湘南骑田岭岩体菜岭超单元花岗岩侵位年龄和物质来源研究

湘南骑田岭岩体菜岭超单元花岗岩以角闪石黑云母二长花岗岩为主,其全岩Rb-Sr等时线年龄为159±1.2Ma,单颗粒锆石熔融法U-Pb年龄为161±2Ma,Sr同位素初始比值偏低(0.70854),Nd同位素初始比值偏高(-5.4～-5.8),Nd模式年龄偏低(0.94～1.49Ga)。在岩石化学和微量元素方面,属钙碱系列,准铝,富含K、Rb等大离子亲石元素和Th、REE、Nb等高场强元素。常见较多具有岩浆混合特征的微花岗岩类暗色包体。这些同位素、岩石学和微量元素特征,总体上反映了菜岭超单元花岗岩的成岩组成中有明显的地幔物质的参与。该花岗岩可能是在燕山早期华南地壳开始拉张减薄的构造背景下定位的,壳幔相互作用对本区大陆地壳物质的重熔和花岗岩浆的形成和演化起了重要的作用。     

豫西南地区北秦岭地体新元古代花岗岩类岩石成因及其地质意义

北秦岭地体中新元古代花岗岩类岩石是秦岭造山带的重要组成部分,记录了造山带基底前寒武纪地壳形成和演化历史。本文报道方庄和德河花岗岩岩体的锆石U-Pb年龄和O同位素组成、全岩元素和Sr-Nd同位素地球化学组成,探讨其岩石成因和地壳演化意义。结果表明,方庄花岗质糜棱岩的锆石结晶年龄为933.4±9.2Ma,δ18O值8.3‰～11.9‰,初始87Sr/86Sr比值0.72455,初始εNd值-6.0,Nd模式年龄2.09Ga(tDM2);德河黑云斜长片麻岩的锆石结晶年龄为948.1±8.9Ma,初始87Sr/86Sr比值变化较大,初始εNd值-5.0,Nd模式年龄2.02Ga。结合已报道的新元古代花岗岩类岩体的年龄和地球化学数据,北秦岭地体新元古代岩浆作用可以划分为980～870Ma挤压碰撞作用和～844Ma伸展裂解作用两大阶段,包括～940Ma强烈变形S型同碰撞花岗岩、～880Ma弱-无变形后碰撞I型花岗岩和～844Ma板内A型碱性岩三类花岗岩体。地球化学组成显示,这些花岗岩类岩石可能源自不同时期形成的秦岭群基底杂岩的部分熔融,但在后碰撞阶段幔源物质或年轻地壳物质的加入明显增加。北秦岭地体中新元古代岩浆活动与Rodinia超大陆演化基本同时代,可能记录超大陆形成过程中的地壳响应。在新元古代之前,北秦岭地体或许具有不同于华北陆块和华南陆块的演化历史。     

海南岛中北部三叠纪花岗岩源区的锶、钕同位素制约及其意义

海南岛中北部三叠纪花岗岩的锶、钕同位素初始比值分别为I(Sr)0. 7080 ~0. 71505、εNd(t) -10 ~-5,表明这些花岗岩属壳源型,其源岩主要为海南岛结晶基底中元古界抱板群,但受到了幔源岩浆的混染。这些花岗岩所表现出来的基本一致的锶、钕同位素特征,表明测区具有统一的前寒武纪基底。     

山西古元古代关帝山花岗岩杂岩的成因:地球化学和Nd同位素证据

关帝山花岗杂岩包括惠家庄岩体、市庄岩体和横坚岩体等诸多不同规模的花岗岩体,它们形成于1906Ma到1848Ma,主要由早期的片麻状花岗闪长岩、二长花岗岩,晚期的块状浅色二长花岗岩组成。地球化学和Nd同位素特征证明它们形成于复杂的砂页岩和粘土岩等表壳岩的部分熔融,部分熔融的残留相主要为石榴子石、辉石、角闪石、斜长石和一些副矿物,岩浆演化经历了云母、长石等矿物的结晶分异。这些花岗岩的源区物质与大陆边缘弧有亲缘关系,岩浆形成与演化发生在同碰撞到造山后的构造背景,可能与华北克拉通中部构造带东部陆块和西部陆块拼合的地质过程有关。山西古元古代关帝山花岗岩杂岩的成因:地球化学和Nd同位素证据@刘超辉$北京大学造山带与地壳演化教育部重点实验室,北京大学地球与空间科学学院!100871 @刘树文$北京大学造山带与地壳演化教育部重点实验室,北京大学地球与空间科学学院!100871     

大兴安岭中部乌兰浩特地区中生代花岗岩的成因——地球化学及Sr-Nd-Hf同位素制约

大兴安岭中部中生代花岗岩成因和构造背景的确定对讨论该地区及东北地区中生代构造-岩浆演化具有重要意义。乌兰浩特地区中生代花岗岩详细的岩石地球化学及Hf、Nd同位素的研究表明:研究区中晚三叠世查干岩体是A2型花岗岩;早中侏罗世景阳岩体为I型花岗岩,而大石寨岩体是具有特殊稀土元素四分组效应的花岗岩;早白垩世花岗岩体可根据其Sr含量划分为高Sr和低Sr两类,它们具有相同或相似的源岩组成,但其起源深度不同。其中高Sr型花岗岩类似于C型埃达克质花岗岩,起源于压力较高的下地壳,而低Sr型及永和屯花岗岩则是起源于压力较低的中地壳的高分异Ⅰ型花岗岩。全岩Nd和锆石Hf同位素特征及前人的研究结果显示,乌兰浩特地区花岗岩类岩石的源区主要为显生宙新增生的年轻地壳物质,并有老的地壳物质的贡献,并且随着花岗岩侵位时间的逐渐变新,锆石的εHf(t)值逐渐减小,认为地幔上涌导致岩浆底侵以及老地壳物质的折返是造成下地壳源岩组成复杂的原因。     

闽西北加里东期混合岩及花岗岩的成因:同变形地壳深熔作用

本文选取闽西北前寒武纪变质基底中的混合岩和花岗岩为研究对象,以探讨两者之间的成因联系.详细的岩石学和主量、微量元素地球化学以及锆石U-Pb年代学研究表明,闽西北混合岩是同变形地壳深熔作用的产物,基底变质岩中的黑云母在较低温(约800℃)、H2O不饱和的条件下发生脱水熔融反应产生熔体,构造变形作用在熔体的分离和迁移过程中起到了重要作用.闽西北基底变质岩可能为形成混合岩和花岗岩的源岩,其深熔产生的初始熔体发生结晶分异作用,堆晶产物形成了混合岩的浅色体,而残余熔体继续演化形成花岗岩.混合岩和相关花岗岩形成基本同时,其成岩年龄为437～441Ma.它们均为华南加里东期构造热事件的产物.     

粤北下庄铀矿田脉石矿物Sr、Nd、Pb同位素地球化学研究

下庄铀矿田为中国南岭地区重要的铀矿基地,矿区内分布有规模大小不等的数个铀矿床。为解决近年来争议较多的该区铀矿床矿质和流体来源问题,本次对下庄矿田铀矿床中的脉石矿物开展了系统的Sr、Nd、Pb同位素地球化学研究。结果表明,本区与成矿有关的碳酸盐矿物富集放射性成因铅,矿床中的Pb和U主要源于帽峰式花岗岩。Sr、Nd同位素组成显示成矿流体主要为壳源,南部矿区部分矿床的成矿流体在上升及矿质沉淀过程中与基性脉岩发生水-岩反应而使其形成的脉石矿物的Sr、Nd同位素组成具有壳幔两端元混合的特征。     

青藏高原中新生代花岗岩Sr、Nd同位素研究

青藏高原中新生代岩浆活动强烈，本文报道青藏高原西部中新生代代表性花岗岩的Sr，Nd同位素测定结果，结合前人已发表的东部地区花岗岩同位素资料，初步探讨了青藏高原地区中新生代花岗岩的Sr，Nd同位素组成、物质来源与成因。研究表明，分布于冈底斯地块北南边界(即冈底斯花岗岩北带和南带)与洋壳俯冲有关的燕山晚期花岗岩，具有低^87Sr／^86Sr初始值(小于0．706)、正εNd(t)值和年轻的t2DM模式年龄的特征，岩浆来源于俯冲洋壳的熔融；与陆-陆碰撞及碰撞后有关的冈底斯花岗岩^87Sr／^86Sr初始值变化大(0．706～0719)，而εNd(t)值和t2DM都在很小范围变化，Sr、Nd同位素组成似乎与时代、岩性无关，说明壳幔混合花岗岩的同位素源区长时期保持相对均一。无洋壳物质参与的通过陆内俯冲作用形成的喜马拉雅区花岗岩，具有高^87Sr/^86Sr初始值(大于0.720)、古老模式t2DM年龄(1792～2206Ma)和低εNd(t)值(-10．3～-16．3)特征，并与基底岩石的Sr，Nd组成一致，岩浆源区为壳源。由此说明花岗岩类及其岩石组合的形成主要取决于深部部分熔融物质的成分，不同火成岩组合的差异反映了青藏高原岩石圈组成和演化的不均一性。     

青藏高原东南木里地区二叠纪苦橄岩的Os-Sr-Nd同位素地球化学研究

本文报道了在青藏高原东南木里地区发现的二叠纪苦橄岩和与其共生玄武岩的主微量元素地球化学特征以及Os-Sr-Nd同位素组成。苦橄岩和与其共生玄武岩受地壳混染作用影响较小。根据苦橄岩的Ti/Y比值和初始的Os同位素组成,将木里苦橄岩分为两类:高Ti/Y型苦橄岩和低Ti/Y型苦橄岩,其中高Ti/Y型苦橄岩具有高的γ_(Os)= 5.3～ 10.7和ε_(Nd)= 5.9～ 6.4,与全球典型洋岛玄武岩的Os和Nd同位素组成接近,代表了地幔柱源区的同位素特征;而低Ti/Y型苦橄岩具有低的γ_(Os)=-4.1～ 1.2和ε_(Nd)= 3.2～ 5.0,可能表明受到了SCLM(大陆岩石圈地幔)源区物质的混染。与其共生的玄武岩具有低的γ_(Os)=-3.5～-1.6和ε_(Nd)=-0.6～ 0.7,表明其来自于不同于低Ti/Y型苦橄岩也有异于高Ti/Y型苦橄岩的地幔源区,但是也可能受到了SCLM物质的混染。基于Nd-Os同位素的地幔柱与SCLM的二端元混合模型显示:低Ti/Y型苦橄岩可能是SCLM物质组分与地幔柱起源的苦橄质原始岩浆混合形成的;与苦橄岩共生的玄武岩可能是由地幔柱来源的玄武质岩浆与SCLM小比例熔融的熔体混合形成的。     

秦岭造山带中部两河口岩体花岗岩锆石U-Pb年代学、地球化学及地质意义

北秦岭两河口岩体位于太白地区,侵位于秦岭群杂岩中,主要岩性为眼球状花岗岩、片麻状花岗岩和二长花岗岩。 本文研究的眼球状花岗岩和片麻状花岗岩的结晶年龄分别为928±19 Ma 和940±12 Ma,岩石中还保留古元古代至中元古代的 继承锆石。眼球状花岗岩含有富铝矿物石榴子石和白云母。岩石的A/CNK 多大于1.1,具有高Si、富铝的特征,属于高钾钙 碱性系列。岩石轻、重稀土分馏明显,具有中等负Eu 异常。岩石富集大离子亲石元素（Rb, Ba, K 等）、亏损高场强元素 （Nb, Ta, Ti 等）,具有明显的Ba, P, Sr 负异常。矿物学和地球化学特征显示眼球状花岗岩和片麻状花岗岩为S 型花岗岩。两河 口岩体初始Sr 同位素组成变化大,87Sr/86Sr(t)=0.701067~0.739451,具有较低的εNd(t)=-5.7~-3.3, 两阶段Nd 模式年龄为TDM2= 1.9~2.1 Ga。样品具有高的放射成因Pb 同位素组成,指示两河口岩体是壳源成因岩石,其源岩可能为秦岭群斜长角闪岩和 片麻岩。结合区域地质背景,认为两河口岩体源于新元古代陆壳碰撞晚期的构造转换阶段古老中下地壳的熔融作用,是对 Rodinia 超大陆汇聚事件的响应。     

Carbon,hydrogen, and oxygen isotope studies of the regional metamorphic complex at Naxos,Greece

At Naxos, Greece, a migmatite dome is surrounded by schists and marbles of decreasing metamorphic grade. Sillimanite, kyanite, biotite, chlorite, and glaucophane zones are recognized at successively greater distances from the migmatite dome. Quartz-muscovite and quartz-biotite oxygen isotope and mineralogie temperatures range from 350 to 700°C.The metamorphic complex can be divided into multiple schist-rich (including migmatites) and marblerich zones. The δ¹⁸O values of silicate minerals in migmatite and schist units and quartz segregations in the schist-rich zones decrease with increase in metamorphic grades. The calculated δ¹⁸O_H2O values of the metamorphic fluids in the schist-rich zones decrease from about 15‰ in the lower grades to an average of about 8.5‰ in the migmatite.The δD values of OH-minerals (muscovite, biotite, chlorite, and glaucophane) in the schist-rich zones also decrease with increase in grade. The calculated δD_H2O values for the metamorphic fluid decrease from ?5‰ in the glaucophane zone to an average of about ?70‰ in the migmatite. The δD values of water in fluid inclusions in quartz segregations in the higher grade rocks are consistent with this trend.Theδ¹⁸O values of silicate minerals and quartz segregations in marble-rich zones are usually very large and were controlled by exchange with the adjacent marbles. The δD values of the OH minerals in some marble-rich zones may reflect the value of water contained in the rocks prior to metamorphism.Detailed data on 20 marble units show systematic variations of δ¹⁸O values which depend upon metamorphic grade. Below the 540°C isograd very steep δ¹⁸O gradients at the margins and large δ¹⁸O values in the interior of the marbles indicate that oxygen isotope exchange with the adjacent schist units was usually limited to the margins of the marbles with more exchange occurring in the stratigraphic bottom than in the top margins. Above the 540°C isograd lower δ¹⁸O values occur in the interior of the marble units reflecting a greater degree of recrystallization and the occurrence of Ca-Mg-silicates.Almost all the δ¹³C values of the marbles are in the range of unaltered marine limestones. Nevertheless, the δ¹³C values of most marble units show a general correlation with δ¹⁸O values.The $\text{CO}{}_2\text{H}{}_2\text{O}$ mole ratio of fluid inclusions in quartz segregations range from 0.01 to 2. Theδ¹³C values of the CO₂ range from ?8.0 to 3.6‰ and indicate that at some localities CO₂ in the metamorphic fluid was not in carbon isotopic equilibrium with the marbles.     

Magnesium isotopic behaviors between metamorphic rocks and their associated leucogranites,and implications for Himalayan orogenesis

Magnesium isotopic compositions, along with new Sr–Nd–Pb isotopic data and elemental analyses, are reported for 12 Miocene tourmaline-bearing leucogranites, 15 Eocene two-mica granites and 40 metamorphic rocks to investigate magnesium isotopic behaviors during metamorphic processes and associated magmatism and constrain the tectonic-magmatic-metamorphic evolution of the Himalayan orogeny. The gneisses, granulites and amphibolites represent samples of the Indian lower crust and display large range in δ²⁶Mg from −0.44‰ to −0.09‰ in mafic granulites, −0.44‰ to −0.10‰ in amphibolites, and −0.70‰ to −0.03‰ in granitic gneisses. The average Mg isotopic compositions of the granitic gneisses (−0.19 ± 0.34‰), mafic granulites (−0.22 ± 0.17‰) and amphibolites (−0.25 ± 0.24‰) are similar, indicating the limited Mg isotope fractionation during prograde metamorphism from granitic gneisses to mafic granulites and retrograde metamorphism from mafic granulites to amphibolites. The Eocene two-mica granites and Miocene leucogranites are characterized by large variations in elemental and Sr–Nd–Pb isotopic compositions. The leucogranites and two-mica granites have their corresponding (⁸⁷Sr/⁸⁶Sr)_i varying from 0.7282 to 0.7860 and 0.7163 to 0.7191, (¹⁴³Nd/¹⁴⁴Nd)_i from 0.511888 to 0.512040 and 0.511953 to 0.512076, ²⁰⁷Pb/²⁰⁴Pb from 15.7215 to 15.7891 and 15.7031 to 15.7317, ²⁰⁸Pb/²⁰⁴Pb from 38.8521 to 39.5286 and 39.2710 to 39.4035, and ²⁰⁶Pb/²⁰⁴Pb from 18.4748 to 19.0139 and 18.7834 to 18.9339. However, they have similar Mg isotopic compositions (−0.21‰ to +0.06‰ versus −0.24‰ to +0.09‰), which did not originate from fractional crystallization nor source heterogeneity. Based on hornblende/biotite/muscovite dehydration melting reaction and Mg isotopic variations in two-mica granites and leucogranites with the proceeding metamorphism, along with elemental discrimination diagrams, Eocene two-mica granites and Miocene leucogranites could be related to hornblende dehydration melting and muscovite dehydration melting, respectively. Mg isotopic compositions of Eocene two-mica granites become heavier compared to the source because of residues of isotopically light garnet in the source; while those of Miocene leucogranites become lighter because of entrainment of isotopically light garnet from the source region. Thus, a new model for crustal anatexis and Himalayan orogenesis was proposed based on the Mg isotope fractionation in the leucogranites and metamorphic rocks. This model emphasizes a successive process from Indian continental subduction to rapid exhumation of the Higher Himalayan Crystalline Series (HHCS). The former underwent high-temperature (HT) and high-pressure (HP) granulite-facies prograde metamorphism, which resulted in the hornblende dehydration melting and the formation of Eocene two-mica granites; while the latter experienced amphibolite-facies retrogression and decompression, which resulted in the muscovite dehydration melting and the formation of Miocene leucogranites.     

Rb-Sr and U-Pb isotope studies on migmatites from the Schwarzwald (Germany): constraints on isotopic resetting during Variscan high-temperature metamorphism

Mineral and isotope studies were undertaken on migmatites from the Schwarzwald, Moldanubian zone of the Variscan belt. The aims of the study were to date the migmatite formation and to determine the processes involved in migmatization in order to evaluate their influence on isotopic resetting. Textural evidence and the comparison of mineral compositions from leucosomes and mesosomes of two centimetre-scale migmatite profiles, respectively, suggest that migmatitic textures and mineral assemblages were formed by metamorphic segregation (deformation-enhanced mass transport) rather than by partial melting (anatexis). The results of Rb-Sr thin-slab dating on these profiles indicate that Sr isotopes were not completely reset during migmatization. No true isochron ages, but ages of approximate isotopic homogenization were obtained on the thin slabs by calculating ⁸⁷Sr/⁸⁶Sr ratios back to various stages in their evolution. The coincidence of these Rb-Sr data with U-Pb ages of monazites from migmatites and non-migmatitic gneisses shows that gneisses and migmatites were formed during the same high-temperature event in the Carboniferous (330-335 Ma). The observation that high-temperature metamorphism failed to equilibrate Sr isotopes on the centimetre-scale imposes limitations on the use of conventional whole-rock isochron techniques in dating migmatites.     

中国东南部花岗岩类Nd—Sr同位素研究

根据本文测定的５８个数据以已发表的１２７个数据讨论了中国东南部不同时代花岗岩类的Ｎｄ－Ｓｒ同位素特征,工通过与基底变质岩Ｓｍ－Ｎｄ同位素组成的对比,研究了这些花岗岩类的物质来源与成因。仅分布于浙西南的古元古代花岗岩娄是由成分上类似干被其侵入的八都群片麻岩经部分熔融形成的。沿江绍断裂带分布的新元古代花岗岩类是由地幔来源岩浆或初生地壳形成的;浙西－皖南－赣北地区的新元古代花岗岩类可能是由中元古代地层中的低成熟度组分形成的。古生代和大部分中生代花岗岩类主要是由所在区域内出露的中元古代变质沉积岩的相当物衍生的。沿浙闽沿海地区分布的大多数晚中生代花岗岩娄含有较多的地幔组分．两种来诹岩浆混台可能是其一种重要的成岩方式。     

碾子山晶洞碱性花岗岩矿物-水氧同位素交换反应动力学

对黑龙江碾子山碱性花岗岩的全岩及其主要单矿物进行了氧同位素分析，结果表明，全岩和单矿物不仅δ^18O 值变化范围较大（全岩－2．4－2．0‰，石英0．0－5．8‰，碱性长石－3．8－0．1‰，磁铁矿－8．5－1．0‰），而且强烈亏损^18O。共生矿物之间表现出明显不平衡的氧同位素分馏特征，指示在花岗岩侵位之后与水之间发生了同位素交换，根据锆石和现代大气降水的氧同位素组成，对岩石与外来流体的δ^18O值进行了估计，多维矿水－岩反应时限约为0．3－3Ma，水／岩比（氧摩尔比）介于0．11－1．02之间。水－岩反应温度较高（约400度）和反应时间较长是导致石英δ^18O值降低的主要原因。     

Geochronology in migmatites a SmNd, UPb and RbSr study from the Proterozoic Damara belt (Namibia): implications for polyphase development of migmatites in high-grade terranes

Sm–Nd (garnet), U–Pb (monazite) and Rb–Sr (biotite) ages from a composite migmatite sample (Damara orogen, Namibia) constrain the time of high‐grade regional metamorphism and the duration of regional metamorphic events. Sm–Nd garnet whole‐rock ages for a strongly restitic melanosome and an adjacent intrusive leucosome yield ages of 534±5, 528±11 and 539±8 Ma. These results provide substantial evidence for pre‐500 Ma Pan‐African regional metamorphism and melting for this segment of the orogen. Other parts of the migmatite yield younger Sm–Nd ages of 488±9 Ma for melanosome and 496±10, 492±5 and 511±16 Ma for the corresponding leucosomes. Garnet from one xenolith from the leucosomes yields an age of 497±2 Ma. Major element compostions of garnet are different in terms of absolute abundances of pyrope and spessartine components, but the flat shape of the elemental patterns suggests late‐stage retrograde equilibration. Rare earth element compositions of the garnet from the different layers are similar except for garnet from the intrusive leucosome suggesting that they grew in different environments. Monazite from the leucosomes is reversely discordant and records ²⁰⁷Pb/²³⁵U ages between 536 and 529 Ma, indicating that this monazite represents incorporated residual material from the first melting event. Monazite from the mesosome MES 2 and the melanosome MEL 3 gives ²⁰⁷Pb/²³⁵U ages of 523 and 526 Ma, and 529 and 531 Ma, respectively, which probably indicates another thermal event. Previously published ²⁰⁷Pb/²³⁵U monazite data give ages between 525 and 521 Ma for composite migmatites, and 521 and 518 Ma for monazite from neosomes. Monazite from granitic to granodioritic veins indicates another thermal event at 507–505 Ma. These ages are also recorded in ²⁰⁷Pb/²³⁵U monazite data of 508 Ma from the metasediment MET 1 from the migmatite and also in the Sm–Nd garnet ages obtained in this study. Taken together, these ages indicate that high‐grade metamorphism started at c. 535 Ma (or earlier) and was followed by thermal events at c. 520 Ma and c. 505 Ma. The latter event is probably connected with the intrusion of a large igneous body (Donkerhoek granite) for which so far only imprecise Rb–Sr whole‐rock data of 520±15 Ma are available. Rb–Sr biotite ages from the different layers of the migmatite are 488, 469 and 473 Ma. These different ages indicate late‐stage disturbance of the Rb–Sr isotopic system on the sub‐sample scale. Nevertheless, these ages are close to the youngest Sm–Nd garnet ages, indicating rapid cooling rates between 13 and 20°C Ma^?1 and fast uplift of this segment of the crust. Similar Sm–Nd garnet and U–Pb monazite ages suggest that the closure temperatures for both isotopic systems are not very different in this case and are probably similar or higher than the previously estimated peak metamorphic temperatures of 730±30°C. The preservation of restitic monazite in leucosomes indicates that dissolution of monazite in felsic water‐undersaturated peraluminous melts can be sluggish. This study shows that geochronological data from migmatites can record polymetamorphic episodes in high‐grade terranes that often contain cryptic evidence for the nature and timing of early metamorphic events.     

广东从化佛冈（主体）黑云母花岗岩定年和成因

佛冈黑云母花岗岩是大型东西走向的佛冈花岗质杂岩体的主体部分、占杂岩体面积的85％。粗等粒或巨晶斑状结构。由黑云母（2－6％），石英（35－41％），斜长石（An10-23,10-18%)和微纹长石（36－48％）组成，系黑云母花岗岩。黑云母具有低的Mg/(Mg+Fe)值（0.17-0.21)。据全岩－矿物Rb-Sr等时线定年其定位年龄为167.5±7.5Ma，MSWD为2.4(中侏罗世晚期）。在岩石化学成分上为富硅（SiO2在71.74-77.64%)，中等过铝质（A／NKC平均为1.056)，钼碱性－弱亚碱性（NK／A平均为0.797)，相对富K2O（K2O／Na2O为1.66)。在微量元素和稀土元素组成方面，显示Nb亏损，具有低Nb/Ta值（平均5.94)，高Rb/Sr(1.98-41.71)，Rb/Nb(11-23)和K／Nb(1498－2976值）；中－强Eu亏损（Eu/Eu在0.12-0.46)；高的（La/Sm)N值（1.67-5.39)等。在Sr,Nd,Pb,O同位素组成上，具有高的Isr值（0.7116±0.0023)和εSr(t)值（96－103）；低的εNd(t)值（－6.19--8.93)。据模拟计算，其源区岩石中华南上壳端元约占66－69％，高的^207Pb/^204Pb(15.734)和^206Pb/^204Pb值（18．962－19．049）位于铅构造模式图的上壳演化线域内，高δ^18O‰（＋9.3-+12.5)等。以上数据表明佛冈黑云母花岗岩系该区中－下地壳层次的源岩部分熔融而成，与华南S型花岗岩有相似之处。古太平洋板块（向西）与欧亚板块和菲律宾地块（向北）与南中国－印支地块的岩石圈消减作用导致的玄武岩底侵，对黑云母花岗岩的形成有一定的贡献。     

秦岭群条带状混合岩矿物空间分布的研究

由于条带状混合岩具多成因,因此,研究混合岩关键的问题之一是确定其成因。矿物空间分布特征可以用来区分混合岩的成因。本文研究表明,石英正长岩质黑云杆状混合岩其脉体、基体均为聚集分布,为分异作用形成,并同变形作用有关。用Wilcoxon秩和检验对比了花岗岩和含榴矽线黑云条带混合岩的脉体,结果表明两者的矿物空间分布一致,且趋于随机分布,这些脉体为部分熔融或注入形成。区域变质岩趋向于规则分布。组成混合岩的不同部分在矿物空间分布上可有也可以没有差异,例如,含榴矽线黑云条带混合岩中古成体同脉体有明显差异,而石英正长岩质黑云杆状混合岩基体和脉体无差异。     

阿尔泰南缘乌拉斯沟铜矿床S-Pb-Sr-Nd-C-H-O同位素特征及其对成矿物质和流体来源限定

新疆乌拉斯沟铜矿床位于阿尔泰造山带南缘克兰盆地内,为近年来新发现的矿床,受NW向断裂控制的脉状矿体产于泥盆系康布铁堡组变质火山岩系中,目前其成矿流体和成矿物质来源尚不明确.在细致的矿床地质研究基础上,通过开展S-Pb-Sr-Nd-C-H-O同位素分析,根据野外和显微镜下观察,可将乌拉斯沟铜矿床的形成划分为黄铁矿-磁铁矿-石英、黄铜矿-绿泥石-绿帘石-石英及石英-碳酸盐阶段.同位素分析结果显示:乌拉斯沟铜矿硫化物样品δ34S值为0.1‰~3.2‰,平均为1.6‰,落入未矿化围岩δ34S值范围（-4.7‰~18.68‰）,矿石硫可能源自康布铁堡组.成矿晚阶段的方解石样品δ13C_V-PDB‰=-1.1‰,δ18O_V-PDB‰=-20.3‰,海相碳酸盐地层和有机碳是可能的碳质来源.8件黄铁矿的Pb同位素为206Pb/204Pb=17.939~18.508（平均18.255）,207Pb/204Pb=15.519~15.674（平均15.578）,208Pb/204Pb=37.881~38.653（平均38.209）,与康布铁堡组围岩类似.初始I_{Sr（220 Ma）}为0.710 4~0.711 7,平均值为0.711 1,初始143Nd/144Nd值为0.512 002~0.512 240（平均0.512 103）.矿石Sr-Nd-Pb同位素组成均指示乌拉斯沟铜矿成矿物质可能主要源自围岩康布铁堡组,并可能有外来成矿物质的加入.流体的δD_V-SMOW变化于-103.8‰~-92‰（平均值为-99.2‰）,石英和方解石矿物的δ18O_V-SMOW值集中在9.4‰~11.5‰（平均值为10.4‰）,δ18O_H2O值为2.1‰~4.2‰（平均值为3.1‰）,结合流体包裹体物理化学特征,成矿热液可能来源于变质水,但可能受到大气降水的影响而偏移.因此,乌拉斯沟铜矿成矿物质主要来源于赋矿围岩的变质脱挥发分作用,这与造山型矿床的成矿机制吻合.      

Multiple isotope composition (S, Pb, H, O, He, and Ar) and genetic implications for gold deposits in the Jiapigou gold belt, Northeast China

The Jiapigou gold belt (>150 t Au), one of the most important gold-producing districts in China, is located at the northeastern margin of the North China Craton. It is composed of 17 gold deposits with an average grade around 10 g/t Au. The deposits are hosted in Archean gneiss and TTG rocks, and are all in shear zones or fractures of varying orientations and magnitudes. The δ³⁴S values of sulfide from ores are mainly between 2.7?‰ and 10?‰. The Pb isotope characteristics of ore sulfides are different from those of the Archean metamorphic rocks and Mesozoic granites and dikes, and indicate that they have different lead sources. The sulfur and lead isotope compositions imply that the ore-forming materials might originate from multiple, mainly deep sources. Fluid inclusions in pyrite have ³He/⁴He ratios of 0.6 to 2.5 Ra, whereas their ⁴⁰Ar/³⁶Ar ratios range from 1,444 to 9,805, indicating a dominantly mantle fluid with a negligible crustal component. δ¹⁸O values calculated from hydrothermal quartz are between ?0.2?‰ and +5.9?‰, and δD values of the fluids in the fluid inclusions in quartz are from ?70?‰ to ?96?‰. These ranges suggest dominantly magmatic water with a minor meteoric component. The noble gas isotopic data, along with the stable isotopic data, suggest that the ore-forming fluids have a dominantly mantle source with minor crustal addition.