Paleohydrology and paleochemistry of Lake Manitoba,Canada: the isotope and ostracode records

Lake Manitoba, the largest lake in the Prairie region of North America, contains a fine-grained sequence of late Pleistocene and Holocene sediment that documents a complex postglacial history. This record indicates that differential isostatic rebound and changing climate have interacted with varying drainage basin size and hydrologic budget to create significant variations in lake level and limnological conditions. During the initial depositional period in the basin, the Lake Agassiz phase (12–9 ka), ¹⁸O of ostracodes ranged from –16 to –5 (PDB), implying the lake was variously dominated by cold, dilute glacial meltwater and warm to cold, slightly saline water.Candona subtriangulata, which prefers cold, dilute water, dominates the most negative ¹⁸O intervals, when the basin was part of proglacial Lake Agassiz. At times during this early phase, the ¹⁸O of the lake abruptly shifted to higher values; euryhaline taxa such asC. rawsoni orLimnocythere ceriotuberosa, and halobiont taxa such asL. staplini orL. sappaensis are dominant in these intervals. This positive covariance of isotope and ostracode records implies that the lake level episodically fell, isolating the Lake Manitoba basin from the main glacial lake.¹⁸O values from inorganic endogenic Mg-calcite in the post-Agassiz phase of Lake Manitoba trend from –4 at 8 ka to –11 at 4.5 ka. We interpret that this trend indicates a gradually increasing influence of isotopically low (–20 SMOW) Paleozoic groundwater inflow, although periods of increased evaporation during this time may account for zones of less negative isotopic values. The ¹⁸O of this inorganic calcite abruptly shifts to higher values (–6) after 4.5 ka due to the combined effects of increased evaporative enrichment in a closed basin lake and the increased contribution of isotopically high surface water inflow on the hydrologic budget. After 2 ka, the ¹⁸O of the Mg-calcite fluctuates between –13 and –7, implying short-term variability in the lake's hydrologic budget, with values indicating the lake varied from outflow-dominated to evaporation-dominated. The ¹³C values of Mg-calcite remain nearly constant from 8 to 4.5 ka and then trend to higher values upward in the section. This pattern suggests primary productivity in the lake was initially constant but gradually increased after 4.5 ka.This is the sixth in a series of papers published in this issue on the paleolimnology of arid regions. These papers were presented at the Sixth International Palaeolimnology Symposium held 19–21 April, 1993 at the Australian National University, Canberra, Australia. Dr A. R. Chivas served as guest editor for these papers.     

Abrupt changes in climatic conditions across the late-glacial/Holocene transition on the N. E. Tibet-Qinghai Plateau: evidence from Lake Qinghai, China

A multi-proxy investigation of two sediment cores from the large closed-basin Lake Qinghai provides evidence of abrupt changes in paleolimnological conditions across the late-glacial/Holocene transition. The chronology of the lacustrine sediment sequence is framed by four AMS ¹⁴C ages for aquatic-plant macrofossil seeds. Four distinct stratigraphic units are identified on the basis of abrupt shifts in lithology, carbonate composition, ¹⁸O of authigenic carbonates, magnetic susceptibility characteristics, and total nitrogen content. These units represent four environmental stages that were each initiated by three abrupt changes in hydro-climatic regime at 11,600, 10,700, and 10,000 ¹⁴C yrs B.P. Each of the four environmental stages thus represents a characteristic precipitation-to-evaporation balance for the lake catchment. The paleoenvironmental evidence indicates that the lake before 11,600 ¹⁴C yrs B.P. was very shallow with carbonate production and organic productivity much lower than in the Holocene, suggesting a much colder and drier climate than in the Holocene. From 11,600 to 10,700 ¹⁴C yrs B.P., the presence of clastic laminations and Ruppia fossil seeds suggests an increased inflow of sediment-laden waters into the lake. Between 10,700 and 10,000 ¹⁴C yrs B.P., the development of a carbonate playa lake indicates that a negative water balance persisted. From 10,000 ¹⁴C yrs B.P. an abrupt increase in rainfall is suggested by a sudden termination of the playa lake environment and the diluted lake waters, as evidenced by negative shift in both total carbonate content and ¹⁸O values of mineral carbonate. However, the lake level during the early Holocene was about 20 m shallower than today, indicating that the effective moisture then was much lower than it is today. The multi-proxy record suggests a step-wise pattern of climatic change across the late-glacial/Holocene transition along with abrupt shifts in P-E balance on the N. E. Tibet-Qinghai Plateau. This pattern is characterized by reorganization of Asian monsoon circulation, which probably was determined by increasing summer insolation and changes in surface boundary conditions accompanying regional deglaciation. The arid event at 10,700–10,000 ¹⁴C yrs B.P. is interpreted as a Younger Dryas equivalent, although climatic cooling is not indicated by the evidence at hand.     

Influence of vegetation change on watershed hydrology: implications for paleoclimatic interpretation of lacustrine δ18O records

Stratigraphic shifts in the oxygen isotopic (¹⁸O) and trace element (Mg and Sr) composition of biogenic carbonate from tropical lake sediment cores are often interpreted as a proxy record of the changing relation between evaporation and precipitation (E/P). Holocene ¹⁸O and Mg and Sr records from Lakes Salpetén and Petén Itzá, Guatemala were apparently affected by drainage basin vegetation changes that influenced watershed hydrology, thereby confounding paleoclimatic interpretations. Oxygen isotope values and trace element concentrations in the two lowland lakes were greatest between ~ 9000 and 6800 ¹⁴C-yr BP, suggesting relatively high E/P, but pollen data indicate moist conditions and extensive forest cover in the early Holocene. The discrepancy between pollen- and geochemically-inferred climate conditions may be reconciled if the high early Holocene ¹⁸O and trace element values were controlled principally by low surface runoff and groundwater flow to the lake, rather than high E/P. Dense forest cover in the early Holocene would have increased evapotranspiration and soil moisture storage, thereby reducing delivery of meteoric water to the lakes. Carbonate ¹⁸O and Mg and Sr decreased between 7200 and 3500 ¹⁴C-yr BP in Lake Salpetén and between 6800 and 5000 ¹⁴C-yr BP in Lake Petén Itzá. This decline coincided with palynologically documented forest loss that may have led to increased surface and groundwater flow to the lakes. In Lake Salpetén, minimum ¹⁸O values (i.e., high lake levels) occurred between 3500 and 1800 ¹⁴C-yr BP. Relatively high lake levels were confirmed by ¹⁴C-dated aquatic gastropods from subaerial soil profiles ~ 1.0–7.5 m above present lake stage. High lake levels were a consequence of lower E/P and/or greater surface runoff and groundwater inflow caused by human-induced deforestation.     

Geochemical and organic petrological characterization of the organic matter of lacustrine Eocene oil shales (Prinz von Hessen,Germany): reconstruction of the depositional environment

Optical and geochemical techniques were applied to sedimentary organic matter from the profundal area of the Eocene Lake Prinz von Hessen, which formed in a pull-apart basin on the Sprendlinger Horst, near Darmstadt, Germany. Variations in total sulphur content (S tot) and total organic carbon content (TOC), hydrogen index (HI), oxygen index (OI) and ¹³C values of the organic matter were used to reconstruct the lakes filling history. Following an initial rapid deepening phase, open lake conditions developed with HI reaching more than 500 mg HC/g TOC and TOC values up to 40%. The productivity of the lake was probably high and organic matter preservation was enhanced by a stratified water column. As the lake began to fill with sediment and became shallower, TOC and HI values declined, as the lake water was better oxygenated and preservation conditions declined. ¹³C values between –31 and –27 are controlled by the mixing of aquatic (algae and microbial mats) and terrigenous organic matter (wood, spores, pollen and cuticles). Following a rapid drop in lake level, shallow lake conditions alternated with swamp deposits (lignites) in the basin center. The organic matter preserved during this stage is strictly terrigenous in nature and experienced oxic degradation (HI 100 mg HC/g TOC). ¹³C values between –26 and –24 are typical for Eocene terrigenous matter. The inferred lake level fluctuations are interpreted to have been controlled by tectonic as well as climatic processes.     

Relationship of Mn-carbonates in varved lake-sediments to catchment vegetation in Big Watab Lake, MN, USA

Mn-carbonates are documented in the late-glacial varved sediments from Big Watab Lake, Minnesota, USA. The Mn-carbonate is authigenic and forms rims around contemporaneous epilimnetic calcite. Although such carbonates are found in minor amounts throughout the entire late-glacial sequence, significant quantities of Mn-carbonate are associated mainly with laminated intervals.Because of the suspected difference in isotopic fractionation between different carbonate minerals, the stable-isotopic compositions of bulk carbonate samples are used as a proxy for relative amounts of the Mn-carbonate in the sediment. High ¹⁸O and low ¹³C values are associated with abundant Mn-carbonates. Low ¹⁸O and high ¹³C values are associated with only minor concentrations of Mn-carbonates.The oxygen-18 record is correlated with fluctuations in the vegetation assemblage based on pollen spectra using a multiple regression model with backward elimination. The proposed link between the sedimentary archive and local vegetation is the mediation of advective mixing in the lake by forest composition. In this model, periods of forest closure resulted in a well-stratified water column that was anoxic at the sediment/water interface, permitting the formation of authigenic Mn-carbonates. Openings of Artemisia in the forest allowed wind shear to mix oxygen to depth, causing bioturbation of the laminations and preventing the formation of Mn-carbonate.     

Paleolimnology of McNearney lake: an acidic lake in northern Michigan

McNearney Lake is an acidic (pH=4.4) lake in the Upper Peninsula of Michigan with low acid neutralizing capacity (ANC=-38 eq L^-1) and high SO _inf4 ^sup2- and aluminium concentrations. Oligotrophy is indicated by high Secchi transparency and by low chlorophyll a, total phosphorus, and total nitrogen concentrations. The lake water is currently acidic because base cations are supplied to the lake water at a low rate and because SO _inf4 ^sup2- from atmospheric deposition was not appreciably retained by the lake sediments or watershed and was present in the water column.This interdisciplinary paleolimnological study indicates that McNearney Lake is naturally acidic and has been so since at least 4000 years B.P., as determined from inferred-pH techniques based on contemporary diatom-pH relationships. Predicted pH values ranged from 4.7 to 5.0 over the 4000-year stratigraphy. Considerable shifts in species composition and abundance were observed in diatom stratigraphy, but present-day distributions indicate that all abundant taxa most frequently occur under acidic conditions, suggesting that factors other than pH are responsible for the shifts. The diatom-inferred pH technique as applied to McNearney Lake has too large an uncertainly and is not sensitive enough to determine the subtle recent changes in lakewater pH expected from changes in atmospheric deposition because: (1) McNearney Lake has the lowest pH in the contemporary diatom data set in the region and confidence intervals for pH predictions increase at the extremes of regressions; (2) other factors in addition to pH may be responsible for the diatom species distribution in the lake and in the entire northern Great Lakes region; (3) McNearney Lake has a well-buffered pH as a consequence of its low pH and high aluminium concentrations and is not expected to exhibit a large pH change as a result of changes in atmospheric deposition; and (4) atmospheric deposition in the region is modest and would not cause a pH shift large enough to be discernable in McNearney Lake.Elevated atmospheric deposition is indicated in recent sediments by Pb, V, and polycyclic aromatic hydrocarbon accumulation rates and to a lesser extent by those of Cu and Zn; however, these accumulation rates are substantially lower than those observed for acidified lakes in the northeastern United States. Although atmospheric loadings of materials associated with fossil fuel combustion have recently increased to McNearney Lake and apparently are continuing, the present study of the diatom subfossil record does not indicate a distinct, recent acidification (pH decrease).Order of the first two authors is alphabetical     

Paleolimnological investigations of anthropogenic environmental change in Lake Tanganyika: VII. Carbonate isotope geochemistry as a record of riverine runoff

Evaporation dominates the removal of water from Lake Tanganyika, and therefore the oxygen isotope composition of lake water has become very positive in comparison to the waters entering the lake. The surface water in Lake Tanganyika has remained relatively unchanged over the last 30 years with a seasonal range of +3.2 to +3.5 VSMOW. Water from small rivers entering the lake seems to have a ¹⁸O value between –3.5 and –4.0, based on scattered measurements. The two largest catchments emptying into the lake deliver water that has a ¹⁸O value between these two extremes. This large contrast is the basis of a model presented here that attempts to reconstruct the history of runoff intensity based on the ¹⁸O of carbonate shells from Lake Tanganyika cores. In order to use biogenic carbonates to monitor changes in the ¹⁸O of mixing-zone water, however, the oxygen isotope fractionation between water and shell carbonate must be well understood. The relatively invariant environmental conditions of the lake allow us to constrain the fractionation of both oxygen and carbon isotope ratios. Although molluskan aragonitic shell ¹⁸O values are in agreement with published mineral-water fractionations, ostracode calcite is 1.2 more positive than that of inorganic calcite precipitated under similar conditions. Ostracode shell ¹⁸O data from two cores from central Lake Tanganyika suggest that runoff decreased in the first half of this millennium and has increased in the last century. This conclusion is poorly constrained, however, and much more work needs to be done on stable isotope variation in both the waters and carbonates of Lake Tanganyika. We also compared the ¹³C of shells against predicted values based solely on the ¹³C of lake water dissolved inorganic carbon (DIC). The ostracode Mecynocypria opaca is the only ostracode or mollusk that falls within the predicted range. This suggests that M. opaca has potential for reconstructing the carbon isotope ratio of DIC in Lake Tanganyika, and may be a useful tool in the study of the history of the lakes productivity and carbon cycle.     

Diatom,pollen, and geochemical evidence for the palaeosalinity of Medicine Lake,S. Dakota,during the late-Wisconsin and early Holocene

Medicine Lake is a highly saline meromictic lake in eastern South Dakota. A lithostratigraphic and biostratigraphic study of the late-glacial and early post-glacial sediments shows that it was a relatively deep dilute freshwater lake during the period of the Picea pollen zone. When spruce forest changed to a Betula and then to a Quercus/Ulmus woodland in the early post-glacial period, the lake water became more concentrated but remained fresh. However, during the subsequent rapid transition to prairie in the early Holocene, when Gramineae, Ambrosia, and Artemisia dominated dry-land vegetation, the freshwater diatom flora was progressively replaced by a saline assemblage characterized by Cyclotella quillensis, Chaetoceros, and eventually Cyclotella caspia. The lake became permanently saline at about 9000 yr BP. A comparison of the fossil diatom assemblages with surface-sediment samples from a range of lakes in the Dakotas indicates that the change involved an increase in conductivity from about 500 S cm^–1 in the late-glacial period to > 10 000 S cm^–1 in the early Holocene. This rapid change is also marked by an abrupt increase in sulphate concentration in the sediment, the first appearance of bands of gypsum crystals, and the beginning of a well-laminated core sequence that continues through the remaining sediment record. Conditions of high salinity have prevailed to the present day.Contribution 299, Limnological Research Center.     

The Late Pleistocene - Holocene palaeolimnology of Lake Victoria, East Africa, based upon elemental and isotopic analyses of sedimentary organic matter

Three piston cores from Lake Victoria (East Africa) have been analysed for organic carbon (TOC) and nitrogen (TN) content, stable isotopes (¹³C and ¹⁵N), and Hydrogen Index (HI). These data are combined with published biogenic silica and water content analyses to produce a detailed palaeolimnological history of the lake over the past ca. 17.5 ka. Late Pleistocene desiccation produced a lake-wide discontinuity marked by a vertisol. Sediments below the discontinuity are characterised by relatively low TOC and HI values, and high C/N, ¹³C and ¹⁵N, reflecting the combined influence of abundant terrestrial plant material and generally unfavourable conditions for organic matter preservation. A thin muddy interval with lower ¹³C and higher HI and water content indicates that dry conditions were interrupted by a humid period of a few hundred years duration when the lake was at least 35 m deep. The climate changed to significantly more humid conditions around 15.2 ka when the dry lake floor was rapidly flooded. Abundant macrophytic plant debris and high TOC and ¹³C values at the upper vertisol surface probably reflect a marginal swamp. ¹³C values decrease abruptly and HI begins to increase around 15 ka BP, marking a shift to deeper-water conditions and algal-dominated lake production. C/N values are relatively low during this period, suggesting a generally adequate supply of nitrogen, but increasing ¹⁵N values reflect intense utilisation of the lake's DIN reservoir, probably due to a dramatic rise in productivity as nutrients were released to the lake from the flooded land surface.An abrupt drop in ¹³C and ¹⁵N values around 13.8-13.6 ka reflects a period of deep mixing. Productivity increased due to more efficient nutrient recycling, and ¹³C values fell as ¹²C-rich CO₂ released by bacterial decomposition of the organic material was brought into the epilimnion. A weak drop in HI values suggests greater oxygen supply to the hypolimnion at this time. Better mixing was probably due to increased wind intensity and may mark the onset of the Younger Dryas in the region.After the period of deep mixing, the water column became more stable. TOC, C/N, ¹³C and HI values were at a maximum during the period between 10 and 4 ka, when the lake probably had a stratified water column with anoxic bottom waters. A gradual decrease in values over the last 4000 yrs suggest a change to a more seasonal climate, with periodic mixing of the water column. Rising sediment accumulation rates and a trend to more uniform surface water conditions over the last 2000 yrs are probably a result of increased anthropogenic impact on the lake and its catchment.Following a maximum at the time of the rapid lake-level rise during the terminal Pleistocene, ¹⁵N has remained relatively low and displays a gradual but consistent trend to lower values from the end of the Pleistocene to the present. TN values have risen during the same period. The lack of correlation between ¹³C and ¹⁵N, and the absence of any evidence for isotopic reservoir effects despite the rise in TN, suggests that the atmosphere, rather than the lake's dissolved nitrogen pool has been the principal source of nitrogen throughout the Holocene. The importance of atmospheric N fixation to Lake Victoria's nitrogen cycle thus predates by a very considerable margin any possible anthropogenic eutrophication of the lake.     

Historical loading record of sulfur in an Adirondack Lake

A model for the distribution of sulfur in the sediments of a lake in the Adirondack Mountains, New York, is developed to gain insight into the timing and magnitude of anthropogenic increases in sulfur loading. Surficial sulfur concentrations are about 3500 µg g^–1, increase to 6000–7000 µg g^–1 at a depth of about 6 cm, and then decrease downcore to background levels of about 2500 µg g^–1. Sulfate concentrations are about 60–80 µM in the overlying water and decrease rapidly below the sediment-water interface. This reflects assimilatory reduction and/or dissimilatory reduction of sulfate and incorporation into the inorganic and/or organic solid-phase fractions of the sediment. A mathematical model is constructed assuming sulfur is incorporated into sediments by burial of detrital organic matter and by diffusion of sulfate from the overlying water with subsequent fixation in the sediment. Several historical scenarios of atmospheric sulfate loading rates were examined as model boundary conditions. Model results are compared with observed sedimentary sulfur profiles. The observed sediment sulfur profiles are best described using model boundary conditions showing increases in lake water sulfate concentrations since about 1940. Assuming as much as a decade of retention of sulfate within the terrestrial portion of the ecosystem, this suggests that significant increases in sulfate deposition rates began sometime after 1930 in this relatively remote area.     

Late holocene paleoclimatic and paleobiologic records from sediments of Devils Lake,North Dakota

An 84 cm sediment core collected from the center of Devils Lake, North Dakota, was analyzed at 1-cm intervals for,²¹⁰Pb,¹³⁷Cs, sediment conductivity, the concentrations of, biogenic silica, total organic carbon, carbon to nitrogen ratio, and the carbon and nitrogen isotopic composition of the organic fraction. Variations in²¹⁰Pb activities in the upper 20 centimeters indicate that sediment accumulations rates in Devils Lake are not constant, and that accumulation rates were highest during periods of high lake level. The mean sedimentation accumulation rate was calculated as 0.24 cm^–1 yr. The¹³⁷Cs profile is characterized by near-surface maximum concentrations, possibly the result of redistribution of¹³⁷Cs during salinity excursions.Biogenic silica is strongly correlated to lake level in Devils Lake. Periods of low lake level (characterized by high sediment conductivity) correspond to low biogenic silica concentrations. The trends in biogenic silica are attributed to variations in diatom productivity in the lake and to variations in sediment accumulation rates. Based on biogenic silica content and the composition of organic matter in the sediment (total organic carbon, carbon:nitrogen ratio and the ¹³C and ¹⁵N composition of total organic matter), paleobiologic conditions of Devils Lake during low lake stands were characterized by, (1) decreased primary productivity, (2) decreased input of detrital organic matter, and (3) increased nitrogen availability.During the 350 years of sediment accumulation represented by the 84-cm sediment core Devils Lake has experienced two periods of sustained high lake level; one between about 130 and 170 years ago (1820 to 1860 A.D.) and the second between 270 and 310 years ago (1680 to 1720 A.D.). Devils Lake experienced a period of intense drying about 260 years ago (1720 A.D.).     

A 6000 year water level history of Europe Lake, Wisconsin, USA

Europe Lake occupies a small, closed, basin that would have been an embayment in Lake Michigan during the high water level events in the larger lake. Cores recovered from the lake reveal late Holocene water level fluctuations in the basin that are inferred from changes in taxa and abundance of molluscs, ostracodes, magnetic susceptibility, organic carbon, and oxygen isotopes.Non-glacial, Holocene lacustrine/paludal sedimentation in this portion of the Europe Lake basin started after 6600 RCYBP and was probably initiated by a rise in the water table of the deep bedrock aquifer, during the Nipissing transgression in Lake Michigan. Isotopically light ground water from this source was probably a major contributor during this phase to the negative ¹⁸O spikes in Valvata tricarinata and Amnicola limosa.The start of stable lacustrine conditions is marked by maximum diversity of ostracode and mollusc taxa and a shift toward much more positive ¹⁸O values. The Europe Lake basin at this time became an embayment of Lake Michigan. This event was probably coeval with the peak of the Nipissing transgression, when the water plane reached an altitude of about 183 m.The isolation of Europe Lake from Lake Michigan started at about 2390 RCYBP and is probably due to a drop in water level in Lake Michigan and/or to isostatic uplift of the Door Peninsula. Since isolation from Lake Michigan, water levels in Europe lake have been controlled primarily by fluctuations in local precipitation, evaporation and ground water discharge.     

Importance of diffuse nutrient loading and lake level changes to the eutrophication of an originally oligotrophic boreal lake: a palaeolimnological diatom and chironomid analysis

The recent environmental history of Lake Lappajärvi in western Finland (63°00 N, 23°30 E, area 149 km²), a humic, brown water lake with an average phosphorus content of ca. 20 g l^–1, was studied from short core sediment samples taken from the two main basins of the lake. Based on the stratigraphy of diatoms and chironomids and the sediment quality it was possible to distinguish four developmental stages during the past century: (1) a pre-industrial stage covering the time up to about 1935; (2) a stage of increasing nutrient loading (ca. 1936–1960); (3) a stage of pronounced erosion from lake level regulation and extensive ditching of the catchment area (ca. 1960–1970); and (4) a meso-eutrophic stage from ca. 1970 onwards.Acidophilous Aulacoseira distans coll. and other species typical of dystrophic, nutrient-poor lakes characterized the diatom assemblages during the first stage, and the profundal zoobenthic assemblages, characterized by Heterotrissocladius subpilosus and Micropsectra, indicated good hypolimnetic oxygen conditions and a low sedimentation of organic matter (approx. less than 50 g m^–2 a^–1). The increased loading rapidly led to changes both in diatoms and chironomids (e.g., to an early extinction of H. subpilosus in the 1950s). The process finally led to eutrophication with a successive proliferation of diatom species such as Asterionella formosa followed by Aulacoseira ambigua, Fragilaria crotonensis, and finally Melosira varians. The relative proportion of alkaliphilous species reached a maximum in the final stage and the original profundal chironomid fauna was replaced by Chironomus anthracinus gr. and C. plumosus which are typical of profundal areas suffering from temporal oxygen deficit. It is notable that the considerable decrease in waste water loading from the point sources (80–86% ) during the past two decades has not led to a recovery in the lake. This highlights the importance of diffuse loading from agriculture, forestry and other human activities even to this comparatively large lake.     

Lacustrine ostracodes as stable isotope recorders of late-glacial and Holocene environmental dynamics and climate

Oxygen- and carbon-isotopic signatures of benthic ostracodes from lake sediments from climate sensitive regions in the Alpine region, Central Europe, the north-central USA, the Chilean Altiplano and Patagonia, Argentina, are used to characterize lake system processes and to reconstruct climate patterns of the past 16,000 years. The case studies provide examples that highlight different aspects of the broad application of isotope stratigraphies, and provide keys for the interpretation of complex lacustrine records.The integration of stable-isotope stratigraphy, sedimentology, and ecological information from ostracode assemblages is a new tool that acquires climate information from the indirect views of climate series provided by lake sediments. This tool (1) identifies lake system characteristics, (2) confines which isotopic signatures are controlled by which processes in the lake system and/or in the catchment, and (3) defines which signatures are ultimately controlled by climate change. If sudden shifts in the isotopic composition occur concomitantly with changes between sedimentological units, then the isotopes reflect first of all changes in catchment hydrology that may be ultimately controlled by climate. Also, if ostracode ¹⁸O and ¹³C values show the same timing and direction of shifts, then this indicates a major change in the hydrological budget of the lake.The case studies presented here show that coupled isotopic signatures may be used to track hydrological changes related to meltwater and deglaciation, shifting rivers and ground water sources, and changes in precipitation mechanisms and patterns. Values of ¹⁸O from large lakes with short water residence time, low evaporation rates and homothermic bottom waters provide records of past temperatures of precipitation. The ¹³C values reflect changes in the ratio of C₃:C₄ plants in the catchment. They indicate shifts in modes of organic decay in the surface sediments that can be linked to a change in hydrodynamics within a lake. The ¹³C values also allow detection of the input of volcanically charged ground waters providing large quantities of ¹⁴C-free CO₂ that hinders accurate ¹⁴C chronology. General climate trends for the sites in the Americas indicate a dry mid-Holocene punctuated by moist spells, and show a general increase in moisture during the past approximately 4000 years, interrupted by recurring droughts. This hints at an interhemispheric connection and a common driving mechanism.Environmental isotopes from high-resolution lake sediments thus provide an ideal tool to identify and characterize the regional impact and magnitude of global climate change. This tool contributes to a better understanding of regional climate change and its driving mechanisms and thus provides the type of information needed to improve climate models. Environmental isotopes provide more information than just moisture balance and airmass history if they are integrated with the detailed sedimentological and ostracode ecological evidence, and understanding for the component system. Thus environmental isotopes serve to a better understanding of the climate signal archived in lake records and represent an essential contribution to Global Change research and Earth System Science.     

Late Holocene lake level dynamics inferred from magnetic susceptibility and stable oxygen isotope data: Lake Elsinore, southern California (USA)

Southern California faces an imminent freshwater shortage. To better assess the future impact of this water crisis, it is essential that we develop continental archives of past hydrological variability. Using four sediment cores from Lake Elsinore in Southern California, we reconstruct late Holocene (3800 calendar years B.P.) hydrological change using a twentieth-century calibrated, proxy methodology. We compared magnetic susceptibility from Lake Elsinore deep basin sediments, lake level from Lake Elsinore, and regional winter precipitation data over the twentieth century to calibrate the late Holocene lake sediment record. The comparison revealed a strong positive, first-order relationship between the three variables. As a working hypothesis, we suggest that periods of greater precipitation produce higher lake levels. Greater precipitation also increases the supply of detritus (i.e., magnetic-rich minerals) from the lake's surrounding drainage basin into the lake environment. As a result, magnetic susceptibility values increase during periods of high lake level. We apply this modern calibration to late Holocene sediments from the lake's littoral zone. As an independent verification of this hypothesis, we analyzed ¹⁸O_(calcite), interpreted as a proxy for variations in the precipitation:evaporation ratio, which reflect first order hydrological variability. The results of this verification support our hypothesis that magnetic susceptibility records regional hydrological change as related to precipitation and lake level. Using both proxy data, we analyzed the past 3800 calendar years of hydrological variability. Our analyses indicate a long period of dry, less variable climate between 3800 and 2000 calendar years B.P. followed by a wet, more variable climate to the present. These results suggest that droughts of greater magnitude and duration than those observed in the modern record have occurred in the recent geological past. This conclusion presents insight to the potential impact of future droughts on the over-populated, water-poor region of Southern California.     

Stratigraphy of the mid-Holocene black bands in Lakes Michigan and Huron: Evidence for possible basin-wide anoxia

The post-glacial history of the Great Lakes has involved several changes in lake levels throughout the latest Pleistocene and Holocene, resulting from the changing position of the retreating Laurentide ice sheet, outlet incision and isostatic rebound. The final lowering of lake levels occurred at approximately 7600 ¹⁴C yr BP, after which lake levels began to rise again to the Nipissing highstand at approximately 4700 ¹⁴C yr BP. During this time of rising lake levels, black bands of iron sulfide were being formed in the sediments of all five of the Great Lakes. These bands signify suboxic to anoxic conditions, at least within the sediments and possibly at the sediment-water interface, during the middle Holocene warm interval. During this interval, the climate was warmer and drier than present, possibly resulting in the occasional absence of seasonal turnover in the lakes. We examined a series of piston cores from northern Lakes Michigan and Huron and found that the black bands are correlatable among cores taken from within the same basin. The observation that the banding can be correlated suggests a basin-wide cause, near-bottom or sub-bottom anoxia in the northern Michigan and northern Huron sediments during the mid-Holocene warm period. The sedimentary and geochemical processes in the Great Lakes during the middle Holocene warm interval are good indicators of possible future scenarios for the lakes as a result of global warming, as 21^st-century temperatures are predicted to reach similar levels due to increased concentrations of greenhouse gases.     

Holocene records of carbon and hydrogen isotope ratios of organic matter in annually laminated sediments of Lake Korttajärvi, central Finland

An 11.6 m long continuous succession of annually laminated sediments from Lake Korttajärvi in central Finland was investigated for the isotopic composition of carbon and hydrogen in organic matter. The sequence covers a time period of 9590 years, and the varve chronology has been thoroughly described in earlier studies. From 7100 to 4400 BC the lake was part of the Ancient Lake Päijänne, but in 4400 BC it became separated and formed the present independent lake system. Two organic fractions were investigated. One fraction obtained by HCl-treatment was analyzed for δ¹³C and another HCl-HF-digested organic fraction was analyzed for both δ¹³C and δD. The isotopic data were compared to atomic C/N ratios, carbon contents, diatom-inferred pH values and other environmental parameters. The diatom-inferred pH values and organic carbon contents provide evidence for a long-term change towards more acidic conditions and lower productivity in Lake Korttajärvi. The inferred pH values decrease from 7.0 to 6.1, followed by a slight increase during the last millennia. Variations in pH are accompanied by an increase in the δ¹³C_HCl-HF values of organic matter from ?31.6 to $-29.2\permilleAn 11.6 m long continuous succession of annually laminated sediments from Lake Korttaj?rvi in central Finland was investigated for the isotopic composition of carbon and hydrogen in organic matter. The sequence covers a time period of 9590 years, and the varve chronology has been thoroughly described in earlier studies. From 7100 to 4400 BC the lake was part of the Ancient Lake P?ij?nne, but in 4400 BC it became separated and formed the present independent lake system. Two organic fractions were investigated. One fraction obtained by HCl-treatment was analyzed for δ¹³C and another HCl-HF-digested organic fraction was analyzed for both δ¹³C and δD. The isotopic data were compared to atomic C/N ratios, carbon contents, diatom-inferred pH values and other environmental parameters. The diatom-inferred pH values and organic carbon contents provide evidence for a long-term change towards more acidic conditions and lower productivity in Lake Korttaj?rvi. The inferred pH values decrease from 7.0 to 6.1, followed by a slight increase during the last millennia. Variations in pH are accompanied by an increase in the δ¹³C_HCl-HF values of organic matter from −31.6 to , followed by a subtle decrease to . The changes in pH and δ¹³C_HCl-HF are closely related (r = − 0.91, P < 0.01), and apparently reflect changing environmental conditions in the lake and in its catchment area. δD values show a marked shift to higher values during the early Holocene, which may be partly related to a climatic amelioration leading to the Holocene Climatic Optimum in 6000–2500 BC. The Medieval Warm Period in AD 980–1250 is associated with a local maximum in δD, lending support for a significant warming during that time.     

Multi-component carbon isotope evidence of early Holocene environmental change and carbon-flow pathways from a hard-water lake in northern Sweden

A 9000-year carbonate-rich sediment sequence from a small hard-water lake in northernmost Sweden was studied by means of multi-component stable carbon isotope analysis. Radiocarbon dating of different sediment fractions provides chronologic control and reveals a rather constant hard-water effect through time, suggesting that the lake has remained hydrologically open throughout the Holocene. Successive depletion of ¹³C in fine-grained calcite and carbonate shells during the early Holocene correlate with a change in catchment vegetation from pioneer herb communities to boreal forest. The vegetational change and associated soil development likely gave rise to an increased supply of ¹³C-depleted carbon dioxide in groundwater recharging the lake. This process is therefore believed to be the main cause of decreasing values of ¹³C in dissolved inorganic carbon of the lake and thereby in limnic carbonates. Strongly ¹³C-depleted sedimentary organic matter may be related to enhanced kinetic fractionation during photosynthetic assimilation by means of proton pumping in Characean algae. This interpretation is supported by a substantial offset between ¹³C of DIC as recorded by mollusc shells and ¹³C of fine-grained calcite.     

Holocene climate reconstructions from tandem trace-element and stable-isotope composition of ostracodes from Coldwater Lake, North Dakota, U.S.A.

The geochemistry of ostracode shells and bulk carbonates in a 19-meter sediment core documents at century-scale resolution the evolution of water chemistry in Coldwater Lake, North Dakota, providing a continuous paleohydrologic record of Holocene climate change in the northern Great Plains. A combination of ¹⁸O, ¹³C, Mg/Ca and Sr/Ca in ostracode calcite aided by Sr/Ca in bulk carbonates are used to constrain the paleoclimatic reconstructions. A fresh-water phase in the early Holocene, indicated by the absence of Candona rawsoni and low concentrations of Sr/Ca in bulk carbonate, was followed by a sharp increase in salinity between 10800 and 8900 yr B.P. The climate was predominately dry during the late part of the early Holocene and most of the middle Holocene (8900–5000 yr B.P.), when the lake was very sensitive and recorded a series of dry and wet oscillations. Maximum salinity occurred around 5500 yr B.P. and was followed by a gradual decrease between 5000 and 2400 yr B.P. From 2400 yr B.P. the ¹⁸O, Mg/Ca, and Sr/Ca in the ostracodes indicate generally wet conditions interrupted by a series of lesser salinity and temperature oscillations lasting until 600 yr B.P. Ostracode geochemistry indicates that a warm and dry climate returned at about the time of the Little Ice Age (600–150 yr B.P.). Ostracode ¹³C shows a ong-term increasing trend during the Holocene, which suggests that lake productivity and atmospheric CO₂ exchange made greater contributions to the hypolimnetic carbon pool as the lake became shallower with time.     

Rapid Holocene hydrologic change along boreal treeline revealed by δ13C and δ18O in organic lake sediments, Northwest Territories, Canada

Analysis of ¹⁸O_cellulose, ¹³C_{organic matter}, and ¹³C_cellulose at about 100 year intervals from organic matter deposited in Toronto Lake, Northwest Territories, Canada, revealed an 8000-year history of rapid, post-glacial hydrologic change at the treeline zone. Several mid-Holocene phases of enriched ¹³C_org and ¹³C_cell, caused by elevated lake productivity, declining [CO_2(aq)], and closed basin conditions, were abruptly terminated by intervals of open hydrology recorded by sharply depleted ¹⁸O_cell. Two of these events, at 5000 and 4500 BP, are correlated with increased total organic content and Picea mariana pollen concentration, which indicate that high levels of productivity were also accompanied by northern treeline advances. A third treeline advance at about 2500 BP is also marked by an apparent outflow event from Toronto Lake, but this was not associated with ¹³C_org/cell enrichment in the sediment record because rapid and substantial lake water renewal probably prevented productivity-driven enrichment of the dissolved inorganic carbon and replenished the CO_2(aq) supply to thriving phytoplankton. However, high sediment organic content during this period suggests increased productivity. Increases in the inflow:evaporation ratio at about 6500 and 3500 BP were also sufficient to cause Toronto Lake to overflow but the prevailing climate during these periods apparently did not favour appreciable northward treeline migration or changes in lake productivity.This is the 14th in a series of papers published in this special AMQUA issue. These papers were presented at the 1994 meeting of the American Quaternary Association held 19–22 June, 1994, at the University of Minnesota, Minneapolis, Minnesota, USA. Dr Linda C. K. Shane served as guest editor for these papers