Mineralogical and geochemical investigations of pyrite-rich mine waste from a kyanite mine in Central Virginia with comments on recycling

A pyrite-rich waste stream is one of three types generated from a kyanite mine in central Virginia near the town of Dillwyn, Buckingham County. Currently, ore consists of approximately 3% pyrite waste and an estimated 382,000 tons of this waste stream has been generated over the past 60 years. The mineralogy of the waste stream consists of variable amounts of pyrite (70–>99%), talc (1–20%), quartz (1–10%), kyanite (0.5–5%) with minor or trace amounts of magnetite, hematite, galena, anorthite and rare earth phosphate. Energy dispersive spectroscopy analysis indicates that talc has minor amounts of Al up to 1.57 wt% and Fe up to 4.29 wt% and pyrite grains have no impurities above detection limit of approximately 0.1 wt%. Bulk chemical analysis of selected elements using inductively coupled plasma-mass spectrometry analysis indicate that Zn (28.82–367.71 ppm), As (8.94–18.26 ppm), Se (44.62–64.50 ppm), Cd (0.19–1.03 ppm), Hg (0.87–35.91 ppm), and Pb (65.10–189.66 ppm) occur at levels of some environmental concern. Au and Ag concentrations are negligible. Currently the waste stream is well managed and sold, but for a low price. Talc is of sufficient quality to be of interest for recycling but the estimated 540 tons generated per year is not a suitable quantity to be economically viable. Currently, the waste stream is not viable for recycling for higher monetary value; however, the characteristics of the pyrite may enable such recycling in the future for solar energy technologies. This and other associated waste streams show long term promise for integrated recycling and may play important economic roles in an economically disadvantaged region.     

Chronology of the Pueblo Viejo epithermal gold–silver deposit,Dominican Republic: formation in an Early Cretaceous intra-oceanic island arc and burial under ophiolite

The Pueblo Viejo deposit (production to 1996: 166 t Au, 760 t Ag) is located in the Dominican Republic on the Caribbean island of Hispaniola and ranks as one of the largest high-sulfidation/acid-sulfate epithermal deposits (reserves in 2007: 635 t Au, 3,648 t Ag). One of the advanced argillic ore bodies is cut by an inter-mineral andesite porphyry dike, which is altered to a retrograde chlorite–illite assemblage but overprinted by late-stage quartz–pyrite–sphalerite veins and associated low-grade Au, Ag, Zn, Cd, Hg, In, As, Se, and Te mineralization. The precise TIMS U–Pb age (109.6 ± 0.6 Ma) of the youngest zircon population in this dike confirms that the deposit is part of the Early Cretaceous Los Ranchos intra-oceanic island arc. Intrusion-related gold–sulfide mineralization took place during late andesite–dacite volcanism within a thick pile (>200 m) of carbonaceous sand- and siltstones deposited in a restricted marine basin. The high-level deposit was shielded from erosion after burial under a late Albian (109–100 Ma) ophiolite complex (8 km thick), which was in turn covered by the volcano-sedimentary successions (>4 km) of a Late Cretaceous–Early Tertiary calc-akaline magmatic arc. Estimates of stratigraphic thickness and published alunite, illite, and feldspar K-Ar ages and closure temperatures (alunite 270 ± 20°C, illite 260 ± 30°C, K-feldspar 150°C) indicate a burial depth of about 12 km at 80 Ma. During peak burial metamorphism (300°C and 300 MPa), the alteration assemblage kaolinite + quartz in the deposit dehydrated to pyrophyllite. Temperature–time relations imply that the Los Ranchos terrane then cooled at a rate of 3–4°C/Ma during slow uplift and erosion.     

Sub—microscopic Textures and Retrogressive Metamorphic Origin of Longxi Nephrite

Nephrite specimens from Longxi,sichuan,prepared by ion-thinning and dispersion techniques have been studied using TEM and SAED.A series of sub-microscopic textures such as (010)multiple-chain faults and related fault terminations.(001)mechanical twinning,sub-grain boundaries or fault walls,tremolite fibrous pseudoform of talc and intergrowth of tremolite and talc with (010)as interface are revealed .By analogy of metallographic textures,characteristics and mechanisms of the process of “deformation-recovery-recrystallization“ are discussed in detail,Topotactic reaction mechanism by which tremolite retrogresses to talc was studied and a retrogressive metamorphic origin of Longxi nephrite is proposed.     

Age constraints on faulting and fault reactivation: a multi-chronological approach

Movement within the Earth’s upper crust is commonly accommodated by faults or shear zones, ranging in scale from micro-displacements to regional tectonic lineaments. Since faults are active on different time scales and can be repeatedly reactivated, their displacement chronology is difficult to reconstruct. This study represents a multi-geochronological approach to unravel the evolution of an intracontinental fault zone locality along the Danube Fault, central Europe. At the investigated fault locality, ancient motion has produced a cataclastic deformation zone in which the cataclastic material was subjected to hydrothermal alteration and K-feldspar was almost completely replaced by illite and other phyllosilicates. Five different geochronological techniques (zircon Pb-evaporation, K–Ar and Rb–Sr illite, apatite fission track and fluorite (U-Th)/He) have been applied to explore the temporal fault activity. The upper time limit for initiation of faulting is constrained by the crystallization age of the primary rock type (known as “Kristallgranit”) at 325 ± 7 Ma, whereas the K–Ar and Rb–Sr ages of two illite fractions <2 μm (266–255 Ma) are interpreted to date fluid infiltration events during the final stage of the cataclastic deformation period. During this time, the “Kristallgranit” was already at or near the Earth’s surface as indicated by the sedimentary record and thermal modelling results of apatite fission track data. (U–Th)/He thermochronology of two single fluorite grains from a fluorite–quartz vein within the fault zone yield Cretaceous ages that clearly postdate their Late-Variscan mineralization age. We propose that later reactivation of the fault caused loss of helium in the fluorites. This assertion is supported by geological evidence, i.e. offsets of Jurassic and Cretaceous sediments along the fault and apatite fission track thermal modelling results are consistent with the prevalence of elevated temperatures (50–80°C) in the fault zone during the Cretaceous.     

Alternative water resources in granitic rock: a case study from Kinmen Island,Taiwan

Kinmen Island is a small, tectonically stable, granitic island that has been suffering from a scarcity of fresh water resources due to excessive annual evapotranspiration over annual precipitation. Recent studies further indicate that shallow (0–70 m) sedimentary aquifers, the major sources of groundwater supply, have already been over-exploited. Therefore, this preliminary study is to investigate the existence of exploitable water resources that can balance the shortage of fresh water on this island. Site characterization data are obtained from island-wide geophysical surveys as well as small-scale tests performed in a study area formed by three deep (maximum depth to 560 m) vertical boreholes installed in mid-east Kinmen northeast to Taiwu Mountain. Vertical fracture frequency data indicate that the rock body is fractured with a spatially correlated pattern, from which three major fracture zones (depths 0–70, 330–360, and below 450 m) can be identified. Geologic investigations indicate that the deepest fracture zone is caused by the large-scale, steeply dipping Taiwushan fault. This fault may have caused a laterally extensive low-resistivity zone, a potential fractured aquifer, near Taiwu Mountain. The middle fracture zone is induced by the Taiwushan fault and intersects the fault approximately 21 m southeast of the study area below a depth of 350 m. Slug testing results yield fracture transmissivity varying from 4.8 × 10⁻⁷ to 2.2 × 10⁻⁴ m²/s. Cross-hole tests have confirmed that hydraulic connectivity of the deeper rock body is controlled by the Taiwushan fault and the middle fracture zone. This connectivity may extend vertically to the sedimentary aquifers through high-angle joint sets. Despite the presence of a flow barrier formed by doleritic dike at about 300 m depth, the existence of fresh as well as meteoric water in the deeper rock body manifests that certain flow paths must exist through which the deeper fractured aquifers can be connected to the upper rock body. Therefore, groundwater stored within the Taiwushan fault and the associated low-resistivity zone can be considered as additional fresh water resources for future exploitation.     

Surface geophysical investigations of landslide at the Wiri area in southeastern Korea

A geophysical survey was undertaken at Wiri area of the Andong in southeastern Korea to delineate subsurface structure and to detect the fault zone, which affected the 1997 mountain–hill subsidence and subsequent road heaving initiated by the intense rainfall. Electrical resistivity methods of dipole–dipole array profiling and Schlumberger array sounding and seismic methods of refraction and reflection profiling were used to map a clay zone, which was regarded as the major factor for the landslide. The clay zone was identified in electrical resistivity and seismic sections as having low electrical resistivity (<100 Ωm) and low seismic velocity (<400 m/s), respectively. The clay zone detected by using geophysical methods is well correlated with its distribution from the trench and drill-core data. The results of the electrical and seismic surveys showed that slope subsidence was associated with the sliding of saturated clay along a fault plane trending NNW–SSE and dipping 10°–20° SW. However, the road heaving was caused by the slope movement of the saturated clay along a sub-vertical NNE-trending fault.     

Cathodoluminescence (CL) and electron paramagnetic resonance (EPR) studies of clay minerals

Summary ?Sheet silicates of the serpentine–kaolin-group (serpentine, kaolinite, dickite, nacrite, halloysite), the talc–pyrophyllite-group (talc, pyrophyllite), the smectite-group (montmorillonite), and illite (as a mineral of the mica-group) were investigated to obtain information concerning their cathodoluminescence behaviour. The study included analyses by cathodoluminescence (CL microscopy and spectroscopy), electron paramagnetic resonance (EPR), X-Ray diffraction (XRD), scanning electron microscopy (SEM) and trace element analysis. In general, all dioctahedral clay minerals exhibit a visible CL. Kaolinite, dickite, nacrite and pyrophyllite have a characteristic deep blue CL, whereas halloysite emission is in the greenish-blue region. On the contrary, the trioctahedral minerals (serpentine, talc) and illite do not show visible CL. The characteristic blue CL is caused by an intense emission band around 400 nm (double peak with two maxima at 375 and 410 nm). EPR measurements indicate that this blue emission can be related to radiation induced defect centres (RID), which occur as electron holes trapped on apical oxygens (Si–O centre) or located at the Al–O–Al group (Al substituting Si in the tetrahedron). Additional CL emission bands were detected at 580 nm in halloysite and kaolinite, and between 700 and 800 nm in kaolinite, dickite, nacrite and pyrophyllite. Time-resolved spectral CL measurements show typical luminescence kinetics for the different clay minerals, which enable differentiation between the various dioctahedral minerals (e.g. kaolinite and dickite), even in thin section. Received December 3, 2001; revised version accepted February 27, 2002     

Subterranean erosion in a crystalline schist landslide in Japan

By employing a complete observation system, the underground erosion in a typical large-scale crystalline schist landslide in Japan, the Zentoku landslide, was studied. It was found that the seasonal heavy rainfall is the main factor leading to the massive underground erosion. Two types of sediment discharge of the landslide were defined. Monitored data indicated that the movement of Zentoku landslide could be affected by the underground erosion following the concentrated heavy rainfall. The influence of the underground erosion on the movement of the landslide presents different features. For the sliding block of shallow and medium depth shear zones (5–20 m), the influence of the underground erosion is most outstanding, while it is negligible for the sliding block of thick soil and rock layers (>30 m). Finally, the rainfall thresholds for the Zentoku landslide, which concern the groundwater state, underground erosion and movement of sliding blocks, were provided to further establish the warning and evacuation system.     

The Baza Fault: a major active extensional fault in the central Betic Cordillera (south Spain)

In the Guadix-Baza Basin (Betic Cordillera) lies the Baza Fault, a structure that will be described for the first time in this paper. Eight gravity profiles and a seismic reflection profile, coupled with surface studies, indicate the existence of a NE-dipping normal fault with a variable strike with N-S and NW-SE segments. This 37-km long fault divides the basin into two sectors: Guadix to the West and Baza to the East. Since the Late Miocene, the activity of this fault has created a half-graben in its hanging wall. The seismic reflection profile shows that the fill of this 2,000–3,000 m thick asymmetric basin is syntectonic. The fault has associated seismicity, the most important of which is the 1531 Baza earthquake. Since the Late Tortonian to the present, i.e. over approximately the last 8 million years, extension rates obtained vary between 0.12 and 0.33 mm/year for the Baza Fault, being one of the major active normal faults to accommodate the current ENE–WSW extension produced in the central Betic Cordillera. The existence of this fault and other normal faults in the central Betic Cordillera enhanced the extension in the upper crust from the Late Miocene to the present in this regional compressive setting.     

Geophysical imaging of municipal solid waste contaminant pathways

Surface electrical and electromagnetic surveys were conducted on top of a solid waste facility in Unguwan Dosa, Kaduna State, Northwest Nigeria. The aim of the geophysical survey was to detect vertical and subvertical fractures that may provide pathways for groundwater and contaminant transport. Results from the 2D electrical resistivity imaging showed vertical and subvertical contacts overlain by 6–10 m thick overburden. Quantitative interpretation of the VLF-EM data correlates well with the results of the 2D resistivity imaging delineating the vertical and subvertical contacts as good and weak conductors (fractures zones) with resistivity values of 40–220 and 300–420 Ω m, respectively. Azimuthal Schlumberger VES measurements yield apparent anisotropy values ranging from 1.01 to 1.47 for electrode spacings of 1–45 m with the highest value recorded at spacing of 2 m. However, azimuthal variations at large spacings (30–45 m) showed no fracture anisotropy due possibly to the array’s low sensitivity to anisotropy at these spacings. The result of the study showed that pollutants in the leachate can reach and contaminate the groundwater. Therefore, urgency for leachate treatment at this site is recommended to prevent contamination of groundwater.     

GPS-derived deformation rates in northwestern Himalaya and Ladakh

Deformation rates derived from GPS measurements made at two continuously operating stations at Leh (34.1°N, 77.6°E) and Hanle (32.7°N, 78.9°E), and eight campaign sites in the trans-Himalayan Ladakh spanning 11 years (1997–2008), provide a clear picture of the kinematics of this region as well as the convergence rate across northwestern Himalaya. All the Ladakh sites move 32–34 mm/year NE in the ITRF2005 reference frame, and their relative velocities are 13–16 mm/year SW in the Indian reference frame and ~19 mm/year W with reference to the Lhasa IGS station in southeastern Tibet. The results indicate that there is no statistically significant deformation in the 200-km stretch between the continuous sites Leh and Hanle as well as between Leh and Nubra valley sites along the Karakoram fault, whereas the sites in and around the splayed Karakoram fault region indicate surface deformation of 2.5 mm/year. Campaign sites along the Karakoram fault zone indicate a fault parallel surface motion of 1.4–2.5 mm/year in the Tangste and western Panamik segment of the Karakoram fault, which quantifies the best possible GPS-derived dextral slip rate of 3 mm/year along this fault during this 11-year period. Baselines of Ladakh sites show convergence rates of 15–18 mm/year with respect to south India and 12–15 mm/year with respect to Delhi in north India and Almora in the Himalaya ~400 km north-northeast of Delhi. These constitute an arc normal convergence of 12–15 mm/year across the western Himalaya, which is consistent with arc normal convergence all along the Himalayan arc from west to east. Baseline extension rates of 14–16 mm/year between Lhasa and Ladakh sites are consistent with the east–west extension rate of Tibetan Plateau.     

Mathematical modeling of thermomechanical erosion beneath Proterozoic komatiitic basaltic sinuous rilles in the Cape Smith Belt,New Québec,Canada

Virtually all of the economic Ni–Cu–(platinum group element (PGE)) mineralization in the central part of the Cape Smith Belt of New Québec is hosted by thick olivine cumulate units in the Katinniq Member of the Raglan Formation at the base of the 1.9 Ga Chukotat Group. These units transgress underlying gabbros and pelitic metasediments, forming 50–200-m deep and 300–1,000-m wide V-shaped embayments and have been interpreted on the basis of surface geology, deep diamond core drilling, and magnetic inversion models to represent the remnants of one or more large, long (at least 20 km, possibly ≥50 km), sinuous, komatiitic basalt lava channels that formed by thermomechanical erosion of their substrates. We have used a mathematical model to test these hypotheses regarding komatiitic lava emplacement and erosion by lava. Our modeling predicts that an initially 10-m thick komatiitic basalt flow should have flowed turbulently near the vent and should have thermomechanically eroded unconsolidated pelitic sediment during emplacement to reach the observed degree of contamination of ≤10% at distances of ~30–60 km downstream from the source. Furthermore, our models predict that, at these distances downstream, a fully inflated 100-m thick komatiitic basalt flow would have had thermal erosion rates over consolidated gabbroic substrate of ~0.7–1.5 m/day, requiring ~70–140 days to incise a 100-m deep channel, depending on the initial temperature of the lava, the paleoslope, and the initial temperature and solidus temperature of the gabbro. These erosion rates would have been associated with volumetric flow rates of >10⁵–10⁶ m³/s and eruption volumes of >10³–10⁴ km³. Although these flow rates are orders of magnitude larger than those of most modern terrestrial basaltic flows, they are of the same order as those estimated for the largest terrestrial flood basalt flows and with those inferred for some of the largest extraterrestrial flows. Our predicted flow volumes are also of the same order as those of the largest terrestrial flood basalt units, consistent with the great thickness and widespread distribution of the Chukotat Group. Our modeling of thermomechanical erosion of gabbro by komatiitic basalt results in negligible contamination (<1%), and geochemical studies show that the spatially and petrogenetically related Chukotat basalts are uncontaminated, suggesting that the observed enrichments in U–Th–Light Rare Earth Elements (REE) > Middle REE–Heavy REE > Nb–Ta–Ti represent contamination by underlying Povungnituk semipelites. This result is consistent with present models for the genesis of the Ni–Cu–(PGE) mineralization in the Raglan Formation that involve thermomechanical erosion of unconsolidated, sulfidic semipelitic sediments, and decoupling of the miscible silicate and immiscible sulfide components.     

Timing of initiation of extension in the Tianshan,based on structural,geochemical and geochronological analyses of bimodal volcanism and olistostrome in the Bogda Shan (NW China)

This paper describes an olistostrome formation and accompanied bimodal volcanic rocks occurring in the Baiyanggou area, south of Bogda Shan. The main lithotectonic units consist of olistostrome, volcanic rocks and turbidite. The olistostrome is tectonically underlain by Upper Carboniferous limestone and sandstone along a NEE-trending detachment fault. Paleo-growth fault is locally observed. The olistostrome unit includes plenty of blocks of limestone, sandstone, rhyolite and volcaniclastic rocks, and a matrix of graywacke. Limestone blocks are dated as Pennsylvanian-Bashkirian in age by the coral and brachiopod fossils that are extensively recognized in the Upper Carboniferous strata. The volcanic unit consists of pillowed and massive basalt and rhyolite, the latter occur as an 8- to 10-meter-thick layer above the olistostrome unit. The turbidite unit is mainly composed of chert, siliceous mudstone and sandstone, within which the Bouma sequence can be locally recognized. Meter-wide gabbro and diabase dykes intrude these three units. Geochemically, rhyolites are characterized by high ACNK value of >1.1, depletion of Ba, Nb and Sm, and enrichment in Rb, Th and Zr. Basaltic rocks are rich in K₂O, they show a LREE-enriched pattern and depletion in Ba, Nb and Zr, and enrichment in Ti, Ce and Hf, similar to continental rift-type tholeiite series. A gabbro porphyrite intruding the olistostrome was dated at 288 ± 3 Ma by a sensitive high-resolution ion microprobe (SHRIMP) zircon U–Pb method, and a rhyolite at 297 ± 2 Ma by a laser ablation inductively coupled plasma mass spectrometer (LA-ICPMS) zircon U–Pb method. The Baiyanggou olistostrome and accompanying bimodal volcanic series are linked to an extensional setting that developed in the south of the Bogda Shan. Several lines of evidence, e.g. occurrence of large-scale strike-slip shear zones, large number of mantle-derived magmatic rocks and available geochronological data, demonstrate a significant geodynamic change from convergence to extension in the Chinese Tianshan belt, even in the whole Central Asian Orogenic Belt. The extension in the Chinese Tianshan belt is initiated at ca. 300 Ma, i.e. around Carboniferous–Permian boundary times, and the peak period of intra-plate magmatism occurred in the interval of 300–250 Ma.     

Relationships between magmatism and extension along the Autun–La Serre fault system in the Variscan Belt of the eastern French Massif Central

The ENE–WSW Autun Shear Zone in the northeastern part of the French Massif Central has been interpreted previously as a dextral wrench fault. New field observations and microstructural analyses document a NE–SW stretching lineation that indicates normal dextral motions along this shear zone. Further east, similar structures are observed along the La Serre Shear Zone. In both areas, a strain gradient from leucogranites with a weak preferred orientation to highly sheared mylonites supports a continuous Autun–La Serre fault system. Microstructural observations, and shape and lattice-preferred orientation document high-temperature deformation and magmatic fabrics in the Autun and La Serre granites, whereas low- to intermediate-temperature fabrics characterize the mylonitic granite. Electron microprobe monazite geochronology of the Autun and La Serre granites yields a ca. 320 Ma age for pluton emplacement, while mica ⁴⁰Ar-³⁹Ar datings of the Autun granite yield plateau ages from 305 to 300 Ma. The ca. 300 Ma ⁴⁰Ar-³⁹Ar ages, obtained on micas from Autun and La Serre mylonites, indicate the time of the mylonitization. The ca. 15-Ma time gap between pluton emplacement and deformation along the Autun–La Serre fault system argue against a synkinematic pluton emplacement during late orogenic to postorogenic extension of the Variscan Belt. A ductile to brittle continuum of deformation is observed along the shear zone, with Lower Permian brittle faults controlling the development of sedimentary basins. These results suggest a two-stage Late Carboniferous extension in the northeastern French Massif Central, with regional crustal melting and emplacement of the Autun and La Serre leucogranites around 320 Ma, followed, at 305–295 Ma, by ductile shearing, normal brittle faulting, and subsequent exhumation along the Autun–La Serre transtensional fault system.     

Cenozoic granitoids in the Dinarides of southern Serbia: age of intrusion,isotope geochemistry,exhumation history and significance for the geodynamic evolution of the Balkan Peninsula

Two age groups were determined for the Cenozoic granitoids in the Dinarides of southern Serbia by high-precision single grain U–Pb dating of thermally annealed and chemically abraded zircons: (1) Oligocene ages (Kopaonik, Drenje, Željin) ranging from 31.7 to 30.6 Ma (2) Miocene ages (Golija and Polumir) at 20.58–20.17 and 18.06–17.74 Ma, respectively. Apatite fission-track central ages, modelling combined with zircon central ages and additionally, local structural observations constrain the subsequent exhumation history of the magmatic rocks. They indicate rapid cooling from above 300°C to ca. 80°C between 16 and 10 Ma for both age groups, induced by extensional exhumation of the plutons located in the footwall of core complexes. Hence, Miocene magmatism and core-complex formation not only affected the Pannonian basin but also a part of the mountainous areas of the internal Dinarides. Based on an extensive set of existing age data combined with our own analyses, we propose a geodynamical model for the Balkan Peninsula: The Late Eocene to Oligocene magmatism, which affects the Adria-derived lower plate units of the internal Dinarides, was caused by delamination of the Adriatic mantle from the overlying crust, associated with post-collisional convergence that propagated outward into the external Dinarides. Miocene magmatism, on the other hand, is associated with core-complex formation along the southern margin of the Pannonian basin, probably associated with the W-directed subduction of the European lithosphere beneath the Carpathians and interfering with ongoing Dinaridic–Hellenic back-arc extension.     

Paleoseismological analysis of an intraplate extensional structure: the Concud fault (Iberian Chain,eastern Spain)

The Concud fault is a 13.5 km long, NW–SE striking normal fault at the eastern Iberian Chain. Its recent (Late Pleistocene) slip history is characterized from mapping and trench analysis and discussed in the context of the accretion/incision history of the Alfambra River. The fault has been active since Late Pliocene times, with slip rates ranging from 0.07 to 0.33 mm/year that are consistent with its present-day geomorphologic expression. The most likely empirical correlation suggests that the associated paleoseisms have potential magnitudes close to 6.8, coseismic displacements of 2.0 m, and recurrence intervals from 6.1 to 28.9 ka. At least six paleoseismic events have been identified between 113 and 32 ka. The first three events (U to W) involved displacement along the major fault plane. The last three events (X to Z) encompassed downthrow and hanging-wall synthetic bending prompting fissure opening. This change is accompanied by a decrease in slip rate (from 0.63 to 0.08–0.17 mm/year) and has been attributed to activation of a synthetic blind fault at the hanging wall. The average coseismic displacement (1.9–2.0 m) and recurrence period (6.7–7.9 ka) inferred from this paleoseismic succession are within the ranges predicted from empirical correlation. Such paleoseismic activity contrasts with the moderate present-day seismicity of the area (maximum instrumental Mb = 4.4), which can be explained by the long recurrence interval that characterizes intraplate regions.     

Formation of chlorite during thrust fault reactivation. Record of fluid origin and P–T conditions in the Monte Perdido thrust fault (southern Pyrenees)

The chemical and isotopic compositions of clay minerals such as illite and chlorite are commonly used to quantify diagenetic and low-grade metamorphic conditions, an approach that is also used in the present study of the Monte Perdido thrust fault from the South Pyrenean fold-and-thrust belt. The Monte Perdido thrust fault is a shallow thrust juxtaposing upper Cretaceous–Paleocene platform carbonates and Lower Eocene marls and turbidites from the Jaca basin. The core zone of the fault, about 6 m thick, consists of intensely deformed clay-bearing rocks bounded by major shear surfaces. Illite and chlorite are the main hydrous minerals in the fault zone. Illite is oriented along cleavage planes while chlorite formed along shear veins (<50 μm in thickness). Authigenic chlorite provides essential information about the origin of fluids and their temperature. δ¹⁸O and δD values of newly formed chlorite support equilibration with sedimentary interstitial water, directly derived from the local hanging wall and footwall during deformation. Given the absence of large-scale fluid flow, the mineralization observed in the thrust faults records the P–T conditions of thrust activity. Temperatures of chlorite formation of about 240°C are obtained via two independent methods: chlorite compositional thermometers and oxygen isotope fractionation between cogenetic chlorite and quartz. Burial depth conditions of 7 km are determined for the Monte Perdido thrust reactivation, coupling calculated temperature and fluid inclusion isochores. The present study demonstrates that both isotopic and thermodynamic methods applied to clay minerals formed in thrust fault are useful to help constrain diagenetic and low-grade metamorphic conditions.     

Dehydration reactions and micro/nanostructures in experimentally-deformed serpentinites

High-T torsion experiments on lizardite + chrysotile serpentinites produced mineralogical and micro/nanostructural changes, with important implications in rheological properties. High-resolution TEM showed that specimens underwent ductile [by microkinking and (001) interlayer glide] and brittle deformation (by microfracturing), together with dehydration and break-down reactions. Lizardite is affected by polytypic disorder and microkinking [kink axial planes at high angle with respect to (001) planes], that were not present in the initial ordered 1T-lizardite. Chrysotile fibres are deformed, resulting in elliptical cross-sections, with strong loss of interlayer cohesion. Both lizardite and chrysotile break down to a fine intergrowth of olivine (up to 200 nm), talc (up to 30 nm) and poorly-crystalline material. Lizardite-out reaction preferentially occurs at kink axial planes, representing sites of preferential strain and enhanced reactivity; conversely, chrysotile break-down is a bulk process, resulting in large healed olivine aggregates, up to micrometric in size. Overall observations suggest that dehydration and break-down reactions are more advanced in chrysotile than in lizardite.     

Clay Minerals in Basalt Sills from the Sediment Cover,East Pacific Rise

Clay minerals in basalt sills from the northern East Pacific Rise, covered by Upper Pleistocene clayey–sandy–silty sediments (turbidites, hemipelagites, and diatom oozes) sampled from DSDP Holes 477, 478, and 481A, were studied by X-ray methods based on the modeling of diffraction patterns. Trioctahedral smectites formed in thin (0.1–0.5 and 1.8–4 m) fissured sills that are well permeable for water delivered from the water-saturated host sediments heated by the sills. Smectites in basalts are found in the interstices (20–40 vol % in the rock and up to 50–80 vol % in hyalobasalts). They replace olivine and fill cracks and vesicles. Plagioclase and clinopyroxene are generally unaltered. The structure of smectites is characterized by different height of layers depending on the composition of cations in the interlayers and the degree of their hydration. The different-height layers either make up individual smectite phases or alternate in different proportions and with a high degree of segregation in the mixed-layer structures. Under conditions of a prolonged cooling, thick (43 m) sills are distinguished from the thin varieties by the formation of trioctahedral minerals (smectite–chlorite, chlorite, defective chlorite, and talc). They are found mainly in the interstices that make up 3–7 vol % of the rock.     

Talc mineralisation associated with soft hematite ore, Gongo Soco deposit, Minas Gerais, Brazil: petrography, mineral chemistry and boron-isotope composition of tourmaline

Talc mineralisation occurs as hematite–talc schist between soft hematite ore and dolomitic itabirite at Gongo Soco, Quadrilátero Ferrífero of Minas Gerais, Brazil. The hematite–talc schist and soft hematite have a prominent tectonic foliation of tabular hematite. Tabular hematite without preferential orientation is superimposed on the tectonic foliation. The talcose schist is enriched in F and has a constant Fe/S ratio. Electron-microprobe analyses indicate trace amounts of S in different generations of hematite. The whole-rock Fe/S ratio possibly represents sulfate S from hematite-hosted fluid inclusions. Fluid inclusions in foliation-overprinting hematite and chlorite geothermometry from talcose rocks suggest, respectively, temperatures from <200°C to ~300°C. Tourmaline, a rarely observed mineral in the hematite–talc schist, belongs to the alkali group and falls in the dravite compositional field. Boron-isotope determinations of tourmaline crystals, using secondary ion mass spectrometry, vary from −20‰ to −12‰ δ¹¹B. This compositional isotopic range and the tourmaline chemical composition suggest a meta-evaporitic origin. A non-marine evaporitic setting is the most likely source of acidic, highly oxidising fluids, which resulted in the abundant F-bearing talc and the presence of otherwise immobile Ti in hematite. Oxidising brines were channelled along shear zones and converted dolomitic itabirite into the Gongo Soco soft hematite and the talc mineralisation. The latter is envisaged as the hydrothermal wall-rock alteration of dolomitic itabirite, which gave rise to the soft hematite ore.