氨氮在弱透水层中的渗透迁移规律研究

通过渗透试验、吸附试验和高压动态土柱试验对氨氮在弱透水层中的渗透、迁移转化规律进行研究。试验结果表明,弱透水层对氨氮具有很强的吸附能力;弱透水层中生物作用微弱,弱透水层对氨氮的去除主要是非生物作用的结果;硬度或其他交换性离子的作用会影响氨氮在弱透水层的穿透时间和吸附稳定性。此研究对揭示深层地下水的氮污染规律及探索地下水污染修复提供理论支持。     

pH 值对有机磷在弱透水层中迁移转化的试验模拟

为研究渗透水pH 值对有机磷通过弱透水黏土层迁移转化的影响规律,采用黏性土层充压渗透装置模拟污染潜水中有机磷渗透通过弱透水层的迁移转化过程。研究发现,有机磷组分通过弱透水层的迁移能力总体较弱,不同pH 值条件下有机磷的矿化率为93. 5% ～ 99. 95%; 在进水pH 值为5. 5 ～ 8. 5 时,进水pH 值越高,土层中磷酸酶的活性也越高,降解转化有机磷的能力也越强; 黏土对有机磷的阻滞能力也增强。进水pH 值为5. 5 时,迁移率为6. 5%; 当pH 达到8. 5 时,矿化率明显增加,迁移率＜ 0. 05%,使其不易渗入深层地下水引起污染。     

有机污染物(菲)在弱透水层中的越流迁移特征

采用高渗透压渗流试验装置,模拟已被污染的浅层地下水越流通过弱透水层污染深层地下水的过程,研究不同矿化度、不同pH条件下有机污染物（菲）通过饱和黏性土弱透水层时的质量浓度变化特征。结果表明：矿化度的增加有利于弱透水层吸附截留渗滤液中的菲;高矿化度水中的Na+交替土层中的Ca²⁺、Mg²⁺,使水中的Ca²⁺、Mg²⁺质量浓度增加,与HCO^-₃、菲组合形成络合物;不同pH条件下,Ca²⁺、Mg²⁺、HCO^-₃对菲的迁移有阻滞作用,SO^2-₄参与还原反应并可与菲形成络合物,对菲迁移有促进作用。菲在弱透水层中的迁移能力很弱,衰减率达82％～96％,高渗透压下菲的污染锋面迁移速度为0.714 m/d,pH=8时菲通过弱透水层的迁移质量浓度最小。控制渗滤液的pH、组分可有效阻止菲在弱透水层中的迁移。     

硫酸根离子在弱透水层中的迁移行为

通过研究地下水中硫酸根离子通过弱透水层时迁移特征的变异规律及其环境效应作用,分析在不同黏性土壤厚度条件下硫酸根离子浓度的变化及其受pH、Eh、钙离子浓度变化的影响特征,以及在不同pH 值条件下硫酸根离子的浓度变化情况。利用土柱填装及淋滤法,得出地下水中硫酸根离子通过弱透水层时穿透能力很强的结论,并揭示了硫酸根离子浓度随渗透土壤厚度的增大而增大,随淋滤液pH 值增大而减小的规律。     

弱透水层中有机污染物(菲)的衰减研究

本文以高渗透压渗流试验装置模拟已被污染的浅层地下水越流通过弱透水层污染深层地下水的过程,研究了有机污染物(菲)通过饱和粘性土弱透水层时的自然衰减特征,以及非生物因子-配位体对于弱透水层中菲迁移转化的影响作用。研究表明,菲的衰减曲线明显分为三阶段:初期吸附截留显著期,中期微生物降解旺盛期,后期微生物降解稳定期;溶液中共存离子HCO 3-、Ca2+与菲形成络合物,SO42-参与菲的生物降解;溶液中主要配位体不同时,菲与阴、阳离子之间相互作用的方式也不同,以络合作用为主。渗透水中菲含量有99%以上被衰减,仅有极少量菲穿透弱透水层。     

黏性土弱透水层压实作用:原理、技术及其水文地质意义

弱透水层与含水层相互作用是国际水文地质学界关注的热点问题,特别是黏性土弱透水层与孔隙含水层的相互作用。近年来,在自然沉积、过量开采地下水、现代化农业机械与建筑业重型机械应用等自然与人为活动影响下,黏土弱透水层会发生有效应力增加、孔隙结构变形和孔隙度减少、渗透性降低、溶解氧和贮水能力减少以及侧向和垂向排水等的压实作用,导致地下水污染、地面沉降等环境问题的发生。本文重点介绍了黏性土弱透水层压实作用的原理,分析了地下水系统中4种不同状态下沉积物压实与孔隙流体压力的关系,基于压实物理模拟和数值模拟两个方面对压实作用的研究方法与技术进行了系统总结,随后探讨了压实作用下黏性土弱透水层对地下水水量与水质的影响,并对此研究的发展趋势及其在地球科学、环境科学等研究领域的潜在应用提出了展望。     

深厚覆盖层坝基水文地质结构控渗机理研究

厚度大且为强-弱-强渗透性组合的覆盖层在我国西南河流中分布较广。为研究此类夹层型水文地质结构覆盖层中坝基渗流场的特征及其影响因素,利用Visual MODFLOW模拟了给定覆盖层厚度下强弱渗透性层组的不同渗透性比值、不同厚度比值,和变覆盖层厚度下不同弱透水层厚度这两种类型16种工况下的渗流场,通过监测坝基渗流场中弱透水层顶底板的水头差和水力坡度,研究弱透水层渗透性和厚度对渗流场的影响。结果表明:强-弱-强夹层型水文地质结构的坝基平面渗流场受上层强透水覆盖层性质控制;给定覆盖层厚度工况中,弱透水层顶底板的水头差与强弱透水层渗透性比值相关,两者先表现出正相关的关系,当强弱透水层渗透性比值大于500时,弱透水层顶底板的水头差变化不再明显;变覆盖层厚度工况中,弱透水层顶底板的水头差也呈现出先增大后趋于稳定的趋势,转折点发生在弱透水层厚度20m的工况条件下;变覆盖层厚度工况中水力坡度则有着随着弱透水层厚度增大而变小的规律。综上所述,在夹层型水文地质结构中,弱透水层厚度与渗透性对渗流场起控制作用。研究结果可为深厚覆盖层河谷区的水电水利工程坝基水害防治提供依据。     

深部弱透水层固结变形模型建议

地面沉降模型是地面沉降研究的重要内容,由于弱透水层的变形量占地层全部变形量的比重较大,因此对弱透水层固结模型的研究是地面沉降模型研究中的重要部分。笔者通过对深部弱透水层中粘性土孔隙水类型进行分析,得出深度弱透水层中孔隙水类型并对该类型孔隙水变形特性进行了研究,总结出深部弱透水层固结机理。在机理分析的基础上,提出采用非达西流计算模式对深部弱透水层计算模型进行了修正,并提出了深部弱透水层固结计算模型建议：孔隙水类型主要为扩散层内结合水时,可以采用利用非达西流修正的太沙基固结方程对深部弱透水层变形进行计算,可以参考给出的采用非达西定律修正过的一维固结方程 孔隙水类型主要为吸附结合水时,可以利用弹性本构关系模型对深部弱透水层进行变形计算。     

一种长期观测资料确定弱透水层参数的方法

弱透水层是含水层系统的重要组成部分,要准确计算弱透水层释水量和变形量需事先确定弱透水层的渗透系数和贮水率值。基于一维含水层系统概念模型,在相邻含水层降深随时间线性增大的边界条件下,推得了无量纲形式的弱透水层降深解析解,分析了弱透水层中滞后降深消散规律。根据水量均衡方程得到了弱透水层累计压缩变形量随时间变化的标准曲线,并提出了一种配线法用以确定弱透水层的渗透系数和贮水率,该配线法能够反映弱透水层释水变形过程的滞后性。以上海含水层系统为例,运用配线法确定了f_(10-7)分层标处第2弱透水层的渗透系数为4.26×10~(-10)m/s,贮水率为2.22×10~(-4)m~(-1)。对于具有长序列变形和水位观测资料的含水层系统,该方法具有一定的适用性。     

滨海地区分层含水层中陆源溶质运移过程

为更好地保护沿海水环境和水生态功能，亟需探究陆源溶质在滨海分层含水层中的迁移机制。构建二维分层含水层数值模型，采用地下水软件SUTRA-MS模拟分析潮汐作用下陆源溶质在分层含水层中的运移特征。结果表明：(1)与均质含水层相比，弱透水层的存在会延长溶质在含水层中的滞留时间、增大溶质最大扩散面积、削弱溶质在水平方向和垂直方向的扩散程度；(2)弱透水层能够降低陆源溶质向海水排放的最大通量，并且延长溶质排放的持续时间；(3)溶质扩散面积、弱透水层中溶质残余量、水平和垂向扩散程度等对弱透水层水力传导系数和厚度的敏感性优于弱透水层深度。     

Effects of slow recovery rates on water column geochemistry in aquitard wells

Monitoring wells are often installed in aquitards to verify effectiveness for preventing migration of surface contaminants to underlying aquifers. However, water sampling of aquitard wells presents a challenge due to the slow recovery times for water recharging the wells, which can take as long as weeks, months or years to recharge depending on the sample volume needed. In this study, downhole profiling and sampling of aquitard wells was used to assess geochemical changes that occur in aquitard wells during water level recovery. Wells were sampled on three occasions spanning 11 years, 1 year and 1 week after they were purged and casing water showed substantial water chemistry variations. Temperature decreased with depth, whereas pH and specific conductance increased with depth in the water column after 11 years of water level recovery. Less stable parameters such as dissolved O₂ (DO) and Eh showed strong zonation in the well column, with DO stratification occurring as the groundwater slowly entered the well. Oxidation of reduced till groundwater along with degassing of CO₂ from till pore water affects mineral solubility and dissolved solid concentrations. Recommendations for sampling slowly recovering aquitard wells include identifying the zone of DO and Eh stratification in the well column and collecting water samples from below the boundary to better measure unstable geochemical parameters.     

粉煤灰-粉质粘土对氟离子的吸附作用

不同土层对氟离子的吸附能力不同,在吸附能力较弱的土层建设贮灰场,会导致周边地下水中氟离子质量浓度较高,污染地下水。吉林市来发屯灰场运行多年来,地下水中氟离子质量浓度与背景环境未见明显差异,本文通过对来发屯灰场粉煤灰-粉质粘土和灰场外土层的比较分析,探究吸附机理,结果表明：粉煤灰-粉质粘土对氟离子有较强的吸附能力,能有效防止其对地下水的污染。     

污染场地六价铬迁移转化机制与数值模拟研究

随着全球工业化迅猛发展,土壤和地下水六价铬污染日益严重。基于某铁合金厂铬渣场地现场调查与采样分析,开展铬渣场地土样吸附、渗透和弥散试验,研究六价铬在粉质黏土土样中的吸附特性和迁移规律,建立考虑对流-弥散-吸附的六价铬迁移三维动力学模型,结合数值软件获取污染源位于场地上、下游时地下水中六价铬迁移分布特征,并揭示弥散度?和分配系数 对六价铬时空分布的影响。试验结果表明,粉质黏土对六价铬吸附符合Langmuir等温吸附模型,最大吸附量为466.6 mg/kg;蒸馏水和160 mg/L 六价铬溶液入渗下粉质黏土渗透系数约为6.5×10–7～6.7×10–7 cm/s,1 000 mg/L六价铬溶液的渗透系数增大至4.4×10–6 cm/s;粉质黏土水动力弥散系数D为1.4×10–4 m2/d,计算得到阻滞因子 为4.2～10。数值模拟结果表明,场地下游受到六价铬污染时,即使不考虑分子扩散作用,上游仍有被污染的风险,污染程度取决于含水层的弥散度;考虑含水层对六价铬吸附时,土体分配系数越大,六价铬污染羽分布范围越小,在预测地下水中六价铬浓度分布时应重点考虑六价铬吸附等转化过程。     

Nitrate enhancement of nitrification depth in sediment/water microcosms

Streams draining agricultural catchments in loward England commonly have high nitrate concentrations. Laboratory microcosms were used to study nitrogen transformations in the sediment from such a stream. Solutions of either 0.5 mmol dm⁻³ calcium nitrate or calcium chloride (control) were passed once only over the sediment surface. After 5 days incubation, Eh in the nitrate treatment stabilized at approximately 500 mV at 5 mm below the water/sediment interface, and 285 mV at 10 mmn, whereas in the chloride treatment Eh was −200 mV to −250 mV at all measured depths (5 mm and below). Inorganic N mesurements of the seidment profiles showed that much more ammonium-N was being lost from the nitrate-treated sediment that the control. It was hypothesized that, when nitrate was present in the streamwater, the combined processed of nitrate diffusion and denitrification progressively consumed organic matter, thereby allowing dissolved oxygen to diffuse further into the sediment. A consequence of these processes would be a greater depth of nitrification and hence more ammounium loss. The plausibility of this hypothesis was evaluated by constructing a deterministic model which simulated the nitrate and ammonium profiles from the processes of diffusion, denitrification, nitrification, and ammonification. Kinetic parameters and diffusion impedance factor were determined from independent experiments. This calibrated model provided reasonable simulations of experimental data obtained from an additional experiment, which also showed that peaks in denitrification and nitrification activity were offset from each other by 2–3 mm, and that they migrated down the profile with increasing incubation time.     

冲积和湖积成因土壤Cd的吸附特征:以安徽省当涂县为例

为揭示冲积与湖积成因土壤镉的吸附特征,以安徽省当涂县冲积成因的江心洲和冲积、湖积成因的大陇乡根际土壤为研究对象,开展土壤镉的等温吸附实验和吸附动力学实验.等温吸附实验结果表明,冲积土壤镉的吸附量（S）、等温吸附常数（K）和固液分配系数（K_d）均较湖积土壤明显偏大,显示冲积土壤对镉的吸附能力较湖积土壤强;吸附动力学实验表明,冲积土壤的最大吸附量、平衡吸附量均较湖积土壤大,吸附速率也明显偏大,尤其在吸附实验早期更为显著;等温吸附常数K和平衡吸附速率V_b与土壤理化性质的分析表明,土壤pH是造成研究区土壤镉吸附能力差异的主要原因,其次为物理性粘粒含量;土壤pH是影响研究区冲积土壤镉吸附能力的主要因素;湖积土壤镉的吸附能力受土壤pH、有机质含量、Cd含量、物理性粘粒含量等因素的综合影响.研究对于揭示Cd在水土系统的迁移转化规律以及土壤Cd的污染防治具有重要的指导意义.      

Trace element remobilization following the resuspension of sediments under controlled redox conditions: City Park Lake,Baton Rouge,LA

The sediments of City Park Lake (Baton Rouge, Louisiana, USA) are characterized by Pb concentrations that exceed the corresponding National Oceanic and Atmospheric Administration probable effect level by more than a factor of two and concentrations of As, Cd, Cu, Ni and Zn that exceed the corresponding threshold effect levels. The sediments of the lake are likely to be dredged because of concern over shoaling of the lake. There is concern that exposing these sediments to an oxidizing environment could mobilize toxic metal(loid)s that are effectively sequestered under reducing conditions. To address this concern, mixtures of sediments collected from seven locations in City Park Lake were incubated in microcosms under controlled oxidizing and reducing conditions. The slurries were sampled at time intervals over a period of nearly 750 h, and the dissolved Fe, Mn and trace metal concentrations determined. Eh and pH were negatively correlated, with Eh declining by 600 mV per unit increase in pH. Of the toxic metals, only the concentration of Cu was positively correlated with Eh, apparently because of the sequestration of Cu as a very insoluble sulfide precipitate under low Eh conditions. Precipitation of the other metals as sulfides was evidently insignificant because of the low S content of the sediments. Concentrations of the remaining potentially toxic metals were negatively correlated with Eh, apparently because of their sequestration as oxides and/or adsorption to Fe oxides or oxy-hydroxides. Concentrations of Ca, Mg, and Sr were positively correlated with Eh, presumably because of their sequestration in carbonate precipitates under low Eh/high pH conditions.