Water interaction with MgCl<Subscript>2</Subscript>×6H<Subscript>2</Subscript>O and NaCl surfaces: measurements of the uptake coefficient

The uptake of water vapor on MgCl₂×6H₂O and NaCl salt dry solid films was studied over the temperature range 240 to 340 K and at 1 Torr pressure of helium using a flow reactor coupled to a modulated molecular beam mass spectrometer. The H₂O to salt uptake data were obtained from the kinetics of H₂O loss on salt coated Pyrex rods. The following Arrhenius expression was obtained for the initial uptake coefficient of H₂O on MgCl₂×6H₂O films: γ ₀ (MgCl₂) = (6.5 ± 1.0) × 10⁻⁶ exp[(470 ± 40)/T] (calculated with specific BET surface area, quoted uncertainties are 1σ statistical). The rate of H₂O adsorption on NaCl was found to be much lower than on MgCl₂×6H₂O, and only an upper limit was determined for the corresponding uptake coefficient: γ (NaCl) ≤ 5.6 × 10⁻⁶ at T = 300 K. The results show that the rate of H₂O adsorption to salt surfaces is drastically dependent on the salt sample composition.     

Influence of the atmospheric conditions on PM<Subscript>10</Subscript> concentrations in Poznań, Poland

This study investigates atmospheric conditions’ influence on the mean and extreme characteristics of PM₁₀ concentrations in Poznań during the period 2006–2013. A correlation analysis was carried out to identify the most important meteorological variables influencing the seasonal dynamics of PM₁₀ concentrations. The highest absolute correlation values were obtained for planetary boundary layer height (r = ?0.57), thermal (daily minimum air temperature: r = ?0.51), anemological (average daily wind speed: r = ?0.37), and pluvial (precipitation occurrence: r = ?0.36) conditions, however the highest correlations were observed for temporal autocorrelations (1 day lag: r = 0.70). As regulated by law, extreme events were identified on the basis of daily threshold value i.e. 50 μg m^?3. On average, annually there are approximately 71.3 days anywhere in the city when the threshold value is exceeded, 46.6 % of those occur in winter. Additionally, 83.7 % of these cases have been found to be continuous episodes of a few days, with the longest one persisting for 22 days. The analysis of the macro-scale circulation patterns led to the identification of an easy-to-perceive seasonal relations between atmospheric fields that favour the occurrence of high PM₁₀ concentration, as well as synoptic situations contributing to the rapid air quality improvement. The highest PM₁₀ concentrations are a clear reaction to a decrease in air temperature by over 3 °C, with simultaneous lowering of PBL height, mean wind speed (by around 1 m s^?1) and changing dominant wind directions from western to eastern sectors. In most cases, such a situation is related to the expansion of a high pressure system over eastern Europe and weakening of the Icelandic Low. Usually, air quality conditions improve along with an intensification of westerlies associated with the occurrence of low pressure systems over western and central Europe. Opposite relations are distinguishable in summer, when air quality deterioration is related to the inflow of tropical air masses originating over the Sahara desert.     

Two years observations on the diurnal evolution of coastal atmospheric boundary layer features over Thiruvananthapuram (8.5<Superscript>∘</Superscript> N, 76.9<Superscript>∘</Superscript> E), India

The atmospheric boundary layer (ABL) over a given coastal station is influenced by the presence of mesoscale sea breeze circulation, together with the local and synoptic weather, which directly or indirectly modulate the vertical thickness of ABL (z _ABL). Despite its importance in the characterization of lower tropospheric processes and atmospheric modeling studies, a reliable climatology on the temporal evolution of z _ABL is not available over the tropics. Here, we investigate the challenges involved in determination of the ABL heights, and discuss an objective method to define the vertical structure of coastal ABL. The study presents a two year morphology on the diurnal evolution of the vertical thickness of sea breeze flow (z _SBF) and z _ABL in association with the altitudes of lifting condensation level (z _LCL) over Thiruvananthapuram (8.5^° N, 76.9^° E), a representative coastal station on the western coastline of the Indian sub-continent. We make use of about 516 balloon-borne GPS sonde measurements in the present study, which were carried out as part of the tropical tropopause dynamics field experiment under the climate and weather of the sun-earth system (CAWSES)–India program. Results obtained from the present study reveal major differences in the temporal evolution of the ABL features in relation to the strength of sea breeze circulation and monsoonal wind flow during the winter and summer monsoon respectively. The diurnal evolution in z _ABL is very prominent in the winter monsoon as against the summer monsoon, which is attributed to the impact of large-scale monsoonal flow over the surface layer meteorology. For a majority of the database, the z _LCL altitudes are found to be higher than that of the z _ABL, indicating a possible decoupling of the ABL with the low-level clouds.     

前期台风擦边过,东北部暴雨成灾;后期强台风登陆,西南部风灾惨重

第三季度影响本省的主要天气系统是热带气旋。今年的特点是影响本省的台风个数少，但破坏力强，造成灾害惨重。1前期台风“江边”过，东北日暴雨成灾。今年以来西北太平洋面和南海海面生成的热带气旋个数偏少，到9月底为止仅有ZI个编号（常年28个），登陆或严重影响广东的热带气旋仅有3个（常年5个）。今年影响广东的台风比较异常，初台比常年迟到47天；至8月份无台风登陆我省；7～8月仅有5个编号热带气旋擦边过：9606号热带风暴7月22日在海南万宁登陆，9607号台风7月27日在福建晋江登陆，9608号台风8月1日在用建福清登陆，9610号热带风合8…