The metabolic balance between autotrophy and heterotrophy in the western Arctic Ocean

The goal of this study was to explore how net community production (NCP) is influenced by the relationship between primary production and community respiration in the western Arctic Ocean. Plankton NCP and respiration were determined by measuring changes in oxygen in light and dark bottle incubations, respectively. Rates of NCP averaged over shelf, slope and basin waters were positive in summer 2002 (57±191 mmol O₂ m⁻² d⁻¹) and spring 2004 (85±86 mmol O₂ m⁻² d⁻¹) and negative in summer 2004 (−25±176 mmol O₂ m⁻² d⁻¹). Determinations of NCP obtained from bottle incubations were similar to rates inferred from in situ changes in dissolved inorganic carbon. An examination of the spatial variability of primary production and community respiration indicated that respiration is distributed more uniformly than primary production. A spatial offset between photosynthesis and respiration from the shelf to the Arctic basin was present in spring 2004, but was not seen at other times. NCP and the potential for export appear to be dependent on an uncoupling of primary production and community respiration. NCP continued into the summer after the stock of NO₃⁻ had been depleted. Our data suggest that the uniform distribution of respiration relative to primary production is an important factor influencing NCP and the potential for export in the western Arctic.     

Cenozoic folding in the Cumuruxatiba basin,Brazil: An approach to the deformation trigger by the Abrolhos magmatism

The Cumuruxatiba basin is located in the central portion of the eastern Brazilian margin surrounded by Cenozoic magmatic highs that belong to the Abrolhos Magmatic Complex. This basin was formed by rifting, in the Neocomian followed by thermal subsidence during late Cretaceous like other basins along the Eastern Brazilian margin. In the Cenozoic, the Abrolhos magmatism took place as sills and dykes intruded the sedimentary section, primarily during the Paleogene. In that time, there was a strong NS contractional deformation in the basin represented by folds related to reverse faults coeval with Abrolhos magmatism activity. The structural restorations of regional 2D seismic sections revealed that most of the contractional deformation was concentrated at the beginning of the Cenozoic with maximum peak at the Eocene (up to 33% of total shortening and rate of 6 km/Ma). The Post-Eocene period was marked by a decrease in the strain rate that continues to the present day (around 4 km/Ma to less than 1). 3D structural modelling exhibited a major, well-developed E–W to NE–SW fold belt that accommodated most of the contractional Cenozoic deformation between Royal Charlotte and Sulphur Minerva magmatic highs. Volcanic eruptions and magmatic flows from the Abrolhos complex resulted in differential overburden on edge of the basin, acting as a trigger for halokinesis and the subsequent formation of fault-related folds. In general, such structures were developed close to adjacent magmatic highs, commonly exhibiting vergence towards the centre of the basin. Some magmatic features formed coeval with Cenozoic syn-deformation sediments clearly indicate that Abrolhos magmatism activity and contractional deformation development were associated. The study of the thickness variation of the syn-deformation section in relation to fault-related folds on deformation maps and maximum strain diagrams revealed that most folds were activated and re-activated several times during the Cenozoic without a systematic kinematic pattern. This lack of systematic deformation might be related to the variation of the magmatic pulse activity of adjacent magmatic highs resulting in a complex interference pattern of Cenozoic folds. These structural interpretations of the timing of fault-related folds that are potential Cenozoic traps in the Cumuruxatiba basin play a fundamental role in petroleum systems and exploration of low-risk hydrocarbon prospects.     

Geometries and mechanism of folds in sediments on the southern Huanghai Sea shelf

1Intraduction Foldsinconsolidatedstrataareoftendocumen ted.Butfoldsinloosely consolidatedsedimentsare rarelydiscussed,probablybecauseofthefollowings:(1)folddeformationsinloosely consolidatedsedi mentsareweakortheyhavebeendestroyed;(2)tectonicactivityhasbe…     

Niger Delta gravity-driven deformation above the relict Chain and Charcot oceanic fracture zones,Gulf of Guinea: Insights from analogue models

The Niger Delta is a classic example of a passive margin delta that has gravitationally deformed above an overpressured shale decollement. The outboard Niger Delta clastic wedge, including the Akata Formation overpressured shale decollement, is differentially thickened across relict oceanic basement steps formed at the Chain and Charcot fracture zones. In this study, five analogue models were applied to investigate the effects of a differentially thickened overpressured shale decollement across relict stepped basement on Niger Delta gravity-driven deformation. Gravity-driven delta deformation was simulated by allowing a lobate, layered sandpack to deform by gravity above a ductile polymer. A first series of experiments had a featureless, horizontal basement whereas a second series had differentially thickened polymer above Niger Delta-like basement steps. Two syn-kinematic sedimentation patterns were also tested. Surface strains were analysed using digital image correlation and key models were reconstructed in 3D. All five model deltas spread radially outward and formed plan view arcuate delta top grabens and arcuate delta toe folds. The arcuate structures were segmented by dip-oriented radial grabens and delta toe oblique extensional tear faults, which were formed by along-strike extensional strains during spreading. Basement steps partitioned delta toe gravity spreading into dual, divergent directions. Similarities between the analogue model structures and the Niger Delta strongly suggest a history of outward radial gravity spreading at the Niger Delta. The Niger Delta western lobe has potentially spread downdip more rapidly due to a thicker or more highly overpressured underlying Akata Fm. shale detachment. Faster western lobe spreading may have produced the Niger Delta toe ‘dual lobe’ geometry, perturbed up dip Niger Delta top growth fault patterns, and implies that western lobe toe thrusts have been very active.     

The Monagas Fold-Thrust Belt of Eastern Venezuela. Part I: Structural and thermal modeling

The Eastern Venezuelan Basin (EVB) contains one of the largest hydrocarbon accumulations in the world. Main petroleum targets are buried structures of the Monagas Fold-Thrust Belt (MFTB) which forms the northeastern edge of the EVB. The objective of this study is to integrate the seismic and well data that has been acquired over the last 10 years across the MFTB and EVB, to create an updated structural model. Three regional cross sections 60-75 km long are presented across an area of 4000 km².Five structural domains are described: Amarilis, Furrial, Jusepín, Cotoperí and Pirital. They are characterized by thrusts and high-angle reverse faults. Structural style changes along strike are related to variations in depth of detachment levels and to the strike-slip component of the deformation. We have estimated a shortening between 43 and 59 km that increases eastward over a distance of 40 km.The evolution of the MFTB is divided in four episodes based on stratigraphic, structural and thermal maturity evidences: (1) Oligocene-early Miocene initial movement of Pirital thrust. (2) Early Miocene simultaneous movement on Pirital, Furrial and Cotoperí thrusts. (3) Middle Miocene increases in velocity and change in geometry of Pirital thrust, during an out of sequence period of thrusting. (4) Late Miocene to Holocene minor thrust activity. This evolution is consistent with the oblique convergence between the Caribbean and South American plates and the convergence between North and South America that affected Eastern Venezuela during the Cenozoic.By analyzing the along-strike variations in structural style, new exploratory opportunities have been identified. Under the Orocual and Santa Bárbara fields two untested duplex structures are proposed; they were developed during the middle Miocene. Other prospective hydrocarbon traps are associated to oblique transpressive faults that create anticline structures.     

Community respiration/production and bacterial activity in the upper water column of the central Arctic Ocean

Community metabolism (respiration and production) and bacterial activity were assessed in the upper water column of the central Arctic Ocean during the SHEBA/JOIS ice camp experiment, October 1997–September 1998. In the upper 50 m, decrease in integrated dissolved oxygen (DO) stocks over a period of 124 d in mid-winter suggested a respiration rate of ∼3.3 nM O₂ h⁻¹ and a carbon demand of ∼4.5 gC m⁻². Increase in 0–50 m integrated stocks of DO during summer implied a net community production of ∼20 gC m⁻². Community respiration rates were directly measured via rate of decrease in DO in whole seawater during 72-h dark incubation experiments. Incubation-based respiration rates were on average 3-fold lower during winter (11.0±10.6 nM O₂ h⁻¹) compared to summer (35.3±24.8 nM O₂ h⁻¹). Bacterial heterotrophic activity responded strongly, without noticeable lag, to phytoplankton growth. Rate of leucine incorporation by bacteria (a proxy for protein synthesis and cell growth) increased ∼10-fold, and the cell-specific rate of leucine incorporation ∼5-fold, from winter to summer. Rates of production of bacterial biomass in the upper 50 m were, however, low compared to other oceanic regions, averaging 0.52±0.47 ngC l⁻¹ h⁻¹ during winter and 5.1±3.1 ngC l⁻¹ h⁻¹ during summer. Total carbon demand based on respiration experiments averaged 2.4±2.3 mgC m⁻³ d⁻¹ in winter and 7.8±5.5 mgC m⁻³ d⁻¹ in summer. Estimated bacterial carbon demand based on bacterial productivity and an assumed 10% gross growth efficiency was much lower, averaging about 0.12±0.12 mgC m⁻³ d⁻¹ in winter and 1.3±0.7 mgC m⁻³ d⁻¹ in summer. Our estimates of bacterial activity during summer were an order of magnitude less than rates reported from a summer 1994 study in the central Arctic Ocean, implying significant inter-annual variability of microbial processes in this region.     

Microbial respiration in the Levantine Sea: evolution of the oxidative processes in relation to the main Mediterranean water masses

First data on microbial respiration in the Levantine Sea are reported with the aim of assessing the distribution of oxidative processes in association with the main Mediterranean water masses and the changing physical structure determined by the Eastern Mediterranean Transient. Respiratory rates, in terms of metabolic carbon dioxide production, were estimated from measured electron transport system activities in the polygonal area of the Levantine Sea (32.5–36.5 N Latitude, 26.0–30.25 E Longitude) and at Station Geo’95, in the Ionian Sea (35°34.88 N; 17°14.99 E). At the Levantine Sea, the mean carbon dioxide production rate decreased from the upper to the deeper layers and varied from 22.0±12.4 μg C h⁻¹ m⁻³ in the euphotic layer to 1.30±0.5 μg C h⁻¹ m⁻³ in the depth range between 1600 and 3000 m. Significant differences were found among upper, intermediate and bottom layers. The euphotic zone supported a daily carbon dioxide production of 96.6 mg C d⁻¹ m⁻² while the aphotic zone (between 200 and 3000 m) sustained a 177.1 mg C d⁻¹ m⁻² carbon dioxide production. In Station Geo’95, the carbon dioxide production rates amounted to 170.4 and 102.2 mg C d⁻¹ m⁻² in the euphotic and aphotic zones, respectively. The rates determined in the identified water masses showed a tight coupling of respiratory processes and Mediterranean circulation patterns. The increasing respiratory rates in the deep layers of the Levantine Sea are explained by the introduction of younger waters recently formed in the Aegean Sea.     

A sediment and organic carbon budget for the greater Strait of Georgia

Recent efforts to construct global ocean budgets for carbon have recognized the importance of continental margins. In this study, we constructed budgets for the Strait of Georgia, a temperate, North American west coast basin that receives the inflow of one of the world's major rivers. Drawing from published and unpublished data, we have estimated the magnitude of the various sources and sinks of fresh water, sediment and organic carbon.The Fraser River is the dominant source of fresh water and particles to the strait, contributing approximately 73% of the 158×10⁹ m³ year⁻¹ of water and 64% of the 30×10⁹ kg year⁻¹ of particles. Other rivers supply most of the remainder, while rain, groundwater and anthropogenic sources of water and particles are negligible in comparison. Fresh water escapes the Strait of Georgia through Juan de Fuca Strait, but particulate inputs are approximately balanced by sedimentation within the greater Strait of Georgia, implying almost complete trapping of particles.Dissolved and particulate organic carbon are derived mainly from in situ primary production (855×10⁶ kg year⁻¹) and from the Fraser River (550×10⁶ kg year⁻¹). Other rivers contribute 200×10⁶ kg year⁻¹ of organic carbon, and anthropogenic sources (ocean dumping, sewage, pulp mills and aquaculture) a further 119×10⁶ kg year⁻¹. Particulate organic carbon is predominantly buried (428×10⁶ kg year⁻¹) or oxidized (90×10⁶ kg year⁻¹) in the sediments of the strait. About 70% of the organic carbon that enters or is produced in the strait is dissolved. Most of the dissolved organic carbon is oxidized within the strait (784×10⁶ kg year⁻¹), but the remainder (400×10⁶ kg year⁻¹) is exported to the Pacific Ocean. Although the particulate organic carbon budget by itself implies net autotrophy, dissolved organic carbon oxidation may make the Strait of Georgia slightly net heterotrophic.     

Diapycnal nutrient fluxes on the northern boundary of Cape Ghir upwelling region

In this study we estimate diffusive nutrient fluxes in the northern region of Cape Ghir upwelling system (Northwest Africa) during autumn 2010. The contribution of two co-existing vertical mixing processes (turbulence and salt fingers) is estimated through micro- and fine-structure scale observations. The boundary between coastal upwelling and open ocean waters becomes apparent when nitrate is used as a tracer. Below the mixed layer (56.15±15.56 m), the water column is favorable to the occurrence of a salt finger regime. Vertical eddy diffusivity for salt (K_s) at the reference layer (57.86±8.51 m, CI 95%) was 3×10⁻⁵ (±1.89×10⁻⁹, CI 95%) m² s⁻¹. Average diapycnal fluxes indicate that there was a deficit in phosphate supply to the surface layer (6.61×10⁻⁴ mmol m⁻² d⁻¹), while these fluxes were 0.09 and 0.03 mmol m⁻² d⁻¹ for nitrate and silicate, respectively. There is a need to conduct more studies to obtain accurate estimations of vertical eddy diffusivity and nutrient supply in complex transitional zones, like Cape Ghir. This will provide us with information about salt and nutrients exchange in onshore–offshore zones.     

Impact of the Late Triassic Dashtak intermediate detachment horizon on anticline geometry in the Central Frontal Fars,SE Zagros fold belt,Iran

Integration of 2-D seismic lines, well data and field studies allow us to determine the geometry variations of anticlines in the highly prolific Central Frontal Fars region in the SE Zagros fold belt. These variations are directly related to changes in thickness of the principal evaporitic intermediate detachment level, located along the Late Triassic Dashtak Formation. Anticlines of short wavelength contain a significant over-thickening of the evaporitic detachment level in their crestal domain that may reach 1900 m (from an original thickness of 550–800 m). Folds containing thick Dashtak evaporites show decoupling across the detachment level and, thus, a shift of the anticline crest in the underlying Permo-Triassic carbonates of the Dehram Group, which form the major gas reservoir in the Central Frontal Fars. Four main parameters control the extent and distribution of the decoupled anticlines in the study area: (a) original large thickness of the Late Triassic evaporitic basin; (b) coinciding larger amounts of anhydrites with increasing total thickness of formation; (c) parallel occurrences of abnormally high fluid pressures; and (d) shortening variations across, and along, the strike of specific folds. The present work relating the different parameters of the Dashtak evaporites with the anticline geometry allows a better understanding of the fold geometry variations with depth, which is applicable to oil and gas exploration in the SE Zagros and other similar hydrocarbon provinces characterised by intermediate detachment horizons.     

Downward transport of organic carbon by diel migratory micronekton in the western equatorial Pacific:: its quantitative and qualitative importance

Using simultaneous sampling with a commercial-sized trawl, a zooplankton net, and a sediment trap, we evaluated the contribution of vertically migrating micronekton to vertical material transport (biological pump) at two stations (3°00′N, 146°00′E and 3°30′N, 145°20′E) in the western equatorial North Pacific. The gravitational sinking particulate organic carbon flux out of the euphotic zone was 54.8 mg C m⁻² day⁻¹. The downward active carbon flux by diel migrant mesozooplankton was 23.53 and 9.97 mg C m⁻² day⁻¹, and by micronekton 4.40 and 2.26mg C m⁻² day⁻¹ at the two stations. Assuming that the micronekton sampling efficiency of the trawl was 14%, we corrected the downward carbon flux due to micronekton respiration to 29.9 and 15.2mg C m⁻² day⁻¹, or 54.6 and 27.7% of the sinking particle flux at the two stations. The corrected micronekton gut fluxes were 1.53 and 0.97mg C m⁻² day⁻¹. The role of myctophid fish fecal matter as a possible food resource for deep-sea organisms, based on its fatty acid and amino acid analysis, is discussed.     

Export fluxes of particulate organic carbon in the Chukchi Sea: A comparative study using 234Th/238U disequilibria and drifting sediment traps

Large-volume sampling of ²³⁴Th and drifting sediment trap deployments were conducted as part of the 2004 Western Arctic Shelf–Basin Interactions (SBI) spring (May 15–June 23) and summer (July 17–August 26) process cruises in the Chukchi Sea. Measurements of ²³⁴Th and particulate organic carbon (POC) export fluxes were obtained at five stations during the spring cruise and four stations during the summer cruise along Barrow Canyon (BC) and along a parallel shelf-to-basin transect from East Hanna Shoal (EHS) to the Canada Basin. ²³⁴Th and POC fluxes obtained with in situ pumps and drifting sediment traps agreed to within a factor of 2 for 70% of the measurements. POC export fluxes measured with in situ pumps at 50 m along BC were similar in spring and summer (average = 14.0 ± 8.0 mmol C m^− 2 day^− 1 and 16.5 ± 6.5 mmol C m^− 2 day^− 1, respectively), but increased from spring to summer at the EHS transect (average = 1.9 ± 1.1 mmol C m^− 2 day^− 1 and 19.5 ± 3.3 mmol C m^− 2 day^− 1, respectively). POC fluxes measured with sediment traps at 50 m along BC were also similar in both seasons (31.3 ± 9.3 mmol C m^− 2 day^− 1 and 29.1 ± 14.2 mmol C m^− 2 day^− 1, respectively), but were approximately twice as high as POC fluxes measured with in situ pumps. Sediment trap POC fluxes measured along the EHS transect also increased from spring to summer (3.0 ± 1.9 mmol C m^− 2 day^− 1 and 13.0 ± 6.4 mmol C m^− 2 day^− 1, respectively), and these fluxes were similar to the POC fluxes obtained with in situ pumps. Discrepancies in POC export fluxes measured using in situ pumps and sediment traps may be reasonably explained by differences in the estimated POC/²³⁴Th ratios that arise from differences between the techniques, such as time-scale of measurement and size and composition of the collected particles. Despite this variability, in situ pump and sediment trap-derived POC fluxes were only significantly different at a highly productive station in BC during the spring.     

A 1.5D model of the steady-state thermal structure of detachment folds

We present a 1.5D steady-state model of thermal perturbations in the core of detachment anticlines. The model incorporates the effects of heat conduction, advection by folding, radiogenic sources, and conversion of work into heat by viscous dissipation. We work out analytical solutions of model's equations for heat flow and temperature field for the case of low amplitude detachment folds growing in a thick homogeneous stratigraphy.Our analytical solutions for the simplest case of no heat sources show that detachment folds develop a thermal boundary layer. Conduction of heat dominates inside the layer, whereas advection of heat by folding prevails outside the boundary layer. We also find that heat flow in a growing detachment fold decays exponentially with the square of the thickness of the detached stratigraphic section. When heat sources are included into the problem we find that radiogenic heat generates thermal anomalies at the crest of the anticlines whereas viscous dissipation produces thermal anomalies at the core of the detachment fold.We analyze three cases of geological interest: detachment folds growing in evaporitic sequences, marine carbonates, and shaley sediments. For a typical uplift rate of 2 mm/yr conduction dominates in the first class of rocks. Viscous dissipation dominates in folds growing in limestone due to its high viscosity. Advection and the generation of heat by radiogenic isotopes dominate the growth of detachment folds in shale. Additionally, the cooling histories of Lagrangian particles embedded in the fold for the last two cases are analyzed. The core of the fold is characterized by rapid cooling whereas the limbs cool at slower rates than the core. Thus, the development of detachment anticlines may either accelerate maturation of source rocks and expand the maturation window or halt it by removing source rocks from the generating window.     

Algal concentration profiles above mussel beds

The distribution of phytoplankton was measured in vertical profiles at three stations in Limfjorden (Denmark) within and above Mytilus edulis beds (−5 to 200 cm above the bed surface) and related to the filtration capacity of the mussels and hydrodynamic conditions. The density of phytoplankton was 2690 to 10 600 cells cm⁻³ at 200 cm above the bottom (∼1.4 to 3.2 mg Chl-a m⁻³), declining towards the bottom to about 1000 cells cm⁻³ at two of the stations. This is a threshold of minimum algal concentration below which mussels are reported to stop feeding. The results of the present study further demonstrate that the near-bed phytoplankton concentrations observed in the field often remained below the concentration level at which mussels reduce their maximal filtration activity.     

Vertical distribution of zooplankton and active flux across an anticyclonic eddy in the Canary Island waters

The vertical distribution (0–900 m) of zooplankton biomass and indices of feeding (gut fluorescence, GF) and metabolism (electron transfer system, ETS) were studied across an anticyclonic eddy south of Gran Canaria Island (Canary Islands). Two dense layers of organisms were clearly observed during the day, one above 200 m and the other at about 500 m, coincident with the deep scattering layer (DSL). The biomass displacement due to interzonal migrants in the euphotic zone was more than 2-fold higher than that previously reported for the southern area of this archipelago. The gut flux estimated (0.14–0.44 mgC m⁻² d⁻¹) was similar to the values previously found in the Canaries. The respiratory flux outside the eddy (1.85 mgC m⁻² d⁻¹) was in the lower range of values reported for this area. Inside the eddy, migrant biomass and respiration rates were 2- and 4- fold higher than in the surrounding waters. Active flux mediated by diel vertical migrants inside the eddy (8.28 mgC m⁻² d⁻¹) was up to 53% of the passive carbon flux to the mesopelagic zone (15.8 mgC m⁻² d⁻¹). It is, therefore, suggested that the anticyclonic eddy enhanced both migration from deep waters and active flux.     

Structural controls on Quaternary deepwater sedimentation, mud diapirism, and hydrocarbon distribution within the actively evolving Columbus foreland basin, eastern offshore Trinidad

Eastward migration of the Caribbean plate relative to the South American plate has caused lithospheric loading along the northern margin of South America, which is recorded by an 1100-km-long foreland basin which is oldest in the west (Maracaibo basin, 65-55 Ma) and youngest in the east (Columbus basin, eastern offshore Trinidad, 15-0 Ma). The Orinoco River has been the primary source of sediment for the basin since early Miocene. We have integrated approximately 775 km of deep-penetration 2D seismic lines acquired in the area of eastern offshore Trinidad as part of the 2004 “Broadband Ocean-Land Investigations of Venezuela and the Antilles arc Region” (BOLIVAR) project, 8000 km² of shallow industry 3D seismic data, and published industry well data from offshore eastern Trinidad. Active mud diapirism in the Columbus basin is widespread and is related to overthrusting and tectono-sedimentary loading of upper Miocene-lower Pliocene age mud. Analysis of the shallow 3D seismic data reveals the presence of extensive gravity-flow depositional elements on the Columbus basin slope and the deepwater area. These stacked gravity-flow deposits are characterized by mass-transport deposits at the base, turbidite frontal-splay deposits, leveed-channel deposits, and capped by fine-grained condensed-section deposits. Exploration targets in the deepwater area are located towards the center of the Columbus basin, where northeast-trending fault-propagation folds are important Plio-Pleistocene trap-forming elements. Deep basin wells drilled in recent years have proven that turbidites were transported into the deepwater Columbus basin during the Plio-Pleistocene. Analysis of these well results suggests that a deeper oil charge is present within the deepwater Columbus basin area. The primary uncertainty for this variable hydrocarbon system is whether fault or diapiric pathways connect or divert the petroleum charge at depth with shallower reservoir rocks.     

Atmospheric nitrogen deposition to the Mullica River-Great Bay Estuary

Measurements of nitrate and ammonium in precipitation and associated with aerosols were conducted at Rutgers University Marine Field Station in Tuckerton, New Jersey from March 2004 to March 2005 to characterize atmospheric nitrogen deposition to the Mullica River-Great Bay Estuary. The arithmetic means of nitrate and ammonium concentrations for precipitation samples were 2.3 mg L⁻¹ and 0.42 mg L⁻¹, respectively. Nitrate and ammonium concentrations in aerosol samples averaged 3.7 μg m⁻³ and 1.6 μg m⁻³, respectively. Wet deposition rates appeared to vary with season; the highest rate of inorganic nitrogen deposition (nitrate + ammonium) occurred in the spring with an average value of 1.33 kg-N ha⁻² month⁻¹. On an annual basis, the total (wet and dry) direct atmospheric deposition fluxes into the Mullica River-Great Bay Estuary were 7.08 kg-N ha⁻² year⁻¹ for nitrate and 4.44 kg-N ha⁻² year⁻¹ for ammonium. The total atmospheric inorganic nitrogen directly deposited to the Mullica River-Great Bay Estuary was estimated to be 4.79 × 10⁴ kg-N year⁻¹, and the total atmospheric inorganic nitrogen deposited to the Mullica River watershed was estimated to be 1.69 × 10⁶ kg-N year⁻¹. Only a fraction of the nitrogen deposited on the watershed will actually reach the estuary; most of the nitrogen will be retained in the watershed due to utilization and denitrification during transport. The amount of N reaching the Mullica River-Great Bay Estuary indirectly is estimated to be 5.07 × 10⁴ kg-N year⁻¹, approximately 97% is retained within the watershed. This atmospheric nitrogen deposition may stimulate phytoplankton productivity in the Mullica River-Great Bay ecosystem.     

Chlorine transport processes through a 2000 m aquifer/aquitard system

In the Paris Basin, in France, the Callovo-Oxfordian (COx) is currently studied over a 250 km² surface area by the French national radioactive waste management agency in order to assess the feasibility of long-term underground nuclear waste repository. The COx is a 140 m thick clay-rich layer, which is part of the 2000 m aquitard/aquifer system constituting the sedimentary cover. In such sedimentary context, the transport processes of potential contaminants can be represented by both vertical diffusion and horizontal advection through the most permeable layers.Chloride is used as a natural conservative tracer, and is monitored in term of concentrations and isotopic composition (δ³⁷Cl) for both pore and groundwater. During this study, the samples were collected from three boreholes located in the center of the studied zone, one of them (EST433) going down to 2000 m depth. The main solute transport process is shown to be vertical diffusion from the massive Keuper halite level to the rest of the sedimentary pile. This global diffusive system can be occasionally disturbed by horizontal circulation of groundwater occurring in the Oxfordian and Dogger limestone formations. Therefore, these circulations cut the global diffusive system in a succession of independent diffusive systems. In this study the data set was implemented in a simplified 2D solute transport model and scenarii reproducing known history in term of paleo circulations inside the system, were applied and allowed to obtained a good fit of the data. Model results showed that paleo circulations, occurring between −145 Ma and −110 Ma, still have an impact on current distribution of chloride in the system, especially for δ³⁷Cl. The model highlights the need of the presence of a circulation spatially limited at the base of the Liassic formation to fit the data. The best fit obtained indicated current residence time of 500 ka in the Dogger and Oxfordian, with respective onset of the circulations at −20 Ma and −5 Ma.     

南黄海陆架沉积物中褶皱的形态及成因

更新世以来南黄海陆架具有构造活动性强、沉积厚度大(100~300m)、褶皱变形保存完整等特点,是研究未固结沉积物中褶皱变形的理想“实验室”.高分辨率单道地震剖面揭示了南黄海陆架沉积物中具有不同几何形态的三种褶皱:(1)断层相关褶皱(包括断层扩展褶皱和断层牵引褶皱);(2)横向弯曲褶皱;(3)复合作用褶皱.对褶皱的成因和几何形态的研究表明,控制未固结沉积物中褶皱形成的因素是基底断层及其形成的断块,而不是区域应力场.大量孔隙水可能对沉积物的几何形变具有重要的影响作用.沉积物中断层扩展褶皱和牵引褶皱在形变程度上具有连续性,说明两者在成因上存在联系.断层扩展褶皱可能引发的地震活动和变形带在海洋工程地质评估中应受到重视.     

Denitrification prevails over anammox in tropical mangrove sediments (Goa,India)

Denitrification, anammox (Anx) and di-nitrogen fixation were examined in two mangrove ecosystems- the anthropogenically influenced Divar and the relatively pristine Tuvem. Stratified sampling at 2 cm increments from 0 to 10 cm depth revealed denitrification as the main process of N₂ production in mangrove sediments. At Divar, denitrification was ∼3 times higher than at Tuvem with maximum activity of 224.51 ± 6.63 nmol N₂ g⁻¹ h⁻¹ at 0–2 cm. Denitrifying genes (nosZ) numbered up to 2 × 10⁷ copies g⁻¹ sediment and belonged to uncultured microorganisms clustering within Proteobacteria. Anammox was more prominent at deeper depths (8–10 cm) mainly in Divar with highest activity of 101.15 ± 87.73 nmol N₂ g⁻¹ h⁻¹ which was 5 times higher than at Tuvem. Di-nitrogen fixation was detected only at Tuvem with a maximum of 12.47 ± 8.36 nmol N₂ g⁻¹ h⁻¹. Thus, in these estuarine habitats prone to high nutrient input, N₂-fixation is minimal and denitrification rather than Anx serves as an important mechanism for counteracting N loading.