Seasonal variability of surface and internal M<Subscript>2</Subscript> tides in the Arctic Ocean

The modeling results of surface and internal M₂ tides for summer and winter periods in the Arctic Ocean (AO) are presented. We employed a modified version of the three-dimensional finite-element hydrothermodynamic model QUODDY-4 differing from the original model by using a rotated (instead of spherical) coordinate system and by considering the equilibrium-tide effects. It has been shown that the modeling results for the surface tide differs little from the results obtained earlier by other authors. According to these results, the amplitudes of internal tidal waves (ITWs) in the AO are significantly lower than in other oceans and the ITWs proper have the character of trapped waves. Their source of generation is located at the continental slope northwest of the New Siberian Islands. Our results are consistent with the fields of average (over a tidal cycle) and integral (by depth) densities of baroclinic tidal energy, the maximum baroclinic tidal velocity, and the coefficient of diapycnic mixing. The local rate of baroclinic tidal energy dissipation at the AO ridges increases as it approaches the bottom, as was observed on Mid-Atlantic and Hawaii ridges (but merely within the bottom boundary layer) and is two to three orders of magnitude lower than in other oceans. The ITW degeneration scale in the AO is several hundreds of kilometers in summer and winter, remaining within the range of its values between 100 and 1000 km in mid- and low-latitude oceans. In both seasons, the integral (over the AO area) rate of baroclinic tidal energy dissipation is two orders of magnitude lower than the global estimate (2.5 × 10¹² W).     

Effect of spatial inhomogeneity of the resistance coefficient on the dynamics of the <Emphasis Type="Italic">M</Emphasis><Subscript>2</Subscript> tidal wave in the White Sea

To find variations in the dynamics of the surface M ₂ tide in the White Sea induced by the spatially inhomogeneity of the resistance coefficient, we use a modified version of the QUODDY-4 three-dimensional finite-element hydrostatic model. This version differs from the original version in that it has a module introduced to calculate the resistance coefficient in the bottom boundary layer (BBL). The resistance coefficient is found from resistance laws for an oscillating rotating turbulent BBL over hydrodynamically rough and partially rough (smoothly rough) underlying surfaces describing the dependence of the resistance coefficient and other integral characteristics of resistance on dimensionless similarity parameters: the sea-bottom Rossby number Ro, the streaming Reynolds number Re, and the relative (normalized to tidal frequency) inertial frequency f/σ. The use of spatial inhomogeneity of the resistance coefficient was shown not to lead to considerable changes in tidal characteristics. The values of these characteristics are several times larger than the instrumental measurement errors for the level and velocity but less than the errors in their calculation.     

Vertical structure of the M<Subscript>2</Subscript> tidal current in the Yellow Sea

The vertical structure of the M₂ tidal current in the Yellow Sea is analyzed from data acquired using an acoustic Doppler current profiler. The observed vertical profiles of the M₂ tidal current are decomposed into two rotating components of counter-clockwise and clockwise, and restructured using a simple one-point model with a constant vertical eddy viscosity. The analyzed results show that the internal fictional effect dominates the vertical structure of the tidal current in the bottom boundary layer. In the Yellow Sea, the effect of the bottom friction reduces the current speed by about 20–40% and induces the bottom phase advance by about 15–50 minutes. In the shallower coastal regions, the effects of bottom topography are more prominent on the vertical structure of tidal currents. The vertical profile of the tidal current in summer, when the water column is strongly stratified, is disturbed near the pycnocline layer. The stratification significantly influences the vertical shear and distinct seasonal variation of the tidal current.     

Basin-scale distribution of NH<Subscript>4</Subscript><Superscript>+</Superscript> and NO<Subscript>2</Subscript><Superscript>−</Superscript> in the Pacific Ocean

We used more than 25,000 nutrient samples to elucidate for the first time basin-scale distributions and seasonal changes of surface ammonium (NH₄ ⁺) and nitrite (NO₂ ^?) concentrations in the Pacific Ocean. The highest NH₄ ⁺, NO₂ ^?, and nitrate (NO₃ ^?) concentrations were observed north of 40°N, in the coastal upwelling region off the coast of Mexico, and in the Tasman Sea. NH₄ ⁺ concentrations were elevated during May–October in the western subarctic North Pacific, May–December in the eastern subarctic North Pacific, and June–September in the subtropical South Pacific. NO₂ ^? concentrations were highest in winter in both hemispheres. The seasonal cycle of NH₄ ⁺ was synchronous with NO₂ ^?, NO₃ ^?, and satellite chlorophyll a concentrations in the western subtropical South Pacific, whereas it was synchronous with chlorophyll-a but out of phase with NO₂ ^? and NO₃ ^? in the subarctic regions.     

Simulation of surface and internal semidiurnal tides in the Kara Sea

The problem of the dynamics of surface and internal waves M ₂ in the Kara Sea is solved within the QUODDY-4 3D finite-element hydrostatic model. It is shown that the conventional concept of surface-tide wave generation due to the interaction of two tidal waves (one arrives from the Barents Sea and the other is generated in the Arctic Ocean (AO) and propagates southward along the west coasts of Severnaya Zemlya) is only partially valid: the east branch of the tidal wave generated in the AO actually exists, but there is also a west branch that propagates along the St. Anna trough and another tidal wave that penetrates in the Kara Sea from the Laptev Sea through the Vilkitsky Strait. Simulated spatial distributions of the tidal velocities, amplitudes of internal tidal waves at the pycnocline depth, and some components of the budgets of barotropic and baroclinic tidal energy are discussed.     

Accurate ocean tide modeling in southeast Alaska and large tidal dissipation around Glacier Bay

An accurate prediction of ocean tides in southeast Alaska is developed using a regional, barotropic ocean model with a finite difference scheme. The model skill is verified by the observational tidal harmonics in southeast Alaska including Glacier Bay. The result is particularly improved in Glacier Bay compared to the previous model described by Foreman et al. (2000). The model bathymetry dominates the model skill. We re-estimate tidal energy dissipation in the Alaska Panhandle and suggest a value for tidal energy dissipation of 3.4 GW associated with the M₂ constituent which is 1.5 times the estimation of Foreman et al. (2000). A large portion of the M₂ energy budget entering through Chatham Strait is dissipated in the vicinity of Glacier Bay. Moreover, it is shown that the developed model has the potential to correct the ocean tide loading effect in geodetic data more efficiently than the model of Foreman et al. (2000), especially around Glacier Bay.     

Influence of the White Sea on tides in adjacent marginal seas of the North European Basin

An investigation into the interaction of surface M ₂ tides in the system of marginal seas of the North European Basin is carried out using the three-dimensional finite-element hydrostatic model QUODDY-4. Three numerical experiments are performed for this purpose. In the first (control), the model equations are solved in the system of the Norwegian, Greenland, Barents, and White seas; thereby the interaction of the tides in these seas is explicitly taken into account. In the second experiment, the White Sea is excluded from consideration and the no-flux condition is posed at the entrance to the sea. The third experiment uses an approach in which the observed tidal elevations that determine the existence of a finite horizontal transport of barotropic energy to the White Sea are specified at the open boundary of the White Sea. It is shown that changes in tidal dynamics represented by changes in the amplitudes and phases of tidal elevations and in the barotropic tidal velocity ellipse parameters are within the model noise in experiments 2 and 3 when compared with the control experiment. On the contrary, changes in energy characteristics (the horizontal wave transport, density, and dissipation rate of barotropic tidal energy) are equal to or greater (in order of magnitude) than the energy characteristics themselves.     

Comparing data obtained from ground-based measurements of the total contents of O<Subscript>3</Subscript>, HNO<Subscript>3</Subscript>,HCl,and NO<Subscript>2</Subscript> and from their numerical simulation

Chemistry climate models of the gas composition of the atmosphere make it possible to simulate both space and time variations in atmospheric trace-gas components (TGCs) and predict their changes. Both verification and improvement of such models on the basis of a comparison with experimental data are of great importance. Data obtained from the 2009–2012 ground-based spectrometric measurements of the total contents (TCs) of a number of TGCs (ozone, HNO₃, HCl, and NO₂) in the atmosphere over the St. Petersburg region (Petergof station, St. Petersburg State University) have been compared to analogous EMAC model data. Both daily and monthly means of their TCs for this period have been analyzed in detail. The seasonal dependences of the TCs of the gases under study are shown to be adequately reproduced by the EMAC model. At the same time, a number of disagreements (including systematic ones) have been revealed between model and measurement data. Thus, for example, the EMAC model underestimates the TCs of NO₂, HCl, and HNO₃, when compared to measurement data, on average, by 14, 22, and 35%, respectively. However, the TC of ozone is overestimated by the EMAC model (on average, by 12%) when compared to measurement data. In order to reveal the reasons for such disagreements between simulated and measured data on the TCs of TGCs, it is necessary to continue studies on comparisons of the contents of TGCs in different atmospheric layers.     

Verification studies for a z-coordinate primitive-equation model: Tidal conversion at a mid-ocean ridge

We document the accuracy and convergence of solutions for a z-coordinate primitive-equation model of internal tide generation and propagation. The model, which is based on MOM3 numerics, is linearized around a state of rest to facilitate comparison with analytic estimates of baroclinic generation at finite-amplitude topography in a channel forced by barotropic tidal flow at its boundaries. Unlike the analytical model, the numerical model includes mixing of both buoyancy and momentum, and several definitions of “baroclinic conversion” are possible. These are clarified by writing out the energetics of the linearized equations in terms of barotropic kinetic energy, baroclinic kinetic energy, and available potential energy. The tidal conversion computed from the model, defined as the rate of conversion of barotropic kinetic energy into available potential energy, agrees well with analytical predictions. A comparison of different treatments of bottom topography (full-cells, partial-cells, and ghost-cells) indicates that the partial-cell treatment is the most accurate in this application. Convergence studies of flow over a smooth supercritical ridge show that the dissipation along tidal characteristics is, apparently, an integrable singularity. When the ocean bottom is not smooth, the accuracy and convergence of the model depend on the power spectrum of the topography. A numerical experiment suggests that the power spectrum of the resolved topography must roll off faster than k⁻² to obtain convergent results from a linear numerical model of this type.     

胶州湾水交换及湾口潮余流特征的数值研究

利用基于普林斯顿海洋模式建立的胶州湾及临近海域潮汐潮流数值模型,结合胶州湾口走航式声学多普勒海流剖面仪(ADCP)测流资料,研究了胶州湾口的潮(余)流特征,并在潮流模型的基础上耦合建立了水质模块,模拟了胶州湾的水交换过程。考虑M2,S2,K1,O1,M4和MS4六个主要分潮,胶州湾口潮流场的模拟与ADCP观测数据吻合较好。外湾口水道上的潮流非常强,大潮期间观测到201 cm/s的峰值流速。团岛岬角的两侧分别存在一个流向相反的余流涡旋,两涡旋在团岛附近辐合,形成了57 cm/s的离岸强余流。整个胶州湾平均水体存留时间为71 d,平均半交换时间为25 d。胶州湾水体交换能力在空间分布上有很大差异:湾口海域最强,向湾顶逐渐减弱。湾内存在两个弱交换区,分别位于湾的西-西南部和东北端,水体存留时间多超过80 d,湾西局部水域最长达120 d,而半交换时间也大多超过40 d。潮流场的结构、强度,以及与湾口距离的远近是造成湾内水交换能力空间差异的主要原因。     

Numerical Study on Tidal Mixing in the Bohai Sea

The spatial and temporal variability of tidal mixing in Bohai Sea is studied using a numerical approach. In calculating tidal mixing, accurate barotropic tidal current is obtained via a harmonic analysis package utilizing the simulated current output from a high-resolution regional ocean model. And a “small-scale” roughness map is adopted to describe the detailed topographic features of Bohai Sea. It is shown that the tidal mixing estimated in Bohai Sea is much higher than the level of global background, and fluctuates considerably at some regions within a single day. In Liaodong Bay, Bohai Bay and Bohai Strait, the mixing varies greatly, with the peak value of O (10^?2) m² s^?1. The order of magnitude of mixing in Laizhou Bay is about O (10^?5～10^?3) m² s^?1. Mixing with background level of O (10^?5) m² s^?1 only appears in central area. Result also shows that rough topography plays relatively a more important role than tidal current in enhancing diapycnal mixing in Bohai Sea. The distributions of tidal mixing in selected sections reveal that the vertical stratification in Bohai Sea is not obvious, generally renders a barotropic structure.     

Analysis of satellite observations of the tropospheric NO<Subscript>2</Subscript> content over the Moscow region

The tropospheric NO₂ content over the Moscow region is analyzed on the basis of data of the satellite Ozone Monitoring Instrument (OMI) in the period 2004–2009. The spatial distributions of NO₂ are presented, and some of their features are interpreted. The characteristics of the seasonal and weekly cycles of NO₂ are described, as are its interannual and long-term variations. The relationship between the variabilities of the NO₂ content and the aerological parameters is investigated on different time scales. The mutual influence of regional pollution and meteorological regimes is discussed. The seasonal and weekly NO₂ cycles over Moscow are compared with those over the largest worldwide agglomerations.     

Influence of export rain ratio changes on atmospheric CO<Subscript>2</Subscript> and sedimentary calcite preservation

The responses of atmospheric pCO₂ and sediment calcite content to changes in the export rain ratio of calcium carbonate to organic carbon are examined using a diffusion-advection ocean biogeochemical model coupled to a one-dimensional sediment geochemistry model. Our model shows that a 25% reduction in rain ratio decreases atmospheric pCO₂ by 59 ppm. This is caused by alkalinity redistribution by a weakened carbonate pump and an alkalinity increase in the whole ocean via carbonate compensation with decreasing calcite burial. The steady state responses of sedimentary calcite content and calcite preservation efficiency are rather insensitive to the deepening of the saturation horizon of 1.9 km. This insensitivity is a result of the reduced deposition flux that decreases calcite burial, counteracting the saturation horizon deepening that increases calcite burial. However, in the first 10,000 years the effect of reduced calcite deposition on the burial change is more prominent; while after 10,000 years, the effect of saturation horizon deepening is more dominant. The lowering of sediment calcite content for the first 10,000 years is effectively decoupled from the 1.9 km downward shift of the saturation horizon. Our results are in part a consequence of the more dominant role that respiration CO₂ plays in sediment calcite dissolution over bottom water chemistry in our control run and support the decoupling of calcite lysocline depth and saturation horizon shifts, as suggested originally by Archer and Maier-Reimer (1994) and Archer et al. (2000).     

Influence of Introduced CO<Subscript>2</Subscript> on Deep-Sea Metazoan Meiofauna

An experiment was performed to determine the effect of injected CO₂ on the deep-sea (3200 m) meiofaunal community in the Monterey Canyon. Approximately 20 L of liquid CO₂ was added to each of three cylindrical corrals (PVC rings pushed into the seabed) that were arranged in a triangular array 10 m on a side. After a 30-day period, sediment cores were collected within an area exposed to the dissolution plume emanating from the CO₂ pools and from a reference site approximately 40 m away; cores were also collected from within two of the CO₂ corrals. Sediment cores were sectioned into 0–5, 5–10, and 10–20 mm layers. Abundances of major groups (harpacticoid copepods, nematodes, nauplii, kinorhynchs, polychaetes, and total meiofauna) were determined for each layer. CO₂ exposure did not significantly influence the abundances or vertical distributions of any of the major taxa. However, other evidence suggests that abundance alone did not accurately reflect the effect of CO₂ on meiofauna. We argue that slow decomposition rates of meiofaunal carcasses can mask adverse effects of CO₂ and that longer experiments and/or careful examination of meiofaunal condition are needed to accurately evaluate CO₂ effects on deep-sea meiofaunal communities. This revised version was published online in July 2006 with corrections to the Cover Date.     

Retrieval of total ozone in the mesosphere with a new model of electronic-vibrational kinetics of O<Subscript>3</Subscript> and O<Subscript>2</Subscript> photolysis products

The paper presents a new model of electronic-vibrational kinetics of the products of ozone and molecular oxygen photodissociation in the terrestrial middle atmosphere. The model includes 45 excited states of the oxygen molecules O₂(b ¹, Σ _g ⁺ ,v= 0−2), O₂ (a ¹Δ _g , v= 0−5), and O₂(X ³Σ _g ⁻ , v= 1−35) and of the metastable atom O (¹ D) and over 100 aeronomic reactions. The model takes into account the dependence of quantum yields of the production of O₂(a ¹Δ _g , v= 0−5) in a singlet channel of ozone photolysis in the Hartley band on the wavelength of photolytic emission. Taking account of the electronic-vibrational kinetics is important in retrieval of the vertical profiles of ozone concentration from measured intensities of the Atm and IR Atm emissions of the oxygen bands above 65 km and leads to an increase in the ozone concentration retrieved from the 1.27-μm emission, in contrast to the previous model of pure electronic kinetics. Sensitivity analysis of the new model is made for variations in the concentrations of atmospheric constituents ([O₂], [N₂], [O(³P)], [O₃], [CO₂]), the gas temperature, rate constants of the reactions, and quantum yields of the reaction products. A group of reactions that most strongly affect the uncertainty of ozone retrieval from measured intensities of atmospheric emissions of molecular oxygen O₂(b ¹Σ _g ⁺ , v) and O₂(a ¹Δ _g , v) has been determined. Original Russian Text ? V.A. Yankovsky, V.A. Kuleshov, R.O. Manuilova, A.O. Semenov, 2007, published in Izvestiya AN. Fizika Atmosfery i Okeana, 2007, Vol. 43, No. 4, pp. 557–569.     

O<Subscript>2</Subscript> consumption rate and its isotopic fractionation factor in the deep water of the Philippine Sea

Concentration and stable isotopic compositions (δ ¹⁸O) of dissolved O₂ were measured in seawater samples collected from the Philippine Sea in June 2006. The in-situ O₂ consumption rate and the isotopic fractionation factor (α _r ) during dissolved O₂ consumption were obtained from field observations by applying a vertical one-dimensional advection diffusion model to the deep water mass of about 1000–4000 m. The average O₂ consumption rate and α _r were, respectively, 0.11 ± 0.07 μmol kg⁻¹yr⁻¹ and 0.990 ± 0.001. These estimated values agree well with values from earlier estimations of Pacific deep water. The in-situ O₂ consumption rates are two or more times higher north of 20°N, although the value of α _r was not significantly different between the north and south. Its levels varied rapidly in the water mass of less about 2000 m depth. These results suggest that organic matter from the continent imparts a meaningful contribution to the upper water in the northern part of the area; it might produce the strong O₂ minimum that is evident in the water mass from about 1000–2000 m in the northern part of the Philippine Sea.     

Three-dimensional numerical model study of the residual current in the South China Sea

A three-dimensional baroclinic shelf sea model is employed to simulate the tidal and non-tidal residual current in the South China Sea. The four most significant constituents, M₂, S₂, K₁ and O₁, are included in the experiments with tidal effect. At most stations, the computed harmonic constants agree well with the observed ones. The circulations of the South China Sea in summer (August) and winter (December) are mainly discussed. It is shown that the barotropic tidal residual current is too weak to affect the South China Sea circulation, whilst the contribution of the baroclinic tidal residual current to the South China Sea circulation would be important in the continental shelf sea areas, especially in the Gulf of Thailand and Gulf of Tonkin. In the deep-sea areas, the upper barotropic or baroclinic tidal residual current is relatively very weak, however, the speed order of the deep baroclinic tidal residual current can be the same as that of the mean current without tidal effect. Moreover, the baroclinic tidal residual current seems to be related to the different seasonal stratification of ocean.     

Effects of CO<Subscript>2</Subscript> on Marine Fish: Larvae and Adults

CO₂-enriched seawater was far more toxic to eggs and larvae of a marine fish, silver seabream, Pagrus major, than HCl-acidified seawater when tested at the same seawater pH. Data on the effects of acidified seawater can therefore not be used to estimate the toxicity of CO₂, as has been done in earlier studies. Ontogenetic changes in CO₂ tolerance of two marine bony fishes (Pag. major and Japanese sillago, Sillago japonica) showed a similar, characteristic pattern: the cleavage and juvenile stages were most susceptible, whereas the preflexion and flexion stages were much more tolerant to CO₂. Adult Japanese amberjack, Seriola quinqueradiata, and bastard halibut, Paralichthys olivaceus, died within 8 and 48 h, respectively, during exposure to seawater equilibrated with 5% CO₂. Only 20% of a cartilaginous fish, starspotted smooth-hound, Mustelus manazo, died at 7% CO₂ within 72 h. Arterial pH initially decreased but completely recovered within 1-24 h for Ser. quinqueradiata and Par. olivaceus at 1 and 3% CO₂, but the recovery was slower and complete only at 1% for M. manazo. During exposure to 5% CO₂, Par. olivaceus died after arterial pH had been completely restored. Exposure to 5% CO₂ rapidly depressed the cardiac output of Ser. quinqueradiata, while 1% CO₂ had no effect. Both levels of ambient CO₂ had no effect on blood O₂ levels. We tentatively conclude that cardiac failure is important in the mechanisms by which CO₂ kills fish. High CO₂ levels near injection points during CO₂ ocean sequestration are likely to have acute deleterious effects on both larvae and adults of marine fishes. This revised version was published online in July 2006 with corrections to the Cover Date.     

The spatial distribution of surface <Emphasis Type="Italic">f</Emphasis>CO<Subscript>2</Subscript> in the Southwestern East Sea/Japan sea during summer 2005

Fugacity of CO₂ (fCO₂), temperature, salinity, nutrients, and chlorophyll-a were measured in the surface waters of southwestern East Sea/Japan Sea in July 2005. Surface waters were divided into three waters based on hydrographic characteristics: the water with moderate sea surface temperature (SST) and high sea surface salinity (SSS) located east of the front (East water); the water with high SST and moderate SSS located west of the front (West water); and the water with low SST and SSS located in the middle part of the study area (Middle water). High fCO₂ larger than 420 μatm were found in the West water. In the Middle water, CO₂ was undersaturated with respect to the atmosphere, with values between 246 and 380 μatm. Moderate fCO₂ values ranging from 370 to 420 μatm were observed in the East water. For the East and West waters, estimates of temperature dependency of fCO₂ (12.6 and 15.1 μatm °C⁻¹, respectively) were rather similar to a theoretical value, indicating that SST is likely to be a major factor controlling the surface fCO₂ distribution in these two regions. In the Middle water, however, the estimated temperature dependence was somewhat lower than the theoretical value, and relatively high concentrations of surface chlorophyll-a coincided with the low surface fCO₂, implying that biological uptake may considerably affect the fCO₂ distribution. The net sea-to-air CO₂ flux of the study area was estimated to be 0.30±4.81 mmol m⁻² day⁻¹ in summer, 2005.     

Wind influence on water exchange between the ria of Ferrol (NW Spain) and the shelf

The wind-induced water exchange between the ria of Ferrol (NW Spain) and the adjacent shelf is analyzed by means of a three-dimensional hydrodynamic model (MOHID2000). Since thermohaline measurements indicate that the estuary can be considered vertically homogeneous a barotropic version of the model has been used. Real in situ wind measurements have been used for model calibration and further analysis. The approach to study the wind effect on water exchange through the ria strait consisted in subtracting the signal calculated with only tidal forcing (T_s) from the one with wind and tidal forcing (WT_s). This shows the existence of a residual circulation, with water flowing in wind direction along surfaces layers and a counter current flowing in the opposite direction at bottom layers. The flux across the strait of Ferrol has shown to increase linearly on wind strength, with a correlation larger than 96% and reaching values close to 20 m³ s⁻¹ under real wind forcing.