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1.
Experiments at 750 °C, 200 MPa(H2O), a
(H2O)=1, and fO2∼Ni-NiO established that the equilibrium among tourmaline, biotite, cordierite, and melt (± spinel, aluminosilicate, or corundum)
occurs with ∼2 wt% B2O3 in strongly peraluminous melt with an aluminosity, measured by the parameter ASI, of >1.2. The experiments demonstrate the
relationship of tourmaline stability to the activity product of the tourmaline components boron and aluminum, which are inversely
related to one another. Tourmaline is unstable in metaluminous to mildly peraluminous melts (ASI <1.2) at 750 °C regardless
of their boron content. For a given aluminosity, addition of components such as F requires a greater boron content of melt
at this equilibrium. The stability of tourmaline increases with decreasing temperatures below 750 °C. At the inception of
melting, tourmaline breaks down incongruently to assemblages containing crystalline AFM silicates (biotite, cordierite, garnet,
sillimanite), aluminates (spinel, corundum), and B-enriched but Fe-Mg-poor melt. Granitic melts are likely to be undersaturated
in tourmaline from the start of their crystallization, and their initial boron contents will be limited by the abundance of
tourmaline in their source rocks. Quartzofeldspathic (gneissic, metapelitic) rocks that reached conditions of the granulite
facies and still contain (prograde) tourmaline are rare, and probably have never yielded a partial melt. Most leucogranitic
magmas will initially crystallize biotite, cordierite, or garnet, but not tourmaline. With crystallization, the Fe-Mg content
of melt decreases, and the B2O3 content increases until the tourmaline-biotite and/or tourmaline-cordierite (or garnet) equilibria are attained. The B2O3 content of melt is buffered as long as these equilibria continue to operate, but low initial Fe-Mg contents of the magmas
limit the quantity of boron that can be consumed by these reactions to <1 wt% B2O3. Normally, leucogranitic magmas contain insufficient Fe and Mg to conserve all boron as tourmaline and thus lose a large
fraction of magmatic boron to wallrocks. Leucogranites and pegmatites with tourmaline as an early and only AFM silicate mineral
probably contained >2 wt% B2O3 in their bulk magmas.
Received: 6 August 1996 / Accepted: 21 July 1997 相似文献
2.
Phosphorus solubility mechanisms in haplogranitic aluminosilicate glass and melt: effect of temperature and aluminum content 总被引:1,自引:0,他引:1
Bjorn O. Mysen 《Contributions to Mineralogy and Petrology》1998,133(1-2):38-50
The solubility behavior of phosphorus in glasses and melts in the system Na2O-Al2O3-SiO2-P2O5 has been examined as a function of temperature and Al2O3 content with microRaman spectroscopy. The Al2O3 was added (2, 4, 5, 6, and 8 mol% Al2O3) to melts with 80 mol% SiO2 and ∼2 mol% P2O5. The compositions range from peralkaline, via meta-aluminous to peraluminous. Raman spectra were obtained of both the phosphorus-free
and phosphorous-bearing glasses and melts between 25 and 1218 °C. The Raman spectrum of Al-free, P-bearing glass exhibits
a characteristic strong band near 940 cm−1 assigned to P=O stretching in orthophosphate complexes together with a weaker band near 1000 cm−1 assigned P2O7 complexes. With increasing Al content, the proportion of P2O7 initially increases relative to PO4 and is joined by AlPO4 complexes which exhibit a characteristic P-O stretch mode slightly above 1100 cm−1. The latter complex appears to dominate in meta-aluminosilicate glass and is the only phosphate complex in peraluminous glasses.
When P-bearing peralkaline silicate and aluminosilicate glasses are transformed to supercooled melts, there is a rapid decrease
in PO4/P2O7 so that in the molten state, PO4 units are barely discernible. The P2O7/AlPO4 abundance ratio in peralkaline compositions increases with increasing temperature. This decrease in PO4/P2O7 with increasing temperature results in depolymerization of the silicate melts. Dissolved P2O5 in peraluminous glass and melts forms AlPO4 complexes only. This solution mechanism has no discernible influence on the aluminosilicate melt structure. There is no effect
of temperature on this solution mechanism.
Received: 7 October 1997 / Accepted: 11 May 1998 相似文献
3.
A. Mücke 《Mineralogy and Petrology》2003,77(3-4):215-234
Summary ?Detailed petrographic studies and microchemical analyses of titanomagnetite from igneous and metamorphic rocks and ore deposits
form the basis of this investigation. Its aim is to compare the data obtained and their interpretations with the experimentally
deduced subsolidus oxidation-exsolution model of Buddington and Lindsley (1964). The results are also considered relevant for the interpretation of compositional variations in black sands which
are recovered for titanium production. The arrangement of the samples investigated is in accordance with textural stages C1
to C5 caused by subsolidus exsolution with increasing degrees of oxidation (Haggerty, 1991).
Stage 1 is represented by two types of optically homogeneous TiO2-rich magnetite: a. An isotropic type considered to represent solid solutions of magnetite and ulvite containing between 5.2
to 27.5 wt% TiO2 corresponding to about 14.7 to 77.7 mol% Fe2TiO4 in solid solution with magnetite. The general formula of this type is Fe2+
1+x
Fe3+
2−2x
Ti
x
O4 (x = 0.0–1.0). b. The second type which has not been reported so far is anisotropic and shows complex internal twinning resembling
inversion textures. It is thus attributed to inversion of a high-temperature ilmenite modification (with statistical distribution
of the cations) which forms solid solutions with magnetite. TiO2 varies between 9.3 and 24.5 wt% corresponding to about 17.2 to 43.6 mol% ilmenite in solid solution with magnetite. This
type is interpreted as a cation-deficient spinel with the general formula Fe2+
12/12 + 1/4xFe3+
24/12 − 3/2x
□
0 + 1/4x
Ti
x
O4 (x = 0.0–16/12). Isotropic and anisotropic homogeneous magnetites occur in volcanic rocks only; the homogeneity of the solid
solutions was explained by fast cooling which prevented the development of exsolution textures.
Stages 2 and 3 are represented by magnetite with or without ulvite. The magnetite host contains ilmenite lamellae forming
trellis and sandwich textures. In contrast to the requirement of the oxidation-exsolution model, the ilmenite lamellae are
concentrated exclusively in the cores of the host crystals. The reverse host-guest relationship may also occur. Stages 4 and
5 are identical with thermally generated martite (= martite due to heating). The textures are characterized by very broad
lamellae of ferrian ilmenite or titanohematite dominantly concentrated along the margins of the host crystals. Thermally generated
martite is restricted to subsolidus-oxidation reactions.
The ilmenite lamellae of trellis and sandwich textures contain low Fe2O3-concentrations (average 4.8 mol%; to a maximum of 8.3), whereas the Fe2O3-content of thermally generated martite is between 32 to 71 mol%. With respect to the Fe2O3-concentrations in the ilmenite lamellae, no transition between the two types was observed.
The results of this paper show that the widely accepted oxy-exsolution model of Buddington and Lindsley (1964) which is based on experimental results can – with the exception of thermally generated martite – not explain the tremendous
variety of magnetite–ilmenite–ulvite relationships in natural rocks and ore deposits.
Received October 16, 2001; accepted May 2, 2002 相似文献
4.
Summary. ?Ca-tourmaline has been synthesized hydrothermally in the presence of Ca(OH)2 and CaCl2-bearing solutions of different concentration at T = 300–700 °C at a constant fluid pressure of 200 MPa in the system CaO-MgO-Al2O3-SiO2-B2O3-H2O-HCl. Synthesis of tourmaline was possible at 400 °C, but only above 500 °C considerable amounts of tourmaline formed. Electron
microprobe analysis and X-ray powder data indicate that the synthetic tourmalines are essentially solid solutions between
oxy-uvite, CaMg3- Al6(Si6O18)(BO3)3(OH)3O, and oxy-Mg-foitite, □(MgAl2)Al6(Si6O18)(BO3)3(OH)3O. The amount of Ca ranges from 0.36 to 0.88 Ca pfu and increases with synthesis temperature as well as with bulk Ca-concentration
in the starting mixture. No hydroxy-uvite, CaMg3(MgAl5)(Si6O18)(BO3)3(OH)3(OH), could be synthesized. All tourmalines have < 3 Mg and > 6 Al pfu. The Al/(Al + Mg)-ratio decreases from 0.80 to 0.70
with increasing Ca content. Al is coupled with Mg and Ca via the substitutions Al2□Mg−2Ca−1 and AlMg−1H−1. No single phase tourmaline could be synthesized. Anorthite ( + quartz in most runs) has been found coexisting with tourmaline.
Other phases are chlorite, tremolite, enstatite or cordierite.
Between solid and fluid, Ca is strongly fractionated into tourmaline ( + anorthite). The concentration ratio D = Ca(fluid)/Ca(tur) increases from 0.20 at 500 °C up to 0.31 at 700 °C. For the assemblage turmaline + anorthite + quartz + chlorite or tremolite
or cordierite, the relationship between Ca content in tourmaline and in fluid with temperature can be described by the equation
(whereby T = temperature in °C, Ca(tur) = amount of Ca on the X-site in tourmaline, Ca( fluid) = concentration of Ca2+ in the fluid in mol/l). The investigations may serve as a first guideline to evaluate the possibility to use tourmaline as
an indicator for the fluid composition.
Received July 24, 1998;/revised version accepted October 21, 1999 相似文献
Zusammenfassung. ?Synthese von Ca-Turmelin im System CaO-MgO-Al 2 O 3 -SiO 2 -B 2 O 3 -H 2 O-HCl Im System CaO-MgO-Al2O3-SiO2-B2O3-H2O-HCl wurde Ca-Turmalin hydrothermal aus Ca(OH)2 and CaCl2-haltigen L?sungen bei T = 300–700 °C und einem konstanten Fluiddruck von 200 MPa synthetisiert. Die Synthese von Turmalin war m?glich ab 400 °C, aber nur oberhalb von 500 °C bildeten sich deutliche Mengen an Turmalin. Elektronenstrahl-Mikrosondenanalysen und R?ntgenpulveraufnahmen zeigen, da? Mischkristalle der Reihe Oxy-Uvit, CaMg3Al6(Si6O18)(BO3)3(OH)3O, und Oxy-Mg-Foitit, □(MgAl2)Al6(Si6O18)(BO3)3(OH)3O gebildet wurden. Der Anteil an Ca variiert zwischen 0.36 und 0.88 Ca pfu und nimmt mit zunehmender Synthesetemperatur und zunehmender Ca-Konzentration im System zu. Hydroxy-Uvit, CaMg3(MgAl5) (Si6O18)(BO3)3(OH)3(OH), konnte nicht synthetisiert werden. Alle Turmaline haben < 3 Mg und > 6 Al pfu. Dabei nimmt das Al/(Al + Mg)- Verh?ltnis mit zunehmendem Ca-Gehalt von 0.80 auf 0.70 ab. Al ist gekoppelt mit Mg und Ca über die Substitutionen Al2□Mg−2Ca−1 und AlMg−1H−1. Einphasiger Turmalin konnte nicht synthetisiert werden. Anorthit (+ Quarz in den meisten F?llen) koexistiert mit Turmalin. Andere Phasen sind Chlorit, Tremolit, Enstatit oder Cordierit. Ca zeigt eine deutliche Fraktionierung in den Festk?rpern Turmalin (+ Anorthit). Das Konzentrationsverh?ltnis D = Ca(fluid)/Ca(tur) nimmt von 0.20 bei 500 °C auf 0.31 bei 700 °C zu. Für die Paragenese Turmalin + Anorthit + Quarz mit Chlorit oder Tremolit oder Cordierit gilt folgende Beziehung zwischen Ca-Gehalt in Turmalin und Fluid und der Temperatur: (wobei T = Temperatur in °C, Ca(tur) = Anteil an Ca auf der X-Position in Turmalin, Ca(fluid) = Konzentration von Ca2+ im Fluid in mol/l). Die Untersuchungen dienen zur ersten Absch?tzung, ob Turmalin als Fluidindikator petrologisch nutzbar ist.
Received July 24, 1998;/revised version accepted October 21, 1999 相似文献
5.
Nuclear reaction analyses on boron in flux-grown Me3+- and Na+-doped diopside crystals utilising the 11B(p,2α)4He reaction in conjunction with EMP analyses for major elements and optical absorption spectroscopy for determination of Me-valence
state distributions show that appreciable amounts of B may enter the diopside lattice in crystals produced in Na2B4O7 fluxes. The results indicate that the substitution [6]Me3+[4]B3+[6]Mg2+
−1
[4]Si4+
−1 operates in the present diopside samples in addition to the coupled substitution [6]Me3+[8]Na+[6]Mg2+
−1
[8]Ca2+
−1. The specific NRA technique applied allows for quantitative, high resolution (ca. 5 μm) B analyses at ppm level as well as
high-resolution and high-contrast imaging of B-concentration patterns in minerals. The estimated detection limit and relative
error of the B analyses are 10 ppm and 5–10%, respectively.
Received: 20 September 1999 / Accepted: 6 June 2000 相似文献
6.
Jürgen Konzett Daniel J. Frost Alexander Proyer Peter Ulmer 《Contributions to Mineralogy and Petrology》2008,155(2):215-228
Experiments have been conducted in the P-T range 2.5–15 GPa and 850–1,500°C using bulk compositions in the systems SiO2–TiO2–Al2O3–Fe2O3–FeO–MnO–MgO–CaO–Na2O–K2O–P2O5 and SiO2–TiO2–Al2O3–MgO–CaO–Na2O to investigate the Ca-Eskola (CaEs Ca0.5□0.5AlSi2O6) content of clinopyroxene in eclogitic assemblages containing garnet + clinopyroxene + SiO2 ± TiO2 ± kyanite as a function of P, T, and bulk composition. The results show that CaEsss in clinopyroxene increases with increasing T and is strongly bulk composition dependent whereby high CaEs-contents are favoured by bulk compositions with high normative
anorthite and low diopside contents. In this study, a maximum of 18 mol% CaEsss was found at 6 GPa and 1,350°C in a kyanite-eclogite assemblage garnet + clinopyroxene + kyanite + rutile + coesite. By comparison,
no significant increase in CaEsss with increasing P could be observed. If the formation of oriented SiO2-rods frequently observed in eclogititc clinopyroxenes is due to the retrogressive breakdown of a CaEs-component then these
textures are a cooling rather than a decompression phenomenon and are most likely to be found in kyanite-bearing eclogites
cooled from temperatures ≥750°C. The presence of clinopyroxene with approx. 4 mol% CaEsss in an experiment conducted at 2.5 GPa/850°C confirms earlier suggestions based on field data that vacancy-rich clinopyroxenes
are not necessarily restricted to ultrahigh pressure metamorphic conditions.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
7.
Enthalpies of drop solution (ΔH
drop-sol) of CaGeO3, Ca(Si0.1Ge0.9)O3, Ca(Si0.2Ge0.8)O3, Ca(Si0.3Ge0.7)O3 perovskite solid solutions and CaSiO3 wollastonite were measured by high-temperature calorimetry using molten 2PbO · B2O3 solvent at 974 K. The obtained values were extrapolated linearly to the CaSiO3 end member to give ΔH
drop-sol of CaSiO3 perovskite of 0.2 ± 4.4 kJ mol−1. The difference in ΔH
drop-sol between CaSiO3, wollastonite, and perovskite gives a transformation enthalpy (wo → pv) of 104.4 ± 4.4 kJ mol−1. The formation enthalpy of CaSiO3 perovskite was determined as 14.8 ± 4.4 kJ mol−1 from lime + quartz or −22.2 ± 4.5 kJ mol−1 from lime + stishovite. A comparison of lattice energies among A2+B4+O3 perovskites suggests that amorphization during decompression may be due to the destabilizing effect on CaSiO3 perovskite from a large nonelectrostatic energy (repulsion energy) at atmospheric pressure. By using the formation enthalpy
for CaSiO3 perovskite, phase boundaries between β-Ca2SiO4 + CaSi2O5 and CaSiO3 perovskite were calculated thermodynamically utilizing two different reference points [where ΔG(P,T )=0] as the measured phase boundary. The calculations suggest that the phase equilibrium boundary occurs between 11.5 and
12.5 GPa around 1500 K. Its slope is still not well constrained.
Received: 20 September 2000 / Accepted: 17 January 2001 相似文献
8.
G. D. Gwanmesia J. Liu G. Chen S. Kesson S. M. Rigden R. C. Liebermann 《Physics and Chemistry of Minerals》2000,27(7):445-452
Dense isotropic polycrystalline specimens of majorite-rich garnets (Py100, Py62Mj38, Py50Mj50, Py21Mj79 and Mj100) along the pyrope (Mg3Al2Si3O12 = Py100)-majorite (MgSiO3 = Mj100) join were fabricated in a 2000-ton uniaxial split-sphere anvil apparatus (USSA-2000) at pressures from 10 to 18.5 GPa and
temperatures from 1200 to 1850 °C, within their stability fields in runs of 2–4-h duration, using hot-pressing techniques
developed by Gwanmesia et al. (1993). These specimens are single-phased, fine-grained (≤5 mm), free of microcracks, and have
bulk densities greater than 99% of the corresponding single-crystal X-ray density. Elastic compressional (P) and shear (S) wave velocities were determined at room pressure and temperature for these polycrystalline garnet specimens by phase comparison
ultrasonic interferometry. For Mj100, the P and S wave velocities are within 1% of the Hashin-Shtrikman averages calculated from the single crystal elastic moduli measured
by Brillouin spectroscopy. Both the elastic bulk modulus (K) and the shear modulus (G) decrease continuously with increasing majorite content from pyrope garnet (Py100) to pure majorite garnet (Mj100). The compositional dependence of K and G are given by K = 172.3 (40) − 0.085X, and G = 91.6 (10) − 0.038X, where X = mol% majorite), respectively, indicating that substitution of Si for Mg and Al decreases both K and G by about 5% along the solid solution series.
Received: 25 March 1999 / Accepted: 12 July 1999 相似文献
9.
Summary ?Part of the Mesoproterozoic (1.6 Ga) Gawler Range Volcanics in South Australia is composed of mingled feldspar- quartz- phyric
dacite, rhyodacite and rhyolite lavas. Field relationships suggest that dacite erupted first, locally grading into rhyodacite,
followed by mingled dacite and rhyolite or rhyodacite and rhyolite, and finally in some areas rhyolite, and imply that the
three lithofacies co-existed in a compositionally stratified magma chamber. Data on the bulk rock, groundmass and melt inclusion
compositions suggest that post-eruption alteration has had very little effect on the original rock compositions. Melt inclusions
in quartz from rhyolite and rhyodacite-dacite, respectively, belong to two compositional populations. Inclusions in the rhyolitic
quartz have less evolved compositions with lower SiO2 (72–76.4 wt %) and higher Al2O3 (13.2–15.6 wt%) and Na2O (2.5–4.2 wt%) abundances. In contrast, melt inclusions in quartz from the rhyodacite-dacite are more “evolved” (i.e., 75.5–78.3 wt%
SiO2, 11.2–12.7 wt% Al2O3 and 1.7–2.2 wt% Na2O). The two melt populations define a single compositional trend towards groundmass compositions, which are essentially similar
in all three lithofaci es (77.8–80.5 wt% SiO2, 9.9–11.1 wt% Al2O3 and 2.2–2.4 wt% Na2O). This trend is consistent with the derivation of the groundmass melt from a single precursor melt of rhyolitic composition
by means of crystallisation of dominant plagioclase, K-feldspar and minor quartz. Plagioclase-enriched dacite-rhyodacite magma
comprises a mixture of the residual melt and plagioclase phenocryst s that accumulated in the upper part of the magma chamber
and erupted first. Similar residual melt containing quartz and K-feldspar phenocrysts was present deeper in the magma chamber
and erupted later to form quartz-, K-feldspar-phyric rhyolite.
Received April 1, 1999;/revised version accepted July 27, 1999 相似文献
Zusammenfassung ?Die Bildung von Si-reichem Dacit aus rhyolitischer Schmelze: Evidenz aus Schmelzeinschlüssen in Laven der 1.6 Ga Gawler Range Volcanics, Südaustralien Ein Teil der mesoproterozoischen (1.6 Ga) Gawler Range Volcanics in Südaustralien setzt sich aus “mingled” Feldspat- Quarz-phyrischen dacitischen, rhyodacitischen und rhyolithischen Laven zusammen. Gel?ndebefunde legen nahe, da? die Dacite, die lokal in Rhyodacite übergehen, zuerst eruptierten, gefolgt vom “mingled” Dacit und Rhyolith oder Rhyodacit und Rhyolith. Schlie?lich bildeten sich in einigen Gebieten Rhyolithe. Diese Beobachtungen lassen die Schlu?folgerung zu, da? die drei Lithofazies in einer geschichteten Magmenkammer koexistierten. Die Daten der Gesamtgesteins-, Grundmasse- und Schmelzeinschlu?- Zusammensetzungen zeigen, da? Alterationsvorg?nge nach der Eruption einen sehr minimalen Effekt auf die ursprüngliche Gesteinszusammensetzung hatten. Die Schmelzeinschl üsse in den Rhyolithen und Rhyodaciten geh?ren zwei unterschiedlich en Populationen an. Die Schmelzeinschlüsse in Quarz der Rhyolithe sind weniger deutlich “entwickelt” mit niedrigeren SiO2 (72–76.4 Gew.%) und h?heren Al2O3 (13.2–15.6 Gew.%) und Na2O-(2.5–4. 2 Gew.%) Gehalten. Im Unterschied dazu sind die Einschlüss e in Quarz aus Rhyodacit-Dacit st?rker “entwickelt” (i.e., 75.5–78.3 Gew.% SiO2, 11.2–12.7 G ew.% Al2O3 und 1.7–2.2 Gew.% Na2O). Die beiden Populationen von Schmelzeinschlüssen definieren einen einzigen Entwicklungstrend hin zur Zusammensetzung der Grundmasse, die in allen drei Lithofazies ?hnlich ist (77.8–80.5 Gew.% SiO2, 9.9–11.1 Gew.% Al2O3 und 2.2–2.4 Gew.% Na2O). Dieser Trend ist mit der Herkunft der Grundmasse-bildenden Schmelze aus einer einzigen Ausgangsschmelze rhyolithischer Zusammensetzung infolge der Kristallisation von haupts?chlich Plagioklas, Alkalifeldspat und untergeordnet Quarz konsistent. Dacit-Rhyodacitmagmen, die an Plagioklas angereichert sind, stellen eine Mischung der Residualschmelze mit Plagioklas- Ph?nokristallen, die sich in den oberen Teilen der Magmenkammer akkumuli ert haben, dar; sie eruptierten zuerst. ?hnliche residuale Schmelzen mit Quarz und Akalifeldspat-Ph?nokristallen waren auf die tieferen Teilen der Magmenkammer beschr?nkt; sie eruptierten sp?ter und bildeten die Quarz- und Akalifeldspat-phyrischen Rhyolithe.
Received April 1, 1999;/revised version accepted July 27, 1999 相似文献
10.
Structural parameters and cation ordering are determined for four compositions in the synthetic MgGa2O4-Mg2GeO4 spinel solid solution (0, 8, 15 and 23 mol% Mg2GeO4; 1400 °C, 1 bar) and for spinelloid β-Mg3Ga2GeO8 (1350 °C, 1 bar), by Rietveld refinement of room-temperature neutron diffraction data. Sample chemistry is determined by
XRF and EPMA. Addition of Mg2GeO4 causes the cation distribution of the MgGa2O4 component to change from a disordered inverse distribution in end member MgGa2O4, [4]Ga = x = 0.88(3), through the random distribution, toward a normal cation distribution, x = 0.37(3), at 23 mol% Mg2GeO4. An increase in ao with increasing Mg2GeO4 component is correlated with an increase in the amount of Mg on the tetrahedral site, through substitution of 2 Ga3+⇄ Mg2++Ge4+. The spinel exhibits high configurational entropy, reaching 20.2 J mol−1 (four oxygen basis) near the compositional upper limit of the solid solution. This stabilizes the spinel in spite of positive
enthalpy of disordering over the solid solution, where ΔH
D
= αx + βx
2, α = 22(3), β = −21(3) kJ mol−1. This model for the cation distribution across the join suggests that the empirically determined limit of the spinel solid
solution is correlated with the limit of tetrahedral ordering of Mg, after which local charge-balanced substitution is no
longer maintained.
Spinelloid β-Mg3Ga2GeO8 has cation distribution M1[Mg0.50(2)Ga0.50(2)] M2[Mg0.96(2)Ga0.04(2)] M3[Mg0.77(2) Ga0.23(2)]2 (Ge0.5Ga0.5)2O8 (tetrahedral site occupancies are assumed). Octahedral site size is correlated to Mg distribution, where site volume, site
distortion, and Mg content follow the relation M1<M3<M2. The disordered cation distribution provides local electrical neutrality
in the structure, and stabilization through increased configurational entropy (27.6 J mol−1; eight oxygen basis). Comparison of the crystal structures of Mg1+
N
Ga2−2
N
Ge
N
O4 spinel, β-Mg3Ga2GeO8, and Mg2GeO4 olivine reveals β-Mg3Ga2GeO8 to be a true structural intermediate. Phase transitions across the pseudobinary are necessary to accommodate an increasing
divergence of cation size and valence, with addition of Mg2GeO4 component. Octahedral volume increases while tetrahedral volume decreases from spinel to β-Mg3Ga2GeO8 to olivine, with addition of Mg and Ge, respectively. Furthermore, M-M distances increase regularly across the join, suggesting
that changes in topology reduce cation-cation repulsion.
Received: 9 November 1998 / Revised, accepted: 3 August 1999 相似文献
11.
Andrea Orlando Yves Thibault Alan D. Edgar 《Contributions to Mineralogy and Petrology》2000,139(2):136-145
Experiments ranging from 2 to 3 GPa and 800 to 1300 °C and at 0.15 GPa and 770 °C were performed to investigate the stability
and mutual solubility of the K2ZrSi3O9 (wadeite) and K2TiSi3O9 cyclosilicates under upper mantle conditions. The K2ZrSi3O9–K2TiSi3O9 join exhibits complete miscibility in the P–T interval investigated. With increasing degree of melting the solid solution becomes progressively enriched in Zr, indicating
that K2ZrSi3O9 is the more refractory end member. At 2 GPa, in the more complex K2ZrSi3O9–K2TiSi3O9–K2Mg6Al2Si6O20(OH)4 system, the presence of phlogopite clearly limits the extent of solid solution of the cyclosilicate to more Zr-rich compositions
[Zr/(Zr + Ti) > 0.85], comparable to wadeite found in nature, with TiO2 partitioning strongly into the coexisting mica and/or liquid. However, at 1200 °C, with increasing pressure from 2 to 3 GPa,
the partitioning behaviour of TiO2 changes in favour of the cyclosilicate, with Zr/(Zr + Ti) of the K2(Zr,Ti)Si3O9 phase decreasing from ∼0.9 to ∼0.6. The variation in the Ti content of the coexisting phlogopite is related to its degree
of melting to forsterite and liquid, following the major substitution VITi+VI□=2VIMg.
Received: 26 January 1999 / Accepted: 10 January 2000 相似文献
12.
Edward S. Grew Nikolai N. Pertsev Stanislav Vrána Martin G. Yates Charles K. Shearer Michael Wiedenbeck 《Contributions to Mineralogy and Petrology》1998,131(1):22-38
Kornerupine, (□,Fe,Mg)(Mg,Fe,Al)9(Si,Al,B)5 (O,OH,F)22, has been reported with talc in rocks from six localities worldwide, but only at Chilapila Hill in the Lufilian Arc, Zambia
do textural relationships imply that kornerupine (Krn) equilibrated with talc (Tlc) during a prograde metamorphic event at
T≈ 640 °C, P≈ 13 kbar; a prograde Krn + Tlc assemblage has also been reported from Mautia Hill, Tanzania (P ≤ 13 kbar). In order to estimate possible constraints on the stability range for the kornerupine + talc paragenesis in nature,
we constructed a P-T diagram in the model system MgO-Al2O3-SiO2-H2O (MASH) for seven phases quartz (Qtz), B-free kornerupine sensu stricto, anthophyllite (Ath), chlorite (Chl), cordierite
(Crd), kyanite (Ky), and talc. The minimum pressure for Krn + Tlc + Ky stability in MASH is close to that for Ky + Tlc stability,
i.e., 6–8 kbar, at T≤ 780 °C. However, in the natural system, B2O3 and Na2O are major constituents in Krn and orthoamphibole (Oam), respectively, and dravitic tourmaline (Tur) is widespread. The critical
assemblage alternative to Krn + Tlc in nature is Tur + Oam. The upper pressure limit of Tur + Ath is determined by the upper
pressure for anthophyllite: 7.7–10.5 kbar at 682–794 °C in the MgO-SiO2-H2O system (Chernosky et al. 1985, Am Mineral 70:223–236), and is undoubtedly higher in the presence of Na2O, CaO, and Al2O3. At three of the six localities, talc is a retrograde phase; nonetheless, it possibly equilibrated with kornerupine on the
retrograde path or during a later metamorphic event at P-T conditions appropriate for Ky + Tlc. At the sixth locality (Mulvoj, southwestern Pamir Mountains, Tajikistan), Krn is found
in the same thin section as talc and kyanite and all three minerals formed during a prograde metamorphic event at T≥ 650 °C, P near 7 kbar. However, Krn is restricted to a lens 4 to 6 mm thick of phlogopite + anthophyllite + Tur and it does not touch
either talc or kyanite. A reaction relating the Mulvoj and Chilapila Hill (Krn + Tlc + Ky + Qtz + Tur) parageneses is calculated
from compositions in the Mulvoj rock to be 0.40Tur + 2.55Ath + 1.33H2O + 0.27F = Krn + 2.16Tlc + 0.36B2O3 + 0.02Rutile + 0.19Na2O + 0.17CaO. Given the difference in metamorphic pressures estimated for Mulvoj and Chilapila Hill, Krn + Tlc is inferred
to be favored by increasing pressure as well as by low Na2O and CaO contents. Some FeO, F, Fe2O3, and BeO are present in measurable amounts in at least one of the phases in the Mulvoj and Chilapila Hill whiteschists (e.g.,
Krn contains 0.24–0.67 wt% BeO), but the effect of these constituents is subordinate to that of Na2O, CaO and B2O3. The Krn + Tlc could be a more important assemblage in B-bearing whiteschists than has been reported to date, particularly
at pressures where orthoamphibole is no longer stable.
Received: 21 April 1997 / Accepted: 13 October 1997 相似文献
13.
Fluid inclusions were studied in quartz samples from early (stage I) gold-poor quartz veins and later (stage II) gold- and
sulphide-rich quartz veins from the Wenyu, Dongchuang, Qiangma, and Guijiayu mesothermal gold deposits in the Xiaoqinling
district, China. Fluid inclusion petrography, microthermometry, and bulk gas analyses show remarkably consistent fluid composition
in all studied deposits. Primary inclusions in quartz samples are dominated by mixed CO2-H2O inclusions, which have a wide range in CO2 content and coexist with lesser primary CO2-rich and aqueous inclusions. In addition, a few secondary aqueous inclusions are found along late-healed fractures. Microthermometry
and bulk gas analyses suggest hydrothermal fluids with typically 15–30 mol% CO2 in stage I inclusions and 10–20 mol% CO2 in stage II inclusions. Estimates of fluid salinity decrease from 7.4–9.2 equivalent wt.% NaCl to 5.7–7.4 equivalent wt.%
NaCl between stage I and II. Primary aqueous inclusions in both stages show consistent salinity with, but slightly lower Th
total than, their coexistent CO2-H2O inclusions. The coexisting CO2-rich, CO2-H2O, and primary aqueous inclusions in both stage I and II quartz are interpreted to have been trapped during unmixing of a
homogeneous CO2-H2O parent fluid. The homogenisation temperatures of the primary aqueous inclusions give an estimate of trapping temperature
of the fluids. Trapping conditions are typically 300–370 °C and 2.2 kbar for stage I fluids and 250–320 °C and 1.6 kbar for
stage II fluids. The CO2-H2O stage I and II fluids are probably from a magmatic source, most likely devolatilizing Cretaceous Yanshanian granitoids.
The study demonstrates that gold is largely deposited as pressures and temperatures fall accompanying fluid immiscibility
in stage II veins.
Received: 15 May 1997 / Accepted: 10 June 1998 相似文献
14.
The relative stabilities of orthozoisite, Ca2Al3[O|OH|Si2O7|SiO4], space group Pnma, and the monoclinic polymorph, clinozoisite, space group P21/m, have been investigated using calculations based on density functional theory. It is found that orthozoisite is more stable
than clinozoisite by about 1 kJ mol−1 at zero pressure in the athermal limit. The bulk moduli of the two polymorphs have been calculated to be Bortho=117.5(1.7) GPa and Bclino=136(4) GPa.
Received: 20 March 2000 / Accepted: 26 February 2001 相似文献
15.
High temperature stability limit of phase egg, AlSiO3(OH) 总被引:1,自引:1,他引:0
Shigeaki Ono 《Contributions to Mineralogy and Petrology》1999,137(1-2):83-89
The stability relations of phase egg, AlSiO3(OH), have been investigated at pressures from 7 to 20 GPa, and temperatures from 900 to 1700 °C in a multi-anvil apparatus.
At the lower pressures phase egg breaks down according to the univariant reaction, phase egg = stishovite + topaz-OH, which
extends from 1100 °C at 11 GPa to 1400 °C at 13 GPa where it terminates at an invariant point involving corundum. At pressures
above the invariant point, the stability of phase egg is limited by the breakdown reaction, phase egg = stishovite + corundum + fluid,
which extends from the invariant point to 1700 °C at 20 GPa. Stishovite crystallized in the Al2O3-SiO2-H2O system contains Al2O3, and the amount of Al2O3 increases with increasing temperature. It is inferred that the Al2O3 content is controlled by the charge-balanced substitution of Si4+ by Al3+ and H+. Aluminum-bearing stishovite coexisting with an H2O-rich fluid may contain a certain amount of water. Therefore, phase egg and stishovite in a subducting slab could transport
some H2O into the deep Earth.
Received: 14 October 1998 / Accepted: 19 May 1999 相似文献
16.
Mark I. Pownceby Michael J. Fisher-White 《Contributions to Mineralogy and Petrology》1999,135(2-3):198-211
Detailed phase relations have been determined within the systems Fe2O3-MgO-TiO2 and FeO-MgO-TiO2. Experiments were performed over the temperature interval 1173–1473 K by equilibrating pelletized, fine-grained oxide mixtures
in either inert calcia-stabilized zirconia pots (Fe2O3-MgO-TiO2 system) or evacuated silica tubes (FeO-MgO-TiO2 system). Equilibrium phase assemblages were determined by combined optical microscope, X-ray diffraction and EMP examination.
Phase relations in the Fe2O3-MgO-TiO2 ternary are dominated by the instability of the M2O3 solid solution relative to the phase assemblage M3O4 + M3O5. A miscibility gap along the M2O3 binary also gives rise to two, 3-phase fields (α-M2O3 + M3O5 + M3O4 and α′-M2O3 + M3O5 + M3O4) separated by the M3O4 + M3O5 phase field. Phase relations in the FeO-MgO-TiO2 ternary were divided into two sub-systems. For the FeTiO3-MgTiO3-TiO2 sub-ternary, there is complete solid solution along the M2O3 and M3O5 binary joins at high temperature. At low temperatures (T < 1373 K) the M3O5 pseudobrookite solid solution decomposes to M2O3 + TiO2. Increasing the concentration of MgO in M3O5 phase results in a decrease in the temperature at which M3O5 becomes unstable and compositional tie lines linking M2O3 and TiO2 fan out, before the appearance of a three-phase region where M2O3, M3O5, and TiO2 coexist. Within the expanded FeO-MgO-TiO2 system, at temperatures above ∼1273 K there is a continuous solid solution along the M3O4 binary. At low temperatures (T < 1273 K) the Mg2TiO4 end-member breaks down to MgO and MgTiO3. The M3O4 phase shows significant non-stoichiometry, down to at least 1173 K. Fe2+-Mg partitioning data were obtained for coexisting M2O3-M3O5 and M2O3-M3O4 pairs in the FeO-MgO-TiO2 ternary. Assuming a regular solution mixing model for all phases, the M2O3 and M3O4 solid solutions were both found to exhibit moderate positive deviations from ideality (∼2600 J/mol), whereas the data for
the M3O5 binary suggest close to ideal behaviour.
Received: 22 May 1998 / Accepted: 3 November 1998 相似文献
17.
A series of experiments on the fluid-absent melting of a quartz-rich aluminous metagreywacke has been carried out. In this
paper, we report the chemical composition of the phases present in the experimental charges as determined by electron microprobe.
This analytical work includes biotite, plagioclase, orthopyroxene, garnet, cordierite, hercynite, staurolite, gedrite, oxide,
and glass, over the range 100–1000 MPa, 780–1025 °C. Biotites are Na- and Mg-rich, with Ti contents increasing with temperature.
The compositions of plagioclase range from An17 to An35, with a significant orthoclase component, and are always different from the starting minerals. At high temperature, plagioclase
crystals correspond to ternary feldspars with Or contents in the range 11–20 mol%. Garnets are almandine pyrope grossular
spessartine solid solutions, with a regular and significant increase of the grossular content with pressure. All glasses are
silicic (SiO2 = 67.6–74.4 wt%), peraluminous, and leucocratic (FeO + MgO = 0.9–2.9 wt%), with a bulk composition close to that of peraluminous
leucogranites, even for degrees of melting as high as 60 vol.%. With increasing pressure, SiO2 contents decrease while K2O increases. At any pressure, the melt compositions are more potassic than the water-saturated granitic minima. The H2O contents estimated by mass balance are in the range 2.5–5.6 wt%. These values are higher than those predicted by thermodynamic
models. Modal compositions were estimated by mass balance calculations and by image processing of the SEM photographs. The
positions of the 20 to 70% isotects (curves of equal proportion of melt) have been located in the pressure-temperature space
between 100 MPa and 1000 MPa. With increasing pressure, the isotects shift toward lower temperature between 100 and 200 MPa,
then bend back toward higher temperature. The melting interval increases with pressure; the difference in temperature between
the 20% and the 70% isotects is 40 °C at 100 MPa, and 150 °C at 800 MPa. The position of the isotects is interpreted in terms
of both the solubility of water in the melt and the nature of the reactions involved in the melting process. A comparison
with other partial melting experiments suggests that pelites are the most fertile source rocks above 800 MPa. The difference
in fertility between pelites and greywackes decreases with decreasing pressure. A review of the glass compositions obtained
in experimental studies demonstrates that partial melting of fertile rock types in the crust (greywackes, pelites, or orthogneisses)
produces only peraluminous leucogranites. More mafic granitic compositions such as the various types of calk-alkaline rocks,
or mafic S-type rocks, have never been obtained during partial melting experiments. Thus, only peraluminous leucogranites
may correspond to liquids directly formed by partial melting of metasediments. Other types of granites involve other components
or processes, such as restite unmixing from the source region, and/or interaction with mafic mantle-derived materials.
Received: 11 July 1995 / Accepted: 27 February 1997 相似文献
18.
Summary Batiferrite, ideally Ba[Ti2Fe10]O19, was found in the Quaternary volcanic rocks near üdersdorf, Graulai, and Altburg, western Eifel area, Germany. The new mineral
typically occurs as euhedral platy grains in cavities of melilite- and leucite-nephelinite basalts. Associated minerals are
hematite, magnetite, titanite, g?tzenite, clinopyroxene, nepheline, and biotite. It exhibits a hexagonal tabular habit flattened
on {0001}, diameter 0.5–1 mm, thickness 20–125 μm, and {10&1macr;3}, {10&1macr;0} as observable forms. The mineral is opaque, of black
color with submetallic lustre, and shows a ferrimagnetic behavior. VHN50 is 793 with a range of 710–841 from ten indentations. The quantitative reflectance measurements of Ro/Re on oriented grains in air and oil immersion, respectively, are [%]: for 470 nm 22.1/20.1 and 8.4/7.1, for 546 nm 21.0/19.4
and 7.8/6.6, for 589 nm 20.2/18.8 and 7.4/6.3, and for 650 nm 19.3/18.3 and 6.8/5.9. The bireflectance is distinct (air) to
weak (oil), and parallel (0001) a moderate anisotropy with straight extinction can be observed. Typical microprobe analyses
give [wt%] K2O 0.28–0.33, Na2O 0.17–0.20, SrO 0.46–0.55, BaO 11.80–12.17, MgO 1.27–1.47, Al2O3 0.31–0.33, TiO2 13.11–13.63, MnO 2.38–2.57, Fe2O3 61.36–63.12, FeO 5.49–5.86 (Fe3+/Fe2+ calculated for charge compensation), which is equivalent to (Ba0.84Na0.06K0.06Sr0.05)1.01(Fe8.48
3+Fe0.86
2+Ti1.82Mg0.37Mn0.37Al0.06)11.96O19 as the average composition based on 19 oxygen atoms. Batiferrite is a magnetoplumbite-type mineral with hexagonal symmetry,
space group P6
3
/mmc (no. 194), a = 5.909(1) ?, c = 23.369(4) ?, V = 706.6(2) ?3, Z = 2, and a calculated density of 5.016 gcm−3. The structure was refined to R1 = 0.031 for 278 unique reflections with Fo
2 > 4σ (Fo
2) and R1 = 0.079 for all 452 unique observations using single crystal X-ray data. The strongest reflections of the X-ray powder diffraction
pattern are [d
obs, I/Io, (hkl)]: 2.631, 100, (114); 2.799, 80, (107); 1.478, 70, (220); 2.429, 60, (203); 1.672, 50, (217). The new mineral is comparable to the other Ba containing magnetoplumbite-type minerals haggertyite and
hawthorneite, the iron content, however, is much higher and in the range of magnetoplumbite. The large cation site (A) is
dominated by Ba, and four of the five remaining crystallographic cation sites in the structure are dominated by Fe (M1, 2,
3, 5), the octahedrally coordinated M4-site is dominated by Ti. No oxygen vacancy on the O3-site like in plumboferrite can
be observed. Batiferrite is named for its main chemical composition and the relationship to the M-type hexaferrites (polytype
5H).
Received December 14, 1999; accepted March 2, 2000 相似文献
Zusammenfassung Batiferrit, ein neues ferrimagnetisches Mineral des Magnetoplumbit-Typs aus den quart?ren Vulkaniten der West-Eifel, Deutschland Das neue Mineral Batiferrite, mit der Idealformel Ba[Ti2Fe10]O19, wurde an drei Fundpunkten in den Quart?ren Vulkangesteinen der westlichen Eifel, Deutschland, in der N?he von üdersdorf, Graulai und Altburg gefunden. Das neue Mineral tritt typischerweise bl?ttchenf?rmig in kleinen Hohlr?umen von Melilith- und Leucit-Nephelininit Basalten auf. Vergesellschaftete Minerale sind H?matit, Magnetit, Titanit, G?tzenit, Klinopyroxen, Nephelin und Biotit. Der Habitus ist hexagonal tafelig nach {0001}, mit einem Durchmesser von 0.5–1 mm und einer Dicke von 20–125 μm, zus?tzlich k?nnen die Formen {10&1macr;3} und {10&1macr;0} beobachtet werden. Das Mineral ist opak, hat eine schwarze Farbe mit einem leicht metallischen Glanz, und ist ferromagnetisch. Die H?rte VHN50 ist 793 mit einem Bereich von 710–841 aus 10 Eindruckbestimmungen. Die quantitativen Reflexionsmessungen von Ro/Re an orientierten K?rnern in Luft beziehungsweise ?limmersion, ergaben [%]: für 470 nm 22.1/20.1 und 8.4/7.1, für 546 nm 21.0/19.4 und 7.8/6.6, für 589 nm 20.2/18.8 und 7.4/6.3, und für 650 nm 19.3/18.3 und 6.8/5.9. Die Bireflexion ist deutlich (Luft) bis schwach (?l) und parallel (0001) kann eine mittlere Anisotropie mit gerader Ausl?schung beobachtet werden. Eine typische Mikrosondenanalyse ergibt [wt%] K2O 0.28–0.33, Na2O 0.17–0.20, SrO 0.46–0.55, BaO 11.80–12.17, MgO 1.27–1.47, Al2O3 0.31–0.33, TiO2 13.11–13.63, MnO 2.38–2.57, Fe2O3 61.36–63.12, FeO 5.49–5.86 (Fe3+/Fe2+ berechnet zum Ladungsausgleich), die mittlere chemische Formel auf der Basis von 19 Sauerstoffatomen lautet (Ba0.84Na0.06K0.06Sr0.05)1.01 (Fe8.48 3+Fe0.86 2+Ti1.82Mg0.37Mn0.37Al0.06)11.96O 19. Batiferrit ist ein Mineral der Magnetoplumbitgruppe, hat hexagonale Symmetrie mit der Raumgruppe P63/mmc (Nr. 194), a = 5.909(1) ?, c = 23.369(4) ?, V = 706.6(2) ?3, Z = 2, und einer berechneten Dichte von 5.016 gcm−3. Die Struktur wurde aus Einkristall-R?ntgendaten bis zu einem R1-Wert von 0.031 für 278 Fo 2 > 4σ(Fo 2), und einem R1-Wert von 0.079 für alle 452 Fo 2 verfeinert. Die st?rksten Beugungsreflexe der Pulver-R?ntgendaten sind [dobs, I/Io, (hkl)]: 2.631, 100, (114); 2.799, 80, (107); 1.478, 70, (220); 2.429, 60, (203); 1.672, 50, (217). Das neue Mineral weist deutliche ?hnlichkeiten zu den anderen beiden Ba-reichen Mineralen Haggertyit und Hawthorneit der Magnetoplumbit-Gruppe auf, jedoch ist der Eisengehalt wesentlich h?her und im Bereich des Minerals Magnetoplumbit. Der gro?e Kationenplatz (A) ist von Barium dominiert, vier (M1, 2, 3, 5) der restlichen fünf kristallographischen Kationenpl?tze in der Struktur sind fast ausschlie?lich mit Fe, die oktaedrisch koordinierte M4-Position ist überwiegend mit Ti besetzt. An der O3-Position konnte kein Sauerstoffdefizit wie in Plumboferrit festgestellt werden. Batiferrit ist nach seiner chemischen Beschaffenheit und nach seiner Zugeh?hrigkeit zu den M-Typ Hexaferriten (Polytyp 5H) benannt.
Received December 14, 1999; accepted March 2, 2000 相似文献
19.
Akira Takada C. R. A. Catlow G. D. Price C. L. Hayward 《Physics and Chemistry of Minerals》1997,24(6):423-431
The structure and electronic properties of trigonal and orthorhombic boric oxide (B2O3) are studied using periodic ab initio Hartree-Fock method. The optimised structural parameters for two B2O3 polymorphs are in good agreement with experimental data. The analyses of their electronic structures provide insights into the chemical nature of the B–O bond and the way in which it changes with the coordination number around boron and oxygen. Our quantum-chemical study suggests that the orthorhombic form is more ionic than the trigonal form and that the coordination number of boron around oxygen plays a more dominant role than that of oxygen around boron in B2O3 crystals. 相似文献
20.
A set of sheeted quartz veins cutting 380 Ma monzogranite at Sandwich Point, Nova Scotia, Canada, provide an opportunity to
address issues regarding fluid reservoirs and genesis of intrusion-related gold deposits. The quartz veins, locally with arsenopyrite
(≤5%) and elevated Au–(Bi–Sb–Cu–Zn), occur within the reduced South Mountain Batholith, which also has other zones of anomalous
gold enrichment. The host granite intruded (P = 3.5 kbars) Lower Paleozoic metaturbiditic rocks of the Meguma Supergroup, well known for orogenic vein gold mineralization.
Relevant field observations include the following: (1) the granite contains pegmatite segregations and is cut by aplitic dykes
and zones (≤1–2 m) of spaced fracture cleavage; (2) sheeted veins containing coarse, comb-textured quartz extend into a pegmatite
zone; (3) arsenopyrite-bearing greisens dominated by F-rich muscovite occur adjacent the quartz veins; and (4) vein and greisen
formation is consistent with Riedel shear geometry. Although these features suggest a magmatic origin for the vein-forming
fluids, geochemical studies indicate a more complex origin. Vein quartz contains two types of aqueous fluid inclusion assemblages
(FIA). Type 1 is a low-salinity (≤3 wt.% equivalent NaCl) with minor CO2 (≤2 mol%) and has T
h = 280–340°C. In contrast, type 2 is a high-salinity (20–25 wt.% equivalent NaCl), Ca-rich fluid with T
h = 160–200°C. Pressure-corrected fluid inclusion data reflect expulsion of a magmatic fluid near the granite solidus (650°C)
that cooled and mixed with a lower temperature (400°C), wall rock equilibrated, Ca-rich fluid. Evidence for fluid unmixing,
an important process in some intrusion-related gold deposit settings, is lacking. Stable isotopic (O, D, S) analyses for quartz,
muscovite and arsenopyrite samples from vein and greisens indicate the following: (1) δ18Oqtz = +11.7‰ to 17.8‰ and δ18Omusc = +10.7‰ to +11.2‰; (2) δDmusc = −44‰ to−54‰; and (3) δ34Saspy = +7.8‰ to +10.3‰. These data are interpreted, in conjunction with fluid inclusion data, to reflect contamination of a magmatic-derived
fluid (d18OH2O {\delta^{{{18}}}}{{\hbox{O}}_{{{{\rm{H}}_{{2}}}{\rm{O}}}}} ≤ +10‰) by an external fluid (d18OH2O {\delta^{{{18}}}}{{\hbox{O}}_{{{{\rm{H}}_{{2}}}{\rm{O}}}}} ≥ +15‰), the latter having equilibrated with the surrounding metasedimentary rocks. The δ34S data are inconsistent with a direct igneous source based on other studies for the host intrusion (d18OH2O {\delta^{{{18}}}}{{\hbox{O}}_{{{{\rm{H}}_{{2}}}{\rm{O}}}}} = +5‰) and are, instead, consistent with an external reservoir for sulphur based on δ34SH2S data for the surrounding metasedimentary rocks. Divergent fluid reservoirs are also supported by analyses of Pb isotopes
for pegmatitic K-feldspar and vein arsenopyrite. Collectively the data indicate that the vein- and greisen-forming fluids
had a complex origin and reflect both magmatic and non-magmatic reservoirs. Thus, although the geological setting suggests
a magmatic origin, the geochemical data indicate involvement of multiple reservoirs. These results suggest multiple reservoirs
for this intrusion-related gold deposit setting and caution against interpreting the genesis of intrusion-related gold deposit
mineralization in somewhat analogous settings based on a limited geochemical data set. 相似文献