Petrographic evidence of magma mixing in Shirouma-Oike volcano,Japan

Detailed petrographic analysis of calcalkaline volcanic rocks of Shirouma-Oike volcano, Japan, reveals that the complex phenocryst assemblage (Ol+Cpx+Opx+Hb+Bt+Qz+Pl+Mt+Hm) in the younger group volcanic rocks can be divided into two groups, a high temperature group (Ol+Cpx±An-rich Pl) and a low temperature group (Op+Hb+Bt+Qz±Ab-rich Pl+Mt+Hm). Compositional zonation of the phenocrystic minerals, normal zoning in olivine and clinopyroxene, and reverse zoning in orthopyroxene and plagioclase, indicate that these two groups of phenocrysts precipitated from two different magmas which mixed before the eruption. The low temperature magma is a stagnant magma in a shallow magma chamber, to which high temperature basaltic magma is intermittently supplied. Magma mixing is also indicated in olivine-bearing two pyroxene andesite of the older group volcanic rocks, by the coexistence of normally zoned Mg-rich clinopyroxene phenocrysts and reversely zoned Fe-rich clinopyroxene phenocrysts, and by reverse zoning in orthopyroxene phenocrysts. It is concluded that magma mixing is an important process responsible for the generation of the disequilibrium features in calc-alkaline volcanic rocks.     

Rifting episode in north iceland in 1874–1875 and the eruptions of askja and sveinagja

In 1874 and 1875 the fissure swarm of Askja central volcano was activated during a major rifting episode. This rifting resulted in a fissure eruption of 0.3 km³ basaltic magma in Sveinagja graben, 50 to 70 km north of Askja and subsequent caldera collapse forming the Oskjuvatn caldera within the main Askja caldera. Five weeks after initial collapse, an explosive mixed magma eruption took place in Askja. On the basis of matching chemistry, synchronous activity and parallels with other rifted central volcanoes, the events in Askja and its lissure swarm are attributed to rise of basaltic magma into a high-level reservoir in the central volcano, subsequent rifting of the reservoir and lateral flow magma within the fissure swarm to emerge in the Sveinagja eruption. This lateral draining of the Askja reservoir is the most plausible cause for caldera collpse. The Sveinagja basalt belong to the group of evolved tholejites characteristie of several Icelandic central volcanoes and associated fissure swarms. Such tholeiites, with Mgvalues in the 40 to 50 tange, represent magmas which have suffered extensive fractional crystallization within the crust. The 12% porphyritic Sveinagja basalt contains phenocrysts of olivine (Fo_62–67), plagioclase (An_57–62), clinopyroxene (Wo₃₈En₄₆Wo₁₆) and titanomagnetite. Extrusion temperature of the lava, calculated on the basis of olivine and plagioclase geothermometry, is found to be close to 1150°C.     

Magma plumbing system of the 2000 eruption of Miyakejima Volcano, Japan

During the 2000 eruption at Miyakejima Volcano, two magmas with different compositions erupted successively from different craters. Magma erupted as spatter from the submarine craters on 27 June is aphyric basaltic andesite (<5 vol% phenocrysts, 51.4–52.2 wt% SiO₂), whereas magma issued as volcanic bombs from the summit caldera on 18 August is plagioclase-phyric basalt (20 vol% phenocrysts, 50.8–51.3 wt% SiO₂). The submarine spatter contains two types of crystal-clots, A-type and A-type (andesitic type). The phenocryst assemblages (plagioclase, pyroxenes and magnetite) and compositions of clinopyroxene in these clots are nearly the same, but only A-type clots contain Ca-poor plagioclase (An < 70). We consider that the A-type clots could have crystallized from a more differentiated andesitic magma than the A-type clots, because FeO*/MgO is not strongly influenced during shallow andesitic differentiation. The summit bombs contain only B-type (basaltic type) crystal-clots of Ca-rich plagioclase, olivine and clinopyroxene. The A-type and B-type clots have often coexisted in Miyakejima lavas of the period 1469–1983, suggesting that the magma storage system consists of independent batches of andesitic and basaltic magmas. According to the temporal variations of mineral compositions in crystal-clots, the andesitic magma became less evolved, and the basaltic magma more evolved, over the past 500 years. We conclude that gradually differentiating basaltic magma has been repeatedly injected into the shallower andesitic magma over this period, causing the andesitic magma to become less evolved with time. The mineral chemistries in crystal-clots of the submarine spatter and 18 August summit bombs of the 2000 eruption fall on the evolution trends of the A-type and B-type clots respectively, suggesting that the shallow andesitic and deeper basaltic magmas existing since 1469 had successively erupted from different craters. The 2000 summit collapse occurred due to drainage of the andesitic magma from the shallower chamber; as the collapse occurred, it may have caused disruption of crustal cumulates which then contaminated the ascending, deeper basalt. Thus, porphyritic basaltic magma could erupt alone without mixing with the andesitic magma from the summit caldera. The historical magma plumbing system of Miyakejima was probably destroyed during the 2000 eruption, and a new one may now form.Editorial responsibility: S Nakada, T Druitt     

Temporal variation in the lavas of Mayon volcano, Philippines

Chemical and petrographic analyses of 51 sequential lava flows from the central vent of Mayon volcano show cyclical variation. In the two most recent cycles, from 1800 to 1876 and from 1881 to the present, one to three basaltic flows are followed by six to ten andesitic flows. Modal and whole-rock chemical parameters show the most regular cyclical variation; calculated groundmass chemical parameters vary less regularly. There is also a long-term trend, over approximately 1700 years of exposed section, toward more basic compositions.The cyclical variation in modes and the chemical composition of the lavas apparently results from periodic influxes of basaltic magma from depth into a shallow magma system. Fractional crystallization of olivine, augite, hypersthene, calcic plagioclase, magnetite and pargasitic hornblende produces successively more andesitic lavas until the next influx of basaltic magma. Differentiation in a deep zone of magma generation is not excluded by the data, but is more likely responsible for the overall change toward more basic compositions than for the cyclical variation.Three points in a cycle — the beginning of basaltic lavas, the beginning of andesitic lavas and a leveling-off of SiO₂, K₂ O and K₂O/Na₂O values — correspond roughly to the beginning of frequent effusive eruptions (with or without an early Plinian eruption), frequent weak to moderately explosive (Strombolian) eruptions, and less frequent explosive (Vulcanian) eruptions, respectively. Recognition of the current stage in a cycle can give a qualitative indication of the nature of forthcoming eruptions. Changes in several specific parameters may precede basaltic lavas and allow early detection of basaltic influxes. These include minima in the glass inclusion/plagioclase phenocryst and phenocryst/groundmass ratios, vesicularity and groundmass TiO₂, a decrease in hypersthene phenocrysts, and constant values for the whole-rock K₂O/Na₂O ratio. The Mayon area is densely populated, making prediction of eruption type important for safety and land-use planning.     

On the Magma Chambers beneath Klyuchevskoi Volcano,Kamchatka

Numerous summit and parasitic eruptions of moderate potassium magnesian and high-alumina basalts and basaltic andesites, their mineralogic and geochemical features, and the composition of in situ chilled melt inclusions in the olivine of cinder lapilli discharged by Klyuchevskoi Volcano all provide evidence of the presence of magma chambers beneath the volcano. This is also supported by a dualism in the variation of CaO and Al₂O₃ concentrations in olivine and clinopyroxene during crystallization. The mineralogic features in the high-alumina basalts that were discharged by all parasitic eruptions of Klyuchevskoi provide evidence of magnesian magma being emplaced from a deeper chamber into a shallow high-alumina chamber. The distribution of incoherent elements in the volcano’s magnesian and aluminiferous rocks shows that they came from a single mantle source. The geochemical and mineralogic data are in good agreement with the results of geophysical surveys that concern the structure and properties of the lithosphere beneath Klyuchevskoi.     

Intracrustal origin of Arenal basaltic andesite in the light of solid–melt interactions and related compositional buffering

The origin of Arenal basaltic andesite can be explained in terms of fractional crystallization of a parental high-alumina basalt (HAB), which assimilates crustal rocks during its storage, ascent and evolution. Contamination of this melt by Tertiary calc-alkalic intrusives (quartz–diorite and granite, with ⁸⁷Sr/⁸⁶Sr ratios ranging 0.70381–0.70397, nearly identical with those of the Arenal lavas) occurs at upper crustal levels, following the interaction of ascending basaltic magma masses with gabbroic–anorthositic layers. Fragments of these layers are found as inclusions within Arenal lavas and tephra and may show reaction rims (1–5 mm thick, consisting of augite, hypersthene, bytownitic–anorthitic plagioclase, and granular titanomagnetite) at the gabbro–lava interface. These reaction rims indicate that complete `assimilation' was prevented since the temperature of the host basaltic magma was not high enough to melt the gabbroic materials (whose mineral phases are nearly identical to the early formed liquidus phases in the differentiating HAB). Olivine gabbros crystallized at pressure of about 5–6 kbar and equilibrated with the parental HAB at pressures of 3–6 kbar (both under anhydrous and hydrous conditions), and temperatures ranging 1000–1100°C. In particular, `deeper' interactions between the mafic inclusions and the hydrous basaltic melt (i.e., with about 3.5 wt.% H₂O) are likely to occur at 5.4 (±0.4) kbar and temperatures approaching 1100°C. The olivine gabbros are thus interpreted as cumulates which represent crystallized portions of earlier Arenal-type basalts. Some of the gabbros have been `mildly' tectonized and recrystallized to give mafic granulites that may exhibit a distinct foliation. Below Arenal volcano a zoned magma chamber evolved prior the last eruptive cycle: three distinct andesitic magma layers were produced by simple AFC of a high-alumina basalt (HAB) with assimilation of Tertiary quartz–dioritic and granitic rocks. Early erupted 1968 tephra and 1969 lavas (which represent the first two layers of the upper part of a zoned magma chamber) were produced by simple AFC, with fractionation of plagioclase, pyroxene and magnetite and concomitant assimilation of quartz–dioritic rocks. Assimilation rates were constant (r<sub>1</sub>=0.33) for a relative mass of magma remaining of 0.77–0.80, respectively. Lavas erupted around 1974 are less differentiated and represent the `primitive andesitic magma type' residing within the middle–lower part of the chamber. These lavas were also produced by simple AFC: assimilation rates and the relative mass of magma remaining increased of about 10%, respectively (r₁=0.36, and F=0.89). Ba enrichment of the above lavas is related to selective assimilation of Ba from Tertiary granitic rocks. Lava eruption occurred as a dynamic response to the intrusion of a new magma into the old reservoir. This process caused the instability of the zoned magma column inducing syneruptive mixing between portions of two contiguous magma layers (both within the column itself and at lower levels where the new basalt was intruded into the reservoir). Syneruptive mixing (mingling) within the middle–upper part of the chamber involved fractions of earlier gabbroic cumulitic materials (lavas erupted around 1970). On the contrary, within the lower part of the chamber, mixing between the intruded HAB and the residing andesitic melt was followed by simple fractional crystallization (FC) of the hybrid magma layer (lavas erupted in 1978–1980). By that time the original magma chamber was completely evacuated. Lavas erupted in 1982/1984 were thus modelled by means of `open system' AFCRE (i.e., AFC with continuous recharge of a fractionating magma batch during eruption): in this case assimilation rates were r₁=0.33 and F=0.86. Recharge rates are slightly higher than extrusion rates and may reflect differences in density (between extruded and injected magmas), together with dynamic fluctuations of these parameters during eruption. Ba and LREE (La, Ce) enrichments of these lavas can be related to selective assimilation of Tertiary granitic and quartz–dioritic rocks. Calculated contents for Zr, Y and other REE are in acceptable agreement with the observed values. It is concluded that simple AFC occurs between two distinct eruption cycles and is typical of a period of repose or mild and decreasing volcanic activity. On the contrary, magma mixing, eventually followed by fractional crystallization (FC) of the hybrid magma layer, occurs during an ongoing eruption. Open-system AFCRE is only operative when the original magma chamber has been totally replenished by the new basaltic magma, and seems a prelude to the progressive ceasing of a major eruptive cycle.     

Petrogenesis of basalts from the project FAMOUS area: experimental study from 0 to 15 kbars

Tholeiitic basalt glasses from the FAMOUS area of the Mid-Atlantic Ridge are among the most primitive basaltic liquids reported from the ocean basins. One of the more primitive of these[Mg/(Mg+Fe²⁺) = 0.68;Ni= 232ppm;TiO₂ = 0.61] glasses (572-1-1) was selected for an experimental investigation. This study found olivine to be the liquidus phase from 1 atm to 10.5 kbar where it is replaced by clinopyroxene. The sequence of appearance of phases at 1 atm pressure is olivine (1268°C), plagioclase (1235°C) and clinopyroxene (1135°C). The sample is multiply saturated at 10.5 kbar with olivine (Fo₈₈), clinopyroxene (Wo₃₂En₆₀Fs₉), and orthopyroxene (Wo₅En₈₃Fs₁₂). From the 1-atm data we have measured (FeO/MgO) olivine/(FeO*/MgO) liquid (K′_D) for olivine-melt pairs equilibrated at 12 temperatures in the range 1268–1205°C.K′_D varies from 0.30 at 1205°C to 0.27 at 1268°C. Analysis of high-pressure olivine melt pairs indicates a systematic increase inK′_D with pressure.Evaluation of the 1-atm experiments reveals that fractionation of olivine followed by olivine + plagioclase can generate much of the variation in major element chemistry observed in the FAMOUS basalt glasses. However, it cannot account for the entire spectrum of glass compositions — particularly with respect to TiO₂ and Na₂O. The variations in these components are such as to require different primary liquids.Comparison of clinopyroxene microphenocrysts/xenocrysts found in oceanic tholeiites with experimental clinopyroxenes reveal that the majority of those in the tholeiites may have crystallized from the magma at pressures greater than ～ 10 kbar and are not accidental xenocrysts. Clinopyroxene fractionation at high pressures may be a viable mechanism for fractionating basaltic magmas.The major and minor element mineral/meltK′_d's from our experiments have been used to model the source region residual mineralogy for given percentages of partial melting. These data suggest that ～20% partial melting of a lherzolite source containing 0–10% clinopyroxene can generate the major and minor element concentrations in the parental magmas of the Project FAMOUS basalt glasses.     

Petrology of basaltic xenoliths in andesitic to dacitic host lavas from Martinique (lesser antilles): Evidence for magma mixing

Some recent calc-alkaline andesites and dacites from southern and central Martinique contain basic xenoliths belonging to two main petrographic types:

The most frequent one has a hyalodoleritic texture (« H type ») with hornblende + plagioclase + Fe-Ti oxides, set in an abundant glassy and vacuolar groundmass.

The other one exhibits a typical porphyritic basaltic texture (« B type ») and mineralogy (olivine + plagioclase + orthopyroxene + clinopyroxene + Fe-Ti oxides and scarce, or absent hornblende).

Gradual textural and mineralogical transitions occur between these two types (« I type ») with the progressive development of hornblende at the expense of olivine and pyroxenes. Mineralogical and chemical studies show no primary compositional correlations between the basaltic xenoliths and their host lavas, thus demonstrating that the former are not cognate inclusions; they are remnants of basaltic liquids intruded into andesitic to dacitic magma chambers. This interpretation is strengthened by the typical calc-alkaline basaltic composition of the xenoliths, whatever their petrographic type (« H », « I » or « B »). The intrusion of partly liquid, hot basaltic magma into colder water-saturated andesitic to dacitic bodies leads to drastic changes in physical conditions. The two components; the basaltic xenoliths are quenched and homogeneized with their host lavas with respect to T^o;fO₂ andpH₂O conditions. « H type » xenoliths represent original mostly liquid basalts in which such physical changes lead to the formation of hornblende and the development of a vacuolar and hyalodoleritic texture. The temperature increase of the acid magma depends on the amount of the intruding basalt and on the thermal contrast between the two components. The textural diversity which characterizes the xenoliths reflects the cooling rate of the basaltic fragments and/or their position relative to the basaltic bodies (chilled margins or inner, more crystallized, portions). In addition to physical equilibration (T, fO₂) between the magmas, mixing involves:

mechanical transfer of phenocrysts from one component to another, in both directions;

volatile transfer to the basaltic xenoliths, with chemical exchanges.

It is here demonstrated that a short period of time (some ten hours to a few days) separates the mixing event from the eruption, outlining the importance of magma mixing in the triggering of eruption. The common occurrence of basaltic xenoliths (generally of « H » type) in calc-alkaline lavas is emphasized, showing that this mechanism is of first importance in calc-alkaline magma petrogenesis.     

Mineralogical and geochemical evolution of the 1982–1983 Galunggung eruption (Indonesia)

Pyroclastic deposits from the 1982–1983 eruption of Galunggung volcano (Java, Indonesia) reflect preeruptive magmatic evolution which is of interest because of: (1) its duration of nine months, compared to a few hours or days for most historical eruptions; (2) the diversity of eruptive styles, from ash and scoria flows to phreatomagmatic explosions, and to the strombolian activity that marked the end of the eruption; and (3) the progressive variation in chemical composition with time, from andesite (58 wt.% SiO₂) to high-Mg basalt (47 wt.% SiO₂). The 1982–1983 Galunggung basalts are rather primitive: 10 to 12 wt% MgO, 180 to 200 ppm Ni and 550 to 700 ppm Cr. Despite the presence of about 40% phenocrysts, they may represent the most primitive basalts recognized in western Java. Basalts contain phenocrysts of olivine (Fo_90-80), diopside-salite, and plagioclase (An_95-75). Andesites contain plagioclase (An_80–60), augite, hypersthene (En_67-64), and titanomagnetite. The distribution of mineral compositions in each petrographic type is nearly unimodal, although scarce plagioclase and olivine xenocrysts have been observed. Abundance of gabbroic cumulates associated with the pyroclastic flows and evolution of mineral compositions from high-Mg basalts to andesites support crystal fractionation as the main differentiation mechanism, although magma mixing of basaltic andesite and andesite cannot be excluded. Major and trace element trends, which display rough decreases of MgO, CaO, Ni, Cr with increasing degree of differentiation and also linear positive correlations of hygromagmaphile elements, are compatible with both processes. However, some discrepancies are observed between major and trace element modelling, which may be explained to some extent by the influence of in situ crystallization and/or magma mixing. The constancy of ¹⁴³Nd/¹⁴⁴Nd (0.51286±3), ²³⁰Th/²³²Th (0.65±0.02), Th/U (4.08±0.07) ratios, and to a lesser extent ¹⁸O values (+5.8 to +6.4 % SMOW) and ⁸⁷Sr/⁸⁶Sr ratios (0.70440 to 0.70468) is compatible with a magmatic evolution through fractional crystallization without significant crustal contamination. Nevertheless low-¹⁸O and high ⁸⁷Sr/⁸⁶Sr values in basaltic andesites may be due to the introduction of meteoric fluids into the Galunggung magma.     

Potassium-rich volcanic rocks of the Muriah complex, Java, Indonesia: Products of multiple magma sources?

The extinct Pleistocene volcano Muriah, situated behind the main Pleistocene—Recent Sunda magmatic arc in north-central Java, has erupted at least two contrasted groups of lavas. One group forms a well-defined compositional series (Anhydrous Series) from leucite basanite to tephritic phonolite, with olivine and tschermakitic clinopyroxene the main phenocrysts. The other group, the “Hydrous Series”, includes compositionally variable tephrites and high-K andesites with common plagioclase, biotite and amphibole. Lavas of the Anhydrous Series are much richer in LIL trace elements than the most potassic lavas of neighbouring active volcanoes, but relative HFS element enrichment is less pronounced. REE patterns have almost constant slopes from La (250–600 times chondrites) to Yb (5–10 times chondrites), while those of lavas of active centres are less light-enriched, and show flattening in the heavy REE. Anhydrous Series initial ⁸⁷Sr/⁸⁶Sr ratios (0.7043–0.7046) are lower than those of active centres (0.7047–0.7053). Hydrous Series lavas are intermediate in all these geochemical characteristics.The most mafic A-series leucite basanite, with Mg/(Mg + Fe²⁺) 0.69, 140 ppm Ni and 620 ppm Cr was probably derived from the primary magma for the series by fractionation of only 5 wt.% olivine. Its REE pattern suggests derivation from a garnet-bearing source. Experiments on this basanite, with up to 10% olivine and 20% orthopyroxene added, and in the presence of H₂O and H₂O/CO₂ mixtures, have shown that for all but very high magma water contents, the olivine and garnet liquidus fields are widely separated by fields of phlogopite and clinopyroxene. There is no liquidus field of orthopyroxene. Hence, if magma production involved an equilibrium melting process alone, the most probable sources are of garnet-bearing phlogopite clinopyroxenite type. Alternatively, this magma may represent the end-product of interaction between a low-K basanite magma from a garnet lherzolite source in the asthenosphere and a phlogopite-bearing lherzolite zone in the lower lithosphere. Its production was probably related to crustal doming and extension superimposed on the dominant subduction regime. Hydrous Series magmas may have resulted from mixing between Anhydrous Series magmas and high-K calc-alkaline basaltic to andesitic magmas more directly related to subduction processes.     

Petrologic investigations of the 1995 and 1996 eruptions of Ruapehu volcano, New Zealand: formation of discrete and small magma pockets and their intermittent discharge

 Ruapehu volcano erupted intermittently between September and November 1995, and June and July 1996, producing juvenile andesitic scoria and bombs. The volcanic activity was characterized by small, sequential phreatomagmatic and strombolian eruptions. The petrography and geochemistry of dated samples from 1995 (initial magmatic eruption of 18 September 1995, and two larger events on 23 September and 11 October), and from 1996 (initial and larger eruptions on 17–18 June) suggest that episodes of magma mixing occurred in separate magma pockets within the upper part of the magma plumbing system, producing juvenile andesitic magma by mixing between relatively high (1000–1200  °C)- and low (∼1000  °C)- temperature (T) end members. Oscillatory zoning in pyroxene phenocrysts suggests that repeated mixing events occurred prior to and during the 1995 and 1996 eruptions. Although the 1995 and 1996 andesitic magmas are products of similar mixing processes, they display chronological variations in phenocryst clinopyroxene, matrix glass, and whole-rock compositions. A comparison of the chemistry of magnesian clinopyroxene in the four tephras indicates that, from 18 September through June 1996, the tephras were derived from at least two discrete high-temperature (high-T) batches of magma. Crystals of magnesian clinopyroxene in the 23 September and 11 October tephras appear to be derived from different high-T magma batches. Whole-rock and matrix-glass compositions of all tephras are consistent with their derivation from distinct mixed melts. We propose that, prior to 1995 there was a shallow low-temperature (low-T) magma storage system comprising crystal-rich mush and remnant magma from preceding eruptive episodes. Crystal clots and gabbroic inclusions in the tephras attest to the existence of relict crystal mush. At least two discrete high-T magmas were then repeatedly injected into the mush zone, forming discrete and mixed magma pockets within the shallow system. The intermittent 1995 and 1996 eruptions sequentially tapped these magma pockets. Received: 1 April 1998 / Accepted: 22 December 1998     

The petrology, phase relations and tectonic setting of basalts from the taupo volcanic zone, New Zealand and the Kermadec Island arc - havre trough, SW Pacific

Volcanism in the Taupo Volcanic Zone (TVZ) and the Kermadec arc-Havre Trough (KAHT) is related to westward subduction of the Pacific Plate beneath the Indo-Australian Plate. The tectonic setting of the TVZ is continental whereas in KAHT it is oceanic and in these two settings the relative volumes of basalt differ markedly. In TVZ, basalts form a minor proportion (< 1%) of a dominant rhyolite (97%)-andesite association while in KAHT, basalts and basaltic andesites are the major rock types. Neither the convergence rate between the Pacific and Indo-Australian Plates nor the extension rates in the back-arc region or the dip of the Pacific Plate Wadati-Benioff zone differ appreciably between the oceanic and continental segments. The distance between the volcanic front and the axis of the back-arc basin decreases from the Kermadec arc to TVZ and the distance between trench and volcanic front increases from around 200 km in the Kermadec arc to 280 km in TVZ. These factors may prove significant in determining the extent to which arc and backarc volcanism in subduction settings are coupled.All basalts from the Kermadec arc are porphyritic (up to 60% phenocrysts) with assemblages generally dominated by plagioclase but with olivine, clinopyroxene and orthopyroxene. A single dredge sample from the Havre Trough back arc contains olivine and plagioclase microphenocrysts in glassy pillow rind and is mildly alkaline (< 1% normative nepheline) contrasting with the tholeiitic nature of the other basalts. Basalts from the TVZ contain phenocryst assemblages of olivine + plagioclase ± clinopyroxene; orthopyroxene phenocrysts occur only in the most evolved basalts and basaltic andesites from both TVZ and the Kermadec Arc.Sparsely porphyritic primitive compositions (Mg/(Mg+Fe²) > 70) are high in Al₂O₃ (>16.5%), and project in the olivine volume of the basalt tetrahedron. They contain olivine (Fo₈₇) phenocrysts and plagioclase (> An₆₀) microphenocrysts. These magmas have ratios of CaO/Al₂O₃, A1₂O₃/TiO₂ and CaO/TiO₂ in the range of MORB and MORB picrites and can evolve to the low-pressure MORB cotectic by crystallisation of olivine±plagiociase. Such rocks may be the parents of other magmas whose evolutionary pathways are complicated by interaction of crystal fractionation, crystal accumulation and mixing processes and the filtering action of crust of variable density and thickness. The interplay of these processes likely accounts for the scatter of data about the cotectic. More evolved rocks from both TVZ and KAHT contain clinopyroxene and orthopyroxene phenocrysts and their compositions merge with basaltic andesites and andesites. Stepwise least-squares modelling using phenocryst assemblages in proportions observed in the rocks suggest that crystal fractionation and accumulation processes can account for much of the diversity observed in the major-element compositions of all lavas.We conclude that the parental basaltic magmas for volcanism in the TVZ and KAHT segments are similar thereby implying grossly similar source mineralogy. We attribute the diversity to secondary processes influencing liquids as they ascended through complex plumbing systems in the sub arc mantle and cross.     

Eruption episodes and magma recharge events in andesitic systems: Mt Taranaki,New Zealand

Eruption episodes, where a series of eruption events are generically related, can include the eruption of a wide spectrum of volcanic activity over decadal periods. This paper concentrates on the opening phases of an eruption episode which occurred approximately 1800 yrs BP from Mt Taranaki, New Zealand. These events spanned the eruption of differing bulk compositions and styles from two distinct vent locations; an andesitic sub-plinian eruption from the summit vent and a scoria cone-building eruption of basaltic magma from a satellite vent. Compositional profiles and zoning textures of plagioclase, amphibole and clinopyroxene phenocrysts from the opening andesitic event show evidence of magma mixing and subsequent crystallisation just prior to the initiation of the eruption episode. Titanomagnetite grain morphology and Ti variation suggest that the magma mixing event occurred within a few days to weeks before the eruption acting as a trigger for it. We present a magmatic model which is constrained by the petrological observations and eruptions of the episode. In this model magma differentiation at depth causes its rise and recharging of a mid-crustal magma storage area at 5–7 km. Although the recharging magma differed slightly in oxygen fugacity and temperature, it was compositionally and physically similar enough to the residing andesitic magma to allow efficient mixing. The petrological characteristics described here can be readily observed and enable identification of mixing events in other recent eruption episodes.     

Structural,stratigraphic, and petrologic aspects of the Arenal-Chato volcanic system,Costa Rica: Evolution of a young stratovolcanic complex

Geologic mapping on a scale of 1:10000 and detailed stratigraphic studies of lava flows and tephra deposits of the Arenal-Chato volcanic system reveal a complex and cyclic volcanic history. This cyclicity provides insight into the evolution of magma batches during the growth of the andesitic volcanic system. The Arenal and Chato volcanoes have a central zone comprised of a lava armor and a distal zone comprised of a tephra apron. During Arenal's last two eruptive periods major craters formed near intersections of regional fractures at the lava armortephra apron transition. We suggest that such intersections are potential sites for future major explosions. The earliest rocks, i.e., the Chato lava flows, range in composition from basaltic andesite to andesite. These rocks, except for the andesitic domes of Chatito and La Espina, appear to have evolved from a common parental magma. The last active period of Chato volcano occurred 3550 B. P. The earliest known activity of Arenal volcano is 2900 B. P. Arenal lava flows have 54–56 wt% SiO₂ and may be subdivided into a high-alumina group (HAG, Al₂O₃ = 20 wt%) and a low-alumina group (LAG, Al₂O₃ = 19 wt%). Compared to the HAG, the LAG also has smaller amounts of incompatible elements and higher amounts of FeO and MgO. Arenal tephra deposits were emplaced by Plinian-Sub-Plinian explosions occurring at 300±150-yr intervals. These deposits are compositionally zoned and alternate between dacite and basalt. The stratigraphy reveals an apparent magmatic cycle consisting of (a) dacitic-andesitic tephra, (b) HAG lava flows, (c) LAG lava flows, and (d) andesitic-basaltic tephra. This magmatic cycle is repeated four times during Arenal's history and is interpreted to have developed by the crystal fractionation and crystal redistribution of a single magma batch. The period of this cycle, and consequently the life of a magma batch, is about 800 years. If the cyclic pattern continues, a basaltic explosive phase may occur in the next 250 years.     

Short time scales of magma-mixing processes prior to the 2011 eruption of Shinmoedake volcano, Kirishima volcanic group, Japan

We estimated time scales of magma-mixing processes just prior to the 2011 sub-Plinian eruptions of Shinmoedake volcano to investigate the mechanisms of the triggering processes of these eruptions. The sequence of these eruptions serves as an ideal example to investigate eruption mechanisms because the available geophysical and petrological observations can be combined for interpretation of magmatic processes. The eruptive products were mainly phenocryst-rich (28 vol%) andesitic pumice (SiO₂ 57 wt%) with a small amount of more silicic pumice (SiO₂ 62–63 wt%) and banded pumice. These pumices were formed by mixing of low-temperature mushy silicic magma (dacite) and high-temperature mafic magma (basalt or basaltic andesite). We calculated the time scales on the basis of zoning analysis of magnetite phenocrysts and diffusion calculations, and we compared the derived time scales with those of volcanic inflation/deflation observations. The magnetite data revealed that a significant mixing process (mixing I) occurred 0.4 to 3 days before the eruptions (pre-eruptive mixing) and likely triggered the eruptions. This mixing process was not accompanied by significant crustal deformation, indicating that the process was not accompanied by a significant change in volume of the magma chamber. We propose magmatic overturn or melt accumulation within the magma chamber as a possible process. A subordinate mixing process (mixing II) also occurred only several hours before the eruptions, likely during magma ascent (syn-eruptive mixing). However, we interpret mafic injection to have begun more than several tens of days prior to mixing I, likely occurring with the beginning of the inflation (December 2009). The injection did not instantaneously cause an eruption but could have resulted in stable stratified magma layers to form a hybrid andesitic magma (mobile layer). This hybrid andesite then formed the main eruptive component of the 2011 eruptions of Shinmoedake.     

Subdivision of the Archean lavas of the Abitibi area,Canada, from Fe-Mg-Ni-Cr relations

The lavas of a part of the Archean Abitibi region may be divided into three stratigraphic levels in each of which FeO-MgO-Ni-Cr contents conform to certain broad differentiation trends. Within each stratigraphic level, there is a tendency for rocks to become more felsic upwards. The earliest and stratigraphically lowest subdivision is composed largely of magnesium-rich basaltic lavas called the magnesian suite. In the central part of the pile, where basalts predominate, the lavas contain intermediate MgO concentrations, and display pronounced Fe enrichment in intermediate members similar to conventional tholeiites. In the latest and stratigraphically highest lavas, where andesites predominate, Fe depletion is characteristic; these lavas are grouped into a primitive calcalkaline suite. All of the Abitibi lavas contain unusually high Ni and Cr. Other Archean lava piles appear to be similarly divisible, although all three suites are not always present.Mafic end-members of the three complete differentiation suites are viewed as possible source magmas derived by partial melting in a primitive, olivine-rich parent, probably the Archean mantle. The earliest, and highest temperature magmas precipitated olivine, Al-clinopyroxene, and minor Al-orthopyroxene, and display moderate FeO, TiO₂, MnO, Al₂O₃, and CaO enrichment in more felsic members. The intermediate age lavas, derived originally by less complete melting in the parent, precipitated plagioclase, olivine, and lesser clinopyroxene, and display, as a result, strong Fe enrichment until, in intermediate members, magma volumes became small enough to yield P_f of levels sufficient to form clinopyroxene plus magnetite. The uppermost lavas, derived by relatively small volumetric melting in the parent, contain abundant Fe-Ti oxides in even the most mafic members, along with augite and plagioclase.     

The 1999 and 2000 eruptions of Mount Cameroon: eruption behaviour and petrochemistry of lava

Mount Cameroon (4,095 m high and with a volume of ~1,200 km³) is one of the most active volcanoes in Africa, having erupted seven times in the last 100 years. This stratovolcano of basanite and hawaiite lavas has an elliptical shape, with over a hundred cones around its flanks and summit region aligned parallel to its NE--SW-trending long axis. The 1999 (28 March–22 April) eruption was restricted to two sites: ~2,650 m (site 1) and ~1,500 m (site 2). Similarly, in the eruption in 2000 (28 May–19 June), activity occurred at two sites: ~4,095 m (site 1) and ~3,300 m (site 2). During both eruptions, the higher vents were more explosive, with strombolian activity, while the lower vents were more effusive. Accordingly, most of the lava (~8×10⁷ m³ in 1999 and ~6×10⁶ m³ in 2000) was emitted from the lower sites. The 1999–2000 lavas are predominantly basanites with low Ni (5–79 ppm), Cr (40–161 ppm) and mg numbers (34–40). Olivine (Fo_77–85, phenocrysts and Fo_68–72, microlites), clinopyroxene (Wo₄₇En₄₁Fs₁₀ to Wo₅₁En₃₄Fs₁₅), plagioclase (An_49–67) and titanomagnetite are the principal phenocryst and groundmass phases. The lavas contain xenocrysts of olivine and clinopyroxene, which are interpreted as fragments of intrusive rocks disrupted by magma ascent. Major and trace element characteristics point to early fractionation of olivine. The clinopyroxenes (Al₂O₃ 1.36–7.83 wt%) have high Al^iv/Al^vi ratios (1.3–1.8) and are rich in TiO₂, characteristics typical of low pressure clinopyroxenes. Geochemical differences between the 1999–2000 lavas and those from previous eruptions, such as higher Nb/Zr of the former, suggest that different eruptions discharged magmas that evolved differently in space and time. Geophysical and petrological data indicate that these fractionated magmas originated just below the geophysical Moho (at 20–22 km) in the lithospheric mantle. During ascent, the magmas disrupted intrusions and earlier magma pockets. The main ascent path is below the summit, where newly arrived magma degasses. Degassed magma simultaneously intrudes the flank rift zones where most lava is extruded.An erratum to this article can be found at     

Relations of cinder cones to the magmatic evolution of Mount Mazama,Crater Lake National Park,Oregon

Cinder cones at Crater Lake are composed of high-alumina basaltic to andesitic scoria and lavas. The Williams Crater Complex, a basaltic cinder cone with andesitic to dacitic lava flows, stands on the western edge of the caldera, against an andesite flow from Mount Mazama. Bombs erupted from Williams Crater contain cores of banded andesite and dacite, similar to those erupted during the climatic eruption of Mount Mazama.Major- and trace-element variations exhibit an increase in incompatible elements and a decrease in compatible elements, consistent with crystal fractionation of olivine, plagioclase, clinopyroxene, orthopyroxene, and magnetite. LREE patterns in the rocks are irregular; each successive basalt is enriched in LREE relative to the preceding andesite.Compositional variations in the magmas of the cinder cones suggest that three magmatic processes were involved, partial melting, fractional crystallization, and magma mixing. Partial melting of more than one source produced primary basaltic magma(s). Subsequent mixing and fractional crystallization produced the more differentiated basaltic to andesitic magmas.     

Petrology and geochronology of basalt breccia from the 1996 earthquake swarm of Loihi seamount, Hawaii: magmatic history of its 1996 eruption

 Samples of basalt were collected during the Rapid Response cruise to Loihi seamount from a breccia that was probably created by the July to August 1996 Loihi earthquake swarm, the largest swarm ever recorded from a Hawaiian volcano. ²¹⁰Po–²¹⁰Pb dating of two fresh lava blocks from this breccia indicates that they were erupted during the first half of 1996, making this the first documented historical eruption of Loihi. Sonobuoys deployed during the August 1996 cruise recorded popping noises north of the breccia site, indicating that the eruption may have been continuing during the swarm. All of the breccia lava fragments are tholeiitic, like the vast majority of Loihi's most recent lavas. Reverse zoning at the rim of clinopyroxene phenocrysts, and the presence of two chemically distinct olivine phenocryst populations, indicate that the magma for the lavas was mixed just prior to eruption. The trace element geochemistry of these lavas indicates there has been a reversal in Loihi's temporal geochemical trend. Although the new Loihi lavas are similar isotopically and geochemically to recent Kilauea lavas and the mantle conduits for these two volcanoes appear to converge at depth, distinct trace element ratios for their recent lavas preclude common parental magmas for these two active volcanoes. The mineralogy of Loihi's recent tholeiitic lavas signify that they crystallized at moderate depths (∼8–9 km) within the volcano, which is approximately 1 km below the hypocenters for earthquakes from the 1996 swarm. Taken together, the petrological and seismic evidence indicates that Loihi's current magma chamber is considerably deeper than the shallow magma chamber (∼3–4 km) in the adjoining active shield volcanoes. Received: 21 August 1997 / Accepted: 15 February 1998     

Petrology and genetic significance of an ultramafic xenolith suite from Tahiti

A suite of ultramafic xenoliths 2–10 cm in size occurs in basanite near Papeete, Tahiti, and consists of spinel lherzolites with minor dunites and wehrlites. Petrographic examination of xenoliths reveals that they are typically coarse grained with well-developed annealed textures. Microprobe analyses of constituent minerals in 11 xenoliths indicate that bulk compositions of xenoliths are magnesian but with significant variability from xenolith to xenolith especially in Fe/Mg and Cr/Al ratios and in absolute amounts of Al₂O₃ and Cr₂O₃. Within any single xenolith, however, coexisting minerals are homogeneous and appear to be compositionally equilibrated. Geothermometry of coexisting orthopyroxene and augite indicates temperatures of equilibration of about 1100°C but there is considerable uncertainty in this estimate due to significant non-quadrilateral pyroxene substitutions. There is no accurate way to determine pressures, but the ubiquity of Cr-poor spinel and absence of garnet imply pressures less than about 15–20 kbar.The margins of most xenoliths show significant alteration through reaction with enclosing alkaline magma. Principal reaction features include zoning of spinels and olivines toward compositions in equilibrium with the magma, and reaction-melting of orthopyroxene to a symplectite of olivine plus silica-rich glass. Glass composition profiles across the symplectites indicate that alkalis, titanium and aluminum diffused into the symplectite from the magma and that silica diffused into the magma. All glass analyses show very low iron, magnesium and calcium.Xenolith mineral assemblages and chemistry indicate their origin in the upper mantle at relatively shallow depths. They are therefore not related genetically to the enclosing basanite magma which came from deeper in the mantle, but rather are accidental fragments of country rock picked up by magma on its way to the surface. The details of the reaction features strongly imply that the magma had partially crystallized by the time it reacted with xenoliths, possibly while still in the mantle.