Sampling the Chemistry of Shallow Aquifer Systems — A Case Study

Pumped waters from 14 Pennsylvania wells, located in shallow sandstone, siltstone and shale aquifers, were continuously monitored for dissolved oxygen (D. O.), nitrate (NO₃), pH, electrical conductivity (EC) and water temperature in a discharge manifold at the well head. The amount of pumping or purging required to stabilize these parameter readings varied by well site and parameter being analyzed. However, the purging required was generally greatest for D. O. and least for water temperature where: D. O. < NO₃ pH < EC < water temperature. Wells located near the siltstone-shale interface generally required far more purging than did wells located elsewhere. Although parameter stability was often achieved within purging one bore volume, the complexity, diversity, and variability in the data and these well-ground water systems, suggest that no single purging rule is appropriate. Instead, the extent of purging required before sampling these shallow aquifers should be determined by incorporating on-site monitoring of target or related parameters into the purging process.
From a sampling perspective, the relationship between NO₃ and D. O. concentrations during purging were analyzed relative to aquifer type. For most wells located in sandstone or siltstone, NO₃ concentrations remained relatively constant during purging irrespective of changes in D. O. For most wells located in shale, these two were positively and similarly correlated, suggesting that a general relationship exists.     

Reduction of Nitrate Loadings to Ground Water

Non-point source pollution of ground water systems has become a national concern in recent years. Researchers and regulatory agencies are investigating the source and processes of the contamination. Agricultural best management practices (BMPs) traditionally developed to reduce non-point source pollution of surface water resources are being investigated for their impact on ground water quality. This study used the CREAMS model to simulate the long-term effects of seven different BMPs on nitrate nitrogen (NO₃-N) loadings to a shallow, unconfined ground water system. Two representative watersheds, 5.8 and 8.9 hectares (14.3 and 22 acres) in area, in the Coastal Plain physiographic region of Maryland were selected for study. Soils in these watersheds belong to the Matapeake silt loam series and have moderate infiltration capacity. Results from this study indicated that BMPs used in conjunction with winter cover (barley) reduced NO₃-N leaching to the ground water system. It was also found that turfgrass reduced surface losses of water and nitrogen, but increased leaching losses of water and NO₃-N significantly. All of the BMPs simulated in this study resulted in leachate NO₃-N concentrations exceeding 10 ppm, the U.S. EPA health standard for public drinking water, indicating a need for alternate practices for reducing nitrate leaching.     

Using Alternate Pumping and Cooperative Game Theory to Reduce Sea Water Intrusion

In this article, alternate pumping is studied as a means used to reduce the salinity concentration in coastal aquifers, pumped using a system of wells. This approach has been applied to a hypothetical confined coastal aquifer. Flow has been modeled, using SEAWAT. Two strategies are proposed based on cooperative game theory, to promote alternate pumping. In both strategies an external player will compensate the users that will pump during an unpopular pumping period. In the first strategy it is supposed that this external player aims at protecting a critical well, e.g. a municipal well, reducing its maximum salinity concentration by pumping alternately. In the second strategy proposed, the target is to reduce the overall salinity of the water pumped by the wells. In applying the cooperative game theory, the Shapley value is used to distribute the benefits of cooperation between the players (well users), according to their marginal contribution. Overall, well users can reduce sea water intrusion by cooperatively changing their pumping time schedules. The game theoretical model developed is a useful tool to promote cooperation toward this direction. The methods applied in the hypothetical aquifer, can be tested in actual aquifers to reduce sea water intrusion.     

Migration of induced-infiltrated stream water into nearby aquifers due to seasonal ground water withdrawal

Analysis of stream-aquifer interaction due to ground water extraction has traditionally focused on the determination of the amount of water depleted in the stream. Less attention has been paid to the movement of infiltrated stream water inside aquifer, particularly for agricultural areas. This paper presents a method of using particle-tracking techniques to evaluate the transport of the leaked stream water in the nearby aquifers. Simple stream-aquifer conditions are used to demonstrate the usefulness of the analysis. Travel times, pathlines, and influence zones of stream water were determined between a stream and nearby pumping wells for seasonal ground water extraction areas. When water quantity is a concern, the analyses provide additional information about stream depletion; when water quality is an issue, they offer information for wellhead protection. Analyses were conducted for transient conditions, and both pumping and nonpumping periods were considered. According to the results from the simulation examples, migration of infiltrated stream water into the nearby aquifers is generally slow and most infiltrated stream water does not arrive at the pumping well at the end of a 90-day irrigation season. Infiltrated stream water may remain in the aquifer for several years before arriving at the pumping well. For aquifers with a regional hydraulic gradient toward streams, part of the infiltrated stream water may discharge back to streams during a recovery period.     

Effects of Improper Characterization of Aquifer Thickness on Estimates of Hydraulic Conductivity from Pumping Tests

Pumping test data for surficial aquifers are commonly analyzed under the assumption that the base of the aquifer corresponds to the bottom of the test wells (i.e., the aquifer is truncated). This practice can lead to inaccurate hydraulic conductivity estimates, resulting from the use of low saturated thickness values with transmissivity estimates, and not accounting for the effects of partially penetrating wells. Theoretical time-drawdown data were generated at an observation well in a hypothetical unconfined aquifer for various values of saturated thickness and were analyzed by standard curve-matching techniques. The base of the aquifer was assumed to be the bottom of the pumping and observation wells. The overestimation of horizontal hydraulic conductivity was found to be directly proportional to the error in assumed saturated thickness, and to the (actual) ratio of vertical to horizontal hydraulic conductivity (K_v/K_h). Inaccurately high estimates of hydraulic conductivity obtained by aquifer truncation can lead to overestimates of ground water velocity and contaminant plume spreading, narrow capture zone configuration estimates, and overestimates of available ground water resources.     

Associations Between Rural Land Uses and Ground Water Quality in the Ogallala Aquifer, Northwest Texas

Recent nitrate, chloride, and bromide concentrations were studied in the Ogallala Aquifer of northwest Texas. The study included 361 wells with a median depth of 92 m in a rural area dominated by agricultural activity and oil and gas production. Only five observations surpassed the 44.3 mg/L standard for nitrate (10 mg/L NO₃-N). Four other observations, and one from the preceding set, exceeded the secondary standard of 250 mg/L for chloride. Maximum concentrations were 91.2 mg/L, 1530 mg/L, and 0.70 mg/L for nitrate, chloride, and bromide, respectively. Chloride/bromide ratios covered a broad range, from 30.4 to 10930, but medians were < 160 for each of two years analyzed. There were statistically significant correlations between nitrate and chloride, and chloride and well depth. Results of this study suggest that agricultural activity has locally impacted ground water in north-west Texas. Regionally, low aquifer recharge rates have curtailed ground water contamination from potentially adverse land uses.     

Modeling of Contaminant Movement Near Pumping Wells: Saturated-Unsaturated Flow with Particle Tracking

A transient axisymmetric saturated-unsaturated numerical flow model was coupled with a particle tracking model to investigate the movement of contaminants when a shallow unconfined aquifer is pumped at a constant rate. The particle tracking model keeps track of locations and masses of solutes in the aquifer, and the time of capture by the well. At the end of each time-step the flow model solves the Richard's equation for the hydraulic head distribution from which elemental velocities are calculated. Solutes are then displaced for a period equivalent to the time-step using both the magnitude and direction of the elemental velocities. Numerical experiments were performed to investigate effluent concentrations in wells with screens of different length and in different positions relative to zones of stratified contamination. At early times of pumping the effluent concentrations were similar to the concentrations adjacent to the well screen, but at late times, the concentrations approached the vertically averaged concentration in the aquifer. Time to attain the vertically averaged concentration was determined by the well geometry, initial location of the contaminant plume in relation to the well screen, and hydraulic properties of the aquifer. The results are consistent with the hydraulics of flow to a pumping well and of particular importance, they demonstrate that short-term pump tests could give erroneous design concentrations for pump-and-treat systems. The model provides a means of quantifying arrival times and mixing ratios. It could therefore provide a useful means of designing production wells in aquifers with stratified contamination and more efficient recovery systems for aquifer remediation.     

Control of Ground Water Contamination at an Active Uranium Mill

Seepage from tailings ponds associated with an active uranium mill in Utah has resulted in contamination of ground water contained in the Dakota-Burro Canyon Formation. This aquifer is used in the area as a supply for domestic and industrial wells.
Results of very low-frequency electromagnetic surveys and ground water quality investigations at the site indicated that the flow of ground water and contaminants is primarily fracture-controlled. Pumping tests were conducted to determine the hydraulic characteristics of the fractured system. The extent of contaminant migration was then determined using an analytical model of transport in fractured aquifers.
Based on these investigations, a plan was designed to control future and remediate past ground water contamination. This plan consists of pumping from a single well intersecting the main fracture that transports contaminants off the site. The effectiveness of the plan was analytically modeled, taking account of the anisotropy of the ground water system. Subsequent monitoring of water levels in the area indicates that the plan has been effective since its inception in November 1983.     

Estimating hydraulic properties using a moving-model approach and multiple aquifer tests

A new method was developed for characterizing geohydrologic columns that extended >600 m deep at sites with as many as six discrete aquifers. This method was applied at 12 sites within the Southwest Florida Water Management District. Sites typically were equipped with multiple production wells, one for each aquifer and one or more observation wells per aquifer. The average hydraulic properties of the aquifers and confining units within radii of 30 to >300 m were characterized at each site. Aquifers were pumped individually and water levels were monitored in stressed and adjacent aquifers during each pumping event. Drawdowns at a site were interpreted using a radial numerical model that extended from land surface to the base of the geohydrologic column and simulated all pumping events. Conceptually, the radial model moves between stress periods and recenters on the production well during each test. Hydraulic conductivity was assumed homogeneous and isotropic within each aquifer and confining unit. Hydraulic property estimates for all of the aquifers and confining units were consistent and reasonable because results from multiple aquifers and pumping events were analyzed simultaneously.     

A Geostatistically Based Ground Water Monitoring Study of Nonpoint Source No3--N Concentrations

Geostatistical interpretations of ground water monitoring data are presented to define the spatial distributions of NO₃^--N in the ground water at two demonstration test sites in the Idaho Snake River Plain. Sequential Gaussian simulation was used to delineate monthly ground water NO₃^--N changes during and after implementation of a prescribed crop rotation at test site 1. Trend surface analyses were used to illustrate monthly ground water NO₃^--N changes during and after a prescribed irrigation practice was implemented at test site 2. These evaluations suggest that geostatistically based ground water monitoring can be effective in the delineation of changes in ground water quality in shallow, unconfined aquifers in agricultural areas such as those in southern Idaho. Geostatistical methods showed spatial and temporal changes in ground water NO₃^--N inferred to be a result of the agricultural practices implemented.     

Electromagnetic‐Induction Logging to Monitor Changing Chloride Concentrations

Water from the San Joaquin Delta, having chloride concentrations up to 3590 mg/L, has intruded fresh water aquifers underlying Stockton, California. Changes in chloride concentrations at depth within these aquifers were evaluated using sequential electromagnetic (EM) induction logs collected during 2004 through 2007 at seven multiple‐well sites as deep as 268 m. Sequential EM logging is useful for identifying changes in groundwater quality through polyvinyl chloride‐cased wells in intervals not screened by wells. These unscreened intervals represent more than 90% of the aquifer at the sites studied. Sequential EM logging suggested degrading groundwater quality in numerous thin intervals, typically between 1 and 7 m in thickness, especially in the northern part of the study area. Some of these intervals were unscreened by wells, and would not have been identified by traditional groundwater sample collection. Sequential logging also identified intervals with improving water quality—possibly due to groundwater management practices that have limited pumping and promoted artificial recharge. EM resistivity was correlated with chloride concentrations in sampled wells and in water from core material. Natural gamma log data were used to account for the effect of aquifer lithology on EM resistivity. Results of this study show that a sequential EM logging is useful for identifying and monitoring the movement of high‐chloride water, having lower salinities and chloride concentrations than sea water, in aquifer intervals not screened by wells, and that increases in chloride in water from wells in the area are consistent with high‐chloride water originating from the San Joaquin Delta rather than from the underlying saline aquifer.     

Vertical Contaminant Profiling of Volatile Organic* in a Deep Fractured Basalt Aquifer

Volatile organic compounds delected in ground water from wells at Test Area North (TAN) at the Idaho National Engineering Laboratory (INEL) prompted RCRA facility investigations in 1989 and 1990 and a CERCLA-driven RI/FS in 1992. In order to address ground water treatment feasibility, one of the main objectives, of the 1992 remedial investigation was to determine the vertical extent of ground water contamination, where the principle contaminant, of concern is trichloroethylene (TCE). It was hypothesized that a sedimentary interbed at depth in the fractured basalt aquifer could be inhibiting vertical migration of contaminants to lower aquifers. Due to the high cost of drilling and installation of ground water monitoring wells at this facility (greater than $100,000 per well), a real time method was proposed for obtaining and analyzing ground water samples during drilling to allow accurate placement of well screens in zones of predicted VOC contamination. This method utilized an inflatable pump packer pressure transducer system interfaced with a datalogger and PC at land surface. This arrangement allowed for real lime monitoring of hydraulic head above and below the packer to detect leakage around the packer during pumping and enabled collection of head data during pumping for estimating hydrologic properties. Analytical results were obtained in about an hour from an on-site mobile laboratory equipped with a gas chromalograplvmass spectrometer (GC/MS). With the hydrologic and analytical results in hand, a decision was made to either complete the well or continue drilling to the next test zone. In almost every case, analytical results of ground water samples taken from the newly installed wells closely replicated the water quality of ground water samples obtained through the pump packer system.     

Identifying Aquifer Type in Fractured Rock Aquifers using Harmonic Analysis

Determining aquifer type, unconfined, semi‐confined, or confined, by drilling or performing pumping tests has inherent problems (i.e., cost and complex field issues) while sometimes yielding inconclusive results. An improved method to cost‐effectively determine aquifer type would be beneficial for hydraulic mapping of complex aquifer systems like fractured rock aquifers. Earth tides are known to influence water levels in wells penetrating confined aquifers or unconfined thick, low‐porosity aquifers. Water‐level fluctuations in wells tapping confined and unconfined aquifers are also influenced by changes in barometric pressure. Harmonic analyses of water‐level fluctuations of a thick (～1000 m) carbonate aquifer located in south‐central Oklahoma (Arbuckle‐Simpson aquifer) were utilized in nine wells to identify aquifer type by evaluating the influence of earth tides and barometric‐pressure variations using signal identification. On the basis of the results, portions of the aquifer responded hydraulically as each type of aquifer even though there was no significant variation in lithostratigraphy. The aquifer type was depth dependent with confined conditions becoming more prevalent with depth. The results demonstrate that harmonic analysis is an accurate and low‐cost method to determine aquifer type.     

A method for evaluating horizontal well pumping tests

Predicting the future performance of horizontal wells under varying pumping conditions requires estimates of basic aquifer parameters, notably transmissivity and storativity. For vertical wells, there are well-established methods for estimating these parameters, typically based on either the recovery from induced head changes in a well or from the head response in observation wells to pumping in a test well. Comparable aquifer parameter estimation methods for horizontal wells have not been presented in the ground water literature. Formation parameter estimation methods based on measurements of pressure in horizontal wells have been presented in the petroleum industry literature, but these methods have limited applicability for ground water evaluation and are based on pressure measurements in only the horizontal well borehole, rather than in observation wells. This paper presents a simple and versatile method by which pumping test procedures developed for vertical wells can be applied to horizontal well pumping tests. The method presented here uses the principle of superposition to represent the horizontal well as a series of partially penetrating vertical wells. This concept is used to estimate a distance from an observation well at which a vertical well that has the same total pumping rate as the horizontal well will produce the same drawdown as the horizontal well. This equivalent distance may then be associated with an observation well for use in pumping test algorithms and type curves developed for vertical wells. The method is shown to produce good results for confined aquifers and unconfined aquifers in the absence of delayed yield response. For unconfined aquifers, the presence of delayed yield response increases the method error.     

Optimal and sustainable extraction of groundwater in coastal aquifers

Four examples are investigated for the optimal and sustainable extraction of groundwater from a coastal aquifer under the threat of seawater intrusion. The objectives and constraints of these management scenarios include maximizing the total volume of water pumped, maximizing the profit of selling water, minimizing the operational and water treatment costs, minimizing the salt concentration of the pumped water, and controlling the drawdown limits. The physical model is based on the density-dependent advective-dispersive solute transport model. Genetic algorithm is used as the optimization tool. The models are tested on a hypothetical confined aquifer with four pumping wells located at various depths. These solutions establish the feasibility of simulating various management scenarios under complex three-dimensional flow and transport processes in coastal aquifers for the optimal and sustainable use of groundwater.     

Temporal changes in the vertical distribution of flow and chloride in deep wells

The combination of flowmeter and depth-dependent water-quality data was used to evaluate the quantity and source of high-chloride water yielded from different depths to eight production wells in the Pleasant Valley area of southern California. The wells were screened from 117 to 437 m below land surface, and in most cases, flow from the aquifer into the wells was not uniformly distributed throughout the well screen. Wells having as little as 6 m of screen in the overlying upper aquifer system yielded as much as 50% of their water from the upper system during drought periods, while the deeper parts of the well screens yielded 15% or less of the total yield of the wells. Mixing of water within wells during pumping degraded higher-quality water with poorer-quality water from deeper depths, and in some cases with poorer-quality water from the overlying upper aquifer system. Changes in the mixture of water within a well, resulting from changes in the distribution of flow into the well, changed the quality of water from the surface discharge of wells over time. The combination of flowmeter and depth-dependent water quality data yielded information about sources of high-chloride water to wells that was not available on the basis of samples collected from nearby observation wells. Changing well design to eliminate small quantities of poor-quality water from deeper parts of the well may improve the quality of water from some wells without greatly reducing well yield.     

Fate of MTBE Relative to Benzene in a Gasoline-Contaminated Aquifer (1993–98)

Methyl tert -butyl ether (MTBE) and benzene have been measured since 1993 in a shallow, sandy aquifer contaminated by a mid-1980s release of gasoline containing fuel oxygenates. In wells downgradient of the release area, MTBK was detected before benzene, reflecting a chromatographic-like separation of these compounds in the direction of ground water flow. Higher concentrations of MTBE and benzene were measured in the deeper sampling ports of multilevel sampling wells located near the release area, and also up to 10 feet (3 m) below the water table surface in nested wells located farther from the release area. This distribution of higher concentrations at depth is caused by recharge events that deflect originally horizontal ground water flowlines. In the laboratory, microcosms containing aquifer material incubated with uniformly labeled ¹⁴C-MTBE under aerobic and anaerobic. Fe(III)-reducing conditions indicated a low but measurable biodegradation potential (<3%¹⁴C-MTBW as ¹⁴CO₂) after a seven-month incubation period, Tert -butyl alcohol (TBA), a proposed microbial-MTBE transformation intermediate, was detected in MTBE-contaminated wells, but TBA was also measured in unsaturated release area sediments. This suggests that TBA may have been present in the original fuel spilled and does not necessarily reflect microbial degradation of MTBE. Combined, these data suggest that milligram per liter to microgram per liter decreases in MTBE concentrations relative to benzene are caused by the natural attenuation processes of dilution and dispersion with less-contaminated ground water in the direction of flow rather than biodegradation at this point source gasoline release site.     

The unusual and large drawdown response of buried-valley aquifers to pumping

The buried-valley aquifers that are common in the glacial deposits of the northern hemisphere are a typical case of the strip aquifers that occur in many parts of the world. Pumping from a narrow strip aquifer leads to much greater drawdown and much more distant drawdown effects then would occur in a sheet aquifer with a similar transmissivity and storage coefficient. Widely used theories for radial flow to wells, such as the Theis equation, are not appropriate for narrow strip aquifers. Previously published theory for flow to wells in semiconfined strip aquifers is reviewed and a practical format of the type curves for pumping-test analysis is described. The drawdown response of strip aquifers to pumping tests is distinctive, especially for observation wells near the pumped well. A case study is presented, based on extensive pumping test experience for the Estevan Valley Aquifer in southern Saskatchewan, Canada. Evaluation of groundwater resources in such buried-valley aquifers needs to take into account the unusually large drawdowns in response to pumping.     

Vulnerability of a public supply well in a karstic aquifer to contamination

To assess the vulnerability of ground water to contamination in the karstic Upper Floridan aquifer (UFA), age-dating tracers and selected anthropogenic and naturally occurring compounds were analyzed in multiple water samples from a public supply well (PSW) near Tampa, Florida. Samples also were collected from 28 monitoring wells in the UFA and the overlying surficial aquifer system (SAS) and intermediate confining unit located within the contributing recharge area to the PSW. Age tracer and geochemical data from the earlier stage of the study (2003 through 2005) were combined with new data (2006) on concentrations of sulfur hexafluoride (SF₆), tritium (³H), and helium-3, which were consistent with binary mixtures of water for the PSW dominated by young water (less than 7 years). Water samples from the SAS also indicated mostly young water (less than 7 years); however, most water samples from monitoring wells in the UFA had lower SF₆ and ³H concentrations than the PSW and SAS, indicating mixtures containing high proportions of older water (more than 60 years). Vulnerability of the PSW to contamination was indicated by predominantly young water and elevated nitrate-N and volatile organic compound concentrations that were similar to those in the SAS. Elevated arsenic (As) concentrations (3 to 19 μg/L) and higher As(V)/As(III) ratios in the PSW than in water from UFA monitoring wells indicate that oxic water from the SAS likely mobilizes As from pyrite in the UFA matrix. Young water found in the PSW also was present in UFA monitoring wells that tap a highly transmissive zone (43- to 53-m depth) in the UFA.     

Hydrochemistry of groundwaters in a spa area of Korea: an implication for water quality degradation by intensive pumping

A geochemical study was carried out in a small spa area (Onyang Spa, Korea) where intensive pumping of deep thermal groundwater (1 300 000 m³ year⁻¹) is taking place. This has caused the deep fractures to lose their artesian pressure and the upper shallow fractures have been encroached by shallow, cold waters. To quantify the influence of long‐term heavy pumping on the quality of the geothermal water, groundwater sampling and chemical analysis, water‐level measurement, and well loggings were performed for the selected deep thermal wells and shallow cold wells. Chemical analysis results indicate a big contrast in water chemistry and origins between the two water types. Shallow groundwater shows a wider concentration ranges in solutes that are closely related to human activity, illustrating the water's vulnerability to contamination near the land surface. Plots of water chemistry as a function of fluoride reveal that the quality of the thermal water was greatly influenced by the shallow, cold groundwater and that intensive pumping of the deep thermal groundwater has caused the introduction of shallow groundwater into the deeper fractures. Although the deep and the shallow fractures were piezometrically separated to some extent, a mixing model based on fluoride and nitrate indicated that the cold‐water fractions in the thermal wells are up to 50%. This suggests that the thermal water is faced with water quality degradation by the downward flow of the shallow, cold water. Restriction on the total of all the pumpage permits per unit area is suggested to restore the artesian pressure of the deep thermal aquifer and to prevent cold‐water intrusion in the study area. Copyright © 2004 John Wiley & Sons, Ltd.