甘肃白银矿田基性火山岩的LA—ICP—MS同位素年代学

对白银矿田基性火山岩进行LA—ICP—MS法单颗粒锆石U—Pb年代学研究,查明白银矿田基性火山岩的成岩时代为465．0Ma±3．7Ma．相当于中奥陶世。结合前人的矿田酸性火山岩精确的同位素定年资料（467．3±2．9Ma和467．1±2．2Ma）,认为白银矿田成矿时代为中奥陶世。舍矿火山岩系形成于奥陶纪的岛弧-裂谷环境。这些成果对进一步深入研究白银矿田的构造演化和指导北祁连山白银式块状硫化物矿床的找寻具有重要意义。     

北祁连东段红土堡基性火山岩锆石LA -IC P-MS U-Pb年代学及其地质意义

为精确限定红土堡基性火山岩的形成时代，结合阴极发光分析，分别对北祁连东段红土堡枕状玄武岩和辉绿岩墙进行了LA - ICP - MS 单颗粒锆石微区U - Pb 同位素测年。红土堡枕状玄武岩获得（443.4 ±1.7 ）Ma 和（1 782 ±34 ）Ma 两组年龄值；同时，获得红土堡基性火山岩中辉绿岩墙的年龄为（385.7 ±7.9 ）Ma，并含有（1 697 ±6 ） ～（2 692 ±4 ）Ma 的捕晶锆石年龄信息。认为红土堡基性火山岩的形成时代为晚奥陶世，与其北的陈家河中酸性火山岩的形成时代大体一致，推断红土堡基性火山岩的原始岩浆不同程度遭受了陇山岩群的混染。这一新资料，对进一步研究北祁连造山带东段大地构造格局、构造演化以及北秦岭—北祁连衔接关系具有重要意义。     

甘肃白银矿田变酸性火山岩锆石LA-ICP-MS测年——白银式块状硫化物矿床形成时代新证据

结合阴极发光,对白银矿田与成矿密切相关的变酸性火山岩中的锆石进行了LA_ICP_MS(激光剥蚀等离子体质谱)U_Pb同位素测年。获得变石英角斑岩内单颗粒锆石的微区U_Pb年龄分别为(467.3±2.9)Ma、(414.2±2.7)Ma,糜棱岩化石英角斑岩内单颗粒锆石的微区U_Pb年龄分别为(467.1±2.2)Ma、(435.9±3.6)Ma和(412.6±2.1)Ma。认为白银矿田变酸性火山岩的形成时代为中奥陶世,由韧性剪切作用引起的糜棱岩化的时代为早志留世晚期,主变质期时代为早泥盆世早期。提出白银铜多金属矿床形成时代为中奥陶世。这一新认识,对进一步深入研究北祁连造山带的构造演化过程以及白银式块状硫化物矿床的形成环境、找矿方向具有重要意义。     

甘肃榆中县黄崖口铅锌矿赋矿岩系变流纹岩锆石U-Pb年龄及其地质意义

黄崖口铅锌矿位于白银矿田外围,一直被认为与小铁山铅锌矿成矿特征类似,是白银矿区外围找矿的重点地段之一。通过对黄崖口铅锌矿区与成矿密切相关的变酸性火山岩LA-ICPMS锆石U-Pb同位素测年,获得铅锌矿赋矿岩系变流纹岩的形成年龄为(507.6±1.8) Ma(MSWD=0.23,Points=23),属于中寒武世。该年龄可代表黄崖口铅锌矿的形成时代,故认为黄崖口铅锌矿形成于中寒武世。结合前人研究成果,白银铜多金属矿形成时代为(467.1±2.2)～(465.0±3.7) Ma,属于中奥陶世,黄崖口铅锌矿的形成时代早于白银铜多金属矿。因此,初步提出白银铜多金属矿田及外围具有多期成矿特征,该认识对白银矿田外围找矿具有重要指示意义。     

相山铀矿田成矿机理研究

本文重点研究了相山铀矿田的成矿时代及成矿环境 ,并剖析了典型矿床在垂向上物质成份的变化规律。研究结果表明 :相山矿田主要经历了两期铀矿化作用 ,第一期为铀 赤铁矿化阶段 ,成矿年龄为 1 1 5± 0 6Ma ;第二期为铀 萤石 水云母化阶段 ,成矿年龄为 99± 6Ma。两期成矿作用分别形成于不同的地质环境 ,第一期成矿作用主要与大规模火山塌陷及次火山岩侵位有关 ,第二期成矿作用则主要与因太平洋板块的松弛作用而形成的区域性伸展、裂解及中基性脉岩的活动有关。相山矿田的热液蚀变类型不仅在平面上存在东碱、西酸的演化趋势 ,而且在垂向上还存在上酸、下碱的演化规律。通过对相山矿田成矿机理的深入探讨 ,认为相山矿田是成矿元素多阶段富集、成矿热液多期叠加以及多种地质因素共同作用的产物。     

柴北缘双口山金- 银- 铅矿床赋矿围岩及含金石英脉热液锆石U- Pb定年对成矿时代的限定及其成因启示

双口山金- 银- 铅矿床地处柴北缘西段,赋存在滩间山变基性- 超基性变火山岩中。矿体由金矿体和银铅矿体组成,成矿作用与热液活动密切相关。本文通过对双口山含金矿体赋矿围岩及含金石英脉进行LA- ICP- MS锆石U- Pb年代学分析和研究。结果表明,赋矿围岩形成时代为443±2. 9Ma,与区域滩间山群火山岩形成年代一致(440~490Ma)。含金石英脉热液锆石U- Pb年代为402. 8±4. 2Ma,与区域金矿床成矿年龄以及韧性剪切带年龄相接近(~400Ma),代表了金矿体热液作用及成矿时代。结合地质特征及前人研究,表明双口山金银铅矿床是柴北缘造山带在不同造山带演化阶段,由不同成矿作用,在不同时期,相互叠加形成的复合型多金属矿床。金矿体具有典型造山型金矿床特征的变质热液型金矿,其成因主要与造山运动过程中的变质和变形作用有关, 成矿物质和流体来源于绿片岩相的滩间山群变基性- 超基性变火山岩。银铅矿体为岩浆热液型,成矿与后碰撞造山作用伸展- 构造转换有关的岩浆作用有关,成矿物质和流体来源于晚泥盆世深部含矿岩浆作用。     

青海门源地区红沟铜矿床含矿基性火山岩 LA-ICP-MS锆石U-Pb年龄

对红沟铜矿床含矿火山岩进行高精度锆石LA-ICP-MS U-Pb同位素测年,获得单颗粒锆石的加权平均年龄为443.2 Ma±1.2Ma。红沟铜矿床形成时代为晚奥陶世,形成环境为晚奥陶世陆缘裂谷环境。高精度年龄的获得对于整个祁连山地区产于陆缘裂谷环境的铜多金属矿床的成矿时代和成因研究具有重要意义。     

东天山企鹅山群火山岩锆石U-Pb年代学

企鹅山群是指分布于东天山觉罗塔格地区康古尔塔格断裂和大草滩断裂之间的一套火山-沉积岩系。新近发现的土屋-延东大型斑岩型铜矿含矿斑岩的围岩为企鹅山群第二组的火山岩系,同时由于该火山岩系与其上覆和下伏岩系均呈断层接触,因而企鹅山群火山岩的形成时代备受关注。对该火山岩系组合中的基性火山岩和酸性火山岩进行锆石U-Pb同位素年龄测定,测得基性火山岩的成岩年龄为322.6Ma±2.0Ma,酸性火山岩的成岩年龄为319.9Ma±1.6Ma。该年龄对认识东疆地区石炭纪构造演化历史和成矿作用具有重要价值。     

湖北省随州三里岗地区二长花岗岩Rb-Sr、40Ar/39Ar同位素年龄

三里岗二长花岗岩与花山蛇绿混杂岩中的基性火山岩呈侵入接触关系,其年龄的确定可解决花山蛇绿混杂岩中基性岩形成年龄的上限问题. 本文对三里岗二长花岗岩分别进行了Sm、Nd同位素研究及Rb-Sr、40Ar/39Ar同位素年龄测定.3个全岩样品的Nd模式年龄平均值为1 064±105 Ma;12个全岩样品的Rb-Sr等时线年龄为422±53(2σ)Ma;二长花岗岩中所含角闪石矿物的40Ar/39Ar坪年龄为141.4±0.3 Ma,等时线年龄为142±2 Ma.这些结果暗示了花山蛇绿混杂岩中基性火山岩的形成年龄不可能晚于422 Ma.     

新疆中天山乔霍特铜矿区I型花岗岩锆石LA-ICP-MS U-Pb年龄及其地质意义

新疆中天山乔霍特铜矿位于中天山南缘,毗邻南天山缝合带。矿区南侧出露有1个花岗闪长岩岩体,该岩体与包裹于赋矿火山岩中的钾长花岗岩均属钙碱性弱过铝质I型花岗岩,具有相似的地球化学特征,富集LILE、亏损HFSE,具显著的Eu、Ta、Nb、Ti负异常,其形成可能与南天山洋的北向俯冲密切相关。LA-ICP-MS锆石U-Pb定年获得花岗闪长岩年龄为450.4±1.1Ma,钾长花岗岩年龄为430.8±4.1Ma,指示晚奥陶世时期,乔霍特地区存在南天山洋向中天山复合弧地体之下的俯冲;早志留世晚期,俯冲作用依然持续,此时,天山地区岩浆活动强烈。乔霍特铜矿赋矿火山岩的形成时代晚于431Ma,矿区南侧出露的花岗闪长岩早于赋矿火山岩形成,成矿作用可能与花岗闪长岩的侵位无直接关系。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

Mountains,nations, parks,and conservation

Between 1985 and 1991, two new mountain protected areas (MTNPA) covering more than 35,000 km² and based on participatory management models — the Makalu-Barun National Park and Conservation Area, Nepal, and Qomolangma Nature Preserve, Tibet Autonomous Region — were successfully established through the collaborative efforts of Woodlands Mountain Institute and conservationists in China and Nepal. Characteristics common to both projects include the importance of establishing (1) effective rationales, (2) local support constituencies, (3) a senior advisory group, (4) a task force, (5) linkages between conservation and development, and (6) fund raising mechanisms. The lessons derived from the experiences of Woodlands Mountain Institute are of significant value to others in preserving MTNPA. Increased collaboration and communication between all interested in conservation, however, will remain a critical component for expanding mountain protected area coverage to throughout the world.     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。     

Regional distribution of Al,B, Ba,Ca, K,La, Mg,Mn, Na,P, Rb,Si, Sr,Th, U and Y in terrestrial moss within a 188,000 km2 area of the central Barents region: influence of geology,seaspray and human activity

Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km² area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).