuffaceous slate increases with temperature although the effect decreases above about 200℃.