冀北高压麻粒岩带岩石组合性质、同位素特征及其演化

通过对冀北高压麻粒岩带中各岩石单元岩石组合和同位素年代学研究，划分出北部红旗营子表壳岩带、中部高压麻粒岩带和南部单塔子－桑干杂岩带三个构造岩石单元，进而对中部高压麻粒岩带划分出南北两个亚带。南部亚带主要为2500Ma的钾长花岗岩、高压麻粒岩和再造的单塔子－桑干杂岩；北部亚带由2000－1800Ma的花岗岩带、红旗营子群岩片组成。推断本区高压麻粒岩带实际是新太古代和古元古代两次超大陆汇聚事件的产物。     

冀西北晚太古代岩石单元的地质关系: 对早期陆壳形成的指示

冀西北地区出露晚太古代桑干杂岩和崇礼杂岩构成的灰色片麻岩(TTG片麻岩)-麻粒岩地体和红旗营子群角闪岩相变质火山沉积岩系.本文对尚义地区红旗营子群中变质火山岩中的变玄武安山岩(角闪斜长片麻岩)进行了锆石LAMC-ICPMS定年,获得207 Pb/206Pb加权平均年龄2528±12Ma(2σ,MSWD=0.1,n=34),这一年龄代表了该岩石的形成时代.虽然这一年龄非常接近灰色片麻岩的形成时代,野外地质关系指示红旗营子群的形成早于灰色片麻岩及其中的闪长质侵入体.在灰色片麻岩分布区,红旗营子群和一些变质辉长质岩石呈岩片、透镜体或者“岩墙”状分布.变质辉长质透镜体或者“岩墙”状岩片以周边发育串珠状小透镜体,以及不见细粒边部和岩墙“手指”可以与该区分布的早元古代变质基性岩墙相区别.这些变辉长质岩石可能是红旗营子群火山岩系根部或者岩浆房的残留体,也可能部分是更早期地壳的残片.红旗营子群火山岩系的岩石化学特征可以和灰色片麻岩及闪长质片麻岩岩体分别进行对比.地(桑干杂岩和崇礼杂岩)组成了该地区晚太古代大陆二维地壳结构.认识这种地壳结构在空间上的延续性,并识别相关地质单元在时代和物质上的演化关系,可以揭示华北克拉通晚太古代大陆地壳的形成机制.     

冀北变质杂岩的地球化学、Nd同位素特征与地壳增生

华北克拉通北缘中段主要由变质的太古宙单塔子杂岩、古元古代红旗营子杂岩、未变质的大庙-长哨营等辉长岩-斜长岩-偏碱性花岗岩和晚古生代变质铁镁质到花岗质岩石组成。约2.49Ga的单塔子杂岩包括麻粒岩相到角闪岩相变质的闪长质-奥长花岗质-花岗闪长质-二长花岗质片麻岩,岩石化学特征表明它们属于中钾—高钾钙碱性演化系列,大部分岩石Mg#在40以下,右斜式从无Eu异常到明显的正Eu异常的稀土配分模式,具有明显的Th、Nd、Ta和Ti的负异常,εNd(t)= 0.65~-0.03,亏损地幔模式年龄tDM=2.78~2.71Ga。岩石成因研究表明,它们形成于初生岩浆和再循环地壳的铁镁质岩石部分熔融的岩浆混合,形成于大陆边缘弧的构造背景。形成于2.44~2.41Ga的红旗营子杂岩主要由变质铁镁质岩石-花岗闪长质-二长花岗质片麻岩组成,表现了与单塔子杂岩类似的岩石化学特征,即中钾—高钾钙碱性岩浆演化系列,其中变质铁镁质岩石表现为大离子亲石元素变化较大,Th、Nb、Ta、Zr负异常,P为正异常。其他的花岗质岩石样品Th、Nb、Ta、P和Ti负异常。所有岩石表现出右斜式无Eu异常的稀土配分模式。其中变质铁镁质岩石εNd(t)=-1....     

晋冀蒙高级区两期高压麻粒岩的地质特征及成因

晋冀蒙高级区存在两期高压麻粒岩,其分布、产状、时代、成因都不同。早期高压麻粒岩,沿宣化西葛峪、大东沟、怀安蔓菁沟南部、恒山白蟒石一带分布,呈透镜状产于钾长花岗岩中,形成时代约2400Ma,属岩浆包体。晚期高压麻粒岩,沿孔兹岩系和麻粒岩杂岩的接触带分布,呈透镜状、岩脉状产出,并和孔兹岩岩片、高温韧性剪切带、超基性岩一同构成具有“混杂岩”性质的构造-岩浆杂岩带,其时代为1800Ma左右。     

辽东盖县矿洞沟地区四张磙子花岗岩锆石U-Pb 年龄及意义

<正>辽东半岛位于华北板块东部,根据岩石建造又可划分为北部的太古宙鞍山-抚顺杂岩(辽北-吉南地块)与南部金州太古宙杂岩(辽南地块)以及中部的辽吉花岗岩带和辽河群变质沉积岩。辽东花岗岩带又分为三套岩石组合:以虎皮峪为代表的片麻状     

华北克拉通北缘隆化地区蓝旗镇古元古代石榴石花岗岩的成因及地质意义

隆化地区蓝旗镇石榴石花岗岩位于华北克拉通北缘中部,与古元古代红旗营子杂岩密切共生。岩石主要由碱性长石、斜长石、石英、石榴石以及少量黑云母等矿物组成。锆石U Pb定年结果表明,石榴石花岗岩的形成时代为1894~1878Ma,属于古元古代中晚期。岩石的SiO2和K2O含量分别介于6409%~7080 %和364%~573 %之间,属于高钾钙碱性到钾玄岩过渡系列;岩石具有较高的Al2O3（1450%~1613%）和较低的CaO（125%~327%）和Na2O（180%~257%）含量,铝饱和指数（ACNK）介于107~134之间,表明该岩体属于S型花岗岩。岩石具有较高的CaO/Na2O比值（>03）,以及较低的Al2O3/Ti2O、Rb/Sr和Rb/Ba比值,指示岩浆源区为贫粘土、富斜长石的砂质岩。锆石Hf同位素分析进一步说明其物源可能是单塔子和红旗营子杂岩经风化作用的产物。蓝旗镇石榴石花岗岩具有与华北克拉通孔兹岩带内S型花岗岩相似的年代学和地球化学特征,结合区域变质岩和岩浆岩资料,本文认为孔兹岩带在空间上可能从内蒙古集宁地区向东延伸到了冀北地区。     

冀北单塔子杂岩的地质学和锆石U-Pb年代学

冀北单塔子杂岩位于华北克拉通北缘中段隆化-赤城断裂以南,主要由高角闪岩相-麻粒岩相变质的英云闪长质、奥长花岗质、花岗闪长质片麻岩(TTG岩套)和铁镁质二辉麻粒岩、辉石斜长角闪岩、石榴石斜长变粒岩、石榴石夕线石黑云母片岩及少量的大理岩等表壳岩残留体组成。详细的SHRIMP和LA-ICPMS锆石U-Pb同位素地质年代学研究表明,冀北单塔子杂岩的形成主要经历了7个演化阶段:(1)2600～2530Ma之间形成了单塔子杂岩中英云闪长质和奥长花岗质片麻岩的围岩,其中一部分铁镁质表壳岩,即铁镁质二辉麻粒岩,可能为英云闪长质—奥长花岗质岩浆的源岩;(2)2517～2505Ma主要为英云闪长质岩浆的侵位结晶阶段;(3)2494～2473Ma,奥长花岗质片麻岩侵位结晶;(4)2427～2404Ma,发生了早期麻粒岩相变形变质作用和深溶混合岩化作用,使这一杂岩经历了强烈的改造;(5)～1859Ma,铁镁质岩浆侵位,形成一些铁镁质岩株和岩脉;(6)～1834Ma到1793Ma,单塔子杂岩经历了最强烈的变质作用改造,形成了晚期麻粒岩相变质作用;(7)～1730Ma经历了强烈的流体活动,使得一些锆石发生了流体交代和改造。但是总体上单塔子杂岩没有经历～300Ma的古生代的变质作用。     

冀北中低级变质表壳岩的年代学特征及其对华北克拉通构造演化的约束

华北克拉通在新太古代末期发生克拉通化,形成了现今规模的古陆,大量的太古宙岩石均经历了~2500Ma左右的区域高级变质作用(高角闪岩相-麻粒岩相)。而华北克拉通北部冀北地区出露一套中低级变质(绿片岩相-角闪岩相)的火山-沉积岩系,主要包括胡麻营地区红旗营子表壳岩和大阴山地区单塔子表壳岩中变质程度较低的部分。胡麻营地区红旗营子表壳岩系主要岩石组合为变基性火山岩、绿帘角闪岩、斜长角闪岩、含石榴石斜长角闪岩、角闪斜长片麻岩、黑云斜长片麻岩、黑云角闪斜长片麻岩、黑云二长片麻岩、石英片岩、磁铁石英岩等,SIMS锆石U-Pb定年结果表明斜长角闪岩形成于2486±18Ma(MSWD=1.4),而黑云斜长片麻岩形成于2507±37Ma(MSWD=2.0)。大阴山地区单塔子中低级变质表壳岩系主要由浅变质火山岩、云母石英片岩、斜长角闪岩、磁铁石英岩和大理岩等组成,SHRIMP锆石U-Pb定年结果显示,浅变质火山岩中的变玄武岩形成于2490±19Ma(MSWD=2.0),而变英安岩形成于2502±8Ma(MSWD=0.83)。因此,冀北中低级变质的表壳岩系主要形成于新太古代末期,形成年龄为2507~2486Ma;结合冀东青龙地区新太古代末期(2511~2503Ma)的浅变质火山-沉积岩系(青龙表壳岩),我们认为新太古代末期,中低级变质表壳岩系广泛分布于华北克拉通的核部和边缘地区,此套岩系覆盖在太古宙高级变质杂岩之上,代表华北克拉通化之后的稳定盖层,是克拉通化的主要标志之一。     

桐柏碰撞造山带及其邻区变形特征与构造格局

桐柏碰撞造山带及其邻区可以划分为九个大地构造单元,自北向南分别是:华北克拉通南缘岩石构造单元——宽坪岩群、具弧后盆地性质的二郎坪岩石构造单元、具岛弧性质的秦岭杂岩单元、龟山岩组和南湾岩组构成的俯冲前缘楔构造带、构造混杂岩带、桐柏北部高压岩片单元、桐柏核部杂岩单元、桐柏南部高压岩片单元以及随州构造变形带。根据详细的构造解析以及新的地质年代学资料,本文将中生代以来的构造变形划分为五幕,前两幕变形主要发育在构造混杂岩带以南的各个岩石构造单元中,之后的三幕变形则波及整个研究区。第一幕变形的时间约为255～238Ma,以发育区域上透入性的片理及北西西向的拉伸线理为主,并导致了高压岩片早期自西向东的挤出。第二幕变形的时间约为230～215Ma,以自北向南的逆冲推覆构造为主,使得高压岩片进一步垂向抬升。第三幕变形应早于下侏罗统,以近北西西向的宽缓褶皱为主要特征,该幕变形期间桐柏核部杂岩及其两侧高压岩片单元发生同步的抬升。第四幕变形大致发生在140～130Ma之间,主要表现为桐柏核部杂岩两侧走滑型韧性剪切带的活动,桐柏核部杂岩表现出向东的挤出。第五幕变形发生在120～80Ma,表现为北西向及北东向的脆性断裂活动,并切割以上所有构造形迹。桐柏高压岩片的抬升剥露受多幕变形控制,呈阶段性的抬升。     

苏鲁造山带东北端石榴辉石麻粒岩的Sm-Nd同位素年代学及其大地构造含义

大量含石榴石的基性麻粒岩透镜体出露于苏鲁变质带的北部及邻近地区,它们可能是再变质的高压变质岩石。在详细的岩相学研究的基础上,确定采自莱西和文登的样品WD01、WD04、ML06 是由高压麻粒岩经中-高压麻粒岩相再变质形成的,而采自威海的样品WH1 是由柯石英榴辉岩经中-高压麻粒岩相再变质形成的。Sm-Nd 同位素年代学研究也证实了二者的重大差别。3 个高压麻粒岩样品的矿物-全岩内部等时线年龄分别是1 846+ /-76Ma,1 743+ /-79Ma 和1 752+ /-30Ma,TDM 模式年龄是3.3Ga,3.0Ga 和2.8Ga.上述数据说明原岩形成在太古宙,而1 800Ma 是麻粒岩相降压变质事件的记录,这与华北克拉通前寒武纪高压麻粒岩的年代学一致。威海样品的Sm-Nd 同位素特征则完全不同。矿物和全岩形不成等时线,表现出它们之间的同位素不平衡。ε_Nd(0)值高达+ 127,TDM 模式年龄是1.3Ga.这与Jahn(1994,1996)对威海同类样品的测定结果相同。可以推测威海样品的原岩是元古宙岩石,在后来复杂的变质过程中,在水岩相互作用和岩浆及重熔作用的影响下,同位素系统发生重大变化。同位素年代学为苏鲁变质带和华北克拉通的界限是昆嵛山岩浆-变质杂岩带提供了依据。     

Police, politics, and the right to the city

Space and spatiality have recently been at the core of debates concerning the political possibilities of the city. The arguments advanced in this paper might be seen as an attempt to contribute to these debates through a reflection on the spatiality of (in) justice, politics, and the right to the city. The case of French urban policy, with its focus on distressed urban areas, and the `suburban problem' in France are used as examples to make arguments more concrete.     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Influences of the unsaturated,saturated, and riparian zones on the transport of nitrate near the Merced River,California, USA

Transport and transformation of nitrate was evaluated along a 1-km groundwater transect from an almond orchard to the Merced River, California, USA, within an irrigated agricultural setting. As indicated by measurements of pore-water nitrate and modeling using the root zone water quality model, about 63% of the applied nitrogen was transported through a 6.5-m unsaturated zone. Transport times from recharge locations to the edge of a riparian zone ranged from approximately 6 months to greater than 100 years. This allowed for partial denitrification in horizons having mildly reducing conditions, and essentially no denitrification in horizons with oxidizing conditions. Transport times across a 50–100-m-wide riparian zone of less than a year to over 6 years and more strongly reducing conditions resulted in greater rates of denitrification. Isotopic measurements and concentrations of excess N₂ in water were indicative of denitrification with the highest rates below the Merced River. Discharge of water and nitrate into the river was dependent on gradients driven by irrigation or river stage. The results suggest that the assimilative capacity for nitrate of the groundwater system, and particularly the riverbed, is limiting the nitrate load to the Merced River in the study area.     

扬子北缘马元铅锌矿床闪锌矿微量元素及S-Pb-He-Ar-C同位素地球化学研究

马元铅锌矿床是近年扬子陆块北缘铅锌找矿的新突破。矿体呈层状、似层状产于碑坝隆起翼部震旦系灯影组角砾状白云岩层间构造带中,围岩蚀变很弱。矿石中硫化物以闪锌矿、方铅矿为主,中粗粒晶质结构,充填于白云岩角砾间。闪锌矿富集Cd、Ge、Ag,贫In、Tl、Se,Ga/In为6~132,Ge/In多1000,成矿温度以中-低温为主。金属硫化物ε~(34)S值相对集中,为12.9‰~19.4‰,平均为17.4‰,来自于海相硫酸盐的还原。铅同位素组成稳定,~(206)Pb/~(204)Pb为17.858~17.918:~(207)Pb/~(204)Pb为15.603~15.694;~(208)Pb/~(204)Pb为37.756~38.046,具有造山带和上地壳铅的特征,震旦系可能提供了金属成矿物质。闪锌矿中流体包裹体的~3He/~4He为0.03Ra~1.05Ra,~(40)Ar/~(36)Ar为326.1~765.1,~(38)Ar/~(36)Ar为0.183~0.204,表明成矿流体主要为地壳流体和饱和大气水(大气降水或海水)的混合。闪锌矿内流体包裹体挥发分δ~(13)C_(CH_4)值为-36.01‰~-28.80‰,δ~(13)C_(C_2H_6)值为-27.72‰~-22.44‰,δ~(13)C_(CO_2)值为-23.24‰~-9.68‰,表明有机流体参与了成矿作用。石英、方解石的H-O同位素结果表明具有海水和有机水混合的特征。可见,成矿流体具有两种流体混合的特征,一为蒸发海水与围岩反应所形成的盆地卤水,二为有机流体。推测矿区可能存在一个古油气藏,由于TSR生成一高硫气藏,为区内还原性有机流体的主要来源。当富含Pb、Zn等成矿物质的成矿流体运移至富含CH_4和H_2S的还原性流体的矿区角砾岩带时,两种流体混合,Pb、Zn等遇到H_2S发生反应而沉淀成矿,并伴生热液白云石等,形成了马元铅锌矿床。综上所述,我们认为马元矿床属MVT型铅锌矿床。     

Rb-Sr, K-Ar, H-and O-Isotope systematics of the Middle Riphean shales from the Debengda Formation, the Olenek Uplift, North Sibera

Clay subfractions (SFs) of <0.1, 0.1–0.2, 0.2–0.3, 0.3–0.6, 0.6–2 and 2–5 μm separated from Middle Riphean shales of the Debengda Formation are studied using the TEM, XRD, K-Ar and Rb-Sr isotopic methods. The oxygen and hydrogen isotope compositions in the SFs are studied as well. The low-temperature illite-smectite is dominant mineral in all the SFs except for the coarsest ones. The XRD, chemical and isotopic data imply that two generations of authigenic illite-smectite different in age are mixed in the SFs. The illite crystallinity index decreases in parallel with size diminishing of clay particles. As compared to coarser SFs, illite of fine-grained subfractions is enriched in Al relative to Fe and Mg, contains more K, and reveals higher K/Rb and Rb/Sr ratios. The Rb-Sr age calculated by means of the leachochron (“inner isochron”) method declines gradually from 1254-1272 Ma in the coarsest SFs to 1038-1044 Ma in finest ones, while the K-Ar age decreases simultaneously from 1225–1240 to 1080 Ma. The established positive correlation of δ¹⁸O and δD values with dimensions of clay particles in the SFs seems to be also consistent with the mixing systematics. The isotopic systematics along with data on mineral composition and morphology lead to the conclusion that mixedlayer illite-smectite was formed in the Debengda shales during two periods 1211–1272 and 1038–1080 Ma ago. The first period is likely close to the deposition time of sediments and corresponds to events of burial catagenesis, whereas the second one is correlative with the regional uplift and changes in hydrological regime during the pre-Khaipakh break in sedimentation.     

贵州岑巩羊桥罗家塘杷榔动物群的发现及其后生动物早期演化的意义

岑巩县羊桥乡罗家塘杷榔组仅出露中-上部地层,岩性单一,均为青灰、灰绿色粉砂质泥、页岩.在其上部层位发现了俞氏贵州始海百合(Guizhoueocrinus yui Zhao,Parsley et Peng,2007),计有棘皮动物始海百合、腕足动物、软体动物-软舌螺、节肢动物-三叶虫等8属9种,包括了2个未定名的新种和1...     

Breakthroughs in the biodiversity, biogeography, biostratigraphy, and basin analysis of the Beaufort group

Over the past decade researchers working on the rocks of the Beaufort Group in the main Karoo Basin of South Africa have vastly increased our understanding of this important Permo-Triassic sequence. Many new fossil forms have been discovered, allowing for breakthroughs into the biodiversity, biogeography and biostratigraphy of the group. Taxonomic and phylogenetic advances are many and varied, and cover most of the vertebrate taxa, but with emphasis placed on the temnospondyl amphibians, archosauriforms and non-mammalian synapsids, in particular the anomodontia. Biostratigraphic breakthroughs have centered on the Middle Permian Eodicynodon and Tapinocephalus assemblage zones, the Late Permian Dicynodon Assemblage Zone, and the Triassic Lystrosaurus and Cynognathus assemblage zones. Correlation of these biozones with better dated sequences in Europe, Russia and China has allowed for many chronostratigraphic refinements, which are in turn vital for sequence stratigraphical analysis of the basin fill. Based on fossil data, both the lower (Ecca–Beaufort) and upper (Beaufort–Molteno) contacts of the group have been proved to be highly diachronous. The refined chronostratigraphic framework has also allowed for a better analysis of the basin evolution through time, particularly in terms of the correlation of external stimuli that affect basin sedimentation patterns.     

Delivery of Trace Metals (Al,Fe, Mn,V, Co,Ni, Cu,Cd, Ag,Pb) from the Trinity River Watershed Towards the Ocean

The Trinity River (Texas, USA) contains in its watershed 23 different reservoir lakes, the largest one being Lake Livingston situated in the lower Trinity River watershed and two potentially polluting metroplexes, Dallas and Houston. In order to determine fluxes of nutrients and trace metals to Galveston Bay, a survey that included 24 discreet samples collected over a year and at various stages of discharge was carried out during 2000–2001. Geochemical (i.e., sorption by Fe oxyhydroxides), biological (i.e., seasonal uptake by sinking algae in Lake Livingston), and hydrological (i.e., dilution effects by increasing flow rates) controls were found to be mainly responsible for variations in dissolved trace metal concentrations rather than pollution sources. The Trinity River loads of suspended sediments and pollutant trace metals entering Galveston Bay at Anahuac were <20% of those reaching Lake Livingston, and only a few percent of the total upstream trace metal load is entering the Gulf of Mexico. Thus, during the transit through the 23 man-made lakes and an estuary, >96% of the pollutant trace metal load is lost to sediments.     

深港西部通道填海区地下水铜、钒、铊、镉、钨迁移的实验研究

填海工程使滨海地区的地下水物理化学条件改变,导致该区域地下水中重金属浓度升高。本文以深港西部通道填海区为例,采用实验室模拟填海条件的办法,初步探讨了影响填海区地下水重金属迁移的关键因素。模拟实验结果表明,填海区地下水中钨元素含量升高与地下水淡化、淤泥氧化过程以及填料风化有关;铜元素含量升高则与淤泥氧化过程以及填料风化有关;钒元素含量升高与地下水淡化和淤泥氧化过程有关,而其他元素含量升高则主要与填料风化释放有关。