洎水河流域重金属污染区五节芒叶片光谱特征响应研究

利用污染物富集因子和污染指数对洎水河流域采样点河滩表层土壤重金属污染状况进行评价。通过分析五节芒叶片重金属富集率,发现五节芒对Cu、Zn、Cr等金属元素有较强的吸收能力,而且,重金属富集率与河滩表层土壤的重金属污染程度呈相反的变化趋势。将五节芒叶片光谱特征参数——可见光波段(450~670 nm)反射率积分值(A1)、近红外波段(760~980 nm)反射率积分值(A2)与五节芒叶片中3种重金属(Cu、Zn、Cr)的质量分数进行相关分析,分别建立2个谱段的光谱特征参数与3种重金属质量分数的多元线性回归方程。结果表明,五节芒叶片中重金属Cu、Zn和Cr的质量分数可以很好地模拟(复相关系数R20.93)五节芒叶片在重金属胁迫下的光谱特征变化。     

GIS的矿区土壤重金属污染评价及空间分布

针对土壤中的重金属含量超标会对人体健康造成极大危害的问题,为检测矿区土壤重金属含量超标状况及空间分布特征,以江西省信丰县4个矿区为例,在28个点位的20~60cm处测定Hg、Cd、As、Cu、Pb、Ni的含量,采用地统计学和地理信息系统相结合的方法进行分析。结果表明,单因子污染指数显示Pb的污染程度最大,污染程度为中度污染;插值分析图显示Cu以西南方向的虎山矿区含量较高,Ni以西南方向的虎山矿区和北部的赤岗矿区含量较高,Pb的污染区域贯穿于整个分布区;重金属含量随深度的增加无明显变化。结合在污染修复方面的经验,建议通过植物修复技术、物理与化学方法进行污染治理和修复。     

基于GIS的矿区土壤重金属污染评价及空间分布

针对土壤中的重金属含量超标会对人体健康造成极大危害的问题,为检测矿区土壤重金属含量超标状况及空间分布特征,以江西省信丰县4个矿区为例,在28个点位的20~60cm处测定Hg、Cd、As、Cu、Pb、Ni的含量,采用地统计学和地理信息系统相结合的方法进行分析。结果表明,单因子污染指数显示Pb的污染程度最大,污染程度为中度污染;插值分析图显示Cu以西南方向的虎山矿区含量较高,Ni以西南方向的虎山矿区和北部的赤岗矿区含量较高,Pb的污染区域贯穿于整个分布区;重金属含量随深度的增加无明显变化。结合在污染修复方面的经验,建议通过植物修复技术、物理与化学方法进行污染治理和修复。     

基于GIS的矿区土壤重金属污染评价及空间分布

针对土壤中的重金属含量超标会对人体健康造成极大危害的问题,为检测矿区土壤重金属含量超标状况及空间分布特征,以江西省信丰县4个矿区为例,在28个点位的20~60cm处测定Hg、Cd、As、Cu、Pb、Ni的含量,采用地统计学和地理信息系统相结合的方法进行分析。结果表明,单因子污染指数显示Pb的污染程度最大,污染程度为中度污染;插值分析图显示Cu以西南方向的虎山矿区含量较高,Ni以西南方向的虎山矿区和北部的赤岗矿区含量较高,Pb的污染区域贯穿于整个分布区;重金属含量随深度的增加无明显变化。结合在污染修复方面的经验,建议通过植物修复技术、物理与化学方法进行污染治理和修复。     

基于GIS的矿区土壤重金属污染评价及空间分布

针对土壤中的重金属含量超标会对人体健康造成极大危害的问题,为检测矿区土壤重金属含量超标状况及空间分布特征,以江西省信丰县4个矿区为例,在28个点位的20~60cm处测定Hg、Cd、As、Cu、Pb、Ni的含量,采用地统计学和地理信息系统相结合的方法进行分析。结果表明,单因子污染指数显示Pb的污染程度最大,污染程度为中度污染;插值分析图显示Cu以西南方向的虎山矿区含量较高,Ni以西南方向的虎山矿区和北部的赤岗矿区含量较高,Pb的污染区域贯穿于整个分布区;重金属含量随深度的增加无明显变化。结合在污染修复方面的经验,建议通过植物修复技术、物理与化学方法进行污染治理和修复。     

基于GIS的矿区土壤重金属污染评价及空间分布

针对土壤中的重金属含量超标会对人体健康造成极大危害的问题,为检测矿区土壤重金属含量超标状况及空间分布特征,以江西省信丰县4个矿区为例,在28个点位的20~60cm处测定Hg、Cd、As、Cu、Pb、Ni的含量,采用地统计学和地理信息系统相结合的方法进行分析。结果表明,单因子污染指数显示Pb的污染程度最大,污染程度为中度污染;插值分析图显示Cu以西南方向的虎山矿区含量较高,Ni以西南方向的虎山矿区和北部的赤岗矿区含量较高,Pb的污染区域贯穿于整个分布区;重金属含量随深度的增加无明显变化。结合在污染修复方面的经验,建议通过植物修复技术、物理与化学方法进行污染治理和修复。     

矿区土壤重金属Pb、Cd污染状况高光谱分类建模

针对矿区土壤重金属含量高度变异性及样本不均衡导致重金属污染状况分类误差较大的问题,本文在光谱预处理及光谱变换基础上,采用主成分分析（PCA）对光谱进行降维处理,并通过SMOTE算法生成虚拟样本均衡各污染等级样本,最后应用随机森林（RF）对Cd、Pb进行回归与分类。研究结果表明：定量反演重金属Pb、Cd含量精度很低;在定性分析试验中对降维前光谱样本应用SMOTE算法,土壤重金属Pb、Cd污染等级分类精度较原始样本分类精度均有较大提升,且少数类别误判率也降低明显。其研究为大面积监测矿区土壤重金属污染状况提供了一种有效、精确的方法。     

湖南典型矿区耕地土壤重金属空间特征研究

运用GS+及GIS技术,对茶陵县耕地土壤中Cd、Cr、Pb、As、Hg的含量进行了特定阈值的条件概率空间分布特征研究。结果显示,该区耕地土壤Cd超标最为严重,其余4种重金属元素污染较轻,其中Cd、Pb、As含量的空间变异性较强。重金属Cd、Cr、Pb、As、Hg监测值的指示变异函数最佳拟合模型全都为指数模型,Cd、Pb、As和Hg的空间自相关性较强,Cr体现为中等强度的空间相关性。茶陵县耕地土壤Cd污染高风险区域位于八团乡、高垅镇以及平水镇,Cr污染高风险区域位于潞水镇、平水镇;Pb污染高风险区域位于平水镇、七地乡、八团乡、高垅镇、尧水乡以及严塘镇,As污染高风险区域位于高垅镇、桃坑乡、严塘镇以及平水镇;Hg污染高风险区集中在平水镇和秩堂乡。研究结果可为研究区域的重金属污染综合防控和农业安全生产布局提供科学依据。     

基于GIS的土壤重金属数据库构建及应用

本文首先探讨了利用GIS技术构建上海市基本农田土壤重金属数据库的方法,该数据库集空间数据、采样点监测数据和元数据于一体,对于土壤重金属信息的管理、应用服务等具有重要的基础作用,是农产品安全生产环境认证和土壤环境长效管理的重要依据;接着,基于数据库进行了重金属元素的描述性统计、动态累积和Kriging插值分析;结果表明,除As外,其余重金属平均含量均高于该区域的背景值含量,尤其是Cd、Hg、Zn、Cu累积指数较高,是上海市农田土壤重金属污染的主要元素。     

频率域光谱的土壤铜铅浓度差异区分及反演研究EI北大核心CSCD

土壤是人类生存环境的重要载体,土壤重金属污染问题一直备受关注。随着可见光-短波红外(VNIR-SWIR)高光谱和X-射线荧光(XRF)技术的发展,因其具有光谱信息量大、高效便利、可无损监测等的优势,在土壤重金属浓度监测中取得了越来越多的成果。总结其应用成果来看,只能借助光谱域变换反演土壤Cu、Pb浓度,鲜有对Cu、Pb污染土壤光谱从频率域角度进行局部细节信息的深入挖掘。     

土壤重金属污染灰色综合评价模型

针对稀疏采样难以准确估测区域土壤重金属综合污染情况和迁移变化规律的问题,提出基于GIS的多属性决策组合赋权灰色综合评价模型。首先采用GIS技术揭示土壤重金属空间变异和污染分布格局;然后利用最大化熵理论集成主客观因素,架构优化组合赋权的土壤重金属污染灰色综合评价体系;最后以试验区土壤中8种(铜、锌、铅、镉、砷、铬、汞、镍)重金属的综合污染情况为例,检验该方法应用效果。结果表明:最优组合权重的灰色综合分析方法兼顾主观偏好和客观属性,其评价结果具有更高的可信度和风险辨识度,提高了综合评价的合理性与有效性,可为土壤重金属污染监测提供方案参考。     

基于GIS的县域土壤重金属生态风险评价

为研究经济快速发展区农田土壤中重金属的含量及污染状况,本文以浙江省慈溪市为研究对象,研究土壤中铜、汞、镉、铅、砷、铬、锌七种重金属含量特征,并采用潜在生态危害指数法对其进行评价,并绘制生态风险危害指数分级图。结果表明:土壤中除汞元素含量较高外,其他各元素含量仅稍高于当地土壤背景值。七种元素的单因子污染指数Cfi值均属于中等的污染参数,综合污染指数Cd上限值已处于高污染指数的范围,但平均值为属于中等污染水平。从潜在生态风险评价结果来看,七种元素的单项潜在生态风险参数Eri的值也只有汞达到了强生态危害,七种元素综合潜在生态危害指数RI刚刚达到中等生态危害水平,说明该区农田土壤尚处于较低的生态风险状态。生态危害指数插值结果表明,慈溪市重金属元素的高风险区分布在中南部人类活动较为活跃、城乡工业较发达的区域,在今后的土地利用中,应高度重视人类活动对土壤重金属污染的影响。     

Feasibility of estimating heavy metal contaminations in floodplain soils using laboratory-based hyperspectral data—A case study along Le’an River,China

It is necessary to estimate heavy metal concentrations within soils for understanding heavy metal contaminations and for keeping the sustainable developments of ecosystems. This study, with the floodplain along Le’an River and its two branches in Jiangxi Province of China as a case study, aimed to explore the feasibility of estimating concentrations of heavy metal lead (Pb), copper (Cu) and zinc (Zn) within soils using laboratory-based hyperspectral data. Thirty soil samples were collected, and their hyperspectral data, soil organic matters and Pb, Cu and Zn concentrations were measured in the laboratory. The potential relations among hyperspectral data, soil organic matter and Pb, Cu and Zn concentrations were explored and further used to estimate Pb, Cu and Zn concentrations from hyperspectral data with soil organic matter as a bridge. The results showed that the ratio of the first-order derivatives of spectral absorbance at wavelengths 624 and 564 nm could explain 52% of the variation of soil organic matter; the soil organic matter could explain 59%, 51% and 50% of the variation of Pb, Cu and Zn concentrations with estimated standard errors of 1.41, 48.27 and 45.15 mg·kg?; and the absolute estimation errors were 8%–56%, 12%–118% and 2%–22%, and 50%, 67% and 100% of them were less than 25% for Pb, Cu and Zn concentration estimations. We concluded that the laboratory-based hyperspectral data hold potentials in estimating concentrations of heavy metal Pb, Cu and Zn in soils. More sampling points or other potential linear and non-linear regression methods should be used for improving the stabilities and accuracies of the estimation models.     

Feasibility of Estimating Heavy Metal Contaminations in Floodplain Soils Using Laboratory-Based Hyperspectral Data—A Case Study Along Le’an River, China

It is necessary to estimate heavy metal concentrations within soils for understanding heavy metal contaminations and for keeping the sustainable developments of ecosystems.This study,with the floodplain along Le’an River and its two branches in Jiangxi Province of China as a case study,aimed to explore the feasibility of estimating concentrations of heavy metal lead(Pb),copper(Cu) and zinc(Zn) within soils using laboratory-based hyperspectral data.Thirty soil samples were collected,and their hyperspectral data,soil organic matters and Pb,Cu and Zn concentrations were measured in the laboratory.The potential relations among hyperspectral data,soil organic matter and Pb,Cu and Zn concentrations were explored and further used to estimate Pb,Cu and Zn concentrations from hyperspectral data with soil organic matter as a bridge.The results showed that the ratio of the first-order derivatives of spectral absorbance at wavelengths 624 and 564 nm could explain 52% of the variation of soil organic matter;the soil organic matter could ex-plain 59%,51% and 50% of the variation of Pb,Cu and Zn concentrations with estimated standard errors of 1.41,48.27 and 45.15 mg·kg-1;and the absolute estimation errors were 8%-56%,12%-118% and 2%-22%,and 50%,67% and 100% of them were less than 25% for Pb,Cu and Zn concentration estimations.We concluded that the laboratory-based hyperspectral data hold potentials in esti-mating concentrations of heavy metal Pb,Cu and Zn in soils.More sampling points or other potential linear and non-linear regression methods should be used for improving the stabilities and accuracies of the estimation models.     

Estimation of Heavy-Metal Contamination in Soil Using Remote Sensing Spectroscopy and a Statistical Approach

Heavy-metal-contaminated soil is a critical environmental issue in suburban regions. This paper focuses on utilizing field spectroscopy to predict the heavy metal contents in soil for two suburban areas in the Jiangning District (JN) and the Baguazhou District (BGZ) in China. The relationship between the surface soil heavy metal contents and spectral features was investigated through statistical modeling. Spectral features of several spectral techniques, including reflectance spectra (RF), the logarithm of reciprocal spectra (LG) and continuum-removal spectra (CR), were employed to establish and calibrate models regarding to Cd, Hg and Pb contents. The optimal bands for each spectral feature were first selected based on the spectra of soil samples with artificially added heavy metals using stepwise multiple linear regressions. With the chosen bands, the average predictive accuracies of the cross-validation, using the coefficient of determination R², for estimating the heavy metal contents in the two field regions were 0.816, 0.796 and 0.652 for Cd; 0.787, 0.888 and 0.832 for Pb; and 0.906 and 0.867 for Hg based on partial least squares regression. Results show that better prediction accuracies were obtained for Cd and Hg, while the poorest prediction was obtained for Pb. Moreover, the performances of the LG and CR models were better than that of the RF model for Pb and Hg, indicating that LG and CR can provide alternative features in determining heavy metal contents. Overall, it’s concluded that Cd, Hg and Pb contents can be assessed using remote-sensing spectroscopy with reasonable accuracy, especially when combined with library and field-collected spectra.     

Remote sensing of soybean stress as an indicator of chemical concentration of biosolid amended surface soils

The accumulation of heavy metals in the biosolid amended soils and the risk of their uptake into different plant parts is a topic of great concern. This study examines the accumulation of several heavy metals and nutrients in soybeans grown on biosolid applied soils and the use of remote sensing to monitor the metal uptake and plant stress. Field and greenhouse studies were conducted with soybeans grown on soils applied with biosolids at varying rates. The plant growth was monitored using Landsat TM imagery and handheld spectroradiometer in field and greenhouse studies, respectively. Soil and plant samples were collected and then analyzed for several elemental concentrations. The chemical concentrations in soils and roots increased significantly with increase in applied biosolid concentrations. Copper (Cu) and Molybdenum (Mo) accumulated significantly in the shoots of the metal-treated plants. Our spectral and Landsat TM image analysis revealed that the Normalized Difference Vegetative Index (NDVI) can be used to distinguish the metal stressed plants. The NDVI showed significant negative correlation with increase in soil Cu concentrations followed by other elements. This study suggests the use of remote sensing to monitor soybean stress patterns and thus indirectly assess soil chemical characteristics.     

模拟多光谱的土壤重金属含量反演研究初探

根据多光谱传感器的光谱响应函数,采用实测ISI921VF反射光谱数据模拟Landsat卫星ETM+传感器多光谱数据,在模拟光谱的基础上,通过光谱特征提取、构建土壤指数对土壤重金属Cu,Pb,As进行预测分析。研究显示,Cu,Pb与模拟ETM+光谱的B2,B3波段显著相关,As与DSI,RSI,NDSI相关系数在0.6以上,基于模拟多光谱建立的Cu,As模型精度较高,平均相对误差分别为7.9%,2.7%,表明模拟的Landsat卫星ETM+传感器多光谱具有预测耕地土壤重金属的潜力,为实现大范围监测土壤重金属污染提供新思路。