2006～2008年重庆大气降水δD和δ18O特征初步分析

大气降水稳定同位素组成受到温度、蒸发、水汽源地等多种因素的复杂影响,在不同时间和不同地区具有很大差异.通过分析2006~2008年间重庆雨水样品的δD和δ18O,初步建立了当地的大气降水线方程.当地的大气降水稳定同位素组成在不同季节变化明显:夏季降水中的稳定同位素值普遍偏轻,而冬季降水中稳定同位素值普遍偏重.水汽来源是控制当地大气降水稳定同位素组成的最重要原因,而蒸发作用等是控制短期次降水事件中雨水稳定同位素组成的重要影响因素.     

贵阳市大气降水中的重金属特征

采集了贵阳市2003年9月—2004年10月的72场降雨样品,用ICP-MS测定了雨水溶解态的Pb、Zn、Cu、Fe、Mn、Al、Sr等重金属离子,阐述了贵阳市降雨的重金属含量特征,并分析了重金属的来源及变化规律。结果表明,贵阳市雨水重金属含量高,Fe、Mn、Cu、Pb、Zn均高于地表水,雨水的重金属含量受人为因素影响明显,燃煤及汽车尾气是雨水重金属的主要来源,为评价贵阳市大气中的重金属污染提供了有力的证据。     

城市降水径流的污染来源与排放特征研究进展

综述了城市地表径流污染的成因、来源和排放特征的研究.城市降水径流污染来自3个方面:降水、城市地表和排水系统.其中,城市地表和排水系统是城市降水径流污染的主要来源.在具合流制排水系统的城市,20%~60%的径流污染(SS、COD和BOD₅)来自排水系统.在一次降雨过程中,城市降雨径流污染的排放一般存在初期冲刷效应,径流中污染物浓度的峰值一般提前于径流的峰值.但是由于影响初期冲刷效应的因素多而随机,使得初期冲刷出现的频率和程度存在明显的差异,而且很难建立初期冲刷与降雨特征和流域特征的通用关系.     

气象因子对洪湖有机氯农药大气沉降的影响

对洪湖进行了为期一年(2005年2月-2006年2月)的大气沉降采样,采用被动大气采样方法对大气沉降中的有机氯农药进行了分析,得到该年通过大气沉降向洪湖输入有机氯农药9.77 kg,其中大气颗粒态沉降量为2.74 kg,湿沉降量为7.03kg。大气沉降中六六六(HCHs)和滴滴涕(DDTs)的沉降量最大。将所获气象数据和各季度有机氯农药大气沉降量进行了相关性分析,结果表明:①气象因子对湿沉降的相关性较大气颗粒态沉降的明显,其中降雨量、平均温度、平均风速与湿沉降量的相关系数最高;②风速、温度、日照对有机氯农药在气相溶解态和大气颗粒态分配影响强烈,而温度是决定有机氯农药在大气中以何种形式沉降的主要因素;③由于降雨的前锋时段具备有效的强沉降能力,使得连续性降雨频次对大气沉降影响强烈。     

成都经济区天降水与下渗水元素地球化学特征及土壤元素输入输出通量

论文研究了成都经济区天降水和下渗水中元素含量、在农田耕层中的输入输出通量及其影响因素.研究表明,研究区雨水中含有大量SO2-4、NO-3等酸性物质,雨水中SO2-4 >NO-3>Cl-.雨水中Ca2 和NH 4含量最高,且NH 4>Ca2 >K >Na >Mg2 .雨水的pH与阴、阳离子摩尔浓度差值具有显著相关性.下渗水中以Ca2 为主要阳离子,且Ca2 >Na >Mg2 >K >NH 4;HCO-3为主要阴离子,且HCO-3>NO-3>SO2-4>Cl->F-,下渗水pH与阳、阴离子摩尔浓度差值具有显著相关性.不同地区雨水中Pb>As>Cd>Se>Hg,下渗水中Pb>As>Se>Cd>Hg,因此,Cd、Pb、Se和Hg等元素累积在耕层中,而As则被下渗水携带迁移出耕层进入地下水.由降雨输入土壤中的Cd通量均大于下渗水输出Cd的通量,局部地区As下渗通量高于雨水输入通量的5.45～13.16倍.土壤中元素的下渗比与土壤质地、pH有关.     

浅谈大气降水对地下水的补给

大气降水入渗补给是地下水的主要补给源.在分析大气降水入渗机理,以及影响降雨入渗诸多因素的基础上,以山西省第二次水资源评价为例,采用相关图解法、回归分析分别对降雨入渗补给量进行计算研究.结果表明,作为大气降水对地下水补给因素影响,综合反映的降水入渗补给系数是计算降水入渗补给量最关键参数,直接表达了降水对地下水垂直入渗补给...     

大气降水与济南泉水动态变化的定量关系研究

济南保泉历经40多年历史,历年枯水期泉水一直受到断流威胁。针对济南泉水动态变化现状,采用相关分析法,研究不同时间尺度下大气降水与泉水动态的关系。研究表明:济南泉域岩溶地下水的主要的补给来源是大气降水,泉水位高低主要受降雨大小的影响;大气降水对泉水位的影响具有滞后性特点;不同时间尺度下累计降水量回归分析得出兴隆雨量站、燕子山雨量站对泉水位影响滞后时间较短;在现状开采条件下,当旬降雨量累计值大于17.58 mm时对泉水位回升有积极的影响。综合济南泉域岩溶水流向、各雨量站距泉的距离、降雨对泉水位影响的滞后时间、各雨量站降水大小与泉水位变幅的关系程度等方面,得出兴隆雨量站所在区域降雨对泉水位的影响较大,是适宜的保泉补源地,能达到科学补源保泉的目的。     

北京西山鹫峰地区氢氧稳定同位素特征分析

以北京西山鹫峰低山区为研究对象,通过对降水、土壤水、泉水氢氧同位素的变化特征分析,研究低山区的降水-土壤水-泉水的转化关系。研究结果表明:该地区的雨季降水线与北京地区的地区降水线有明显区别,斜率和截距偏小;随降雨的进行氢氧同位素特征有时程变化和降雨量效应,而降雨的时程变化也对土壤水的同位素特征产生了影响;土壤水分同位素分布特征相对集中,蒸发线方程的斜率和截距相对于当地大气降水线和雨季降水线都偏小,栓皮栎混交林土壤水对于小雨量次降雨事件反应不敏感,而侧柏林的土壤水分运动较栓皮栎混交林快,说明林分类型和土壤特性对不同水体之间的转化有影响;泉水的同位素特征比较稳定,主要分布在地区降水线的右下方与雨季降水线的交点附近;不同水体中降雨的δD、δ18O变化范围较大,土壤水次之,泉水变化最小;而沿着大气降水-土壤水-地下水(泉水)这一水循环路径,水体中的δD、δ18O值总体上呈下降趋势。     

桂林地区大气降水（大雨、暴雨）的δ18O特征与水汽来源的关系

现代大气降水中的稳定同位素组成是全球或地区性水循环研究的重要载体,同时也是冰芯、湖泊沉积物、石笋等研究领域中,运用稳定同位素来重建古气候的重要依据。本文研究了桂林地区2012年大气降水氢氧同位素组成的逐日变化,根据得到的132组氢氧稳定同位素组成建立了桂林局地大气降水线方程为δD = 8.8δ18O +17.96,大气降水的δ18O波动范围在-13.56‰～+1.07‰,平均为-5.78‰;δD在-101.52‰～+16.02‰,δD平均为-41.03‰。利用降水稳定同位素资料,结合后向轨迹法( Backwards Trajectory) 对桂林水汽来源进行追踪,发现夏季(5-10月)大气降水的水汽来源主要受来自孟加拉湾、南海海洋气团的水汽源的控制,降水的δ18O值偏负,平均为-8.02‰(共64组);冬季(11月至次年4月)大气降水的水汽来源主要受来自西太平洋暖湿气团、冬季风冷气团或西风环流所携带的大陆性气团的影响,不同程度地叠加了局地环流气团、蒸发水汽的补给的影响,降水的δ18O值偏正,平均为-2.86‰(共68组)。研究结果表明,桂林大气降水的稳定同位素组成与降水的水汽来源、季风类型、降水云团来源和性质有关,来自远距离输送夏季风海洋性水汽团形成的降水δ18O值较低(或偏负), 而大陆性气团或局地蒸发水汽循环形成的降水δ18O值较高（或偏正）。不同的水汽来源是决定降水中δ18O值变化的主要因素,因此,通过降水中的δ18O值,特别是其季节变化的特征分析,可以反过来揭示当地降水的水汽来源。      

城市化对上海市区域降水的影响

随着城市化进程加快,城市局地气候特征发生改变,降水的变化尤为显著.采用同时期不同站横向对比,不同时期同站纵向对比的方法对上海市城区及郊区代表雨量站1979～2007年降水时间序列进行研究,分析表明城区的年降雨量、汛期降雨量、主汛期降雨量、月降雨量等均存在较明显的增雨效应,且降雨在年内的分配有向主汛期集中的趋势.城区的梅雨及台风雨增雨明显,城市化对不同类型降雨的影响随降水量级的升高而逐渐显著.城市化使城区的强对流及灾害性天气增多,防洪排涝压力增大,在进行城市规划时应充分予以考虑.     

生物有机酸的来源及其测试分析方法

对目前生物有机酸的来源及其测试分析方法研究现状进行了评述,目前已知的生物有机酸的来源有植物生代过程中的直接释放,有机物质的燃烧,机动车辆燃油的尾气排放、稀烃等不饱和有机物的大气氧化,人类生产和生活对大气环境的污染以及及甲酸蚁社会活动过程中的释放等等,有机酸来源的一个判别指标是甲酸／乙酸比值的大小,与人类活动有关的来源中,甲酸／乙酸比值〈１。而自然源的两者比值〉１。要准确地测定降水中生物有机酸的含量     

Suspended sediments and organic matter in mountain headwaters of the Amazon River: Results from a 1-year time series study in the central Peruvian Andes

Few studies have examined the dynamics of sediments and suspended organic matter and their export from headwater basins in the Andes Mountains to the Amazon River, despite the fact that the Andes are the primary source of sediments to the lower Amazon basin. We measured river discharge as well as the concentration, δ¹⁵N, δ¹³C, %N, and %OC of coarse and fine suspended sediments (CSS and FSS) in the Chorobamba River, located in the central Andean Amazon of Peru. Samples were taken at least weekly over an entire year (July 2004-July 2005), with additional sampling during storms. Concentrations of particulate organic matter (POM) were generally low in the study river, with concentrations increasing by up to several orders of magnitude during episodic rain events. Because both overall flow volumes and POM concentrations increased under stormflow conditions, the export of POM was enhanced multiplicatively during these events. We estimated that a minimum of 80% of annual suspended sediment transfer occurred during only about 10 days of the year, also accounting for 74% of particulate organic carbon and 64% of particulate organic nitrogen transport. Significant differences occurred between seasons (wet and dry) for δ¹³C of coarse and fine POM in the Chorobamba River, reflecting seasonal changes in organic matter sources. The time series data indicate that this Andean river exports approximately equal amounts of fine and coarse POM to the lower Amazon. The observation that the vast majority of sediments and associated OM exported from Andean rivers is mobilized during short, infrequent storm events and landslides has important implications for our understanding of Amazon geochemistry, especially in the face of incipient global change.     

盆地流体中有机组分的成矿效应

盆地流体含有丰富的有机组分。有机质-金属耦合作用是盆地流体金属成矿机制的关键,具有极其重要的意义。有机质的成矿作用主要表现为：1)沉积有机质对盆地流体物理化学特征的制约;2)有机组分对金,属成矿元素在盆地流体中的迁移能力、迁移形式以及沉淀就位机制的制约;3)富有机质的地层作为地球化学还原障和H2S障对于流体中金属沉淀就位的制约;4)沉积有机质的演化对于盆地流体运移的制约(通过油气的阵发性析出和二次孔隙的产生)。     

Influence of radon on the acidification of atmospheric precipitation

Mechanisms of the acidification of precipitation at the expense of radiochemical effects were considered. The results of natural measurements of physicochemical and metrological parameters (pH, T, and radiation background) of atmospheric precipitation (rain and snow) are reported. The possible influence of radon radioactivity (decay energy) on physicochemical processes in the atmosphere was analyzed. A hypothesis was proposed on the mechanism of this process.     

Modeling humic acids transport in a bauxite profile: Los Pijiguaos, Venezuela

Los Pijiguaos bauxite deposit is located in Southern Venezuela, in a tropical rain forest environment. Among the various impurities during the bauxite processing (Bayer process), organic matter compounds present in Bayer liquor can slow the rate of alumina precipitation, and reduce product yield and quality. Soil samples were taken from a 37-m-deep core and the distribution of organic carbon (OC) was investigated as well as its relationship with major oxides Al₂O₃, Fe₂O₃, SiO₂ and with the mineral phases gibbsite, hematite, kaolinite and quartz. Each sample was subjected to an adsorption process of humic acids by interaction with solutions of known concentrations. Maximum adsorption capacity was also studied in each mineral separately, which allowed calculation of the theoretical adsorption capacity of each soil sample. Even if concentrations of OC were higher in the first 5 m of the profile (0.2–0.5%), samples exhibited a low adsorption capacity (0.02%), while at depth between 10 and 37 m, samples showed lower OC concentrations (0.03–0.05%), and a larger OC adsorption capacity (0.08%). The model for the adsorption capacity only works between 10 and 30 m of depth, since in the first 10 m the bauxitic profile seems to be saturated in OC, because the concentration of OC is higher than the maximum predicted by adsorption experiments.     

Application of radar wind profiler data in analyzing the process of torrential rains in Urumqi Xinjiang,China

To deeply understand the micro-/mesoscale dynamic characteristics of the torrential rain process in Urumqi and improve the levels of torrential rain monitoring, forecasting and early warning, this paper analyzed the wind profile features and related scientific problems of three typical torrential rain events seen in 2013–2015 in this region. The research results suggested that: (1) Radar wind profiler can record in detail the movement condition of the atmosphere during the process of torrential rains. Carrying out detailed analyses on the wind profile data is conductive to the improvement in monitoring, forecasting and warning to torrential rain event at a single observation station. (2) When Urumqi experiences heavy rain weather, noticeable wind shear is usually observed above the observation station. In the upper air, it is southwest wind, while in the lower air it is northwest wind, which is the typical wind profile pattern for heavy rain events in the Urumqi region. (3) Obvious northwest low-level jet stream is found to go together with precipitation, and the jet is positively correlated with precipitation intensity. The velocity of low-level jet stream greatly impacts the amount and intensity of precipitation. (4) The rainstorm weather phenomena are clearly presented by the time–height chart of radar reflectivity factors. The high reflectivity values correspond positively to the height range of cloud–rain particles as well as the duration and intensity of precipitation, so it can be used as a reference index of precipitation monitoring and early warning. In a word, this research deepens on the recognition to the micro-/mesoscale weather systems during the process of heavy rains in Urumqi. Moreover, it would contribute to the application improvement of wind profiler data in analyzing the heavy rainfalls in this region.     

Coordination nature of aluminum (oxy)hydroxides formed under the influence of low molecular weight organic acids and a soil humic acid studied by X-ray absorption spectroscopy

Organic ligands in the environment hinder the formation of crystalline Al precipitation products by perturbing the hydrolytic and polymeric reactions of Al resulting in the formation of short-range ordered (SRO) mineral colloids with varying degrees of crystallinity. However, the effect of these ligands on the mechanisms of their formation and nature of the transformation products of Al (oxy)hydroxides at the atomic and molecular levels is not well understood. In this study, the coordination structure of Al in Al (oxy)hydroxides formed under the influence of varying concentrations of low molecular weight (LMW) organic acids such as citric, malic, salicylic and acetic acids and a humic acid (HA) was investigated with X-ray absorption near edge structure (XANES) spectroscopy, Fourier transform infrared (FTIR) spectroscopy and X-ray diffraction analysis. The Al K- and L-edge XANES spectra showed that with increasing LMW organic acid concentration the coordination number of Al changed from 6-fold to a mixture of 4- and 6-fold, except for acetate as acetate was unable to perturb the formation of Al (oxy)hydroxides at the acetate/Al molar ratio (MR) = 0.1. The proportion of 4-fold to 6-fold coordinated Al in the Al precipitation products depended on the structure and functionality of the LMW organic acids. The incorporation of the LMW organic acid into the network structure of Al (oxy)hydroxides prevented the formation of sheets/inter-layer H-bonding that was required for the formation of crystalline Al (oxy)hydroxides. The HA used in this study only slightly perturbed the crystallization of the Al (oxy)hydroxides at the concentrations used. The Al K-edge data showed that Al coordination number had not been altered in the presence of HA. The findings obtained in the present study are of fundamental significance in understanding the physicochemical behavior of soils and sediments, and their relation to the accumulation and transport of nutrients and pollutants in the environment.     

A procedure for partitioning bulk sediments into distinct grain-size fractions for geochemical analysis

A method to separate sediments into discrete size fractions for geochemical analysis has been tested. The procedures were chosen to minimize the destruction or formation of aggregates and involved gentle sieving and settling of wet samples. Freeze-drying and sonication pretreatments, known to influence aggregates, were used for comparison. Freeze-drying was found to increase the silt/clay ratio by an average of 180 percent compared to analysis of a wet sample that had been wet sieved only. Sonication of a wet sample decreased the silt/clay ratio by 51 percent. The concentrations of metals and organic carbon in the separated fractions changed depending on the pretreatment procedures in a manner consistent with the hypothesis that aggregates consist of fine-grained organic- and metal-rich particles. The coarse silt fraction of a freeze-dried sample contained 20–44 percent higher concentrations of Zn, Cu, and organic carbon than the coarse silt fraction of the wet sample. Sonication resulted in concentrations of these analytes that were 18–33 percent lower in the coarse silt fraction than found in the wet sample. Sonication increased the concentration of lead in the clay fraction by an average of 40 percent compared to an unsonicated sample. Understanding the magnitude of change caused by different analysis protocols is an aid in designing future studies that seek to interpret the spatial distribution of contaminated sediments and their transport mechanisms.     

Aerosol particles in the Mexican East Pacific. Part II: Numerical simulations of the impact of enhanced CCN on precipitation development

A number of studies have explored the effect of anthropogenic emissions on the development and evolution of precipitation in different types of clouds; however, the magnitude of the effect is still not clear, particularly for the case of deep, mixed-phase clouds. In this study, changes in the parameterization of the autoconversión process were introduced in the Advanced Regional Prediction System (ARPS) model to further evaluate this question. The simulations were initialized with cloud droplet distributions measured from an instrumented C-130 aircraft flying 600-800 km offshore in the intertropical convergence zone during the East Pacific Investigations of Climate (EPIC) project. Two contrasting cases were selected, one with and the other without the influence of anthropogenic aerosols. The simulations indicate that the increased cloud condensation nuclei (CCN) concentrations lead to a delay in the formation of rain and to a decrease in precipitation that reaches the surface as a result of the inhibition of the autoconversion of cloud water to rain water and the subsequent delay in the formation of hail. In addition, hail forms at higher levels in the cloud for the case of anthropogenic CCN. The most important process in the production of rain water in both cases is the melting of hail. A decrease in the mass of hail that falls below the freezing level in the polluted case, leads to a decrease in the resulting precipitation at the surface. Changes in the initial concentration of CCN do not appear to influence the storm strength in terms of updrafts and cloud top height, suggesting little sensitivity of the cloud dynamics. A control case simulation using the old microphysics scheme produces much more precipitation than either of the clean and polluted cases. In addition, the clean case with the modified parameterization shows a better agreement to observations than the control case. It is suggested to use the new scheme to simulate deep convective development over tropical maritime regions.     

中国大陆降水时空变异规律——Ⅲ. 趋势变化原因

中国大陆现代降水表现出若干长期变化特征,对现代降水趋势性变化的原因,目前还没有很好了解。结合多种资料分析以及前人研究成果,对中国大陆近几十年降水变化趋势的原因进行了探讨,得到以下初步认识:① 现代降水量变化趋势具有明显的地域性差异,全国平均没有表现出显著增加或减少的长期变化,但强降水事件频率和降水量出现明显增多,而小雨事件特别是痕量降水事件显著减少。② 再分析资料表明,最近几十年全国水汽净收支量在一定程度上增加了,实际观测资料显示近地面和对流层中下层空气比湿或大气可降水量出现较明显上升趋势。③ 代用资料序列分析显示,全国大部地区近几十年降水变化仍处于晚近历史时期正常自然波动范围内;近百年观测的降水量序列也表明,黄淮海地区降水具有多重时间尺度相互叠加作用特点,低频自然气候变异的影响信号有清晰表现。④ 人类活动引起的大气中温室气体浓度增加对全国或东部季风区现代降水变化影响的信号,目前仍难以识别;区域性近地面风速减弱导致的雨量观测系统偏差以及大范围气溶胶浓度增加,可能是东部季风区大多数台站观测到的强降水事件频率增加和小雨频率显著减少的两个重要原因。⑤ 主要与城市化影响相关的地面观测资料系统偏差,可以部分解释现有分析表明的短历时强降水事件频率和累计降水量增加现象,同时也很可能是城市台站小雨和痕量降水事件频率明显下降的另一重要原因。