强弱风浪扰动下太湖的营养盐垂向分布特征

在一次风速12m/s的强风浪过程中及在连续多天弱风浪之后,对太湖梅梁湾一浅水区营养盐、悬浮物等的垂向分布进行了观测和分析。结果表明,在水底沉积物约20cm的情况下,强风浪期间与弱风浪期间相比,湖水中悬浮物浓度提高了10倍,总磷浓度提高了3 6倍。而强风浪期间与弱风浪期间的水体溶解性总磷(DTP)、溶解性活性磷(SRP)的浓度无显著差异。说明尽管强风浪过程引起沉积物大量悬浮,水体悬浮颗粒态营养盐显著增高,但是由于悬浮过程营养盐释放与沉降机制作用十分复杂,活性营养盐的浓度未必能提高。无论强风浪还是弱风浪期间,水体的表层至水土界面上50cm层的悬浮物浓度、营养盐浓度没有明显的分层现象,但明显低于水土界面上50cm内的悬浮物浓度和总磷浓度。无论是强风浪期间还是弱风浪期间,表层到底层水体SRP浓度无显著差异。     

沉水植物黑藻对上覆水中各形态磷浓度的影响

室内模拟研究了沉水植物黑藻对上覆水中不同形态磷浓度的影响及其季节性变化,并从沉水植物生长、间隙水和碱性磷酸酶活性(APA)三方面进行了讨论,进一步揭示磷在浅水湖泊水-沉积物界面的交换机理。结果表明,在本研究条件下,上覆水中各形态磷以溶解性总磷(DTP)为主,其他形态磷浓度变异较大,黑藻降低了上覆水中总磷(TP)、溶解性活性磷(SRP)和DTP浓度,也降低了DTP和SRP占总磷的比例,从而使颗粒态总磷(PP)和溶解性有机磷(DOP)占总磷比例升高。黑藻主要通过吸收上覆水中的磷和抑止沉积物、上覆水中APA使上覆水中各形态磷浓度保持较低水平,其中对SRP和DTP浓度的影响更明显。上覆水中各形态磷浓度呈现明显的季节性变化。在7～8月,TP、SRP和DTP浓度呈下降趋势,并在8月达到最低值;9～10月间有所升高,但仍然维持在较低水平,不同采样时间存在波动。     

波浪扰动对太湖底泥磷释放影响模拟

为揭示波浪扰动对湖泊底泥磷释放的影响,在波浪水槽中模拟了不同波高情况下扰动对水体、水土界面、底泥间隙水的磷、溶解氧等的影响.结果显示,在大波扰动下,沉积物大量悬浮,水体总磷随之增加,溶解性磷增加却不显著;波浪扰动显著增加了水体和沉积物界面的溶解氧浓度,并增加了溶解氧在沉积物的侵蚀深度;波浪扰动降低了沉积物表层10 cm内间隙水中的磷浓度,而10 cm以下沉积物中间隙水中磷浓度基本保持不变.研究表明,波浪扰动可迅速增加水体中颗粒态的营养盐,但是对于溶解态营养盐,尤其是水体中活性磷浓度的影响,则受沉积物性质、水-沉积物间隙水磷浓度差,以及水-沉积物中氧含量等多方面因素的影响.     

太湖水体氮、磷赋存量的逐月变化规律研究

基于中国科学院太湖湖泊生态系统研究站2005~2009年对太湖逐月叶绿素a、氮、磷各形态因子及水深的监测,结合太湖大浦水文站的逐日水位数据,估算出2005~2009年太湖的逐日水量,并运用泰森多边形法,估算出太湖水体总氮（TN）、总磷（TP）、溶解性总氮（TDN）、溶解性总磷（TDP）、硝态氮（NO3）、铵态氮（NH4）、亚硝态氮（NO2）、反应性活性磷（PO₄）、颗粒态总氮（TPN）、颗粒态总磷（TPP）、浮游藻类叶绿素a（Chla）的逐月动态变化过程。结果表明:（1）太湖2005~2009年TN、TDN、NO₂、NO₃、NH₄、TP、TDP、PO₄、TPN、TPP、Chla的平均赋存量分别为1.36×104t、1.02×104t、0.02×104t、0.37×104t、0.25×104t、514.34 t、147.30 t、51.44 t、0.34×104t、367.04 t、7.92 t,不同月份、年际之间变化剧烈,变幅分别为106%、142%、657%、252%、233%、95%、196%、276%、236%、131%、276%;（2）2007年6月无锡贡湖水厂"饮用水危机"事件之后,截止到2009年12月,太湖水体各形态氮及总磷赋存量的下降趋势不明显,溶解性总磷、反应性活性磷的赋存量反而增高,反映出营养盐控制任务的艰巨性。本研究表明,对于年水量变幅巨大的大型湖泊,全湖水体营养盐赋存量在评估水体营养盐污染状况中是一个有价值的指标;对于太湖流域的污染控制效果,仅从浓度角度评价具有一定的缺陷,有必要从水体营养盐赋存量的变化规律上探讨其治理效果。     

滇池湖滨带叶绿素a与营养盐空间分布特征

为探讨滇池湖滨带叶绿素a与营养盐空间分布特征及其对滇池水体富营养化的影响,在滇池湖滨带设置21个采样点进行水质调查,采集滇池水样,分析测定总氮(TN)、总磷(TP)、化学需氧量(CODCr)、叶绿素a(Chla)和悬浮固体(SS)。结果表明:滇池湖滨带水体TN、TP、CODCr、Chla、SS浓度均值的空间分布存在差异,叶绿素a空间分布呈现北高南低,西高东低的趋势。滇池湖滨带的北部和东部水体Chla与TN极显著相关,TN具有强变异性。南部和西部TN与CODCr、TP显著相关,南部Chla与营养盐空间变异性较小,污染风险相对较小。按照"一区一策"的原则,滇池北部和东部湖滨带富营养化以控制TN的水平为主,南部、西部的富营养化防控则需要控制整体营养盐元素浓度。     

南印度洋海区营养盐的分布特征

探讨了南印度洋海区总有机磷(TOP)、总有机氮(TON)以及溶解无机营养盐的分布规律。分析结果表明：研究海区内溶解无机营养盐受水体中生物活动和物理过程的综合影响,表层水体由于生物活动的消耗,其磷酸盐等无机营养元素的含量一般是采样水深范围内最低的;中深层水体由于生物活动的降低以及有机质矿化作用的影响,无机营养元素的变化范围较小。表层水体中TOP和TON含量占TP和TN的主要部分,说明表层水体中的氮和磷主要以有机态形式存在,且沿着37.8°S从西向东,TOP和TON的含量以及TOP/TP和TON/TN的比值呈降低的趋势。研究海区叶绿素a的分析结果表明,初级生产力的变化可能是控制研究海区TON和TOP空间分布的主要因素。不同形态氮、磷营养元素的相关分析表明,有机营养盐和无机营养盐之间互为补充,且表层水体中有机氮和磷是水体初级生产所需营养盐的重要来源,总氮、总磷的关系表明研究区初级生产力并不受氮、磷的限制。     

浅水湖泊水体中不同颗粒悬浮物静沉降规律研究

为了解浅水湖泊水体中颗粒悬浮物的静沉降规律,以太湖为例,采用重复深度吸管法计算了2005年4月、5月间在太湖进行的4次静沉降模拟实验中的沉降速度。结果表明:①在悬浮物沉降过程内,3种颗粒物的沉速关系为颗粒无机物(PIM)>悬浮物(SS)>颗粒有机物(POM)。在相同的沉降时间内,PIM的沉速为SS沉速的1.6~2.0倍,POM的沉速为SS沉速的0.3~0.7倍,PIM的沉速为POM沉速的2.5~5.5倍;②水体中悬浮物浓度与沉降时间均呈现出明显的指数衰减规律,悬浮物中无机物含量较高时这种规律更为明显;③悬浮物浓度较低时,太湖悬浮物的沉降速率与水体中的悬浮物浓度无明显的相关关系;而悬浮物浓度较高时,沉降速率随悬浮物浓度升高而增大。     

长江悬浮颗粒物中磷的赋存形态

2006年9~10月在长江采集悬浮颗粒物样品,应用改进后的SEDEX法对磷的赋存形态进行了分析.结果表明,自生磷灰石磷是长江悬浮颗粒物中磷的主要赋存形态.涪陵至万州江段,碎屑磷灰石磷的含量较高,弱吸附态磷和有机磷含量较低,磷的赋存形态主要受悬浮颗粒物含量的影响;香溪至葛洲坝下江段,弱吸附态磷和有机磷含量较高,碎屑磷灰石磷含量较低,磷的赋存形态主要受浮游植物生长及泥沙粒径的影响;城陵矶至大通江段,有机磷、碎屑磷灰石磷和铁结合态磷含量较高,弱吸附态磷含量较低,磷的赋存形态主要受泥沙粒径和洞庭湖输入的影响.长江悬浮颗粒物中生物可利用磷占颗粒态磷的45.6%,长江上游水体中生物可利用磷含量较低,下游含量较高.     

平水期洞庭湖不同形态磷赋存特征

通过现场调查和室内实验,对平水期洞庭湖24个断面上覆水-沉积物磷的污染程度、分布特征进行研究;同时,分析了各形态磷间的相关性,探讨了磷的赋存形态对水体富营养化的影响、沉积物释放量和释放风险。结果表明,水体内总磷分布规律为南洞庭西洞庭东洞庭大通湖,东洞庭湖以颗粒态磷为主,西洞庭湖、南洞庭湖、大通湖均以溶解态磷、无机磷为主。沉积物中总磷的分布规律为南洞庭西洞庭东洞庭大通湖。东洞庭湖、西洞庭湖、南洞庭湖则以Ca-P为主,大通湖以Fe/Al-P为主。Ca-P与Fe/Al-P呈现较显著的负相关关系。大通湖释放风险较大,可释放量大;东洞庭湖有一定的可释放量,应对这两个湖泊给予较多的关注。与国内其他湖泊比较,洞庭湖沉积物中TP处于中下水平,IP在沉积物中占据较高比例。湖区沉积物中Fe/Al-P与水体中DIP、DTP、TP均具有较显著的负相关关系,存在磷的内源释放。     

长江中下游不同营养水平湖泊水体环境变化特征及机制

选择长江中下游49个湖泊进行不同季节的水体溶解无机氮(DIN)、总氮(TN)、总磷(TP),溶解性无机磷(DIP)以及叶绿素a(Chla)等环境参数分析,开展不同营养水平湖泊水体环境变化特征及生物响应机制研究。结果表明:DIN、TN/TP随TP的变化规律反映了不同营养水平和季节下地球化学作用的影响;氨氮(NH₄-N)、TP、DIP、Chla尤其是NH₄-N的季节性变化规律与营养水平关系密切;TP<0.05 mg/L时,NH₄-N随总磷升高的趋势夏季大于其他季节,TN/TP与硝态氮(NO₃-N)、TN相关性好,营养源组成和氨化作用是主要影响因素;0.05 mg/L4-N随总磷升高的趋势基本相同,TN/TP与亚硝态氮(NO₂-N)、NO₃-N、TN相关好,水生植物利用、氨化和反硝化作用是主要影响因素。TP>0.1 mg/L,冬季NH₄-N随总磷升高的趋势明显大于其他季节,TN/TP在冬季和春季与TN、NO₃-N相关性好,夏季和秋季与TP相关性好,其主要原因在于夏季和秋季水生植物对DIN的利用量、反硝化作用和湖泊内源释放的显著增强。     

河岸带土壤磷素空间分布及其对水文过程响应

野外观测太湖地区典型农业河岸带——浯溪荡河岸带土壤总磷（TP）和溶解性总磷（DTP）含量以及当地降雨量、河水水位和地下水水位,探讨了丰水年条件下该河岸带土壤TP和DTP的空间分布特征以及水文过程对其空间分布的影响。结果表明:①在水平方向上,土壤TP和DTP含量从远岸向近岸均呈现先减少后增加的变化趋势;在深度方向上,各断面TP和DTP含量随土层深度的增加均呈减少的变化趋势。②不同月份河水水位均低于地下水水位,地下水补给河水。河水水位和地下水水位随时间的变化规律与降雨量的相似,但具有一定的滞后性。③降雨是土壤水分运动的主要驱动力,降雨、河水水位以及地下水水位对河岸带土壤磷素空间分布的影响显著不同。     

Distribution of phosphorus along the Delaware,an urbanized coastal plain estuary

The Delaware Estuary is heavily urbanized with elevated concentrations of phosphorus from industrial and municipal inputs. For 24 research cruises during 1986–1988, total phosphorus (TP) concentration was highest near maximum inputs in the tidal river and at low salinity where turbidity was maximal. In these contiguous regions, average TP concentration over the study period was 5.3–6.1 μM. Downstream of the TP peak in the high turbidity zone of the estuary, TP decreased to minimum concentrations (1.3–1.5 μM) near the mouth of Delaware Bay. Distributions of dissolved reactive (DRP), dissolved organic (DOP), and particulate (PP) phosphorus along the estuary reflected spatial and temporal patterns in phosphorus inputs, turbidity, river flow, and biological production. In the river, DRP was 2–4 μM (51–65% of TP) and inversely related to river flow. PP, although enriched in the river (1–3 μM), was highest (>4 μM) in the turbidity maximum at low salinity. In the bay, distributions of DRP, PP, and DOP were all linked, in different ways, to biological production. The dependence of DOP on production was, however, complex and affected by DRP concentrations. During the past 30 yr, there has been a fourfold decrease in TP concentrations in the tidal river of the Delaware Estuary. This dramatic decrease in TP, however, is contrasted by an apparent increase in DRP concentration over the past 12 yr. This apparent increase in DRP may be linked to improved water quality (e.g., higher pH) in the river over the past decade.     

Influence of inactivation agents on phosphorus release from sediment

The effects of inactivation agents, including common polymeric aluminium (Al) chloride (CPAC) and Ecological Type PAC (UNIC), on phosphorus (P) released from sediment are unclear. To determine these effects, we performed seven experiments using various inactivation agent additions. The experimental schemes used were as follows: (1) CPAC, 15 mg Al L^?1; (2) CPAC (15 mg Al L^?1) + polyacrylamide (PAM) (0.5 mg L^?1); (3) UNIC, 5 mg Al L^?1; (4) UNIC, 15 mg Al L^?1; (5) UNIC, 60 mg Al L^?1; (6) control set without any inactivation agent addition; and (7) alkali shock load (the pH value of overlying water in the scheme 7 was adjusted to 11 by addition of sodium hydroxide to simulate alkali shock load at 13 days after CPAC addition). The experiments were conducted in glass columns, each containing 0.3 L sediment from Lake Dianchi and 3 L of overlying water. The results showed that P release rate decreased as the amount of inactivation agent added increased. P release rate was calculated according to each inactivation agent and the amount of inactivation agent added. Release rate found was in the decreasing order: (6) > (3) > (4) > (1) > (5) > (2). The corresponding rate was calculated to be 7.11, 6.16, 4.55, 1.76, 1.46 and 1.00 mg P m^?2 day^?1, respectively. Dissolved total P (DTP) was the main form of total P (TP) in the overlying water. After the addition of PAM, the DTP:TP ratio decreased while the dissolved inorganic P (DIP):DTP ratio increased. With increasing the amount of inactivation agents added, both DTP:TP and DIP:TP ratios decreased. Experimental group 3 had similar DTP:TP and DIP:TP ratios to experimental group 6. These results are significant in terms of the large-scale application of inactivation agents for reducing levels of bioreactive P. Alkali shock load (experimental group 7) caused failure in the inactivation of P by CPAC.     

Sediment phosphorus fractions and profile distribution at different vegetation growth zones in a macrophyte dominated shallow Wuliangsuhai Lake,China

Sediment phosphorus (P) fractions and profile distribution at submerged macrophyte growth zone, emergent macrophyte growth zone and open-water zone were studied in Wuliangsuhai Lake, China, as well as the correlations among water content, grain size, and organic matter and P fractions. Among the three surveyed zones, the highest concentrations of most P forms occurred in the surface sediment and the lowest between a depth of 12 and 22 cm, except HCl-P and NaOH-P. Sediment phosphorus was mainly associated to inorganic forms (>50%) in three surveyed areas, and the highest value of inorganic phosphorus (IP) in the surface sediment was obtained from submerged macrophyte growth zone. Submerged and emergent macrophytes increased the IP content by 107 and 44 μg/g, respectively, in the surface sediment compared with open-water zone. Vertical profiles of IP in the three surveyed zones showed that the concentrations decreased from surface to 12 cm depth and then increased. There was a similar trend in the sediment profiles of organic phosphorus (OP) and total phosphorus (TP), but the highest concentration of OP and TP in surface sediment was obtained from the emergent macrophyte growth zone. Compared with open-water zone, the emergent macrophyte increased TP content in surface sediment by 1.73 times to 1,320 μg/g, while submerged macrophyte enhanced TP content in the surface sediment by 1.13 times to 865 μg/g. It was observed that in macrophyte growth zones, a strong linear correlation existed between organic matter and OP (r > 0.98), and the maximum concentrations of OP were present in the areas with maximum concentrations of organic matter. Results show that, although rooted macrophyte could uptake directly P from sediments, it is responsible for increasing the internal P loading especially OP by reducing current velocities, attenuating wave energy and generating organic residue in Wuliangsuhai Lake.     

爆破开挖对岩体含水裂纹扩展的扰动机制

岩体裂纹的水力劈裂是岩体开裂渗漏甚至施工涌水的重要影响因素之一,也是岩土工程界的研究热点。从断裂力学角度分析了爆破开挖对岩体含水裂纹扩展的扰动作用,结果表明,爆破开挖扰动下,岩体含水裂纹的扩展,与爆炸应力波强度及其入射角、地应力的大小与方向、孔隙水压大小、裂纹的倾角及断裂韧度等因素相关;爆炸应力波的作用,相当于增大了岩体裂纹中的孔隙水压力,每1 cm/s的峰值振动速度相当于增大100 kPa的孔隙水压力,爆破振动速度越大,所产生的爆破扰动荷载越大;岩体开挖引起的岩体裂纹近区地应力及其孔隙水压力的变化,对裂纹的失稳与扩展具有较复杂的影响,可改变裂纹的失稳扩展模式。     

Phosphorus in suspended matter and sediments of a hypertrophic lake. A case study: Lake Dianchi,China

From June 2004 to December 2004, Lake Dianchi, which had large scale of cyanobacterial blooms was investigated in order to study P-fractionation in the suspended matter and the sediment. The investigation improves our understanding of phosphorus in Lake Dianchi and the relationship between phosphorus and cyanobacterial blooms. It contributes to the available literature on the behavior of P in hypertrophic lakes. The distribution of P-fractions in Lake Dianchi was not uniform from northwest to south, but was closely related to the trophic status of the whole lake. The concentrations of total phosphorus, labile P (NH₄Cl-P), Organic P (NaOH-NRP) and loss on ignition in suspended matter were positively correlated with the strength of cyanobacterial blooms. Total phosphorus in suspended matter was relatively stable for almost half an year and closely related to Chl. a concentration. The main content of organic phosphorus is in the cyanobacterial blooms. The concentrations of phosphorus bound to metal oxides and carbonates (NaOH-SRP and HCl-P) in sediment were similar to NaOH-SRP and HCl-P in the corresponding suspended matter. The latter two forms of P in suspended matter were not affected by cyanobacterial blooms, indicating that the inorganic phosphorus is derived from the sediment after resuspension from the sediment due to wind and wave action. The contribution of the different P-fractions to TP in sediment and in suspended matter indicates that NH₄Cl-P in the suspended matter is an important buffer for maintaining dissolved phosphorus in water.