渤海南部莱州湾Lz908孔沉积物的岩石磁学性质

亚洲大陆边缘海和陆表海在区域的物质和能量交换以及区域气候与环境演化过程中扮演了关键角色.磁性地层学和环境磁学方法是建立年代框架和环境演变序列的有效手段,但是,由于该地区边缘海和陆表海沉积物中磁性矿物来源十分复杂,磁性地层学和环境磁学研究的重要基础是要精细地解译沉积物的岩石磁学性质.为此,本文利用渤海南部莱州湾Lz908孔与钻孔附近的现代沉积物样品进行了详细的岩石磁学对比研究.结果显示,渤海南部沉积物中的磁性矿物主要是较粗颗粒(较大的准单畴至多畴)磁铁矿,还有少量磁赤铁矿,部分沉积物还含有赤铁矿和针铁矿,其中磁铁矿是特征剩磁的主要载体;莱州湾现代河流-海洋沉积物和钻孔样品之间的磁性特征无显著差异,说明莱州湾沉积物堆积之后尚未经历明显的沉积后期改造.     

泥河湾盆地大长梁剖面河湖相沉积物的岩石磁学性质

以热磁分析为主,对中国北方泥河湾盆地更新世河湖相地层中灰绿色粉砂和灰黄色粉砂/细砂两种典型沉积物进行了详细的岩石磁学研究,有效确定了这两类沉积物中磁性矿物的种类、粒度特征以及加热过程中磁性矿物的变化过程和产物,并对其包含的古环境意义进行了初步探讨.灰绿色粉砂样品主要含有磁铁矿和赤铁矿两种磁性矿物,磁性相对较弱,颗粒相对较细;灰黄色粉砂/细砂主要含有磁铁矿和磁赤铁矿,磁性相对较强,颗粒相对较粗.在氩气环境中经700℃加热处理后,这两种沉积物中的绿泥石都分解,并生成超细粒（处于超顺磁和单畴颗粒区间）的磁铁矿,导致磁化率大幅升高.因此泥河湾盆地沉积物的热磁特征可以用来检测样品中绿泥石的相对含量,进而反映该地区化学风化作用强度的变化.此外,灰绿色粉砂样品中绿泥石含量比灰黄色粉砂/细砂样品的含量高,在氩气中加热后,磁化率升高幅度也较高,可能反映了化学风化相对较弱的沉积环境.     

甘肃西山坪遗址岩石磁学性质及其研究意义探讨

对甘肃西山坪遗址剖面样品进行磁化率、频率磁化率、热磁分析、非磁滞剩磁和等温剩磁等一系列岩石磁学实验测试,分析环境磁学参数特征变化,试图探讨西山坪遗址研究意义,为今后深入研究该沉积序列蕴含的古环境记录提供了岩石磁学基础.结果表明：西山坪遗址剖面沉积物中磁性矿物主要以低矫顽力的磁铁矿和磁赤铁矿为主,高矫顽力磁性矿物赤铁矿含量极其有限,越向剖面表层,强磁性矿物含量逐渐增加.磁性矿物颗粒表现出黄土的典型特征,以单畴、准单畴为主,含有一定量的超顺磁颗粒,颗粒度越向剖面表层越细.从物源上看,遗址沉积物主要来自近源的黄土风尘堆积,主要是风成堆积,并混合大量人类活动信息,给今后综合研究岩石磁学与人类活动特征的关系有一定借鉴意义.     

呼伦湖地区扎赉诺尔晚第四纪湖泊沉积物的磁化率变化及其影响因素

呼伦湖盆地扎赉诺尔晚第四纪湖泊沉积物为砂,泥质碎屑沉,地东露天矿剖面沉积物样品进行了低,高频磁化率测量,粒度分析,磁性矿物成分鉴定和Al2O3 ,Fe2O3含量分析,分析表明,磁铁矿是沉积物磁化率的主要贡献者,全铁含量控制了磁化率值的变化,磁化率与沉积物粒度呈负相关,进一步讨论认为,磁性矿物主要为粉砂－粘土级碎屑,集中分布在细粒沉积物中,因此造成其率较高,砂质沉积物中频率磁化率较高,其原因可能是其中的磁性颗粒比粉砂一粘土级沉积物中的磁性颗粒更细一些。     

南黄海表层沉积物粒度端元反演及其对沉积动力环境的指示意义

应用端元分析模型对南黄海表层沉积物粒度数据进行了反演,分离出四个端元.根据各端元频率分布曲线及平面分布特征,结合南黄海沉积动力格局,分析了各端元与研究区物源和水动力环境的对应关系.端元1和端元2反映了海洋动力过程对陆源沉积物的输运和分选,端元3和端元4反映了海洋动力对残留砂的改造.南黄海海洋锋面主要对陆源较粗颗粒沉积物的输运有影响,陆源较粗颗粒沉积物基本不能跨越山东外海海洋锋面.陆源细颗粒沉积物受海洋锋面影响较小,并在潮汐动力条件较弱的南黄海中部大量沉降,构成南黄海中部泥质区主体.南黄海中部细颗粒沉积物可能有西北和西南两个不同物源方向,其北部沉积物主要来自沿岸流输运跨越锋面后的黄河沉积物的细颗粒部分,西南部沉积物主要来自跨越苏北海洋锋面具有长江和黄河混合物源的苏北沿岸沉积物的细颗粒部分.和直接利用沉积物粒度数据研究沉积动力环境的传统方法相比,利用沉积物粒度端元分析方法分离出的沉积物不同端元分析区域沉积动力环境效果更好.     

长江口潮滩沉积物的磁学性质及其与粒度的关系

对长江口潮滩沉积物的环境磁学研究表明, 沉积物磁性特征由多畴/假单畴磁铁矿所主导. 磁铁矿除陆源碎屑成因外, 在磁性最强的石洞口排污口附近沉积物中出现了球形磁性颗粒, 系工业污染的产物. 粒度是影响长江口潮滩沉积物磁性特征的重要因素, 磁化率、饱和等温剩磁与8~16 mm粒级含量呈正相关, 而非磁滞剩磁磁化率等指示细颗粒亚铁磁性矿物的参数与<4 mm乃至<32 mm粒级组分高度正相关. 这一特征表明, 在将磁化率作为污染物含量代用指标时, 需考虑粒度造成的磁化率波动的可能影响, 非磁滞剩磁磁化率则可以作为沉积物细粒级组分的代用指标, 并应用于污染物含量的粒度校正.     

贵州省麦岗水库沉积物磁性特征及其与粒度的关系

对贵州省麦岗水库沉积物环境磁性特征的研究表明,亚铁磁性矿物主导了沉积物矿物磁性特征,但同时也存在反铁磁性矿物等其他矿物,超顺磁颗粒在沉积物中广泛存在.在所选矿物磁性参数中,χlf、χfd、SOFT与粒度不相关;χARM、SIRM、F300与粒度相关,但相关系数不高;χARM/χlf、χARM/SIRM和粒度显著相关,可以作为粒度的代用指标.研究结果显示,磁性参数确实可以作为粒度的代用指标.但对比研究表明,在不同沉积环境,甚至相似沉积环境的沉积物中,矿物磁性参数和粒度的关系可能不同,在特定沉积环境中,利用磁性参数作为粒度的代用指标应该在充分研究的基础上进行,使研究结果更为可靠.     

福州盆地全新世沉积物的磁学性质及其对环境变化的响应

福州盆地位于海陆过渡地带,在海陆变迁过程中,沉积物记录了高分辨率的环境信息,是揭示沉积特征对环境变化响应过程及模式的理想区域.本文选择位于福州盆地的FZ5钻孔进行岩石磁学、环境磁学和古地磁学方面的研究,以期阐明该区域沉积物磁学性质对陆源碎屑输入、海平面变化和成岩作用的响应.岩石磁学结果表明钻孔沉积物以低矫顽力的亚铁磁性矿物为主体,但是在不同的环境变化阶段,磁性矿物的类型有较大变化.在9~3 cal. ka BP的海侵过程中,沉积物中以磁铁矿为主体,存在菱铁矿和铁硫化物等还原性矿物.硫化作用使细粒磁铁矿溶解形成胶黄铁矿和黄铁矿,其峰面随碎屑磁性矿物的浓度变化而迁移.但硫化作用没有完全消除磁铁矿携带的特征剩磁和陆源碎屑输入量以及海平面升降对该阶段沉积物磁性的控制.在~3 cal. ka BP以来随着海平面下降、沉积环境向陆相氧化环境转化,虽然早期还原作用仍然存在,但后期氧化作用使磁性矿物向高矫顽力的赤铁矿等矿物转变,氧化作用基本扰乱了磁铁矿携带的剩磁.沉积及其后期成岩作用过程中,发生在约~8.2、~7.7、~7.5、~2.7、~1.5、~0.5 cal. ka BP六次强烈的古氧化界面反映了福州盆地当时异常干旱或湿热的气候事件.     

南极普里兹湾NP93－2柱样磁组构特征及其古气候意义

对采自东南极普里兹湾海区沉积物ＮＰ９３－２柱样系统的磁组构分析，结果表明：１．普里兹湾海洋沉积物具有较大的磁化率各向异性，较好地指示了沉积过程中水动力过程的变化；２．由磁化率各向异性主轴方向确定的古水流方面主要为近ＥＷ向及ＮＳ向，分别对应着南极绕极环流的方向及由融冰水的大量生成而导致的南极底层水形成的方向，这两种不同方向的水流在该海区不同时段的表现各不相同；３．依据表征磁组构的参数及古水流方向的变化，可将１２７００ａＢ．Ｐ．以来的南极地区的古气候分成５个古气候变化带．     

南极普里兹湾NP93－2柱样磁组构特征及其古气候意义

对采自东南极普里兹湾海区沉积物ＮＰ９３－２柱样系统的磁组构分析，结果表明：１．普里兹湾海洋沉积物具有较大的磁化率各向异性，较好地指示了沉积过程中水动力过程的变化；２．由磁化率各向异性主轴方向确定的古水流方面主要为近ＥＷ向及ＮＳ向，分别对应着南极绕极环流的方向及由融冰水的大量生成而导致的南极底层水形成的方向，这两种不同方向的水流在该海区不同时段的表现各不相同；３．依据表征磁组构的参数及古水流方向的变化，可将１２７００ａＢ．Ｐ．以来的南极地区的古气候分成５个古气候变化带．     

Regional and global effects of southern ocean constraints in a global model

Global ocean circulation models do not usually take high-latitude processes into account in an adequate form due to a limited model domain or insufficient resolution. Without the processes in key areas contributing to the lower part of the global thermohaline circulation, the characteristics and flow of deep and bottom waters often remain unrealistic in these models. In this study, various sections of the Bremerhaven Regional Ice Ocean Simulation model results are combined with a global inverse model by using temperature, salinity, and velocity constraints for the Hamburg Large Scale Geostrophic ocean general circulation model. The differences between the global model with and without additional constraints from the regional model demonstrate that the Weddell Sea circulation exerts a significant influence on the course of the Antarctic Circumpolar Current with consequences for Southern Ocean water mass characteristics and the spreading of deep and bottom waters in the South Atlantic. The influence of the Ross Sea is found to be less important in terms of global influences. However, regional changes in the Pacific sector of the Southern Ocean are found to be of Ross Sea origin. The additional constraints change the hydrographic conditions of the global model in the vicinity of the Antarctic Circumpolar Current in such a way that transport values, e.g., in Drake Passage no longer need to be prescribed to obtain observed transports. These changes not only improve the path and transport of the Antarctic Circumpolar Current but affect the meso- and large-scale circulation. With a higher (lower) mean Drake Passage transport, the mean Weddell Gyre transport is lower (higher). Furthermore, an increase (decrease) in the Antarctic Circumpolar Current leads to a decrease (increase) of the circum-Australian flow, i.e., a decrease (increase) of the Indonesian Throughflow.     

矫顽力组分定量分析揭示下蜀黄土磁化率异常降低的原因

镇江大港下蜀黄土剖面多个层位的磁化率出现异常降低,导致与北方黄土的磁化率记录难以对比.为探讨磁化率异常降低的原因,我们在大港钻探ZK孔获取了岩芯.在10个具代表性的层位采样并测量了其等温剩磁获得曲线.通过基于期望最大化算法的计算程序（Irmunmix V2.2）,定量分析了样品的磁性矫顽力组分（magnetic coercivity component）.结果显示这10个样品可大致分成3类,第一类不含中磁组分,第二类含有较少的中磁组分,第三类则含较多的中磁组分.矫顽力组分的含量与样品中铁锰结核的含量密切相关.铁锰结核含量高的样品,中磁组分、硬磁组分含量也高,而软磁组分含量低,与此对应的是这类样品的磁化率低.表明在铁锰结核的形成过程中,原始的软磁组分被溶解,而产生新的中磁组分、硬磁组分,这个次生变化过程导致样品磁化率异常降低.铁锰结核含量高的样品,经历过较强的还原作用,因此ZK剖面磁化率异常降低是还原作用的结果,可能是某时期降水量增大所致.     

渤海BH08孔磁学参数变化机制与环境指示

边缘海-陆架区是研究海陆交互作用的理想区域,该区沉积物记录了海平面、气候与构造变化的重要信息.渤海作为我国的内海,前人对该区虽然进行了环境磁学方面的研究,但是受复杂的沉积环境影响,渤海沉积物的磁性变化机制十分复杂,因而需要对该区沉积物磁学性质及变化机制进行深入研究.针对这一问题,本文详细研究了渤海BH08孔岩芯沉积物的磁学性质,结果表明：①沉积物中主要载磁矿物是磁铁矿,部分层位含有高矫顽力的矿物;②岩芯整体磁学性质变化复杂,各项磁学参数变化剧烈,其总体波动与S/Cl值、沉积物红度a^*和深海底栖有孔虫δ¹⁸O相关性较好;③在主要的海陆交替边界层位发现胶黄铁矿,表明是富硫的弱还原环境,而快速变化的沉积环境和较高的沉积速率是胶黄铁矿得以保存的重要因素,因而胶黄铁矿可作为沉积环境发生转变的一种特征矿物.这些新认识为深入开展渤海地区,乃至陆架-边缘海区古环境研究提供了新的思路和方法.     

The alkalinity of the deep Pacific

The distribution of alkalinity obtained by the GEOSECS Pacific expedition provides implications for the ocean circulation and for the dissolution of CaCO₃. Alkalinity has a maximum in the deep water at all stations occupied north of the Circumpolar. The distribution of alkalinity at its maximum suggests a cyclonic circulation in the deep water. The bottom water in the North Pacific gains alkalinity primarily by vertical mixing with deep water and the deep water loses most of its alkalinity by mixing with Circumpolar and Antarctic Intermediate Water in the South Pacific. The alkalinity distribution can be explained only by local sources in the water column. Calcium carbonate, like silicate, seems to dissolve primarily in the deep water.     

联合卫星测高和模式资料研究海水热含量变化

本文在考虑洋底压力变化的情况下,利用2003~2008年融合多颗卫星的测高资料估计了全球和中国近海的海水热含量变化.顾及洋底压力(OBP)变化以及热膨胀系数随海水深度变化的影响,提出的改进方法提高了对中高纬度地区热含量变化的估算精度.在OBP变化较为明显的北太平洋区域I(30°N~50°N,170°E~190°E)、南印度洋区域II(40°S~60°S,100°E~120°E)和南太平洋区域III(40°S~60°S,100°W~120°W),改进方法的均方差较传统方法分别降低了16.3%、60.5%和48.4%.同时研究表明,卫星测高的精度以及盐度变化是影响中高纬度地区热含量估计精度的重要因素.在中国近海地区,东海和黄海的热含量主要表现为周年变化;南海区域的热含量除周年变化外,还存在半周年项和年际变化项,且南海的海水热含量近年有增加的趋势.     

Characterization of Individual Rock Magnetic Components by Analysis of Remanence Curves, 1. Unmixing Natural Sediments

Natural sediments are a complex mixture of magnetic minerals with different origins and different geochemical history, each of which is called a magnetic component. Magnetic components practically never occur in isolated form, and their characterization using bulk magnetic measurements relies on the individuation of the systematic variation of some parameters within a large group of samples. These variations can be interpreted either as a mixing trend or as the result of natural processes, which affect the physical and chemical properties of the magnetic particles. An alternative approach is offered by the analysis of magnetization curves using model functions, which are supposed to represent the magnetic properties of individual components. The success of this approach relies on (1) the choice of model functions that can reproduce the natural properties of a component with sufficient accuracy by varying a minimum number of parameters and (2) on very precise and accurate measurements, which are necessary to overcome the extreme sensitivity of the method to noise. In this paper, the analysis of remanent magnetization curves proposed by Egli (2003) is applied to a large set of representative sediments from the most variable environments and to a set of artificial magnetite samples. Despite the variety of materials and natural processes involved in the formation of these sediments, seven groups of magnetic components with well-defined and consistent properties could be identified. It has been found that both lacustrine and marine sediments contain two magnetically distinct groups of magnetosomes, which react differently to changes of the redox potential. The effects of some natural processes, such as weathering, reductive dissolution and transport could be observed on the individual components.     

现代黄河三角洲沉积物磁性地层年代框架及环境磁学研究

本文对黄河三角洲Z07孔沉积物进行了系统的磁性地层学和环境磁学研究.通过结合沉积速率和古地磁长期变化数据,我们为该孔建立了较为精确可信的年代框架(1999-03—2006-06A.D.).环境磁学结果表明黄河三角洲沉积物与中国黄土的磁学特征相似,主要载磁矿物为单畴(SD)磁铁矿,超顺磁颗粒(SP)含量也较高.整体上,该孔沉积物磁学参数的变化主要受粒度和含量控制.岩芯磁性参数在2003年前后发生了系统变化.我们认为,黄河自2002年起进行调水调沙工程,黄河下游河道冲刷加剧,形成新的物质来源,河流输入的沉积物粒度变粗,输沙量增加,这一新的物质来源是造成Z07钻孔磁性参数发生显著变化的主因.     

Regional and interannual variability of ecosystem dynamics in the Southern Ocean

To investigate regional and interannual variability of the ecosystem in the Southern Ocean, a coupled circumpolar ice–ocean–plankton model has been developed. The ice–ocean component (known as BRIOS-2) is based on a modified version of the s-coordinate primitive equation model (SPEM) coupled to a dynamic–thermodynamic sea-ice model. The biological model (BIMAP) comprises two biogeochemical cycles – silica and nitrogen – and a prognostic iron compartment to include possible effects of micronutrient limitation. Simulations with the coupled ice–ocean–plankton model indicate that the physical–biological interaction is not limited to the effect of a varying surface mixed-layer depth. In the Pacific sector, large anomalies in winter mixed-layer depth cause an increased iron supply and enhance primary production and plankton biomass in the following summer, whereas in the Atlantic sector variability in primary production is caused mainly by fluctuations of oceanic upwelling. Thus, the Antarctic Circumpolar Wave (ACW) induces regional oscillations of phytoplankton biomass in both sectors, but not a propagating signal. Furthermore, interannual variability in plankton biomass and primary production is strong in the Coastal and Continental Shelf Zone and the Seasonal Ice Zone around the Antarctic continent. Interannual variability induced by the ACW has large effects on the regional scale, but the associated variability in biogenic carbon fluxes is small compared to the long-term carbon sequestration of the Southern Ocean.     

一阶反转曲线（FORC）图的原理及应用实例

自然样品中的磁性矿物携带着丰富的环境演化信息．然而在一般情况下,自然样品的磁性是其含有的诸多磁性矿物的综合反映．为了分离这些磁信息,近年来发展了一种新的岩石磁学方法：一阶反转曲线（FORC）图．该方法不但可以确定磁性矿物矫顽力的分布以及磁性矿物颗粒之间磁相互作用的强弱,而且还可以帮助区分磁性矿物的种类和磁畴状态．本文首先详细介绍该方法的基本原理和其物理意义,在此基础上,给出了一个应用FORC图确定含铝的钛磁铁矿玄武岩样品中磁性矿物在加热过程发生转变的研究实例．在两个温度下的FORC图密度分布差的结果表明,这种新方法可以灵敏地检测样品中微弱的磁性矿物改变,因此在岩石磁学、环境磁学和古地磁学研究中具有很好的应用前景．     

Constraining the dating of late Quaternary marine sediment records from the Scotia Sea (Southern Ocean)

In Southern Ocean sediments south of the Antarctic Polar Front, the scarcity of calcareous microfossils hampers the development of sediment chronologies based on radiocarbon dating and oxygen isotope stratigraphy established from carbonate. In this study, radiometric dating, magnetic susceptibility (MS), biogenic opal content, diatom abundance fluctuation, and paleomagnetic information were investigated on a north–south transect of central Scotia Sea sediment cores to verify their reliability as stratigraphic tools in the study area. Radiocarbon dating on organic carbon humic acid fraction can be used to establish the stratigraphy of upper core sections, but regional comparison and correlation are needed to verify a possible bias by fossil carbon contamination. For the long-term stratigraphy, MS, which can be correlated to the Antarctic ice core dust/climate signal, represents the most valuable parameter. Fine-grained single domain magnetite, probably of biogenic origin, makes a significant contribution to the interglacial MS signal, while major contributions from detrital material affect the glacial MS record. The core from the southern Scotia Sea contains significant proportions of biogenic magnetite also in glacial sediments, suggesting depositional environments different from those of the northern Scotia Sea. Our data suggest low contributions of high-coercive minerals to the overall magnetic intensity of glacial and interglacial Scotia Sea sediments, which excludes dust as a main source of the magnetic signal. Opal content can be used to distinguish between cold and warm intervals for the past 300 thousand years. Abundance fluctuation patterns of diatom species Fragilariopsis kerguelensis and Eucampia antarctica are useful stratigraphic tools for periods back to Marine Isotope Stage (MIS) 6. The Mono Lake geomagnetic excursion is identified in Scotia Sea sediments for the first time. Possible correlations of ash layers are suggested between Scotia Sea sediments and East Antarctic ice cores. They have potential to serve as additional age markers for further studies in this area.